US20180372417A1 - Heat exchanger for heating or cooling bulk solids - Google Patents
Heat exchanger for heating or cooling bulk solids Download PDFInfo
- Publication number
- US20180372417A1 US20180372417A1 US15/633,365 US201715633365A US2018372417A1 US 20180372417 A1 US20180372417 A1 US 20180372417A1 US 201715633365 A US201715633365 A US 201715633365A US 2018372417 A1 US2018372417 A1 US 2018372417A1
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- United States
- Prior art keywords
- heat exchange
- heat
- transfer tubes
- heat transfer
- exchange chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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- 239000007787 solid Substances 0.000 title claims abstract description 62
- 238000001816 cooling Methods 0.000 title claims abstract description 7
- 238000010438 heat treatment Methods 0.000 title claims abstract description 6
- 230000005484 gravity Effects 0.000 claims abstract description 11
- 230000008602 contraction Effects 0.000 claims abstract description 10
- 238000007599 discharging Methods 0.000 claims abstract description 4
- 238000003466 welding Methods 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000010964 304L stainless steel Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/0066—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
- F28D7/0075—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids with particular circuits for the same heat exchange medium, e.g. with the same heat exchange medium flowing through sections having different heat exchange capacities or for heating or cooling the same heat exchange medium at different temperatures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D15/00—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
- F28D15/02—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
- F28D15/04—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/0066—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
- F28D7/0083—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids with units having particular arrangement relative to a supplementary heat exchange medium, e.g. with interleaved units or with adjacent units arranged in common flow of supplementary heat exchange medium
- F28D7/0091—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids with units having particular arrangement relative to a supplementary heat exchange medium, e.g. with interleaved units or with adjacent units arranged in common flow of supplementary heat exchange medium the supplementary medium flowing in series through the units
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
- F28F9/02—Header boxes; End plates
- F28F9/0236—Header boxes; End plates floating elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0045—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for granular materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2265/00—Safety or protection arrangements; Arrangements for preventing malfunction
- F28F2265/26—Safety or protection arrangements; Arrangements for preventing malfunction for allowing differential expansion between elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
- F28F9/02—Header boxes; End plates
Definitions
- the present disclosure relates to a heat exchanger for heating or cooling bulk solids.
- Heat exchangers may be used to heat or cool bulk solids.
- the solids may flow through the heat exchanger, by the force of gravity, as heat is exchanged with a heat exchange medium.
- the temperature of the bulk solids being cooled, or the temperature to which the bulk solids are heated is typically limited because of the effects of thermal expansion and contraction of the elements of the heat exchanger, wear on elements of the heat exchanger, and thus the reduced operational life of the heat exchanger.
- a heat exchanger for heating or cooling bulk solids includes a housing including an inlet for receiving the bulk solids into the housing, an outlet for discharging the bulk solids from the housing, and a heat exchange chamber disposed between the inlet and the outlet.
- the heat exchanger also includes a plurality of spaced apart heat transfer tubes supported within the housing, between the inlet and the outlet, and extending through the heat exchange chamber, for indirect heat exchange of a heat exchange medium in the heat exchange chamber with the bulk solids that flow, by gravity, from the inlet, and through the heat transfer tubes, toward the outlet.
- the heat transfer tubes include a first end for receiving the bulk solids into the heat transfer tubes, and a second end for release of bulk solids flowing by the force of gravity, out of the heat transfer tubes. At least one of the first end and the second end is moveable relative to the housing to accommodate thermal expansion or contraction.
- the housing may include a top plate and a bottom plate enclosing the heat exchange chamber within the housing.
- the heat transfer tubes may be supported by the top plate, for example, by welding.
- the top plate may be shaped to facilitate flow of the bulk solids into the heat exchange tubes.
- the heat transfer tubes may extend through apertures in the bottom plate and may extend below the bottom plate.
- Bellows may be coupled to the second end of the heat transfer tubes and to the bottom plate such that the heat transfer tubes extend through the tube bellows.
- FIG. 1 is a perspective view of a heat exchanger in accordance with an embodiment
- FIG. 2 is a side view of the heat exchanger of FIG. 1 ;
- FIG. 3 is a sectional side view of the heat exchanger of FIG. 1 ;
- FIG. 4 is a sectional perspective view of the heat exchanger of FIG. 1 ;
- FIG. 5 is a sectional side view of an example of a heat exchanger according to an embodiment
- FIG. 6 is simplified sectional side view of a heat exchanger according to another embodiment
- FIG. 7 is simplified sectional side view of a heat exchanger according to yet another embodiment.
- the disclosure generally relates to a heat exchanger 100 for heating or cooling bulk solids.
- the heat exchanger 100 includes a housing 102 that has an inlet 104 for receiving the bulk solids into the housing 102 , an outlet 106 for discharging the bulk solids from the housing 102 , and a heat exchange chamber 108 disposed between the inlet 104 and the 106 outlet.
- the heat exchanger 100 also includes a plurality of spaced apart heat transfer tubes 110 supported within the housing 102 , between the inlet 104 and the outlet 106 , and extending through the heat exchange chamber 108 , for indirect heat exchange of a heat exchange medium in the heat exchange chamber 108 with the bulk solids that flow, by gravity, from the inlet 104 , through the heat transfer tubes 110 , toward the outlet 106 .
- the heat transfer tubes 110 include a first end 112 for receiving the bulk solids into the heat transfer tubes 110 , and a second end 114 for release of bulk solids flowing by the force of gravity. At least one of the first end and the second end is moveable relative to the housing to accommodate thermal expansion or contraction.
