US2143853A - Spark plug - Google Patents
Spark plug Download PDFInfo
- Publication number
- US2143853A US2143853A US46180A US4618035A US2143853A US 2143853 A US2143853 A US 2143853A US 46180 A US46180 A US 46180A US 4618035 A US4618035 A US 4618035A US 2143853 A US2143853 A US 2143853A
- Authority
- US
- United States
- Prior art keywords
- tungsten
- alloy
- spark plug
- electrodeposited
- spindle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001080 W alloy Inorganic materials 0.000 description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 8
- 239000010937 tungsten Substances 0.000 description 8
- 229910000990 Ni alloy Inorganic materials 0.000 description 7
- 229910052721 tungsten Inorganic materials 0.000 description 7
- 229910001362 Ta alloys Inorganic materials 0.000 description 6
- 239000010953 base metal Substances 0.000 description 5
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 5
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- JPNWDVUTVSTKMV-UHFFFAOYSA-N cobalt tungsten Chemical compound [Co].[W] JPNWDVUTVSTKMV-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910000531 Co alloy Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- DZZDTRZOOBJSSG-UHFFFAOYSA-N [Ta].[W] Chemical compound [Ta].[W] DZZDTRZOOBJSSG-UHFFFAOYSA-N 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000003870 refractory metal Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910002058 ternary alloy Inorganic materials 0.000 description 2
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- PVGJRWNHTQDBQK-UHFFFAOYSA-N [W].[Ta].[Ni] Chemical compound [W].[Ta].[Ni] PVGJRWNHTQDBQK-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T13/00—Sparking plugs
- H01T13/20—Sparking plugs characterised by features of the electrodes or insulation
- H01T13/39—Selection of materials for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9265—Special properties
- Y10S428/929—Electrical contact feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12951—Fe-base component
Definitions
- This invention relates to improvements in spark plugs.
- spark plugs may be markedly improved by providing at least the exposed surface of the spark points and spindles with a surface of a refractory metal of high atomic density. More particularly we have found that new improved spark plugs and analogous sparking apparatus may 'be produced by electrodepositing a surface of a tungsten alloy on the metallic parts subjected to the deleterious effects of electrical discharge and/or the high temperature combustion gases.
- An object of the present invention therefore is to produce a novel type of spark plug.
- Another object is to improve the'efiiciency of electrodes which operate under high temperature conditions.
- Yet another object is to prolong the effective life of electrodes subjected to the errosive efiects of electrical discharge at elevated temperatures.
- Still another object is to produce an electrode which is highly resistant to deterioration due to electrical influences under high temperatures.
- the invention comprehends the concept of surfacing such electrodes with an alloy having as one component a heavy refractory metal of the 6th group, such as tungsten or molybdenum.
- the electrode is electroplated with an alloy of tungsten and a, second metal, such as nickel, although it will be understood that other binary tungsten alloys, such as tungsten cobalt, tungsten tantalum and so forth, or ternary alloys, such as tungsten nickel tantalum, may be utilized.
- molybdenum may be used.
- spark plug produced, according to the improved method is illustrated in the single figure of the accompanying drawing.
- Such spark plug may, for example, comprise the usual metallic body I, prepared in the usual manner with a squared portion for the reception of a suitable tool and formed at its lower end with the threaded section 2.
- the insulating material such as the porcelain tube 3.
- this tube is hollow and is adapted to receive the central electrode 4.
- the electrode is threaded at its upper portion and is adapted to receive the knurled nut 6.
- the lower portion of the central spindle projects below the end of the body I in the usual manner and adjacent this is placed one or more sparking points i.
- the central spindle 4 is provided with a surface 8 which consists of a suitable electrodeposited tungsten alloy. If desired, and as shown in the drawing, the sparking point or points 1 may be similarly covered and protected with an alloy surface 9.
- the steel wire from which the central spindle is to be made is suitably cleaned as by brushing, subjection to bars 744,566 and 14,372.
- adense, adherent, chemically resistant electrodeposited plate of a tungsten alloy, such as tungsten nickel is formedon the spindle.
- the composition of the bath and hence the resulting electrodeposited plate 8 may be varied.
- the spindle may first be plated with nickel either in dull or bright form and thereafter a surface of a tungsten alloy may be electrodeposited on the nickel.
- the respective percentages of the components of the alloys may be varied over wide ranges depending upon such factors as the initial ionic concentration of the platable components in the bath, the acidity of the bath, temperature and current density.
- electrodeposited plates of say tungsten and nickel may be produced ranging from five percent be formed on the lower portion of the spindle or on the entire length.
