US2470034A - Electric contact formed of a ruthenium composition - Google Patents
Electric contact formed of a ruthenium composition Download PDFInfo
- Publication number
- US2470034A US2470034A US631206A US63120645A US2470034A US 2470034 A US2470034 A US 2470034A US 631206 A US631206 A US 631206A US 63120645 A US63120645 A US 63120645A US 2470034 A US2470034 A US 2470034A
- Authority
- US
- United States
- Prior art keywords
- ruthenium
- gold
- cobalt
- contact
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 23
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title description 20
- 229910052707 ruthenium Inorganic materials 0.000 title description 19
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 16
- 229910052751 metal Inorganic materials 0.000 description 16
- 239000002184 metal Substances 0.000 description 16
- 229910052737 gold Inorganic materials 0.000 description 15
- 239000010931 gold Substances 0.000 description 15
- 229910017052 cobalt Inorganic materials 0.000 description 11
- 239000010941 cobalt Substances 0.000 description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 11
- 239000000463 material Substances 0.000 description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NTUMULUKEGRBRP-UHFFFAOYSA-N [Au].[Co].[Ru] Chemical compound [Au].[Co].[Ru] NTUMULUKEGRBRP-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- -1 carbides Chemical class 0.000 description 2
- VLWBWEUXNYUQKJ-UHFFFAOYSA-N cobalt ruthenium Chemical compound [Co].[Ru] VLWBWEUXNYUQKJ-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910001316 Ag alloy Inorganic materials 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- DYCKMDCRYZZTOV-UHFFFAOYSA-N [Os].[Ir].[Pt] Chemical compound [Os].[Ir].[Pt] DYCKMDCRYZZTOV-UHFFFAOYSA-N 0.000 description 1
- OGGGKVODAVGXNR-UHFFFAOYSA-N [Rh].[Os] Chemical compound [Rh].[Os] OGGGKVODAVGXNR-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SFOSJWNBROHOFJ-UHFFFAOYSA-N cobalt gold Chemical compound [Co].[Au] SFOSJWNBROHOFJ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- CFQCIHVMOFOCGH-UHFFFAOYSA-N platinum ruthenium Chemical compound [Ru].[Pt] CFQCIHVMOFOCGH-UHFFFAOYSA-N 0.000 description 1
- HWLDNSXPUQTBOD-UHFFFAOYSA-N platinum-iridium alloy Chemical compound [Ir].[Pt] HWLDNSXPUQTBOD-UHFFFAOYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 229910000898 sterling silver Inorganic materials 0.000 description 1
- 239000010934 sterling silver Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/023—Composite material having a noble metal as the basic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/1216—Continuous interengaged phases of plural metals, or oriented fiber containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12181—Composite powder [e.g., coated, etc.]
Definitions
- Patenteci May 10, 1949 ELECTRIC CONTACT FORMED OF A RUTHENIUM COMPOSITION Franz R. Hensel, James W. Wiggs, and Vernon E.
- This invention relates to ruthenium metal compositions.
- An oliject of the invention is to improve ruthenium compositions.
- Another object is to improve electric contacts and the compositions thereof.
- the invention contemplates a sintered metal composition formed essentially of ruthenium, cohalt and gold.
- Gold is a material which is most resistant to sulfiding. It has, however, definite disadvantages as a contact material as compared with silver, such as needle-type transfer characteristics and Welding at low current ratings.
- the gold-cobalt alloy has a liquid phase at approximately 1000 C. This liquid phase combines with the ruthenium dissolving a small portion of the latter, thereby causing the sintered compacts to shrink. Thus a practically 100% dense structure is formed which is highly resistant to arcing when used in electrical devices for contacts or the like.
- the oxidation characteristics of both ruthenium and cobalt are such that oxide layers are formed, eliminating any sticking tendencies of the contact materials without creating films of Per cent by weight Ruthenium 60 to 95 Cobalt .5 to 20 Gold, balance.
- compositions which can be readily produced and which have suitable properties for such applications as electric con tacts, for example, are:
- the metal compositions are produced by powder metallurgical methods which comprise mixing the powders by such methods as ball milling, pressing the mixed powders into suitable shapes at unit pressures varying from about 5 to 50 tons tons per square inch and sintering in a non-oxidizin atmosphere over a temperature range of about 1000 C. to 1500 C.
- the procedure may be modified by uniting first the ruthenium and cobalt powders in such a manner that the ruthenium particles are coated with cobalt.
- the mixture is pressed and then sintered at temperatures ranging from about 1100 C. to 1400 C. depending on the amount of porosity desired in the sintered compact.
- the porous compact is then alloyed or impregnated with gold at temperatures ranging from about 1200 C, to 1400 C.
- the metal compositions may be pressed in the form of small discs, slabs, bars, rods or other forms for use as electric contacts, or they may be formed into special shapes for use as contacts or other purposes.
