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US2633347A - Rotary internally-fired kiln - Google Patents

Rotary internally-fired kiln Download PDF

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US2633347A
US2633347A US223933A US22393351A US2633347A US 2633347 A US2633347 A US 2633347A US 223933 A US223933 A US 223933A US 22393351 A US22393351 A US 22393351A US 2633347 A US2633347 A US 2633347A
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lining
kiln
coating
concrete
conductive
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US223933A
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Arthur W Heyman
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GOOD SHEPHERD HOME
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GOOD SHEPHERD HOME
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/20Details, accessories or equipment specially adapted for rotary-drum furnaces
    • F27B7/28Arrangements of linings

Definitions

  • This invention relates to rotary internally-med kilns and more particularly to the burning-zone lining of internally-med kilns such as are used in the production of Portland cement, lime and similar materials.
  • a steel cylinder In kilns of this general type, a steel cylinder is provided with a lining of flrebrick.
  • the ilrebrick prevents destruction of the steel cylinder and a coating of the material being processed protects the flrebrick. Were it not for this coating of the material under process, the nrebrick would be destroyed and the cylinder ruined.
  • it is exceedingly important therefore to maintain a relatively thick layer or coating of the material being processed on the rebrick and particularly on the rebrick which lines the lower end of the kiln at the point where the temperatures are highest.
  • the kiln is heated gradually while the raw material moves downwardly through the kiln and becomes decarbonated. 'I'his occurs in the calcining zone of the kiln.
  • the temperature is increased until the surface of the rebrick begins to melt.
  • the decarbonated material flows over the melted rebrick surfaces and unites therewith to form the initial coating. This phenomenon'takes place in the burning zone of the kiln.
  • the coating may be built up to a thickness of several inches.
  • the material at the junction between the iirebrick and the coating has a much lower melting point than either the coating or the brick and, due to the fact that Aexcessively high temperatures are occasionally built up in the kiln, such overheating may penetrate a coating which has not attained sufficient thickness, whereupon the junction material may soften and the coating fall ofi.
  • Another object of this invention it the provision of a lining construction for ⁇ kilns of the type herein referred to, in which provision is made for better heat dissipation whereby the accumulation of excessive heat in the bond between the lining and its coating is prevented.
  • the key to the present invention lies in the recognition of the fact that good heat dissipation through the kiln wall is necessary to prevent destruction of the bond between the kiln lining and the coating applied thereto. It has 10 heretofore been believed that only rebrick or a substance equally as indestructible as flrebrick l in the presence of heat, is necessary to protect the steel cylinder which constitutes the outer wall of the kiln. Although the lining of the kiln protects the steel cylinder, such lining-even if composed of the most refractory rebrick--also needs protection from the heat and from the erosive and scorifying effects of the materialV being processed and this is furnished by the above mentioned coating. If this coating can be built up to such a thickness that the bond between coating and lining is not weakened by the occasional overheats which sometimes occui during operation, then it is unnecessary for the lining to be resistant to high temperatures.
  • the method by which the present invention is carried out consists in substituting a heat-conductive material for the less-conductive flrebrick.
  • the steel cylinder is lined in whole or in part with a composition consisting of concre i l balls xnw, e metal is ighly conductive and the more metal the concrete contains,-4 the more conductive will be the lining.
  • Figure 1 is a cross sectional view through a 40 typical kiln of the character to which the lining forming the subject matter of this application is applied;
  • Figure-2 is an enlarged detailed fragmentary view of a portion of the kiln wall showing the nature of the new lining
  • Figure 3 is a view showing a rotary internallyred kiln to which the lining is applied.
  • the kiln I0 has an outer wall or shell Il which is made of steel plate. 5o
  • a lining I2 is applied to the inside surface of said wall, and it will be seen that said lining comprises a concrete mix containing pieces of metal I3. These pieces of metal may be scrap metal, metal balls, borings and filings, or the like.