- this surface may comprise a tungsten nickel alloy with varying percentages of the two components or may comprise other binary alloys, such as tungsten cobalt.
- the electrodeposited surface 8 may comprise a tungsten tantalum alloy or a ternary alloy of tungsten, nickel and tantalum. Such surface, for example, may be produced according to the method described in the copending application Serial No. 28,187.
- the sparking point I may be similarly treated.-
- sparking point I may be plated with tungsten nickel, tungsten cobalt, or other binary tungsten or molybdenum alloys and, if desired, the electrodeposited plate on the sparking point 1 may be of an alloy of diflerent characteristics from that plated on the central spindle 4.
- the electrodeposited alloys of tungsten and analogous metals referred to herein are characterized by a smooth and resistant surface and hence considerably reduce the tendency to accumulation of amorphous carbon on the surface.
- a major advantage of the improved spark plug resides in the resistance of the sparking surface to disintegration due to the effect of the electrical discharge accentuated or accelerated under the high temperature conditions obtaining in the cylinder head.
- the electrodes comprising the spark plug present many advantages.
- the ferruginous base of the electrodes provide adequate heat conduction and satisfactory tensile properties.
- the improved electrodeposited surface insures improved electrical characteristics and increased longevity due to the fact that such surface is substantially non-scaling at elevated temperatures and is eminently resistant to erosion under the conditions of electrical discharge at the elevated temperatures obtaining during use.
- a spark plug forinternal combustion motors having sparking elements, said elements having a surface comprising an electrodeposited tungsten alloy, said alloy having a tungsten content of from five to seventy percent.
- a spark plug spindle comprising a metallic base and a surface comprising an electrodeposited alloy of tungsten, said alloy containing from twenty-five percent to fifty percent tungsten.
- a spark plug spindle comprising a metallic ,base and a surface comprising an electrodeposited alloy of tungsten and nickel.
- a spark plug spindle comprising a metallic base and a surface comprising an electrodeposited alloy of tungsten and cobalt.
- a spark plug spindle comprising a fermginous base metal and a surface comprising an electrodeposited alloy of tungsten and tantalum. 6.
- a spark plug spindle comprising a ferruginous base metal and a sparking point which is surfaced with an electrodeposited alloy of tungsten, the alloy containing approximately between thirty and forty percent of tungsten.
- a spark plug spindle comprising a ferruginous base metal and a sparking point which is surfaced with an electrodeposited alloy of tungsten and nickel.
- a spark plug spindle comprising a 'ferruginous base metal and a sparking point' which is surfaced with an electrodeposited alloy of tungsten and cobalt.
- a spark plug spindle comprising a fermginous base metal and a sparking point which is surfaced with an electrodeposited alloy of tungsten and tantalum.
- a spark plug for internal combustion engines comprising a central electrode and an adjacent cooperating spark point, each of which are surfaced with an electrodeposited tungsten nickel alloy.
- a spark plug for internal combustion engines comprising a central electrode and an adjacent cooperating spark point, the electrode being surfaced with an electrodeposited tungsten nickel alloy, the sparking point being surfaced with an electrodeposited tungsten alloy of different characteristics.
- a spark plug electrode comprising a metallic base, which base is surfaced with an electrodeposited alloy of tungsten, tantalum and nickel.
- a spark plug electrode comprising a metallic base, which base is surfaced with an electrodeposited alloy of tungsten, tantalum and co balt.
Landscapes
- Spark Plugs (AREA)
Description
Jan. l 7, 1939. H. H. ARMSTRONG ET AL 2,143,353
SPARK PLUG Filed Oct. 22, 1955 9m WJ V 5% M Patented Jan. 17, 1939 UNITED STATES PATENT OFFICE SPARK PLUG Application October 22, 1935, Serial No. 46,180
13 Claims.
This invention relates to improvements in spark plugs.
As is known, the conditions to which a spark plug is subjected during use impose difllcultably obtainable criteria for the several elements, particularly for the central spindle or electrode. This element, in addition to possessing good thermal conductivity and requisite tensile strength, should be of such a character as to resist the errosive action of electrical discharge, accentuated as it is in this case by the high temperature conditions obtaining in the cylinder head. The metal of the electrode furthermore should present minimal tendency to scaling and pitting. These properties are not present to any considerable degree in the typical steel spindle and sparking points generally employed.
We have found that the operative characteristics of spark plugs may be markedly improved by providing at least the exposed surface of the spark points and spindles with a surface of a refractory metal of high atomic density. More particularly we have found that new improved spark plugs and analogous sparking apparatus may 'be produced by electrodepositing a surface of a tungsten alloy on the metallic parts subjected to the deleterious effects of electrical discharge and/or the high temperature combustion gases.
