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US2449917A - Surface treatment of metal - Google Patents

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Publication number
US2449917A
US2449917A US583481A US58348145A US2449917A US 2449917 A US2449917 A US 2449917A US 583481 A US583481 A US 583481A US 58348145 A US58348145 A US 58348145A US 2449917 A US2449917 A US 2449917A
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Prior art keywords
metal
coating
electrode
pits
areas
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US583481A
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John A Tansley
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Old Carco LLC
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Chrysler Corp
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/08Metallic material containing only metal elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/06Surface hardening
    • C21D1/09Surface hardening by direct application of electrical or wave energy; by particle radiation
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B4/00Electrothermal treatment of ores or metallurgical products for obtaining metals or alloys
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas

Definitions

  • Thisinvention relates to improvements in the preparation of a metallic surface for receiving a coating of metal or other material.
  • the operating life of machine parts such as shafts and the like can be extended by the forma tion or rebuilding of hearings or like working surfaces of the parts.
  • a layer or coating of metal is applied to such surfaces by spraying, for example, in the well known manner, and it is essential that such coating be fixedly adhered or secured in place.
  • the surface to be coated is roughened preparatory to receiving the coating.
  • An object of this invention is the provision of an improved method for roughening a surface preparatory to application of a coating thereto, and more particularly to create a surface having the desired characteristics for this purpose with out the necessity for the application of a similar or dissimilar metal to such surface.
  • portions of the metallic surface are relatively displaced to create a surface pattern including a multiplicity of pits and projections characterized by shapes and sizes to effectively interlock with the coating and hence provide a high degree of fixation for the latter.
  • Such pits are of a magnitude sufficient to receive portions of the coating therein and are characterized by restricted entrant necks, and a typical projection varies in size from a minimum adjacent the base to a maximum outwardly therefrom.
  • a piece of work having a surface to be roughened and an infusible electrode are positioned in an electrical circuit with a source of electrical energy and then alternately relatively moved into and out of such proximity as to respectively create and break an electric arc therebetween. Successive selected areas of the surface are thus treated under conditions of current flow in the circuit sufficient to displace portions of the metal at the surface incident to creating and breaking the are between the work and the electrode.
  • a highly concentrated heat is applied to relatively small successive areas of the surface which in effect fuses the metal at these areas, producing pits and displacing the metal in the form of projections adjacent the pits.
  • the electrode being infusible, there is no deposition of the metal or other material on the surface and the latter retains its original metallic characteristic.
  • a suitable electrode for example carbon
  • a holder connected to 2 conventional arc welding equipment, and a series of arcs made with successive areas of the surface to be treated.
  • a relatively small pencil-like infusible electrode is employed to work over the metallic surface to create the electric arc.
  • the size of the electrode may vary depending somewhat on the size of the pit desired.
  • Fig. 1 is a view in perspective illustrating application of the invention to a bearing surface of a crankshaft.
  • Fig. 2 is an enlarged fragmentary sectional view illustrating the bearing surface after roughening thereof.
  • Fig. 3 is a View, partly in section, showing the application of a coating to the surface shown in Fig. 2.
  • a crank shaft 5 has a hearing surface 6 which is to be resurfaced by a metallizing coating, this surface having been reduced by grinding or machining to allow for the proper thickness of the coating.
  • the crankshaft may be supported in any suitable manner for operation on the surface 6 thereof by the mechanism including one or more carbon electrodes 1, as desired, supported in a holder 8 connected to electric arc welding equipment.
  • the latter includes an electrically driven motor 9, driving a generator I0 having a first conductor I I connected to the crankshaft 5 and a second conductor I2 connected to the holder 8.
