US20170119917A1

US20170119917A1 - Malodor reduction compositions

Info

Publication number: US20170119917A1
Application number: US15/407,477
Authority: US
Inventors: Gayle Marie Frankenbach; Judith Ann Hollingshead; Steven Anthony Horenziak; Prakash J. MADHAV; David Thomas Stanton; Christine Marie Readnour; Zaiyou Liu; Jonathan Robert Cetti
Original assignee: Procter and Gamble Co
Current assignee: Procter and Gamble Co
Priority date: 2014-09-26
Filing date: 2017-01-17
Publication date: 2017-05-04
Also published as: CA2959697A1; US20160090555A1; CA2960390A1; JP2017537173A; KR101971378B1; JP2017530122A; US20160089462A1; EP3197426A1; JP2017531469A; US20160092661A1; MX2017003965A; US11334694B2; JP2020000884A; WO2016049393A1; CA2959555A1; CN107001995A; MX2017003967A; US20170255725A1; JP7328058B2; WO2016049407A1

Abstract

The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags. Such malodor control technologies do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.

Description

FIELD OF THE INVENTION

The present invention relates to malodor reduction compositions and methods of making and using same.

BACKGROUND OF THE INVENTION

Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C₂-C₁₂carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors. Often times, manufacturers incorporate scented perfumes to help mask these difficult malodors.
Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor's access to a sensory cell, in order to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules. Thus, the malodor control technologies disclosed herein do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.

SUMMARY OF THE INVENTION

DETAILED DESCRIPTION OF THE INVENTION

As used herein “MORV” is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.
As used herein “consumer product” means baby care, beauty care, fabric & home care, family care, feminine care, health care, snack and/or beverage products or devices. Such products include but are not limited to plastic films garbage bags, storage bags, storage wraps, diapers, bibs, wipes, garments, textiles including sheets and towels, composters; products for and/or methods relating to treating hair (human, dog, and/or cat), including, bleaching, coloring, dyeing, conditioning, wet or dry shampooing, styling, scalp treatments; deodorants and antiperspirants; personal cleansing; cosmetics; skin care including application of creams, lotions, fine fragrances and other topically applied products for consumer use; and shaving products, products for and/or methods relating to treating fabrics, hard surfaces and any other surfaces in the area of fabric and home care, including: air care including air filtration, car care, dishwashing, fabric conditioning (including softening), laundry detergency, laundry and rinse additive and/or care, hard surface cleaning and/or treatment, towel bowl cleaners and other cleaning and/or malodor treatments for consumer, agricultural, industrial or institutional use; products and/or methods relating to bath tissue, facial tissue, paper handkerchiefs, and/or paper towels; tampons, feminine napkins; products and/or methods relating to oral care including toothpastes, tooth gels, tooth rinses, denture adhesives, tooth whitening.
As used herein “energized system”, refers to a system that operates by using an electrical and/or mechanical energy source such as a battery or electrical wall outlet to emit the malodor reduction composition. Examples of such devices include but are limited to liquid electric pluggable type air freshening devices.
As used herein, “malodor” refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.
As used herein, “neutralize” or “neutralization” refers to the ability of a compound or product to reduce or eliminate malodorous compounds. Odor neutralization may be partial, affecting only some of the malodorous compounds in a given context, or affecting only part of a malodorous compound. A malodorous compound may be neutralized by chemical reaction resulting in a new chemical entity, by sequestration, by chelation, by association, or by any other interaction rendering the malodorous compound less malodorous or non-malodorous. Neutralization is distinguishable from odor masking or odor blocking by a change in the malodorous compound, as opposed to a change in the ability to perceive the malodor without any corresponding change in the condition of the malodorous compound. Malodor neutralization provides a sensory and analytically measurable (e.g. gas chromatograph) malodor reduction. Thus, if a malodor reduction composition delivers genuine malodor neutralization, the composition will reduce malodors in the vapor and/or liquid phase.
As used herein, “non-energized” refers to a system that emits a targeted active passively or without the need for an electrical energy source. Handheld aerosol sprayers and traditional trigger/pump sprayers are considered non-energized systems.
As used herein, “odor blocking” refers to the ability of a compound to dull the human sense of smell.
As used herein, “odor masking” refers to the ability of a compound with a non-offensive or pleasant smell that is dosed such that it limits the ability to sense a malodorous compound. Odor-masking may involve the selection of compounds which coordinate with an anticipated malodor to change the perception of the overall scent provided by the combination of odorous compounds.
As used herein, the terms “a” and “an” mean “at least one”.
As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting.
Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.
All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.
It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.

Malodor Reduction Materials


Codes

	A = Vapor Pressure >0.1 torr
	B = Vapor Pressure is between 0.01 torr and 0.1 torr
	C = ClogP <3
	D = ClogP >3
	E = Probability of Ingredient Color Instability = 0%
	F = Probability of Ingredient Color Instability <71%
	G = Odor Detection Threshold less than p.ol = 8
	H = Odor Detection Threshold greater than p.ol = 8
	I = Melamine formaldehyde PMC Headspace Response
	Ratio greater than or equal to 10
	J = Melamine formaldehyde PMC leakage less than or
	equal to 5%
	K = Log of liquid dish neat product liquid-air partition
	coefficient greater than or equal to −7
	L = Log of liquid dish neat product liquid-air partition
	coefficient greater than or equal to −5

