US2902344A - Process for the preparation of hydrous potassium magnesium sulfate and potassium sulfate from kainite containing sodium chloride - Google Patents
Process for the preparation of hydrous potassium magnesium sulfate and potassium sulfate from kainite containing sodium chloride Download PDFInfo
- Publication number
- US2902344A US2902344A US644207A US64420757A US2902344A US 2902344 A US2902344 A US 2902344A US 644207 A US644207 A US 644207A US 64420757 A US64420757 A US 64420757A US 2902344 A US2902344 A US 2902344A
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- United States
- Prior art keywords
- potassium
- sulfate
- kainite
- sodium chloride
- potassium sulfate
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title claims description 40
- BMQVDVJKPMGHDO-UHFFFAOYSA-K magnesium;potassium;chloride;sulfate;trihydrate Chemical compound O.O.O.[Mg+2].[Cl-].[K+].[O-]S([O-])(=O)=O BMQVDVJKPMGHDO-UHFFFAOYSA-K 0.000 title claims description 23
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 title claims description 20
- 229910052939 potassium sulfate Inorganic materials 0.000 title claims description 20
- 239000011780 sodium chloride Substances 0.000 title claims description 20
- WZISDKTXHMETKG-UHFFFAOYSA-H dimagnesium;dipotassium;trisulfate Chemical compound [Mg+2].[Mg+2].[K+].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O WZISDKTXHMETKG-UHFFFAOYSA-H 0.000 title claims description 19
- 235000011151 potassium sulphates Nutrition 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 10
- 238000002360 preparation method Methods 0.000 title description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 10
- 239000012452 mother liquor Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 5
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 2
- 239000002609 medium Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 claims 1
- GMLLYEDWRJDBIT-UHFFFAOYSA-J magnesium;dipotassium;disulfate Chemical compound [Mg+2].[K+].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GMLLYEDWRJDBIT-UHFFFAOYSA-J 0.000 description 18
- 238000000354 decomposition reaction Methods 0.000 description 14
- 229910001868 water Inorganic materials 0.000 description 13
- 239000000203 mixture Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000000926 separation method Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000012267 brine Substances 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 241000612182 Rexea solandri Species 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- AAIXGPLMFDSDPW-UHFFFAOYSA-K magnesium;potassium;chloride;sulfate Chemical compound [Mg+2].[K]Cl.[O-]S([O-])(=O)=O AAIXGPLMFDSDPW-UHFFFAOYSA-K 0.000 description 1
- OJXVUEMVNWMNCR-UHFFFAOYSA-L magnesium;potassium;sulfate Chemical compound [Mg+2].[K+].[O-]S([O-])(=O)=O OJXVUEMVNWMNCR-UHFFFAOYSA-L 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000001120 potassium sulphate Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- -1 schoenite or leonite Chemical compound 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/12—Preparation of double sulfates of magnesium with sodium or potassium
Definitions
- the present invention relates to the manufacture of hydrous potassium magnesium sulfate and of potassium sulfate from potassium chloride-magnesium sulfate minerals, such as kainite.
- the present invention provides a process for the manufacture of hydrous potassium magnesium sulfate by the decomposition of kainite, combined with the manufacture of potassium sulfate by decomposition of the hydrous potassium magnesium sulfate with water, wherein the decomposition of the kainite is effected by means of brines consisting of or containing the salt solution that constitute therunoff of the decomposition of the hydrous potassium magnesium sulfate.
- the washing liquors running off from the potassium magnesium sulfate and/or those from the sodium chloride in the first stage may also be used for the decomposition of -the kainite.
- the potassium sulfate which is a more valuable product for use as a fertilizer than the hydrous potassium magnesium sulfate, can be produced in a cycle of operations which starts with the decomposition of the kainite and in which the circulation of liquids as well as the potassium losses in the rejected end brines are reduced to a minimum.
- the residual potassium contents of the rejected end brines which are of the order of 2-3% by weight, may, if desired, be recovered by known processes.
- the subsequent decomposition of the hydrous potassium magnesium sulfate is effected by water in a known manner, preferably at about 45 C. at which temperature the ratio of solubilities of potassium sulfate and magnesium sulfate is most favourable for dissolving a maximum of magnesium sulfate and a minimum of potassium sulfate.
