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US2428362A - Means for recovering coating material from melted electrolytically coated continuous strip material - Google Patents

Means for recovering coating material from melted electrolytically coated continuous strip material Download PDF

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Publication number
US2428362A
US2428362A US480224A US48022443A US2428362A US 2428362 A US2428362 A US 2428362A US 480224 A US480224 A US 480224A US 48022443 A US48022443 A US 48022443A US 2428362 A US2428362 A US 2428362A
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Prior art keywords
strip
tank
tin
roll
quenching medium
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US480224A
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Egge Klaus
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Carnegie Illinois Steel Corp
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Carnegie Illinois Steel Corp
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Priority to US480224A priority Critical patent/US2428362A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48After-treatment of electroplated surfaces
    • C25D5/50After-treatment of electroplated surfaces by heat-treatment

Definitions

  • This invention relates to electrolytically coated continuous strip material, especially tin coated steel strip and particularly to improvements in means for collecting and recovering any excess tin or coating material and scale discharged from the surface of the strip during and after the bright melting thereof.
  • a coating such as tin
  • continuous length strip material such as iron or steel
  • electrolytc means After the strip is electrolytically tin coated, it is usually passed through a melting unit wherein the coat.. ing thereon is melted so as to provide a finished vstrip having a bright luster and smooth, even ilnish.
  • the melting is done by passing the strip through hot oil, heating by electrical inductance, or by subjecting the strip to electrical resistance.
  • the strip is usually disposed in a vertical plane during the melting ci the coating thereon and then passes around a horizontal disposed roll, which is usually a conductor roll for supplying the electrical power to the stri-p for such resistance melting.
  • This conductor roll is usually disposed in a tank containing a quenching medium which is adapted to quench the strip and coating immediately aiter the melting operation.
  • a quenching medium which is adapted to quench the strip and coating immediately aiter the melting operation.
  • Figure 1 is a vertical section through the melting unit and the quenching tank of an electrotinning line showing my invention incorporated therewith;
  • Fig. 2 is a sectional view taken on line II--II of Figure 1;
  • Figure 3 is an enlarged sectional view taken on line III-III of Figure 2.
  • S indicates a continuous length coated strip as it is delivered from the electroplating bath of a continuous electrotinning line with the strip traveling in the direction of the arrows, as shown in Figure 1 of the drawings and which is conveyed therethrough and therefrom by suitable driving means (now shown).
  • suitable driving means now shown.
  • the strip After the strip has been electrolytically coated, it is passed through a heating unit designed to melt the deposited tin or coating thereon with such heating being effected by any suitable means.
  • resistance melting may be employed including energized conductor rolls 2 and t entrance leg 'l and a discharge leg 8 which legs;
  • the rheat applied thereto by means of electrical resistance is designed to bring the tin or coated material on the strip t its melting point in a zone indicated at M adjacent the lower end of the discharge leg 8 of the mufiie 6.
  • a tank 9 containing a quenching medium and in which the conductor roll 3 is disposed is arranged. The strip passes from the muboard 6 into and through the quenching medium in the tank 9 from which the strip passes to subsequent processing steps.
  • the discharge leg 8 there is arranged in one side of the discharge leg 8 adjacent the lower end thereof on the'inner side of the strip S above the roll 3, and within the quenching tank 9, means for introducing a fluid under pressure thereinto directly into the path of the strip through the lower end of the discharge leg 8, for the purpose of circulating the quenching medium disposed therein.
  • the means for introducing a uid under pressure consists preferably of a. pair of nozzles Il) which are connected preferably to a pair of pipe lines I2 extending through the side wall of the tank 9 and connected to a pump or any other suitable source of supply (not shown). It is preferable that this fluid directed thereinto be the quenching medium itself which is usually water, and the lines I2 would then constitute the inlet supply for the tank 9. In such case, there is arranged adjacent the bottom of the tank 9,
  • a. discharge line I3 which likewise is connected to the pump or other source of discharge for conveying any excess quenching medium from the tank.
  • an inclined trough member I4 which extends substantially the full width of the lower end of the discharge leg 8.
  • the trough-like member I4 is preferably made of fiber, Micarta or some other suitable insulating material.
  • the improved apparatus of my invention functions in the following manner.
  • the strip S passes through the muumble 6 and down through the melting zone M in the lower end of the discharge leg 8, it will be understood that the tin or coating is heated to its melting point. After the tin or coating is melted, the strip passes directly into the quenching medium in the tank 9 so as to immediately quench the melted tin or coating on the surface of the strip.
  • the strip passes into the quenching medium in the lower end of the discharge leg 8 small globules of tin cr coating material and pieces of scale will drop from the tin or coated surface of the strip material.
  • the fluid or quenching medium under pressure introduced through the pipe I2 and the nozzles I8 into the lower end of the discharge leg 8 across the path of the strip S and circulates the quenchingrmedium in the vicinity thereof.
  • Such circulation of the quenching medium will tend to carry any excess tin or coating material and scale from around the strip to a point at the side of the discharge leg 8, and the tank 9, at one end of the roll 3, or the same will fall into the trough-like member I4, and, it will be carried to the lower end of the trough member and drop therefrom to the bottom of the tank, as
  • a filter or screen (not shown) so as to prevent the small particles of tin or coating material from passing from the bottom of the tank through the discharge line.
  • a pump is used to recirculate the quenching medium and to which the inlet lines I2 and the discharge line I3 are connected, so as to prevent recirculating of the small tin or coating particles which otherwise would be vcarried through the pump and back into the tank by the recirculating current.
  • a rubber contact roll I5 which is arranged on the outer side of thestrip S, directly opposite the conductor roll 3 so as to maintain the strip at all times in contact with the conductor roll 3 as the strip passes therearound. If such a roll is provided, it may be desirable to prevent any excess tin or coating material and scale from dropping between the outer side of the strip S and the contact roll. In such case it is preferable that additional fluid pressure means be introduced-into the lower end of the discharge leg 8 on the outer side of the strip directly opposite the first mentioned fluid pressure means.
  • Such a fluid pressure means would consist, as before, preferably of a pair of inlet linesA I6 extending through the side of the tank 9 having nozzles arranged on the ends thereof for discharging the iiuid or quenching medium under pressure to the space on the outer side of the strip.
  • a trough member I1 similar to the trough member I4, which is positioned directly below the path of the fluid or the quenching medium directed from the lines I6 into the tank.
  • the uid pressure or quenching medium introduced into the tank 9 through the line I6 circulates the quenching medium on the outer side of ⁇ the strip S, and tends to carry any excess tin or coating material and scale to the side of the discharge leg 8 and the tank 9 where it drops to the bottom of the quenching tank thereby preventing such tin or coating material and scale from dropping to a point between the I claim:
  • quenching medium from said introducing means circulating the quenching medium in said tank in the vicinity of the strip so that any excess tin or scale is forced from' the space between the strip and the roll and caused to drop either into said trough member or into the bottom of said tank.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Description

