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US2613626A - Method of cold drawing sheet metal - Google Patents

Method of cold drawing sheet metal Download PDF

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Publication number
US2613626A
US2613626A US40001A US4000148A US2613626A US 2613626 A US2613626 A US 2613626A US 40001 A US40001 A US 40001A US 4000148 A US4000148 A US 4000148A US 2613626 A US2613626 A US 2613626A
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United States
Prior art keywords
sheets
per cent
approximately
dies
deep drawing
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Expired - Lifetime
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US40001A
Inventor
Jr Forrest Jerome Whitney
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Heintz Manufacturing Co
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Heintz Manufacturing Co
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Priority to US40001A priority Critical patent/US2613626A/en
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Publication of US2613626A publication Critical patent/US2613626A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82After-treatment
    • C23C22/83Chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/063Peroxides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
    • C10M2201/103Clays; Mica; Zeolites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/241Manufacturing joint-less pipes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/242Hot working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/246Iron or steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/247Stainless steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles

Definitions

  • This invention relates to a method of facilitating the drawing of metal sheets.
  • An object of the invention is to provide an improved method of cold working metal sheets which has the advantages of permitting faster operation of the metal working machinery, decreasing the number of imperfect articles made in the metal working process, and decreasing the number of delays occasioned by stoning the parts of the metal working machinery, such as dies and the like.
  • An example of the application of this invention is in the drawing of a metal tub by use of hard ened steel dies, the final product having a diameter of around 25 inches and a depth of about 24 inches, and formed from a circular fiat sheet of steeTTfor example of type AlSl Specification C1008) having a gauge of approximately .062.
  • the above bath is preferably used at a pH of 2.8 to 2.9, and at a temperature of 20 to. 25 C'., with an immersion time of 3 to 5 minutes.
  • the blanks After treatment in the bath, the blanks are rinsed in cold running water and dried.
  • the blanks after this treatment have a thin coating of zinc phosphate tightly adherent chemically to their surfaces.
  • the coated blanks are put through three drawing operations, before each of which drawing operations the blanks are dipped or coated by swabbing, with a lubricant.
  • Various types of lubricants are used, and among the most desirable are the following:
  • the two lubricants just described are used to adjust the lubricating conditions, the non-pigmerited lubricant being used for adjusting the conditions of the first draw, while the pigmented type disclosed can be used only for the second and third drawing operations, sinc it is too slippery for the first draw and would permit the blank to slide between the blank holders without getting a sufficient cup formed for the subsequent operation.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Metal Extraction Processes (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Description