- Kanite is decomposed with mother liquor from the separation of potassium sulfate (step (d) below);
- reaction mixture is admixed with a separating liquor, preferably the mother liquor from a preceding separation (step (c) below);
- step (c) The potassium magnesium sulfate (schoenite or leonite) fines are separated from the sodium chloride sediment by decantation or the like, the decantated liquor is filtered, the filtrate is recycled to step (b) hereinbefore; the filter residue and NaCl 'are washed separately, the washing liquors are optionally recycled to step (b);
- step (d) The residue of step (c), being schoenite or leonite, is decomposed with water, preferably at about 45 C., the reaction mixture is filtered;
- step (e) The filtrate from step (d) is recycled to the decomposition of kainite (step (a)); the filter residue is potassium sulfate.
- Example 1 138 g. of schoenite of any desired provenience of the following composition (percent by weight):
- the filtrate (245 g.) is mixed, as a decomposition brine, with 204 g. of crude kainite ground to a fineness-so as to passa 35 mesh sieve and having the following composi- K' Mg" S04" Cl Na' Ca" H2O l1. 33 6. 98 28. 83 2G. 37 10. 8 0. l2
- the mixture is vigorously shaken first at 40 C., then at 20 C.
- the supernatant containing the bulk ofthe schoenite thus produced in very fine crystals in suspension is separated from the rapidly settling coarser crystals of NaCl.
- the separation may be repeated, if desired, upon the addition of some more separating liquor.
- the decanted liquor is filtered.
- the filtrate is recycled as a separating liquor to the stage where the schoenite is separated from sodium chloride.
- the schoenite is washed with little water and filtered off.
- the yield is 171.1 g. of schoenite of a similar composition as indicated above in this example.
- the sodium chloride is ltered off, washed and dried.
- Example 2 245 g. of mother liquors (iltrate) obtained in the decomposition of the schoenite to the K2SO4 according to Example 1 is combined with 82 g.V of the Washing watersl running 01T the schoenite and NaCl in the first stage of the operation described in Example 1. The combined liquor is used for the decomposition of 264 g. of crudev kainite of the same composition as in Example 1. In the manner described in Example l, 185.5 g. of schoenite of the following composition (percent by weight) is obtained:
- the yield of NaCl is 44.3 g. of the following composition (percent by weight):
- Example 34 245 g. of brine resulting from the conversion of schoenite to K2SO4 is combined with 110 g. of mother liquor resulting from the decomposition of kainite to schoenite, both as described in Example l.
- the combined liquor is used as decomposition and separating liquor for 292 g. of kainite ground to a degree of fineness so as to lpass through a 35 mesh sieve and having the following corn- ⁇ position (percent by weight):
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Sept. 1, 1959 GL' CEVIDALLI ET AL PROCESS FOR THE PREPARATION OF' HYDROUS POTASSIUM MAGNESIUM SULFATE AND POTASSIUM SULFATE FROM KAINITE CONTAINING SODIUM CHLORIDE Filed March 6, 1957 A Trae/VWS f' a 2,902,344 'Patented Sept. 1, 1959 Guidobaldo Cevidalli, Fulvio Marchi, and Pietro Saccardo, Milan, Italy, assignors to Sincat Societ Industriale Catanese S.p.A., Milan, Italy Application March 6, 19.57, Serial No. 644,207 Claims priority, application Italy September 14, 1956 s claims. (c1. 23-121) The present invention relates to the manufacture of hydrous potassium magnesium sulfate and of potassium sulfate from potassium chloride-magnesium sulfate minerals, such as kainite.
The difficulties connected with the processing of kainite have been set out in the copeuding patent application Ser. No. 644,206. This latter specification claims a process for the conversion of kainite into hydrous potassium magnesium sulfate, such as schoenite or leonite, by reaction with water in a known manner, wherein the naturally present sodium chloride is removed by the addition to the reaction mixture of a separating liquor in which the coarser sodium chloride crystals settle more rapidly than the finer schoenite or leonite crystals, so that the latter can be removed from thevformerv by decantation of the like operation. According to the cognate invention, the mother liquor remaining after the separation of the schoenite or leonite crystals from the sodium chloride sediment are used as the separating liquor.
The present invention provides a process for the manufacture of hydrous potassium magnesium sulfate by the decomposition of kainite, combined with the manufacture of potassium sulfate by decomposition of the hydrous potassium magnesium sulfate with water, wherein the decomposition of the kainite is effected by means of brines consisting of or containing the salt solution that constitute therunoff of the decomposition of the hydrous potassium magnesium sulfate.