Federated @et 7 94? stares e Klaus Egge, Mount Lebanon, Pa., assigner to Car- :regle-Illinois Steel Corporation, a corporation of New Jersey Application March 23, 1943, Serial No. 480,224
This invention relates to electrolytically coated continuous strip material, especially tin coated steel strip and particularly to improvements in means for collecting and recovering any excess tin or coating material and scale discharged from the surface of the strip during and after the bright melting thereof.
It is now common practice to apply a coating. such as tin, to continuous length strip material, such as iron or steel, by electrolytc means. After the strip is electrolytically tin coated, it is usually passed through a melting unit wherein the coat.. ing thereon is melted so as to provide a finished vstrip having a bright luster and smooth, even ilnish. Sometimes the melting is done by passing the strip through hot oil, heating by electrical inductance, or by subjecting the strip to electrical resistance. In the resistance melting, the strip is usually disposed in a vertical plane during the melting ci the coating thereon and then passes around a horizontal disposed roll, which is usually a conductor roll for supplying the electrical power to the stri-p for such resistance melting. This conductor roll is usually disposed in a tank containing a quenching medium which is adapted to quench the strip and coating immediately aiter the melting operation. Such a melting unit and quenching tank arrangement is disclosed in the copending application `of Ewart S. Taylerson, Serial No. 447,966, iiled June 22, 1942.
It has been found that as'the strip passes vertically down into the quenching tank that small globules of the tin or coating material and pieces of scale are carried into the tank by the strip as it passes thereinto and fall free from the surface of the strip into the quenching medium in the space between the conductor roll therein and the strip and would lodgetherebetween and .become pulverized. This excess tin or coating material and scale not only tended to scratch the vsurface of the strip and the roll but also caused iiashings of electric current from the strip to the roll thereby resulting in burning and pitting the roll surface. This condition necessitated relatively frequent resurfacing and replacement of the conductor roll which was inconvenient. as well as expensive. Furthermore, the valuable tin or other coating material was lost under such conditions. It is vto an improved means or apparatus for preventing this excess tin or coating material and4vv scale from being disposed between the conductor, roll and the strip so that the tin or coating may be recovered that the present invention relates.
Accordingly, itis the general object of the 3 Claims. (Cl. 26E-4) Apresent invention to provide an improved means or apparatus for preventing any excess tin or coating material and scale from passing into the space between the conductor roll and strip in the quenching tank.
It is a more specific object of the invention to provide an improved means or apparatus for introducing a fluid under pressure across the path of the strip as it enters the quenching tank so as to cause the quenching medium therein to 'circulate whereby any excess tin or coating material and scale are prevented from passing into the space between the strip and the conductor roll and are caused to drop to the bottom of the tank.
It is a further object of this invention to provide an improved method for preventing any excess tin or coating material and scale from passing into the space between the conductor roll and the strip in the quenching tank by introducing a suitable iiuid or the quenching medium under pressure into the lower end of the heating unit across the path of the strip as it passes therethrough so that the excess tin or coating material and scale are carried to one side of the tank and caused to drop to the bottomthereof.
Various other objects and advantages of this invention will be more apparent in the course of the following specification and will be particularly pointed out in the appended claims.
Inthe accompanying drawings there is shown, for the purpose of illustration,'an embodiment which my invention may assume in practice.
In these drawings:
Figure 1 is a vertical section through the melting unit and the quenching tank of an electrotinning line showing my invention incorporated therewith;
Fig. 2 is a sectional view taken on line II--II of Figure 1; and
Figure 3 is an enlarged sectional view taken on line III-III of Figure 2.
Referring more particularly to the drawings, S indicates a continuous length coated strip as it is delivered from the electroplating bath of a continuous electrotinning line with the strip traveling in the direction of the arrows, as shown in Figure 1 of the drawings and which is conveyed therethrough and therefrom by suitable driving means (now shown). After the strip has been electrolytically coated, it is passed through a heating unit designed to melt the deposited tin or coating thereon with such heating being effected by any suitable means.
For example, resistance melting may be employed including energized conductor rolls 2 and t entrance leg 'l and a discharge leg 8 which legs;
