US2787559A - Process for increasing the heat resistance of cellulose acetate butyrate coatings onflash bulbs - Google Patents
Process for increasing the heat resistance of cellulose acetate butyrate coatings onflash bulbs Download PDFInfo
- Publication number
- US2787559A US2787559A US558178A US55817856A US2787559A US 2787559 A US2787559 A US 2787559A US 558178 A US558178 A US 558178A US 55817856 A US55817856 A US 55817856A US 2787559 A US2787559 A US 2787559A
- Authority
- US
- United States
- Prior art keywords
- cellulose acetate
- bulbs
- acetate butyrate
- flash
- titanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000576 coating method Methods 0.000 title claims description 21
- 238000000034 method Methods 0.000 title claims description 13
- 229920006217 cellulose acetate butyrate Polymers 0.000 title description 20
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 32
- 239000011248 coating agent Substances 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 11
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 claims description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 16
- 239000004922 lacquer Substances 0.000 description 14
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- QUVMSYUGOKEMPX-UHFFFAOYSA-N 2-methylpropan-1-olate;titanium(4+) Chemical compound [Ti+4].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] QUVMSYUGOKEMPX-UHFFFAOYSA-N 0.000 description 7
- 229920002301 cellulose acetate Polymers 0.000 description 7
- 229940035429 isobutyl alcohol Drugs 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 239000012456 homogeneous solution Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- -1 alkyl titanate Chemical compound 0.000 description 3
- 238000001879 gelation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920006265 cellulose acetate-butyrate film Polymers 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000428198 Lutrinae Species 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011284 combination treatment Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- F21K5/00—Light sources using charges of combustible material, e.g. illuminating flash devices
- F21K5/02—Light sources using charges of combustible material, e.g. illuminating flash devices ignited in a non-disrupting container, e.g. photo-flash bulb
Definitions
- Flash bulbs which are used for providing illumination for photographic purposes have been subject to shattering or exploding due to the extreme heat atthe moment of flash.
- the glass envelope of the bulbs has been coated with a tough transparent film.
- films which have been used such as those containing cellulose derivatives have not in themselves been heat resistant and, therefore, produced fumes and odors when the bulb has been flashed.
- the melted film might stick to the coat pockets or fingers of rapid fire photographers.
- One object of this invention is to provide a heat resistant coating for flash bulbs. Another object is to provide a method for making flash bulbs resistant to exploding. A further object is to provide a coating for flash lamps which does not melt at normal flash lamp temperatures or which does not stick to objects which contact the flash lamps at the time of flashing.
- the above objects are obtained by incorporating an alkyl titanate in the cellulose acetate butyrate or cellulose acetate film deposited on the flash lamps and carefully compounding the solvent mixtures.
- the titanate may be added to the dipping lacquer or the bulbs containing a cellulose ester coating may be dipped into a solvent solution of the titanate.
- Fig. 1 shows a photographic flash lamp comprising a customary glass envelope, and a base adapted for electrical discharge of a combustible material contained within the envelope.
- a transparent coating 1 comprising cellulose acetate butyrate and isobutyl titanate or cellulose acetate containing isobutyl titanate is carried on the outside of the glass envelope.
- Fig. 2 is a fragmentary view taken substantially on line 22 of Fig. 1 looking in the direction of the arrows and shows the glass 2 having a transparent coating 3 thereon.
- tetra isobutyltitanate may be prepared from tetra isopropyl titanate by reacting the tetra isopropyl titanate withan excess of isobutyl alcohol in the presence of toluene, and adding this solution to the cellulose acetate butyrate solution containing approximately 20% isobutanol.
- Various other formulations may be prepared'containing cellulose acetate butyrate and toluene to which the isopropyl titanate may be added.
- toluene is the preferred solvent for the cellulose acetate butyrate used for coating flash bulbs.
- 15-25% cellulose acetate butyrate may be used, 3559% toluene, 25-35% isobutyl alcohol and l-4 tetraisopropyl titanate as illustrated in Example I.
- the cellulose acetate butyrate preferred for our dipping lacquer has an acetyl content of above 13%, a butyryl content of above 26.5% and a hydroxyl content of above 2.0%.
