US2223158A - Metallic soap solution - Google Patents
Metallic soap solution Download PDFInfo
- Publication number
- US2223158A US2223158A US220700A US22070038A US2223158A US 2223158 A US2223158 A US 2223158A US 220700 A US220700 A US 220700A US 22070038 A US22070038 A US 22070038A US 2223158 A US2223158 A US 2223158A
- Authority
- US
- United States
- Prior art keywords
- composition
- polyvalent metal
- soaps
- group
- soap
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000008149 soap solution Substances 0.000 title description 7
- 239000000344 soap Substances 0.000 description 55
- 239000000203 mixture Substances 0.000 description 36
- 229910052751 metal Inorganic materials 0.000 description 29
- 239000002184 metal Substances 0.000 description 29
- 239000002904 solvent Substances 0.000 description 25
- 239000000080 wetting agent Substances 0.000 description 17
- 241000158728 Meliaceae Species 0.000 description 14
- 238000004078 waterproofing Methods 0.000 description 14
- 239000007788 liquid Substances 0.000 description 11
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 10
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 8
- 229940063655 aluminum stearate Drugs 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- ZCZLQYAECBEUBH-UHFFFAOYSA-L calcium;octadec-9-enoate Chemical compound [Ca+2].CCCCCCCCC=CCCCCCCCC([O-])=O.CCCCCCCCC=CCCCCCCCC([O-])=O ZCZLQYAECBEUBH-UHFFFAOYSA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- JJCSYJVFIRBCRI-UHFFFAOYSA-K aluminum;hexadecanoate Chemical compound [Al].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O JJCSYJVFIRBCRI-UHFFFAOYSA-K 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 235000015096 spirit Nutrition 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002169 ethanolamines Chemical class 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 125000005608 naphthenic acid group Chemical group 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- -1 such as Substances 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/042—Sulfate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/06—Groups 3 or 13
Definitions
- the invention relates in general to solutions of polyvalent metal soaps and in particular to polyvalent metal soap solutions of high concentration and to correlated improvements in waterproofing and other compositions produced therefrom.
- polyvalent metal soaps also known in the art as metallic soaps
- the waterproofing properties of the polyvalent metal soaps has been fully recognized and their use for this purpose is now well established.
- the most convenient method of applying polyvalent metal soaps to various surfaces is to produce a solution thereof in a solvent therefor.
- Various organic solvents have been used in the preparation of polyvalent metal soapsolution, the more common ones including, among others, the hy drocarbons and their halogenated derivatives. While the foregoing practice has enjoyed some success, many difficulties have been encountered 2 in view of the fact when more than about 2% or 3% of the soap is dissolved in solvent, the resulting mass forms a gel under atmospheric conditions, thus rendering it substantially useless as a coating or waterproofing composition.
- a specific object of the invention is to provide an improved free flowing concentrated polyvalent metal soap solution. 5
- a further object of the invention is to provide ricinoleic, palmitic, etc. acids.
- Another object of the invention is to provide free flowing polyvalentmetal soap solutions containing up to 50% polyvalent metal soap.
- a relatively small proportion of a suitable oil-soluble wetting agent containing an $03 group is used in the process of dissolving polyvalent metal soaps in a suitable organic solvent.
- the quantity of wetting agent used is usually determined by the concentration as well as the fluidity desired in theultimate product. While any suitable oil-soluble wetting agent may be used, the sulfated or sufonated types have been found to be superior, and they are, therefore, preferred.
- the free flowing composition of the invention is particularly adapted.
- wetting agents of the preferred type further provide a desirable plasticizing efi'ect in the deposited coating.
- the expressions solution and dissolving are used so in a broad sense and they are to include dispersions and dispersing respectively,
- the invention accordingly comprises a compoproperties and the relation of components which will be exemplifledin the composition hereinafter described and the scope of the invention will be indicated in the claims.