The washing liquors running off from the potassium magnesium sulfate and/or those from the sodium chloride in the first stage may also be used for the decomposition of -the kainite.
In this manner, the potassium sulfate which is a more valuable product for use as a fertilizer than the hydrous potassium magnesium sulfate, can be produced in a cycle of operations which starts with the decomposition of the kainite and in which the circulation of liquids as well as the potassium losses in the rejected end brines are reduced to a minimum. The residual potassium contents of the rejected end brines, which are of the order of 2-3% by weight, may, if desired, be recovered by known processes.
The decomposition of the kainite into schoenite and MgCl2 and the separation of the potassium magnesium sulfate fines from the coarser sodium chloride proceeds in principle in the manner described in specification Ser. No. 644,206.
The subsequent decomposition of the hydrous potassium magnesium sulfate is effected by water in a known manner, preferably at about 45 C. at which temperature the ratio of solubilities of potassium sulfate and magnesium sulfate is most favourable for dissolving a maximum of magnesium sulfate and a minimum of potassium sulfate.
The entire cycle of operation can thus briefly be summarized with reference to the attached drawing which shows a comprehensive ow sheet of the overall kainite conversion procedure.
'tion (percent in weight):
(a) Kanite is decomposed with mother liquor from the separation of potassium sulfate (step (d) below);
(b) The reaction mixture is admixed with a separating liquor, preferably the mother liquor from a preceding separation (step (c) below);
. (c) The potassium magnesium sulfate (schoenite or leonite) fines are separated from the sodium chloride sediment by decantation or the like, the decantated liquor is filtered, the filtrate is recycled to step (b) hereinbefore; the filter residue and NaCl 'are washed separately, the washing liquors are optionally recycled to step (b);
` (d) The residue of step (c), being schoenite or leonite, is decomposed with water, preferably at about 45 C., the reaction mixture is filtered;
(e) The filtrate from step (d) is recycled to the decomposition of kainite (step (a)); the filter residue is potassium sulfate.
The invention is illustrated by the following examples to which it is not limited.
Example 1 138 g. of schoenite of any desired provenience of the following composition (percent by weight):
K- Mgjso," Ca" Na- C1' H20 is shaken at 45 with 138 cc. of Water. Most of the magnesium sulfate dissolved while most of the potassium sulfate remains undissolved. The mixture is filtered, the filter residue is dried.
The filtrate (245 g.) is mixed, as a decomposition brine, with 204 g. of crude kainite ground to a fineness-so as to passa 35 mesh sieve and having the following composi- K' Mg" S04" Cl Na' Ca" H2O l1. 33 6. 98 28. 83 2G. 37 10. 8 0. l2
The mixture is vigorously shaken first at 40 C., then at 20 C. The supernatant containing the bulk ofthe schoenite thus produced in very fine crystals in suspension is separated from the rapidly settling coarser crystals of NaCl. The separation may be repeated, if desired, upon the addition of some more separating liquor.
The decanted liquor is filtered. The filtrate is recycled as a separating liquor to the stage where the schoenite is separated from sodium chloride.
The schoenite is washed with little water and filtered off. The yield is 171.1 g. of schoenite of a similar composition as indicated above in this example.
After drying at C., the product weighs 151.8 g. :and has the following composition:
The sodium chloride is ltered off, washed and dried.
The yield is 31.4 g. of the following composition:
K' Mg S04" Gl' Na' Ca" n In this example the Washing Waters are rejected. The yield in potassium is about 63%. l
Example 2 245 g. of mother liquors (iltrate) obtained in the decomposition of the schoenite to the K2SO4 according to Example 1 is combined with 82 g.V of the Washing watersl running 01T the schoenite and NaCl in the first stage of the operation described in Example 1. The combined liquor is used for the decomposition of 264 g. of crudev kainite of the same composition as in Example 1. In the manner described in Example l, 185.5 g. of schoenite of the following composition (percent by weight) is obtained:
The yield of NaCl is 44.3 g. of the following composition (percent by weight):
1;- Mgu sol" oa Naoi' H10 The total potassium yield is about 68%.
Example 34 245 g. of brine resulting from the conversion of schoenite to K2SO4 is combined with 110 g. of mother liquor resulting from the decomposition of kainite to schoenite, both as described in Example l. The combined liquor is used as decomposition and separating liquor for 292 g. of kainite ground to a degree of fineness so as to lpass through a 35 mesh sieve and having the following corn-` position (percent by weight):
K' Mg" S04" Cl Na Cn" H20 The yield of schoenite is 140.2 g. of the following composition:
K- Mg" S04" C1' Na' Ca" H2O The yield of NaCl is 125.5 g. It contains 0.75% of K.