- Cellulose acetate may also be uses as a base for a lacquer for coating flash bulbs.
- tetraisopropyl titanate used with cellulose acetate requires a critical solvent combination. Use of these critical solvents provides a type of lacquer which gels on the surface of the bulb almost immediately after thebulb is withdrawn from the solution.
- 32-50% methylene chloride, 20-66% isobutyl alcohol, 17-24% ethyl lactate, and 3-5% toluene are used with 842% cellulose acetate and O.52% tetraisopropyl titanate.
- Example I A cellulose acetate butyrate lacquer was prepared having the following composition:
- a further embodiment of our invention concerns treatment of bulbs which have been coated with cellulose acetate butyrate film where the alkyl titanate was used as a subsequent treatment.
- Example II Bulbs coated with a cellulose acetate butyrate lacquer (without an alkyl titanate added) were immersed in a 2% solution of tetra isopropyl titanate in hexane. With the titanate treatment there was no sticking of the cheesecloth on the bulb after flashing. However, bulbs with cellulose acetate butyrate lacquer which had not been dipped in the tetra isopropyl titanate solution showed embedding of the cloth in the film and adhering to the film.
- a combination treatment may also be used in which a lacquer containing tetra isobutyl titanate is applied to the flash lamp and the film subsequently treated by dipping into a solvent solution of tetra isopropyl titanate.
- Example III Flash bulbs coated as described in Example I were given a post-treatment by immersing the flash bulbs for approximately one minute in a solution of 20% toluene, 76% ethyl acetate, and 4% tetra isopropyl titanate. An extremely isoluble and heat resistant film was produced.
- Example I V A cellulose acetate lacquer was prepared having the following composition:
- Solution B should be added to homogeneous solution of A.
- Flash bulbs were dipped into the solution, withdrawn and gelation of the film on the bulb occurred almost immediately. A haze developed as the solvents evaporated from the film but on further drying, the haze disappeared leaving a perfectly clear film.
- the rapid gelation of the film permitted complete drying in an inverted position, permitting the bulb to be placed almost immediately at 160 F. for rapid drying. This gelation also permitted the coating to be built up with subsequent clippings.
- Films prepared from cellulose acetate butyrate and cellulose acetate containing isobutyl titanate or isopropyl titanate have been found to have particularly good flexibility in addition to having good insolubility and heat resisting characteristics.
- Hexane may be also used as a solvent for tetra ispropyl titanate when used as a post-coating treatment.
- Percents as used herein are percents by weight.
- a process for increasing the solvent and heat resistance of cellulose acetate butyrate coatings on flash lamps comprising immersing the coating in a solution of tetra isopropyl titanate.
- a process for providing a coating for flash bulbs comprising dipping the flash bulbs in a lacquer prepared by mixing 10 parts of toluene, 10 parts isobutyl alcohol and 2 parts of tetra isopropyl titanate, reacting for 30 minutes, and adding to a homogeneous solution contain ing 20 parts cellulose acetate butyrate, 37 parts toluene and 21 parts isobutyl alcohol, drying, and immersing the flash bulbs for approximately one minute in a solution of 20% toluene, 76% ethyl acetate and 4% tetra isopropyl titanate.
- a process for providing a coating for flash bulbs comprising dipping the flash bulbs in a lacquer prepared by mixing 10 parts of toluene, 10 parts isobutyl alcohol and 2 parts of tetra isopropyl titanate, reacting for 30 minutes, and adding to a homogeneous solution containing 20 parts cellulose acetate butyrate, 37 parts toluene and 21 parts isobutyl alcohol, drying, and immersing the flash bulbs for approximately one minute in a solution of 4% tetra isopropyl titanate in hexane.
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Paints Or Removers (AREA)
Description
April 2, 1957 c, co ETAL 2,787,559
PROCESS FOR INCREASING THE HEAT RESISTANCE OF CELLULOSE ACETATE BUTYRATE COATINGS 0N FLASH BULBS Filed Jan. 9, 1956 1 A 2 PHOTO GRAPHIC F L ASH 1. AMP
TRANSPARENT c 0A TING CharlesHCon Fr e-dM B a l INVENTOR.