  • the holder 8 is provided with a handle 13 by which the electrodes 1 are moved relative to the surface 6 to be operated on.
  • the work to be operated on may be suitably moved to bring successive areas thereof into registration with the electrodes.
  • the electrodes are alternately moved into and out of such proximity to the surface 6 as to alternately create and break an electric arc therebetween, the electrodes being moved about the surface to subject successive areas thereof to the arc.
  • the metal of the surface is subjected to relatively high temperature fusing the same and causing displacement thereof as the arc is alternately made and broken. Displacement of the metal produces a pit as shown at I4, the pit being characterized by a, dimension which is smaller adjacent the surface than at the bottom or base of the pit, thus in effect producing a restricted entrant neck or opening.
  • the pits so produced are of a magnitude suflicient to receive therein the material of the coating.
  • the metal displaced in producing the pits is deposited on the surface in the form of projections, as shown at l5, of various shapes and sizes. In most instances the metal displaced moves to the surface in the form of a globular-like body and hence the projections l5 are mostly round and have a neck, somewhat smaller than the main body thereof, attached to the surface.
  • the depth of the pits and the height of the projections are controlled by the amount of voltage, the length of the are produced and the physical characteristics of the metal.
  • a current of 30 to 40 volts and 150 amperes is satisfactory.
  • the surface may be treated by alternately making and breaking contact with the electrode although the latter method is not believed to be as satisfactory in all respects as that had by the creation of an are as aforesaid.
  • the surface 6 so perated on has a pattern including pits characterized by restricted neck entrants and projections of a type which facilitate interlocking engagement with the resurface coating. In this roughening of the surface no similar or dissimilar metal is added thereto and but little if any of the metallic surface is lost.
  • a metal spray gun apparatus for applying a coating 11 to the reconditioned surface 5.
  • Apparatus of this type is well known and in general metal is fed to a heating zone from which the metal is propelled in molten or heat plastic condition against the surface to be sprayed. The sprayed metal interlocks with the pits and projections of the roughened surface to fixedly secure the coating in position.
  • the method is equally applicable for conditioning the surface of either hard or soft metals for the application thereto of a coating of metal or such other material as may be desired.
  • the method of preparing a surface of a metallic article for receiving a layer of metal to be fixed thereto which comprises positioning said article and a carbon electrode in electric circuit with a source of electric energy, relatively moving said article and electrode alternately from one spaced relationship to another spaced relationship to respectively create and break an electrical arc therebetween, and subjecting successive selected areas of said surface to the are so created under conditions of current flow sufli- 4 cient to fuse the metal at said selected areas and to displace at least a portion of such fused metal into projecting relationship from other areas of said surface adjacent said selected areas.
  • the method of roughening a metallic surface to facilitate interlocking of a coating therewith which comprises the steps of relatively moving said surface and an electrically charged infusible electrode as to alternately make and break an electrical arc therebetween having an intensity sufficient to fuse the metal at said surface and to displace such fused metal from one portion of said surface into projecting relationship from another portion of said surface adjacent the first portion, and so further relatively moving said surface and electrode as to successively subject selected portions of said surface to the arc so made to thereby create from the metal at said surface a pattern including pits at said one portion and projections at said adjacent portions.
  • the method of preparing a surface of a metallic article for receiving a layer of metal to be fixed thereto which comprises arranging said surface and an infusible electrode in electric circuit with a source of electric energy capable of creating an arc therebetween having an intensity sufficient to fuse the metal at selected portions of said surface and to displace at least some of such fused metal to an adjacent portion of said surface, and alternately making and breaking such arc.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