  • the type of metal which may be used is not critical and the prime consideration is that it be highly conductive to heat. Therefore, scrap iron, for example. would be highly desirable to use for the purpose indicated. If the more expensive metals such as copper are also used. the purposes for which the present invention has been devised will be served equally as well. The more metal the concrete mix contains, the more conductive will the lining as a whole be.
  • the ratio of metal pieces to the cementitious binder is such that a preponderance of metal is present, It is not m intent to limit this disclosure to a defined percentage. With the fact in mind that extensive conductivity is the aim, efficiency can be obtained by a selected degree of preponderance of metal as long as the cementitous material is suilicient in quantity to provide proper binder and adhesive surface for 4the formation of the coating of raw material in the kiln.
  • the concrete itself may be laid directly upon the inside of the wall I i, being cast into the shape of a cylindrical shell surrounded by .the metal wall or shell il.
  • the conductive lining may .consist basically of a binder of any type of cementitious material of the class known to the industry as hydraulic cements and this binder mixed with metal as described.
  • An illustrative mix or composition however, Wammes-mmm welg t of a y raul'iccemeiitucl as calcuim alummate cement, aout one part byftigeigfr Crus e. e Hek ahfLplllourinsixcparts bs weight of scra metal.
  • Sufllcient water is added t'wmake'a dense concrete and this is tamped or vibrated into place on the inside of the steel shell.
  • the pieces of metal should be of various sizes (like sand and gravel'l'ndmary'concretewinrder to attain greater density. Porosity increases the insulating quality of the concrete and this would negative to a certain extent the heat dissipating benets which would be attained by incorporating metal into the concrete mix.
  • the concrete has hereinabove been described as being laid directly upon the inside of the steel wall of the kiln, it will be appreciated that the concrete may be preformed in the shape of blocks similar to the rebrick heretofore used. and these concrete blocks may of course be mounted on the inside of the kiln wall in substantially the same manner as has heretofore been done with the rebrck. It may be found desirable when the concrete mix is laid directly upon the kiln wall to ailix metal bars or rods to the inside surface of said wall by means of Welding or by similar means before the mix is laid thereon so that a better attachment or adherence of the concrete to the wall may thereby be attained.
  • lining composition under discussion is applied to the kiln only in those areas Where it is desirable to have a clinker coating I4 such as has above been described. i, e., in the burning zone. In all other parts of the kiln, conventional firebrick or other conventional material may be used for the lining.
  • the readiness with which a thick coating may be formed depends largely on the .heat-dissipating quality of .the lining on which the coating is to be deposited. If such lining is highly nonconductive, it is very diicult to build a coating of the desired thickness. By the use of a conductive lining, heat is more readily dissipated. whereby a coating is formed which is sufficiently thick to prevent the penetration of an overheat to the vulnerable junction point.
  • my conductive lining is doubly eective in protecting the junction point; first, it allows the deposition of a thicker coating; second, it dissipates to the outside shell any heat which may penetrate the coating and thus prevents the melting or softening of the junction material.
  • the kiln under discussion may be a conventional aircooled kiln.
  • it may also be a water-cooled kiln. It will be appreciated that if water is poured or spread upon the kiln shown in the accompanying drawing, even greater heatdissipating qualities will be provided than would be possible in the absence of such water-cooling process.
  • a rotary internally-fired kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone.
  • said lining consisting essentially of a binder of hydraulic cement having a preponderance by Weight of iron pieces of varying size distributed throughout it. together with suflicient water to make it a dense concrete, said lining adapted to have built up thereon a coating of materiaiclneing processed to a thickness such that the i inction of coating and lining does not 5 soften due to occasional overheats of the kiln.
  • a rotary internally-med kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of calcium aluminate cement having a preponderance by weight of highly conductive iron pieces distributed throughout it, together with sufficient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
  • a rotary internally-fired kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of hydraulic cement with crushed rebrick and having a preponderance by weight of iron pieces of varying size distributed throughout it, together with sufiicient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction oi' coating and lining does not soften due to occasional overheats of the kiln.