Part of all of this schoenite is further processed to produce K2SO4 in the manner described in Example 1.
What we claim is:
1. In a process for the conversion of natural kainite containing sodium chloride as an impurity into potassium sulfate and magnesium-potassium sulfate involving the steps of: (1) decomposing the kainite by Contact with an aqueous medium in about the stoichiometric quantity for dissolving .all the resulting magnesium chloride; and (2) then separating the resulting magnesiumpotassium sulfate suspended in said medium from undissolved sodium chloride crystals, the improvement which comprises contacting recovered magnesium-potassium sulfate with Water, thereby forming a suspension of potassium sulfate in a magnesium sulfate mother liquor, re-
covering the suspended potassium sulfate, and employing the mother liquor remaining as the aqueous medium for decomposing the kainite.
2. The process of claim 1 in which the treatment of magnesium-potassium sulfate with water is eiected at about 45 C.
3. The process of claim 1 in which the NaCl and the potassium-magnesium sulphate are separately washed 4with water, and the resulting washing waters are employed together with the mother liquors of potassium sulphate for the conversion of other raw kainite.
References Cited in the file of this patent UNITED STATES PATENTS Hake June 29, 1880 Nagelvoort Oct. 30, y1917' OTHER REFERENCES Mellor: Comprehensive Treatise on Inorganic and Theoretical Chemistry, vol. 4, p. 340, 1923, Longmans, Green and Co., N.Y.
Claims (1)
1. IN A PROCESS FOR THE CONVERSION OF NATURAL KAINITE CONTAINING SODIUM CHLORIDE AS AN IMPURITY INTO POTASSIUM SULFATE AND MAGNESIUM-POTASSIUM SULFATE INVOLVING THE STEPS OF: (1) DECOMPOSING THE KAINITE BY CONTACT WITH AN AQUEOUS MEDIUM IN ABOUT THE STOICHIOMETRIC QUANTITY FOR DISSOLVING ALL THE RESULTING MAGNESIUM CHLORIDE; AND (2) THEN SEPARATING THE RESULTING MAGNESIUMPOTASSIUM SULFATE SUSPENDED IN SAID MEDIUM FROM UNDISSOLVED SODIUM CHLORIDE CRYSTALS, THE IMPROVEMENT WHICH COMPRISES CONTACTING RECOVERED MAGNESIUM-POTASSIUM SULFATE WITH WATER, THEREBY FORMING A SUSPENSION OF POTASSIUM SULFATE IN A MAGNESIUM SULFATE MOTHER LIQUOR, RECOVERING THE SUSPENDED POTASSIUM SULFATE, AND EMPLOYING THE MOTHER LIQUOR REMAINING AS THE AQUEOUS MEDIUM FOR DECOMPOSING THE KAINITE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2902344X | 1956-09-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2902344A true US2902344A (en) | 1959-09-01 |
Family
ID=11436245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US644207A Expired - Lifetime US2902344A (en) | 1956-09-14 | 1957-03-06 | Process for the preparation of hydrous potassium magnesium sulfate and potassium sulfate from kainite containing sodium chloride |
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| Country | Link |
|---|---|
| US (1) | US2902344A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3003849A (en) * | 1957-10-18 | 1961-10-10 | Montedison Spa | Process for the separation of schoenite from mixtures of schoenite, sodium chloride and magnesium sulphate |
| US3004826A (en) * | 1957-07-22 | 1961-10-17 | Montedison Spa | Process for obtaining schoenite by direct treatment of kainite containing sodium chloride as an impurity |
| US3058806A (en) * | 1959-01-16 | 1962-10-16 | Metallgesellschaft Ag | Method of preparing potassium sulfate from kainite |
| US3082063A (en) * | 1956-12-05 | 1963-03-19 | Sincat Spa | Process for the preparation of potassium sulphate and hydrous potassium-magnesium sulphates from natural kainite |
| US3110561A (en) * | 1960-03-19 | 1963-11-12 | Wintershall Ag | Process for the production of potassium sulfate |
| US3499725A (en) * | 1962-07-17 | 1970-03-10 | Sincat Spa | Method of processing kainite ores through intermediate formation of langbeinite |
| US3634041A (en) * | 1969-02-14 | 1972-01-11 | Great Salt Lake Minerals | Method for the production of potassium sulfate from potassium-containing double salts of magnesium sulfate |
