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US2741364A - Preparatory treatment for froth flotation - Google Patents

Preparatory treatment for froth flotation Download PDF

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US2741364A
US2741364A US370220A US37022053A US2741364A US 2741364 A US2741364 A US 2741364A US 370220 A US370220 A US 370220A US 37022053 A US37022053 A US 37022053A US 2741364 A US2741364 A US 2741364A
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slurry
mineral
value
boiling temperature
silicate
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Wilson Alexander Murray
Woodward Herbert Spencer
Bailey Harold Durward
Lucas Emil August
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MOLYBDENUM CORP
MOLYBDENUM Corp OF AMERICA
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MOLYBDENUM CORP
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/02—Froth-flotation processes

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  • the invention relates to a method for the separation of a mineral from accompanying earthy material, or gangue, and more particularly, to the separation of tungsten and rare earth ores from gangue and includes correlated improvements and discoveries whereby such a separation may be advantageously accomplished.
  • An object of the invention is the provision of a method in accordance with which a marked recovery of a high concentration of mineral may be obtained from an earthy material containing a small percentage of such mineral.
  • a further object of the invention is to provide a method for recovering a desired mineral from earthy material as a high grade salable concentrate.
  • Another object of the invention is the provision of a method for the recovery of a mineral which may be readily, effectively and economically carried out.
  • a more particular object of the invention is the provision of a method whereby a mineral concentrate may be separated from earthy material or gangue with distinctively high recoveries.
  • a specific object of the invention is the provision of a method which entails boiling a slurry of earthy material containing a mineral, e. g'. Scheelite or Bastnasite, in the presence of adjuvants under adjusted pH conditions followed by cooling, and finally floating.
  • a mineral e. g'. Scheelite or Bastnasite
  • the invention accordingly comprises the several steps and the relation of one or more of such steps with respect to each of the others thereof, which will be exemplified in the method hereinafter disclosed, and the scope of the invention will be indicated in the claims.
  • a mineral may be selectively. separated from accompanying earthy material or gangue by a method which comprises forming a slurry thereof with water, heating the slurry, suitably to about boiling temperature, and incorporating adiuvants which may be a depressing agent, a collecting agent and a frothing agent, including an acidified silicate of an alkali metal viz: sodium and potassium.
  • adiuvants which may be a depressing agent, a collecting agent and a frothing agent, including an acidified silicate of an alkali metal viz: sodium and potassium.
  • the pH is adjusted, either before or after addition of adjuvants, to a value from about 8.5 to about 10.5, preferably about 10.0, by the addition of an alkaline reacting material, and the temperature of the slurry maintained at about boiling temperature for a critical minimum period of about 1 minute and which period may be about 10 minutes, preferably for about 5 minutes, with agitation which may be effected through the introduction of compressed air or steam, or ay-mechanical means.
  • the slurry is then cooled to a temperature from about 70 F to about 140 F more particularly to about 100 F. and finally floated.
  • the adjuvants may include a member of the group consisting of acidified silicates and lignin sulfonates of an alakil metal.
  • Bastnasite is a mineral found at Mountain Pass, California, which contains rare earths as carbonates and fluorocarbonates.
  • the acidified silicate of an alkali metal may be a sodium or a potassium silicate to which an amount of a mineral acid as sulphuric, hydrochloric, phosphoric acids or an organic acid such as oxalic, tartaric and citric acids, has been added to render the reagent acidic, preferably having a pH value from about 1.0 to about 4.0.
  • the acidified silicate may be a sodium silicate to which sulphuric acid or other acid has been added to the desired pH.
  • the acidified silicate acts as a depressing agent; and as an additional depressant, employment may be made of a tannin containing material, especially tanning extracts prepared by treating tannin containing substances with water and evaporating usually to a thick syrup or to dryness, and as tannin containing materials, mention may be made of chestnut, sumac, larch, logwood, oak, hemlock, quebracho, palmetto and osage orange.
  • tannin containing materials mention may be made of chestnut, sumac, larch, logwood, oak, hemlock, quebracho, palmetto and osage orange.
