US2651608A - Electrodeposition of aluminum from nonaqueous solutions - Google Patents
Electrodeposition of aluminum from nonaqueous solutions Download PDFInfo
- Publication number
- US2651608A US2651608A US268325A US26832552A US2651608A US 2651608 A US2651608 A US 2651608A US 268325 A US268325 A US 268325A US 26832552 A US26832552 A US 26832552A US 2651608 A US2651608 A US 2651608A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- hydride
- ether
- ethyl
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229910052782 aluminium Inorganic materials 0.000 title claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 14
- 238000004070 electrodeposition Methods 0.000 title description 7
- 239000012457 nonaqueous media Substances 0.000 title description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- -1 LITHIUM ALUMINUM HYDRIDE Chemical compound 0.000 claims description 7
- 125000001495 ethyl group Chemical class [H]C([H])([H])C([H])([H])* 0.000 claims description 7
- 229910000103 lithium hydride Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000012280 lithium aluminium hydride Substances 0.000 claims description 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 5
- 229910052987 metal hydride Inorganic materials 0.000 claims description 5
- 150000004681 metal hydrides Chemical class 0.000 claims description 5
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims description 5
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 claims description 5
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 4
- 238000009713 electroplating Methods 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 claims 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 12
- 238000007747 plating Methods 0.000 description 12
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 7
- 238000007792 addition Methods 0.000 description 6
- ZNSMNVMLTJELDZ-UHFFFAOYSA-N Bis(2-chloroethyl)ether Chemical compound ClCCOCCCl ZNSMNVMLTJELDZ-UHFFFAOYSA-N 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 150000004678 hydrides Chemical class 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- PZHIWRCQKBBTOW-UHFFFAOYSA-N 1-ethoxybutane Chemical compound CCCCOCC PZHIWRCQKBBTOW-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000001427 coherent effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000009499 grossing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 125000006003 dichloroethyl group Chemical group 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/42—Electroplating: Baths therefor from solutions of light metals
- C25D3/44—Aluminium
Definitions
- This invention relates to the electrodeposition of aluminum from nonaqueous solutions, and in particular to a hydride type aluminum plating bath.
- Another object of the invention is to develop a bath that is simply controlled.
- Another object of the invention is to provide a bath for the electrodeposition of aluminum that is stable over long periods of time.
- Another object is to develop a bath that requires infrequent filtration.
- Another object is to develop a bath for the electrodeposition of aluminum thathas deposition rates of at least 0.001 inch per hour. 7
- the bath consists of an ethereal solution of anhydrous aluminum chloride and a metallic hydride.
- concentration of aluminum chloride can be varied from 1 to 4 molar, but optimum results are obtained with a 2 to 3 molar solution.
- a number of difierent ethers were tried as the solvent but the best results were obtained when ethyl ether was used.
- Table 1 (gm-rent R 1 i ensity e at ve Ether Used for best rating Type of Deposit deposit Anisole (methyl 0.6 good White, ductile, smooth.
- Phenyl Ethyl N-Butyl 0.54.0 do Gray, brittle, coherent. D1-Phenyl 0.5 do White, ductile, smooth.
- the bath as described above has several dis-' tinct advantages.
- the plating solution is stable over long periods of time if moisture is excluded. A sample of the plating bath which had been hermetically sealed for eight months yielded deposits as good as those from a freshly prepared bath.
- a process of electroplating that comprises tained. electrodepositing aluminum from a bath consist- Table 2 Current Den- Tim f Tune sity, ampjldmJ Time Efiective Ratio Plating Typeoi 32 8 R 1. R Iflate] Curl/231111;, Deposit eeeverse amp. Plate verse Plate verse 23 20 3 3 10 7 ll: Smooth matt. 4a 40 s 3 12 7 1. a Very smooth. s4 so 4 s 12 20 2.4 Do. 168 160 s a 12 20 2.4 Do.
- BB dichloroethyl ether has been found to be the only one to have a marked effect upon the deposit.