United States Patent PROCESS FOR. INCREASING THEl-IEAT RESIST- ANCE OF CELLULOSE .ACETATE BUTYRATE COATINGS ON FLASH BULBS Charles H. Coney and Fred M. Ball, Kingspart, Tenn, assrgnors to Eastman Kodak Company, Rochester, N. Y., a corporation of New J ersey Application January 9, 1956', Serial No. 558,178 3 Claims. or. 117--85) This invention concerns flash bulb coatings, more particularly flash bulb coatings containing cellulose acetate butyrate.
Flash bulbs which are used for providing illumination for photographic purposes have been subject to shattering or exploding due to the extreme heat atthe moment of flash. In order to prevent exploding of the bulbs, the glass envelope of the bulbs has been coated with a tough transparent film. However, in some instances, films which have been used such as those containing cellulose derivatives have not in themselves been heat resistant and, therefore, produced fumes and odors when the bulb has been flashed. In addition, the melted film might stick to the coat pockets or fingers of rapid fire photographers. To avoid this undesirable feature, a three-coat method has been used consisting of one coat on the inside of the flash bulb envelope and two coats on the outside However, the necessity of coating the glass envelope three times contributes to the expense of the flash bulbs which may be an expensive item when many pictures are taken requiring such illumination. In addition, the interior coating otters an obstacle in sealing the bulb to the filament stem, since it must be burned off before the union is made. Consequently, a need has been felt for a simple inexpensive method of rendering the flash bulbs non-explosive.
We have discovered a method wherein the flash bulbs may be coated on the outside with a single coating. This method consists of eliminating the inside coating on the bulb and applying 3 to 7 mils of a special heat resistant lacquer on the outside.
One object of this invention is to provide a heat resistant coating for flash bulbs. Another object is to provide a method for making flash bulbs resistant to exploding. A further object is to provide a coating for flash lamps which does not melt at normal flash lamp temperatures or which does not stick to objects which contact the flash lamps at the time of flashing.
The above objects are obtained by incorporating an alkyl titanate in the cellulose acetate butyrate or cellulose acetate film deposited on the flash lamps and carefully compounding the solvent mixtures. The titanate may be added to the dipping lacquer or the bulbs containing a cellulose ester coating may be dipped into a solvent solution of the titanate.
Fig. 1 shows a photographic flash lamp comprising a customary glass envelope, and a base adapted for electrical discharge of a combustible material contained within the envelope. A transparent coating 1 comprising cellulose acetate butyrate and isobutyl titanate or cellulose acetate containing isobutyl titanate is carried on the outside of the glass envelope. Fig. 2 is a fragmentary view taken substantially on line 22 of Fig. 1 looking in the direction of the arrows and shows the glass 2 having a transparent coating 3 thereon.
In order to produce a film using cellulose acetate butyrate as a base which would have good solubility and heat resistance on evaporation of the solvents, the titanate Patented? Apr. 2, 1957 is added directly to the solution. This must be done by a certain method or the solution will gelimmediately. We have discovered that tetra isobutyltitanate may be prepared from tetra isopropyl titanate by reacting the tetra isopropyl titanate withan excess of isobutyl alcohol in the presence of toluene, and adding this solution to the cellulose acetate butyrate solution containing approximately 20% isobutanol.
Various other formulations may be prepared'containing cellulose acetate butyrate and toluene to which the isopropyl titanate may be added. However, from 2 to 10% tetra isobutyl titanate is operative in the cellulose acetate butyrate films based on the weight of the cellulose acetate butyrate. Increasing the amount of tetra isobutyl titanate increases the solubility or heat resistance of the film. Although other solvents may be used, we find that toluene is the preferred solvent for the cellulose acetate butyrate used for coating flash bulbs. We have found that 15-25% cellulose acetate butyrate may be used, 3559% toluene, 25-35% isobutyl alcohol and l-4 tetraisopropyl titanate as illustrated in Example I.
The cellulose acetate butyrate preferred for our dipping lacquer has an acetyl content of above 13%, a butyryl content of above 26.5% and a hydroxyl content of above 2.0%.