extend toward the inner peripheries of the respective conductor rolls 2 and 3, and enclosing the strip to points adjacent the latter, As the strip passes through the muflie 8, the rheat applied thereto by means of electrical resistance is designed to bring the tin or coated material on the strip t its melting point in a zone indicated at M adjacent the lower end of the discharge leg 8 of the mufiie 6. Directly below the lower end of the discharge leg 8, and into which the same extends, there is arranged a tank 9 containing a quenching medium and in which the conductor roll 3 is disposed. The strip passes from the muiile 6 into and through the quenching medium in the tank 9 from which the strip passes to subsequent processing steps.
According to the present invention, there is arranged in one side of the discharge leg 8 adjacent the lower end thereof on the'inner side of the strip S above the roll 3, and within the quenching tank 9, means for introducing a fluid under pressure thereinto directly into the path of the strip through the lower end of the discharge leg 8, for the purpose of circulating the quenching medium disposed therein. It wil1 be understood that the lower end of the discharge leg 8 is disposed in the quenching medium in the tank 9. The means for introducing a uid under pressure consists preferably of a. pair of nozzles Il) which are connected preferably to a pair of pipe lines I2 extending through the side wall of the tank 9 and connected to a pump or any other suitable source of supply (not shown). It is preferable that this fluid directed thereinto be the quenching medium itself which is usually water, and the lines I2 would then constitute the inlet supply for the tank 9. In such case, there is arranged adjacent the bottom of the tank 9,
a. discharge line I3 which likewise is connected to the pump or other source of discharge for conveying any excess quenching medium from the tank.
If desired, there is suitably arranged on the inner Wall of the discharge leg 8 along the inner side of the strip S at a point above the roll 3 and directly below the path of the fluid pressure or the nozzles IIJ, an inclined trough member I4 which extends substantially the full width of the lower end of the discharge leg 8. The trough-like member I4 is preferably made of fiber, Micarta or some other suitable insulating material.
The improved apparatus of my invention functions in the following manner. As the strip S passes through the muiile 6 and down through the melting zone M in the lower end of the discharge leg 8, it will be understood that the tin or coating is heated to its melting point. After the tin or coating is melted, the strip passes directly into the quenching medium in the tank 9 so as to immediately quench the melted tin or coating on the surface of the strip. As the strip passes into the quenching medium in the lower end of the discharge leg 8, small globules of tin cr coating material and pieces of scale will drop from the tin or coated surface of the strip material. To prevent these small globules and pieces of scale from dropping between the conductor roll 3 and the strip S, the fluid or quenching medium under pressure introduced through the pipe I2 and the nozzles I8 into the lower end of the discharge leg 8 across the path of the strip S and circulates the quenchingrmedium in the vicinity thereof. Such circulation of the quenching medium will tend to carry any excess tin or coating material and scale from around the strip to a point at the side of the discharge leg 8, and the tank 9, at one end of the roll 3, or the same will fall into the trough-like member I4, and, it will be carried to the lower end of the trough member and drop therefrom to the bottom of the tank, as
shown in Figure 2 of the drawings. It will be seen then that the tin or other coating material disposed in the bottom of the quenching tank 9 may be easily recovered therefrom.
It is preferable that there be arranged in the tank 9 at the inner end of the discharge line I3, a filter or screen (not shown) so as to prevent the small particles of tin or coating material from passing from the bottom of the tank through the discharge line. Such is especially advisable it a pump is used to recirculate the quenching medium and to which the inlet lines I2 and the discharge line I3 are connected, so as to prevent recirculating of the small tin or coating particles which otherwise would be vcarried through the pump and back into the tank by the recirculating current. l
In certain cases, it may be desirable to provide a rubber contact roll I5, which is arranged on the outer side of thestrip S, directly opposite the conductor roll 3 so as to maintain the strip at all times in contact with the conductor roll 3 as the strip passes therearound. If such a roll is provided, it may be desirable to prevent any excess tin or coating material and scale from dropping between the outer side of the strip S and the contact roll. In such case it is preferable that additional fluid pressure means be introduced-into the lower end of the discharge leg 8 on the outer side of the strip directly opposite the first mentioned fluid pressure means. Such a fluid pressure means would consist, as before, preferably of a pair of inlet linesA I6 extending through the side of the tank 9 having nozzles arranged on the ends thereof for discharging the iiuid or quenching medium under pressure to the space on the outer side of the strip. If desired, there is likewise provided a trough member I1 similar to the trough member I4, which is positioned directly below the path of the fluid or the quenching medium directed from the lines I6 into the tank. As before, the uid pressure or quenching medium introduced into the tank 9 through the line I6 circulates the quenching medium on the outer side of` the strip S, and tends to carry any excess tin or coating material and scale to the side of the discharge leg 8 and the tank 9 where it drops to the bottom of the quenching tank thereby preventing such tin or coating material and scale from dropping to a point between the I claim:
