US2136205A - Blasting powder - Google Patents
Blasting powder Download PDFInfo
- Publication number
- US2136205A US2136205A US174694A US17469437A US2136205A US 2136205 A US2136205 A US 2136205A US 174694 A US174694 A US 174694A US 17469437 A US17469437 A US 17469437A US 2136205 A US2136205 A US 2136205A
- Authority
- US
- United States
- Prior art keywords
- powder
- explosive
- nitrate
- blasting
- blasting powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000843 powder Substances 0.000 title description 22
- 238000005422 blasting Methods 0.000 title description 15
- 239000002360 explosive Substances 0.000 description 15
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 13
- 239000008188 pellet Substances 0.000 description 11
- 229910002651 NO3 Inorganic materials 0.000 description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 235000010344 sodium nitrate Nutrition 0.000 description 5
- 239000004317 sodium nitrate Substances 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- 239000003517 fume Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000011872 intimate mixture Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 230000001464 adherent effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- RVCKCEDKBVEEHL-UHFFFAOYSA-N 2,3,4,5,6-pentachlorobenzyl alcohol Chemical compound OCC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl RVCKCEDKBVEEHL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229960003711 glyceryl trinitrate Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- -1 trimethylal-ethyl-methane-trinitrate Chemical compound 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/18—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component
- C06B45/30—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component
- C06B45/32—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component the coating containing an organic compound
- C06B45/34—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component the coating containing an organic compound the compound being an organic explosive or an organic thermic component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S149/00—Explosive and thermic compositions or charges
- Y10S149/11—Particle size of a component
- Y10S149/112—Inorganic nitrogen-oxygen salt
Definitions
- This invention relates to blasting powder and has for its object an improvement in explosive compositions suitable for general blasting purposes which will have important advantages over i black powder.
- my improved powder over blasting powder may be mentioned a lesser density with same heave or moving power, greater rate of decomposition upon explosion, more resistant to water or moisture, much less subject to ignition from shock or friction, not subject to ignition from contact with ordinary flame, no poisonous fumes, and with all cheaper and quicker to manufacture.
- my improved blasting powder may be said to comprise a loose mass of sodium nitrate kernels, each of which is entirely enveloped by an adherent layer of explosive agents adapted to form a substantially balanced fortified and sensitized entity complete itself, and exhibiting all of the characteristics above enumerated.
- My improved blasting powder consists of the following ingredients:
- the finer mesh pellets are employed where increased rate of combustion or greater brisance in the blasting powder is desired, and vice versa.
- This pelleted sodium nitrate is placed in a suitable tumbler or inclined rotating pellet coating bowl, and while under rotation the liquid nitro body (preferably D. N. T. or M. N. T., T. N. T.) is added to the revolving and rolling mass, preferably in the form of a fine spray to form a slightly sticky film of this explosive material about each pellet of the nitrate.
- the liquid nitro body preferably D. N. T. or M. N. T., T. N. T.
- the coating of the nitrate pellets as described should be carried out at a temperature sufficiently 15 above the setting point of the particular liquifiable nitro body being used so that this binding agent will remain in fluid condition until the completion of the coating operation.
- nitro bodies instead of the particular nitro bodies set out, others such as the nitro glycerine, benzenes, naphthalenes, etc. may be used, but those given in the formula are preferred.
- the specific nitrate or perchlorate and oxidizable metal used as the coating layer may be varied within the knowledge of explosive engineers, but after my experiments I feel that the above simple formula will meet all requirements in a blasting powder of this kind, though any such modifications as suggestedare intended to be included in the scope of my appended claims.
- the safety of my improved blasting powder over black powder is particularly outstanding in ignition tests, for not only does the improved powder withstand ignition from ordinary flame contact, such for instance as burning a box of matches on top of a pile of it, but it will not ignite if a teaspoonful of black powder is placed on top of a pile of it and the black powder ignited.