| US4533536A (en) * | 1982-03-11 | 1985-08-06 | Mines De Potasse D'alsace S.A. | Process for the manufacture of potassium sulphate by treating solutions containing magnesium chloride and potassium chloride |
| US7780941B1 (en) * | 2009-04-06 | 2010-08-24 | Nichromet Extraction Inc. | Potassium magnesium fertilizer |
| WO2016180692A1 (en) | 2015-05-08 | 2016-11-17 | Yara Dallol Bv | Methods for the production of potassium sulphate from potassium-containing ores at high ambient temperatures |
| WO2017220709A1 (en) | 2016-06-24 | 2017-12-28 | Yara Dallol Bv | Method for the reduction of halite in the preparation of potassium sulphate from potassium-containing ores at high ambient temperatures |
| US10815130B2 (en) | 2017-10-13 | 2020-10-27 | Novopro Projects Inc. | Systems and methods of producing potassium sulfate |
| US11021411B2 (en) | 2017-05-24 | 2021-06-01 | Ksm Inc. | Potassium magnesium fertilizer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US229249A (en) * | 1880-06-29 | Cecil ist | ||
| US1244884A (en) * | 1916-06-16 | 1917-10-30 | Virginia Haloid Company | Process of recovering liquids used for separating solids of different specific gravities. |
-
1957
- 1957-03-06 US US644207A patent/US2902344A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US229249A (en) * | 1880-06-29 | Cecil ist | ||
| US1244884A (en) * | 1916-06-16 | 1917-10-30 | Virginia Haloid Company | Process of recovering liquids used for separating solids of different specific gravities. |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3082063A (en) * | 1956-12-05 | 1963-03-19 | Sincat Spa | Process for the preparation of potassium sulphate and hydrous potassium-magnesium sulphates from natural kainite |
| US3004826A (en) * | 1957-07-22 | 1961-10-17 | Montedison Spa | Process for obtaining schoenite by direct treatment of kainite containing sodium chloride as an impurity |
| US3003849A (en) * | 1957-10-18 | 1961-10-10 | Montedison Spa | Process for the separation of schoenite from mixtures of schoenite, sodium chloride and magnesium sulphate |
| US3058806A (en) * | 1959-01-16 | 1962-10-16 | Metallgesellschaft Ag | Method of preparing potassium sulfate from kainite |
| US3110561A (en) * | 1960-03-19 | 1963-11-12 | Wintershall Ag | Process for the production of potassium sulfate |
| US3499725A (en) * | 1962-07-17 | 1970-03-10 | Sincat Spa | Method of processing kainite ores through intermediate formation of langbeinite |
| US3634041A (en) * | 1969-02-14 | 1972-01-11 | Great Salt Lake Minerals | Method for the production of potassium sulfate from potassium-containing double salts of magnesium sulfate |
| US4533536A (en) * | 1982-03-11 | 1985-08-06 | Mines De Potasse D'alsace S.A. | Process for the manufacture of potassium sulphate by treating solutions containing magnesium chloride and potassium chloride |
| US7780941B1 (en) * | 2009-04-06 | 2010-08-24 | Nichromet Extraction Inc. | Potassium magnesium fertilizer |
| WO2016180692A1 (en) | 2015-05-08 | 2016-11-17 | Yara Dallol Bv | Methods for the production of potassium sulphate from potassium-containing ores at high ambient temperatures |
| US10399861B2 (en) | 2015-05-08 | 2019-09-03 | Yara Dallol Bv | Methods for the production of potassium sulphate from potassium-containing ores at high ambient temperatures |
| WO2017220709A1 (en) | 2016-06-24 | 2017-12-28 | Yara Dallol Bv | Method for the reduction of halite in the preparation of potassium sulphate from potassium-containing ores at high ambient temperatures |
| US11021411B2 (en) | 2017-05-24 | 2021-06-01 | Ksm Inc. | Potassium magnesium fertilizer |
| US10815130B2 (en) | 2017-10-13 | 2020-10-27 | Novopro Projects Inc. | Systems and methods of producing potassium sulfate |
| US10954133B2 (en) | 2017-10-13 | 2021-03-23 | Novopro Projects Inc. | Systems and methods of producing potassium sulfate |
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