Patented Oct. 14, 1952 METHOD OF GOLD DRAWING SHEET METAL Forrest Jerome Whitney, Jr., Wayne, Pa., assignor to Heintz Manufacturing Company, Philadelphia, Pa., a, corporation of Pennsylvania No Drawing. Application July 21, 1948, Serial No. 40,001
2 Claims. 1
This invention relates to a method of facilitating the drawing of metal sheets.
An object of the invention is to provide an improved method of cold working metal sheets which has the advantages of permitting faster operation of the metal working machinery, decreasing the number of imperfect articles made in the metal working process, and decreasing the number of delays occasioned by stoning the parts of the metal working machinery, such as dies and the like.
An example of the application of this invention is in the drawing of a metal tub by use of hard ened steel dies, the final product having a diameter of around 25 inches and a depth of about 24 inches, and formed from a circular fiat sheet of steeTTfor example of type AlSl Specification C1008) having a gauge of approximately .062.
Before putting the steel sheets through the drawing operations, a quantity of sheets to be coated are first washed in an alkaline bath to accomplish degreasing, after which they are rinsed in cold running water. The blanks are thereafter immersed in a bath having the following chemical composition:
Grams per liter Zinc 11.0 P205 9 to 9.5 N03 18 NazO 1.5 Ni 0.1 Cu 0.03 NaNOa 1 to 1 5 The above bath is preferably used at a pH of 2.8 to 2.9, and at a temperature of 20 to. 25 C'., with an immersion time of 3 to 5 minutes.
After treatment in the bath, the blanks are rinsed in cold running water and dried. The blanks after this treatment have a thin coating of zinc phosphate tightly adherent chemically to their surfaces.
After the phosphate coating operation, the coated blanks are put through three drawing operations, before each of which drawing operations the blanks are dipped or coated by swabbing, with a lubricant. Various types of lubricants are used, and among the most desirable are the following:
1. 1% sodium soap-99% water.
2. 2% sulphonated tallow98% water, with enough sodium hydroxide to produce a pH value of 8.
and the other of which is non-pigmented, the
two compositions following being used to adjust the lubricating conditions by addition to whichever of the three above-listed lubricants is being used.
Non-pigmented 24% animal fatty acid (lard, oil, or degras) 24% vegetable fatty acid (soy bean fatty acid) 6% solid alkali (NaOI-I) 10% chlorinated Wax Balance water.
Pigmented 24% animal fatty acid (lard, oil, or degras) 24% vegetable fatty acid (soy bean fatty acid) 6% solid alkali (NaOI-I) 10% chlorinated wax 20% pigment (talc, or inert clay) Balance water.
The two lubricants just described are used to adjust the lubricating conditions, the non-pigmerited lubricant being used for adjusting the conditions of the first draw, while the pigmented type disclosed can be used only for the second and third drawing operations, sinc it is too slippery for the first draw and would permit the blank to slide between the blank holders without getting a sufficient cup formed for the subsequent operation.
In one test operation of the type just described, 80 of the coated blanks were run through the dies, and only one of the 80 showed any evidences of pick-up by the dies, and friction was reduced as much as An astonishing and unexpected result followed the processing of the phosphate coated blanks, in that the processing of the 80 blanks was followed with drawing of an additional 70 uncoated blanks, and only one additional metal score from pick-up was observed in the 70 additional blanks, showing that the beneficial resultsvwere carried over (apparently by the dies). The results from the processing of the uncoated blanks are made all the more unusual when it is considered that in the ordinary stamping of the uncoated blanks using the same lubricants, but without previously processing a series of coated blanks, pickup occurred as frequently as every third or fourth draw, and caused bad scoring of the stampings. It was also necessary to stone the dies frequently under the previous practice because of the metal which the dies picked up from the blanks.
By using the new method and first running a series of coated blanks followed by a series of uncoated blanks, it is obvious that considerable savings in the use of the coating solution will be provided.
I claim:
1. In the cold deep drawing of steel sheets by means of dies, the steps of providing a thin chemically adherent coating of zinc phosphate on .a quantity of said sheets, applying to said quantity of sheets, a non-pigmented lubricant containing a high fatty acid radical which chemically reacts with said coating, cold deep drawing said quantity of sheets by the use of dies whereby there is transferred from said sheets to said dies as the deep drawing is effected material which includes at least some of the phosphate coating material and some of the product of said reaction, applying to a smaller quantity of uncoated steel sheets a non-pigmented lubricant of the same type as applied to the coated sheets, and cold deep drawing said second smaller quantity of sheets by the use of the same dies, the lubricants being selected from the group consisting of approximately one per cent sodium soap ninety-nine per cent water; approximately two per cent sulphonated tallow-ninety-eight per cent water, the pH of the lubricant being ap-, proximately 8; approximately one per cent chlorinated paraffin, forming an emulsion with approximately two per cent sodium soap, using approximately ninety-seven per cent water.
2. A process as defined in claim 1, the number of coated blanks being in the order of 80, and the number of uncoated blanks being in the order of 70.
FORREST JEROME WHITNEY, JR.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Name Date Mill Aug. 10, 1943 OTHER REFERENCES Number

Claims (1)