- One contact combination which has been found very good for D. C. operation comprises a positive contact of the ruthenium-cobalt-gold metal composition and a negative contact of tungsten.
- Other contact combinations which suggest themselves are those wherein the positive contact is one of the metal compositions of the present invention and the negative contact is of tungsten, tungsten carbide or a refractory metal composition such as tungsten or molybdenum or compounds of these metals such as carbides, borides or nitrides mixed or impregnated with metals or alloys of the copper, silver, gold group.
- the metal compositions of the present invention give satisfactory performance as contact material when operated against themselves both in A. C. and D. C. applications. While in certain D. C. applications it may be preferred to use them on the positive contact, tests have indicated that they perform satisfactorily on the negative contact.
- the metal compositions of the present invention have also shown satisfactory performance when used in contact combinations where the mating contact consists of platinum-iridium, platinum-ruthenium, platinum-osmium-iridium, platinum-palladium, pure palladium, pure ruthenium, osmium-rhodium and similar alloys.
- the new metal compositions can also be used in contact combinations where the mating contact consists of coin silver or sterling silver or silver alloys generally useclfor contact work.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Contacts (AREA)
Description
Patenteci May 10, 1949 ELECTRIC CONTACT FORMED OF A RUTHENIUM COMPOSITION Franz R. Hensel, James W. Wiggs, and Vernon E.
Heil, Indianapolis, Ind., assignors to P. R. Mallory 85 (30., Inc., Indianapolis, Ind., a corporation of Delaware No Drawing. Application November 27, 1945, Serial No. 631,206
4 Claims.
This invention relates to ruthenium metal compositions.
An oliject of the invention is to improve ruthenium compositions.
Another object is to improve electric contacts and the compositions thereof.
Other objects of the invention will be apparent from the description and claims.
This invention is a continuation-in-part of our prior-filed co-pending application, Serial Number 474,178, filed January 30, 1943, now abancloned.
The invention contemplates a sintered metal composition formed essentially of ruthenium, cohalt and gold.
The advantages of this composition over cobaltfree materials are its increased density, wear resistance and particularly its increased resistance towards arcing.
The advantage of such a composition as compared with silver base materials is resistance to sulficling.
Gold is a material which is most resistant to sulfiding. It has, however, definite disadvantages as a contact material as compared with silver, such as needle-type transfer characteristics and Welding at low current ratings.
These disadvantages are overcome by combining the gold with ruthenium and cementing the ruthenium with the gold by the addition of cobalt which enters into a solid solution formation both with the gold and the ruthenium.
The gold-cobalt alloy has a liquid phase at approximately 1000 C. This liquid phase combines with the ruthenium dissolving a small portion of the latter, thereby causing the sintered compacts to shrink. Thus a practically 100% dense structure is formed which is highly resistant to arcing when used in electrical devices for contacts or the like.
The oxidation characteristics of both ruthenium and cobalt are such that oxide layers are formed, eliminating any sticking tendencies of the contact materials without creating films of Per cent by weight Ruthenium 60 to 95 Cobalt .5 to 20 Gold, balance.
Some of the specific compositions which can be readily produced and which have suitable properties for such applications as electric con tacts, for example, are:
Per cent by weight Ruthenium 80 Cobalt 5 Gold 15 Per cent by weight Ruthenium Cobalt 10 Gold 25 Per cent by weight Ruthenium 92 Cobalt 3 Gold 5 Per cent by weight Ruthenium Cobalt 8 Gold 17 The metal compositions are produced by powder metallurgical methods which comprise mixing the powders by such methods as ball milling, pressing the mixed powders into suitable shapes at unit pressures varying from about 5 to 50 tons tons per square inch and sintering in a non-oxidizin atmosphere over a temperature range of about 1000 C. to 1500 C.
The procedure may be modified by uniting first the ruthenium and cobalt powders in such a manner that the ruthenium particles are coated with cobalt. The mixture is pressed and then sintered at temperatures ranging from about 1100 C. to 1400 C. depending on the amount of porosity desired in the sintered compact. The porous compact is then alloyed or impregnated with gold at temperatures ranging from about 1200 C, to 1400 C.
The metal compositions may be pressed in the form of small discs, slabs, bars, rods or other forms for use as electric contacts, or they may be formed into special shapes for use as contacts or other purposes.
Contacts of this material have proven suitable for D. C. voltage regulator contacts.
One contact combination which has been found very good for D. C. operation comprises a positive contact of the ruthenium-cobalt-gold metal composition and a negative contact of tungsten. Other contact combinations which suggest themselves are those wherein the positive contact is one of the metal compositions of the present invention and the negative contact is of tungsten, tungsten carbide or a refractory metal composition such as tungsten or molybdenum or compounds of these metals such as carbides, borides or nitrides mixed or impregnated with metals or alloys of the copper, silver, gold group.