- the tube size and spacing between tubes may differ from the tube size and spacing illustrated in the figures, depending on the desired heat exchange, the volume of bulk solids and the pressure drop across the gaseous heat exchange medium.
- the housing 102 is generally cylindrical in shape and includes three sections, including an entry hopper 116 , the heat exchange chamber 108 , and a discharge hopper 118 .
- the sections of the housing are coupled together, for example, by bolting the sections together.
- An entry hopper flange 124 is coupled to an upper heat exchange chamber flange 126 .
- a lower heat exchange chamber flange 128 is coupled to a discharge hopper flange 130 .
- the entry hopper 116 is separated from the heat exchange chamber 108 by a top plate 120 that is coupled to the inside wall of the heat exchange chamber 108 section of the housing 102 to form a seal.
- the top plate 120 may be welded to the inside wall of the housing 102 .
- the top plate 120 provides a seal between the entry hopper 116 and the heat exchange chamber 108 .
- the discharge hopper 118 is separated from the heat exchange chamber 108 by a bottom plate 132 that is coupled, for example, by welding, to the inside wall of the housing 102 to form a seal.
- the bottom plate 132 provides a seal between the heat exchange chamber 108 and the discharge hopper 118 .
- a plurality of spaced apart heat transfer tubes 110 are disposed within the housing 102 and extend generally vertically through the heat exchange chamber 108 .
- the heat transfer tubes 110 may be stainless steel, such as Type 304L stainless steel.
- the heat transfer tubes 110 extend generally linearly and vertically.
- the heat transfer tubes 110 may have a circular cross-section or may have an oval shaped cross-section.
- the ends of the heat transfer tubes 110 have a circular cross-section and the center portion or majority of the body of the heat transfer tubes 110 have an oval cross-section.
- the heat transfer tubes 110 may have any other suitable shape.
- the heat transfer tubes 110 are coupled to the top plate 120 , at apertures that extend through the top plate 120 . Thus, the heat transfer tubes 110 are supported by the top plate 120 . Each heat transfer tube 110 is coupled at a first end 112 , to the top plate 120 at a respective aperture such that the respective aperture provides an opening for the flow of bulk solids into the heat transfer tube 110 .
- the heat transfer tube 110 is coupled to the top plate 120 , for example, by welding thereto, to maintain the seal between the entry hopper 116 and the heat exchange chamber 108 . Thus, the first end 112 of each of the heat transfer tubes 110 is isolated from the heat exchange chamber 108 .
- the bottom plate 132 also includes a plurality of apertures.
- the heat transfer tubes 110 extend through the apertures in the bottom plate 132 such that each heat transfer tube 110 extends through a respective aperture in the bottom plate 132 .
- the apertures are sized to provide a clearance fit for the heat transfer tubes 110 to facilitate thermal expansion and contraction of the heat transfer tubes 110 .
- the heat transfer tubes 110 extend through and below the bottom plate 132 .
- a second end 114 of each of the heat transfer tubes 110 is coupled to a respective tube bellows 134 .
- the tube bellows 134 is a metal tube bellows, is coupled at a bottom end 136 thereof to the second end 114 of the respective heat transfer tube 110 , and is coupled at a top end 138 thereof to the bottom plate 132 , around the respective one of the apertures through which the respective heat transfer tube 110 extends.
- the heat transfer tube 110 extends through the respective tube bellows 134 .
- the top end 138 of the tube bellows 134 may be, for example, welded to the bottom plate 132 to provide a seal between the heat exchange chamber 108 and the discharge hopper 118 .
- the second end 114 of each of the heat transfer tubes 110 is isolated from the heat exchange chamber 108 .
- the heat transfer tubes 110 are supported by the bottom plate 132 while facilitating thermal expansion and contraction of the heat transfer tubes 110 .
- the second ends 114 of the heat transfer tubes 110 are movable relative to the housing 102 to accommodate thermal expansion and contraction of the heat transfer tubes 110 .
- the tube bellows 134 provide a seal around the apertures in the bottom plate 132 to isolate the second ends of the heat transfer tubes 110 from the heat exchange chamber.
- the heat transfer tubes 110 may be coupled to the bottom plate 132 by welding directly to the bottom plate 132 and tube bellows may be utilized to couple the heat transfer tubes 110 to the top plate 120 .
- the inlet 104 is disposed in the top of the housing 102 and is sufficiently spaced from the top plate 120 to provide the entry hopper 116 .
- the entry hopper 116 facilitates distribution of bulk solids that flow from the inlet 104 , as a result of the force of gravity, over the top plate 120 , thus disbursing the bulk solids over the top plate 120 as bulk solids flow from the inlet 104 into the housing 102 .
- the top plate 120 may be shaped to facilitate flow of the bulk solids into the heat transfer tubes 110 .
- the top plate 120 may include ridges between the apertures in the top plate 120 and valleys surrounding the apertures to direct the flow of bulk solids into the heat transfer tubes 110 .
- the bottom plate 132 and the send ends 114 of the heat transfer tubes 110 are spaced from the outlet 106 for the flow of bulk solids through the outlet and out of the housing 102 .
- the discharge hopper 118 includes a generally conical section 140 utilized to create a mass flow or “choked flow” of bulk solids and to regulate the flow rate of the bulk solids out of the heat exchanger 100 .
- the term “choked flow” is utilized herein to refer to a flow other than a free fall of the bulk solids as a result of the force of gravity.
- the heat exchange chamber 108 includes a gas inlet 142 for the flow of a gaseous heat exchange medium into the heat exchange chamber 108 , and a gas outlet 144 for the flow of the gaseous heat exchange medium out of the heat exchange chamber 108 .