  • the adjuvants may include an alkali metal, viz: sodium and potassium, lignin sulfonate, fluoride and dichromate. Adjustment of the pH value may be effected through the addition of an alkaline reacting material which may be a carbonate, bicarbonate or hydroxide of sodium, potassium or calcium.
  • EXAlVlPLE I Separation of Scheelite An earthy material containing Scheelite is ground with water to form a slurry and the slurry thus produced is heated to boiling temperature. There are then incorporated into the slurry sodium silicate acidified with sulphuric acid, quebracho extract and a mixture of oleic and linoleic acids. The pH value of the slurry is adjusted through the addition of sodium carbonate to about 10.0 either before or after the addition of the desired reagents whereupon the slurry is maintained at boiling, temperature with agitation for about 5 minutes. Thereby there is eifected a conditioning for depression of calcite and other gangue materials and a collection of the desired Scheelite. The boiled slurry is now cooled to approximately F. and separated or collected Scheelite removed by floating. The concentrate thus obtained may be cleaned by refloating with or without the addition of further reagents as found necessary.
  • Bastnasite An earthy material containing Bastnasite which con tains rare earths largely in the form of carbonates and fluorocarbonates, is ground with water to form a slurry which is heated and the pH value thereof adjusted to about 9.0 by the addition thereto of sodium carbonate. Thereafter, the heated slurry is transferred to another receptacle into which sodium lignin sulfonate, acidified sodium silicate, potassium bichromate, sodium fluoride and a fatty acid substance, for example, a mixture of oleic and linoleic acids are introduced and the slurry boiled for about 5 minutes, suitablywith stirring whereby a conditioning for collection of Bastnasite is effected.
  • Earthy materials consisting largely of barite, barytocelestite, calcite, dolomite, silica and silicates are thereby conditioned for depression.
  • the slurry is then cooled by dilution with cool water to a temperature of about F. andfloated.
  • the mineral content of the concentrate thus produced may be concentrated further, i. e. cleaned by adding sodium lignin sulfonate and acidified sodium silicate, and refloating.
  • sodium ligninsulfonate depresses barite and barytocelestite andto some extent also calcite and dolomite
  • the acidified sodium silicate prepared by adding sufiicient sulphuric acid to a silicate of sodium to render the silicate acidic, but suitably not more than equal proportions of sulphuric acid and the silicate of sodium by weight, disperses the fine gangue particles and conditions silica and silicates for depressing
  • the sodium fluoride effects a distinctive recovery of Bastnasite in the presence of the depressants and the mixture of oleic and linoleic acids serves asa collecting and frothing agent for the rare earth
  • a method for selective. separation of a mineral from accompanying earthy material which comprises preparing a slurry with water, heating said slurry approximately to the boiling temperature, adjusting the pH to a value from about 8.5 to about 10.5, incorporating adjuvants, maintaining'at boiling temperature for a minimum period of about l'minute, cooling to a temperature from about 70F. to about 140 F., and floating.
  • a method for selective separation of a mineral from accompanying earthy material which comprises preparing a slurry with Water, heating said slurry approximately to the boiling temperature, adjusting the pH by the addition of an alkalinereacting material to a value from about 8.5 to about l0.5,'incorporating adjuvants, maintaining at boiling temperature for a minimum period of about 1 minute, cooling to a temperature from abou 70 F. to about 140 F., and floating.
  • a method for selective separation of a mineral from accompanying earthy material which comprises preparing a slurry with water, heating said slurry approximately to the boiling temperature, adjustingthe pH to a value from about 8.5 to about 10.5, incorporating adjuvants including an acidified silicate of an alkali metal, said acidification being to a pH value from about 1.0 to about 4.0, maintaining at boiling temperature for a minimum period of about 1 minute, cooling to a temperature from about 70 .F. to about 140 F., and floating.