1. IN THE COLD DEEP DRAWING OF STEL SHEETS BY MEANS OF DIES, THE STEPS OF PROVIDING A THIN CHEMICALLY ADHERENT COATING OF ZINC PHOSPHATE ON A QUANTITY OF SAID SHEETS, APPLYING TO SAID QUANTITY OF SHEETS, A NON-PIGMENTED LUBRICANT CONTAINING A HIGH FATTY ACID RADICAL WHICH CHEMICALLY REACTS WITH SAID COATING, COLD DEEP DRAWING SAID QUANTITY OF SHEETS BY THE USE OF DIES WHEREBY THERE IS TRANSFERRED FROM SAID SHEETS TO SAID DIES AS THE DEEP DRAWING IS EFFECTED MATERIAL WHICH INCLUDES AT LEAST SOME OF THE PHOSPHATE COATING MATERIAL AND SOME OF THE PRODUCT OF SAID REACTION, APPLYING TO A SMALLER QUANTITY OF UNCOATED STEEL SHEETS A NON-PIGMENTED LUBRICANT OF THE SAME TYPE AS APPLIED TO THE COATED SHEETS, AND COLD DEEP DRAWING SAID SECOND SMALLER QUANTITY OF SHEETS BY THE USE OF THE SAME DIES, THE LUBRICANTS BEING SELECTED FROM THE GROUP CONSISTING OF APPROXIMATELY ONE PER CENT SODIUM SOAPNINETY-NINE PER CENT WATER; APPROXIMATELY TWO PER CENT SULPHONATED TALLOW-NINETY-EIGHT PER CENT WATER, THE PH OF THE LUBRICANT BEING APPROXIMATELY 8; APPROXIMATELY ONE PER CENT CHLORINATED PARAFFIN, FORMING AN EMULSION WITH APPROXIMATELY TWO PER CENT SODIUM SOAP USING APPROXIMATELY NINETY-SEVEN PER CENT WATER.
US40001A 1948-07-21 1948-07-21 Method of cold drawing sheet metal Expired - Lifetime US2613626A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2739128A (en) * 1951-05-23 1956-03-20 Nicholas M Adams Film forming compositions
US2776255A (en) * 1955-07-07 1957-01-01 Rockwell Spring & Axle Co Method of making formed, plated articles
US2831782A (en) * 1954-05-21 1958-04-22 Dow Chemical Co Lubricants for coating and working light metals
US2849107A (en) * 1954-01-26 1958-08-26 Parker Rust Proof Co Lubricant for spraying on chemically coated metal surfaces
US3098294A (en) * 1960-11-30 1963-07-23 Arthur M Shapiro Lubricant for metal forming process
US3105400A (en) * 1954-05-10 1963-10-01 Aluminum Co Of America Rolling of aluminous metal foil
US4752405A (en) * 1986-05-01 1988-06-21 Coral Chemical Company Metal working lubricant

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2326387A (en) * 1940-07-31 1943-08-10 Montgomery H A Co Drawing composition and method of making the same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2326387A (en) * 1940-07-31 1943-08-10 Montgomery H A Co Drawing composition and method of making the same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2739128A (en) * 1951-05-23 1956-03-20 Nicholas M Adams Film forming compositions
US2849107A (en) * 1954-01-26 1958-08-26 Parker Rust Proof Co Lubricant for spraying on chemically coated metal surfaces
US3105400A (en) * 1954-05-10 1963-10-01 Aluminum Co Of America Rolling of aluminous metal foil
US2831782A (en) * 1954-05-21 1958-04-22 Dow Chemical Co Lubricants for coating and working light metals
US2776255A (en) * 1955-07-07 1957-01-01 Rockwell Spring & Axle Co Method of making formed, plated articles
US3098294A (en) * 1960-11-30 1963-07-23 Arthur M Shapiro Lubricant for metal forming process
US4752405A (en) * 1986-05-01 1988-06-21 Coral Chemical Company Metal working lubricant

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