- the gaseous heat exchange medium flows generally upwardly in the heat exchange chamber 108 .
- the gas inlet and gas outlet may be reversed to flow downwardly, or co-current, in the heat exchange chamber.
- baffles may extend into the heat exchange chamber to facilitate circuitous flow of the gaseous heat exchange medium through the heat exchange chamber 108 .
- the housing may be made from any suitable material, such as Type 314L stainless steel or Type 316L stainless steel.
- all or part of the housing may be lined with a heat resistant lining.
- materials for the heat resistant lining include graphite or any other suitable insulating material, such as a refractory board or other fibrous or foam type board.
- FIG. 1 through FIG. 4 may be utilized as inspection or cleanout ports as well as instrumentation and spare ports.
- bulk solids are introduced into the heat exchanger 100 through the inlet 104 .
- the entry hopper 116 facilitates the distribution of the bulk solids into the first ends 112 of the heat transfer tubes 110 .
- the bulk solids flow through the heat transfer tubes 110 , by the force of gravity, thus passing through the heat exchange chamber 108 .
- the bulk solids are heated or cooled by indirect heat exchange with the gaseous heat exchange medium flowing around the heat transfer tubes 110 that extend through the heat exchange chamber 108 .
- the bulk solids then exit the second ends 114 of the heat transfer tubes 110 , into the discharge hopper 118 .
- the discharge hopper is utilized to create a choked flow of the bulk solids out of the heat exchanger 100 and thereby control residence time of the bulk solids in the heat exchanger 100 .
- the bulk solids are contained in the heat transfer tubes 110 as they flow through the heat exchange chamber 108 . As a result, the bulk solids are atmospherically isolated from the heat exchange medium in the heat exchange chamber 108 .
- the bulk solids may be introduced into the heat exchanger 100 at temperature of, for example, about 500° C. and cooled to a temperature of about 100° C.
- the gaseous heat transfer medium which may be air, may be introduced to the heat exchange chamber 108 at a temperature of about 50° C. and may exit the heat exchange chamber 108 at a temperature of about 145° C.
- bulk solids may be introduced into the heat exchanger at a temperature below 500° C. and heated to a temperature above 500° C.
- the gaseous heat transfer medium may be heated air, introduced at a temperature in excess of 900° C.
- tube bellows are utilized to couple the heat transfer tubes 110 to the bottom plate 132 , or, alternatively, to the top plate 120 , as described.
- the heat transfer tubes 120 may be coupled to one of the top plate 120 or the bottom plate 132 and may extend through the other of the top plate 120 and the bottom plate 132 , in a sliding fit.
- the heat transfer tubes 120 may be welded to the top plate 120 to support the heat transfer tubes 120 , and may extend through apertures in the bottom plate 132 , in a sliding fit.
- a small volume of the gaseous heat exchange medium may exit the heat exchange chamber 108 .
- tube bellows are not utilized, resulting a lower manufacturing cost for the heat exchanger.
- the heat exchanger 500 includes baffles 550 that extend into the heat exchange chamber 508 .
- the baffles 508 shown in the cross section illustrated in FIG. 5 extend inwardly to facilitate circuitous flow of the heat exchange medium flowing through the heat exchange chamber 550 .
- the baffles 550 are generally semicircular and, in the example illustrated in FIG. 5 , extend past a centerline or axis of the heat exchanger 100 to promote flow the heat exchange medium throughout the heat exchange chamber 508 .
- the heat exchanger 600 includes two heat exchange chambers, including a first heat exchange chamber 608 and a second heat exchange chamber 609 .
- the first heat exchange chamber 608 and the second heat exchange chamber 609 are separated by an intermediate plate 660 .
- the heat transfer tubes 610 in the present example extend from the top plate 620 , through apertures in the intermediate plate 660 , and through the apertures in the bottom plate 632 .
- the apertures in the intermediate plate 660 are sized to provide a clearance fit for the heat transfer tubes 610 and thus, no seal is provided between the first heat exchange chamber 608 and the second heat exchange chamber 609 .
- the apertures in the intermediate plate 660 may be sized to provide a tight fit through which expansion and contraction of the heat exchange tubes 610 may occur.
- the first heat exchange chamber 608 includes a gas inlet 642 for the flow of a gaseous heat exchange medium into the first heat exchange chamber 608 , and a gas outlet 644 for the flow of the gaseous heat exchange medium out of the first heat exchange chamber 608 .
- the second heat exchange chamber 609 includes a gas inlet 662 and a gas outlet 664 .
- the gas outlet 664 of the second heat exchange chamber 609 is coupled to the gas inlet 642 of the first heat exchange chamber 608 such that the gaseous heat exchange medium flows from the second heat exchange chamber 609 into the first heat exchange chamber 608 .
- the first heat exchange chamber 608 is not atmospherically isolated from the second heat exchange chamber 609 .
- the intermediate plate 660 is utilized as a baffle to facilitate circuitous flow of the gaseous heat exchange medium in the heat exchanger 600 .
- Further heat exchange chambers may also be employed.
- each bank of heat exchange tubes may utilize separate tube bellows.
- FIG. 7 shows an example of an embodiment in which two banks 750 , 752 of heat exchange tubes 710 , 711 are utilized. Many of the elements described above with reference to FIG. 1 through FIG. 4 and FIG. 6 are similar to those of FIG. 7 and are therefore not described again in detail.
- the heat exchanger 700 includes two heat exchange chambers, including a first heat exchange chamber 708 and a second heat exchange chamber 709 .
