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US2626870A - Wax and silicone oil auto polish - Google Patents

Wax and silicone oil auto polish Download PDF

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Publication number
US2626870A
US2626870A US131244A US13124449A US2626870A US 2626870 A US2626870 A US 2626870A US 131244 A US131244 A US 131244A US 13124449 A US13124449 A US 13124449A US 2626870 A US2626870 A US 2626870A
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United States
Prior art keywords
wax
weight
amount
water
silicone oil
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Expired - Lifetime
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US131244A
Inventor
Henry H Cooke
Russo Dominick
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Standard Oil Development Co
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Standard Oil Development Co
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Priority to US131244A priority Critical patent/US2626870A/en
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Publication of US2626870A publication Critical patent/US2626870A/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09G—POLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00—Polishing compositions
    • C09G1/02—Polishing compositions containing abrasives or grinding agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/01—Silicones

Definitions

  • compositions of a type adaptable for use on smooth, painted or enameled surfaces are quite familiar to those experienced in the art.
  • One of the more popular of these polishes is the wax composition of the oil-in-water emulsion type which has found wide usage for polishing automobiles.
  • the more important ingredients of the water emulsion polishes of this invention are: silicone oils, wax, an abrasive, an emulsifying agent of the bodying type, a water soluble wetting agent, and an organic solvent for the wax.
  • silicone oils employed may be represented by the following chemical formula in which siloxane units are joined together to form chains of varying length.
  • the methyl groups may be substituted or re placed by other organic or inorganic groups or by single atoms.
  • These silicone fluids are complex, highly molecular weight polymers whose viscosity varies roughly directly with molecular Weight.
  • the characteristics of the silicone oils which are useful in the compositions of this invention are illustrated below in Tables I, II and III.
  • non-ionic emulsifying agents such as the ethyl- Viscosity Flash Gt Reir. ene oxide condensation products of alkylated 3 9;- g gf' 25 0. gggsg phenols may also be used.
  • the products of this invention consist of two 2040 120 M62 407 phases, the aqueous or continuous phase and the oily or dispersed phase.
  • the oily phase To form the oily phase,
  • Silicone oils having an upper viscosity limit of 500 cstks. at 25 C. are particularly effective.
  • the preferred range of the silicone oil in the aqueous emulsion compositions of this invention is about from 0.001 to 5% by weight.
  • the amount of silicone oil employed varies roughly in an inverse manner to the viscosity of the oils. Mixtures of silicone oils can be employed. Solid and semisolid silicone polymers may also be used. It should be noted particularly that very small quantities of these silicone oils give the desired effect. These silicone oils may also be incorporated in paste type polishes.
  • the waxes employed in the compositions of this invention are synthetic waxes, natural waxes, or mixtures. It is to be understood that the term waxes as used herein refers to any combination of the before-mentioned types.
  • the range of the waxes in the polishing compositions is about from 0.2 to 15% and preferably 1 to 5% by weight.
  • Some of the particular waxes that can be used are 'carnauba wax, beeswax, candelilla, ouricury,