TABLE 1

List of materials with at least one MORV from 1 to 5

Num-		CAS	Comment
ber	Material Name	Number	Code

1	2-ethylhexyl (Z)-3-(4-	5466-77-3	DEFHJ
	methoxyphenyl)acrylate
2	2,4-dimethyl-2-(5,5,8,8-tetramethyl-	131812-67-4	DFHJ
	5,6,7,8-tetrahydronaphthalen-2-yl)-
	1,3-dioxolane
3	1,1-dimethoxynon-2-yne	13257-44-8	ACEFHJK
4	para-Cymen-8-ol	1197-01-9	BCGIJK
7	3-methoxy-7,7-dimethyl-10-	216970-21-7	BDEFHJK
	methylenebicyclo[4.3.1]decane
9	Methoxycyclododecane	2986-54-1	DEFHJK
10	1,1-dimethoxycyclododecane	950-33-4	DEFHJK
11	(Z)-tridec-2-enenitrile	22629-49-8	DEFHJK
13	Oxybenzone	131-57-7	DEFGJ
14	Oxyoctaline formate	65405-72-3	DFHJK
16	4-methyl-1-oxaspiro[5.5]undecan-4-	57094-40-3	CFGIJK
	ol
17	7-methyl-2H-benzo[b][1,4]dioxepin-	28940-11-6	CGIK
	3(4H)-one
18	1,8-dioxacycloheptadecan-9-one	1725-01-5	DGJ
21	4-(tert-pentyl)cyclohexan-1-one	16587-71-6	ADFGIJKL
22	o-Phenyl anisol	86-26-0	DEFHJK
23	3a,5,6,7,8,8b-hexahydro-	823178-41-2	DEFHJK
	2,2,6,6,7,8,8-heptamethyl-4H-
	indeno(4,5-d)-1,3-dioxole
25	7-isopropyl-8,8-dimethyl-6,10-	62406-73-9	BDEFHIJK
	dioxaspiro[4.5]decane
28	Octyl 2-furoate	39251-88-2	DEFHJK
29	Octyl acetate	112-14-1	BDEFHJKL
30	octanal propylene glycol acetal	74094-61-4	BDEFHJKL
31	Octanal	124-13-0	ACHIKL
32	Octanal dimethyl acetal	10022-28-3	ACEFGJKL
33	Myrcene	123-35-3	ADEFGIKL
34	Myrcenol	543-39-5	BCEFGIJK
35	Myrcenyl acetate	1118-39-4	ADEFGJK
36	Myristaldehyde	124-25-4	DFHJK
37	Myristicine	607-91-0	CGJK
38	Myristyl nitrile	629-63-0	DEFHJK
39	2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-	103614-86-4	DEFHIJK
	octahydronaphthalen-1-ol
42	Ocimenol	5986-38-9	BCHIJK
43	Ocimenol	28977-58-4	BCHIJK
47	Nopyl acetate	128-51-8	DEFHJK
48	Nootkatone	4674-50-4	DHJK
49	Nonyl alcohol	143-08-8	BDEFGIJKL
50	Nonaldehyde	124-19-6	ADHIKL
52	12-methyl-14-tetradec-9-enolide	223104-61-8	DFHJK
57	N-ethyl-p-menthane-3-carboxamide	39711-79-0	DEFGIJK
61	1-(3-methylbenzofuran-2-yl)ethan-1-	23911-56-0	CEFHIK
	one
62	2-methoxynaphthalene	93-04-9	BDEFHK
63	Nerolidol	7212-44-4	DEFHJK
64	Nerol	106-25-2	BCHIK
65	1-ethyl-3-	31996-78-8	ACEFHIJKL
	methoxytricyclo[2.2.1.02,6]heptane
67	Methyl (E)-non-2-enoate	111-79-5	ADEFHJKL
68	10-isopropyl-2,7-dimethyl-1-	89079-92-5	BDEFHIJK
	oxaspiro[4.5]deca-3,6-diene
69	2-(2-(4-methylcyclohex-3-en-1-	95962-14-4	DHJK
	yl)propyl)cyclopentan-1-one
70	Myrtenal	564-94-3	ACFHIJKL
71	(E)-4-(2,2,3,6-	54992-90-4	BDEFHIJK
	tetramethylcyclohexyl)but-3-en-2-
	one
74	Myraldyl acetate	53889-39-7	DHJK
75	Musk tibetine	145-39-1	DHIJ
76	1,7-dioxacycloheptadecan-8-one	3391-83-1	DGJ
77	Musk ketone	81-14-1	DHJ
78	Musk ambrette	83-66-9	DHIJ
79	3-methylcyclopentadecan-1-one	541-91-3	DEFHJK
80	(E)-3-methylcyclopentadec-4-en-1-	82356-51-2	DHJK
	one
82	3-methyl-4-phenylbutan-2-ol	56836-93-2	BCEFHIK
83	1-(4-isopropylcyclohexyl)ethan-1-ol	63767-86-2	BDEFHIJK
85	Milk Lactone	72881-27-7	DEFHJK
91	Methyl octine carbonate	111-80-8	BDEFHKL
92	Methyl octyl acetaldehyde	19009-56-4	ADFHJKL
93	6,6-dimethoxy-2,5,5-trimethylhex-2-	67674-46-8	ACHIJKL
	ene
98	Methyl phenylethyl carbinol	2344-70-9	BCEFHIK
100	Methyl stearate	112-61-8	DEFHJ
101	Methyl nonyl acetaldehyde dimethyl	68141-17-3	BDEFHJK
	acetal
102	Methyl nonyl ketone	112-12-9	BDFHJKL
103	Methyl nonyl acetaldehyde	110-41-8	BDFHJK
104	Methyl myristate	124-10-7	DEFHJK
105	Methyl linoleate	112-63-0	DEFHJ
106	Methyl lavender ketone	67633-95-8	CFHJK
108	Methyl isoeugenol	93-16-3	ACEFHK
109	Methyl hexadecanoate	112-39-0	DEFHJK
110	Methyl eugenol	93-15-2	ACEFHK
112	Methyl epijasmonate	1211-29-6	CHJK
113	Methyl dihydrojasmonate	24851-98-7	DFHJK
114	Methyl diphenyl ether	3586-14-9	DEFHJK
117	Methyl cinnamate	103-26-4	BCEFHK
119	Methyl chavicol	140-67-0	ADEFHK
120	Methyl beta-naphthyl ketone	93-08-3	CEFHK
122	Methyl 2-octynoate	111-12-6	ACEFHKL
123	Methyl alpha-cyclogeranate	28043-10-9	ACHIJKL
126	Methoxycitronellal	3613-30-7	ACFGIJK
128	Menthone 1,2-glycerol ketal	67785-70-0	CEFHJ
	(racemic)
130	Octahydro-1H-4,7-methanoindene-1-	30772-79-3	BCFHIJKL
	carbaldehyde
134	3-(3-(tert-butyl)phenyl)-2-	62518-65-4	BDHJK
	methylpropanal
135	(E)-4-(4,8-dimethylnona-3,7-dien-1-	38462-23-6	DEFHJK
	yl)pyridine
137	(E)-trideca-3,12-dienenitrile	134769-33-8	DEFHJK
140	2,2-dimethyl-3-(m-tolyl)propan-1-ol	103694-68-4	CEFHIJK
141	2,4-dimethyl-4,4a,5,9b-	27606-09-3	CEFHJK
	tetrahydroindeno[1,2-d][1,3]dioxine
142	Maceal	67845-30-1	BDFHJK
143	4-(4-hydroxy-4-	31906-04-4	CHJ
	methylpentyl)cyclohex-3-ene-1-
	carbaldehyde
145	l-Limonene	5989-54-8	ADEFGIJKL
146	(Z)-3-hexen-1-yl-2-cyclopenten-1-	53253-09-1	BDHK
	one
148	Linalyl octanoate	10024-64-3	DEFHJ
149	Linalyl isobutyrate	78-35-3	BDHJK
152	Linalyl benzoate	126-64-7	DFHJ
153	Linalyl anthranilate	7149-26-0	DFHJ
155	Linalool oxide (furanoid)	60047-17-8	BCHIJK
156	linalool oxide	1365-19-1	CGIJK
158	(2Z,6E)-3,7-dimethylnona-2,6-	61792-11-8	BDEFHJK
	dienenitrile
159	3-(4-methylcyclohex-3-en-1-	6784-13-0	ACFHIJK
	yl)butanal
161	(2,5-dimethyl-1,3-dihydroinden-2-	285977-85-7	CEFHJK
	yl)methanol
162	3-(4-(tert-butyl)phenyl)-2-	80-54-6	BDHJK
	methylpropanal
167	(E)-1-(1-methoxypropoxy)hex-3-ene	97358-54-8	ACEFGJKL
168	Leaf acetal	88683-94-7	ACEFGJKL
170	l-Carveol	2102-58-1	BCHIJK
174	Lauryl alcohol	112-53-8	DEFGJK
175	Lauryl acetate	112-66-3	DEFHJK
176	Lauric acid	143-07-7	DEFHJ
177	Lactojasmone	7011-83-8	BDEFHIJKL
178	Lauraldehyde	112-54-9	BDFHJK
179	3,6-dimethylhexahydrobenzofuran-	92015-65-1	BCEFHIJKL
	2(3H)-one
182	4-(1-ethoxyvinyl)-3,3,5,5-	36306-87-3	BDFHIJK
	tetramethylcyclohexan-1-one
183	Khusimol	16223-63-5	CEFHJK
184	5-(sec-butyl)-2-(2,4-	117933-89-8	DEFHJ
	dimethylcyclohex-3-en-1-yl)-5-
	methyl-1,3-dioxane
185	(1-methyl-2-((1,2,2-	198404-98-7	DEFHJK
	trimethylbicyclo[3.1.0]hexan-3-
	yl)methyl)cyclopropyl)methanol
186	2-propylheptanenitrile	208041-98-9	ADEFHIJKL
187	(E)-6-(pent-3-en-1-yl)tetrahydro-2H-	32764-98-0	BCFHIKL
	pyran-2-one
189	2-hexylcyclopentan-1-one	13074-65-2	BDFHJKL
190	2-methyl-4-phenyl-1,3-dioxolane	33941-99-0	BCEFGIK
192	2,6,9,10-tetramethyl-1-	71078-31-4	BDEFHIJK
	oxaspiro(4.5)deca-3,6-diene
193	Isopulegol	89-79-2	BCEFHIJKL
195	Isopropyl palmitate	142-91-6	DEFHJ
196	Isopropyl myristate	110-27-0	DEFHJK
197	Isopropyl dodecanoate	10233-13-3	DEFHJK
199	Isopimpinellin	482-27-9	CFGJ
206	Iso3-methylcyclopentadecan-1-one	3100-36-5	DEFGJK
208	Isomenthone	491-07-6	ADEFGIJKL
209	Isojasmone	95-41-0	BDFHJKL
210	Isomenthone	36977-92-1	ADEFGIJKL
211	Isohexenyl cyclohexenyl	37677-14-8	DFHJK
	carboxaldehyde
212	Isoeugenyl benzyl ether	120-11-6	DFHJ
215	1-((2S,3S)-2,3,8,8-tetramethyl-	54464-57-2	DHJK
	1,2,3,4,5,6,7,8-octahydronaphthalen-
	2-yl)ethan-1-one
218	Isocyclocitral	1335-66-6	ACFHIJKL
221	Isobutyl quinoline	65442-31-1	DEFHJK
227	Isobornylcyclohexanol	68877-29-2	DEFHJK
228	Isobornyl propionate	2756-56-1	BDEFHIJK
229	Isobornyl isobutyrate	85586-67-0	BDEFHIJK
230	Isobornyl cyclohexanol	66072-32-0	DEFHJK
231	Isobornyl acetate	125-12-2	ADEFHIJKL
233	Isobergamate	68683-20-5	DEFHJK
234	Isoamyl undecylenate	12262-03-2	DEFHJK
238	Isoamyl laurate	6309-51-9	DEFHJK
242	Isoambrettolide	28645-51-4	DGJ
243	Irisnitrile	29127-83-1	ADEFHKL
244	Indolene	68527-79-7	DEFHJ
246	Indol/Hydroxycitronellal Schiff base	67801-36-9	DEFHJ
247	4,4a,5,9b-tetrahydroindeno[1,2-	18096-62-3	BCEFGJK
	d][1,3]dioxine
249	Hydroxy-citronellol	107-74-4	CEFGIJK
252	2-cyclododecylpropan-1-ol	118562-73-5	DEFHJK
253	Hydrocitronitrile	54089-83-7	CEFHJK
254	Hydrocinnamyl alcohol	122-97-4	BCEFHIK
256	Hydratropaldehyde dimethyl acetal	90-87-9	ACEFHJK
259	5-ethyl-4-hydroxy-2-methylfuran-	27538-09-6	CFGIK
	3(2H)-one
260	2,3-dihydro-3,3-dimethyl-1H-indene-	173445-44-8	DHJK
	5-propanal
261	3-(3,3-dimethyl-2,3-dihydro-1H-	173445-65-3	DHJK
	inden-5-yl)propanal
263	Hexyl octanoate	1117-55-1	DEFHJK
267	Hexyl hexanoate	6378-65-0	DEFHJKL
269	Hexyl cinnamic aldehyde	101-86-0	DHJ
271	Hexyl benzoate	6789-88-4	DEFHJK
274	Hexenyl tiglate	84060-80-0	BDEFHJK
276	(E)-3,7-dimethylocta-2,6-dien-1-yl	3681-73-0	DEFHJ
	palmitate
277	Hexadecanolide	109-29-5	DEFGJK
278	2-butyl-4,4,6-trimethyl-1,3-dioxane	54546-26-8	ADEFHIJKL
280	Ethyl (1R,2R,3R,4R)-3-	116126-82-0	BDEFHIJK
	isopropylbicyclo[2.2.1]hept-5-ene-2-
	carboxylate
281	3a,4,5,6,7,7a-hexahydro-1H-4,7-	5413-60-5	CEFGJK
	methanoinden-6-yl acetate
285	2-(1-(3,3-	141773-73-1	DEFHJ
	dimethylcyclohexyl)ethoxy)-2-
	methylpropyl propionate
286	Heliotropine diethyl acetal	40527-42-2	CEFGJ
288	Helional	1205-17-0	CHJK
289	(E)-oxacyclohexadec-13-en-2-one	111879-80-2	DGJK
290	Gyrane	24237-00-1	ADEFHIJKL
292	Guaiol	489-86-1	DEFHJK
293	1-(2,6,6-trimethylcyclohex-2-en-1-	68611-23-4	DHJK
	yl)pentan-3-one
294	Ethyl 2-ethyl-6,6-dimethylcyclohex-	57934-97-1	BDEFHIJK
	2-ene-1-carboxylate
295	Germacrene B	15423-57-1	DEFHJK
296	Germacrene D	23986-74-5	DEFHJK
300	Geranyl phenylacetate	102-22-7	DFHJ
301	Geranyl phenyl acetate	71648-43-6	DFHJ
303	Geranyl linalool	1113-21-9	DFHJ
307	Geranyl cyclopentanone	68133-79-9	DHJK
316	gamma-Undecalactone (racemic)	104-67-6	DEFHJKL
317	gamma-Terpinyl acetate	10235-63-9	BDHJK
318	gamma-Terpineol	586-81-2	BCGIJK
321	gamma-Nonalactone	104-61-0	BCEFHIKL
322	gamma-Muurolene	30021-74-0	DEFHJKL
323	gamma-(E)-6-(pent-3-en-1-	63095-33-0	BCEFHKL
	yl)tetrahydro-2H-pyran-2-one
324	gamma-Ionone	79-76-5	BDEFHIJK
325	gamma-Himachalene	53111-25-4	BDEFHJKL
328	gamma-Gurjunene	22567-17-5	DEFHJKL
329	gamma-Eudesmol	1209-71-8	DFHJK
330	gamma-Dodecalactone	2305-05-7	DEFHJK
331	gamma-Damascone	35087-49-1	BDEFHIJK
332	gamma-Decalactone	706-14-9	BDEFHIJKL
333	gamma-Cadinene	39029-41-9	DEFHJKL
334	1-(3,3-dimethylcyclohexyl)pent-4-	56973-87-6	BDEFHJK
	en-1-one
335	4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-	1222-05-5	DEFHJK
	hexahydrocyclopenta[g]isochromene
336	Furfuryl octanoate	39252-03-4	DEFHJK
338	Furfuryl hexanoate	39252-02-3	CEFHJK
339	Furfuryl heptanoate	39481-28-2	CEFHJK
342	2-methyldecanenitrile	69300-15-8	BDEFHJKL
343	8,8-dimethyl-3a,4,5,6,7,7a-	76842-49-4	DEFHJK
	hexahydro-1H-4,7-methanoinden-6-
	yl propionate
344	Ethyl (3aR,4S,7R,7aR)-octahydro-	80657-64-3	DEFHIJK
	3aH-4,7-methanoindene-3a-
	carboxylate
347	Diethyl cyclohexane-1,4-	72903-27-6	CEFHJK
	dicarboxylate
349	(6-isopropyl-9-methyl-1,4-	63187-91-7	CEFHJ
	dioxaspiro[4.5]decan-2-yl)methanol
350	2-isobutyl-4-methyltetrahydro-2H-	63500-71-0	BCEFHIJK
	pyran-4-ol
352	Undec-10-enenitrile	53179-04-7	BDEFHJK
353	(Z)-6-ethylideneoctahydro-2H-5,8-	69486-14-2	CEFGJK
	methanochromen-2-one
356	3-(2-ethylphenyl)-2,2-	67634-15-5	BDHJK
	dimethylpropanal
358	(E)-4,8-dimethyldeca-4,9-dienal	71077-31-1	BDFHJK
359	(E)-4-((3aR,4R,7R,7aR)-	501929-47-1	DEFHJK
	1,3a,4,6,7,7a-hexahydro-5H-4,7-
	methanoinden-5-ylidene)-3-
	methylbutan-2-ol
360	8,8-dimethyl-3a,4,5,6,7,7a-	171102-41-3	DEFHJK
	hexahydro-1H-4,7-methanoinden-6-
	yl acetate
361	3-(4-ethylphenyl)-2,2-	134123-93-6	DEFHJK
