US2982641A - Aluminized explosives - Google Patents
Aluminized explosives Download PDFInfo
- Publication number
- US2982641A US2982641A US667732A US66773246A US2982641A US 2982641 A US2982641 A US 2982641A US 667732 A US667732 A US 667732A US 66773246 A US66773246 A US 66773246A US 2982641 A US2982641 A US 2982641A
- Authority
- US
- United States
- Prior art keywords
- parts
- weight
- explosives
- aluminized
- explosive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title claims description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 10
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 claims description 9
- 239000000015 trinitrotoluene Substances 0.000 claims description 9
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002274 desiccant Substances 0.000 claims description 7
- MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 11
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- BNPSSFBOAGDEEL-UHFFFAOYSA-N albuterol sulfate Chemical compound OS(O)(=O)=O.CC(C)(C)NCC(O)C1=CC=C(O)C(CO)=C1.CC(C)(C)NCC(O)C1=CC=C(O)C(CO)=C1 BNPSSFBOAGDEEL-UHFFFAOYSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000003975 dentin desensitizing agent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- -1 i.e. Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000008674 spewing Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/009—Wetting agents, hydrophobing agents, dehydrating agents, antistatic additives, viscosity improvers, antiagglomerating agents, grinding agents and other additives for working up
Definitions
- This invention relates to aluminized explosives, i.e., explosives which contain powdered aluminum as one of their principal components, such as those known in the art as Torpex and Minol; the invention pertains particularly to aluminized explosives which are conditioned to pour into a container without spewing and to generate only an inappreciable quantity of gas in the enclosed container.
- aluminized explosives may be desensitized with wax and this practice has been almost universally adopted by the ordnance profession.
- the wax has a tendency to exude at moderately high storage temperatures, for example 60 degrees C., such as might be found in the holds of ships or in the tropics.
- aluminized explosive compositions to generate gas is greatly reduced or eliminated by the addition thereto of a hydrophilic or desiccating agent, such as magnesium nitrate, calcium chloride, or magnesium perchlorate.
- a hydrophilic or desiccating agent such as magnesium nitrate, calcium chloride, or magnesium perchlorate.
- the mechanism by which the hydrophilic agent inhibits the generation of gas is believed to be a hydration reaction whereby the moisture contained in the explosive mixture is chemically combined with the hydrophilic agent to form a hydrate thereof, thus rendering the Water incapable of reacting with the aluminum to form a gas.
- aluminized explosives which have been desensitized with wax, exhibit a considerably smaller tendency to exude even at moderately high storage temperatures. It is believed that this advantage results from the fact that the hydrophilic agent reduces the gas evolved from the explosive, and that when little or no gas is thus generated the tendency for the wax to exude is reduced.
- RDX is a short designation for cyclotrimethylenetrinitramine (also known as cyclonite)
- TNT is the short designation for trinitrotoluene
- TNT 80 Aluminum (finely divided) 20 Calcium chloride (anhydrous, finely divided) 0.5
- the explosive composition exhibited a greatly reduced tendency to spew and to generate gas both while the pouring operation was being conducted and also after the explosive had been introduced into a projectile or mine body.
- Example 4 in which wax was used as a desensitizing agent, little or no wax was seen to exude from the explosive case. It should be noted that in all of the above examples there was no perceptible change in sensitivity of explosive caused by the addition of the hydrophilic or desiccating agent.
- a cast composition consisting essentially of at least 18 parts by weight of powdered aluminum, a minor portion varyingfrom /2 to 4 parts by weight of a desiccant selected from the group consisting of anhydrous calcium chloride, magnesium nitrate, and magnesium perchlorate,
- a cast composition consisting essentially of about 20 parts by weight of powdered aluminum, about /2 part by weight of powdered anhydrous calcium chloride, and about 82 parts by weight of an explosive containing approximately 42 parts cyclonite and 40 parts of trinitrotoluene.
- a cast composition consisting essentially of about 20 parts by weight of powdered aluminum, about /2 part by weight of powdered anhydrous calcium chloride, and about 80 parts by weight of an explosive containing approximately 40 parts of ammonium nitrate and 40 parts of trinitrotoluene.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Description
1 tainers.