An object of the present invention therefore is to produce a novel type of spark plug.
Another object is to improve the'efiiciency of electrodes which operate under high temperature conditions.
Yet another object is to prolong the effective life of electrodes subjected to the errosive efiects of electrical discharge at elevated temperatures.
Still another object is to produce an electrode which is highly resistant to deterioration due to electrical influences under high temperatures.
With these and other equally important and related objects in view, the invention comprehends the concept of surfacing such electrodes with an alloy having as one component a heavy refractory metal of the 6th group, such as tungsten or molybdenum. In the preferred method the electrode is electroplated with an alloy of tungsten and a, second metal, such as nickel, although it will be understood that other binary tungsten alloys, such as tungsten cobalt, tungsten tantalum and so forth, or ternary alloys, such as tungsten nickel tantalum, may be utilized. Similarly, as will appear more fully hereinafter, in lieu of or in combination with tungsten, molybdenum may be used.
In order to more readily describe the invention a spark plug produced, according to the improved method is illustrated in the single figure of the accompanying drawing. Such spark plug may, for example, comprise the usual metallic body I, prepared in the usual manner with a squared portion for the reception of a suitable tool and formed at its lower end with the threaded section 2. Mounted within the body, in the usual manner, is the insulating material, such as the porcelain tube 3. As is known, this tube is hollow and is adapted to receive the central electrode 4. The electrode is threaded at its upper portion and is adapted to receive the knurled nut 6. The lower portion of the central spindle projects below the end of the body I in the usual manner and adjacent this is placed one or more sparking points i.
In accordance with the present invention the central spindle 4 is provided with a surface 8 which consists of a suitable electrodeposited tungsten alloy. If desired, and as shown in the drawing, the sparking point or points 1 may be similarly covered and protected with an alloy surface 9.
In carrying out the invention the steel wire from which the central spindle is to be made is suitably cleaned as by brushing, subjection to bars 744,566 and 14,372. Under the operative conditions as defined in the copending applications referred to, adense, adherent, chemically resistant electrodeposited plate of a tungsten alloy, such as tungsten nickel, is formedon the spindle.
It will be appreciated that depending upon the particular electrical characteristics desired to be imparted to the electrode, the composition of the bath and hence the resulting electrodeposited plate 8 may be varied. Thus, if desired, the spindle may first be plated with nickel either in dull or bright form and thereafter a surface of a tungsten alloy may be electrodeposited on the nickel. Similarly the respective percentages of the components of the alloys may be varied over wide ranges depending upon such factors as the initial ionic concentration of the platable components in the bath, the acidity of the bath, temperature and current density. Operating under the disclosures referred to heretofore electrodeposited plates of say tungsten and nickel may be produced ranging from five percent be formed on the lower portion of the spindle or on the entire length. Similarly this surface may comprise a tungsten nickel alloy with varying percentages of the two components or may comprise other binary alloys, such as tungsten cobalt. Where a surface characterized by a high degree of resistance to thermal influences is desired, the electrodeposited surface 8 may comprise a tungsten tantalum alloy or a ternary alloy of tungsten, nickel and tantalum. Such surface, for example, may be produced according to the method described in the copending application Serial No. 28,187.
The sparking point I may be similarly treated.-
As is known, such points may be separately formed and'inserted in a tapped aperture or hole formed in the metal body I. The sparking point I may be plated with tungsten nickel, tungsten cobalt, or other binary tungsten or molybdenum alloys and, if desired, the electrodeposited plate on the sparking point 1 may be of an alloy of diflerent characteristics from that plated on the central spindle 4.
It will likewise be understood that if it is desired to secure the advantages of the invention alloy which, besides presenting advantageous electrical characteristics, is most resistant to chemical action. The electrodeposited alloys of tungsten and analogous metals referred to herein are characterized by a smooth and resistant surface and hence considerably reduce the tendency to accumulation of amorphous carbon on the surface. A major advantage of the improved spark plug resides in the resistance of the sparking surface to disintegration due to the effect of the electrical discharge accentuated or accelerated under the high temperature conditions obtaining in the cylinder head.
It will thus be seen that the electrodes comprising the spark plug present many advantages. The ferruginous base of the electrodes provide adequate heat conduction and satisfactory tensile properties. The improved electrodeposited surface insures improved electrical characteristics and increased longevity due to the fact that such surface is substantially non-scaling at elevated temperatures and is eminently resistant to erosion under the conditions of electrical discharge at the elevated temperatures obtaining during use.