  • a rotary internally-fired kiln used in the production o1 Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of calcium aluminate cement with crushed nre-brick and having a preponderance by weight of highly conductive iron pieces distributed throughout it, together with suicient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
  • a rotary internally-fired kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of hydraulic cement having from four to six parts by weight of iron pieces of varying size distributed throughout it. together with sufiicient water to make it a dense concrete, said 6 lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
  • a rotary internally-med kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone.
  • said lining consisting essentially of a binder of calcium aluminate cement having from four to six parts by weight of highly conductive iron pieces distributed throughout it, together with suilicient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
  • a rotary internally-fired kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of hydraulic cement with crushed fire brick and having from four to six parts by weight of highly conductive iron particles distributed through it. together with sufficient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Muffle Furnaces And Rotary Kilns (AREA)

Description

1 0 6 9 7 @Ross REFERENCE mmm t E .V
March 31, 1953 A. w. HEYMAN 2,633,347
ROTARY INTERNALLY-FIRED xILN Filed lay 1, 1951 Patented Mar. 31, 1953 ROTARY INTERNALLY-FIRED KILN Arthur W. Heyman, Allentown, Pa., asslgnor to Good Shepherd Home, Allentown, Pa.
Application May 1, 1951, Serial No. 223,933
7 Claims.
This invention relates to rotary internally-med kilns and more particularly to the burning-zone lining of internally-med kilns such as are used in the production of Portland cement, lime and similar materials.
This application is a continuation-in-part of my previous application Serial No. '759,609 led July 8, 1947, and now abandoned.
In kilns of this general type, a steel cylinder is provided with a lining of flrebrick. The ilrebrick prevents destruction of the steel cylinder and a coating of the material being processed protects the flrebrick. Were it not for this coating of the material under process, the nrebrick would be destroyed and the cylinder ruined. In the operation of kilns of the type described, it is exceedingly important therefore to maintain a relatively thick layer or coating of the material being processed on the rebrick and particularly on the rebrick which lines the lower end of the kiln at the point where the temperatures are highest.
The method by which this coating is applied to the rebrick may be described as follows:
Referring now to a rebrick lined kiln used for clinkering Portland cement, the kiln is heated gradually while the raw material moves downwardly through the kiln and becomes decarbonated. 'I'his occurs in the calcining zone of the kiln. When this decarbonated material approaches the point where the coating is desired, the temperature is increased until the surface of the rebrick begins to melt. The decarbonated material flows over the melted rebrick surfaces and unites therewith to form the initial coating. This phenomenon'takes place in the burning zone of the kiln. By skillful handling, the coating may be built up to a thickness of several inches. The material at the junction between the iirebrick and the coating has a much lower melting point than either the coating or the brick and, due to the fact that Aexcessively high temperatures are occasionally built up in the kiln, such overheating may penetrate a coating which has not attained sufficient thickness, whereupon the junction material may soften and the coating fall ofi.
It is accordingly the principal object of this invention to provide a lined construction for kilns of the general type described which will insure a strong and permanent bond between the lining andthe coating which protects the lining.
Another object of this invention it the provision of a lining construction for `kilns of the type herein referred to, in which provision is made for better heat dissipation whereby the accumulation of excessive heat in the bond between the lining and its coating is prevented.
The key to the present invention lies in the recognition of the fact that good heat dissipation through the kiln wall is necessary to prevent destruction of the bond between the kiln lining and the coating applied thereto. It has 10 heretofore been believed that only rebrick or a substance equally as indestructible as flrebrick l in the presence of heat, is necessary to protect the steel cylinder which constitutes the outer wall of the kiln. Although the lining of the kiln protects the steel cylinder, such lining-even if composed of the most refractory rebrick--also needs protection from the heat and from the erosive and scorifying effects of the materialV being processed and this is furnished by the above mentioned coating. If this coating can be built up to such a thickness that the bond between coating and lining is not weakened by the occasional overheats which sometimes occui during operation, then it is unnecessary for the lining to be resistant to high temperatures.
Bearing these considerations in mind, the method by which the present invention is carried out consists in substituting a heat-conductive material for the less-conductive flrebrick. In the preferred form of this invention, the steel cylinder is lined in whole or in part with a composition consisting of concre i l balls xnw, e metal is ighly conductive and the more metal the concrete contains,-4 the more conductive will be the lining.