- a blasting powder comprising a loose mass of pellets having a sodium nitrate center coated with a viscous film of an explosive nitric ester liquefiable at moderate temperatures forming a araaecs binder holding an outer layer of an intimate mixture of powdered ammonium nitrate, potassium perchlorate and powdered aluminum, so as to make each pellet a complete explosive unit.
- a blasting powder comprising a loose mass of pellets having a sodium nitrate center coated with .a. viscous film of an explosive nitric ester liquefiable at moderate temperature forming a binder holding an outer layer of an intimate mixture of a finely divided explosive including a nitrate salt, a perchlorate, and an easily oxidizable metal.
- a blasting powder comprising a loose mass of substantially uniform size pellets having a sodium nitrate center coated with a viscous film of an explosive nitric ester liquefiable at moderate temperatures forming a binder holding an outer layer of an intimate mixture of a finely divided explosive including an oxygen yielding salt, and an easily oxidizable metal.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Chemistry (AREA)
- Disintegrating Or Milling (AREA)
Description
Patented Nov. 8, 1938 UNETED STATES PATNT OFFCE BLASTIN G POWDER Land 8. Byers,
Glendale, Calif.
3 Claims.
This invention relates to blasting powder and has for its object an improvement in explosive compositions suitable for general blasting purposes which will have important advantages over i black powder.
Among the advantages of my improved powder over blasting powder may be mentioned a lesser density with same heave or moving power, greater rate of decomposition upon explosion, more resistant to water or moisture, much less subject to ignition from shock or friction, not subject to ignition from contact with ordinary flame, no poisonous fumes, and with all cheaper and quicker to manufacture.
Briefly described my improved blasting powder may be said to comprise a loose mass of sodium nitrate kernels, each of which is entirely enveloped by an adherent layer of explosive agents adapted to form a substantially balanced fortified and sensitized entity complete itself, and exhibiting all of the characteristics above enumerated.
My improved blasting powder consists of the following ingredients:
Percent by weight 5 Pelleted sodium nitrate 90 to 80 A liquid nitro body (liquifiable at modcrate temperatures) 3 to 6 Ammonium nitrate 3 to 6 Potassium perchlorate 3 to 6 Powdered aluminum l to 2 (1) Minus 6 mesh, plus 8 mesh (2) Minus 8 mesh, plus 10 mesh (3) Minus 10 mesh, plus 12 mesh,
and so on up to minus 36 mesh, plus 40 mesh.
The finer mesh pellets are employed where increased rate of combustion or greater brisance in the blasting powder is desired, and vice versa.
This pelleted sodium nitrate is placed in a suitable tumbler or inclined rotating pellet coating bowl, and while under rotation the liquid nitro body (preferably D. N. T. or M. N. T., T. N. T.) is added to the revolving and rolling mass, preferably in the form of a fine spray to form a slightly sticky film of this explosive material about each pellet of the nitrate.
As soon as the nitrate pellets are evenly coated the previously finely powdered and intimately 5 mixed remaining ingredients are dusted in while the rolling is continued until each individual sodium nitrate pellet is completely enveloped and enclosed in a layer of the thoroughly mixed powdered ingredients evenly distributed thereover, and bound thereto so as to form a substantially dry granular mass each grain of which is a complete explosive unit.
The coating of the nitrate pellets as described should be carried out at a temperature sufficiently 15 above the setting point of the particular liquifiable nitro body being used so that this binding agent will remain in fluid condition until the completion of the coating operation.
Instead of the particular nitro bodies set out, others such as the nitro glycerine, benzenes, naphthalenes, etc. may be used, but those given in the formula are preferred.
Also, the specific nitrate or perchlorate and oxidizable metal used as the coating layer may be varied within the knowledge of explosive engineers, but after my experiments I feel that the above simple formula will meet all requirements in a blasting powder of this kind, though any such modifications as suggestedare intended to be included in the scope of my appended claims.