	dimethylpropanenitrile
362	2-heptylcyclopentan-1-one	137-03-1	DFHJKL
363	1-ethoxyethoxy Cyclododecane	389083-83-4	DEFHJK
364	3-cyclohexene-1-carboxylic acid,	815580-59-7	ACHIJKL
	2,6,6-trimethyl-, methyl ester
368	Farnesyl acetate	29548-30-9	DEFHJK
369	Farnesol	4602-84-0	DEFHJK
370	Oxacyclohexadecan-2-one	106-02-5	DEFGJK
371	1-cyclopentadec-4-en-1-one	14595-54-1	DEFGJK
372	1-cyclopentadec-4-en-1-one	35720-57-1	DEFGJK
373	2-methoxy-4-(4-	128489-04-3	CGJ
	methylenetetrahydro-2H-pyran-2-
	yl)phenol
374	Eugenyl acetate	93-28-7	CFHJK
375	Eugenol	97-53-0	CHIK
377	Ethylmethylphenylglycidate	77-83-8	CFHJK
378	Ethylene brassylate	105-95-3	DFGJ
381	Ethyl undecylenate	692-86-4	DEFHJK
385	Ethyl palmitate	628-97-7	DEFHJ
386	Ethyl nonanoate	123-29-5	BDEFHJKL
388	Ethyl myristate	124-06-1	DEFHJK
390	Ethyl linalool	10339-55-6	BCEFHJK
391	Ethyl laurate	106-33-2	DEFHJK
394	Ethyl hexyl ketone	925-78-0	ADFHIKL
397	Ethyl decanoate	110-38-3	BDEFHJK
398	Ethyl gamma-Safranate	35044-57-6	ADHIJK
407	Ethyl 3-phenylglycidate	121-39-1	CGJK
413	6-ethyl-2,10,10-trimethyl-1-	79893-63-3	BDEFHIJK
	oxaspiro[4.5]deca-3,6-diene
414	Elemol	639-99-6	DEFHJK
415	(2-(1-ethoxyethoxy)ethyl)benzene	2556-10-7	BCEFHJK
416	(E)-3-methyl-5-(2,2,3-	67801-20-1	DHJK
	trimethylcyclopent-3-en-1-yl)pent-4-
	en-2-ol
417	d-xylose	58-86-6	CGIJ
418	(E)-4-((3aS,7aS)-octahydro-5H-4,7-	30168-23-1	DFHJK
	methanoinden-5-ylidene)butanal
421	Dodecanal dimethyl acetal	14620-52-1	DEFHJK
424	d-Limonene	5989-27-5	ADEFGIJKL
425	Dipropylene Glycol	25265-71-8	CEFGIK
426	Dispirone	83863-64-3	BDEFHJK
428	Diphenyloxide	101-84-8	BDEFHK
429	Diphenylmethane	101-81-5	DEFGK
432	Dimethyl benzyl carbinyl butyrate	10094-34-5	DEFHJK
436	2,6-dimethyloct-7-en-4-one	1879-00-1	ADEFHIJKL
441	Octahydro-1H-4,7-methanoinden-5-	64001-15-6	DEFHJKL
	yl acetate
444	Dihydrocarveol acetate	20777-49-5	BDEFHIJK
445	Dihydrocarveol	619-01-2	BCEFHIJKL
449	Dihydro Linalool	18479-51-1	BCEFGIJKL
450	Dihydro Isojasmonate	37172-53-5	DHJK
453	Dibutyl sulfide	544-40-1	ADEFHIKL
457	Dibenzyl	103-29-7	DEFGJK
459	delta-Undecalactone	710-04-3	DEFHJKL
461	delta-Elemene	20307-84-0	BDEFHJK
462	delta-Guaiene	3691-11-0	DEFHJKL
463	delta-Dodecalactone	713-95-1	DEFHJK
464	delta-Decalactone	705-86-2	BDEFHIJKL
465	delta-Cadinene	483-76-1	DEFHJKL
466	delta-damascone	57378-68-4	ADHIJK
467	delta-Amorphene	189165-79-5	DEFHJKL
468	delta-3-Carene	13466-78-9	ADEFGIJKL
470	Decylenic alcohol	13019-22-2	BDEFHJK
471	Decyl propionate	5454-19-3	DEFHJK
473	Decanal diethyl acetal	34764-02-8	DEFHJK
474	Decahydro-beta-naphthol	825-51-4	BCEFGIK
475	1-cyclohexylethyl (E)-but-2-enoate	68039-69-0	BDFHJK
478	3-(4-isopropylphenyl)-2-	103-95-7	BDFHJK
	methylpropanal
479	Cyclotetradecane	295-17-0	DEFGJKL
480	Cyclopentadecanone	502-72-7	DEFGJK
482	Cyclohexyl salicylate	25485-88-5	DFGJ
484	3a,4,5,6,7,7a-hexahydro-1H-4,7-	113889-23-9	DEFHJK
	methanoinden-6-yl butyrate
485	Cyclic ethylene dodecanedioate	54982-83-1	DFGJ
486	8,8-dimethyl-1,2,3,4,5,6,7,8-	68991-97-9	DHJK
	octahydronaphthalene-2-
	carbaldehyde
487	3a,4,5,6,7,7a-hexahydro-1H-4,7-	67634-20-2	DEFHJK
	methanoinden-5-yl isobutyrate
488	Curzerene	17910-09-7	DHJK
491	Cumic alcohol	536-60-7	CHIJK
493	Coumarone	1646-26-0	BCEFHIK
497	2-(3-phenylpropyl)pyridine	2110-18-1	CEFHJK
498	Dodecanenitrile	2437-25-4	DEFHJK
501	(E)-cycloheptadec-9-en-1-one	542-46-1	DEFGJ
502	Citryl acetate	6819-19-8	DFHJK
503	Citrus Propanol	15760-18-6	CEFHIJK
505	Citronitrile	93893-89-1	CEFHJK
519	Citral propylene glycol acetal	10444-50-5	CEFHJK
520	Citral dimethyl acetal	7549-37-3	BCEFHJK
521	Citral diethyl acetal	7492-66-2	BDEFHJK
524	cis-Ocimene	3338-55-4	ADGIKL
527	cis-Limonene oxide	13837-75-7	ADEFGIJKL
529	Cis-iso-ambrettolide	36508-31-3	DGJ
530	cis-6-nonenol	35854-86-5	BCEFHIKL
531	cis-carveol	1197-06-4	BCHIJK
532	cis-4-Decen-1-al	21662-09-9	ADHKL
534	cis-3-hexenyl-cis-3-hexenoate	61444-38-0	BDEFHJK
537	cis-3-Hexenyl salicylate	65405-77-8	DEFGJ
541	Cis-3-hexenyl Benzoate	25152-85-6	DEFHJK
544	cis-3-Hexenyl 2-methylbutyrate	53398-85-9	ADEFHJKL
546	cis-3, cis-6-nonadienol	53046-97-2	ACEFHK
548	Cinnamyl propionate	103-56-0	DEFHJK
550	Cinnamyl isobutyrate	103-59-3	DEFHJK
551	Cinnamyl formate	104-65-4	BCEFHK
552	Cinnamyl cinnamate	122-69-0	DHJ
553	Cinnamyl acetate	103-54-8	BCEFHK
555	Cinnamic alcohol	104-54-1	BCEFHIK
558	Cetyl alcohol	36653-82-4	DEFHJ
559	(E)-1-(2,6,6-trimethylcyclohex-2-en-	79-78-7	DHJK
	1-yl)hepta-1,6-dien-3-one
560	2-methyl-4-(2,6,6-trimethylcyclohex-	65405-84-7	DFHJK
	1-en-1-yl)butanal
561	(3aR,5aR,9aR,9bR)-3a,6,6,9a-	3738-00-9	DEFHJK
	tetramethyldodecahydronaphtho[2,1-
	b]furan
562	1,6-dioxacycloheptadecan-7-one	6707-60-4	DGJ
563	1-(6-(tert-butyl)-1,1-dimethyl-2,3-	13171-00-1	DEFHJK
	dihydro-1H-inden-4-yl)ethan-1-one
565	Cedryl methyl ether	19870-74-7	ADEFHJK
566	Cedryl formate	39900-38-4	BDEFHJK
567	Cedryl acetate	77-54-3	DEFHJK
568	(4Z,8Z)-1,5,9-trimethyl-13-	71735-79-0	DFHJK
	oxabicyclo[10.1.0]trideca-4,8-diene
569	Cedrol	77-53-2	DEFHJK
570	5-methyl-1-(2,2,3-	139539-66-5	DEFHJK
	trimethylcyclopent-3-en-1-yl)-6-
	oxabicyclo[3.2.1]octane
571	5-methyl-1-(2,2,3-	426218-78-2	DFHJ
	trimethylcyclopent-3-en-1-yl)-6-
	oxabicyclo[3.2.1]octane
572	1,1,2,3,3-pentamethyl-1,2,3,5,6,7-	33704-61-9	BDEFHIJK
	hexahydro-4H-inden-4-one
573	Caryophyllene alcohol acetate	32214-91-8	DEFHJK
574	Caryolan-1-ol	472-97-9	DEFHJK
577	Carvyl acetate	97-42-7	BDHIJK
578	Caprylnitrile	124-12-9	ACEFGIKL
580	Caprylic alcohol	111-87-5	ACEFGIKL
581	Caprylic acid	124-07-2	BCEFHIK
582	Capric acid	334-48-5	DEFHJK
584	Capraldehyde	112-31-2	ADHKL
586	3-(4-methoxyphenyl)-2-	5462-06-6	BCHJK
	methylpropanal
587	Camphorquinone	10373-78-1	ACEFGIJK
589	Camphene	79-92-5	ADEFGIJKL
591	Ethyl 2-methyl-4-oxo-6-	59151-19-8	DHJ
	pentylcyclohex-2-ene-1-carboxylate
592	Butylated hydroxytoluene	128-37-0	DEFGIJK
594	Butyl stearate	123-95-5	DEFHJ
595	Butyl butyryl lactate	7492-70-8	CEFGJK
599	Butyl 10-undecenoate	109-42-2	DEFHJK
600	2-methyl-4-(2,2,3-	72089-08-8	DEFHJK
	trimethylcyclopent-3-en-1-yl)butan-
	1-ol
601	3-(4-(tert-butyl)phenyl)propanal	18127-01-0	BDHJK
603	Bornyl isobutyrate	24717-86-0	BDEFHIJK
604	Bornyl acetate	76-49-3	ADEFHIJKL
606	2-ethoxy-2,6,6-trimethyl-9-	68845-00-1	BDEFHJK
	methylenebicyclo[3.3.1]nonane
607	(ethoxymethoxy)cyclododecane	58567-11-6	DEFHJK
608	Bisabolene	495-62-5	DEFHJK
609	Bigarade oxide	72429-08-4	ADEFHJKL
610	beta-Vetivone	18444-79-6	DHJK
611	beta-Terpinyl acetate	10198-23-9	BDHJK
612	beta-Terpineol	138-87-4	BCGIJK
613	beta-Sinensal	60066-88-8	DHJK
614	beta-Sesquiphellandrene	20307-83-9	DEFHJK
615	beta-Selinene	17066-67-0	BDEFGJK
616	beta-Santalol	77-42-9	DEFHJK
618	beta-Pinene	127-91-3	ADEFGIJKL
620	beta-Naphthyl ethyl ether	93-18-5	BDEFHJK
621	beta-Patchoulline	514-51-2	BDEFGJKL
624	beta-Himachalene Oxide	57819-73-5	BDFHJK
625	beta-Himachalene	1461-03-6	DEFHJKL
626	beta-Guaiene	88-84-6	DEFHJKL
627	(2,2-dimethoxyethyl)benzene	101-48-4	DHJK
628	beta-Farnesene	18794-84-8	DEFHJK
631	beta-Copaene	18252-44-3	BDEFHJKL
632	beta-Cedrene	546-28-1	BDEFGJKL
633	beta-Caryophyllene	87-44-5	DEFHJKL
635	beta-Bisabolol	15352-77-9	DFHJK
636	Beta ionone epoxide	23267-57-4	BDEFHIJK
638	Bergaptene	484-20-8	CGJ
639	Benzyl-tert-butanol	103-05-9	CEFGJK
644	Benzyl laurate	140-25-0	DEFHJ
649	Benzyl dimethyl carbinol	100-86-7	BCEFGIK
650	Benzyl cinnamate	103-41-3	DHJ
653	Benzyl benzoate	120-51-4	DHJ
655	Benzophenone	119-61-9	DEFHK
658	7-isopentyl-2H-	362467-67-2	DHJ
	benzo[b][1,4]dioxepin-3(4H)-one
659	2′-isopropyl-1,7,7-	188199-50-0	DEFHJK
	trimethylspiro[bicyclo[2.2.1]heptane-
	2,4′-[1,3]dioxane]
660	4-(4-methylpent-3-en-1-yl)cyclohex-	21690-43-7	DEFHJK
	3-ene-1-carbonitrile
661	Aurantiol	89-43-0	DEFHJ
663	Anisyl phenylacetate	102-17-0	DFHJ
668	Methyl (E)-octa-4,7-dienoate	189440-77-5	ACEFHKL
671	Amyl Cinnamate	3487-99-8	DEFHJK
673	(3aR,5aS,9aS,9bR)-3a,6,6,9a-	6790-58-5	DEFHJK
	tetramethyldodecahydronaphtho[2,1-
	b]furan
674	(4aR,5R,7aS,9R)-2,2,5,8,8,9a-	211299-54-6	DEFHJK
	hexamethyloctahydro-4H-4a,9-
	methanoazuleno[5,6-d][1,3]dioxole
675	2,5,5-trimethyl-1,2,3,4,5,6,7,8-	71832-76-3	DEFHJK
	octahydronaphthalen-2-ol
676	2,5,5-trimethyl-1,2,3,4,5,6,7,8-	41199-19-3	DEFHJK
	octahydronaphthalen-2-ol
677	1-((2-(tert-	139504-68-0	DEFHJK
	butyl)cyclohexyl)oxy)butan-2-ol
678	(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-	57345-19-4	DEFHJ
	tetramethyldodecahydro-5H-3,5a-
	epoxynaphtho[2,1-c]oxepine
679	2,2,6,6,7,8,8-heptamethyldecahydro-	476332-65-7	ADEFHJK
	2H-indeno[4,5-b]furan
680	2,2,6,6,7,8,8-heptamethyldecahydro-	647828-16-8	ADEFHJK
	2H-indeno[4,5-b]furan
681	Amber acetate	37172-02-4	BDEFHJK
682	Alpinofix	811436-82-5	DEFHJ
683	alpha-Thujone	546-80-5	ADEFGIJKL
684	alpha-Vetivone	15764-04-2	DHJK
686	alpha-Terpinyl propionate	80-27-3	BDEFHJK
691	alpha-Sinensal	17909-77-2	DHJK
692	alpha-Selinene	473-13-2	BDEFHJK
693	alpha-Santalene	512-61-8	ADEFHJKL
694	alpha-Santalol	115-71-9	DEFHJK
696	alpha-Patchoulene	560-32-7	ADEFHJKL
697	alpha-neobutenone	56973-85-4	BDHJK
698	alpha-Muurolene	10208-80-7	DEFHJKL
700	alpha-methyl ionone	127-42-4	BDHJK
702	alpha-Limonene	138-86-3	ADEFGIJKL
704	alpha-Irone	79-69-6	BDHJK
706	alpha-Humulene	6753-98-6	DEFHJK
707	alpha-Himachalene	186538-22-7	BDEFHJK
708	alpha-Gurjunene	489-40-7	BDEFHJKL
709	alpha-Guaiene	3691-12-1	DEFHJKL
710	alpha-Farnesene	502-61-4	DEFHJK
711	alpha-Fenchene	471-84-1	ADEFGIJKL
712	alpha-Eudesmol	473-16-5	DEFHJK
713	alpha-Curcumene	4176-17-4	DEFHJK
714	alpha-Cubebene	17699-14-8	ADEFHJKL
715	alpha-Cedrene epoxide	13567-39-0	ADEFHJK
716	alpha-Cadinol	481-34-5	DEFHJK
717	alpha-Cadinene	24406-05-1	DEFHJKL
718	alpha-Bisabolol	515-69-5	DFHJK
719	alpha-bisabolene	17627-44-0	DEFHJK
720	alpha-Bergamotene	17699-05-7	BDEFHJKL
721	alpha-Amylcinnamyl alcohol	101-85-9	DEFHJ
722	alpha-Amylcinnamyl acetate	7493-78-9	DEFHJ
723	alpha-Amylcinnamaldehyde diethyl	60763-41-9	DEFHJ
	acetal
724	alpha-Amylcinnamaldehyde	122-40-7	DHJK
725	alpha-Amorphene	23515-88-0	DEFHJKL
726	alpha-Agarofuran	5956-12-7	BDEFHJK
727	1-methyl-4-(4-methyl-3-penten-1-	52475-86-2	DFHJK
	yl)-3-Cyclohexene-1-carboxaldehyde
730	1-Phenyl-2-pentanol	705-73-7	CEFHK
731	1-Phenyl-3-methyl-3-pentanol	10415-87-9	CEFHJK
733	2,3,4-trimethoxy-benzaldehyde	2103-57-3	BCGI
735	2,4,5-trimethoxy-benzaldehyde	4460-86-0	BCG
736	2,4,6-trimethoxybenzaldehyde	830-79-5	BCGI
738	2,4-Nonadienal	6750-03-4	ACHKL
741	2,6,10-Trimethylundecanal	105-88-4	BDFGJK
742	alpha,4-Dimethyl benzenepropanal	41496-43-9	ACHJK
746	Allyl cyclohexyl propionate	2705-87-5	BDEFHJK
748	Allyl amyl glycolate	67634-00-8	BCEFGJK
750	Allo-aromadendrene	25246-27-9	BDEFHJKL
752	Aldehyde C-11	143-14-6	ADHJK
754	Methyl (E)-2-(((3,5-	94022-83-0	DEFHJ
	dimethylcyclohex-3-en-1-
	yl)methylene)amino)benzoate
757	2,6,10-trimethylundec-9-enal	141-13-9	BDFHJK