A preferred form of this invention is shown on the accompanying drawing in which:
Figure 1 is a cross sectional view through a 40 typical kiln of the character to which the lining forming the subject matter of this application is applied;
'Figure-2 is an enlarged detailed fragmentary view of a portion of the kiln wall showing the nature of the new lining; and
Figure 3 is a view showing a rotary internallyred kiln to which the lining is applied.
It will be seen that the kiln I0 has an outer wall or shell Il which is made of steel plate. 5o A lining I2 is applied to the inside surface of said wall, and it will be seen that said lining comprises a concrete mix containing pieces of metal I3. These pieces of metal may be scrap metal, metal balls, borings and filings, or the like. The type of metal which may be used is not critical and the prime consideration is that it be highly conductive to heat. Therefore, scrap iron, for example. would be highly desirable to use for the purpose indicated. If the more expensive metals such as copper are also used. the purposes for which the present invention has been devised will be served equally as well. The more metal the concrete mix contains, the more conductive will the lining as a whole be.
As previously expressed, the ratio of metal pieces to the cementitious binder is such that a preponderance of metal is present, It is not m intent to limit this disclosure to a defined percentage. With the fact in mind that extensive conductivity is the aim, efficiency can be obtained by a selected degree of preponderance of metal as long as the cementitous material is suilicient in quantity to provide proper binder and adhesive surface for 4the formation of the coating of raw material in the kiln. The concrete itself may be laid directly upon the inside of the wall I i, being cast into the shape of a cylindrical shell surrounded by .the metal wall or shell il.
The conductive lining may .consist basically of a binder of any type of cementitious material of the class known to the industry as hydraulic cements and this binder mixed with metal as described. An illustrative mix or composition however, Wammes-mmm welg t of a y raul'iccemeiitucl as calcuim alummate cement, aout one part byftigeigfr Crus e. e Hek ahfLplllourinsixcparts bs weight of scra metal. Sufllcient water is added t'wmake'a dense concrete and this is tamped or vibrated into place on the inside of the steel shell. As much metal as possible is used consistent with the attainment of @porosity in the final concrete product; also, the pieces of metal should be of various sizes (like sand and gravel'l'ndmary'concretewinrder to attain greater density. Porosity increases the insulating quality of the concrete and this would negative to a certain extent the heat dissipating benets which would be attained by incorporating metal into the concrete mix.
While calcium alumnate cement is a preferable binder for the lining, it should be kept in mind that Portland or any other type of hydraulic cement could be used and such use would not be a departure from the scope of this invention.
Although the concrete has hereinabove been described as being laid directly upon the inside of the steel wall of the kiln, it will be appreciated that the concrete may be preformed in the shape of blocks similar to the rebrick heretofore used. and these concrete blocks may of course be mounted on the inside of the kiln wall in substantially the same manner as has heretofore been done with the rebrck. It may be found desirable when the concrete mix is laid directly upon the kiln wall to ailix metal bars or rods to the inside surface of said wall by means of Welding or by similar means before the mix is laid thereon so that a better attachment or adherence of the concrete to the wall may thereby be attained.
It should be understood that the lining composition under discussion is applied to the kiln only in those areas Where it is desirable to have a clinker coating I4 such as has above been described. i, e., in the burning zone. In all other parts of the kiln, conventional firebrick or other conventional material may be used for the lining.
The process by which the clinker coating may be deposited upon the concrete lining under discussion may now be described. Substantially the same process as has above been described in connection with conventionally lined kilns may be followed in connection with the concrete lining of the present invention. The newly-lined kiln is heated until the raw material which moves down the kiln becomes decarbonated. This of course is a. continuous process, and when the decarbonated material approaches the concrete lining, the temperature is increased to such a .degree that the exposed surface of the concrete lining is caused to melt. When the decarbonated material flows over the melted surface of the concrete lining, .a bond is created between such material and said lining and the initial coating is thereby achieved. The process continues until the coating is built up to a desirable thickness.
