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US2988630A - Method of inert-gas metal arc-welding - Google Patents

Method of inert-gas metal arc-welding Download PDF

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Publication number
US2988630A
US2988630A US758558A US75855858A US2988630A US 2988630 A US2988630 A US 2988630A US 758558 A US758558 A US 758558A US 75855858 A US75855858 A US 75855858A US 2988630 A US2988630 A US 2988630A
Authority
US
United States
Prior art keywords
inert
wire
metal
copper
gas metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US758558A
Inventor
Moore Donald Charles
Watson Gerald Vivian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of US2988630A publication Critical patent/US2988630A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/302Cu as the principal constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/934Electrical process
    • Y10S428/935Electroplating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S75/00Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
    • Y10S75/95Consolidated metal powder compositions of >95% theoretical density, e.g. wrought
    • Y10S75/951Oxide containing, e.g. dispersion strengthened
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12903Cu-base component
    • Y10T428/1291Next to Co-, Cu-, or Ni-base component

Definitions

  • United States Patent This invention is concerned with methods of inertgas metal-arc welding in which an electrode wire of an aluminum-bronze alloy is used.
  • aluminumbronze alloy as used in this specification refers to all copper-rich bina-r-y copper-aluminum alloys and includes Within its scope complex aluminum-bronze alloys which contain, in addition to copper and aluminum, such ele-' ments as manganese, iron or nickel. Such methods using these electrode wires may be used for welding aluminum-bronze alloys or brass or may be used for the purpose of overlaying on steel and other metals.
  • inert-gas metal-arc welding it is usual to introduce an electrical current into the electrode wire through a contactor tube which frictionally bears against the electrode wire. It has been found in practice, when using aluminum-bronze alloy electrode wire, that the oxide film on the surface of the wire leads to inferior working, due, mainly, to variations of contact resistance and to arcing between the contactor tube and the surface of the electrode wire.
  • the copper is deposited electrolytically on the surface of the wire after cleaning and etching thereof, and has a minimum thickness of about 0.0002".
  • the wire was degreased in a mineral solvent and etched in an acid pickle containing sulphuric, phosphoric and nitric acids. The wire was then electroplated with copper in the usual ice manner until the copper deposited on the wire, which is an adherent surface coating, had a thickness of substantially 0.0002.
  • An electrode wire in accordance with the invention has a further advantage in that it can be stored over lengthy periods without the formation of such a deleterious oxide coating as would give rise to the operating difliculties mentioned.
  • An electrode wire for use with a contactor tube in inert-gas metal arc welding; said wire comprising a base of aluminum bronze alloy metal, and a thin adherent coating of copper metal upon the exterior of said base.
  • An electrode wire for use with a contactor tube in inert-gas metal arc welding; said wire comprising a base of aluminum bronze alloy metal, and an adherent electrolytically deposited coating of copper metal upon the exterior of said base.
  • An electrode wire for use with a contactor tube in inert-gas metal arc welding comprising a base of aluminum bronze alloy metal, and an adherent electrolytically deposited coating of copper metal having a minimum thickness of 0.0002 inch upon the exterior of said base.
  • An electrode wire for use with a contactor tube in inert-gas metal arc welding comprising a base of aluminum bronze alloy metal, and an adherent coating of copper metal substantially 0.0002 inch thick upon the exterior of said base.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Arc Welding In General (AREA)

Description

United States Patent This invention is concerned with methods of inertgas metal-arc welding in which an electrode wire of an aluminum-bronze alloy is used. The term aluminumbronze alloy as used in this specification refers to all copper-rich bina-r-y copper-aluminum alloys and includes Within its scope complex aluminum-bronze alloys which contain, in addition to copper and aluminum, such ele-' ments as manganese, iron or nickel. Such methods using these electrode wires may be used for welding aluminum-bronze alloys or brass or may be used for the purpose of overlaying on steel and other metals.
In inert-gas metal-arc welding it is usual to introduce an electrical current into the electrode wire through a contactor tube which frictionally bears against the electrode wire. It has been found in practice, when using aluminum-bronze alloy electrode wire, that the oxide film on the surface of the wire leads to inferior working, due, mainly, to variations of contact resistance and to arcing between the contactor tube and the surface of the electrode wire.
According to this invention we provide a method of inert-gas metal-arc welding in which an electrode wire of an aluminium-bronze alloy is used, the surface of the wire having, adhering thereto, a coating of copper.
Preferably the copper is deposited electrolytically on the surface of the wire after cleaning and etching thereof, and has a minimum thickness of about 0.0002".
In one embodiment of the invention, which is given by way of an example, an aluminium-bronze electrode wire containing:
And unavoidable impurities,
was degreased in a mineral solvent and etched in an acid pickle containing sulphuric, phosphoric and nitric acids. The wire was then electroplated with copper in the usual ice manner until the copper deposited on the wire, which is an adherent surface coating, had a thickness of substantially 0.0002.
We have found that when an electrode wire in accordance with this embodiment of the invention is used in an inertgas metal-arc welding operation, there is an improved transference of the current from the contactor tube to the copper-coated electrode wire, and little or no arcing occurs, with a consequent improvement in operating characteristic, particularly a decrease in wire feed rate variation.
An electrode wire in accordance with the invention has a further advantage in that it can be stored over lengthy periods without the formation of such a deleterious oxide coating as would give rise to the operating difliculties mentioned.
We claim:
1. An electrode wire for use with a contactor tube in inert-gas metal arc welding; said wire comprising a base of aluminum bronze alloy metal, and a thin adherent coating of copper metal upon the exterior of said base.
2. An electrode wire for use with a contactor tube in inert-gas metal arc welding; said wire comprising a base of aluminum bronze alloy metal, and an adherent electrolytically deposited coating of copper metal upon the exterior of said base.
3. An electrode wire for use with a contactor tube in inert-gas metal arc welding; said wire comprising a base of aluminum bronze alloy metal, and an adherent electrolytically deposited coating of copper metal having a minimum thickness of 0.0002 inch upon the exterior of said base.
4. An electrode wire for use with a contactor tube in inert-gas metal arc welding; said wire comprising a base of aluminum bronze alloy metal, and an adherent coating of copper metal substantially 0.0002 inch thick upon the exterior of said base.
References Cited in the file of this patent UNITED STATES PATENTS 1,600,856 Stoody Sept. 21, 1926 1,794,983 Ritter Mar. 3, 1931 2,238,392 Matush Apr. 15, 1941 2,320,676 Swift June 1, 1943 2,797,300 Hawthorne June 25, 1957 2,827,550 Unrath Mar. 18, 1958 FOREIGN PATENTS 2,733 Great Britain Oct. 21, 1865