  • a method 'for selective separation of a mineral from accompanying earthy material which comprises preparing a slurry with water, heating said slurry approxi- 'mately to the boiling temperature, adjusting thepH by the addition of an alkaline reacting material to a value from about 8.5 :to about 10.5, incorporating adjuvants including an acidified silicate of an alkali metalsaid acidification beingto a pH valuefrom about 1.0 to about 4.0, maintaining at boiling temperature for a minimum period of about 1 minute, cooling to a temperature from about 70 F. to about 140 F., and floating.
  • a method for selective separation of a mineral from accompanying earthy material which comprises forming a slurry of earthy material containing Scheelite with water, heating said slurry to about boiling temperature, adjusting the pH to a value from about 8.5 to about 10.5 by the addition of an alkaline reacting material, incorporating adjuvants including an acidified silicate of an alkali metal, said acidification being to a pH value from about 1.0 to about 4.0, agitating at boiling temperature for a minimum period of aboutl minute, cooling to a temperaturefrom about F. to about 140 F., and floating.
  • a method for selective separation of a mineral from accompanying earthy material whichcomprises forming a slurry of an earthy material containing Scheelite with Water, heating said slurry to about boiling temperature, adjusting the pH to a value of about 10.0 by the addition of sodium carbonate, incorporating adjuvants including an acidified silicate ofsodium, said acidification being to a pH value from about 1.0 to about 4.0, agitating at boiling temperature for a period of about 5 minutes, cooling to a temperature of about F., and floating.
  • a method for selective separation of a mineral from accompanying'earthy material which comprises forming a slurry of an earthy'material containing Scheelite with Water, heating said slurry to about boiling temperature, adjusting the pH to a value of about 10.0 by the addition of sodium carbonate, incorporating therewith an acidified silicate of sodium,'said acidification being to a pH value from about 1.0 to about 4.0, a tannin containing material and a mixture containing oleic and linoleic acids, agitating at boiling temperature for a period of about 5 minutes,
  • acidified silicate of an alkali metal said acidification being I to a pH value from about 1.0 to about 4.0.
  • the. improvement 7 which comprises incorporating into a slurry of such a material having a pH value from about 8.5 to about 10.5, a sodium silicate acidified with sulphuric' acid, said acidification being to a pH value from about 1.0 to about 4.0
  • a method for selective separation of a mineral from accompanying ,earthy material comprising heatinga slurry'having a pH value from about 8.5 to about 10.5 containinga member of the group consisting of Bastnasite and Scheelite to about boiling temperature,-and incorporation therewith of an acidified silicate of an alkali metal, said acidification being to a pH value from about 1.0 to about 4.0.
  • a method for selective separation of a mineral from accompanying earthy material which comprises preparing a slurry with water, heating said slurry approximately to the boiling temperature, adjusting the pH to a value from about 8.5 to about 10.5, incorporating adjuvants including a member of the group consistingpf acidified silicates; and lignin sulfonates of an alkalimetal, said acidification of the silicate being to a pH value from about 1.0 to about 4.0, maintaining at boiling temperature fora minimum periodofabout 1 minute, cooling to a temperature from about 70 F. to about F., and

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  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Description

United States Patent "6 PREPARATORY TREATMENT FOR FROTH FLOTATION Alexander Murray Wilson, Mountain Pass, via Nipton, Califi, Herbert Spencer Woodward, Good Springs, Nev., Harold Durward Bailey, San Bernardino, Calif., and Emil August Lucas, Washington, Pa., assignors to Molybdenum Corporation of America, New York, N. Y., a corporation of Delaware No Drawing. Application July 24, 1953, Serial No. 370,220
13 Claims. (Cl. 209-11) The invention relates to a method for the separation of a mineral from accompanying earthy material, or gangue, and more particularly, to the separation of tungsten and rare earth ores from gangue and includes correlated improvements and discoveries whereby such a separation may be advantageously accomplished.
An object of the invention is the provision of a method in accordance with which a marked recovery of a high concentration of mineral may be obtained from an earthy material containing a small percentage of such mineral.
A further object of the invention is to provide a method for recovering a desired mineral from earthy material as a high grade salable concentrate.
Another object of the invention is the provision of a method for the recovery of a mineral which may be readily, effectively and economically carried out.