It is recognized by men skilled in the art that the readiness with which a thick coating may be formed depends largely on the .heat-dissipating quality of .the lining on which the coating is to be deposited. If such lining is highly nonconductive, it is very diicult to build a coating of the desired thickness. By the use of a conductive lining, heat is more readily dissipated. whereby a coating is formed which is sufficiently thick to prevent the penetration of an overheat to the vulnerable junction point.
Thus, in my invention I have departed from the old established theory in the industry that a highly protective lining such as rebrick is absolutely essential. By turning to the theory of conductivity I have proved that a lining which will readily conduct heat Will so permit the buildup of clinker coating that the protective characteristics of the lining composition is not critical.
C It will be seen that my conductive lining is doubly eective in protecting the junction point; first, it allows the deposition of a thicker coating; second, it dissipates to the outside shell any heat which may penetrate the coating and thus prevents the melting or softening of the junction material.
It will be understood from the foregoing that, although the concrete lining is not as resistant as ordinary flrebrick to the destructive effect of high temperatures it will nevertheless have a much longer life because of the greater protection afforded by the thicker coating.
The invention above described is susceptible of modifications in accordance with the practices and skills of the art and these modifications are contemplated herein. For example, the kiln under discussion may be a conventional aircooled kiln. On the other hand, it may also be a water-cooled kiln. It will be appreciated that if water is poured or spread upon the kiln shown in the accompanying drawing, even greater heatdissipating qualities will be provided than would be possible in the absence of such water-cooling process.
I claim:
1. A rotary internally-fired kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone. said lining consisting essentially of a binder of hydraulic cement having a preponderance by Weight of iron pieces of varying size distributed throughout it. together with suflicient water to make it a dense concrete, said lining adapted to have built up thereon a coating of materiaiclneing processed to a thickness such that the i inction of coating and lining does not 5 soften due to occasional overheats of the kiln.
2. A rotary internally-med kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of calcium aluminate cement having a preponderance by weight of highly conductive iron pieces distributed throughout it, together with sufficient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
3. A rotary internally-fired kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of hydraulic cement with crushed rebrick and having a preponderance by weight of iron pieces of varying size distributed throughout it, together with sufiicient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction oi' coating and lining does not soften due to occasional overheats of the kiln.
4. A rotary internally-fired kiln used in the production o1 Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of calcium aluminate cement with crushed nre-brick and having a preponderance by weight of highly conductive iron pieces distributed throughout it, together with suicient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
5. A rotary internally-fired kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of hydraulic cement having from four to six parts by weight of iron pieces of varying size distributed throughout it. together with sufiicient water to make it a dense concrete, said 6 lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
6. A rotary internally-med kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone. said lining consisting essentially of a binder of calcium aluminate cement having from four to six parts by weight of highly conductive iron pieces distributed throughout it, together with suilicient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
7. A rotary internally-fired kiln used in the production of Portland cement, lime and similar materials having a conductive lining in its burning zone, said lining consisting essentially of a binder of hydraulic cement with crushed fire brick and having from four to six parts by weight of highly conductive iron particles distributed through it. together with sufficient water to make it a dense concrete, said lining adapted to have built up thereon a coating of material being processed to a thickness such that the junction of coating and lining does not soften due to occasional overheats of the kiln.
ARIHUR W. HEYMAN.