Claims (1)

1. AN ELECTRODE WIRE FOR USE WITH A CONTACTOR TUBE IN INERT-GAS METAL ARC WELDING, SAID WIRE COMPRISING A BASE OF ALUMINUM BRONZE ALLOY METAL, AND A THIN ADHERENT COATING OF COPPER METAL UPON THE EXTERIOR OF SAID BASE.
US758558A 1957-09-06 1958-09-02 Method of inert-gas metal arc-welding Expired - Lifetime US2988630A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2988630X 1957-09-06

Publications (1)

Publication Number Publication Date
US2988630A true US2988630A (en) 1961-06-13

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Family Applications (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3360349A (en) * 1965-04-01 1967-12-26 Sperry Rand Corp Copper layer bonded to a non-conductive layer by means of a copper alloy
US5312696A (en) * 1991-09-16 1994-05-17 United Technologies Corporation Method for reducing fretting wear between contacting surfaces
US6089828A (en) * 1998-02-26 2000-07-18 United Technologies Corporation Coated article and method for inhibiting frictional wear between mating titanium alloy substrates in a gas turbine engine
WO2009082238A3 (en) * 2007-12-21 2010-02-18 Efd Induction A.S. Electric welding of aluminium or aluminium alloy

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1600856A (en) * 1926-08-19 1926-09-21 Stoody Co Method of and apparatus for electric welding
US1794983A (en) * 1928-06-29 1931-03-03 Westinghouse Electric & Mfg Co Welding electrode
US2238392A (en) * 1939-12-04 1941-04-15 Ampco Metal Inc Bronze welding electrode
US2320676A (en) * 1942-07-24 1943-06-01 Ampco Metal Inc Arc welding electrode
US2797300A (en) * 1955-03-03 1957-06-25 Revere Copper & Brass Inc Welding
US2827550A (en) * 1955-08-15 1958-03-18 Smith Corp A O Gas shielded nozzle for arc welding head

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1600856A (en) * 1926-08-19 1926-09-21 Stoody Co Method of and apparatus for electric welding
US1794983A (en) * 1928-06-29 1931-03-03 Westinghouse Electric & Mfg Co Welding electrode
US2238392A (en) * 1939-12-04 1941-04-15 Ampco Metal Inc Bronze welding electrode
US2320676A (en) * 1942-07-24 1943-06-01 Ampco Metal Inc Arc welding electrode
US2797300A (en) * 1955-03-03 1957-06-25 Revere Copper & Brass Inc Welding
US2827550A (en) * 1955-08-15 1958-03-18 Smith Corp A O Gas shielded nozzle for arc welding head

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3360349A (en) * 1965-04-01 1967-12-26 Sperry Rand Corp Copper layer bonded to a non-conductive layer by means of a copper alloy
US5312696A (en) * 1991-09-16 1994-05-17 United Technologies Corporation Method for reducing fretting wear between contacting surfaces
US6089828A (en) * 1998-02-26 2000-07-18 United Technologies Corporation Coated article and method for inhibiting frictional wear between mating titanium alloy substrates in a gas turbine engine
WO2009082238A3 (en) * 2007-12-21 2010-02-18 Efd Induction A.S. Electric welding of aluminium or aluminium alloy
US20110168677A1 (en) * 2007-12-21 2011-07-14 Efd Induction A.S. Electric welding of aluminium or aluminium alloy

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