- any suitable polyvalent metal soap of a. higher fatty or similar acids such as the naphthenic acids
- soaps include, inter alia, the polyvalent metal soaps of fatty acids containing 8 or more carbon atoms, such as the aluminum,v calcium, magnesium, zinc, etc., soaps of stearic, oleic, 'linoleic
- the expression polyvalent metal soap is employed to connote water-insoluble metal soaps of the higher fatty acids containing 8 or-more carbon atoms and like soaps of the naphthenic acids, the latter of which may be obtained synthetically or from the refining of petroleum.
- the aluminum and calcium soaps are thenic acids, naphthalene sulphonic acid, sul-' fated animal and vegetable oils (particularly the anhydrous and salt-free type produced in accordance with the disclosures in copending U. S. patent applications Serial No. 77,761, filed May 4, 1936: Serial No. 160,270, filed August 21, 1937;
- any suitable solvent may be used such as the hydrocarbons or their halogenated derivatives, examples of which include, petroleum spirits, gasolene, toluol, benzol, xylol,
- Oxygen containing solvents such as alcohols, aldehydes, ketones, etc., may also be used in combination with the foregoing type.
- the percentage of polyvalent metal soap present in the final composition may be varied up to 50% depending upon the particular use of the composition.
- the quantity of oil-soluble wetting agent may likewise be varied to obtain the desired properties in the composition. Best results have been obtained by using an amount of the wetting agent within the range of about 1% to 20% by weight of the composition, the quantity used depending, in part, on the quantity of soap included.
- Example I 45 A composition particularly adapted for waterproofing various materials and surfaces may have the following formula:
- Example I 1 Another composition of the invention may have the following formula:
- composition of the invention may be produced from the following constituents:
- anyother suitable oil-soluble wetting agent containing an 80: group or mixture of such agents may be used in lieu of the mahogany soaps specifically illustrated in the foregoing examples.
- other suitable sol. vents or polyvalent metal soaps or appropriate mixtures of solvents and soaps may also be employed.
- the solvent or solvents to be used should be selected according to their boiling point in order to obtain the desired rate of evaporation. In applications where drying is to be effected at atmospheric conditions, solvents having a boiling' point of 150 C. or less is recommended, while higher boiling solvents may be employed when drying is to be carried out under heat and/or under reduced pressure.
- a coating depositedfrom the composition of the invention on paper adds decided transparency thereto and thus yields an ideal and relatively inexpensive method for simultaneouslywaterproofing paper and rendering the same transparent. This is highly advantageous in the preparation of certain grades of wrapping paper. Moreover, the plasticized coating facilitates the sealing of the paper in the wrapping of various articles therein. In the application of the free flowing solution to any surface, anysuitable means known to the art may be resorted to.
- oil-soluble wetting agent containing an 503 group While any suitable oil-soluble wetting agent containing an 503 group is recommended, the use of mahogany soaps is highly preferred.
- the proportions of polyvalent metal soap, oil-soluble wetting agent and solvent may be varied-relative to one another to suit the conditions athand.
- the wetting agent may be added to the solvent or to a gel of polyvalent metal soap in solvent, or'the agent may be distributed throughout the polyvalent metal soap before dissolving or dispersing the same in the solvent.
- a free flowing composition comprising a polyvalent metal soap, an oil-soluble wetting agent containing an S0: group and a liquid solvent for the polyvalent metal soap selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
- a free flowing composition comprising an aluminum soap of a higher fatty acid, an oilsoluble wetting agent containing an $03 group and a liquid solvent for the polyvalent metal soap selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
- a free flowing composition comprising an aluminum soap of a higher fatty acid, an oilsoluble wetting agent containing an S03 group and a liquid solvent for the aluminum soap selected from the group consisting of aromatic hydro carbons, aliphatic hydrocarbonsand chlorinated hydrocarbons.