- the first heat exchange chamber 708 and the second heat exchange chamber 709 are separated by an intermediate plenum 754 in which the bulk solids from the heat transfer tubes 710 of the first bank 750 collect and are distributed into the heat transfer tubes 711 of the second bank 752 .
- the heat transfer tubes 710 of the first bank 750 are coupled to a first top plate 720 at aperatures that extend through the first top plate 720 and extend through apertures in the first bottom plate 732 .
- First tube bellows (not shown) may be utilized to couple the heat transfer tubes 710 to the first bottom plate 732 , as described above with reference to FIG. 1 .
- the heat transfer tubes 711 of the second bank 752 are coupled to a second top plate 721 at aperatures that extend through the second top plate 721 and extend through apertures in the second bottom plate 733 .
- Second tube bellows (not shown) may be utilized to couple the heat transfer tubes 711 to the second bottom plate 733 .
- the intermediate plenum 754 referred to above is formed by the spacing between the first bottom plate 732 and second top plate 721 . Bulk solids that exit from the heat transfer tubes 710 of the first bank 750 are received in the intermediate plenum 754 and are distributed into the heat transfer tubes 711 of the second bank 752 .
- the intermediate plenum 754 may also include a vent or outlet (not shown) for exit of gasses from the bulk solids.
- the first heat exchange chamber 708 includes a gas inlet 742 for the flow of a gaseous heat exchange medium into the first heat exchange chamber 708 , and a gas outlet 744 for the flow of the gaseous heat exchange medium out of the first heat exchange chamber 708 .
- the second heat exchange chamber 709 includes a gas inlet 762 and a gas outlet 764 .
- the gas outlet 764 of the second heat exchange chamber 709 is coupled to the gas inlet 742 of the first heat exchange chamber 708 such that the gaseous heat exchange medium flows from the second heat exchange chamber 709 into the first heat exchange chamber 608 .
- a greater volume of gaseous heat exchange medium may be utilized at lower pressure than, for example, utilizing tubes for the flow of heat exchange fluid therethrough.
- the velocity of the gaseous heat exchange medium are also lower. The velocity and lower pressure results in a reduced cost of operation.
- the heat transfer tubes of the heat exchanger are supported within the heat exchanger and extend through the heat exchange chamber while thermal expansion and contraction of the heat transfer tubes is facilitated.
- the heat exchanger is suitable for use in relatively high temperature applications, such as cooling of bulk solids from a temperature of 500° C. or greater.
- the bulk solids flowing through the heat transfer tubes may be atmospherically isolated from the heat exchange medium in the heat exchange chamber.
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Abstract
Description
- The present disclosure relates to a heat exchanger for heating or cooling bulk solids.
- Heat exchangers may be used to heat or cool bulk solids. The solids may flow through the heat exchanger, by the force of gravity, as heat is exchanged with a heat exchange medium.
- The temperature of the bulk solids being cooled, or the temperature to which the bulk solids are heated is typically limited because of the effects of thermal expansion and contraction of the elements of the heat exchanger, wear on elements of the heat exchanger, and thus the reduced operational life of the heat exchanger.
- Improvements to heat exchangers for high temperature applications is desirable.
- According to an aspect of an embodiment, a heat exchanger for heating or cooling bulk solids, includes a housing including an inlet for receiving the bulk solids into the housing, an outlet for discharging the bulk solids from the housing, and a heat exchange chamber disposed between the inlet and the outlet. The heat exchanger also includes a plurality of spaced apart heat transfer tubes supported within the housing, between the inlet and the outlet, and extending through the heat exchange chamber, for indirect heat exchange of a heat exchange medium in the heat exchange chamber with the bulk solids that flow, by gravity, from the inlet, and through the heat transfer tubes, toward the outlet. The heat transfer tubes include a first end for receiving the bulk solids into the heat transfer tubes, and a second end for release of bulk solids flowing by the force of gravity, out of the heat transfer tubes. At least one of the first end and the second end is moveable relative to the housing to accommodate thermal expansion or contraction.
- The housing may include a top plate and a bottom plate enclosing the heat exchange chamber within the housing. The heat transfer tubes may be supported by the top plate, for example, by welding. The top plate may be shaped to facilitate flow of the bulk solids into the heat exchange tubes.
- The heat transfer tubes may extend through apertures in the bottom plate and may extend below the bottom plate. Bellows may be coupled to the second end of the heat transfer tubes and to the bottom plate such that the heat transfer tubes extend through the tube bellows.
- Embodiments of the present invention will be described, by way of example, with reference to the drawings and to the following description, in which:
-
FIG. 1 is a perspective view of a heat exchanger in accordance with an embodiment; -
FIG. 2 is a side view of the heat exchanger ofFIG. 1 ; -
FIG. 3 is a sectional side view of the heat exchanger ofFIG. 1 ; -
FIG. 4 is a sectional perspective view of the heat exchanger ofFIG. 1 ; -
FIG. 5 is a sectional side view of an example of a heat exchanger according to an embodiment; -
FIG. 6 is simplified sectional side view of a heat exchanger according to another embodiment; -
FIG. 7 is simplified sectional side view of a heat exchanger according to yet another embodiment. - For simplicity and clarity of illustration, reference numerals may be repeated among the figures to indicate corresponding or analogous elements. Numerous details are set forth to provide an understanding of the embodiments described herein. The embodiments may be practiced without these details. In other instances, known methods, procedures, and components have not been described in detail to avoid obscuring the embodiments described. The description is not to be considered as limited to the scope of the embodiments described herein.