Description

Sept. 21, 1948.. .1. A. TANSLEY' 2,449 7 SURFACE TREATMENT OF METAL Filed March 19, 1945 IN V EN TOR.
Patented Sept. 21, 1948 SURFACE TREATMENT OF METAL John A. Tansley, New Castle, Ind., assignor to Chrysler Corporation, Highland Park, Mich, a
corporation of Delaware Application March 19, 1945, Serial No. 583,481
4 Claims. 1
Thisinvention relates to improvements in the preparation of a metallic surface for receiving a coating of metal or other material.
The operating life of machine parts such as shafts and the like can be extended by the forma tion or rebuilding of hearings or like working surfaces of the parts. In this operation a layer or coating of metal is applied to such surfaces by spraying, for example, in the well known manner, and it is essential that such coating be fixedly adhered or secured in place. For this purpose the surface to be coated is roughened preparatory to receiving the coating.
An object of this invention is the provision of an improved method for roughening a surface preparatory to application of a coating thereto, and more particularly to create a surface having the desired characteristics for this purpose with out the necessity for the application of a similar or dissimilar metal to such surface. Preferably in carrying out the foregoing, portions of the metallic surface are relatively displaced to create a surface pattern including a multiplicity of pits and projections characterized by shapes and sizes to effectively interlock with the coating and hence provide a high degree of fixation for the latter. Such pits are of a magnitude sufficient to receive portions of the coating therein and are characterized by restricted entrant necks, and a typical projection varies in size from a minimum adjacent the base to a maximum outwardly therefrom.
In accordance with the invention a piece of work having a surface to be roughened and an infusible electrode are positioned in an electrical circuit with a source of electrical energy and then alternately relatively moved into and out of such proximity as to respectively create and break an electric arc therebetween. Successive selected areas of the surface are thus treated under conditions of current flow in the circuit sufficient to displace portions of the metal at the surface incident to creating and breaking the are between the work and the electrode. In this opera tion a highly concentrated heat is applied to relatively small successive areas of the surface which in effect fuses the metal at these areas, producing pits and displacing the metal in the form of projections adjacent the pits. The electrode being infusible, there is no deposition of the metal or other material on the surface and the latter retains its original metallic characteristic.
In practice no specialized equipment is necessary inasmuch as a suitable electrode, for example carbon, may be attached to a holder connected to 2 conventional arc welding equipment, and a series of arcs made with successive areas of the surface to be treated.
Preferably, a relatively small pencil-like infusible electrode is employed to work over the metallic surface to create the electric arc. However, the size of the electrode may vary depending somewhat on the size of the pit desired.
For a typical embodiment of the invention, reference is made to the accompanying drawing, in which:
Fig. 1 is a view in perspective illustrating application of the invention to a bearing surface of a crankshaft.
Fig. 2 is an enlarged fragmentary sectional view illustrating the bearing surface after roughening thereof.
Fig. 3 is a View, partly in section, showing the application of a coating to the surface shown in Fig. 2.
Referring to Fig. 1, a crank shaft 5 has a hearing surface 6 which is to be resurfaced by a metallizing coating, this surface having been reduced by grinding or machining to allow for the proper thickness of the coating. The crankshaft may be supported in any suitable manner for operation on the surface 6 thereof by the mechanism including one or more carbon electrodes 1, as desired, supported in a holder 8 connected to electric arc welding equipment. The latter includes an electrically driven motor 9, driving a generator I0 having a first conductor I I connected to the crankshaft 5 and a second conductor I2 connected to the holder 8. The holder 8 is provided with a handle 13 by which the electrodes 1 are moved relative to the surface 6 to be operated on. If desired, the work to be operated on may be suitably moved to bring successive areas thereof into registration with the electrodes. In operation the electrodes are alternately moved into and out of such proximity to the surface 6 as to alternately create and break an electric arc therebetween, the electrodes being moved about the surface to subject succesive areas thereof to the arc. The metal of the surface is subjected to relatively high temperature fusing the same and causing displacement thereof as the arc is alternately made and broken. Displacement of the metal produces a pit as shown at I4, the pit being characterized by a, dimension which is smaller adjacent the surface than at the bottom or base of the pit, thus in effect producing a restricted entrant neck or opening. The pits so produced are of a magnitude suflicient to receive therein the material of the coating. The metal displaced in producing the pits is deposited on the surface in the form of projections, as shown at l5, of various shapes and sizes. In most instances the metal displaced moves to the surface in the form of a globular-like body and hence the projections l5 are mostly round and have a neck, somewhat smaller than the main body thereof, attached to the surface.