  • Mild abrasives which do not scratch the surface are also used in order to obtain improved cleaning characteristics. These abrasives are utilized in a range of about from 5 to 15% by Weight. Some particular abrasives that can be used are diatomaceous earth, amorphous silica, tripoli and chalk.
  • emulsifying agent of the bodying type is employed in order to obtain stable emulsions of the wax in water. These emulsifying agents are used in a range of about from 0.2 to 4% by weight. It is to be understood that the term emulsifying agents of the budying type" connotes the following type substances: gum tragacanth, gum arabic. bentonite, locust bean gum, starch, albumen, karaya gum, Irish moss, water-colloidable methyl cellulose, and the like.
  • Organic solvents are employed in order to dissolve the wax before dispersion of the latter in the water. These solvents are used in a range of about from 3 to 25% by weight. Typical solvents are illustrated by turpentine, kerosene, Stoddard solvent. naphtha and spindle oil.
  • Water soluble wetting agents are employed in an amount of less than 1%. These wetting agents contribute to the ready spreading of the polish on the polished surface.
  • the water soluble wetting agents that can be used are the sulfates of long chain alcohols such as dodecanol up to octadecanol, sulfonated amide and ester derivatives, sulfonated aromatic and mixed alkylaryl sulfonate derivatives. esters of fatty acids such as the ricinoleic acid ester of sorbitol, and
  • the wax is gently heated to its melting point and the solvent is added while the mixture is kept warm above the melting point of the wax.
  • An emulsifying agent of the bodying type is added.
  • the silicone oil is then also added.
  • the mixture is stirred until smooth and free from lumps.
  • the aqueous phase is formed by adding the water soluble ingredients such as the wetting agent to hot water, e. g., F.
  • the oil phase is then added slowly to the aqueous phase with continued stirring to effect emulsification.
  • the abrasive is then added with stirring. Coloring matter and odorants are next dispersed in the mixture.
  • the polishing compositions described above are generally useful for imparting a high luster to all kinds of smooth, painted metal surfaces. They are principally useful for polishing automobile bodies finished with various types of coating compositions, including pigmented nitrocellulose lacquers, enamels containing either natural or synthetic resin vehicles, or combinations thereof, asphaltic varnishes and pigmented derivatives thereof, etc. Its use is not confined to automobiles, however; it may be used wherever it is desired to impart a high luster to paint applied over smooth metal surfaces. Thus, it finds wide application in the field of furniture and building partitions, particularly those made of metal; for burial caskets, painted household heating stoves, refrigerators, and for many objects having similar surfaces.
  • the composition is applied to the surface to be polished after most of the dirt and grit has been removed. After it has been allowed to dry, it is wiped off and polished with a clean dry cloth.
  • An emulsion polishing composition of the oil in water type consisting essentially of a straight chain polydimethyl siloxane having a viscosity of no more than 500 centistokes at 25 C. in an amount of from about 0.001 to by weight, a wax in an amount of about from 1 to 5% by weight, an abrasive in an amount of about 5 to 15% by weight, an emulsifying agent of the bodying type in an amount of about from 0.2 to 4% by weight, a hydrocarbon solvent for the wax in an amount of about from 3 to 25% by weight, a water soluble wetting agent selected from the group consisting of synthetic non-ionic and anionic wetting agents in an amount of less'than 1% by weight and the balance water.
  • a polishing composition having approximately the following weight percent composition:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