- the addition of a sufiicient amount of BB dichloroethyl ether to constitute 4 to 8 percent by volume of the bath caused considerable smoothing and greatly increased the Vickers hardness.
- the Vickers hardness obtained depended upon the plating procedures used; that is, whether or not periodic reverse currents were used or BB When neither was used the Vickers hardness ranged from 37 to 47 depending upon the current density employed. These deposits were very ductile. When periodic reverse currents were used with an effective platingcurrent of 2 amperes per dm. the Vickers hardness was 67 and the deposits were slightly less ductile.
- BB dichloroethyl ether was added the Vickers hardness was 97 and the deposits were brittle.
- the deposits obtained besides being white and very smooth showed no appreciable amounts of lithium when lithium hydride or lithium aluminum hydride was used in the bath.
- the deposits ranged in thickness up to 0.75 mm. or approximately 0.03 inch, which is considered to be a. very thick plate.
- the time required for plating is comparatively short; the deposition rate being 0.025 mm. per hour. Deposition rates as high as 0.05 mm. per hour are practical when a thinner plate is desired.
- a process of electroplating that comprises electrodepositing aluminum from a bath consisting of a mixture of an ether selected from the group consisting of ethyl ether, ethyl n-butyl ether, a mixture of ethyl and butyl ethers, anisole, phenetole, and di-phenyl ether; a metal hydride at 0.5 to 1 molar selected from the group ing of a mixture of an ether selected from the group consisting of ethyl ether, ethyl n-butyl ether, a mixture of ethyl and butyl ethers, anisole, phenetole, and di-phenyl ether; a metal hydride at 0.5 to 1 molar selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride; and anhydrous aluminum chloride at from 1 to 4 molar, and at current densities of from 0.5 to 5 amperes per d
- a non-aqueous bath for use in the electrodeposition of aluminum comprising an ether selected from the group consisting of a mixture of ethyl and butyl ether, anisole, phenetole, ethyl n-butyl ether, di-phenyl ether and ethyl ether; 2. metal hydride at 0.5 to 1 molar selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride; and
- anhydrous aluminum chloride at from 1 to 4 molar.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Description
Patented Sept. 8, 1953 ELECTRODEPOSITION F ALUMINUMIFROM NONAQUEOUS SOLUTIONS Abner Brenner, Chev y Chase, Md., and Dwight E. Couch, Washington, D. 0., assignors to the United States of America as represented by the Secretary of Commerce N 0 Drawing. Application January 25, 1952, Serial No. 268,325
6 Claims. (01. 204-14) (Granted under Title 35, U. S. Code-(1952),
sec. 266) The invention described herein may be manufactured and used by or for the Government of the United States for governmental purposes Without the payment to us of any royalty thereon in accordance with the provisions of the act of March 3, 1883, as amended (45 Stat. 467; 35 U. S. C. 45).
This invention relates to the electrodeposition of aluminum from nonaqueous solutions, and in particular to a hydride type aluminum plating bath.
Several different types of baths for electroplating aluminum have been developed in the past. However, it has not been possible up to the present, to build up plates of more than 0.002 inch thickness without the plates becoming nodular or treed. Studies of additions to these baths have not as yet produced any appreciable improvement. These prior art methods probably all worked on the same basic theory; aluminum halide reacts with another halide which may be a quaternary ammonium salt or an alkali salt to form a complex salt RalCl'i. This salt probably ionizes to form AlClr ions which are discharged at the cathode as aluminum. Besides the disadvantage of not being able to build up very thick deposits, these prior art methods have the added disadvantage of requiring very critical control.
It is the primary object of the present invention to develop a method for the electrodeposition of aluminum that will produce relatively thick and smooth deposits of aluminum.
Another object of the invention is to develop a bath that is simply controlled.
Another object of the invention is to provide a bath for the electrodeposition of aluminum that is stable over long periods of time.
Another object is to develop a bath that requires infrequent filtration.