- a free flowing composition comprising aluminum stearate, an oil-soluble wetting agent containing an S: group and a liquid solvent for aluminum stearate selected from the group consist ing of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
- a free flowing composition comprising aluminum palmitate, an oil-soluble wetting agent containing an S0: group and a liquid solvent for aluminum palmitate selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
- a free flowing composition comprising calcium oleate, an oil-soluble wetting agent containing an S0: group and a liquid solvent for calcium oleate selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
- a free flowing waterproofing composition comprising a polyvalent metal soap, mahogany soaps and a liquid solvent for the polyvalent metal soap selected from the group consisting of arcmatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
- a free flowing waterproofing composition comprising an aluminum stearate, mahogany soaps and a liquid solvent for aluminum stearate selected from the group consisting of aromatic selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
- A'free flowing waterproofing composition comprising a calcium oleate, mahogany soaps and a liquid solvent for calcium oleate selected from the group consisting of aromatic hydrocarbons,
- a free flowing waterproofing composition comprising a polyvalent metal soap, mahogany soaps and toluol.
- a free flowing waterproofing composition comprising an aluminum stearate, mahogany soaps and toluol.
- a free flowing waterprooflng'composition comprising an aluminum stearate, mahogany soaps and petroleum spirits.
- a free flowing waterproofing composition comprising an aluminum stearate, mahogany soaps and carbon tetrachloride.
- a free flowing waterproofing composition comprising a polyvalent metal soap, mahogany soaps and a liquid solvent for the polyvalent metal soap selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated. hydrocarbons, the polyvalent metal soap comprising 3% to 50% of the composition.
- a free flowing waterproofing composition comprising an aluminum soap, mahogany soaps and a liquid solvent for the aluminum soap selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons, the aluminum soap comprising 3% to 50% of the composition.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Textile Engineering (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Description
' Patented Nov. 26,1940
UNITED STATES IHETALLIC SOAP SOLUTION Francis J. Licata, New York, N. Y., and Joseph P. Nothm Elizabeth, N. 1.; assignors to National Oil Products Company, Harrison, N. .L, a corporation of New'Jersey No Drawing. Application July 22, 1938, Serial No. 220.700
. 16 Claims. ((1134-11 The invention relates in general to solutions of polyvalent metal soaps and in particular to polyvalent metal soap solutions of high concentration and to correlated improvements in waterproofing and other compositions produced therefrom.
The waterproofing properties of the polyvalent metal soaps, also known in the art as metallic soaps, has been fully recognized and their use for this purpose is now well established. The most convenient method of applying polyvalent metal soaps to various surfaces is to produce a solution thereof in a solvent therefor. Various organic solvents have been used in the preparation of polyvalent metal soapsolution, the more common ones including, among others, the hy drocarbons and their halogenated derivatives. While the foregoing practice has enjoyed some success, many difficulties have been encountered 2 in view of the fact when more than about 2% or 3% of the soap is dissolved in solvent, the resulting mass forms a gel under atmospheric conditions, thus rendering it substantially useless as a coating or waterproofing composition. While the 25 gel can be heated to render it somewhat fluid, the application thereof in a heated state is entirely unsatisfactory for most purposes. The application of solutions containing from 2% to 3% polyvalent metal soap is also highly impractical 30 in view of the diluteness of the solution. Moreover, the cost is high due to the large amounts of solvent necessary.
Various proposals have been .ofiered in an atsition of matter possessing the characteristics,
tempt to solve the foregoing problem by increas- 35 ing the soap concentration without affecting the fluidity of the resulting solution. Peptizlng agents such as acetic acid, phenol, tartaric acid, oxalic acid and the like have been used to increase the soap concentration in a solvent mixture without affecting the fluidity thereof. This proposal has proven to be highly undesirable commercially in view of the corrosive character imparted to the composition by such acidic agents. Another proposal includes the use of the ethanolamines or the ethanolamine salts of the higher fatty acids for the purpose of increasing the con centration of polyvalent metal soap solutions. A solution produced according to this teaching also has its drawbacks. The general object of the invention is to obviate the foregoing and other disadvantages.
A specific object of the invention is to provide an improved free flowing concentrated polyvalent metal soap solution. 5 A further object of the invention is to provide ricinoleic, palmitic, etc. acids.
an improved coating and waterproofing composition.
Another object of the invention is to provide free flowing polyvalentmetal soap solutions containing up to 50% polyvalent metal soap.
Other objects will in part appear obvious and 5 will in part appear hereinafter.