758	Acetoxymethyl-isolongifolene	59056-62-1	BDEFHJK
	(isomers)
763	Acetate C9	143-13-5	BDEFHJKL
764	Acetarolle	744266-61-3	DFHJK
766	Acetaldehyde phenylethyl propyl	7493-57-4	CEFHJK
	acetal
767	Acetaldehyde dipropyl acetal	105-82-8	ACEFGIKL
768	Acetaldehyde benzyl 2-methoxyethyl	7492-39-9	BCEFHJK
	acetal
769	(Z)-2-(4-methylbenzylidene)heptanal	84697-09-6	DHJ
770	9-decenal	39770-05-3	ADHKL
771	8-Hexadecenolide	123-69-3	DGJ
772	7-Methoxycoumarin	531-59-9	CHK
774	7-epi-alpha-Selinene	123123-37-5	BDEFHJK
775	7-eip-alpha-Eudesmol	123123-38-6	DEFHJK
776	7-Acetyl-1,1,3,4,4,6-	1506-02-1	DEFHJ
	hexamethyltetralin
778	6-Isopropylquinoline	135-79-5	CEFHJK
781	6,6-dimethyl-2-norpinene-2-	33885-51-7	BCFHJK
	propionaldehyde
782	6,10,14-trimethyl-2-Pentadecanone	502-69-2	DEFHJK
786	5-Isopropenyl-2-methyl-2-	13679-86-2	ACGIJKL
	vinyltetrahydrofuran
788	5-Cyclohexadecenone	37609-25-9	DEFGJK
791	4-Terpinenol	562-74-3	BCHIJK
792	4-Pentenophenone	3240-29-7	BCEFHIK
800	4-Carvomenthenol	28219-82-1	BCHIJK
802	4,5,6,7-Tetrahydro-3,6-	494-90-6	BCEFHIJKL
	dimethylbenzofuran
803	4-(p-Methoxyphenyl)-2-butanone	104-20-1	BCEFHJK
804	3-Thujopsanone	25966-79-4	BDEFHJK
805	3-Propylidenephthalide	17369-59-4	CEFHK
806	3-Nonylacrolein	20407-84-5	BDFHJK
807	3-Methyl-5-phenyl-1-pentanal	55066-49-4	BDFHJK
814	3-Hexenyl isovalerate	10032-11-8	ADEFHJKL
821	3,6-Dimethyl-3-octanyl acetate	60763-42-0	ADEFHIJKL
824	3,4,5-trimethoxybenzaldehyde	86-81-7	BCGIK
826	3-(p-	7775-00-0	BDFHJK
	Isopropylphenyl)propionaldehyde
827	2-Undecenenitrile	22629-48-7	BDEFHJK
828	2-Undecenal	2463-77-6	ADHJK
829	2-trans-6-trans-Nonadienal	17587-33-6	ACHKL
831	2-Phenylethyl butyrate	103-52-6	DEFHJK
833	2-Phenyl-3-(2-furyl)prop-2-enal	57568-60-2	CHJ
834	2-Phenoxyethanol	122-99-6	BCEFGIK
837	2-Nonen-1-al	2463-53-8	ADHKL
839	2-Nonanol	628-99-9	BDEFGIKL
840	2-Nonanone	821-55-6	ADFHIKL
849	2-Isobutyl quinoline	93-19-6	CEFHJK
850	2-Hexylidene cyclopentanone	17373-89-6	DFHJKL
852	2-Heptyl tetrahydrofuran	2435-16-7	BDEFHJKL
856	2-Decenal	3913-71-1	ADHKL
864	2,6-Nonadienal	26370-28-5	ACHKL
865	2,6-Nonadien-1-ol	7786-44-9	ACEFHK
866	2,6-dimethyl-octanal	7779-07-9	ADFGIJKL
868	1-Decanol	112-30-1	BDEFGJK
869	1-Hepten-1-ol, 1-acetate	35468-97-4	ACEFHKL
870	10-Undecen-1-ol	112-43-6	DEFHJK
871	10-Undecenal	112-45-8	ADHJK
872	10-epi-gamma-Eudesmol	15051-81-7	DFHJK
873	1,8-Thiocineol	68391-28-6	ADEFHIJKL
876	1,3,5-undecatriene	16356-11-9	ADEFHJKL
877	1,2-Dihydrolinalool	2270-57-7	BCEFGIJKL
878	1,3,3-trimethyl-2-norbornanyl	13851-11-1	ADEFHIJKL
	acetate
879	1,1,2,3,3-Pentamethylindan	1203-17-4	ADHIJKL
881	(Z)-6,10-dimethylundeca-5,9-dien-2-	3239-37-0	DEFHJK
	yl acetate
884	(Z)-3-Dodecenal	68141-15-1	BCFHJK
885	(S)-gamma-Undecalactone	74568-05-1	DEFHJKL
886	(R)-gamma-Undecalactone	74568-06-2	DEFHJKL
890	(E)-6,10-dimethylundeca-5,9-dien-2-	3239-35-8	DEFHJK
	yl acetate
892	(2Z)-3-methyl-5-phenyl-2-	53243-59-7	DEFHJK
	Pentenenitrile
893	(2S,5S,6S)-2,6,10,10-tetramethyl-1-	65620-50-0	DFHIJK
	oxaspiro[4_5]decan-6-ol
894	(2E)-3-methyl-5-phenyl-2-	53243-60-0	CEFHJK
	pentenenitrile
897	(+)-Dihydrocarveol	22567-21-1	BCEFHIJKL
905	Menthone	89-80-5	ADEFGIJKL
908	(R,E)-2-methyl-4-(2,2,3-	185068-69-3	CHJK
	trimethylcyclopent-3-en-1-yl)but-2-
	en-1-ol
912	2-(8-isopropyl-6-	68901-32-6	DEFHJK
	methylbicyclo[2.2.2]oct-5-en-2-yl)-
	1,3-dioxolane
913	gamma-methyl ionone	7388-22-9	BDHIJK
914	3-(3-isopropylphenyl)butanal	125109-85-5	BDHJK
916	3-(1-ethoxyethoxy)-3,7-	40910-49-4	BDEFHJK
	dimethylocta-1,6-diene
919	3a,4,5,6,7,7a-hexahydro-1H-4,7-	17511-60-3	CEFHJK
	methanoinden-6-yl propionate
920	Bulnesol	22451-73-6	DEFHJK
922	Benzyl phenylacetate	102-16-9	DHJ
923	Benzoin	119-53-9	CEFHJ
924	(E)-1,2,4-trimethoxy-5-(prop-1-en-1-	2883-98-9	BCFGJK
	yl)benzene
925	alpha,alpha,6,6-tetramethyl	33885-52-8	BDFHJK
	bicyclo[3.1.1]hept-2-ene-propanal
926	7-epi-sesquithujene	159407-35-9	DEFHJKL
927	5-Acetyl-1,1,2,3,3,6-	15323-35-0	DEFHJK
	hexamethylindan
928	3-Methylphenethyl alcohol	1875-89-4	BCEFHIK
929	3,6-Nonadien-1-ol	76649-25-7	ACEFHK
930	2-Tridecenal	7774-82-5	BDFHJK
933	Patchouli alcohol	5986-55-0	DEFHIJK
937	p-Cresyl isobutyrate	103-93-5	BDHJK
939	p-Cresyl n-hexanoate	68141-11-7	DEFHJK
941	5-hexyl-4-methyldihydrofuran-	67663-01-8	BDEFHIJKL
	2(3H)-one
942	Ethyl (2Z,4E)-deca-2,4-dienoate	3025-30-7	BDEFHJK
943	Pelargene	68039-40-7	DEFHJK
945	2-cyclohexylidene-2-	10461-98-0	DFHJK
	phenylacetonitrile
946	Perillaldehyde	2111-75-3	ACHIJK
947	Perillyl acetate	15111-96-3	DFHJK
948	Perillyl alcohol	536-59-4	CHIJK
950	(2-isopropoxyethyl)benzene	68039-47-4	ACEFHJKL
951	Ethyl (2Z,4E)-deca-2,4-dienoate	313973-37-4	BDEFHJK
953	(2-(cyclohexyloxy)ethyl)benzene	80858-47-5	DEFHJK
954	Phenethyl 2-methylbutyrate	24817-51-4	DEFHJK
955	Phenethyl alcohol	60-12-8	BCEFGIK
959	Phenethyl phenylacetate	102-20-5	DHJ
962	Phenoxanol	55066-48-3	DEFHJK
965	Phenyl benzoate	93-99-2	DFHJK
967	Phenyl ethyl benzoate	94-47-3	DHJ
969	Phenylacetaldehyde ethyleneglycol	101-49-5	BCEFGIK
	acetal
973	2-(6,6-dimethylbicyclo[3.1.1]hept-2-	30897-75-7	ACFHIJKL
	en-2-yl)acetaldehyde
974	Pinocarveol	5947-36-4	BCEFGIJKL
976	Piperonyl acetone	55418-52-5	CEFGJ
978	3a,4,5,6,7,7a-hexahydro-1H-4,7-	68039-44-1	DEFHJK
	methanoinden-6-yl pivalate
980	(4aR,8aS)-7-methyloctahydro-1,4-	41724-19-0	CEFGJKL
	methanonaphthalen-6(2H)-one
982	p-Menth-3-en-1-ol	586-82-3	BCGIJK
985	(E)-3,3-dimethyl-5-(2,2,3-	107898-54-4	DHJK
	trimethylcyclopent-3-en-1-yl)pent-4-
	en-2-ol
988	1-methyl-4-(4-methylpent-3-en-1-	52474-60-9	DFHJK
	yl)cyclohex-3-ene-1-carbaldehyde
993	Propylene glycol	57-55-6	ACEFGIKL
998	p-Tolyl phenylacetate	101-94-0	DFHJ
1000	Ethyl 2,4,7-decatrienoate	78417-28-4	BDEFHJK
1003	2-benzyl-4,4,6-trimethyl-1,3-dioxane	67633-94-7	DEFHJK
1006	2,4-dimethyl-4-	82461-14-1	BDEFHJK
	phenyltetrahydrofuran
1007	(2R,4a′R,8a′R)-3,7′-dimethyl-	41816-03-9	DEFHJK
	3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-
	spiro[oxirane-2,2′-
	[1,4]methanonaphthalene]
1008	(Z)-6-ethylideneoctahydro-2H-5,8-	93939-86-7	BCEFHJKL
	methanochromene
1009	2-((S)-1-((S)-3,3-	236391-76-7	DFHJ
	dimethylcyclohexyl)ethoxy)-2-
	oxoethyl propionate
1010	Methyl 2,2-dimethyl-6-	81752-87-6	ADHIJKL
	methylenecyclohexane-1-carboxylate
1012	2-methyl-5-phenylpentan-1-ol	25634-93-9	DEFHJK
1016	4-methyl-2-phenyl-3,6-dihydro-2H-	60335-71-9	BCEFGJK
	pyran
1020	Sabinol	471-16-9	BCEFHIJKL
1021	Safrole	94-59-7	BCEFHK
1022	2,2,7,9-tetramethylspiro(5.5)undec-	502847-01-0	DHIJK
	8-en-1-one
1023	3-methyl-5-(2,2,3-	65113-99-7	DEFHJK
	trimethylcyclopent-3-en-1-yl)pentan-
	2-ol
1024	(Z)-2-ethyl-4-(2,2,3-	28219-61-6	DEFHJK
	trimethylcyclopent-3-en-1-yl)but-2-
	en-1-ol
1025	(E)-2-methyl-4-(2,2,3-	28219-60-5	CHJK
	trimethylcyclopent-3-en-1-yl)but-2-
	en-1-ol
1026	5-methoxyoctahydro-1H-4,7-	86803-90-9	CHJK
	methanoindene-2-carbaldehyde
1027	5-methoxyoctahydro-1H-4,7-	193425-86-4	CHJK
	methanoindene-2-carbaldehyde
1028	Sclareol	515-03-7	DEFHJ
1029	Sclareol oxide	5153-92-4	DEFHJK
1031	Selina-3,7(11)-diene	6813-21-4	DEFHJKL
1032	2-(1-(3,3-	477218-42-1	DEFHJ
	dimethylcyclohexyl)ethoxy)-2-
	methylpropyl
	cyclopropanecarboxylate
1033	3-(4-isobutylphenyl)-2-	6658-48-6	DHJK
	methylpropanal
1035	Spathulenol	6750-60-3	DEFHJK
1036	Spirambrene	533925-08-5	BCEFHJK
1037	Spirodecane	6413-26-9	BCEFGIJKL
1038	1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-	224031-70-3	DGJK
	1-one
1042	2-(4-methylthiazol-5-yl)ethan-1-ol	137-00-8	CGIKL
1043	2-(heptan-3-yl)-1,3-dioxolane	4359-47-1	ACEFHIJKL
1045	(Z)-dodec-4-enal	21944-98-9	BDFHJK
1046	tau-Cadinol	5937-11-1	DEFHJK
1047	tau-Muurolol	19912-62-0	DEFHJK
1053	Tetrahydrojasmone	13074-63-0	BDFHIJKL
1057	2,6,10,10-tetramethyl-1-	36431-72-8	BDFHIJKL
	oxaspiro[4.5]dec-6-ene
1059	Thiomenthone	38462-22-5	BDEFHIJKL
1060	Thujopsene	470-40-6	BDEFGJKL
1062	Thymol methyl ether	1076-56-8	ADHIJKL
1063	1-(2,2,6-trimethylcyclohexyl)hexan-	70788-30-6	DEFHJK
	3-ol
1064	trans, trans-2,4-Nonadienal	5910-87-2	ACHKL
1065	trans, trans-Farnesol	106-28-5	DEFHJK
1066	trans-2, cis-6-Nonadienal	557-48-2	ACHKL
1067	trans-2-Decenal	3913-81-3	ADHKL
1070	trans-2-Nonen-1-al	18829-56-6	ADHKL
1072	trans-3, cis-6-nonadienol	56805-23-3	ACEFHK
1073	trans-4-Decen-1-al	65405-70-1	ADHKL
1075	trans-ambrettolide	51155-12-5	DGJ
1077	trans-beta-ocimene	13877-91-3	ADGIKL
1078	trans-beta-Ocimene	3779-61-1	ADGIKL
1082	trans-Geraniol	106-24-1	BCHIK
1083	trans-Hedione	2570-03-8	DFHJK
1085	7-(1,1-Dimethylethyl)-2H-1,5-	195251-91-3	CEFHJ
	benzodioxepin-3(4H)-one
1089	Tricyclone	68433-81-8	DEFHJK
1090	Tridecyl alcohol	112-70-9	DEFGJK
1091	Triethyl citrate	77-93-0	CEFGJ
1093	Methyl 2-((1-hydroxy-3-	144761-91-1	DFHJ
	phenylbutyl)amino)benzoate
1095	1-((2E,5Z,9Z)-2,6,10-	28371-99-5	DHJK
	trimethylcyclododeca-2,5,9-trien-1-
	yl)ethan-1-one
1097	Decahydro-2,6,6,7,8,8-hexamethyl-	338735-71-0	BDEFHJK
	2h-indeno(4,5-b)furan
1099	13-methyl oxacyclopentadec-10-en-	365411-50-3	DEFHJK
	2-one
1102	Undecanal	112-44-7	BDHJK
1104	(E)-4-methyldec-3-en-5-ol	81782-77-6	BDEFHIJK
1105	Valencene	4630-07-3	BDEFHJK
1107	Valerianol	20489-45-6	DEFHJK
1111	Vanillin isobutyrate	20665-85-4	CHJ
1113	Vaniwhite	5533-03-9	CGIK
1116	(Z)-2-methyl-4-(2,6,6-	68555-62-4	BDFHJK
	trimethylcyclohex-2-en-1-yl)but-2-
	enal
1117	Methyl 2,4-dihydroxy-3,6-	4707-47-5	CGIJ
	dimethylbenzoate
1120	1-methoxy-3a,4,5,6,7,7a-hexahydro-	27135-90-6	ACEFHJKL
	1H-4,7-methanoindene
1121	Methyl (Z)-2-((3-(4-(tert-	91-51-0	DFHJ
	butyl)phenyl)-2-
	methylpropylidene)amino)benzoate
1125	(Z)-hex-3-en-1-yl isobutyrate	41519-23-7	ADEFHJKL
1126	Vertacetal	5182-36-5	BCFHJK
1129	1-((3R,3aR,7R,8aS)-3,6,8,8-	32388-55-9	DHJK
	tetramethyl-2,3,4,7,8,8a-hexahydro-
	1H-3a,7-methanoazulen-5-yl)ethan-
	1-one
1131	Methyl (Z)-2-(((2,4-	68738-99-8	DEFHJ
	dimethylcyclohex-3-en-1-
	yl)methylene)amino)benzoate
1135	Vetiverol	89-88-3	CEFHIJK
1136	Vetivert Acetate	117-98-6	DEFHJK
1137	Decahydro-3H-spiro[furan-2,5′-	68480-11-5	DEFGJKL
	[4,7]methanoindene]
1138	(2Z,6E)-nona-2,6-dienenitrile	67019-89-0	ACEFHKL
1139	(Z)-cyclooct-4-en-1-yl methyl	87731-18-8	BCHJKL
	carbonate
1140	(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-	552-02-3	DEFHJK
	tetramethyldecahydro-1H-
	cyclopropa[e]azulen-4-ol
1142	3,5,5,6,7,8,8-heptamethyl-5,6,7,8-	127459-79-4	DHJ
	tetrahydronaphthalene-2-carbonitrile
1143	(1S,2S,3S,5R)-2,6,6-	133636-82-5	DEFHJK
	trimethylspiro[bicyclo[3.1.1]heptane-
	3,1′-cyclohexan]-2′-en-4′-one
1144	1′,1′,5′,5′-tetramethylhexahydro-	154171-76-3	DEFHJK
	2′H,5′H-spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene]
1145	1′,1′,5′,5′-tetramethylhexahydro-	154171-77-4	DEFHJK
	2′H,5′H-spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene] K
1146	4-(4-hydroxy-3-	122-48-5	CEFGJ
	methoxyphenyl)butan-2-one
1147	(1R,8aR)-4-isopropyl-1,6-dimethyl-	41929-05-9	DEFHJKL
	1,2,3,7,8,8a-hexahydronaphthalene