REFERENCES CITED The following references are of record in the le of this patent:
UNITED STATES PATENTS Number Name Date 531,520 Eddy Dec. 25, 1894 895,787 Pope Aug. 11, 1908 1,364,587 Sanders et al Jan. 4, 1921 1,470,378 Kleinlogel Oct. 9, 1923 1,647,083 Croll Oct. 25, 1927 1,817,421 Saito Aug. 4, 1931 2,170,434 Seigle Aug. 22, 1939 2,279,262 Edwards Apr. 7, 1942
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3332751A (en) * 1965-11-04 1967-07-25 Du Pont Corrosion-inhibited sintered composite of a metal matrix with occluded cement
US4168915A (en) * 1976-07-30 1979-09-25 Ed. Zublin Aktiengesellschaft Rotary drum
EP0263404A1 (en) * 1986-09-30 1988-04-13 Nihon Cement Co., Ltd. Rotary kiln
US5566626A (en) * 1994-12-12 1996-10-22 Rollins Environmental Services, Inc. Incineration kiln devices and methods of protecting the same
US5695329A (en) * 1996-09-24 1997-12-09 Orcutt; Jeffrey W. Rotary kiln construction with improved insulation means
US5873714A (en) * 1997-03-03 1999-02-23 Reframerica, Inc. Rotary kiln having a lining with a wave-shaped inner face
US20160153717A1 (en) * 2013-06-04 2016-06-02 Sichuan Ko Chang Technology Co., Ltd Rotary kiln for reducing phosphate ore in kiln phosphoric acid process and method for solving ring forming in kiln tail in kiln phosphoric acid process

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US531520A (en) * 1894-12-25 Composition for artificial stone
US895787A (en) * 1908-02-21 1908-08-11 Charles E Pope Brick or lining composition for use at high temperatures and process of making the same.
US1364587A (en) * 1915-12-10 1921-01-04 Sanders Ludwig Adrian Coating process
US1470378A (en) * 1921-12-05 1923-10-09 Kleinlogel Adolf Method of manufacturing artificial building materials
US1647083A (en) * 1923-07-05 1927-10-25 Atlas Portland Cement Company Furnace lining
US1817421A (en) * 1927-10-18 1931-08-04 Saito Hachiro Lining brick for rotary cement kilns
US2170434A (en) * 1935-10-12 1939-08-22 Johns Manville Article of manufacture and method of making the same
US2279262A (en) * 1937-02-15 1942-04-07 Continental Oil Co Weighted cement

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US531520A (en) * 1894-12-25 Composition for artificial stone
US895787A (en) * 1908-02-21 1908-08-11 Charles E Pope Brick or lining composition for use at high temperatures and process of making the same.
US1364587A (en) * 1915-12-10 1921-01-04 Sanders Ludwig Adrian Coating process
US1470378A (en) * 1921-12-05 1923-10-09 Kleinlogel Adolf Method of manufacturing artificial building materials
US1647083A (en) * 1923-07-05 1927-10-25 Atlas Portland Cement Company Furnace lining
US1817421A (en) * 1927-10-18 1931-08-04 Saito Hachiro Lining brick for rotary cement kilns
US2170434A (en) * 1935-10-12 1939-08-22 Johns Manville Article of manufacture and method of making the same
US2279262A (en) * 1937-02-15 1942-04-07 Continental Oil Co Weighted cement

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3332751A (en) * 1965-11-04 1967-07-25 Du Pont Corrosion-inhibited sintered composite of a metal matrix with occluded cement
US4168915A (en) * 1976-07-30 1979-09-25 Ed. Zublin Aktiengesellschaft Rotary drum
EP0263404A1 (en) * 1986-09-30 1988-04-13 Nihon Cement Co., Ltd. Rotary kiln
US5566626A (en) * 1994-12-12 1996-10-22 Rollins Environmental Services, Inc. Incineration kiln devices and methods of protecting the same
US5695329A (en) * 1996-09-24 1997-12-09 Orcutt; Jeffrey W. Rotary kiln construction with improved insulation means
US5873714A (en) * 1997-03-03 1999-02-23 Reframerica, Inc. Rotary kiln having a lining with a wave-shaped inner face
US20160153717A1 (en) * 2013-06-04 2016-06-02 Sichuan Ko Chang Technology Co., Ltd Rotary kiln for reducing phosphate ore in kiln phosphoric acid process and method for solving ring forming in kiln tail in kiln phosphoric acid process
US9982947B2 (en) * 2013-06-04 2018-05-29 Sichuan Ko Chang Technology Co., Ltd. Rotary kiln for reducing phosphate ore in kiln phosphoric acid process and method for solving ring forming in kiln tail in kiln phosphoric acid process

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