A more particular object of the invention is the provision of a method whereby a mineral concentrate may be separated from earthy material or gangue with distinctively high recoveries. V
A specific object of the invention is the provision of a method which entails boiling a slurry of earthy material containing a mineral, e. g'. Scheelite or Bastnasite, in the presence of adjuvants under adjusted pH conditions followed by cooling, and finally floating.
Other objects of the invention will in part be obvious and will in part appear hereinafter. p
The invention accordingly comprises the several steps and the relation of one or more of such steps with respect to each of the others thereof, which will be exemplified in the method hereinafter disclosed, and the scope of the invention will be indicated in the claims.
In the practice of the invention, a mineral may be selectively. separated from accompanying earthy material or gangue by a method which comprises forming a slurry thereof with water, heating the slurry, suitably to about boiling temperature, and incorporating adiuvants which may be a depressing agent, a collecting agent and a frothing agent, including an acidified silicate of an alkali metal viz: sodium and potassium. The pH is adjusted, either before or after addition of adjuvants, to a value from about 8.5 to about 10.5, preferably about 10.0, by the addition of an alkaline reacting material, and the temperature of the slurry maintained at about boiling temperature for a critical minimum period of about 1 minute and which period may be about 10 minutes, preferably for about 5 minutes, with agitation which may be effected through the introduction of compressed air or steam, or ay-mechanical means. The slurry is then cooled to a temperature from about 70 F to about 140 F more particularly to about 100 F. and finally floated. More particularly, the adjuvants may include a member of the group consisting of acidified silicates and lignin sulfonates of an alakil metal.
Various mineral values may be selectively separated by the relatively high temperature procedure described herein and more especially, Scheelite, Arsenopyrite, Cobaltite,
Patented Apr. 10, 1956 Monazite, and Bastnasite. Bastnasite is a mineral found at Mountain Pass, California, which contains rare earths as carbonates and fluorocarbonates.
The acidified silicate of an alkali metal may be a sodium or a potassium silicate to which an amount of a mineral acid as sulphuric, hydrochloric, phosphoric acids or an organic acid such as oxalic, tartaric and citric acids, has been added to render the reagent acidic, preferably having a pH value from about 1.0 to about 4.0. Thus, the acidified silicate may be a sodium silicate to which sulphuric acid or other acid has been added to the desired pH.
The acidified silicate acts as a depressing agent; and as an additional depressant, employment may be made of a tannin containing material, especially tanning extracts prepared by treating tannin containing substances with water and evaporating usually to a thick syrup or to dryness, and as tannin containing materials, mention may be made of chestnut, sumac, larch, logwood, oak, hemlock, quebracho, palmetto and osage orange. As collecting and frothing agents, use may be made of mixtures of higher fatty acids such as a mixture of oleic and linoleic acids. The adjuvants may include an alkali metal, viz: sodium and potassium, lignin sulfonate, fluoride and dichromate. Adjustment of the pH value may be effected through the addition of an alkaline reacting material which may be a carbonate, bicarbonate or hydroxide of sodium, potassium or calcium. 7
As an illustrative embodiment of a manner in which the invention may be practiced, the following examples are presented:
EXAlVlPLE I Separation of Scheelite An earthy material containing Scheelite is ground with water to form a slurry and the slurry thus produced is heated to boiling temperature. There are then incorporated into the slurry sodium silicate acidified with sulphuric acid, quebracho extract and a mixture of oleic and linoleic acids. The pH value of the slurry is adjusted through the addition of sodium carbonate to about 10.0 either before or after the addition of the desired reagents whereupon the slurry is maintained at boiling, temperature with agitation for about 5 minutes. Thereby there is eifected a conditioning for depression of calcite and other gangue materials and a collection of the desired Scheelite. The boiled slurry is now cooled to approximately F. and separated or collected Scheelite removed by floating. The concentrate thus obtained may be cleaned by refloating with or without the addition of further reagents as found necessary.