The metal compositions of the present invention give satisfactory performance as contact material when operated against themselves both in A. C. and D. C. applications. While in certain D. C. applications it may be preferred to use them on the positive contact, tests have indicated that they perform satisfactorily on the negative contact.
The metal compositions of the present invention have also shown satisfactory performance when used in contact combinations where the mating contact consists of platinum-iridium, platinum-ruthenium, platinum-osmium-iridium, platinum-palladium, pure palladium, pure ruthenium, osmium-rhodium and similar alloys.
The new metal compositions can also be used in contact combinations where the mating contact consists of coin silver or sterling silver or silver alloys generally useclfor contact work.
Small percentages of such metals as nickel, iron, silver, copper, palladium and platinum group metals, tungsten, molybdenum may be present in the final composition providing they do not deleteriously affect the contact properties of the ruthenium-cobalt-gold combination.
While specific embodiments of the invention have been described, it is intended to cover the invention broadly within the spirit and scope of the appended claims.
What is claimed, is:
1. An electric contact formed of a metal composition consisting of to 95% by weight of ruthenium, .5 to 20% by weight of cobalt, and the balance all gold.
2. An electric contact formed of a metal composition consisting of about by weight of ruthenium, about 10% by weight of cobalt and about 25 by weight of gold.
3. An electric contact formed of a metal composition consisting of about 92% by weight of ruthenium, about 3% by weight of cobalt and about 5% by weight of gold.
4. An electric contact formed of a metal composition consisting of about by weight of ruthenium, about 8% by weight of cobalt and about 1'? by weight of gold.
. FRANZ R. HENSEL.
JAMES W. WIGGS. VERNON E.
REFERENCES CITED The following references are of record in the file of this patent:
UlilI'IED STATES PATENTS 1-lu7:r.=ber Name Date 1,165,448 Richter Dec. 28, 1915 1,415,233 Fahrenwald May 9, 1922 1,832,307 Kingsbury Nov. 17, 1931 2,048,647 Feussner et a1 July 21, 1936
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US631206A US2470034A (en) | 1945-11-27 | 1945-11-27 | Electric contact formed of a ruthenium composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US631206A US2470034A (en) | 1945-11-27 | 1945-11-27 | Electric contact formed of a ruthenium composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2470034A true US2470034A (en) | 1949-05-10 |
Family
ID=24530220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US631206A Expired - Lifetime US2470034A (en) | 1945-11-27 | 1945-11-27 | Electric contact formed of a ruthenium composition |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2470034A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2793423A (en) * | 1954-04-19 | 1957-05-28 | Baker & Co Inc | Compound metal stock |
| US2876097A (en) * | 1957-03-28 | 1959-03-03 | Purolator Products Inc | Aluminum filters and method of production |
| US3039000A (en) * | 1956-07-14 | 1962-06-12 | Schwarzkopf Dev Co | Radiation shield structures and their production |
| US3278280A (en) * | 1964-03-16 | 1966-10-11 | Int Nickel Co | Workable ruthenium alloy and process for producing the same |
| US3301641A (en) * | 1964-01-27 | 1967-01-31 | Mallory & Co Inc P R | Tungsten-ruthenium alloy and powdermetallurgical method of making |
| US3498763A (en) * | 1968-03-25 | 1970-03-03 | Int Nickel Co | Workable duplex structured ruthenium alloys |
| US3957451A (en) * | 1974-08-02 | 1976-05-18 | General Motors Corporation | Ruthenium powder metal alloy |
| US3977841A (en) * | 1974-08-02 | 1976-08-31 | General Motors Corporation | Ruthenium powder metal alloy and method for making same |
| US4855102A (en) * | 1987-03-20 | 1989-08-08 | Hitachi, Ltd. | Sintering method |
| WO2004011178A1 (en) * | 2002-07-26 | 2004-02-05 | The Government Of The United States Of America, As Represented By The Secretary Of The Navy | Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds |
| US7347885B1 (en) | 2001-12-10 | 2008-03-25 | The United States Of America As Represented By The Secretary Of The Navy | Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds |
| US8436520B2 (en) | 2010-07-29 | 2013-05-07 | Federal-Mogul Ignition Company | Electrode material for use with a spark plug |
| US8471451B2 (en) | 2011-01-05 | 2013-06-25 | Federal-Mogul Ignition Company | Ruthenium-based electrode material for a spark plug |