- Referring to
FIG. 1 throughFIG. 4 , the disclosure generally relates to aheat exchanger 100 for heating or cooling bulk solids. Theheat exchanger 100, includes ahousing 102 that has aninlet 104 for receiving the bulk solids into thehousing 102, anoutlet 106 for discharging the bulk solids from thehousing 102, and aheat exchange chamber 108 disposed between theinlet 104 and the 106 outlet. Theheat exchanger 100 also includes a plurality of spaced apartheat transfer tubes 110 supported within thehousing 102, between theinlet 104 and theoutlet 106, and extending through theheat exchange chamber 108, for indirect heat exchange of a heat exchange medium in theheat exchange chamber 108 with the bulk solids that flow, by gravity, from theinlet 104, through theheat transfer tubes 110, toward theoutlet 106. Theheat transfer tubes 110 include afirst end 112 for receiving the bulk solids into theheat transfer tubes 110, and asecond end 114 for release of bulk solids flowing by the force of gravity. At least one of the first end and the second end is moveable relative to the housing to accommodate thermal expansion or contraction. - The tube size and spacing between tubes may differ from the tube size and spacing illustrated in the figures, depending on the desired heat exchange, the volume of bulk solids and the pressure drop across the gaseous heat exchange medium.
- In the example shown in
FIG. 1 throughFIG. 4 , thehousing 102 is generally cylindrical in shape and includes three sections, including anentry hopper 116, theheat exchange chamber 108, and adischarge hopper 118. In this example, the sections of the housing are coupled together, for example, by bolting the sections together. Anentry hopper flange 124 is coupled to an upper heatexchange chamber flange 126. A lower heatexchange chamber flange 128 is coupled to adischarge hopper flange 130. - The
entry hopper 116 is separated from theheat exchange chamber 108 by atop plate 120 that is coupled to the inside wall of theheat exchange chamber 108 section of thehousing 102 to form a seal. For example, thetop plate 120 may be welded to the inside wall of thehousing 102. Thetop plate 120 provides a seal between theentry hopper 116 and theheat exchange chamber 108. - The
discharge hopper 118 is separated from theheat exchange chamber 108 by abottom plate 132 that is coupled, for example, by welding, to the inside wall of thehousing 102 to form a seal. Thebottom plate 132 provides a seal between theheat exchange chamber 108 and thedischarge hopper 118. - A plurality of spaced apart
heat transfer tubes 110 are disposed within thehousing 102 and extend generally vertically through theheat exchange chamber 108. Theheat transfer tubes 110 may be stainless steel, such as Type 304L stainless steel. In this example, theheat transfer tubes 110 extend generally linearly and vertically. Theheat transfer tubes 110 may have a circular cross-section or may have an oval shaped cross-section. In one example, the ends of theheat transfer tubes 110 have a circular cross-section and the center portion or majority of the body of theheat transfer tubes 110 have an oval cross-section. Alternatively, theheat transfer tubes 110 may have any other suitable shape. - The
heat transfer tubes 110 are coupled to thetop plate 120, at apertures that extend through thetop plate 120. Thus, theheat transfer tubes 110 are supported by thetop plate 120. Eachheat transfer tube 110 is coupled at afirst end 112, to thetop plate 120 at a respective aperture such that the respective aperture provides an opening for the flow of bulk solids into theheat transfer tube 110. Theheat transfer tube 110 is coupled to thetop plate 120, for example, by welding thereto, to maintain the seal between theentry hopper 116 and theheat exchange chamber 108. Thus, thefirst end 112 of each of theheat transfer tubes 110 is isolated from theheat exchange chamber 108. - The
bottom plate 132 also includes a plurality of apertures. Theheat transfer tubes 110 extend through the apertures in thebottom plate 132 such that eachheat transfer tube 110 extends through a respective aperture in thebottom plate 132. The apertures are sized to provide a clearance fit for theheat transfer tubes 110 to facilitate thermal expansion and contraction of theheat transfer tubes 110. Thus, theheat transfer tubes 110 extend through and below thebottom plate 132. - A
second end 114 of each of theheat transfer tubes 110 is coupled to arespective tube bellows 134. Thetube bellows 134 is a metal tube bellows, is coupled at abottom end 136 thereof to thesecond end 114 of the respectiveheat transfer tube 110, and is coupled at atop end 138 thereof to thebottom plate 132, around the respective one of the apertures through which the respectiveheat transfer tube 110 extends. Thus, theheat transfer tube 110 extends through therespective tube bellows 134. Thetop end 138 of the tube bellows 134 may be, for example, welded to thebottom plate 132 to provide a seal between theheat exchange chamber 108 and thedischarge hopper 118. Thus, thesecond end 114 of each of theheat transfer tubes 110 is isolated from theheat exchange chamber 108. - By coupling the
second end 114 of each of theheat transfer tubes 110 to abottom end 136 of the respective tube bellows 134 and coupling thetop end 138 of the tube bellows 134 to thebottom plate 132, theheat transfer tubes 110 are supported by thebottom plate 132 while facilitating thermal expansion and contraction of theheat transfer tubes 110. Thus, the second ends 114 of theheat transfer tubes 110 are movable relative to thehousing 102 to accommodate thermal expansion and contraction of theheat transfer tubes 110. Additionally, the tube bellows 134 provide a seal around the apertures in thebottom plate 132 to isolate the second ends of theheat transfer tubes 110 from the heat exchange chamber. - Alternatively, the
heat transfer tubes 110 may be coupled to thebottom plate 132 by welding directly to thebottom plate 132 and tube bellows may be utilized to couple theheat transfer tubes 110 to thetop plate 120. - The
inlet 104 is disposed in the top of thehousing 102 and is sufficiently spaced from thetop plate 120 to provide theentry hopper 116. Theentry hopper 116 facilitates distribution of bulk solids that flow from theinlet 104, as a result of the force of gravity, over thetop plate 120, thus disbursing the bulk solids over thetop plate 120 as bulk solids flow from theinlet 104 into thehousing 102. Optionally, thetop plate 120 may be shaped to facilitate flow of the bulk solids into theheat transfer tubes 110. For example, thetop plate 120 may include ridges between the apertures in thetop plate 120 and valleys surrounding the apertures to direct the flow of bulk solids into theheat transfer tubes 110. - The
bottom plate 132 and the send ends 114 of theheat transfer tubes 110 are spaced from theoutlet 106 for the flow of bulk solids through the outlet and out of thehousing 102. In this example, thedischarge hopper 118 includes a generallyconical section 140 utilized to create a mass flow or “choked flow” of bulk solids and to regulate the flow rate of the bulk solids out of theheat exchanger 100. The term “choked flow” is utilized herein to refer to a flow other than a free fall of the bulk solids as a result of the force of gravity. - The
