US3047511A - Mineral acid inhibitor - Google Patents
Mineral acid inhibitor Download PDFInfo
- Publication number
- US3047511A US3047511A US835429A US83542959A US3047511A US 3047511 A US3047511 A US 3047511A US 835429 A US835429 A US 835429A US 83542959 A US83542959 A US 83542959A US 3047511 A US3047511 A US 3047511A
- Authority
- US
- United States
- Prior art keywords
- inhibitor
- percent
- butyn
- acid
- mineral acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003112 inhibitor Substances 0.000 title claims description 15
- 239000002253 acid Substances 0.000 title claims description 14
- 229910052500 inorganic mineral Inorganic materials 0.000 title 1
- 239000011707 mineral Substances 0.000 title 1
- XRGPFNGLRSIPSA-UHFFFAOYSA-N butyn-2-one Chemical compound CC(=O)C#C XRGPFNGLRSIPSA-UHFFFAOYSA-N 0.000 claims description 9
- 238000005260 corrosion Methods 0.000 claims description 9
- 230000007797 corrosion Effects 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000011260 aqueous acid Substances 0.000 description 4
- 235000011167 hydrochloric acid Nutrition 0.000 description 3
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- -1 ferrous metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 241000282461 Canis lupus Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/068—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors compounds containing a C=C bond
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/04—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in markedly acid liquids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/933—Acidizing or formation destroying
- Y10S507/934—Acidizing or formation destroying with inhibitor
Definitions
- This invention relates to a corrosion inhibitor for use in aqueous, non-oxidizing acids to inhibit the corrosion of ferrous based metals and nickel by such acids. It more particularly relates to the use of 3-butyn-2-one as a corrosion inhibitor for use in such acids.
- aqueous acid any composition comprising a non-oxidizing acid and water and does not mean to exclude the presence of other substances. Only a small amount of the inhibitor is needed in the aqueous acids, as little as a few thousandths of 1 percent, based on the weight of aqueous acid, significantly reducing the corrosion of iron, steel or nickel exposed to the acid. The degree of inhibition increases with the concentration of the inhibitor up to a level of about 1 percent. Beyond this point little added protection of the metal is obtained by the use of more inhibitor. Generally, it is preferred to use the inhibitor at al evel of about 0.1 to 0.4 percent of the total weight of acid, this amount being adequate for most purposes.
- the 3-butyn-2-one is an etfective inhibitor not only at ordinary temperatures, but also at elevated temperatures up to the decomposition point of the compound. High effectiveness is shown at 150 Fahrenheit and higher. Moreover, it is effective as an inhibitor in various concentrations of acids; e.g., even in commercial concentrated hydrochloric acids containing up to 37 percent hydrogen chloride.
- inhibitors particularly useful include metal-picl 1ing, cleaning and polishing baths, oil well-acidizing solutions, boiler-cleaning compositions and the like.
- the 3-butyn-2-one is easily made by the controlled electrolytic oxidation of the corresponding alkynol in acid solution according to the method reported by Wolf, Chem. Ber., 87, 668-76 (1954).
- An aqueous solution of a non-oxidizing acid containing from about 0.1 to about 1 percent of 3 butyn-2- one corrosion inhibitor.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Description
3,047,511 Patented July 31, 1962 This invention relates to a corrosion inhibitor for use in aqueous, non-oxidizing acids to inhibit the corrosion of ferrous based metals and nickel by such acids. It more particularly relates to the use of 3-butyn-2-one as a corrosion inhibitor for use in such acids.
In practicing this invention, 3-butyn-2-one HOgO-i'J-CHQ is dissolved in the aqueous acid, the corrosive action of which is to be inhibited. By aqueous acid is meant any composition comprising a non-oxidizing acid and water and does not mean to exclude the presence of other substances. Only a small amount of the inhibitor is needed in the aqueous acids, as little as a few thousandths of 1 percent, based on the weight of aqueous acid, significantly reducing the corrosion of iron, steel or nickel exposed to the acid. The degree of inhibition increases with the concentration of the inhibitor up to a level of about 1 percent. Beyond this point little added protection of the metal is obtained by the use of more inhibitor. Generally, it is preferred to use the inhibitor at al evel of about 0.1 to 0.4 percent of the total weight of acid, this amount being adequate for most purposes.
The 3-butyn-2-one is an etfective inhibitor not only at ordinary temperatures, but also at elevated temperatures up to the decomposition point of the compound. High effectiveness is shown at 150 Fahrenheit and higher. Moreover, it is effective as an inhibitor in various concentrations of acids; e.g., even in commercial concentrated hydrochloric acids containing up to 37 percent hydrogen chloride.
Applications in which the inhibitor is particularly useful include metal-picl 1ing, cleaning and polishing baths, oil well-acidizing solutions, boiler-cleaning compositions and the like.
The 3-butyn-2-one is easily made by the controlled electrolytic oxidation of the corresponding alkynol in acid solution according to the method reported by Wolf, Chem. Ber., 87, 668-76 (1954).