Another object is to develop a bath for the electrodeposition of aluminum thathas deposition rates of at least 0.001 inch per hour. 7
According to the present invention the bath consists of an ethereal solution of anhydrous aluminum chloride and a metallic hydride. The concentration of aluminum chloride can be varied from 1 to 4 molar, but optimum results are obtained with a 2 to 3 molar solution. A number of difierent ethers were tried as the solvent but the best results were obtained when ethyl ether was used.
Good deposits were obtained, however, when several other ethers were employed. The results obtained with the different ethers are compared in Table 1. e
Table 1 (gm-rent R 1 i ensity e at ve Ether Used for best rating Type of Deposit deposit Anisole (methyl 0.6 good White, ductile, smooth.
phenyl Ethyl (d1ethyl) 0.5-5.0 excellent" White, ductile, smooth,
coherent. Phenetole(Etl1yl- 0.5 good Do.
Phenyl). Ethyl N-Butyl 0.54.0 do Gray, brittle, coherent. D1-Phenyl 0.5 do White, ductile, smooth.
In addition to the ethers listed in the table a mixture of ethyl and butyl ether gave satisfactory deposits. The ethyl ether was necessary to give the desired solubility of the lithium hydride.
The allowable current densities were rather low for all except ethyl ether. However, even though the range for'ethyl ether is from 0.5 to 5 amperes per dmfi, optimum results were obtained with densities of approximately 2 amperes per dmfi. At this current density, deposit rates offrom 0.025 mm. to 0.05 mm. per hour were obtained. Aluminum anodes are used and dissolve in the bath at about percent 'efiiciency. Several metal hydrides were used but lithium hydride at concentrations of from 0.5 to 1 molar give the best results. Lithium aluminum hydride gave equally good results, but the hydride contained insoluble fractions which have to be filtered out before use. Freshly prepared aluminum hydride also gave good results, but after standing for some time it was found to be insoluble when added to the bath.
The bath as described above has several dis-' tinct advantages. One is that the plating solution does not require frequent filtration, since the impurities from the aluminum chloride and the small amount of anode slime developed settle to the bottom of the vessel and usually do not affect the depositions. If small amounts of moisture enter the bath it is easily rejuvenated by the addition of the desired metallic hydride. Secondly the plating solution is stable over long periods of time if moisture is excluded. A sample of the plating bath which had been hermetically sealed for eight months yielded deposits as good as those from a freshly prepared bath.
In efforts to improve the deposits obtained by the original solution, periodic reverse currents were applied during the entire plating operation. This produced considerable smoothing of the deposits, A higher current for a short period of time is passed during the anodic cycle, but the ampere minutes are less than in the cathodic cycle. Table No. 2 shows the relation between the plate and reverse currents for several different plating operations and shows the results ob;
4 consisting of lithium hydride, lithium aluminum hydride and aluminum hydride; and anhydrous aluminum chloride at from 1 to 4 molar.
2. A process of electroplating that comprises tained. electrodepositing aluminum from a bath consist- Table 2 Current Den- Tim f Tune sity, ampjldmJ Time Efiective Ratio Plating Typeoi 32 8 R 1. R Iflate] Curl/231111;, Deposit eeeverse amp. Plate verse Plate verse 23 20 3 3 10 7 ll: Smooth matt. 4a 40 s 3 12 7 1. a Very smooth. s4 so 4 s 12 20 2.4 Do. 168 160 s a 12 20 2.4 Do.
Several addition agents have been tested but BB dichloroethyl ether has been found to be the only one to have a marked effect upon the deposit. The addition of a sufiicient amount of BB dichloroethyl ether to constitute 4 to 8 percent by volume of the bath caused considerable smoothing and greatly increased the Vickers hardness. The Vickers hardness obtained depended upon the plating procedures used; that is, whether or not periodic reverse currents were used or BB When neither was used the Vickers hardness ranged from 37 to 47 depending upon the current density employed. These deposits were very ductile. When periodic reverse currents were used with an effective platingcurrent of 2 amperes per dm. the Vickers hardness was 67 and the deposits were slightly less ductile. When BB dichloroethyl ether was added the Vickers hardness was 97 and the deposits were brittle.
dichloroethyl ether was added. Y
The deposits obtained besides being white and very smooth showed no appreciable amounts of lithium when lithium hydride or lithium aluminum hydride was used in the bath. The deposits ranged in thickness up to 0.75 mm. or approximately 0.03 inch, which is considered to be a. very thick plate. The time required for plating is comparatively short; the deposition rate being 0.025 mm. per hour. Deposition rates as high as 0.05 mm. per hour are practical when a thinner plate is desired.
