US2568705A - Nonsputtering cathode for electron discharge devices - Google Patents
Nonsputtering cathode for electron discharge devices Download PDFInfo
- Publication number
- US2568705A US2568705A US122381A US12238149A US2568705A US 2568705 A US2568705 A US 2568705A US 122381 A US122381 A US 122381A US 12238149 A US12238149 A US 12238149A US 2568705 A US2568705 A US 2568705A
- Authority
- US
- United States
- Prior art keywords
- cathode
- discharge
- nonsputtering
- discharge devices
- electron discharge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 229910052703 rhodium Inorganic materials 0.000 description 5
- 239000010948 rhodium Substances 0.000 description 5
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- -1 but Chemical compound 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J17/00—Gas-filled discharge tubes with solid cathode
- H01J17/02—Details
- H01J17/04—Electrodes; Screens
- H01J17/06—Cathodes
- H01J17/066—Cold cathodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2893/00—Discharge tubes and lamps
- H01J2893/0064—Tubes with cold main electrodes (including cold cathodes)
- H01J2893/0065—Electrode systems
- H01J2893/0066—Construction, material, support, protection and temperature regulation of electrodes; Electrode cups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/1275—Next to Group VIII or IB metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12778—Alternative base metals from diverse categories
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
- Y10T428/12847—Cr-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12875—Platinum group metal-base component
Definitions
- the present invention relates to cold cathode electric discharge tubes and is particularly concerned with means for preventing sputtering of cathode material from the cathode of a discharge gap.
- cathode glow In electric discharge tubes, it is required in many applications that the cathode glow be confined to a specific area of the cathode. This is particularly important in sequence discharge tubes in which an array of discharge gaps is provided, it being arranged that due to ionisation coupling, discharge at one gap may prime the next succeeding gap in the array. In order to control the degree of ionisation coupling between gaps, it is necessary, in general, to limit discharge at any cathode to a specified current. This may readily be done by arranging that the discharge occurs in the region of abnormal glowwhen the whole of the available cathode surface is covered with glow.
- Fig. 1 shows an electric glow discharge tube in which the present invention may be embodied.
- Figs. 2 and 3 show diagrammatically cathode coating arrangements according to the invention.
- the tube envelope I encloses a plurality of cathode rod electrodes 2 mounted on .a conventional press 3.
- the cathode electrodes 2 are a close fit in corresponding apertures of a mica sheet I so that only the top of the cathode rods protrude therethrough to form the cathode discharge surfaces.
- a common anode 5 mounted on a further mica sheet 8 is connected to a top cap 'I.
- I provide a cathode having a surface which is hard and has large cohesive forces between molecules.
- the cathode at the same time having a good value of thermal conductivity to allow heat to be rapidly removed from the surface, whereby sputtering may be considerably reduced below that usual for metals such as" copper and nickel.
- I use copper as the base metal and coat it with rhodium.
- I provide a coating of hard, high current density chromium. In both cases the coating may have a thickness of .001 inch.
- a metal of good thermal conductivity I mean one-whose thermal conductivity is not less than 12% of that of silver.
- chromium I mean that produced by electroplating at a current density of from 300 to 1000 amperes per square foot.
- a flashing of rhodium between the underlying metal and the hard chromium as is indicated in Fig. 3.
- a flash coating of rhodium I mean one that is continuous but limited in thickness to the order of l0 inch.
- a gas filledcold cathode electric discharge tube comprising a discharge gap electrode formed from a metal of the group consisting 01' copper. aluminium and nickel and having a layer of rhodium whereby sputteringoi the underlying metal during glow discharge operation is .prevented.
- a gas filled cold cathode electric discharge tube comprising a discharge gap electrode formed the softer underlying metal during glow discharge operation is prevented.