In order to demonstrate the effectiveness of the inhibitor 0.4 percent of the 3-butyn-2-one was put into a 10 percent aqueous solution of hydrochloric acid ml.) held at 150 F. and a coupon (2.75 in. x 1.0 in. x 0.12 in.) of AISI-l020 mild steel was suspended in the solution for 16 hrs. Thereafter the coupon was cleaned, dried and weighted to determine the amount of metal dissolved. Table I compares the result of this test with that obtained using a similar metal coupon in a non-inhibited 10 percent aqueous solution of hydrochloric acid.
TABLE I Corrosion of AISI-1020 Mild Steel by 10 Percent HCl in the Presence of 0.4 Percent 3-Butyn-2-One Concentration Concentration Soln. Corrosion Example No. 3-Butyn-2- Hydrochloric Tern Rate,
One (Percent) Acid (Percent) F.) lbJftfl/day 0.4 10 O. 077 (no inhibitor). 10 1 Results generally paralleling those shown in Table I were obtained when similar tsets were run at lower temperatures, with lower or higher concentration of HCl, or with other ferrous metals or nicket as the test metal. Likewise, other aqueous non-oxidizing acids, such as phosphoric, sulfuric and acetic aids are similary inhibited.
Various modifications can be made in the present invention without departing from the spirt or scope thereof for it is understood that I limit myself only as defined in the appended claims.
I claim:
1. An aqueous solution of a non-oxidizing acid containing an eifective amount of 3-butyn-2-one corrosion inhibitor.
2. An aqueous solution of a non-oxidizing acid containing from about 0.1 to about 1 percent of 3 butyn-2- one corrosion inhibitor.
References Cited in the file of this patent UNITED STATES PATENTS 2,106,181 Kreimeier Jan. 25, 1938 2,838,458 Baohtel June 10, 1958 2,905,588 Youngson Sept. 22, 1959 2,913,408 Pumpelly et-al Nov. 17, 1959 FOREIGN PATENTS 468,231 Italy Dec. 29, 1951 235,291 Switzerland Apr. 3, 1945
Claims (1)
1. AN AQUEOUS SOLUTION OF A NON-OXIDIZING ACID CONTAINING AN EFFECTIVE AMOUNT OF 3-BUTYN-2-ONE CORROSION INHIBITOR.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US835429A US3047511A (en) | 1959-08-24 | 1959-08-24 | Mineral acid inhibitor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US835429A US3047511A (en) | 1959-08-24 | 1959-08-24 | Mineral acid inhibitor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3047511A true US3047511A (en) | 1962-07-31 |
Family
ID=25269483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US835429A Expired - Lifetime US3047511A (en) | 1959-08-24 | 1959-08-24 | Mineral acid inhibitor |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3047511A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6068056A (en) * | 1999-10-13 | 2000-05-30 | Schlumberger Technology Corporation | Well treatment fluids comprising mixed aldehydes |
| US11892193B2 (en) | 2017-04-18 | 2024-02-06 | Nortek Air Solutions Canada, Inc. | Desiccant enhanced evaporative cooling systems and methods |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2106181A (en) * | 1936-07-20 | 1938-01-25 | Du Pont | Ethynyl carbinols and process of preparing the same |
| CH235291A (en) * | 1941-06-18 | 1944-11-30 | Ig Farbenindustrie Ag | Process for reducing the corrosion of metals by acidic liquids. |
| US2838458A (en) * | 1955-09-30 | 1958-06-10 | Dow Chemical Co | Inhibited methyl chloroform |
| US2905588A (en) * | 1957-04-26 | 1959-09-22 | Dow Chemical Co | Growing and protection of crops and compositions therefor containing an ethynyl ketone |
| US2913408A (en) * | 1956-12-28 | 1959-11-17 | Dow Chemical Co | Corrosion inhibitors for ferrous metals in aqueous solutions of non-oxidizing acids |
-
1959
- 1959-08-24 US US835429A patent/US3047511A/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2106181A (en) * | 1936-07-20 | 1938-01-25 | Du Pont | Ethynyl carbinols and process of preparing the same |
| CH235291A (en) * | 1941-06-18 | 1944-11-30 | Ig Farbenindustrie Ag | Process for reducing the corrosion of metals by acidic liquids. |
| US2838458A (en) * | 1955-09-30 | 1958-06-10 | Dow Chemical Co | Inhibited methyl chloroform |
| US2913408A (en) * | 1956-12-28 | 1959-11-17 | Dow Chemical Co | Corrosion inhibitors for ferrous metals in aqueous solutions of non-oxidizing acids |
| US2905588A (en) * | 1957-04-26 | 1959-09-22 | Dow Chemical Co | Growing and protection of crops and compositions therefor containing an ethynyl ketone |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6068056A (en) * | 1999-10-13 | 2000-05-30 | Schlumberger Technology Corporation | Well treatment fluids comprising mixed aldehydes |
| US11892193B2 (en) | 2017-04-18 | 2024-02-06 | Nortek Air Solutions Canada, Inc. | Desiccant enhanced evaporative cooling systems and methods |
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