Patented Jan. 27, 1953 WAX AND SILICONE OIL AUTO POLISH Henry H. Cooke and Dominick Russo, Elizabeth, N. J., assignors to Standard Oil Development Company, a corporation of Delaware No Drawing. Application December 5, 1949,
- Serial No. 131,244
2 Claims.
constitute an old and well-known art. Such compositions of a type adaptable for use on smooth, painted or enameled surfaces, are quite familiar to those experienced in the art. One of the more popular of these polishes is the wax composition of the oil-in-water emulsion type which has found wide usage for polishing automobiles.
It has become apparent in practice, however, that these wax emulsions suffer from certain distinct disadvantages. ne of these disadvantages resides in the formation of wax streaks on the polished surface. This formation of streaks occurs most readily in dry atmospheres. Another disadvantage resides in the excessive amount of rubbing needed in using these wax polishes in order to secure the desired luster.
It has now been found that incorporation of small amounts of silicone oils in the indicated wax oil-in-water type emulsion compositions results in polishes which, when applied to a painted or lacquered metal surface, impart a high degree of luster and a pleasing appearance to the surface, and require comparatively little effort in the application and polishing. These polishes leave no waxy streaks on the surface to which they are applied, even under extremely dry conditions, When the products are applied to the automobile surfaces and allowed to dry, the film is very easy to remove and a high deep luster is obtained without the formation of wax streaks. The silicone oils plasticize the wax and prevent it from drying to a hard film. In addition, the silicone and wax together act as a binder for the abrasive particles in the dried film on the automobile surface, and help to prevent excessive dust formation in the polishing operation. Tests show that this luster stands up exceptionally well under outdoor conditions.
When particles of dust and dirt become attached to the automobile surface, they can be easily removed with a damp cloth and the original luster is obtained again. This is due to the protecting silicone and wax film which remains on the surface. This film is also resistant to rain spotting, and subsequent dirt formations can be readily wiped off with a dusting cloth. All these results are obtained because of the combined cooperative eifect of the wax and silicone oils.
The more important ingredients of the water emulsion polishes of this invention are: silicone oils, wax, an abrasive, an emulsifying agent of the bodying type, a water soluble wetting agent, and an organic solvent for the wax.
The silicone oils employed may be represented by the following chemical formula in which siloxane units are joined together to form chains of varying length.
The methyl groups may be substituted or re placed by other organic or inorganic groups or by single atoms. These silicone fluids are complex, highly molecular weight polymers whose viscosity varies roughly directly with molecular Weight. The characteristics of the silicone oils which are useful in the compositions of this invention are illustrated below in Tables I, II and III.
TABLE I 1 Expansion Cociiicient 1 Viscosity Flash 8 m P d R f oxim per 0. csiks- Grade in point pcc c cum 5 c me We E 25 C. F. 25Ct-0 0 25 tglOO" F' 0 F. 0 F
350 625 O. 972 8. 11 1. 4032 O. 917 0. 956 1, 950 250 135 500 625 O 972 8. 11 1. 4033 0. 909 0. 955 3, 300 370 TABLE II Expansion Viscosity Flash Reir Viscosity in cst ks. Pgint, 9& 560 Ind ex g ig gg a C'Iemp. 100 F. O. 25 C (254500 c oeifielent 4 70 0.9175 0. 390 l. 3910 10. 63x10. 4 0. s20 40 314 0. was 0. an 1. 4031 9. 4t 10. 4 o. 510 100 320 o. 9653 0.370 1. 4030 9. 68Xl0. 4 o. 590 1, 000 323 o. 9603 o. 352 1. 4030 9. 20x10. 4 0. 599
TABLE III petroleum sulfonates of C to C20 length. The
non-ionic emulsifying agents such as the ethyl- Viscosity Flash Gt Reir. ene oxide condensation products of alkylated 3 9;- g gf' 25 0. gggsg phenols may also be used.
The products of this invention consist of two 2040 120 M62 407 phases, the aqueous or continuous phase and the oily or dispersed phase. To form the oily phase,
Silicone oils having an upper viscosity limit of 500 cstks. at 25 C. are particularly effective. The preferred range of the silicone oil in the aqueous emulsion compositions of this invention is about from 0.001 to 5% by weight. The amount of silicone oil employed varies roughly in an inverse manner to the viscosity of the oils. Mixtures of silicone oils can be employed. Solid and semisolid silicone polymers may also be used. It should be noted particularly that very small quantities of these silicone oils give the desired effect. These silicone oils may also be incorporated in paste type polishes.
The waxes employed in the compositions of this invention are synthetic waxes, natural waxes, or mixtures. It is to be understood that the term waxes as used herein refers to any combination of the before-mentioned types. The range of the waxes in the polishing compositions is about from 0.2 to 15% and preferably 1 to 5% by weight. Some of the particular waxes that can be used are 'carnauba wax, beeswax, candelilla, ouricury,