Landscapes
- Discharge Lamp (AREA)
Description
A. H. w. BECK 2,568,705
NONSPUTTERING CATHODE FOR ELECTRON DISCHARGE DEVICES Sept. 25, 1951 Filed Oct 20, 1949 E B w .WWD w a- A 3 p m M G m A .1 F M A w k m MP M w t P m m M P 2 G F Patented Sept. 1951 NONSPU'ITEBING CATHODE FOB ELECTRON DISOHARGE DEVICES Arnold Hugh William Beck, London, England, minor to International Standard Elect-lo Corporation, New York, N. Y., a corporation 'of Delaware I Application October 20, 1949, Serial No. 122,381 In Great Britain November 4, 1948 2 Claims. 1
The present invention relates to cold cathode electric discharge tubes and is particularly concerned with means for preventing sputtering of cathode material from the cathode of a discharge gap.
In electric discharge tubes, it is required in many applications that the cathode glow be confined to a specific area of the cathode. This is particularly important in sequence discharge tubes in which an array of discharge gaps is provided, it being arranged that due to ionisation coupling, discharge at one gap may prime the next succeeding gap in the array. In order to control the degree of ionisation coupling between gaps, it is necessary, in general, to limit discharge at any cathode to a specified current. This may readily be done by arranging that the discharge occurs in the region of abnormal glowwhen the whole of the available cathode surface is covered with glow. To this end, earlier sequence discharge tubes have had their cathodes shaped in the form of rods coated with alumina leaving only the tips exposed to provide a discharge surface of limited area. This procedure, however, permitted only short life due to sputtering of the cathode material onto the alumina so that eventually the cathode glow spread beyond the desired limit.
Another form of construction has been proposed in which the cathode rods might be left uncoated, the discharge being prevented from spreading beyond the specified area by the provision of a field control plate of metal or of insulating material which surrounds the cathode at a distance less than that of the cathode fall vso preventing a discharge from spreading from one side of the plate to the other. This solution has proved very satisfactory from all points of view except ease of manufacture, for if the cathode touches the control plate or is badly off centre in the hole, the tube is either useless or may still have only a short life due to material being sputtered onto the dielectric where it touches the surface of the cathode. From a manufacturing point of view, it would be much easier to be able to assemble the cathode as a push-fit in a mica sheet which may act as a glow defining member while eliminating the difficulty of maintaining small but accurate clearances.
In the accompanying drawings,
Fig. 1 shows an electric glow discharge tube in which the present invention may be embodied.
Figs. 2 and 3 show diagrammatically cathode coating arrangements according to the invention.
In Fig. 1, the tube envelope I encloses a plurality of cathode rod electrodes 2 mounted on .a conventional press 3. The cathode electrodes 2 are a close fit in corresponding apertures of a mica sheet I so that only the top of the cathode rods protrude therethrough to form the cathode discharge surfaces. A common anode 5 mounted on a further mica sheet 8 is connected to a top cap 'I.
In the present invention I provide a cathode having a surface which is hard and has large cohesive forces between molecules. the cathode at the same time having a good value of thermal conductivity to allow heat to be rapidly removed from the surface, whereby sputtering may be considerably reduced below that usual for metals such as" copper and nickel.
In one embodiment of the invention, as illustrated in Fig. 2, I use copper as the base metal and coat it with rhodium. As an alternative to rhodium I provide a coating of hard, high current density chromium. In both cases the coating may have a thickness of .001 inch.
In the claims, by a metal of good thermal conductivity I mean one-whose thermal conductivity is not less than 12% of that of silver.
In practice, I prefer to use copper, but, aluminium is also suitable. Nickel may also be used but, with a conductivity 14% that of silver, this metal is very near the lower limit of what I consider to be practicable. By hard high current density chromium I mean that produced by electroplating at a current density of from 300 to 1000 amperes per square foot.
As an alternative to the single coating of chromium, in order to overcome porosity of the hard chromium and prevent diflfusion of the copper I prefer to interpose a flashing of rhodium between the underlying metal and the hard chromium as is indicated in Fig. 3. By a flash coating of rhodium I mean one that is continuous but limited in thickness to the order of l0 inch.