1. In izombination with apparatus for coating electroly/ ically continuous length strip material, means for melting the coating thereon so as to obtain a smooth, high-luster finish, a tank having a quenching medium disposed therein into and through which the strip passes immediately after it is delivered from the melting means, a horizontally disposed rotatable roll arranged in said tank and around which said strip passes, said strip being delivered from said melting unit to said roll at an angle to the horizontal, means f or introducing the quenching fluid under pressure into the quenching tank in substantially a horizontal plane substantially into the path of the strip on the inner side thereof at a point above said roll, and an inclined trough member arranged in said quenching tank above said roll adjacent the inner side ofthe strip and below the path of the fluid directed thereinto, said iluid circulating the quenching medium in the vicinity of the strip so that any excess coating material or scale is forced from the space between the strip and said roll and caused to drop either into said trough member or into the bottom of said tank.
2. In combination with apparatus for tin coating .electrolytically continuous length strip steel, means through which the strip is adapted to pass in substantially a vertical plane for melting the tin coating thereon so as to obtain a smooth, high-luster nish, a tank having a quenching medium disposed therein into and through which the strip passes substantially vertically from said melting means, a horizontally disposed rotatable roll arranged in said tank around which the strip passes, means for introducing the quenching medium under pressure into said tank in substantially a horizontal plane substantiallyin the path of the strip on theinner side thereof as the same enters the tank at a point above said roll, and a trough member arranged in said quenching medium above said roll adjacent the inner side oi.' the strip and'below the point of introduction of the quenching medium into said tank, said.
quenching medium from said introducing means circulating the quenching medium in said tank in the vicinity of the strip so that any excess tin or scale is forced from' the space between the strip and the roll and caused to drop either into said trough member or into the bottom of said tank.
3. In combination with apparatus for tin coating electrolytically continuous length strip steel, means through which the strip passes in substantially a vertical plane for melting the tin coating thereon so as to obtain a smooth, highluster nish, a tank having a quenchingfmedium i disposed therein into and through which the strip passes immediately after it is delivered from said melting means in substantially a vertical plane, said melting means including a horizontally disposed conductor roll arranged in said tank around which the strip passes, a contact roll arranged in said tank diametrically oppodte said conductor roll and with which it forms a path through which the strip passes in contact with .both rolls, means for introducing the quenching medium under pressure into said tank in substantially a horizontal plane substantially in the path of the 'strip on both the outer and inner sides thereof as the same enters the tank at a point above said rolls, and a trough member arranged in said quenching medium to either side of the strip and adjacent thereto, each of said trough members positioned above said rolls and below the point of introduction of the quenching medium into said tank, said quenching medium as it is delivered into said tank circulating the quenching medium in the vicinity of the strip so that any excess tin or scale is forced from the space between the strip and each of said rolls and caused to drop either into said trough members or into the bottom ot said tank.
KLAUS EGGE.
REFERENCES crrEn The following references are of record in the nie of this patent:
UNITED STATES PATENTS iiowing Methods, page 3,reprint fromrNovember, 1942, issue or Westinghouse Engineer. (Reprint lnDivision 56, 20d-28.)
US480224A 1943-03-23 1943-03-23 Means for recovering coating material from melted electrolytically coated continuous strip material Expired - Lifetime US2428362A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2546538A (en) * 1945-10-30 1951-03-27 Crown Cork & Seal Co Apparatus for handling and brightening metal
US3021236A (en) * 1958-05-28 1962-02-13 Midland Ross Corp Convective heat transfer furnace and method

