US2189395A - Insulated conductor and a method of making the same - Google Patents

Description

Feb. 6, 1940. A. N. GRAY 2,189,395

INSULATED CONDUCTOR AND A METHOD OF MAKING THE SAME Filed April 14, 1937 WIRE RUBBER COMPOUND PA RA FF/N l/VVENTOR A TTORNEY Patented Feb. 6, 1 940 UNITED STATES PATENT OFFICE INSULATED CONDUCTOR AND A METHOD OF MAKING THE SAME Alvin N. Gray Baltimore,

Md, assignor to Application April 14, 1931, Serial No. 130,712

6Claims.

The invention relates to insulated conductors and a method of making the same and more particularly to rubber insulated wire and a method of making it.

I Metallic wire with an electrically insulating sheathing may be made by extruding a seamless sheath of suitable plastic insulating material over a wire. When the'insulation is a compound of rubber or the like vulcanizable or otherwise 10 heat-hardenable material and it is desired to produce a sheath or coating of considerable thickness, attempts have been made to produce the desired result by applying the coating material in two or more successive layers, each of which is vulcanized or hardened individually to avoid dimculties which may arise when attempt is made to harden a single thick layer of material which is by nature heat insulating as well as electrically insulating. However, in the extru- 10 sion of a second sheath over a preformed and vulcanized or cured sheath, difllculties may arise from the frictional resistance of the sheathed wire to passage through the coating apparatus, from unsatisfactory adhesion of the second I sheath to the first, from reduction of dielectric strength of the insulation by lubricants attempted to be used, and other like causes.

It has been found that, in the case of insulation consisting of a vulcanizable mixture com- N prising rubber, if a coating of paraflin, preferably hot, be applied to a sheathed conductor prior to the extrusion of a second sheath thereon of like material, the parafllned coated core passes freely through the extrusion apparatus, the sec- I 0nd coating of rubber material adheres tightly to the first and forms a substantially integral mass therewith, and also that the wire thus coated has an insulation resistance which may be as much as three times that of a wire coated do with an equal thickness of the same insulation in one operation.

An object of the invention is to provide an insulated electrical conductor having an insulating sheath thereon of improved mechanical I and electrical properties, and to provide a method of making such conductors.

One embodiment of the invention contemplates an insulated electrical conductor comprising a conductor strand and a sheath thereon consisting of two or more layers of vulcanized rubber material adhered together by paraflln; and a method of making such conductors in which paraflin is applied to rubber covered wire and a second sheath of rubber material is extruded ll over and cured on such paraflin coated core.

Other objects and features of the invention will appear from the following detailed description of one embodiment thereof taken in connection with the accompanying drawing in which the single figure is a broken view in side eleva- I: tion of a portion of electrical conductor embodying the invention.

In the embodiment of the invention herein disclosed an insulated electrical conductor generally indicated at comprises a core strand 2| 10: of metal, which may be a solid individual wire as shown, or may be made up of a plurality of finer wires intertwisted or interbraided together. Over the core 2| is a sheath 22 of heat hardened or vulcanized material such as one of the many minutely varying vulcanizable mixtures containing rubber. Over the sheath 22 is a second sheath 23 of the same or like material. Both sheaths 22 and 23 are in a substantially completely cured or vulcanized state. Between the two sheaths 22 and 23 or. more accurately described. at the interface 25 of union between the two sheaths and intermingled with their substance in the neighborhood of their interface of union is a layer 24 comprising material from 25 both sheaths containing paraffin or the like.