| US8575830B2 (en) | 2011-01-27 | 2013-11-05 | Federal-Mogul Ignition Company | Electrode material for a spark plug |
| US8760044B2 (en) | 2011-02-22 | 2014-06-24 | Federal-Mogul Ignition Company | Electrode material for a spark plug |
| US8766519B2 (en) | 2011-06-28 | 2014-07-01 | Federal-Mogul Ignition Company | Electrode material for a spark plug |
| US8890399B2 (en) | 2012-05-22 | 2014-11-18 | Federal-Mogul Ignition Company | Method of making ruthenium-based material for spark plug electrode |
| US8979606B2 (en) | 2012-06-26 | 2015-03-17 | Federal-Mogul Ignition Company | Method of manufacturing a ruthenium-based spark plug electrode material into a desired form and a ruthenium-based material for use in a spark plug |
| US10044172B2 (en) | 2012-04-27 | 2018-08-07 | Federal-Mogul Ignition Company | Electrode for spark plug comprising ruthenium-based material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1165448A (en) * | 1913-04-30 | 1915-12-28 | Richter & Co Dr | Gold alloy. |
| US1415233A (en) * | 1916-11-06 | 1922-05-09 | Rhotanium Company | Composition of matter for platinum substitute in chemical apparatus and other uses and method of making same |
| US1832307A (en) * | 1925-07-11 | 1931-11-17 | Western Electric Co | Alloy for electrical contacts |
| US2048647A (en) * | 1931-07-15 | 1936-07-21 | Firm W C Heraeus Gmbh | Process of producing hard alloys |
-
1945
- 1945-11-27 US US631206A patent/US2470034A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1165448A (en) * | 1913-04-30 | 1915-12-28 | Richter & Co Dr | Gold alloy. |
| US1415233A (en) * | 1916-11-06 | 1922-05-09 | Rhotanium Company | Composition of matter for platinum substitute in chemical apparatus and other uses and method of making same |
| US1832307A (en) * | 1925-07-11 | 1931-11-17 | Western Electric Co | Alloy for electrical contacts |
| US2048647A (en) * | 1931-07-15 | 1936-07-21 | Firm W C Heraeus Gmbh | Process of producing hard alloys |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2793423A (en) * | 1954-04-19 | 1957-05-28 | Baker & Co Inc | Compound metal stock |
| US3039000A (en) * | 1956-07-14 | 1962-06-12 | Schwarzkopf Dev Co | Radiation shield structures and their production |
| US2876097A (en) * | 1957-03-28 | 1959-03-03 | Purolator Products Inc | Aluminum filters and method of production |
| US3301641A (en) * | 1964-01-27 | 1967-01-31 | Mallory & Co Inc P R | Tungsten-ruthenium alloy and powdermetallurgical method of making |
| US3278280A (en) * | 1964-03-16 | 1966-10-11 | Int Nickel Co | Workable ruthenium alloy and process for producing the same |
| US3498763A (en) * | 1968-03-25 | 1970-03-03 | Int Nickel Co | Workable duplex structured ruthenium alloys |
| US3957451A (en) * | 1974-08-02 | 1976-05-18 | General Motors Corporation | Ruthenium powder metal alloy |
| US3977841A (en) * | 1974-08-02 | 1976-08-31 | General Motors Corporation | Ruthenium powder metal alloy and method for making same |
| US4855102A (en) * | 1987-03-20 | 1989-08-08 | Hitachi, Ltd. | Sintering method |
| US7347885B1 (en) | 2001-12-10 | 2008-03-25 | The United States Of America As Represented By The Secretary Of The Navy | Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds |
| WO2004011178A1 (en) * | 2002-07-26 | 2004-02-05 | The Government Of The United States Of America, As Represented By The Secretary Of The Navy | Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds |
| US8436520B2 (en) | 2010-07-29 | 2013-05-07 | Federal-Mogul Ignition Company | Electrode material for use with a spark plug |
| US8471451B2 (en) | 2011-01-05 | 2013-06-25 | Federal-Mogul Ignition Company | Ruthenium-based electrode material for a spark plug |
| US8575830B2 (en) | 2011-01-27 | 2013-11-05 | Federal-Mogul Ignition Company | Electrode material for a spark plug |
| US8760044B2 (en) | 2011-02-22 | 2014-06-24 | Federal-Mogul Ignition Company | Electrode material for a spark plug |
| US8766519B2 (en) | 2011-06-28 | 2014-07-01 | Federal-Mogul Ignition Company | Electrode material for a spark plug |
| US10044172B2 (en) | 2012-04-27 | 2018-08-07 | Federal-Mogul Ignition Company | Electrode for spark plug comprising ruthenium-based material |
| US8890399B2 (en) | 2012-05-22 | 2014-11-18 | Federal-Mogul Ignition Company | Method of making ruthenium-based material for spark plug electrode |
| US8979606B2 (en) | 2012-06-26 | 2015-03-17 | Federal-Mogul Ignition Company | Method of manufacturing a ruthenium-based spark plug electrode material into a desired form and a ruthenium-based material for use in a spark plug |
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