Cellulose acetate may also be uses as a base for a lacquer for coating flash bulbs. We have found that tetraisopropyl titanate used with cellulose acetate requires a critical solvent combination. Use of these critical solvents provides a type of lacquer which gels on the surface of the bulb almost immediately after thebulb is withdrawn from the solution. We have found that 32-50% methylene chloride, 20-66% isobutyl alcohol, 17-24% ethyl lactate, and 3-5% toluene are used with 842% cellulose acetate and O.52% tetraisopropyl titanate.
The following examples are intended to illustrate our invention but are not intended to limit it in any Way.
Example I A cellulose acetate butyrate lacquer was prepared having the following composition:
A, percent B, percent Cellulose Acetate Butyrate ponents to react and then was added to a homogeneous solution of A. The flash bulbs were dipped in the above lacquer at F. which became insoluble and heat resistant on drying.
In order to determine how soft and tacky the films are upon flashing a flash bulb, a test method was devised in which a bulb was wrapped with cheesecloth, held tightly against the film with a rubber band. Films formed using the lacquer shown in Example I had good heat resistance, preventing the cheesecloth from sticking to the flash bulb.
A further embodiment of our invention concerns treatment of bulbs which have been coated with cellulose acetate butyrate film where the alkyl titanate was used as a subsequent treatment.
Example II Bulbs coated with a cellulose acetate butyrate lacquer (without an alkyl titanate added) were immersed in a 2% solution of tetra isopropyl titanate in hexane. With the titanate treatment there was no sticking of the cheesecloth on the bulb after flashing. However, bulbs with cellulose acetate butyrate lacquer which had not been dipped in the tetra isopropyl titanate solution showed embedding of the cloth in the film and adhering to the film.
A combination treatment may also be used in which a lacquer containing tetra isobutyl titanate is applied to the flash lamp and the film subsequently treated by dipping into a solvent solution of tetra isopropyl titanate.
Example III Flash bulbs coated as described in Example I were given a post-treatment by immersing the flash bulbs for approximately one minute in a solution of 20% toluene, 76% ethyl acetate, and 4% tetra isopropyl titanate. An extremely isoluble and heat resistant film was produced.
Example I V A cellulose acetate lacquer was prepared having the following composition:
Solution B should be added to homogeneous solution of A.
Flash bulbs were dipped into the solution, withdrawn and gelation of the film on the bulb occurred almost immediately. A haze developed as the solvents evaporated from the film but on further drying, the haze disappeared leaving a perfectly clear film. The rapid gelation of the film permitted complete drying in an inverted position, permitting the bulb to be placed almost immediately at 160 F. for rapid drying. This gelation also permitted the coating to be built up with subsequent clippings.
Films prepared from cellulose acetate butyrate and cellulose acetate containing isobutyl titanate or isopropyl titanate have been found to have particularly good flexibility in addition to having good insolubility and heat resisting characteristics.
Hexane may be also used as a solvent for tetra ispropyl titanate when used as a post-coating treatment.
Percents as used herein are percents by weight.
We claim:
1. A process for increasing the solvent and heat resistance of cellulose acetate butyrate coatings on flash lamps comprising immersing the coating in a solution of tetra isopropyl titanate.
2. A process for providing a coating for flash bulbs comprising dipping the flash bulbs in a lacquer prepared by mixing 10 parts of toluene, 10 parts isobutyl alcohol and 2 parts of tetra isopropyl titanate, reacting for 30 minutes, and adding to a homogeneous solution contain ing 20 parts cellulose acetate butyrate, 37 parts toluene and 21 parts isobutyl alcohol, drying, and immersing the flash bulbs for approximately one minute in a solution of 20% toluene, 76% ethyl acetate and 4% tetra isopropyl titanate.
3. A process for providing a coating for flash bulbs comprising dipping the flash bulbs in a lacquer prepared by mixing 10 parts of toluene, 10 parts isobutyl alcohol and 2 parts of tetra isopropyl titanate, reacting for 30 minutes, and adding to a homogeneous solution containing 20 parts cellulose acetate butyrate, 37 parts toluene and 21 parts isobutyl alcohol, drying, and immersing the flash bulbs for approximately one minute in a solution of 4% tetra isopropyl titanate in hexane.