heat exchange chamber 108 includes agas inlet 142 for the flow of a gaseous heat exchange medium into theheat exchange chamber 108, and agas outlet 144 for the flow of the gaseous heat exchange medium out of theheat exchange chamber 108. Thus, in this embodiment, the gaseous heat exchange medium flows generally upwardly in theheat exchange chamber 108. Alternatively, the gas inlet and gas outlet may be reversed to flow downwardly, or co-current, in the heat exchange chamber. Optionally, baffles may extend into the heat exchange chamber to facilitate circuitous flow of the gaseous heat exchange medium through theheat exchange chamber 108. - The housing may be made from any suitable material, such as Type 314L stainless steel or Type 316L stainless steel. Optionally, all or part of the housing may be lined with a heat resistant lining. Examples of materials for the heat resistant lining include graphite or any other suitable insulating material, such as a refractory board or other fibrous or foam type board.
- The additional flanges and openings illustrated in
FIG. 1 throughFIG. 4 may be utilized as inspection or cleanout ports as well as instrumentation and spare ports. - In use, bulk solids are introduced into the
heat exchanger 100 through theinlet 104. Theentry hopper 116 facilitates the distribution of the bulk solids into the first ends 112 of theheat transfer tubes 110. The bulk solids flow through theheat transfer tubes 110, by the force of gravity, thus passing through theheat exchange chamber 108. The bulk solids are heated or cooled by indirect heat exchange with the gaseous heat exchange medium flowing around theheat transfer tubes 110 that extend through theheat exchange chamber 108. The bulk solids then exit the second ends 114 of theheat transfer tubes 110, into thedischarge hopper 118. The discharge hopper is utilized to create a choked flow of the bulk solids out of theheat exchanger 100 and thereby control residence time of the bulk solids in theheat exchanger 100. The bulk solids are contained in theheat transfer tubes 110 as they flow through theheat exchange chamber 108. As a result, the bulk solids are atmospherically isolated from the heat exchange medium in theheat exchange chamber 108. - In a particular example application, the bulk solids may be introduced into the
heat exchanger 100 at temperature of, for example, about 500° C. and cooled to a temperature of about 100° C. The gaseous heat transfer medium, which may be air, may be introduced to theheat exchange chamber 108 at a temperature of about 50° C. and may exit theheat exchange chamber 108 at a temperature of about 145° C. - In another example application, bulk solids may be introduced into the heat exchanger at a temperature below 500° C. and heated to a temperature above 500° C. The gaseous heat transfer medium may be heated air, introduced at a temperature in excess of 900° C.
- In the above-described embodiment, tube bellows are utilized to couple the
heat transfer tubes 110 to thebottom plate 132, or, alternatively, to thetop plate 120, as described. In another embodiment, theheat transfer tubes 120 may be coupled to one of thetop plate 120 or thebottom plate 132 and may extend through the other of thetop plate 120 and thebottom plate 132, in a sliding fit. For example, theheat transfer tubes 120 may be welded to thetop plate 120 to support theheat transfer tubes 120, and may extend through apertures in thebottom plate 132, in a sliding fit. In this example, a small volume of the gaseous heat exchange medium may exit theheat exchange chamber 108. Thus, in this embodiment, tube bellows are not utilized, resulting a lower manufacturing cost for the heat exchanger. - Referring now to
FIG. 5 , another embodiment will be briefly described. Many of the elements described above with reference toFIG. 1 throughFIG. 4 are similar to those ofFIG. 5 and are therefore not described again in detail. In the example, shown inFIG. 5 , theheat exchanger 500 includesbaffles 550 that extend into theheat exchange chamber 508. Thebaffles 508 shown in the cross section illustrated inFIG. 5 , extend inwardly to facilitate circuitous flow of the heat exchange medium flowing through theheat exchange chamber 550. Thebaffles 550 are generally semicircular and, in the example illustrated inFIG. 5 , extend past a centerline or axis of theheat exchanger 100 to promote flow the heat exchange medium throughout theheat exchange chamber 508. - Referring to
FIG. 6 , another embodiment is illustrated. Many of the elements described above with reference toFIG. 1 throughFIG. 4 are similar to those ofFIG. 6 and are therefore not described again in detail. In the embodiment illustrated inFIG. 6 , theheat exchanger 600 includes two heat exchange chambers, including a firstheat exchange chamber 608 and a secondheat exchange chamber 609. - The first
heat exchange chamber 608 and the secondheat exchange chamber 609 are separated by anintermediate plate 660. Theheat transfer tubes 610 in the present example extend from thetop plate 620, through apertures in theintermediate plate 660, and through the apertures in thebottom plate 632. In this example, the apertures in theintermediate plate 660 are sized to provide a clearance fit for theheat transfer tubes 610 and thus, no seal is provided between the firstheat exchange chamber 608 and the secondheat exchange chamber 609. Alternatively, the apertures in theintermediate plate 660 may be sized to provide a tight fit through which expansion and contraction of theheat exchange tubes 610 may occur. - The first
heat exchange chamber 608 includes agas inlet 642 for the flow of a gaseous heat exchange medium into the firstheat exchange chamber 608, and agas outlet 644 for the flow of the gaseous heat exchange medium out of the firstheat exchange chamber 608. The secondheat exchange chamber 609 includes agas inlet 662 and agas outlet 664. Thegas outlet 664 of the secondheat exchange chamber 609 is coupled to thegas inlet 642 of the firstheat exchange chamber 608 such that the gaseous heat exchange medium flows from the secondheat exchange chamber 609 into the firstheat exchange chamber 608. Thus, the firstheat exchange chamber 608 is not atmospherically isolated from the secondheat exchange chamber 609. - In this example, the
intermediate plate 660 is utilized as a baffle to facilitate circuitous flow of the gaseous heat exchange medium in theheat exchanger 600. Further heat exchange chambers may also be employed. - Alternatively, multiple banks of heat exchange tubes may be utilized such that bulk solids flow through a first bank of heat exchange tubes, exit the first bank of heat exchange tubes and enter a second bank of heat exchange tubes. Optionally, each bank of heat exchange tubes may utilize separate tube bellows.