Tests show that in discharge tubes according to the invention, cathode life is increased by a factor of at least. four or live from what is obtained with pure nickel, i. e. a satisfactory life of from 800 to 1000 hours working under pulse conditions is now obtainable as compared with '200 hours for a nickel cathode coated with alumina. These figures apply to discharge tubes in which the cathode current density is of the order of one ampere per cm. and in which the maintaining voltage is a few hundred volts.
While the principles of the invention have been described above in connection with specific embodiments, and particular modifications thereof, it is to be clearly understood that this description is made only by way of example and not as a limitation on the scope of the invention.
What is claimed is: I
1. A gas filledcold cathode electric discharge tube comprising a discharge gap electrode formed from a metal of the group consisting 01' copper. aluminium and nickel and having a layer of rhodium whereby sputteringoi the underlying metal during glow discharge operation is .prevented.
2. A gas filled cold cathode electric discharge tube comprising a discharge gap electrode formed the softer underlying metal during glow discharge operation is prevented.
mom HUGH wnimm nmcx.
REFERENCES CITED The following references are 01 record in the file of this patent:
UNITED QTATES PATENTS Number, Name Date 1,834,251 Moore Dec. 1, 1931
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2568705X | 1948-11-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2568705A true US2568705A (en) | 1951-09-25 |
Family
ID=10910367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US122381A Expired - Lifetime US2568705A (en) | 1948-11-04 | 1949-10-20 | Nonsputtering cathode for electron discharge devices |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2568705A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE929626C (en) * | 1951-09-29 | 1955-06-30 | Int Standard Electric Corp | Electronic switching device with a multi-section cold cathode gas discharge tube |
| DE1007889B (en) * | 1951-10-26 | 1957-05-09 | Int Standard Electric Corp | Multi-section cold cathode gas discharge tubes with a number of pin cathodes, the active areas of which are limited by a barrier |
| US2876400A (en) * | 1953-02-27 | 1959-03-03 | Siemens Ag | Composite electrodes for directional crystal devices |
| US2925531A (en) * | 1958-07-22 | 1960-02-16 | Philips Corp | Cold-cathode stepping tubes |
| DE1090772B (en) * | 1955-10-05 | 1960-10-13 | Siemens Edison Swan Ltd | Gas-filled electrical counting and storage tubes with a screw-shaped cathode and an anode which is arranged parallel to the axis of the cathode screw |
| US3092749A (en) * | 1960-04-15 | 1963-06-04 | Gen Electric | Electron discharge device |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1834251A (en) * | 1930-09-02 | 1931-12-01 | Gen Electric | Electrical discharge device |
-
1949
- 1949-10-20 US US122381A patent/US2568705A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1834251A (en) * | 1930-09-02 | 1931-12-01 | Gen Electric | Electrical discharge device |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE929626C (en) * | 1951-09-29 | 1955-06-30 | Int Standard Electric Corp | Electronic switching device with a multi-section cold cathode gas discharge tube |
| DE1007889B (en) * | 1951-10-26 | 1957-05-09 | Int Standard Electric Corp | Multi-section cold cathode gas discharge tubes with a number of pin cathodes, the active areas of which are limited by a barrier |
| US2876400A (en) * | 1953-02-27 | 1959-03-03 | Siemens Ag | Composite electrodes for directional crystal devices |
| DE1090772B (en) * | 1955-10-05 | 1960-10-13 | Siemens Edison Swan Ltd | Gas-filled electrical counting and storage tubes with a screw-shaped cathode and an anode which is arranged parallel to the axis of the cathode screw |
| US2925531A (en) * | 1958-07-22 | 1960-02-16 | Philips Corp | Cold-cathode stepping tubes |
| US3092749A (en) * | 1960-04-15 | 1963-06-04 | Gen Electric | Electron discharge device |
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