ceresin, paraflin, hydrogenated castor oil and synthetic ester waxes.
Mild abrasives which do not scratch the surface are also used in order to obtain improved cleaning characteristics. These abrasives are utilized in a range of about from 5 to 15% by Weight. Some particular abrasives that can be used are diatomaceous earth, amorphous silica, tripoli and chalk.
An emulsifying agent of the bodying type is employed in order to obtain stable emulsions of the wax in water. These emulsifying agents are used in a range of about from 0.2 to 4% by weight. It is to be understood that the term emulsifying agents of the budying type" connotes the following type substances: gum tragacanth, gum arabic. bentonite, locust bean gum, starch, albumen, karaya gum, Irish moss, water-colloidable methyl cellulose, and the like.
Organic solvents are employed in order to dissolve the wax before dispersion of the latter in the water. These solvents are used in a range of about from 3 to 25% by weight. Typical solvents are illustrated by turpentine, kerosene, Stoddard solvent. naphtha and spindle oil.
Water soluble wetting agents are employed in an amount of less than 1%. These wetting agents contribute to the ready spreading of the polish on the polished surface. Among the water soluble wetting agents that can be used are the sulfates of long chain alcohols such as dodecanol up to octadecanol, sulfonated amide and ester derivatives, sulfonated aromatic and mixed alkylaryl sulfonate derivatives. esters of fatty acids such as the ricinoleic acid ester of sorbitol, and
the wax is gently heated to its melting point and the solvent is added while the mixture is kept warm above the melting point of the wax. An emulsifying agent of the bodying type is added. The silicone oil is then also added. The mixture is stirred until smooth and free from lumps. The aqueous phase is formed by adding the water soluble ingredients such as the wetting agent to hot water, e. g., F. The oil phase is then added slowly to the aqueous phase with continued stirring to effect emulsification. The abrasive is then added with stirring. Coloring matter and odorants are next dispersed in the mixture.
Typical formulations are illustrated in the following examples.
Example No. 1
Per cent by weight Petroleum sulfonate 0.33 Water 74.17 Silicone oil 3.00 Bentonite 1.50 Diatomaceous earth 9.00 Carnauba wax 2.00 Kerosene 10.00
Example No. 2
Per cent by weight Water, tap 76.17 Petroleum sulfonate 0.33 Silicone oil emulsion 5.00 Bentonite 1.50 Diatomaceous earth 10.00 Carnauba wax 2.00 Kerosene 5.00
Example No. 3
Per cent by weight Glycerine 2.00 Diatomaceous earth 10.00 Bentonite 1.50 Spindle oil 6.00 Silicone oil 0.10 Petroleum sulfonate 0.33 Water 77.07 Paraiiin Wax 1 1.50 Candelilla Wax 1.50
The polishing compositions described above are generally useful for imparting a high luster to all kinds of smooth, painted metal surfaces. They are principally useful for polishing automobile bodies finished with various types of coating compositions, including pigmented nitrocellulose lacquers, enamels containing either natural or synthetic resin vehicles, or combinations thereof, asphaltic varnishes and pigmented derivatives thereof, etc. Its use is not confined to automobiles, however; it may be used wherever it is desired to impart a high luster to paint applied over smooth metal surfaces. Thus, it finds wide application in the field of furniture and building partitions, particularly those made of metal; for burial caskets, painted household heating stoves, refrigerators, and for many objects having similar surfaces. The composition is applied to the surface to be polished after most of the dirt and grit has been removed. After it has been allowed to dry, it is wiped off and polished with a clean dry cloth.
It is to be understood that the invention is not limited to the specific examples which have been offered merely as illustrations, and that modifications may be made without departing from the spirit of the invention.
What is claimed is:
1. An emulsion polishing composition of the oil in water type consisting essentially of a straight chain polydimethyl siloxane having a viscosity of no more than 500 centistokes at 25 C. in an amount of from about 0.001 to by weight, a wax in an amount of about from 1 to 5% by weight, an abrasive in an amount of about 5 to 15% by weight, an emulsifying agent of the bodying type in an amount of about from 0.2 to 4% by weight, a hydrocarbon solvent for the wax in an amount of about from 3 to 25% by weight, a water soluble wetting agent selected from the group consisting of synthetic non-ionic and anionic wetting agents in an amount of less'than 1% by weight and the balance water.
2. A polishing composition having approximately the following weight percent composition:
Percent by weight Glycerine 2.00 Diatomaceous earth -1 10.00 Bentonite g 1.50 Spindle oil 6.00 Silicone oil 0.10 Petroleum sulfonate 0.33 Water 77.07 Paraffin wax 1.50 Candelilla wax 1.50
HENRY H. COOKE. DOMINICK RUSSO.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,392,805 Biefeld Jan. 15, 1946 2,406,671 Diamond Aug. 27, 1946 2,482,888 Walsh Sept. 27, 1949 2,523,281 Currie Sept. 26, 1950 OTHER REFERENCES Chemistry and Technology of Waxes Warth; Reinhold Pub. 00., N. Y., 1947, pp. 454 and 455.