Keukens et al. June 10, 1952 Beacham Aug. 10, 1954
Claims (1)
1. A PROCESS FOR INCREASING HE SOLVENT AND HEAT RESISTANCE OF CELLULOSE ACETATAE BUTYRATE COATINGS ON FLASH LAMPS COMPRISING IMMERSING THE COATING IN A SOLUTION OF TETRA ISOPROPYL TITANATE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US558178A US2787559A (en) | 1956-01-09 | 1956-01-09 | Process for increasing the heat resistance of cellulose acetate butyrate coatings onflash bulbs |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US558178A US2787559A (en) | 1956-01-09 | 1956-01-09 | Process for increasing the heat resistance of cellulose acetate butyrate coatings onflash bulbs |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2787559A true US2787559A (en) | 1957-04-02 |
Family
ID=24228509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US558178A Expired - Lifetime US2787559A (en) | 1956-01-09 | 1956-01-09 | Process for increasing the heat resistance of cellulose acetate butyrate coatings onflash bulbs |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2787559A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2946911A (en) * | 1957-11-01 | 1960-07-26 | Gen Electric | Coated electric lamp |
| US3022653A (en) * | 1958-12-24 | 1962-02-27 | Westinghouse Electric Corp | Coated flashlamp and coating composition |
| US3067352A (en) * | 1959-02-05 | 1962-12-04 | Gen Electric | Coated electric lamp and method of manufacture |
| US3156107A (en) * | 1961-11-21 | 1964-11-10 | Sylvania Electric Prod | Photoflash lamp and protective coating therefor |
| US3157812A (en) * | 1962-04-27 | 1964-11-17 | Friedman Herbert | Teflon coated photon counter tube |
| US3420694A (en) * | 1966-02-01 | 1969-01-07 | Gen Electric | Plural coated transparent colored lamp and method of forming same |
| US4076489A (en) * | 1976-06-24 | 1978-02-28 | General Electric Company | Method for coating photoflash lamps |
| US4174944A (en) * | 1978-01-30 | 1979-11-20 | Gte Sylvania Incorporated | Single lead electrically-activated flashlamp |
| US20020123209A1 (en) * | 2000-12-25 | 2002-09-05 | Taketoshi Yamada | Film substrate and its manufacturing method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2599644A (en) * | 1949-03-05 | 1952-06-10 | Hartford Nat Bank & Trust Co | Flash lamp |
| US2686133A (en) * | 1950-09-13 | 1954-08-10 | Nat Lead Co | Coating solution containing a cellulose compound and an alkyl titanate |
-
1956
- 1956-01-09 US US558178A patent/US2787559A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2599644A (en) * | 1949-03-05 | 1952-06-10 | Hartford Nat Bank & Trust Co | Flash lamp |
| US2686133A (en) * | 1950-09-13 | 1954-08-10 | Nat Lead Co | Coating solution containing a cellulose compound and an alkyl titanate |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2946911A (en) * | 1957-11-01 | 1960-07-26 | Gen Electric | Coated electric lamp |
| US3022653A (en) * | 1958-12-24 | 1962-02-27 | Westinghouse Electric Corp | Coated flashlamp and coating composition |
| US3067352A (en) * | 1959-02-05 | 1962-12-04 | Gen Electric | Coated electric lamp and method of manufacture |
| US3156107A (en) * | 1961-11-21 | 1964-11-10 | Sylvania Electric Prod | Photoflash lamp and protective coating therefor |
| US3157812A (en) * | 1962-04-27 | 1964-11-17 | Friedman Herbert | Teflon coated photon counter tube |
| US3420694A (en) * | 1966-02-01 | 1969-01-07 | Gen Electric | Plural coated transparent colored lamp and method of forming same |
| US4076489A (en) * | 1976-06-24 | 1978-02-28 | General Electric Company | Method for coating photoflash lamps |
| US4174944A (en) * | 1978-01-30 | 1979-11-20 | Gte Sylvania Incorporated | Single lead electrically-activated flashlamp |
| US20020123209A1 (en) * | 2000-12-25 | 2002-09-05 | Taketoshi Yamada | Film substrate and its manufacturing method |
| US7141304B2 (en) * | 2000-12-25 | 2006-11-28 | Konica Corporation | Film substrate and its manufacturing method |
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