TABLE 2

List of materials with at least one MORV greater than 5 to 10

Number	Material Name	CAS Number	Comment Code

2	2,4-dimethyl-2-(5,5,8,8-tetramethyl-	131812-67-4	DFHJ
	5,6,7,8-tetrahydronaphthalen-2-yl)-
	1,3-dioxolane
23	3a,5,6,7,8,8b-hexahydro-	823178-41-2	DEFHJK
	2,2,6,6,7,8,8-heptamethyl-4H-
	indeno(4,5-d)-1,3-dioxole
141	2,4-dimethyl-4,4a,5,9b-	27606-09-3	CEFHJK
	tetrahydroindeno[1,2-d][1,3]dioxine
185	(1-methyl-2-((1,2,2-	198404-98-7	DEFHJK
	trimethylbicyclo[3.1.0]hexan-3-
	yl)methyl)cyclopropyl)methanol
227	Isobornylcyclohexanol	68877-29-2	DEFHJK
230	Isobornyl cyclohexanol	66072-32-0	DEFHJK
246	Indol/Hydroxycitronellal Schiff base	67801-36-9	DEFHJ
248	Hydroxymethyl isolongifolene	59056-64-3	DEFHJK
343	8,8-dimethyl-3a,4,5,6,7,7a-	76842-49-4	DEFHJK
	hexahydro-1H-4,7-methanoinden-6-
	yl propionate
359	(E)-4-((3aR,4R,7R,7aR)-	501929-47-1	DEFHJK
	1,3a,4,6,7,7a-hexahydro-5H-4,7-
	methanoinden-5-ylidene)-3-
	methylbutan-2-ol
565	Cedryl methyl ether	19870-74-7	BDEFHJK
631	beta-Copaene	18252-44-3	BDEFHJKL
659	2′-isopropyl-1,7,7-	869292-93-3	BDEFHJK
	trimethylspiro[bicyclo[2.2.1]heptane-
	2,4′-[1,3]dioxane]
674	(4aR,5R,7aS,9R)-2,2,5,8,8,9a-	211299-54-6	DEFHJK
	hexamethyloctahydro-4H-4a,9-
	methanoazuleno[5,6-d][1,3]dioxole
678	(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-	57345-19-4	DEFHJ
	tetramethyldodecahydro-5H-3,5a-
	epoxynaphtho[2,1-c]oxepine
679	2,2,6,6,7,8,8-heptamethyldecahydro-	476332-65-7	DEFHJK
	2H-indeno[4,5-b]furan
715	alpha-Cedrene epoxide	13567-39-0	BDEFHJK
758	Acetoxymethyl-isolongifolene	59056-62-1	DEFHJK
	(isomers)
1028	Sclareol	515-03-7	DEFHJ
1097	Decahydro-2,6,6,7,8,8-hexamethyl-	338735-71-0	DEFHJK
	2h-indeno(4,5-b)furan