The depth of the pits and the height of the projections are controlled by the amount of voltage, the length of the are produced and the physical characteristics of the metal. For operation on ferrous metals a current of 30 to 40 volts and 150 amperes is satisfactory. If desired, the surface may be treated by alternately making and breaking contact with the electrode although the latter method is not believed to be as satisfactory in all respects as that had by the creation of an are as aforesaid.
The surface 6 so perated on has a pattern including pits characterized by restricted neck entrants and projections of a type which facilitate interlocking engagement with the resurface coating. In this roughening of the surface no similar or dissimilar metal is added thereto and but little if any of the metallic surface is lost.
In Fig. 3 there is shown a metal spray gun apparatus, generally designated by the numeral I5, for applying a coating 11 to the reconditioned surface 5. Apparatus of this type is well known and in general metal is fed to a heating zone from which the metal is propelled in molten or heat plastic condition against the surface to be sprayed. The sprayed metal interlocks with the pits and projections of the roughened surface to fixedly secure the coating in position.
The method is equally applicable for conditioning the surface of either hard or soft metals for the application thereto of a coating of metal or such other material as may be desired.
Although but one specific embodiment of the invention has herein been shown and described, it will be understood that various changes in the size, shape and arrangement of parts may be made without departing from the spirit of the invention.
I claim:
1. The method of preparing a surface of a metallic article for receiving a layer of metal to be fixed thereto which comprises positioning said article and a carbon electrode in electric circuit with a source of electric energy, relatively moving said article and electrode alternately from one spaced relationship to another spaced relationship to respectively create and break an electrical arc therebetween, and subjecting successive selected areas of said surface to the are so created under conditions of current flow sufli- 4 cient to fuse the metal at said selected areas and to displace at least a portion of such fused metal into projecting relationship from other areas of said surface adjacent said selected areas.
2. The method of preparing a surface of a metallic article for receiving a layer of metal to be fixed thereto which comprises alternately creating and breaking an electrical are between selected areas of the surface of said article and an infusible electrode having an intensity sufficient to fuse the metal at said selected areas and to displace at least a portion of such fused metal into projecting relationship from other areas of said surface adjacent said selected areas.
3. The method of roughening a metallic surface to facilitate interlocking of a coating therewith, which comprises the steps of relatively moving said surface and an electrically charged infusible electrode as to alternately make and break an electrical arc therebetween having an intensity sufficient to fuse the metal at said surface and to displace such fused metal from one portion of said surface into projecting relationship from another portion of said surface adjacent the first portion, and so further relatively moving said surface and electrode as to successively subject selected portions of said surface to the arc so made to thereby create from the metal at said surface a pattern including pits at said one portion and projections at said adjacent portions.
4. The method of preparing a surface of a metallic article for receiving a layer of metal to be fixed thereto which comprises arranging said surface and an infusible electrode in electric circuit with a source of electric energy capable of creating an arc therebetween having an intensity sufficient to fuse the metal at selected portions of said surface and to displace at least some of such fused metal to an adjacent portion of said surface, and alternately making and breaking such arc.
JOHN A. TANSLEY.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 687,612 Davis Nov. 26, 1901 774,491 Pfalzgraf Nov. 8, 1904 2,066,588 Taylor Jan. 5, 1937 2,079,310 Bennett May 4, 1937 2,273,819 Cooke et al Feb. 24, 1942 2,284,351 Wyer May 26, 1942 2,285,583 Jennings et al June 9, 1942 2,314,902 Shepard Mar. 30, 1943
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2909641A (en) * 1958-05-02 1959-10-20 Republic Aviat Corp Tool for electro-shaping
US3071490A (en) * 1959-05-13 1963-01-01 Pevar Maxwell Bond between a base metal and a sprayed-on metal layer
US3102948A (en) * 1961-11-08 1963-09-03 William M Mccampbell Electric arc welding
US3460246A (en) * 1965-09-10 1969-08-12 Resinite Corp Coil form method of manufacture
US3995845A (en) * 1972-12-26 1976-12-07 Rca Corporation Ultrasonic wire bonding chuck
FR2467285A1 (en) * 1979-10-12 1981-04-17 Gen Electric
EP0196306A4 (en) * 1984-09-21 1986-12-16 Gen Electric Alternating segment ring structure.
EP0633327A1 (en) * 1993-07-10 1995-01-11 PTG PLASMA-OBERFLÄCHENTECHNIK GmbH Process for coating household and kitchen utensils
DE10057187A1 (en) * 2000-11-17 2002-05-23 Alstom Switzerland Ltd Manufacturing compound structures of metallic and non-metallic materials involves adhesive layer of individual weld/anchor points produced by especially light arc weld process