- Reference is now made to
FIG. 7 , which shows an example of an embodiment in which two 750, 752 ofbanks 710, 711 are utilized. Many of the elements described above with reference toheat exchange tubes FIG. 1 throughFIG. 4 andFIG. 6 are similar to those ofFIG. 7 and are therefore not described again in detail. In the embodiment illustrated inFIG. 7 , theheat exchanger 700 includes two heat exchange chambers, including a firstheat exchange chamber 708 and a secondheat exchange chamber 709. - The first
heat exchange chamber 708 and the secondheat exchange chamber 709 are separated by anintermediate plenum 754 in which the bulk solids from theheat transfer tubes 710 of thefirst bank 750 collect and are distributed into theheat transfer tubes 711 of thesecond bank 752. - The
heat transfer tubes 710 of thefirst bank 750 are coupled to a firsttop plate 720 at aperatures that extend through the firsttop plate 720 and extend through apertures in thefirst bottom plate 732. First tube bellows (not shown) may be utilized to couple theheat transfer tubes 710 to thefirst bottom plate 732, as described above with reference toFIG. 1 . - The
heat transfer tubes 711 of thesecond bank 752 are coupled to a secondtop plate 721 at aperatures that extend through the secondtop plate 721 and extend through apertures in thesecond bottom plate 733. Second tube bellows (not shown) may be utilized to couple theheat transfer tubes 711 to thesecond bottom plate 733. - The
intermediate plenum 754 referred to above is formed by the spacing between thefirst bottom plate 732 and secondtop plate 721. Bulk solids that exit from theheat transfer tubes 710 of thefirst bank 750 are received in theintermediate plenum 754 and are distributed into theheat transfer tubes 711 of thesecond bank 752. Theintermediate plenum 754 may also include a vent or outlet (not shown) for exit of gasses from the bulk solids. - The first
heat exchange chamber 708 includes agas inlet 742 for the flow of a gaseous heat exchange medium into the firstheat exchange chamber 708, and agas outlet 744 for the flow of the gaseous heat exchange medium out of the firstheat exchange chamber 708. The secondheat exchange chamber 709 includes agas inlet 762 and agas outlet 764. In this example, thegas outlet 764 of the secondheat exchange chamber 709 is coupled to thegas inlet 742 of the firstheat exchange chamber 708 such that the gaseous heat exchange medium flows from the secondheat exchange chamber 709 into the firstheat exchange chamber 608. - Advantageously, utilizing tubes through which the solids flow, a greater volume of gaseous heat exchange medium may be utilized at lower pressure than, for example, utilizing tubes for the flow of heat exchange fluid therethrough. As a result, the velocity of the gaseous heat exchange medium are also lower. The velocity and lower pressure results in a reduced cost of operation.
- The heat transfer tubes of the heat exchanger are supported within the heat exchanger and extend through the heat exchange chamber while thermal expansion and contraction of the heat transfer tubes is facilitated. Thus, the heat exchanger is suitable for use in relatively high temperature applications, such as cooling of bulk solids from a temperature of 500° C. or greater. In addition, the bulk solids flowing through the heat transfer tubes may be atmospherically isolated from the heat exchange medium in the heat exchange chamber.
- The described embodiments are to be considered in all respects only as illustrative and not restrictive. The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given the broadest interpretation consistent with the description as a whole. All changes that come with meaning and range of equivalency of the claims are to be embraced within their scope.