TABLE 3

List of materials with at least one MORV from 0.5 to less than 1

Number	Material Name	CAS Number	Comment Code

12	1-ethoxy-4-(tert-	181258-89-9	ADEFHJK
	pentyl)cyclohexane
19	(3Z)-1-(2-buten-1-yloxy)-3-	888744-18-1	ADEFHJKL
	hexene
20	4-(2-methoxypropan-2-yl)-1-	14576-08-0	ADHIJKL
	methylcyclohex-1-ene
24	O-Methyl linalool	60763-44-2	ADHIJKL
26	o-Methoxycinnamaldehyde	1504-74-1	ACHK
27	Octanal, 3,7-dimethyl-	25795-46-4	ADGIJKL
53	3,3-Dimethyl-5(2,2,3-	329925-33-9	CEFHJ
	Trimethyl-3-Cyclopenten-
	1yl)-4-Penten-2-ol
54	n-Hexyl salicylate	6259-76-3	DEFHJ
55	n-Hexyl 2-butenoate	19089-92-0	ADEFHJKL
59	Neryl Formate	2142-94-1	BCEFHJK
72	Methyl-beta-ionone	127-43-5	DHJK
73	Myroxide	28977-57-3	ADGIJKL
81	(E)-3,7-dimethylocta-4,6-	18479-54-4	BCEFGIJK
	dien-3-ol
84	(Z)-hex-3-en-1-yl	188570-78-7	BCEFHIKL
	cyclopropanecarboxylate
96	Methyl phenyl carbinyl	120-45-6	BCHJK
	propionate
97	Methyl phenylacetate	101-41-7	ACEFHIKL
107	2-methyl-6-	91069-37-3	BCEFGIKL
	oxaspiro[4.5]decan-7-one
111	Methyl geraniate	2349-14-6	BCHJKL
115	2-ethoxy-4-	5595-79-9	CFGK
	(methoxymethyl)phenol
116	Methyl	40203-73-4	ACEFHIKL
	cyclopentylideneacetate
125	Methoxymelonal	62439-41-2	ACGIJK
133	((1s,4s)-4-	13828-37-0	BDEFHIJK
	isopropylcyclohexyl)methanol
147	Linalyl propionate	144-39-8	BDFHJK
150	Linalyl formate	115-99-1	ACFHJK
151	Linalyl butyrate	78-36-4	BDEFHJK
154	Linalyl acetate	115-95-7	BDHJK
157	Linalool	78-70-6	BCEFGIJK
163	(Z)-hex-3-en-1-yl methyl	67633-96-9	ACEFGKL
	carbonate
166	Lepidine	491-35-0	BCEFHIKL
169	L-Carvone	6485-40-1	ACGIJKL
181	Khusinil	75490-39-0	DHJK
191	Isoraldeine	1335-46-2	BDHIJK
194	Isopropylvinylcarbinol	4798-45-2	ACGIKL
198	Isopropyl 2-methylbutyrate	66576-71-4	ACEFGIJKL
201	Isopentyrate	80118-06-5	ADEFGIJKL
204	Isononyl acetate	40379-24-6	BDEFHJKL
205	Isononanol	27458-94-2	BDEFGIKL
213	Isoeugenyl acetate	93-29-8	CFHJK
214	Isoeugenol	97-54-1	CEFHIK
232	Isoborneol	124-76-5	ACEFHIJKL
237	Isoamyl octanoate	2035-99-6	DEFHJK
239	Isoamyl isobutyrate	2050-01-3	ACEFGIJKL
255	Hydrocinnamic acid	501-52-0	CEFHIK
258	Hydratopic alcohol	1123-85-9	BCEFHIK
264	Hexyl propanoate	2445-76-3	ADEFHIKL
270	Hexyl butyrate	2639-63-6	BDEFHJKL
273	Hexyl 2-methylbutanoate	10032-15-2	BDEFHJKL
275	Hexyl 2-furoate	39251-86-0	DEFHJK
282	Heptyl alcohol	111-70-6	ACEFGIKL
283	Heptyl acetate	112-06-1	ADEFHKL
284	Heptaldehyde	111-71-7	ACHIKL
287	Heliotropin	120-57-0	BCGIK
302	Geranyl nitrile	5146-66-7	BCEFHKL
306	Geranyl formate	105-86-2	BCEFHJK
308	Geranyl caprylate	51532-26-4	DEFHJ
310	Geranyl benzoate	94-48-4	DFHJ
312	Geranial	141-27-5	ACHIKL
314	N,2-dimethyl-N-	84434-18-4	BCEFHJK
	phenylbutanamide
319	gamma-Terpinene	99-85-4	ADEFGIJKL
346	2-(sec-butyl)cyclohexan-1-	14765-30-1	ADFHIKL
	one
354	3-(2-ethylphenyl)-2,2-	67634-14-4	BDHJK
	dimethylpropanal
355	2-(tert-butyl)cyclohexyl ethyl	67801-64-3	BDFHJK
	carbonate
365	2-(tert-butyl)cyclohexyl ethyl	81925-81-7	ACFHIKL
	carbonate
366	Fenchyl alcohol	1632-73-1	ACGIJKL
376	Eucalyptol	470-82-6	ADEFGIJKL
379	Ethyl vanillin acetate	72207-94-4	CHJ
387	Ethyl octanoate	106-32-1	BDEFHJKL
400	Ethyl cinnamate	103-36-6	BCEFHK
412	Ethyl 2-	2511-00-4	BDFHIJKL
	(cyclohexyl)propionate
419	d-p-8(9)-Menthen-2-one	5524-05-0	ACGIJKL
420	4-methyl-2-phenyltetrahydro-	94201-73-7	BDEFHJK
	2H-pyran
437	Dihydromyrcenol	18479-58-8	ADEFGIJK
438	Dihydrojasmone	1128-08-1	BCFHIJKL
439	Dihydroisophorone	873-94-9	ACEFGIJKL
440	Dihydroeugenol	2785-87-7	CEFHIJK
442	Dihydrocoumarin	119-84-6	BCGIKL
443	Dihydrocarvone	7764-50-3	ACGIJKL
447	Dihydro-alpha-terpinyl	80-25-1	BDEFHIJKL
	acetate
448	Dihydro-alpha-ionone	31499-72-6	BDHIJK
454	Dibenzyl ether	103-50-4	DEFHJK
455	Dibutyl o-phthalate	84-74-2	DEFHJ
469	2-pentylcyclopentan-1-one	4819-67-4	BDFHIKL
472	Decyl anthranilate	18189-07-6	DEFHJ
477	Methyl (1s,4s)-1,4-	23059-38-3	ADEFHIJKL
	dimethylcyclohexane-1-
	carboxylate
481	Cyclohexylethyl acetate	21722-83-8	BDEFHJKL
492	Creosol	93-51-6	BCHIK
495	Cosmene	460-01-5	ADEFGIKL
496	4-cyclohexyl-2-methylbutan-	83926-73-2	BDEFGIJK
	2-ol
504	2-benzyl-2-methylbut-3-	97384-48-0	BDHJK
	enenitrile
509	Citronellyl nitrile	51566-62-2	BCEFGIKL
510	Citronellyl phenylacetate	139-70-8	DFHJ
512	Citronellyl formate	105-85-1	BCEFGJKL
515	Citronellyl benzoate	10482-77-6	DFHJ
517	Citronellol	106-22-9	BCHIJKL
518	Citronellal	106-23-0	ACHIJKL
522	Citral	5392-40-5	ACHIKL
525	cis-Pinane	6876-13-7	ADEFGIJKL
526	(Z)-3-methyl-2-(pent-2-en-1-	488-10-8	BCHIJKL
	yl)cyclopent-2-en-1-one
528	cis-iso-Eugenol	5912-86-7	CEFHIK
535	cis-3-Hexenyl valerate	35852-46-1	BDEFHJKL
536	cis-3-Hexenyl tiglate	67883-79-8	BDEFHJK
538	cis-3-Hexenyl propionate	33467-74-2	ACEFHIKL
540	cis-3-Hexenyl butyrate	16491-36-4	ADEFHJKL
542	cis-3-Hexen-1-ol	928-96-1	ACEFHIKL
547	cis-2-Hexenol	928-94-9	ACEFHIKL
549	Cinnamyl nitrile	4360-47-8	ACEFGIK
554	Cinnamic aldehyde	104-55-2	ACHIK
556	Cinnamyl nitrile	1885-38-7	ACEFGIK
557	Chloroxylenol	88-04-0	BCHIJK
575	Carvacrol	499-75-2	DHIJK
576	Carvone	99-49-0	ACGIJKL
579	Carbitol	111-90-0	BCEFGIK
583	Caproyl alcohol	111-27-3	ACEFGIKL
585	2-(2,2,3-trimethylcyclopent-3-	15373-31-6	ACGIJKL
	en-1-yl)acetonitrile
588	Camphor	76-22-2	ACEFGIJKL
602	(E)-2-methyl-4-(2,6,6-	3155-71-3	DHJK
	trimethylcyclohex-1-en-1-
	yl)but-2-enal
605	Borneol	507-70-0	ACEFHIJKL
617	beta-Pinene epoxide	6931-54-0	ACEFGIJKL
619	beta-Phellandrene	555-10-2	ADEFGIJKL
640	Benzylacetone	2550-26-7	ACEFGIK
641	Benzyl salicylate	118-58-1	DFGJ
645	Benzyl isovalerate	103-38-8	BDEFHJK
647	Benzyl isobutyrate	103-28-6	BCHJK
651	Benzyl butyrate	103-37-7	BCEFHJK
652	Benzyl alcohol	100-51-6	ACEFGIKL
662	1-(3,3-	25225-08-5	ADEFHIJKL
	dimethylcyclohexyl)ethyl
	formate
664	Anisyl acetate	104-21-2	BCEFGK
665	Anisyl formate	122-91-8	BCEFGK
667	Anethole	104-46-1	ACEFHK
672	Amyl benzoate	2049-96-9	DEFHJK
687	alpha-Terpinyl acetate	80-26-2	BDHJK
699	alpha-methyl-	10528-67-3	BDEFHIK
	cyclohexanepropanol
701	alpha-methyl cinnamaldehyde	101-39-3	ACHIK
703	alpha-Isomethylionone	127-51-5	BDHIJK
740	2,5-Dimethyl-4-methoxy-	4077-47-8	ACEFGIJKL
	3(2H)-furanone
743	Allyl phenoxyacetate	7493-74-5	BCGK
744	Allyl Phenethyl ether	14289-65-7	ACEFHK
745	Allyl heptanoate	142-19-8	ADEFHJKL
755	N-ethyl-N-(m-	179911-08-1	CEFHJK
	tolyl)propionamide
760	3-hydroxybutan-2-one	513-86-0	ACEFGIKL
761	Acetoanisole	100-06-1	BCEFHIK
777	6-Methylquinoline	91-62-3	BCEFHIKL
779	6,8-Diethyl-2-nonanol	70214-77-6	BDEFGIJKL
784	5-Methyl-3-heptanone	541-85-5	ACFGIKL
789	4-Vinylphenol	2628-17-3	BCHIK
796	4-hydroxy-3-methoxy-	458-36-6	CH
	cinnamaldehyde
797	4-Ethylguaiacol	2785-89-9	CEFHIK
799	4-Damascol	4927-36-0	BDFHJK
808	3-methyl-4-phenylpyrazole	13788-84-6	CEFHK
810	3-Methyl-1,2-	765-70-8	ACEFGIKL
	cyclopentanedione
811	3-Methoxy-5-methylphenol	3209-13-0	BCHIK
812	3-Methoxy-3-Methyl Butanol	56539-66-3	ACGIKL
817	3-Hexenol	544-12-7	ACEFHIKL
819	3,7-dimethyl-2-methylene-6-	22418-66-2	ADFHIJK
	octenal
820	3,7-dimethyl-1-octanol	106-21-8	BDEFGIJKL
832	2-Phenylethyl acetate	103-45-7	BCEFHK
835	2-Phenethyl propionate	122-70-3	BCEFHJK
836	2-Pentylcyclopentan-1-ol	84560-00-9	DEFHIKL
838	2-nonanone propylene glycol	165191-91-3	BDEFHJK
	acetal
845	2-Methoxy-3-(1-	24168-70-5	BCEFGIK
	methylpropyl)pyrazine
846	2-isopropyl-N,2,3-	51115-67-4	ACEFGIJK
	trimethylbutyramide
847	2-Isopropyl-5-methyl-2-	35158-25-9	ADFGIJKL
	hexenal
848	2-Isopropyl-4-methylthiazole	15679-13-7	ACHIJKL
851	2-Hexen-1-ol	2305-21-7	ACEFHIKL
858	2-Butoxyethanol	111-76-2	ACEFGIKL
875	1,4-Cineole	470-67-7	ADGIJKL
880	1-(2,6,6-Trimethyl-2-	43052-87-5	BDHIJK
	cyclohexen-1-yl)-2-buten-1-
	one
882	(Z)-3-hepten-1-yl acetate	1576-78-9	ACEFHKL
883	(S)-(1R,5R)-4,6,6-	1196-01-6	ACEFGIJKL
	trimethylbicyclo[3.1.1]hept-3-
	en-2-one
888	(R)-(−)-Linalool	126-91-0	BCEFGIJK
889	(l)-Citronellal	5949-05-3	ACHIJKL
891	(d)-Citronellal	2385-77-5	ACHIJKL
899	(+)-Citronellol	1117-61-9	BCHIJKL
900	(−)-Citronellol	7540-51-4	BCHIJKL
901	(+)-alpha-Pinene	7785-70-8	ADEFGIJKL
902	(+)-Carvone	2244-16-8	ACGIJKL
903	(−)-alpha-Pinene	7785-26-4	ADEFGIJKL
904	Methyl 2-methylbutyrate	868-57-5	ACEFGIKL
909	Hexyl tiglate	16930-96-4	BDEFHJKL
918	Allyl 2-	68901-15-5	CHJK
	(cyclohexyloxy)acetate
921	1,5-	75147-23-8	CFHIJK
	dimethylbicyclo[3.2.1]octan-
	8-one oxime
931	alpha-acetoxystyrene	2206-94-2	ACEFHIK
940	p-Cymene	99-87-6	ADGIJKL
956	Phenethyl formate	104-62-1	ACEFHK
958	Phenethyl isobutyrate	103-48-0	DHJK
960	Phenethyl tiglate	55719-85-2	DHJK
971	Phenylethyl methacrylate	3683-12-3	DHJK
977	p-	4395-92-0	BDFHK
	Isopropylphenylacetaldehyde
981	1,2-dimethyl-3-(prop-1-en-2-	72402-00-7	BCEFGIJKL
	yl)cyclopentan-1-ol
983	p-Methoxyphenylacetone	122-84-9	BCEFHK
986	(2Z,5Z)-5,6,7-trimethylocta-	358331-95-0	ADHIJKL
	2,5-dien-4-one
987	p-Propyl anisole	104-45-0	ADEFHKL
994	p-t-butyl phenyl acetaldehyde	109347-45-7	BDHJK
995	p-tert-Amyl cyclohexanol	5349-51-9	BDEFHIJK
1001	Racemic alpha-Pinene	80-56-8	ADEFGIJKL
1002	4-(4-hydroxyphenyl)butan-2-	5471-51-2	CEFGIK
	one
1004	Rhodinol	141-25-3	BCHIJKL
1005	Ethyl (2,3,6-	93981-50-1	BDEFHJKL
	trimethylcyclohexyl)carbonate
1011	1-(3,3-	25225-10-9	ADHIJKL
	dimethylcyclohexyl)ethyl
	acetate
1017	S)-(+)-Linalool	126-90-9	BCEFGIJK
1018	Sabinene	3387-41-5	ADEFGIJKL
1019	Sabinene hydrate	546-79-2	ADEFGIJKL
1030	Propyl (S)-2-(tert-	319002-92-1	BDEFHJK
	pentyloxy)propanoate
1039	Spirolide	699-61-6	BCGIKL
1040	(Z)-5-methylheptan-3-one	22457-23-4	BCEFGIJKL
	oxime
1041	1-phenylethyl acetate	93-92-5	ACEFHIK
1051	Tetrahydrogeranial	5988-91-0	ADGIJKL
1052	Tetrahydroionol	4361-23-3	BDEFHIJK
1054	Tetrahydrolinalool	78-69-3	BDEFGIJKL
1055	Tetrahydrolinalyl acetate	20780-48-7	ADEFHJKL
1058	Ethyl (1R,6S)-2,2,6-	22471-55-2	ADEFHIJKL
	trimethylcyclohexane-1-
	carboxylate
1061	Thymol	89-83-8	BDHIJK
1069	trans-2-Hexenol	928-95-0	ACEFHIKL
1071	trans-2-tert-	5448-22-6	ACGIJKL
	Butylcyclohexanol
1074	trans-alpha-Damascone	24720-09-0	BDHIJK
1076	trans-Anethole	4180-23-8	ACEFHK
1079	trans-Cinnamic acid	140-10-3	CEFHK
1081	trans-Dihydrocarvone	5948-04-9	ACGIJKL
1084	trans-Isoeugenol	5932-68-3	CEFHIK
1088	Trichloromethyl phenyl	90-17-5	BDEFGJ
	carbinyl acetate
1098	2-mercapto-2-methylpentan-	258823-39-1	ACEFHIJKL
	1-ol
1110	Vanillin acetate	881-68-5	CH
1112	Vanitrope	94-86-0	CEFHK
1115	2,2,5-trimethyl-5-	65443-14-3	BDFGIJKL
	pentylcyclopentan-1-one
1118	Veratraldehyde	120-14-9	BCGIK
1119	(1R,5R)-4,6,6-	18309-32-5	ACEFGIJKL
	trimethylbicyclo[3.1.1]hept-3-
	en-2-one
1122	Verdol	13491-79-7	ACGIJKL
1127	4-(tert-butyl)cyclohexyl	10411-92-4	BDEFHJK
	acetate
1128	4-(tert-butyl)cyclohexyl	32210-23-4	BDEFHJK
	acetate
1133	Vethymine	7193-87-5	CEFGK
1134	4-methyl-4-phenylpentan-2-yl	68083-58-9	BDFHJK
	acetate
1141	(Z)-1-((2-	292605-05-1	ADEFHKL
	methylallyl)oxy)hex-3-ene