Claims (1)

1. AN EMULSION POLISHING COMPOSITION OF THE OIL IN WATER TYPE CONSISTING ESSENTIALLY OF A STRAIGHT CHAIN POLYDIMETHYL SILOXANE HAVING A VISCOSITY OF NO MORE THAN 500 CENTISTOKES AT 25* C. IN AN AMOUNT OF FROM ABOUT 0.001 TO 5% BY WEIGHT, A WAX IN AN AMOUNT OF ABOUT FROM 1 TO 5% BY WEIGHT, AN ABRASIVE IN AN AMOUNT OF ABOUT 5 TO 15% BY WEIGHT, AN EMULSIFYING AGENT OF THE BODYING TYPE IN AN AMOUNT OF ABOUT FROM 0.2 TO 4% BY WEIGHT, A HYDROCARBON SOLVENT FOR THE WAX IN AN AMOUNT OF ABOUT FROM 3 TO 25% BY WEIGHT, A WATER SOLUBLE WETTING AGENT SELECTED FROM THE GROUP CONSISTING OF SYNTHETIC NON-IONIC AND ANIONIC WETTING AGENTS IN AN AMOUNT OF LESS THAN 1% BY WEIGHT AND THE BALANCE WATER.
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Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2676893A (en) * 1951-04-21 1954-04-27 Johnson & Son Inc S C Wood-coating composition
US2681859A (en) * 1954-06-22 Liquid polishing composition
US2698805A (en) * 1950-09-29 1955-01-04 Dow Corning Polishing composition
US2702276A (en) * 1951-04-10 1955-02-15 Du Pont Water-dispersible emulsions of polysiloxanes
US2738282A (en) * 1951-11-05 1956-03-13 Hamilton Edgar Kingdon Polishing composition
US2777772A (en) * 1953-06-22 1957-01-15 Ca Nat Research Council Composition for maintaining clear vision in windshields
US2799599A (en) * 1957-07-16 Lustered fur hairs and method for
US2807557A (en) * 1951-04-16 1957-09-24 Clifford R Carney Method of treating furs
US2807554A (en) * 1953-08-06 1957-09-24 Rhone Poulenc Sa Coating compositions containing a wax and a methyl polysiloxane
US2827387A (en) * 1953-02-25 1958-03-18 Socony Mobil Oil Co Inc Stabilized paraffin wax
US2849324A (en) * 1956-11-19 1958-08-26 Simoniz Co Polishing composition
DE1046225B (en) * 1953-08-06 1958-12-11 Rhone Poulenc Sa Care products for wood, leather and paintwork
US2956888A (en) * 1959-01-20 1960-10-18 Union Carbide Corp Chrome protector
US2978422A (en) * 1959-02-19 1961-04-04 Simoniz Co Pressurized polishing composition containing polyvinyl-alcohol and gum tragacanth
US3021294A (en) * 1958-05-26 1962-02-13 Fuld Brothers Inc Floor polish compositions
US3088158A (en) * 1961-03-28 1963-05-07 Union Carbide Corp Cleaning and polishing sponge
DE1169062B (en) * 1959-09-22 1964-04-30 Chem Fab Kossack A G Surface protection of floor coverings made of linoleum, rubber, plastics or the like.
DE1188234B (en) * 1960-03-29 1965-03-04 Dehydag Gmbh Cleaning agent for smooth glass and ceramic surfaces
US3392040A (en) * 1954-09-03 1968-07-09 Bishop Ind Inc Silicone compositions
US3395028A (en) * 1966-09-12 1968-07-30 Drackett Co Wax composition and method for making the same
US3442676A (en) * 1965-12-29 1969-05-06 Fmc Corp Method of preparing a stable wax dispersion using beta-1,4 glucan
US3518099A (en) * 1969-01-21 1970-06-30 Edward Holbus Protective coating for metal surfaces
US3527723A (en) * 1968-03-06 1970-09-08 Park Chem Co Preservative and dressing coating for automobile vinyl tops and the like
US3775147A (en) * 1971-12-30 1973-11-27 Chevron Res White mulch composition
DE2300245A1 (en) * 1973-01-04 1974-07-18 Bayer Ag SURFACE CARE PRODUCTS BASED ON ORGANOPOLYSILOXANES AND WAX
US20030075077A1 (en) * 2001-09-10 2003-04-24 Lewis Glenn H. Water wax emulsion cleaner and waxer
US20040110850A1 (en) * 2002-12-09 2004-06-10 Jordan Elsie A. Wax composition and method of applying same to a wet surface
US20060144003A1 (en) * 2004-12-21 2006-07-06 Cocina Joseph Jr Use of siloxane to recondition siding
US11261347B2 (en) 2017-10-11 2022-03-01 Carroll Benford Dickens Water in oil emulsion automotive wax product