Unite ttes a ALUNIINIZED EXPLOSIVES John W. Dawson, Philadelphia, Pa., and Frank H. Westheimer, Chicago, 11]., assignors, by mesne assignments, to the United States of America as represented by the Secretary of the Navy No Drawing. Filed May 6, 1946, Ser. No. 667,732
3 Claims. (Cl. 52-6) This invention relates to aluminized explosives, i.e., explosives which contain powdered aluminum as one of their principal components, such as those known in the art as Torpex and Minol; the invention pertains particularly to aluminized explosives which are conditioned to pour into a container without spewing and to generate only an inappreciable quantity of gas in the enclosed container.
An obvious disadvantage to aluminized explosives which have a tendency to spew is the accompanying difficulty with which such explosives are loaded into con- The marked tendency for these aluminized explosives to generate gas, even when in the solid form, is another disadvantage of previously used aluminized explosives since the pressure thus generated inside the container may grow to the point where it is capable of collapsing the booster cavity, or some similar weak structure within the container assembly. Moreover, in the case of Torpex some of the gas generated is hydrogen and thus represents a fire hazard. Presumably, this gas is generated by the action of moisture on aluminum or other constituents of the explosive mixture.
It is known that aluminized explosives may be desensitized with wax and this practice has been almost universally adopted by the ordnance profession. The wax, however, has a tendency to exude at moderately high storage temperatures, for example 60 degrees C., such as might be found in the holds of ships or in the tropics.
We have found that the tendency of aluminized explosive compositions to generate gas is greatly reduced or eliminated by the addition thereto of a hydrophilic or desiccating agent, such as magnesium nitrate, calcium chloride, or magnesium perchlorate.
The mechanism by which the hydrophilic agent inhibits the generation of gas is believed to be a hydration reaction whereby the moisture contained in the explosive mixture is chemically combined with the hydrophilic agent to form a hydrate thereof, thus rendering the Water incapable of reacting with the aluminum to form a gas. As a further consequence of this gas-inhibiting reaction, it has been found that aluminized explosives which have been desensitized with wax, exhibit a considerably smaller tendency to exude even at moderately high storage temperatures. It is believed that this advantage results from the fact that the hydrophilic agent reduces the gas evolved from the explosive, and that when little or no gas is thus generated the tendency for the wax to exude is reduced.
In the following examples of aluminized explosives made in accordance with the present invention, it will be understood that the term RDX is a short designation for cyclotrimethylenetrinitramine (also known as cyclonite), and that the term TNT is the short designation for trinitrotoluene.
Calcium chloride (anhydrous, finely divided)-.. 0.5
2 Example 2:
Ammonium nitrate 40 TNT 40 Aluminum (finely divided) l8 Magnesium nitrate (anhydrous or monohydrate,
finely divided) I 4 Example 3:
TNT 80 Aluminum (finely divided) 20 Calcium chloride (anhydrous, finely divided) 0.5 Example 4:
RDX 42 TNT 40 Aluminum (finely divided) 18 Wax 4 Nitrocellulose 0.7 Lecithin 0.2
Calcium chloride (anhydrous, finely divided) 0.5
In all of the above examples, the explosive composition exhibited a greatly reduced tendency to spew and to generate gas both while the pouring operation was being conducted and also after the explosive had been introduced into a projectile or mine body. In the case of Example 4 in which wax was used as a desensitizing agent, little or no wax was seen to exude from the explosive case. It should be noted that in all of the above examples there was no perceptible change in sensitivity of explosive caused by the addition of the hydrophilic or desiccating agent.
Although we prefer to employ magnesium nitrate, calcium cloride or magnesium perchlorate as the desiccating agents with our improved aluminized explosives, and have limited the examples herein to those agents, we do not intend so to limit our invention, for it is obvious that other desiccating or hydrophilic agents may be effectively used in this manner. Moreover, we do not intend to be limited closely to the preferred proportions in which our desiccants have been used, as set forth in the examples, since theeifectiveness of the desiccant to perform its appointed function is manifestly dependent upon the quantity used and may be varied widely according to the preference of the individual employing the invention.