EXAMPLE II Separation of Bastnasite An earthy material containing Bastnasite which con tains rare earths largely in the form of carbonates and fluorocarbonates, is ground with water to form a slurry which is heated and the pH value thereof adjusted to about 9.0 by the addition thereto of sodium carbonate. Thereafter, the heated slurry is transferred to another receptacle into which sodium lignin sulfonate, acidified sodium silicate, potassium bichromate, sodium fluoride and a fatty acid substance, for example, a mixture of oleic and linoleic acids are introduced and the slurry boiled for about 5 minutes, suitablywith stirring whereby a conditioning for collection of Bastnasite is effected. Earthy materials consisting largely of barite, barytocelestite, calcite, dolomite, silica and silicates are thereby conditioned for depression. The slurry is then cooled by dilution with cool water to a temperature of about F. andfloated.
The mineral content of the concentrate thus produced may be concentrated further, i. e. cleaned by adding sodium lignin sulfonate and acidified sodium silicate, and refloating. As to the roles of theadjuvants, it may be mentioned that sodium ligninsulfonate depresses barite and barytocelestite andto some extent also calcite and dolomite; the acidified sodium silicate prepared by adding sufiicient sulphuric acid to a silicate of sodium to render the silicate acidic, but suitably not more than equal proportions of sulphuric acid and the silicate of sodium by weight, disperses the fine gangue particles and conditions silica and silicates for depressing; the potassium bichromate depresses calcite and dolomite; the sodium fluoride effects a distinctive recovery of Bastnasite in the presence of the depressants and the mixture of oleic and linoleic acids serves asa collecting and frothing agent for the rare earths,
The foregoing procedures effect the separation of minerals, such as Scheelite and rare earths as Bartnasite from earthy or gangue material with the production of high-grade concentrates and with high recoveries. Thus, whenan ore containing about 0.60 W03 was treated, concentrates were obtained of at least 60% W03 content and recoveries as high as 90% W03 have been obtained.
Since certain changes may be made in carrying out the above method without departing from the scope of the invention, it is intended that all matter contained in the above description shall be interpreted as illustrative and not in a limiting reuse.
It is also to be understood that the following claims are intended to cover all of the generic and specific features of the invention herein described, and all statements of thescope of the invention which, as 'a matter of language, might be said to fall therebetween.
Having described our invention, what we claim as new and desire to secure by Letters Patent is:
1. A method for selective. separation of a mineral from accompanying earthy material which comprises preparing a slurry with water, heating said slurry approximately to the boiling temperature, adjusting the pH to a value from about 8.5 to about 10.5, incorporating adjuvants, maintaining'at boiling temperature for a minimum period of about l'minute, cooling to a temperature from about 70F. to about 140 F., and floating.
2. A method for selective separation of a mineral from accompanying earthy material which comprises preparing a slurry with Water, heating said slurry approximately to the boiling temperature, adjusting the pH by the addition of an alkalinereacting material to a value from about 8.5 to about l0.5,'incorporating adjuvants, maintaining at boiling temperature for a minimum period of about 1 minute, cooling to a temperature from abou 70 F. to about 140 F., and floating.
3. A method for selective separation of a mineral from accompanying earthy material which comprises preparing a slurry with water, heating said slurry approximately to the boiling temperature, adjustingthe pH to a value from about 8.5 to about 10.5, incorporating adjuvants including an acidified silicate of an alkali metal, said acidification being to a pH value from about 1.0 to about 4.0, maintaining at boiling temperature for a minimum period of about 1 minute, cooling to a temperature from about 70 .F. to about 140 F., and floating.
4. A method 'for selective separation of a mineral from accompanying earthy material which comprises preparing a slurry with water, heating said slurry approxi- 'mately to the boiling temperature, adjusting thepH by the addition of an alkaline reacting material to a value from about 8.5 :to about 10.5, incorporating adjuvants including an acidified silicate of an alkali metalsaid acidification beingto a pH valuefrom about 1.0 to about 4.0, maintaining at boiling temperature for a minimum period of about 1 minute, cooling to a temperature from about 70 F. to about 140 F., and floating.