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2392805A (en) * 1943-10-11 1946-01-15 Owens Corning Fiberglass Corp Glass fiber strand
US2406671A (en) * 1944-09-25 1946-08-27 Shell Dev Cutting oil
US2482888A (en) * 1946-06-21 1949-09-27 Du Pont Organic silicon compounds for dewebbing elastomer latices
US2523281A (en) * 1950-09-26 automobile polish

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2523281A (en) * 1950-09-26 automobile polish
US2392805A (en) * 1943-10-11 1946-01-15 Owens Corning Fiberglass Corp Glass fiber strand
US2406671A (en) * 1944-09-25 1946-08-27 Shell Dev Cutting oil
US2482888A (en) * 1946-06-21 1949-09-27 Du Pont Organic silicon compounds for dewebbing elastomer latices

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2681859A (en) * 1954-06-22 Liquid polishing composition
US2799599A (en) * 1957-07-16 Lustered fur hairs and method for
US2698805A (en) * 1950-09-29 1955-01-04 Dow Corning Polishing composition
US2702276A (en) * 1951-04-10 1955-02-15 Du Pont Water-dispersible emulsions of polysiloxanes
US2807557A (en) * 1951-04-16 1957-09-24 Clifford R Carney Method of treating furs
US2676893A (en) * 1951-04-21 1954-04-27 Johnson & Son Inc S C Wood-coating composition
US2738282A (en) * 1951-11-05 1956-03-13 Hamilton Edgar Kingdon Polishing composition
US2827387A (en) * 1953-02-25 1958-03-18 Socony Mobil Oil Co Inc Stabilized paraffin wax
US2777772A (en) * 1953-06-22 1957-01-15 Ca Nat Research Council Composition for maintaining clear vision in windshields
US2807554A (en) * 1953-08-06 1957-09-24 Rhone Poulenc Sa Coating compositions containing a wax and a methyl polysiloxane
DE1046225B (en) * 1953-08-06 1958-12-11 Rhone Poulenc Sa Care products for wood, leather and paintwork
US3392040A (en) * 1954-09-03 1968-07-09 Bishop Ind Inc Silicone compositions
US2849324A (en) * 1956-11-19 1958-08-26 Simoniz Co Polishing composition
US3021294A (en) * 1958-05-26 1962-02-13 Fuld Brothers Inc Floor polish compositions
US2956888A (en) * 1959-01-20 1960-10-18 Union Carbide Corp Chrome protector
US2978422A (en) * 1959-02-19 1961-04-04 Simoniz Co Pressurized polishing composition containing polyvinyl-alcohol and gum tragacanth
DE1169062B (en) * 1959-09-22 1964-04-30 Chem Fab Kossack A G Surface protection of floor coverings made of linoleum, rubber, plastics or the like.
DE1188234B (en) * 1960-03-29 1965-03-04 Dehydag Gmbh Cleaning agent for smooth glass and ceramic surfaces
US3088158A (en) * 1961-03-28 1963-05-07 Union Carbide Corp Cleaning and polishing sponge
US3442676A (en) * 1965-12-29 1969-05-06 Fmc Corp Method of preparing a stable wax dispersion using beta-1,4 glucan
US3395028A (en) * 1966-09-12 1968-07-30 Drackett Co Wax composition and method for making the same
US3527723A (en) * 1968-03-06 1970-09-08 Park Chem Co Preservative and dressing coating for automobile vinyl tops and the like
US3518099A (en) * 1969-01-21 1970-06-30 Edward Holbus Protective coating for metal surfaces
US3775147A (en) * 1971-12-30 1973-11-27 Chevron Res White mulch composition
DE2300245A1 (en) * 1973-01-04 1974-07-18 Bayer Ag SURFACE CARE PRODUCTS BASED ON ORGANOPOLYSILOXANES AND WAX
US3856533A (en) * 1973-01-04 1974-12-24 Bayer Ag Surface polishes based on organopolysiloxanes and wax
US20030075077A1 (en) * 2001-09-10 2003-04-24 Lewis Glenn H. Water wax emulsion cleaner and waxer
US6953500B2 (en) * 2001-09-10 2005-10-11 Lewis Glenn H Water wax emulsion cleaner and waxer
US20040110850A1 (en) * 2002-12-09 2004-06-10 Jordan Elsie A. Wax composition and method of applying same to a wet surface
US20060144003A1 (en) * 2004-12-21 2006-07-06 Cocina Joseph Jr Use of siloxane to recondition siding
WO2006069189A3 (en) * 2004-12-21 2009-04-23 Joseph Cocina Jr Use of siloxane to recondition siding
US11261347B2 (en) 2017-10-11 2022-03-01 Carroll Benford Dickens Water in oil emulsion automotive wax product

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