-It has now been found that the foregoing and other objects of the invention may be achieved by the use of suitable oil-soluble wetting agents. According to the invention a relatively small proportion of a suitable oil-soluble wetting agent containing an $03 group is used in the process of dissolving polyvalent metal soaps in a suitable organic solvent. The quantity of wetting agent used is usually determined by the concentration as well as the fluidity desired in theultimate product. While any suitable oil-soluble wetting agent may be used, the sulfated or sufonated types have been found to be superior, and they are, therefore, preferred. The free flowing composition of the invention is particularly adapted. for use in coating and'waterprooflng paper, textiles, leather and other similar materials, and particularly in the waterproofing of building materials, such as, stone, concrete, bricks, wood and the like. It has been found that the wetting agents of the preferred type further provide a desirable plasticizing efi'ect in the deposited coating. The expressions solution and dissolving are used so in a broad sense and they are to include dispersions and dispersing respectively,
The invention accordingly comprises a compoproperties and the relation of components which will be exemplifledin the composition hereinafter described and the scope of the invention will be indicated in the claims.
In the preparation of the composition of the invention, any suitable polyvalent metal soap of a. higher fatty or similar acids, such as the naphthenic acids, may be employed. Examples of such soaps include, inter alia, the polyvalent metal soaps of fatty acids containing 8 or more carbon atoms, such as the aluminum,v calcium, magnesium, zinc, etc., soaps of stearic, oleic, 'linoleic, The expression polyvalent metal soap is employed to connote water-insoluble metal soaps of the higher fatty acids containing 8 or-more carbon atoms and like soaps of the naphthenic acids, the latter of which may be obtained synthetically or from the refining of petroleum. While any suitable polyvalent metal soap may be used in accordance with the invention, the aluminum and calcium soaps are thenic acids, naphthalene sulphonic acid, sul-' fated animal and vegetable oils (particularly the anhydrous and salt-free type produced in accordance with the disclosures in copending U. S. patent applications Serial No. 77,761, filed May 4, 1936: Serial No. 160,270, filed August 21, 1937;
and Serial No. 197,858, filed March 24, 1938.
As for the vehicle, any suitable solvent may be used such as the hydrocarbons or their halogenated derivatives, examples of which include, petroleum spirits, gasolene, toluol, benzol, xylol,
terpenes, carbon tetrachloride, trichloroethane,
etc. Oxygen containing solvents, such as alcohols, aldehydes, ketones, etc., may also be used in combination with the foregoing type.
The percentage of polyvalent metal soap present in the final composition may be varied up to 50% depending upon the particular use of the composition. Moreover, the quantity of oil-soluble wetting agent may likewise be varied to obtain the desired properties in the composition. Best results have been obtained by using an amount of the wetting agent within the range of about 1% to 20% by weight of the composition, the quantity used depending, in part, on the quantity of soap included.
For a fuller understanding of the nature and objects of the invention, reference should be had to the following examples which are given mere- 0 1y to further illustrate the invention and are not to be construed in'a limiting snse, all parts given being by weight:
Example I 45 A composition particularly adapted for waterproofing various materials and surfaces may have the following formula:
' Parts Aluminum stearate 30 Mahogany soaps 8 Toluol 62 60 Example I 1 Another composition of the invention may have the following formula:
' Parts $35 Aluminum palmitate 25 Mahogany soaps 6 Petroleum spirits 69 Example 111 Still another composition of the invention may be produced from the following constituents:
Parts Aluminum steara'te 20 Mahogany soaps 3 75 Carbon tetrachloride 77 Itis obvious that anyother suitable oil-soluble wetting agent containing an 80: group or mixture of such agents may be used in lieu of the mahogany soaps specifically illustrated in the foregoing examples. Likewise, other suitable sol. vents or polyvalent metal soaps or appropriate mixtures of solvents and soaps may also be employed. The solvent or solvents to be used should be selected according to their boiling point in order to obtain the desired rate of evaporation. In applications where drying is to be effected at atmospheric conditions, solvents having a boiling' point of 150 C. or less is recommended, while higher boiling solvents may be employed when drying is to be carried out under heat and/or under reduced pressure.