5. A method for selective separation of a mineral from accompanying earthy material which comprises forming a slurry of earthy material containing Scheelite with water, heating said slurry to about boiling temperature, adjusting the pH to a value from about 8.5 to about 10.5 by the addition of an alkaline reacting material, incorporating adjuvants including an acidified silicate of an alkali metal, said acidification being to a pH value from about 1.0 to about 4.0, agitating at boiling temperature for a minimum period of aboutl minute, cooling to a temperaturefrom about F. to about 140 F., and floating.
6. A method for selective separation of a mineral from accompanying earthy material whichcomprises forming a slurry of an earthy material containing Scheelite with Water, heating said slurry to about boiling temperature, adjusting the pH to a value of about 10.0 by the addition of sodium carbonate, incorporating adjuvants including an acidified silicate ofsodium, said acidification being to a pH value from about 1.0 to about 4.0, agitating at boiling temperature for a period of about 5 minutes, cooling to a temperature of about F., and floating.
7. A method for selective separation of a mineral from accompanying'earthy material which comprises forming a slurry of an earthy'material containing Scheelite with Water, heating said slurry to about boiling temperature, adjusting the pH to a value of about 10.0 by the addition of sodium carbonate, incorporating therewith an acidified silicate of sodium,'said acidification being to a pH value from about 1.0 to about 4.0, a tannin containing material and a mixture containing oleic and linoleic acids, agitating at boiling temperature for a period of about 5 minutes,
.coolingto a temperature of about 100 F., and floating.
8. In a method for selective separation of a mineral from accompanying earthy material, the improvement which comprises incorporating into a slurry of such a material having a pH value from about 8.5 to about 10.5, an
acidified silicate of an alkali metal, said acidification being I to a pH value from about 1.0 to about 4.0.
9. In a method for selective separation of a mineral from accompanying earthy material, the. improvement 7 which comprises incorporating into a slurry of such a material having a pH value from about 8.5 to about 10.5, a sodium silicate acidified with sulphuric' acid, said acidification being to a pH value from about 1.0 to about 4.0
10. In a method, for selective separation of a mineral from accompanying earthy material, the improvement which comprises heating a slurry of sucha material having a pH value from about 8.5 to about 10.5, to about boiling temperature, and incorporation therewith of anacidified silicate of an alkali metal, said acidification being to a pH value from about 1.0 to about 4.0
11. In a method for selective separation of a mineral from accompanying ,earthy material, the improvement which comprises heatinga slurry'having a pH value from about 8.5 to about 10.5 containinga member of the group consisting of Bastnasite and Scheelite to about boiling temperature,-and incorporation therewith of an acidified silicate of an alkali metal, said acidification being to a pH value from about 1.0 to about 4.0. Y
12. A method for selective separation of a mineral from accompanying earthy material which comprises preparing a slurry with water, heating said slurry approximately to the boiling temperature, adjusting the pH to a value from about 8.5 to about 10.5, incorporating adjuvants including a member of the group consistingpf acidified silicates; and lignin sulfonates of an alkalimetal, said acidification of the silicate being to a pH value from about 1.0 to about 4.0, maintaining at boiling temperature fora minimum periodofabout 1 minute, cooling to a temperature from about 70 F. to about F., and
floating. 7
13. In a methodfor selective separation of a mineral 6 fonate into a slurry of such a material substantially at the 2,373,305 Gieseke Aug. 10, 1945 boiling temperature, said slurry having a pH value from 2,407,651 7 Clemmer et a1. Sept. 17, 1946 about 8.5 to about 10.5. 2,471,414 Dasher May 31, 1949 2,607,479 Bates Aug. 19, 1952 References Clted 1n the file of tins patent 5 OTHER REFERENCES UNITED STATES PATENTS Bureau of Mines, Report of Investigations 4919, Octo- 2,120,485 Clemmer et a1. June 14, 1938 her 1952, pages 4 and 11.