While the preferred modification of the invention has been described, it is to be understood that this has been givendidactically to illustrate the principles involved. It will be appreciated that these principles may be invoked in other circumstances where analogous conditions obtain and a comparable product is desired; this is to say that the invention is considered to comprehend not only specific units such as spark plugs, but other articles or units functioning similarly under equivalent conditions.
We claim:
1. A spark plug forinternal combustion motors having sparking elements, said elements having a surface comprising an electrodeposited tungsten alloy, said alloy having a tungsten content of from five to seventy percent.
2. A spark plug spindle comprising a metallic base and a surface comprising an electrodeposited alloy of tungsten, said alloy containing from twenty-five percent to fifty percent tungsten.
3. A spark plug spindle comprising a metallic ,base and a surface comprising an electrodeposited alloy of tungsten and nickel.
4. A spark plug spindle comprising a metallic base and a surface comprising an electrodeposited alloy of tungsten and cobalt.
5. A spark plug spindle comprising a fermginous base metal and a surface comprising an electrodeposited alloy of tungsten and tantalum. 6. A spark plug spindle comprising a ferruginous base metal and a sparking point which is surfaced with an electrodeposited alloy of tungsten, the alloy containing approximately between thirty and forty percent of tungsten.
7. A spark plug spindle comprising a ferruginous base metal and a sparking point which is surfaced with an electrodeposited alloy of tungsten and nickel.
8. A spark plug spindle comprising a 'ferruginous base metal and a sparking point' which is surfaced with an electrodeposited alloy of tungsten and cobalt.
9. A spark plug spindle comprising a fermginous base metal and a sparking point which is surfaced with an electrodeposited alloy of tungsten and tantalum.
10. A spark plug for internal combustion engines comprising a central electrode and an adjacent cooperating spark point, each of which are surfaced with an electrodeposited tungsten nickel alloy.
11. A spark plug for internal combustion engines comprising a central electrode and an adjacent cooperating spark point, the electrode being surfaced with an electrodeposited tungsten nickel alloy, the sparking point being surfaced with an electrodeposited tungsten alloy of different characteristics.
12. A spark plug electrode comprising a metallic base, which base is surfaced with an electrodeposited alloy of tungsten, tantalum and nickel.
13. A spark plug electrode comprising a metallic base, which base is surfaced with an electrodeposited alloy of tungsten, tantalum and co balt.
HARRY HOWARD ARMSTRONG. ARTHUR BURLEY MENEFEE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US46180A US2143853A (en) | 1935-10-22 | 1935-10-22 | Spark plug |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US46180A US2143853A (en) | 1935-10-22 | 1935-10-22 | Spark plug |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2143853A true US2143853A (en) | 1939-01-17 |
Family
ID=21942030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US46180A Expired - Lifetime US2143853A (en) | 1935-10-22 | 1935-10-22 | Spark plug |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2143853A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2678270A (en) * | 1951-10-06 | 1954-05-11 | Climax Molybdenum Co | Molybdenum-tantalum alloys |
| US3374385A (en) * | 1963-07-10 | 1968-03-19 | Rca Corp | Electron tube cathode with nickel-tungsten alloy base and thin nickel coating |
| US3737712A (en) * | 1971-11-17 | 1973-06-05 | Gen Electric | Sparkgap assembly having a semi-conductive coating adjacent the electrodes thereof |
| US3958144A (en) * | 1973-10-01 | 1976-05-18 | Franks Harry E | Spark plug |
| US4396855A (en) * | 1979-06-18 | 1983-08-02 | Nissan Motor Co., Ltd. | Plasma jet ignition plug with cavity in insulator discharge end |
| US20070222350A1 (en) * | 2006-03-24 | 2007-09-27 | Federal-Mogul World Wide, Inc. | Spark plug |
-
1935
- 1935-10-22 US US46180A patent/US2143853A/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2678270A (en) * | 1951-10-06 | 1954-05-11 | Climax Molybdenum Co | Molybdenum-tantalum alloys |
| US3374385A (en) * | 1963-07-10 | 1968-03-19 | Rca Corp | Electron tube cathode with nickel-tungsten alloy base and thin nickel coating |
| US3737712A (en) * | 1971-11-17 | 1973-06-05 | Gen Electric | Sparkgap assembly having a semi-conductive coating adjacent the electrodes thereof |
| US3958144A (en) * | 1973-10-01 | 1976-05-18 | Franks Harry E | Spark plug |
| US4396855A (en) * | 1979-06-18 | 1983-08-02 | Nissan Motor Co., Ltd. | Plasma jet ignition plug with cavity in insulator discharge end |
| US20070222350A1 (en) * | 2006-03-24 | 2007-09-27 | Federal-Mogul World Wide, Inc. | Spark plug |
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