It will be apparent that the embodiments shown are only exemplary and that various modifications can be made in construction and arrangement within the scope of our invention as defined in the appended claims.
We claim:
1. A process of electroplating that comprises electrodepositing aluminum from a bath consisting of a mixture of an ether selected from the group consisting of ethyl ether, ethyl n-butyl ether, a mixture of ethyl and butyl ethers, anisole, phenetole, and di-phenyl ether; a metal hydride at 0.5 to 1 molar selected from the group ing of a mixture of an ether selected from the group consisting of ethyl ether, ethyl n-butyl ether, a mixture of ethyl and butyl ethers, anisole, phenetole, and di-phenyl ether; a metal hydride at 0.5 to 1 molar selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride; and anhydrous aluminum chloride at from 1 to 4 molar, and at current densities of from 0.5 to 5 amperes per dmfi.
3. The invention according to claim 2 in which BB dichloroethyl ether is used as an addition agent to improve the smoothness and hardness of the plating.
4. The invention according to claim 1 in which periodic reverse currents are applied across the bath, the effective plating current being from 1 to 3 amperes per dmf 5. A non-aqueous bath for use in the electrodeposition of aluminum comprising an ether selected from the group consisting of a mixture of ethyl and butyl ether, anisole, phenetole, ethyl n-butyl ether, di-phenyl ether and ethyl ether; 2. metal hydride at 0.5 to 1 molar selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride; and
anhydrous aluminum chloride at from 1 to 4 molar.
6. The invention according to claim 5 in which BB dichloroethyl other is used as an addition agent to improve the smoothness and hardness of the plating.
ABNER BRENNER. DWIGHT E. COUCH.
References Cited in the file of this patent FOREIGN PATENTS Number Country Date 496,972 Germany Apr. 30, 1930 694,738 Germany Aug. 8, 1940 OTHER REFERENCES Studies in the Electrodeposition of Metals, by Keyes et al., University of Illinois 13111., May 20, 1930, pages 5-10.
Claims (1)
1. A PROCESS OF ELECTROPLATING THAT COMPRISES ELECTRODEPOSITING ALUMINUM FROM A BATH CONSISTING OF A MIXTURE OF AN ETHER SELECTED FROM THE GROUP CONSISTING OF ETHYL ETHER, ETHYL N-BUTYL EHERE, A MIXTURE OF ETHYL AND BUTLY ETHERS, ANISOLE, PHENETOLE, AND DI-PHENYL ETHER; A METAL HYDRIDE AT 0.5 TO 1 MOLAR SELECTED FROM THE GROUP CONSISTING OF LITHIUM HYDRIDE, LITHIUM ALUMINUM HYDRIDE AND ALUMINUM HYDRIDE; AND ANHYDROUS ALUMIUNUM CHLORIDE AT FROM 1 TO 4 MOLAR.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US268325A US2651608A (en) | 1952-01-25 | 1952-01-25 | Electrodeposition of aluminum from nonaqueous solutions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US268325A US2651608A (en) | 1952-01-25 | 1952-01-25 | Electrodeposition of aluminum from nonaqueous solutions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2651608A true US2651608A (en) | 1953-09-08 |
Family
ID=23022464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US268325A Expired - Lifetime US2651608A (en) | 1952-01-25 | 1952-01-25 | Electrodeposition of aluminum from nonaqueous solutions |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2651608A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2763605A (en) * | 1955-05-23 | 1956-09-18 | Aluminum Co Of America | Electrodepositing aluminum |
| US2934478A (en) * | 1954-10-19 | 1960-04-26 | William C Schickner | Process of electroplating metals with aluminum |
| US2952589A (en) * | 1956-04-09 | 1960-09-13 | Karl Ziegler | Purification of aluminum |