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US482879A (en) * 1892-09-20 Method of and apparatus for tempering wire
US1517910A (en) * 1917-10-10 1924-12-02 Kirschner Felix Plant for electroplating metal
US1717460A (en) * 1927-07-01 1929-06-18 Joseph J Mascuch Apparatus for electroplating metallic bands
US1860065A (en) * 1930-11-25 1932-05-24 Singer Mfg Co Metal treating furnace
US1937420A (en) * 1932-04-20 1933-11-28 Wood Apparatus for heat treating wire
US2141382A (en) * 1938-08-10 1938-12-27 Pittsburgh Crucible Steel Comp Apparatus for treating plated strip metal
US2192303A (en) * 1938-12-27 1940-03-05 Pittsburgh Crucible Steel Comp Apparatus for treating plated strip metal

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US482879A (en) * 1892-09-20 Method of and apparatus for tempering wire
US1517910A (en) * 1917-10-10 1924-12-02 Kirschner Felix Plant for electroplating metal
US1717460A (en) * 1927-07-01 1929-06-18 Joseph J Mascuch Apparatus for electroplating metallic bands
US1860065A (en) * 1930-11-25 1932-05-24 Singer Mfg Co Metal treating furnace
US1937420A (en) * 1932-04-20 1933-11-28 Wood Apparatus for heat treating wire
US2141382A (en) * 1938-08-10 1938-12-27 Pittsburgh Crucible Steel Comp Apparatus for treating plated strip metal
US2192303A (en) * 1938-12-27 1940-03-05 Pittsburgh Crucible Steel Comp Apparatus for treating plated strip metal

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2546538A (en) * 1945-10-30 1951-03-27 Crown Cork & Seal Co Apparatus for handling and brightening metal
US3021236A (en) * 1958-05-28 1962-02-13 Midland Ross Corp Convective heat transfer furnace and method

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