TABLE 4

List of materials with ALL MORVs from 1 to 5

Num-		CAS	Comment
ber	Material Name	Number	Code

7	3-methoxy-7,7-dimethyl-10-	216970-21-7	BDEFHJK
	methylenebicyclo[4.3.1]decane
14	Oxyoctaline formate	65405-72-3	DFHJK
39	2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-	103614-86-4	DEFHIJK
	octahydronaphthalen-1-ol
48	Nootkatone	4674-50-4	DHJK
183	Khusimol	16223-63-5	CEFHJK
199	Isopimpinellin	482-27-9	CFGJ
206	Iso3-methylcyclopentadecan-1-one	3100-36-5	DEFGJK
212	Isoeugenyl benzyl ether	120-11-6	DFHJ
215	1-((2S,3S)-2,3,8,8-tetramethyl-	54464-57-2	DHJK
	1,2,3,4,5,6,7,8-octahydronaphthalen-
	2-yl)ethan-1-one
229	Isobornyl isobutyrate	85586-67-0	BDEFHIJK
260	2,3-dihydro-3,3-dimethyl-1H-indene-	173445-44-8	DHJK
	5-propanal
261	3-(3,3-dimethyl-2,3-dihydro-1H-	173445-65-3	DHJK
	inden-5-yl)propanal
281	3a,4,5,6,7,7a-hexahydro-1H-4,7-	5413-60-5	CEFGJK
	methanoinden-6-yl acetate
329	gamma-Eudesmol	1209-71-8	DFHJK
335	4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-	1222-05-5	DEFHJK
	hexahydrocyclopenta[g]isochromene
353	(Z)-6-ethylideneoctahydro-2H-5,8-	69486-14-2	CEFGJK
	methanochromen-2-one
360	8,8-dimethyl-3a,4,5,6,7,7a-	171102-41-3	DEFHJK
	hexahydro-1H-4,7-methanoinden-6-
	yl acetate
441	Octahydro-1H-4,7-methanoinden-5-	64001-15-6	DEFHJKL
	yl acetate
484	3a,4,5,6,7,7a-hexahydro-1H-4,7-	113889-23-9	DEFHJK
	methanoinden-6-yl butyrate
487	3a,4,5,6,7,7a-hexahydro-1H-4,7-	67634-20-2	DEFHJK
	methanoinden-5-yl isobutyrate
488	Curzerene	17910-09-7	DHJK
501	(E)-cycloheptadec-9-en-1-one	542-46-1	DEFGJ
566	Cedryl formate	39900-38-4	BDEFHJK
567	Cedryl acetate	77-54-3	DEFHJK
569	Cedrol	77-53-2	DEFHJK
570	5-methyl-1-(2,2,3-	139539-66-5	DEFHJK
	trimethylcyclopent-3-en-1-yl)-6-
	oxabicyclo[3.2.1]octane
573	Caryophyllene alcohol acetate	32214-91-8	DEFHJK
574	Caryolan-1-ol	472-97-9	DEFHJK
603	Bornyl isobutyrate	24717-86-0	BDEFHIJK
616	beta-Santalol	77-42-9	DEFHJK
621	beta-Patchoulline	514-51-2	BDEFGJKL
624	beta-Himachalene Oxide	57819-73-5	BDFHJK
627	(2,2-dimethoxyethyl)benzene	101-48-4	DHJK
632	beta-Cedrene	546-28-1	BDEFGJKL
663	Anisyl phenylacetate	102-17-0	DFHJ
680	2,2,6,6,7,8,8-heptamethyldecahydro-	647828-16-8	ADEFHJK
	2H-indeno[4,5-b]furan
684	alpha-Vetivone	15764-04-2	DHJK
694	alpha-Santalol	115-71-9	DEFHJK
696	alpha-Patchoulene	560-32-7	ADEFHJKL
708	alpha-Gurjunene	489-40-7	BDEFHJKL
712	alpha-Eudesmol	473-16-5	DEFHJK
714	alpha-Cubebene	17699-14-8	ADEFHJKL
726	alpha-Agarofuran	5956-12-7	BDEFHJK
750	Allo-aromadendrene	25246-27-9	BDEFHJKL
764	Acetarolle	744266-61-3	DFHJK
775	7-eip-alpha-Eudesmol	123123-38-6	DEFHJK
776	7-Acetyl-1,1,3,4,4,6-	1506-02-1	DEFHJ
	hexamethyltetralin
788	5-Cyclohexadecenone	37609-25-9	DEFGJK
804	3-Thujopsanone	25966-79-4	BDEFHJK
872	10-epi-gamma-Eudesmol	15051-81-7	DFHJK
919	3a,4,5,6,7,7a-hexahydro-1H-4,7-	17511-60-3	CEFHJK
	methanoinden-6-yl propionate
927	5-Acetyl-1,1,2,3,3,6-	15323-35-0	DEFHJK
	hexamethylindan
933	Patchouli alcohol	5986-55-0	DEFHIJK
978	3a,4,5,6,7,7a-hexahydro-1H-4,7-	68039-44-1	DEFHJK
	methanoinden-6-yl pivalate
1007	(2R,4a′R,8a′R)-3,7′-dimethyl-	41816-03-9	DEFHJK
	3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-
	spiro[oxirane-2,2′-
	[1,4]methanonaphthalene]
1022	2,2,7,9-tetramethylspiro(5.5)undec-	502847-01-0	DHIJK
	8-en-1-one
1024	(Z)-2-ethyl-4-(2,2,3-	28219-61-6	DEFHJK
	trimethylcyclopent-3-en-1-yl)but-2-
	en-1-ol
1027	5-methoxyoctahydro-1H-4,7-	193425-86-4	CHJK
	methanoindene-2-carbaldehyde
1029	Sclareol oxide	5153-92-4	DEFHJK
1035	Spathulenol	6750-60-3	DEFHJK
1038	1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-	224031-70-3	DGJK
	1-one
1060	Thujopsene	470-40-6	BDEFGJKL
1089	Tricyclone	68433-81-8	DEFHJK
1107	Valerianol	20489-45-6	DEFHJK
1129	1-((3R,3aR,7R,8aS)-3,6,8,8-	32388-55-9	DHJK
	tetramethyl-2,3,4,7,8,8a-hexahydro-
	1H-3a,7-methanoazulen-5-yl)ethan-
	1-one
1131	Methyl (Z)-2-(((2,4-	68738-99-8	DEFHJ
	dimethylcyclohex-3-en-1-
	yl)methylene)amino)benzoate
1136	Vetivert Acetate	117-98-6	DEFHJK
1137	Decahydro-3H-spiro[furan-2,5′-	68480-11-5	DEFGJKL
	[4,7]methanoindene]
1140	(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-	552-02-3	DEFHJK
	tetramethyldecahydro-1H-
	cyclopropa[e]azulen-4-ol
1142	3,5,5,6,7,8,8-heptamethyl-5,6,7,8-	127459-79-4	DHJ
	tetrahydronaphthalene-2-carbonitrile
1143	(1S,2S,3S,5R)-2,6,6-	133636-82-5	DEFHJK
	trimethylspiro[bicyclo[3.1.1]heptane-
	3,1′-cyclohexan]-2′-en-4′-one
1144	1′,1′,5′,5′-tetramethylhexahydro-	154171-76-3	DEFHJK
	2′H,5′H-spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene]
1145	1′,1′,5′,5′-tetramethylhexahydro-	154171-77-4	DEFHJK
	2′H,5′H-spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene] K

TABLE 5

List of materials with ALL MORVs greater than 5 to 10

Number	Material Name	CAS Number	Comment Code

248	Hydroxymethyl	59056-64-3	BDEFHJK
	isolongifolene

TABLE 6

List of materials with ALL MORVs from 0.5 to less than 1

Number	Material Name	CAS Number	Comment Code

472	Decyl anthranilate	18189-07-6	DEFHJ
526	(Z)-3-methyl-2-(pent-	488-10-8	BCHIJKL
	2-en-1-yl)cyclopent-
	2-en-1-one

Compositions and Methods

A composition comprising a malodor reduction material having an MORV of at least 0.5, from about 0.5 to about 10, from 0.5 to about 10, from about 1 to about 10, or from about 1 to about 5 is disclosed.