This layer or circumferential region 24 is only diagrammatically shown in the drawing, of ne-' cessity. It is originally applied as a dip, spray or other form of coating over the preformed and 80 precured coating 22, and the sheath 23 is formed and cured on the paraflin coated sheath 22. However, it is found that in the finished article the two sheaths 22 and 23 have become closely 4 adherent, even quasi-welded to each other, and 88 the paraflln has dissolved into or permeated the compound near the original interface 25 of the sheaths. In effect there is now a single sheath of rubber material containing little or no paraflln at or in the neighborhood of its exterior siu'face 40 26 and its interior surface 21, and containing a maximum of paraflin at and near the site of original interface 25. To make such a conductor, a strand 2| as described above is covered with a sheath of cured 5 rubber material, preferably in an extrusion apparatus such as is familiar in the art, e. g., as disclosed in U. S. Patent 1,689,206 issued October 30, 1928, to Leslie F. Lamplough. The sheathed conductor is then provided with a second sheath of the same or like material in the same or a like machine, but Just prior to being fed into this machine is coated with paraflin. This coating is preferably hot and may be applied in any convenient manner, e. g., it may be painted on 56 by hand with a'brush, sponge, rag or the like, or it may be sprayed or squirted on, or the singly coated wire may be led through a tank or other container of molten parafiin material just before entering the machine in which the second insulating sheath is applied and hardened.

During the passage of the parafiin coated strand into and through the extrusion head of the machine, the parafiin acts as a lubricant. At the same time a part of the paraiiin is absorbed into the rubber sheath. When the material of the second sheath is applied, being hot and under pressure, it absorbs the remainder of the paraflin and comes into direct contactwith the mass of the inner sheath. The two sheaths are not separated by a layer or lamina of paraflin. All the paraffin is absorbed into the material of the two sheaths.

Apparently in some manner not clearly understood, the paraflln assists in the union of the two sheaths at their interface during the extrusion and subsequent heat-hardening of the outer layer, and remains in the double thick sheath thus formed concentrated about the medial zone of the sheath. 7

An essential feature of the invention is the use of a waxy material at 24 which is a lubricant to reduce the friction of the surface 25 of the singly coated strand while passing through the I coating machine to the extrusion point, which is absorbable by or soluble in the hardened material of the layer 22 and in the material of the layer 23, which does not prevent but rather assists in bringing about the close adhesion or union of the layers 22 and 23, and which enhances the insulation resistance of the material of the layers 22 and 23. Paraflin is one material having the requisite properties, the word paraifin here being understood to include the greasy and waxy, heavy members of the saturated open chain hydrocarbons whether thick oils, soft waxes or hard waxes in consistency, such as the heavy oil known commercially as Nujol, the soft waxes or pastes known as petrolatum, and the hard waxes commonly called parafiine, "Superlo wax, etc.

The embodiments of the invention herein disclosed are merely illustrative and may be modified and departed from without departing from the spirit and scope of the invention as pointed out in and limited only by the appended claims.

What is claimed is:

1. A method of making an insulated electrical conductor which comprises forming a sheath of rubber compound on a conductive strand, applying paraflln to the sheath, and forming an adhering second sheath oi rubber compound upon the paraffin treated surface oi the first sheath.

2. A method of making an insulated electrical conductor which comprises extruding and vulcanizing a sheath of rubber compound on a conductive strand, applying parafiln to the sheath, and extruding and vulcanizing a second sheath of rubber compound upon the raraflin treated surface of the first sheath said sheaths being adheringly united.

3. A method of making an insulated electrical conductor which comprises extruding a sheath of rubber compound on a conductive strand, applying hot paraflln to the sheath, and extruding a second sheath of rubber compound upon the hot paraffin treated surface of the first sheath said sheaths being adheringly united.

4. A method of making an insulated electrical conductor which comprises extruding and vulcanizing a sheath of rubber compound on a conductive strand, applying hotparaffin to the sheath, and extruding and vulcanizing a second sheath of rubber compound upon the hot parafiin treated surface of the first sheath said sheaths being adheringly united to form in effect a single sheath. 1

5. An insulated electrical conductor comprising a conductive core, an insulating layer of rubber compound having its surface impregnated with paramn, and a second layer of rubber compound over the first layer and adhered thereto.

6. An insulated electrical conductor comprising a conductive core, an insulating layer of rubber compound on said core, a second layer of rubber compound adheringly united with said first layer, and parafiin contained at the juncture of said layers.

ALVIN N. GRAY.

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