We claim:
1. A cast composition consisting essentially of at least 18 parts by weight of powdered aluminum, a minor portion varyingfrom /2 to 4 parts by weight of a desiccant selected from the group consisting of anhydrous calcium chloride, magnesium nitrate, and magnesium perchlorate,
and at least parts by weight of an explosive containing at least 40 parts by weight of trinitrotoluene.
2. A cast composition consisting essentially of about 20 parts by weight of powdered aluminum, about /2 part by weight of powdered anhydrous calcium chloride, and about 82 parts by weight of an explosive containing approximately 42 parts cyclonite and 40 parts of trinitrotoluene.
3. A cast composition consisting essentially of about 20 parts by weight of powdered aluminum, about /2 part by weight of powdered anhydrous calcium chloride, and about 80 parts by weight of an explosive containing approximately 40 parts of ammonium nitrate and 40 parts of trinitrotoluene.
References Cited in the file of this patent UNITED STATES PATENTS 857,580 Bowen June 25, 1907 2,344,840 Watt Mar. 21, 1944 2,369,517 Bagley Feb. 13, 1945 FOREIGN PATENTS 22,030 Great Britain 1910
Claims (1)
1. A CAST COMPOSITION CONSISTING ESSENTIALLY OF AT LEAST 18 PARTS BY WEIGHT OF POWDERED ALUMINUM, A MINOR PORTION VARYING FROM 1/2 TO 4 PARTS BY WEIGHT OF A DESICCANT SELECTED FROM THE GROUP CONSISTING OF ANHYDROUS CALCIUM CHLORIDE, MAGNESIUM NITRATE, AND MAGNESIUM PERCHLORATE, AND AT LEAST 80 PARTS BY WEIGHT OF AN EXPLOSIVE CONTAINING AT LEAST 40 PARTS BY WEIGHT OF TRINITROTOLUENE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US667732A US2982641A (en) | 1946-05-06 | 1946-05-06 | Aluminized explosives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US667732A US2982641A (en) | 1946-05-06 | 1946-05-06 | Aluminized explosives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2982641A true US2982641A (en) | 1961-05-02 |
Family
ID=24679406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US667732A Expired - Lifetime US2982641A (en) | 1946-05-06 | 1946-05-06 | Aluminized explosives |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2982641A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3368929A (en) * | 1964-12-28 | 1968-02-13 | Commercial Solvents Corp | Particulate ammonium nitrate sensitized with a liquid hydrocarbon fuel containing calcium chloride as anti-caking agent |
| US3369944A (en) * | 1963-06-12 | 1968-02-20 | Dynamit Nobel Ag Patentabteilu | Thickened aqueous detonator composition containing a brisant explosive |
| US3472713A (en) * | 1967-07-20 | 1969-10-14 | Dynamit Nobel Ag | Fusible aromatic nitrocompound explosive composition containing particular wax as a desensitizer |
| US3951706A (en) * | 1962-07-03 | 1976-04-20 | Eldridge Judson B | Solid propellant mixtures and process of preparation |
| EP0035376A3 (en) * | 1980-02-29 | 1982-08-18 | Dyno Industrier A.S. | A process for the preparation of aluminium-containing high-energy explosive compositions |
| US4488916A (en) * | 1982-09-22 | 1984-12-18 | Messerschmitt-Bolkow-Blohm Gmbh | Cast explosive charge composition |
| US10094190B2 (en) | 2014-04-04 | 2018-10-09 | Halliburton Energy Services, Inc. | Downhole severing tools employing a two-stage energizing material and methods for use thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US857580A (en) * | 1904-10-05 | 1907-06-25 | Frank Eustace Wilkins Bowen | Explosive. |
| GB191022030A (en) * | 1909-09-29 | 1911-04-27 | Manuel Antonio Gomes Himalaya | Improvements in the Manufacture of Safety Explosives. |
| US2344840A (en) * | 1940-06-14 | 1944-03-21 | Illinois Powder Mfg Company | Explosive composition and method of producing same |
| US2369517A (en) * | 1942-03-16 | 1945-02-13 | Dev Engineering Company | Explosive material |
-
1946