A coating depositedfrom the composition of the invention on paper adds decided transparency thereto and thus yields an ideal and relatively inexpensive method for simultaneouslywaterproofing paper and rendering the same transparent. This is highly advantageous in the preparation of certain grades of wrapping paper. Moreover, the plasticized coating facilitates the sealing of the paper in the wrapping of various articles therein. In the application of the free flowing solution to any surface, anysuitable means known to the art may be resorted to.
While any suitable oil-soluble wetting agent containing an 503 group is recommended, the use of mahogany soaps is highly preferred. The proportions of polyvalent metal soap, oil-soluble wetting agent and solvent may be varied-relative to one another to suit the conditions athand.
Inpreparing the free flowing solution, the wetting agent may be added to the solvent or to a gel of polyvalent metal soap in solvent, or'the agent may be distributed throughout the polyvalent metal soap before dissolving or dispersing the same in the solvent.
This application is a continuation-impart of our U. S. application SerialNo. 117,018, filed December 21, 1936.
Since certain changes may be made in the above composition of matter and different embodiments of the invention could be made without departing from its scope, it is intended that all matter contained in the above description shall be interpreted as illustrative and not in a limiting sense.
It is also to be understood that the following claims are intended to cover all the generic and Y specific features of the invention herein. described and all statements of the scope of the invention,
which as a matter of language might be said to' fall therebetween; and that they are intended to be inclusive in scope and not exclusive, in that if desired, other materials may be added to our novel composition of matter herein claimed without departing from the spirit of the invention. Particularly, it is to be understood that in said claims, ingredients or components recited in the singular are intended to include compatible mixtuires of said ingredients wherever the sense perm s.
' Having described our invention, what we claim as new and desire to secure by Letters Patent is: 1. A free flowing composition comprising a polyvalent metal soap, an oil-soluble wetting agent containing an S0: group and a liquid solvent for the polyvalent metal soap selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
2. A free flowing composition comprising an aluminum soap of a higher fatty acid, an oilsoluble wetting agent containing an $03 group and a liquid solvent for the polyvalent metal soap selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
3. A free flowing composition comprising an aluminum soap of a higher fatty acid, an oilsoluble wetting agent containing an S03 group and a liquid solvent for the aluminum soap selected from the group consisting of aromatic hydro carbons, aliphatic hydrocarbonsand chlorinated hydrocarbons.
4. A free flowing composition comprising aluminum stearate, an oil-soluble wetting agent containing an S: group and a liquid solvent for aluminum stearate selected from the group consist ing of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
5. A free flowing composition comprising aluminum palmitate, an oil-soluble wetting agent containing an S0: group and a liquid solvent for aluminum palmitate selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
6. A free flowing composition comprising calcium oleate, an oil-soluble wetting agent containing an S0: group and a liquid solvent for calcium oleate selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
7. A free flowing waterproofing composition comprising a polyvalent metal soap, mahogany soaps and a liquid solvent for the polyvalent metal soap selected from the group consisting of arcmatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons. V
8. A free flowing waterproofing composition 'comprising an aluminum stearate, mahogany soaps and a liquid solvent for aluminum stearate selected from the group consisting of aromatic selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons.
10. A'free flowing waterproofing composition comprising a calcium oleate, mahogany soaps and a liquid solvent for calcium oleate selected from the group consisting of aromatic hydrocarbons,
aliphatic hydrocarbons and chlorinated hydrocarbOnS. r 4
11. A free flowing waterproofing composition comprising a polyvalent metal soap, mahogany soaps and toluol. v
12. A free flowing waterproofing composition comprising an aluminum stearate, mahogany soaps and toluol.
13. A free flowing waterprooflng'composition comprising an aluminum stearate, mahogany soaps and petroleum spirits.
14. A free flowing waterproofing composition comprising an aluminum stearate, mahogany soaps and carbon tetrachloride.
15. A free flowing waterproofing composition comprising a polyvalent metal soap, mahogany soaps and a liquid solvent for the polyvalent metal soap selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated. hydrocarbons, the polyvalent metal soap comprising 3% to 50% of the composition.