' I am aware of pelleted nitrate of sodium as such being used in explosives of the dynamite class, also the coating of ammonium nitrate pellets with trimethylal-ethyl-methane-trinitrate, and also with other substances, but I am not aware of a blasting powder being heretofore produced in which each granule is a complete explosive unit in itself formed of a central kernel of sodium nitrate entirely enclosed in the fortifying, sen- 40 sitizing and flame supporting agents in even dissemination and in adherent relation about its surface in proportions to make of each a substantially balanced explosive unit. Nor do I know of any comparable powder no matter of what constituted which has all of the valuable properties in comparison with black powder, as above set out.
Percussion tests of my improved blasting powder as above described, made under Bureau of Explosives requirements, Falling weight test, gave zero results with the 8 pound weight and 7 inch drop (steel on steel anvil) and actually required in excess of a 12 inch drop before explosion could be induced.
Similarly, frictional impact tests as per Bureau of Mines requirements Anvil friction test, both with the fiber and steel shoe, produced neither explosion, nor ignition-in fact no distinguishable crackling, and furthermore Bureau of Mines tests for fumes reported Poisonous fumes nil.
The safety of my improved blasting powder over black powder is particularly outstanding in ignition tests, for not only does the improved powder withstand ignition from ordinary flame contact, such for instance as burning a box of matches on top of a pile of it, but it will not ignite if a teaspoonful of black powder is placed on top of a pile of it and the black powder ignited.
Having thus described my improved blasting composition, what I claim is:
1. A blasting powder comprising a loose mass of pellets having a sodium nitrate center coated with a viscous film of an explosive nitric ester liquefiable at moderate temperatures forming a araaecs binder holding an outer layer of an intimate mixture of powdered ammonium nitrate, potassium perchlorate and powdered aluminum, so as to make each pellet a complete explosive unit.
2. A blasting powder comprising a loose mass of pellets having a sodium nitrate center coated with .a. viscous film of an explosive nitric ester liquefiable at moderate temperature forming a binder holding an outer layer of an intimate mixture of a finely divided explosive including a nitrate salt, a perchlorate, and an easily oxidizable metal.
3. A blasting powder comprising a loose mass of substantially uniform size pellets having a sodium nitrate center coated with a viscous film of an explosive nitric ester liquefiable at moderate temperatures forming a binder holding an outer layer of an intimate mixture of a finely divided explosive including an oxygen yielding salt, and an easily oxidizable metal.
LAUD S. BYERS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US174694A US2136205A (en) | 1937-11-15 | 1937-11-15 | Blasting powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US174694A US2136205A (en) | 1937-11-15 | 1937-11-15 | Blasting powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2136205A true US2136205A (en) | 1938-11-08 |
Family
ID=22637142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US174694A Expired - Lifetime US2136205A (en) | 1937-11-15 | 1937-11-15 | Blasting powder |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2136205A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE938594C (en) * | 1953-04-13 | 1956-02-02 | Dynamit Nobel Ag | Process for the production of explosives with an arbitrarily increased shelf life |
| US3118796A (en) * | 1959-06-05 | 1964-01-21 | Lawrence D Colburn | Trilaminar explosive composition and method of preparation |
| US3356545A (en) * | 1965-07-20 | 1967-12-05 | Hercules Inc | Aqueousslurry type nitrocarbonitrate blasting compositions containing flake aluminum-dinitro-toluene as the only sensitizer |
-
1937
- 1937-11-15 US US174694A patent/US2136205A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE938594C (en) * | 1953-04-13 | 1956-02-02 | Dynamit Nobel Ag | Process for the production of explosives with an arbitrarily increased shelf life |
| US3118796A (en) * | 1959-06-05 | 1964-01-21 | Lawrence D Colburn | Trilaminar explosive composition and method of preparation |
| US3356545A (en) * | 1965-07-20 | 1967-12-05 | Hercules Inc | Aqueousslurry type nitrocarbonitrate blasting compositions containing flake aluminum-dinitro-toluene as the only sensitizer |
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