- 1946-05-06 US US667732A patent/US2982641A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US857580A (en) * | 1904-10-05 | 1907-06-25 | Frank Eustace Wilkins Bowen | Explosive. |
| GB191022030A (en) * | 1909-09-29 | 1911-04-27 | Manuel Antonio Gomes Himalaya | Improvements in the Manufacture of Safety Explosives. |
| US2344840A (en) * | 1940-06-14 | 1944-03-21 | Illinois Powder Mfg Company | Explosive composition and method of producing same |
| US2369517A (en) * | 1942-03-16 | 1945-02-13 | Dev Engineering Company | Explosive material |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951706A (en) * | 1962-07-03 | 1976-04-20 | Eldridge Judson B | Solid propellant mixtures and process of preparation |
| US3369944A (en) * | 1963-06-12 | 1968-02-20 | Dynamit Nobel Ag Patentabteilu | Thickened aqueous detonator composition containing a brisant explosive |
| US3368929A (en) * | 1964-12-28 | 1968-02-13 | Commercial Solvents Corp | Particulate ammonium nitrate sensitized with a liquid hydrocarbon fuel containing calcium chloride as anti-caking agent |
| US3472713A (en) * | 1967-07-20 | 1969-10-14 | Dynamit Nobel Ag | Fusible aromatic nitrocompound explosive composition containing particular wax as a desensitizer |
| EP0035376A3 (en) * | 1980-02-29 | 1982-08-18 | Dyno Industrier A.S. | A process for the preparation of aluminium-containing high-energy explosive compositions |
| US4376083A (en) * | 1980-02-29 | 1983-03-08 | Dyno Industrier A.S. | Process for the preparation of aluminum-containing high-energy explosive compositions |
| US4488916A (en) * | 1982-09-22 | 1984-12-18 | Messerschmitt-Bolkow-Blohm Gmbh | Cast explosive charge composition |
| US10094190B2 (en) | 2014-04-04 | 2018-10-09 | Halliburton Energy Services, Inc. | Downhole severing tools employing a two-stage energizing material and methods for use thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2982641A (en) | Aluminized explosives | |
| US3121036A (en) | Explosive composition comprising ammonium nitrate and a heat-producing metal | |
| US3113059A (en) | Inhibited aluminum-water composition and method | |
| US3153606A (en) | Aqueous explosive composition containing flake aluminum and ammonium nitrate | |
| US2975046A (en) | Ammonium nitrate explosive composition | |
| GB748820A (en) | Improvements in delay connectors for explosive charges | |
| US3390029A (en) | Inorganic oxidizer salt explosive composition containing organic fuel solvent for said salt | |
| US2970900A (en) | Priming composition | |
| US3111439A (en) | High explosive mixtures | |
| US2817581A (en) | Cast ammonium nitrate and urea explosive | |
| US3619305A (en) | Explosive compositions containing expanded ammonium nitrate in crystalline form and method of preparing same | |
| US2048050A (en) | Explosive composition | |
| US4874441A (en) | Explosive for warheads and solid rocket propellant | |
| US3026221A (en) | Explosive composition | |
| US3419443A (en) | Hydrazine containing explosive compositions | |
| US3390032A (en) | Gelled aqueous slurry explosive composition containing as a gas generating agent a carbonate or bicarbonate with a nitrite | |
| EP0011383B1 (en) | Gelled aqueous slurry explosives containing gas bubbles | |
| US3730789A (en) | Monopropellant composition including hydroxylamine perchlorate | |
| US3523047A (en) | Hydrazine and aluminum containing explosive compositions | |
| US3304211A (en) | Pelletized explosive of trinitrotoluene prills coated with sodium and ammonium nitrat in an organic binder | |
| US2942965A (en) | Aluminized explosive composition | |
| US2829036A (en) | Fire damp proof explosive compositions | |
| US3765965A (en) | Composite propellant composition with ferrocene compound as bonding agent and ballistic modifier | |
| US3326734A (en) | Water resistant inorganic nitrate based explosive composition | |
| US3012868A (en) | Enhanced organic explosives |