Claims (14)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/633,365 US20180372417A1 (en) | 2017-06-26 | 2017-06-26 | Heat exchanger for heating or cooling bulk solids |
| EP18823247.4A EP3645956A4 (en) | 2017-06-26 | 2018-06-19 | Heat exchanger for heating or cooling bulk solids |
| CA3066818A CA3066818A1 (en) | 2017-06-26 | 2018-06-19 | Heat exchanger for heating or cooling bulk solids |
| PCT/CA2018/050744 WO2019000079A1 (en) | 2017-06-26 | 2018-06-19 | Heat exchanger for heating or cooling bulk solids |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/633,365 US20180372417A1 (en) | 2017-06-26 | 2017-06-26 | Heat exchanger for heating or cooling bulk solids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20180372417A1 true US20180372417A1 (en) | 2018-12-27 |
Family
ID=64691552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US15/633,365 Abandoned US20180372417A1 (en) | 2017-06-26 | 2017-06-26 | Heat exchanger for heating or cooling bulk solids |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20180372417A1 (en) |
| EP (1) | EP3645956A4 (en) |
| CA (1) | CA3066818A1 (en) |
| WO (1) | WO2019000079A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110927205A (en) * | 2019-11-26 | 2020-03-27 | 北京科技大学 | Device for measuring heat exchange coefficient of bulk material flowing around pipe |
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|---|---|---|---|---|
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| US3527291A (en) * | 1968-05-16 | 1970-09-08 | Aero Flow Dynamics Inc | Expansion accommodating means and method |
| US3710473A (en) * | 1971-06-28 | 1973-01-16 | Caterpillar Tractor Co | Method of manufacturing a heat exchanger |
| US4220193A (en) * | 1977-04-12 | 1980-09-02 | Esmil, B.V. | Method and equipment for heat exchange |
| US4303434A (en) * | 1980-09-08 | 1981-12-01 | Owens-Illinois, Inc. | Method and apparatus for preheating pulverous materials prior to their introduction into a melting furnace |
| US4305453A (en) * | 1979-11-19 | 1981-12-15 | Rockwell International Corporation | Slide guide for tube-type heat exchanger |
| US4585051A (en) * | 1983-05-13 | 1986-04-29 | University Of Queensland | Heat exchange between solids |
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| US5915472A (en) * | 1996-05-22 | 1999-06-29 | Usui Kokusai Sangyo Kaisha Limited | Apparatus for cooling EGR gas |
| US6153152A (en) * | 1990-04-03 | 2000-11-28 | The Standard Oil Company | Endothermic reaction apparatus and method |
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| DE3541887A1 (en) * | 1985-11-27 | 1987-06-04 | Krupp Koppers Gmbh | HEAT EXCHANGER FOR COOLING SOLIDS CONTAINING GASES |
| US6247232B1 (en) * | 1999-03-10 | 2001-06-19 | Transpro, Inc. | Method of manufacturing a welded heat exchanger with grommet construction |
| MY121525A (en) * | 1999-03-11 | 2006-01-28 | Nippon Catalytic Chem Ind | Shell-and tube heat exchanger and method for inhibiting polymerization in the shell-and-tube heat exchanger |
| JP4450887B2 (en) * | 1999-05-20 | 2010-04-14 | 株式会社ティラド | Heat exchanger |
| JP3668870B2 (en) * | 2001-08-09 | 2005-07-06 | 株式会社日立製作所 | Synchronous motor drive system |
| DE102006016622B4 (en) * | 2006-04-06 | 2009-10-01 | Coperion Gmbh | Device for controlling the temperature of bulk material |
-
2017
- 2017-06-26 US US15/633,365 patent/US20180372417A1/en not_active Abandoned
-
2018
- 2018-06-19 WO PCT/CA2018/050744 patent/WO2019000079A1/en not_active Ceased
- 2018-06-19 CA CA3066818A patent/CA3066818A1/en active Pending
- 2018-06-19 EP EP18823247.4A patent/EP3645956A4/en not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1882085A (en) * | 1931-04-04 | 1932-10-11 | Herman Nelson Corp | Radiator |
| US2519315A (en) * | 1946-03-27 | 1950-08-15 | Socony Vacuum Oil Co Inc | Method and apparatus for heating granular solids |
| US3527291A (en) * | 1968-05-16 | 1970-09-08 | Aero Flow Dynamics Inc | Expansion accommodating means and method |
| US3710473A (en) * | 1971-06-28 | 1973-01-16 | Caterpillar Tractor Co | Method of manufacturing a heat exchanger |
| US4220193A (en) * | 1977-04-12 | 1980-09-02 | Esmil, B.V. | Method and equipment for heat exchange |
| US4305453A (en) * | 1979-11-19 | 1981-12-15 | Rockwell International Corporation | Slide guide for tube-type heat exchanger |
| US4303434A (en) * | 1980-09-08 | 1981-12-01 | Owens-Illinois, Inc. | Method and apparatus for preheating pulverous materials prior to their introduction into a melting furnace |
| US4585051A (en) * | 1983-05-13 | 1986-04-29 | University Of Queensland | Heat exchange between solids |
| US5167933A (en) * | 1990-02-02 | 1992-12-01 | Haldor Topsoe A/S | Heat exchange reforming process and reactor system |
| US6153152A (en) * | 1990-04-03 | 2000-11-28 | The Standard Oil Company | Endothermic reaction apparatus and method |
| US5915472A (en) * | 1996-05-22 | 1999-06-29 | Usui Kokusai Sangyo Kaisha Limited | Apparatus for cooling EGR gas |
| US20070297959A1 (en) * | 2004-09-27 | 2007-12-27 | Sumitomo Chemical Company, Limited | Multitubular Reaction Apparatus For Contact Gas-Phase Reaction |
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| CN110927205A (en) * | 2019-11-26 | 2020-03-27 | 北京科技大学 | Device for measuring heat exchange coefficient of bulk material flowing around pipe |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3645956A4 (en) | 2021-01-27 |
| WO2019000079A1 (en) | 2019-01-03 |
| CA3066818A1 (en) | 2019-01-03 |
| EP3645956A1 (en) | 2020-05-06 |
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