| US3268421A (en) * | 1961-12-04 | 1966-08-23 | Nat Steel Corp | Electrodeposition of metals from a fused bath of aluminum halohydride organic complex and composition therefor |
| US3355368A (en) * | 1962-12-13 | 1967-11-28 | Nat Steel Corp | Electrodeposition of metals |
| DE1771116B1 (en) * | 1967-04-07 | 1970-11-26 | Nisshin Steel Co Ltd | Galvanic bath for the deposition of aluminum |
| US3929611A (en) * | 1974-07-19 | 1975-12-30 | Ametek Inc | Electrodepositing of aluminum |
| US3997410A (en) * | 1974-02-06 | 1976-12-14 | Eliezer Gileadi | Electrodeposition of aluminum |
| US4145261A (en) * | 1977-02-25 | 1979-03-20 | U.S. Philips Corporation | Electrolyte-liquid for the electrodeposition of aluminum |
| US4222827A (en) * | 1978-05-22 | 1980-09-16 | U.S. Philips Corporation | Electroplating solution for the electrodeposition of aluminium |
| DE10134559A1 (en) * | 2001-07-16 | 2003-02-06 | Fraunhofer Ges Forschung | Coating e.g. metal or plastics component involves electrolytic coating using non-aqueous or aprotic dispersant containing aluminum and/or magnesium compound and disperse phase, then anodic oxidation |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE496972C (en) * | 1926-10-22 | 1930-04-30 | Degussa | Process for protecting metals against tarnishing |
| DE694738C (en) * | 1939-05-03 | 1940-08-08 | Dr Helmuth Scheibler | Process for the production of non-aqueous bath fluids for the electrolytic deposition of aluminum |
-
1952
- 1952-01-25 US US268325A patent/US2651608A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE496972C (en) * | 1926-10-22 | 1930-04-30 | Degussa | Process for protecting metals against tarnishing |
| DE694738C (en) * | 1939-05-03 | 1940-08-08 | Dr Helmuth Scheibler | Process for the production of non-aqueous bath fluids for the electrolytic deposition of aluminum |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2934478A (en) * | 1954-10-19 | 1960-04-26 | William C Schickner | Process of electroplating metals with aluminum |
| US2763605A (en) * | 1955-05-23 | 1956-09-18 | Aluminum Co Of America | Electrodepositing aluminum |
| US2952589A (en) * | 1956-04-09 | 1960-09-13 | Karl Ziegler | Purification of aluminum |
| US3268421A (en) * | 1961-12-04 | 1966-08-23 | Nat Steel Corp | Electrodeposition of metals from a fused bath of aluminum halohydride organic complex and composition therefor |
| US3355368A (en) * | 1962-12-13 | 1967-11-28 | Nat Steel Corp | Electrodeposition of metals |
| DE1771116B1 (en) * | 1967-04-07 | 1970-11-26 | Nisshin Steel Co Ltd | Galvanic bath for the deposition of aluminum |
| US3997410A (en) * | 1974-02-06 | 1976-12-14 | Eliezer Gileadi | Electrodeposition of aluminum |
| US3929611A (en) * | 1974-07-19 | 1975-12-30 | Ametek Inc | Electrodepositing of aluminum |
| US4145261A (en) * | 1977-02-25 | 1979-03-20 | U.S. Philips Corporation | Electrolyte-liquid for the electrodeposition of aluminum |
| US4222827A (en) * | 1978-05-22 | 1980-09-16 | U.S. Philips Corporation | Electroplating solution for the electrodeposition of aluminium |
| DE10134559A1 (en) * | 2001-07-16 | 2003-02-06 | Fraunhofer Ges Forschung | Coating e.g. metal or plastics component involves electrolytic coating using non-aqueous or aprotic dispersant containing aluminum and/or magnesium compound and disperse phase, then anodic oxidation |
| DE10134559B4 (en) * | 2001-07-16 | 2008-10-30 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Process for coating components, processable dispersible coatings and use |
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