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US687612A (en) * 1901-09-27 1901-11-26 Cleland Davis Process of cementing iron or steel.
US774491A (en) * 1903-12-16 1904-11-08 Charles F Pfalzgraf Enameling metal.
US2066588A (en) * 1933-02-15 1937-01-05 Kapeila Ltd Method and apparatus for electrical etching
US2079310A (en) * 1933-10-31 1937-05-04 Joseph W Piercy Mechanism for producing printing plates by electric arcs
US2273819A (en) * 1940-01-01 1942-02-24 Kapella Ltd Apparatus for electrically etching metallic articles
US2284351A (en) * 1938-08-17 1942-05-26 Gen Electric Electric deseaming
US2285583A (en) * 1940-04-13 1942-06-09 Westinghouse Electric & Mfg Co Surface preparation of bearings for babbitting
US2314902A (en) * 1940-04-16 1943-03-30 Metallizing Engineering Compan Method for causing sprayed metal to adhere to metal surfaces

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US687612A (en) * 1901-09-27 1901-11-26 Cleland Davis Process of cementing iron or steel.
US774491A (en) * 1903-12-16 1904-11-08 Charles F Pfalzgraf Enameling metal.
US2066588A (en) * 1933-02-15 1937-01-05 Kapeila Ltd Method and apparatus for electrical etching
US2079310A (en) * 1933-10-31 1937-05-04 Joseph W Piercy Mechanism for producing printing plates by electric arcs
US2284351A (en) * 1938-08-17 1942-05-26 Gen Electric Electric deseaming
US2273819A (en) * 1940-01-01 1942-02-24 Kapella Ltd Apparatus for electrically etching metallic articles
US2285583A (en) * 1940-04-13 1942-06-09 Westinghouse Electric & Mfg Co Surface preparation of bearings for babbitting
US2314902A (en) * 1940-04-16 1943-03-30 Metallizing Engineering Compan Method for causing sprayed metal to adhere to metal surfaces

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2909641A (en) * 1958-05-02 1959-10-20 Republic Aviat Corp Tool for electro-shaping
US3071490A (en) * 1959-05-13 1963-01-01 Pevar Maxwell Bond between a base metal and a sprayed-on metal layer
US3102948A (en) * 1961-11-08 1963-09-03 William M Mccampbell Electric arc welding
US3460246A (en) * 1965-09-10 1969-08-12 Resinite Corp Coil form method of manufacture
US3995845A (en) * 1972-12-26 1976-12-07 Rca Corporation Ultrasonic wire bonding chuck
FR2467285A1 (en) * 1979-10-12 1981-04-17 Gen Electric
EP0196306A4 (en) * 1984-09-21 1986-12-16 Gen Electric Alternating segment ring structure.
EP0633327A1 (en) * 1993-07-10 1995-01-11 PTG PLASMA-OBERFLÄCHENTECHNIK GmbH Process for coating household and kitchen utensils
DE10057187A1 (en) * 2000-11-17 2002-05-23 Alstom Switzerland Ltd Manufacturing compound structures of metallic and non-metallic materials involves adhesive layer of individual weld/anchor points produced by especially light arc weld process
DE10057187B4 (en) * 2000-11-17 2011-12-08 Alstom Technology Ltd. Process for the production of composite structures between metallic and non-metallic materials

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