16. A free flowing waterproofing composition comprising an aluminum soap, mahogany soaps and a liquid solvent for the aluminum soap selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons and chlorinated hydrocarbons, the aluminum soap comprising 3% to 50% of the composition. I
- FRANCIS J. LICATA.
JOSEPH P. NOTHUM.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US220700A US2223158A (en) | 1938-07-22 | 1938-07-22 | Metallic soap solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US220700A US2223158A (en) | 1938-07-22 | 1938-07-22 | Metallic soap solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2223158A true US2223158A (en) | 1940-11-26 |
Family
ID=22824592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US220700A Expired - Lifetime US2223158A (en) | 1938-07-22 | 1938-07-22 | Metallic soap solution |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2223158A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2442972A (en) * | 1941-01-23 | 1948-06-08 | Sidney M Edelstein | Aqueous dispersions of electropositive materials |
| US2785989A (en) * | 1954-03-29 | 1957-03-19 | American Cyanamid Co | Metallic soaps of fatty acids and polyhydroxy monocarboxylic acids |
| US2793132A (en) * | 1954-03-29 | 1957-05-21 | American Cyanamid Co | Metallic soaps of fatty acids and alphahydroxy alkanoic acids |
| US2952555A (en) * | 1957-09-16 | 1960-09-13 | Ales M Kapral | Coating compositions |
| US3039895A (en) * | 1960-03-29 | 1962-06-19 | Du Pont | Textile |
| US3523034A (en) * | 1968-02-05 | 1970-08-04 | Soo Valley Co | Fly fishing line with water-repellent preservative dressing |
| US3535155A (en) * | 1967-06-22 | 1970-10-20 | Exxon Research Engineering Co | Oil impregnated papers |
| US3544362A (en) * | 1967-03-29 | 1970-12-01 | Pfersee Chem Fab | Process for improving the delustering and the slipping resistance of textiles |
| US4296174A (en) * | 1980-08-08 | 1981-10-20 | E. I. Du Pont De Nemours And Company | Spandex filaments containing certain metallic soaps |
| US20090263656A1 (en) * | 2006-10-11 | 2009-10-22 | Byung-Joon Chae | Organic-inorganic hybrid structures having nanoparticles adhering thereon and method for preparing the same |
-
1938
- 1938-07-22 US US220700A patent/US2223158A/en not_active Expired - Lifetime
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2442972A (en) * | 1941-01-23 | 1948-06-08 | Sidney M Edelstein | Aqueous dispersions of electropositive materials |
| US2785989A (en) * | 1954-03-29 | 1957-03-19 | American Cyanamid Co | Metallic soaps of fatty acids and polyhydroxy monocarboxylic acids |
| US2793132A (en) * | 1954-03-29 | 1957-05-21 | American Cyanamid Co | Metallic soaps of fatty acids and alphahydroxy alkanoic acids |
| US2952555A (en) * | 1957-09-16 | 1960-09-13 | Ales M Kapral | Coating compositions |
| US3039895A (en) * | 1960-03-29 | 1962-06-19 | Du Pont | Textile |
| US3544362A (en) * | 1967-03-29 | 1970-12-01 | Pfersee Chem Fab | Process for improving the delustering and the slipping resistance of textiles |
| US3535155A (en) * | 1967-06-22 | 1970-10-20 | Exxon Research Engineering Co | Oil impregnated papers |
| US3523034A (en) * | 1968-02-05 | 1970-08-04 | Soo Valley Co | Fly fishing line with water-repellent preservative dressing |
| US4296174A (en) * | 1980-08-08 | 1981-10-20 | E. I. Du Pont De Nemours And Company | Spandex filaments containing certain metallic soaps |
| US20090263656A1 (en) * | 2006-10-11 | 2009-10-22 | Byung-Joon Chae | Organic-inorganic hybrid structures having nanoparticles adhering thereon and method for preparing the same |
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