Claims (1)

1. A METHOD FOR SELECTIVE SEPARATION OF A MINERAL FROM ACCOMPANYING EARTHY MATERIAL WHICH COMPRISES PREPARING A SLURRY WITH WATER, HEATING SAID SLURRY APPROXIMATELY TO THE BOILING TEMPERATURE, ADJUSTING THE PH TO A VALVE FROM ABOUT 8.5 TO ABOUT 10.5, INCORPORATING ADJUVANTS MAINTAINING AT BOILING TEMPERATURE FOR A MINIMUM PERIOD OF ABOUT 1 MINUTE, COOLING TO A TEMPERATURE FROM ABOUT 70* F. TO ABOUT 140* F., AND FLOATING
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3067957A (en) * 1959-09-08 1962-12-11 Cleveland Cliffs Iron Process of upgrading iron ore concentrates
US3246748A (en) * 1962-12-17 1966-04-19 Burwell Blair Flotation concentration of non-metallic minerals containing calcite
US3768738A (en) * 1971-10-21 1973-10-30 United States Borax Chem Flotation of arsenic minerals from borate ores
US3913742A (en) * 1973-05-29 1975-10-21 Heikki Reino Laapas Flotation of oxide minerals in hot pulp
US3915391A (en) * 1972-07-17 1975-10-28 Engelhard Min & Chem Recovery of scheelite from ores by flotation
US4040519A (en) * 1974-03-28 1977-08-09 Nittetsu Mining Company, Ltd. Froth flotation process for recovering sheelite
US4229287A (en) * 1978-12-04 1980-10-21 Engelhard Minerals & Chemicals Corporation Tin flotation
US4366050A (en) * 1981-01-19 1982-12-28 Amax Inc. Scheelite flotation
US4368117A (en) * 1978-06-22 1983-01-11 Outokumpu Oy Process for the selective froth-flotation of sulfidic, oxidic and salt-type minerals

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2120485A (en) * 1933-12-29 1938-06-14 Semmes And Semmes Ore flotation
US2373305A (en) * 1942-10-07 1945-04-10 American Cyanamid Co Tungsten ore flotation
US2407651A (en) * 1944-11-01 1946-09-17 Nasa Concentrating fluorspar by froth flotation
US2471414A (en) * 1945-01-11 1949-05-31 Dasher John Conditioning minerals for film concentration
US2607479A (en) * 1948-02-04 1952-08-19 California Research Corp Agglomerate tabling of tungsten bearing ores

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2120485A (en) * 1933-12-29 1938-06-14 Semmes And Semmes Ore flotation
US2373305A (en) * 1942-10-07 1945-04-10 American Cyanamid Co Tungsten ore flotation
US2407651A (en) * 1944-11-01 1946-09-17 Nasa Concentrating fluorspar by froth flotation
US2471414A (en) * 1945-01-11 1949-05-31 Dasher John Conditioning minerals for film concentration
US2607479A (en) * 1948-02-04 1952-08-19 California Research Corp Agglomerate tabling of tungsten bearing ores

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3067957A (en) * 1959-09-08 1962-12-11 Cleveland Cliffs Iron Process of upgrading iron ore concentrates
US3246748A (en) * 1962-12-17 1966-04-19 Burwell Blair Flotation concentration of non-metallic minerals containing calcite
US3768738A (en) * 1971-10-21 1973-10-30 United States Borax Chem Flotation of arsenic minerals from borate ores
US3915391A (en) * 1972-07-17 1975-10-28 Engelhard Min & Chem Recovery of scheelite from ores by flotation
US3913742A (en) * 1973-05-29 1975-10-21 Heikki Reino Laapas Flotation of oxide minerals in hot pulp
US4040519A (en) * 1974-03-28 1977-08-09 Nittetsu Mining Company, Ltd. Froth flotation process for recovering sheelite
US4368117A (en) * 1978-06-22 1983-01-11 Outokumpu Oy Process for the selective froth-flotation of sulfidic, oxidic and salt-type minerals
US4229287A (en) * 1978-12-04 1980-10-21 Engelhard Minerals & Chemicals Corporation Tin flotation
US4366050A (en) * 1981-01-19 1982-12-28 Amax Inc. Scheelite flotation

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