In one aspect, said composition comprises a malodor reduction material is selected from the group consisting of Table 1 materials Table 2 materials, Table 3 materials and mixtures thereof; in one aspect said material is selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 31; 32; 33; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101; 102; 103; 108; 110; 114; 117; 119; 122; 123; 126; 130; 142; 145; 146; 149; 155; 159; 167; 168; 170; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 375; 386; 394; 397; 398; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 466; 468; 471; 473; 474; 475; 491; 519; 520; 524; 527; 530; 531; 532; 534; 544; 546; 551; 555; 565; 578; 580; 581; 584; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 738; 742; 748; 750; 752; 763; 766; 767; 768; 770; 774; 778; 781; 786; 791; 792; 800; 802; 806; 814; 821; 826; 827; 828; 829; 834; 837; 839; 840; 850; 852; 856; 864; 865; 866; 868; 869; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 928; 929; 937; 946; 947; 950; 955; 969; 973; 974; 982; 993; 1006; 1008; 1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1064; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145, Table 2 materials 565; 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108; 110; 111; 114; 116; 119; 125; 126; 133; 142; 146; 147; 150; 154; 157; 159; 163; 166; 167; 169; 178; 189; 192; 194; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 284; 287; 290; 302; 306; 312; 319; 322; 325; 333; 338; 344; 346; 354; 358; 362; 365; 366; 375; 376; 387; 412; 419; 420; 428; 429; 437; 438; 439; 443; 444; 447; 448; 461; 469; 474; 477; 481; 491; 492; 495; 496; 509; 512; 517; 518; 522; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 554; 555; 556; 557; 575; 576; 579; 583; 585; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 647; 651; 652; 662; 664; 665; 667; 683; 686; 687; 693; 698; 699; 701; 717; 725; 730; 740; 742; 744; 745; 760; 761; 777; 779; 784; 789; 792; 797; 806; 810; 812; 817; 819; 820; 827; 828; 832; 835; 836; 838; 839; 845; 846; 847; 848; 850; 851; 858; 865; 875; 878; 879; 882; 883; 888; 889; 891; 899; 900; 901; 902; 903; 904; 909; 914; 931; 937; 940; 946; 947; 956; 977; 981; 986; 987; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039; 1040; 1041; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069; 1071; 1076; 1081; 1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128; 1141 and mixtures thereof, in one aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 31; 32; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101; 102; 103; 108; 114; 117; 122; 123; 126; 130; 142; 145; 146; 149; 155; 159; 167; 168; 170; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 375; 386; 394; 397; 398; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 466; 468; 471; 473; 474; 475; 491; 519; 520; 524; 527; 530; 531; 532; 534; 544; 546; 551; 555; 565; 578; 580; 581; 584; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 742; 748; 750; 752; 763; 766; 767; 768; 770; 774; 778; 781; 786; 791; 792; 800; 802; 806; 814; 821; 826; 827; 828; 829; 834; 837; 839; 840; 850; 852; 856; 864; 865; 866; 868; 869; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 928; 929; 937; 946; 947; 950; 955; 969; 973; 974; 982; 993; 1006; 1008; 1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145, Table 2 materials 565; 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108; 110; 111; 114; 116; 119; 125; 126; 133; 142; 146; 147; 150; 154; 157; 159; 163; 166; 167; 169; 178; 189; 192; 194; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 284; 287; 290; 306; 312; 319; 322; 325; 333; 338; 344; 346; 354; 358; 362; 365; 366; 375; 376; 387; 412; 419; 420; 428; 429; 437; 438; 439; 443; 444; 447; 448; 461; 469; 474; 477; 481; 491; 492; 495; 496; 509; 512; 517; 518; 522; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 554; 555; 556; 557; 575; 576; 579; 583; 585; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 647; 651; 652; 662; 664; 665; 667; 683; 686; 687; 693; 698; 699; 701; 717; 725; 730; 740; 742; 744; 745; 760; 761; 777; 779; 784; 789; 792; 797; 806; 810; 812; 817; 819; 820; 827; 828; 832; 835; 836; 838; 839; 845; 846; 847; 848; 850; 851; 858; 865; 875; 878; 879; 882; 883; 888; 889; 891; 899; 900; 901; 902; 903; 904; 909; 914; 931; 937; 940; 946; 947; 956; 977; 981; 986; 987; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039; 1040; 1041; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069; 1071; 1076; 1081; 1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128; 1141 and mixtures thereof, in one aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 4; 29; 30; 31; 32; 50; 65; 67; 70; 92; 93; 103; 122; 123; 145; 167; 168; 208; 210; 218; 243; 256; 278; 290; 364; 386; 394; 424; 436; 453; 468; 524; 527; 532; 578; 580; 584; 589; 609; 618; 627; 668; 683; 702; 711; 763; 767; 770; 786; 802; 821; 829; 837; 839; 840; 852; 864; 866; 869; 873; 876; 878; 905; 950; 973; 993; 1010; 1037; 1043; 1066; 1070; 1073; 1077; 1078; 1102; 1120; 1125, Table 3 materials 12; 19; 20; 24; 27; 32; 53; 55; 65; 70; 73; 97; 116; 119; 125; 154; 163; 167; 194; 198; 201; 204; 239; 256; 264; 270; 273; 282; 283; 284; 290; 319; 346; 365; 376; 387; 412; 419; 437; 439; 443; 447; 469; 477; 481; 495; 518; 525; 538; 540; 542; 547; 583; 588; 589; 609; 617; 619; 652; 683; 740; 744; 745; 760; 784; 789; 810; 812; 817; 838; 839; 847; 848; 851; 858; 875; 878; 882; 889; 891; 901; 903; 904; 940; 987; 1001; 1010; 1011; 1018; 1041; 1051; 1054; 1055; 1069; 1081; 1098; 1102; 1120; 1127; 1128; 1141.
In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 3; 7; 9; 25; 29; 30; 32; 33; 34; 35; 42; 49; 62; 65; 67; 70; 91; 92; 98; 101; 102; 103; 108; 110; 114; 117; 119; 122; 126; 130; 142; 145; 159; 167; 168; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 322; 325; 333; 338; 342; 344; 358; 362; 386; 394; 397; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 468; 471; 473; 474; 475; 519; 520; 527; 530; 534; 544; 546; 551; 555; 565; 578; 580; 581; 587; 589; 603; 604; 606; 609; 614; 615; 618; 621; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 748; 750; 763; 766; 767; 768; 774; 778; 781; 792; 802; 806; 814; 821; 826; 827; 834; 839; 840; 850; 852; 865; 866; 868; 869; 873; 876; 877; 878; 884; 897; 905; 926; 928; 929; 950; 955; 969; 973; 974; 993; 1006; 1008; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1072; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145 and table 3 materials 9; 12; 19; 21; 25; 32; 34; 53; 55; 59; 65; 70; 81; 84; 97; 98; 108; 110; 114; 116; 119; 126; 133; 142; 147; 150; 157; 159; 163; 166; 167; 178; 189; 192; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 290; 302; 306; 319; 322; 325; 333; 338; 344; 346; 358; 362; 365; 376; 387; 412; 420; 428; 429; 437; 438; 439; 444; 447; 461; 469; 474; 477; 481; 495; 496; 509; 512; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 579; 583; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 651; 652; 662; 664; 665; 667; 683; 686; 693; 698; 699; 744; 745; 760; 761; 777; 779; 784; 792; 797; 806; 810; 817; 819; 820; 827; 832; 835; 836; 838; 839; 845; 846; 847; 850; 851; 858; 865; 878; 882; 883; 888; 901; 903; 904; 909; 931; 987; 995; 1001; 1008; 1017; 1018; 1019; 1020; 1030; 1031; 1040; 1041; 1053; 1054; 1055; 1057; 1058; 1069; 1076; 1098; 1127; 1128; 1141 and mixtures thereof.
In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147, Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; and Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147 and mixtures thereof, in one aspect, said composition comprises a material selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147, Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; and Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147 and mixtures thereof.
In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 4; 13; 16; 17; 18; 21; 32; 33; 34; 35; 37; 42; 49; 57; 76; 126; 145; 156; 167; 168; 174; 190; 199; 206; 208; 210; 242; 247; 249; 259; 277; 281; 286; 289; 318; 353; 370; 371; 372; 373; 378; 407; 417; 424; 425; 429; 449; 457; 468; 474; 479; 480; 482; 485; 501; 524; 527; 529; 537; 562; 578; 580; 587; 589; 592; 595; 612; 615; 618; 621; 632; 638; 639; 649; 683; 702; 711; 733; 735; 736; 741; 748; 767; 771; 786; 788; 824; 834; 839; 866; 868; 877; 905; 924; 955; 969; 974; 976; 980; 982; 993; 1016; 1037; 1038; 1042; 1060; 1075; 1077; 1078; 1090; 1091; 1117; 1137; 1146, Table 3 materials 13; 21; 27; 32; 34; 37; 73; 81; 107; 115; 125; 126; 157; 163; 167; 169; 194; 198; 201; 205; 239; 242; 277; 282; 286; 287; 289; 319; 366; 370; 371; 372; 376; 378; 407; 417; 419; 429; 437; 439; 442; 443; 457; 474; 479; 480; 482; 485; 495; 496; 509; 512; 525; 529; 537; 549; 556; 576; 579; 583; 585; 588; 589; 592; 617; 619; 638; 640; 641; 652; 664; 665; 683; 740; 743; 760; 771; 779; 784; 810; 812; 820; 839; 845; 846; 847; 858; 875; 883; 888; 901; 902; 903; 904; 940; 981; 1001; 1002; 1017; 1018; 1019; 1039; 1040; 1051; 1054; 1071; 1075; 1081; 1088; 1091; 1115; 1118; 1119; 1122; 1133; 114, and mixtures thereof, in one aspect, said composition comprises a material selected from Table 1 materials 4; 21; 32; 33; 34; 35; 42; 49; 145; 167; 168; 190; 208; 210; 259; 281; 424; 429; 449; 468; 474; 524; 527; 578; 580; 587; 589; 612; 615; 618; 621; 632; 639; 649; 683; 702; 711; 748; 767; 786; 834; 839; 866; 868; 877; 905; 955; 969; 974; 982; 993; 1016; 1037; 1060; 1077; 1078; 1137, Table 3 materials 21; 27; 32; 34; 73; 81; 125; 126; 157; 163; 167; 169; 194; 198; 201; 205; 239; 282; 287; 319; 366; 376; 419; 429; 437; 439; 443; 474; 495; 496; 509; 512; 525; 549; 556; 576; 579; 583; 585; 588; 589; 617; 619; 640; 652; 664; 665; 683; 740; 760; 779; 784; 810; 812; 820; 839; 845; 846; 847; 858; 875; 883; 888; 901; 902; 903; 904; 940; 981; 1001; 1017; 1018; 1019; 1039; 1040; 1051; 1054; 1071; 1081; 1115; 1122 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material, in one aspect, comprises a malodor reduction material having a Universal MORV.
Preferably, said composition comprising a malodor reduction material having a Universal MORV comprises a malodor reduction material selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 627; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, and Table 6 material 627 and mixtures thereof. In one aspect, such materials are selected from Table 4 material 627 and mixtures thereof are disclosed.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV. In one aspect, said composition comprises, a malodor reduction material selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, and mixtures thereof are disclosed.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 7; 14; 39; 48; 183; 206; 212; 215; 229; 260; 261; 329; 335; 360; 441; 484; 487; 488; 501; 566; 567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663; 680; 684; 694; 696; 708; 712; 714; 726; 750; 775; 776; 788; 804; 872; 919; 927; 933; 978; 1007; 1022; 1024; 1029; 1035; 1038; 1060; 1089; 1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145, Table 5 materials 248, and Table 6 material 472 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 199; 206; 281; 353; 501; 621; 632; 788; 1038; 1060; 1137 and mixtures thereof. In one aspect, such materials are selected from Table 4 281; 621; 632; 1060; 1137 and mixtures thereof.
A composition according to any preceding embodiment wherein said malodor reduction material is not a material selected from the group consisting of 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 and mixtures thereof.
A composition according to any preceding embodiment, said malodor reduction composition being a consumer product, said consumer comprising a total of, based on total consumer product weight, from about 0.0001% to about 100% of one or more of said malodor reduction materials and an adjunct material is disclosed.
In one aspect, said malodor reduction composition that is a consumer product is a laundry detergent that comprises a total of, based on total consumer product weight, from about 0.0001% to about 10%, in one aspect, from about 0.001% to about 5%, in one aspect, from about 0.1% to about 3%, in one aspect, from about 0.3% to about 2% of one or more of said malodor reduction materials and, a material selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, a fabric softener active, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and mixtures thereof, in none aspect, said laundry detergent comprises an adjunct material selected from the group consisting of an organic acid, in one aspect, citric acid and/or lactic acid, hydrogenated castor oil, ethoxylated polyethleneimines, in one aspect, PEI 600 EO 20 and/or PEI 600, an enzyme, in one aspect, a cold water amylase, cold water protease and/or xylogluconase.
In one aspect, said malodor reduction composition that is a consumer product is air care composition that comprises a total of, based on total consumer product weight, from about 0.001% to about 100%, in none apect, from 0.01 to 10%, of one or more of said malodor reduction materials and, optionally, one or more materials selected from the group consisting of surfactants, antimicrobial agents, wetting agents, buffering agents, cyclodextrins, propellants, and solvents.
In one aspect, said malodor reduction composition that is a consumer product is a liquid fabric enhancer that comprises a total of, based on total composition weight, from about 0.05% to about 10% of one or more of said malodor reduction materials and, a fabric softener active selected from the group consisting of a quaternary ammonium compound, a silicone polymer, a polysaccharide, a clay, an amine, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, in one aspect, said quaternary ammonium compound is selected from the group consisting of bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester, 1,2-di(acyloxy)-3-trimethylammoniopropane chloride, N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium methylsulfate, 1,2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride dicanoladimethylammonium methylsulfate, 1-methyl-1-stearoylamidoethyl-2-stearoylimidazolinium methylsulfate, 1-tallowylamidoethyl-2-tallowylimidazoline, Dipalmethyl Hydroxyethylammoinum Methosulfate and mixtures thereof, in one aspect, said fabric softening active has an Iodine Value of between 0-140, in one aspect, 5-100, in one aspect,10-80, in one aspect, 15-70, in one aspect 18-25.
In one aspect, said malodor reduction composition that is a consumer product is a fabric enhancer solid particle or bead composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and at least about 25% PEG 8000.
In one aspect, said malodor reduction composition that is a consumer product is a soluble unit-dose composition contained within a PVA film.
In one aspect, said malodor reduction composition that is a consumer product is a fabric softener dryer added sheet composition, said fabric softener dryer added sheet composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and impregnated onto a non-woven sheet.
In one aspect, said malodor reduction composition that is a consumer product is a spray-dried laundry detergent powder, said composition comprising from about 0.05% to about 20% of one or more of said malodor reduction materials and at least 10% solids chosen from the following list or combinations thereof: sodium carbonate, sodium sulfate, carboxy methyl cellulose powder, a polymer comprising an acrylate monomer.
In one aspect, said malodor reduction composition that is a consumer product is a plastic film said plastic film comprising LLDPE, LDPE, HDPE, and/or compostable film, in one aspect, said plastic film comprises about 0.5 mg to about 100 mg of said malodor reduction composition per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 30 mg per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 15 mg per 20 grams of said plastic film.
In one aspect, said malodor reduction composition that is a consumer product is an absorbent article said absorbent article comprising a total of, based on total consumer product weight, from about 0.1% to about 75%, in one aspect, from about 1% to about 50%, in one aspect, from about 5% to about 40%, in one aspect, from about 12% to about 30% of one or more of said malodor reduction materials and, wherein the article comprises a topsheet, a backsheet, an absorbent core disposed between the topsheet and the backsheet, and an acquisition layer disposed between the topsheet and the absorbent core, wherein the malodor reduction composition is disposed on one of the backsheet, absorbent core, or acquisition layer, in one aspect, said absorbant article comprises a hot melt adhesive and the hot melt adhesive comprises the malodor reduction composition, in one aspect, the hot melt adhesive adheres the backsheet to the topsheet, in one aspect, the backsheet comprises a nonwoven layer and a film layer, and the hot melt adhesive adheres the backsheet nonwoven layer to the backsheet film layer.
In one aspect, said malodor reduction composition that is a consumer product is a personal care deodorant composition, said deodorant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 0.01% to about 75% of an antimicrobial, in one aspect, said antimicrobialsare selected from the group consisting of metals, zeolites, metal zeolites, quaternary ammonium (quat) compounds (e.g., cetyl pyridinium chloride, and benzylalkonium chloride), quat bound clays, metal bound clays, polyaspirin. salicylic acid, polyvinyl amines, coal tar, sulfur, whitfield's ointment, castellani's paint, aluminum chloride, gentian violet, octopirox (piroctone olamine), ciclopirox olamine, undecylenic acid and it's metal salts, potassium permanganate, selenium sulfide, sodium thiosulfate, glycols, diols, oil of bitter orange, urea preparations, griseofulvin, 8-Hydroxyquinoline ciloquinol, thiobendazole, thiocarbamates, haloprogin, polyenes, hydroxypyridone, morpholine, benzylamine, allylamines (such as terbinafine), tea tree oil, clove leaf oil, coriander, palmarosa, berberine, thyme red, cinnamon oil, citronellic acid, hinokitol, ichthyol pale, Sensiva SC-50, Elestab HP-100, azelaic acid, lyticase, iodopropynyl butylcarbamate (IPBC), triclosan, triclocarban, isothiazalinones and azoles, and combinations thereof, more preferably, hexanediol, triclosan, octyl isothiazalinone metals selected from the group consisting of Zn, Cu, Al, Ti, Sn, Bi, and Ag, metal salts selected from the group consisting of zinc carbonate, copper sulfate, and zinc gluconate, metal pyrithione salts selected from the group consisting of ZPT and CuPT, glycols selected from the group consisting of propylene glycol, dipropylene glycol and hexylene glycol and mixtures thereof, in one aspect, said personal care deodorant composition comprises, based on total deodorant weight, from about 10% to about 75% glycol.
In one aspect, said malodor reduction composition that is a consumer product is a personal care body wash/shampoo composition, said body wash/shampoo comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials from about 3% to 30% of a surfactant, and, optionally, a miscellar phase and/or lamellar phase.
In one aspect, said malodor reduction composition that is a consumer product is a personal care antiperspirant composition, said antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 1% to about 25% of an aluminum salt antiperspirant active.
In one aspect, said malodor reduction composition that is a consumer product is an anhydrous antiperspirant composition, said anhydrous antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and from about 1% to about 25% oof an antiperspirant actives slected from the group consisiting of astringent metallic salts, in one aspect, inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof, in one aspect, aluminum halides, aluminum chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.
In one aspect, said malodor reduction composition that is a consumer product is a dish cleaning composition, said dish cleaning composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials.
In one aspect, a method of controlling malodors comprising: contacting the material comprising a malodor with a composition selected from the group consisting of any of the compositions comprising a malodor reduction material disclosed herein and mixtures thereof, in one aspect, said contacting step comprises contacting said material containing a malodor with about 1 mg to about 50 mg, from about 3 mg to 30 mg, or from about 5 mg to about 20 mg of said composition per 20 grams of said material containing a malodor is disclosed.
In one aspect, a method of determining the material's ability to decrease or even eliminate the perception of one or more malodors comprising determining the MORV and/or Universal MORV of said material, in one aspect, determining said MORV and/or Universal MORV by the MORV and Universal MORV method provided in Test Method 1, is disclosed.

Process of Making Encapsulates

Methods of making suitable encapsulated malodor reduction compositions, for example condensation processes, as well as suitable shell materials for such encapsulated malodor reduction compositions are described in U.S. Pat. No. 6,869,923 B1 and US Published Patent Applications Nos. 2005/0276831 A1 and 2007/020263 A1. Such shell materials include acrylates, acrylics, aminoplast materials such as melamine formaldehyde material and combinations thereof. Suitable equipment for use in the processes disclosed herein may include continuous stirred tank reactors, homogenizers, turbine agitators, recirculating pumps, paddle mixers, ploughshear mixers, ribbon blenders, vertical axis granulators and drum mixers, both in batch and, where available, in continuous process configurations, spray dryers, and extruders. Such equipment can be obtained from Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Ky., U.S.A.), Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex Corp. (Minneapolis, Minn., U.S.A.), Arde Barinco (N.J., U.S.A.).

Adjunct Materials

While not essential for the purposes of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant compositions and may be desirably incorporated in certain aspects of the invention, for example to assist or enhance cleaning performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the fabric treatment operation for which it is to be used. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives.
As stated, the adjunct ingredients are not essential to Applicants' compositions. Thus, certain aspects of Applicants' compositions do not contain one or more of the following adjuncts materials: surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems structure elasticizing agents, carriers, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below.
Hueing Dye—The liquid laundry detergent composition may comprise a hueing dye. The hueing dyes employed in the present laundry care compositions may comprise polymeric or non-polymeric dyes, organic or inorganic pigments, or mixtures thereof. In one aspect, the hueing dye comprises a polymeric dye, comprising a chromophore constituent and a polymeric constituent. The chromophore constituent is characterized in that it absorbs light in the wavelength range of blue, red, violet, purple, or combinations thereof upon exposure to light. In one aspect, the chromophore constituent exhibits an absorbance spectrum maximum from about 520 nanometers to about 640 nanometers in water and/or methanol, and in another aspect, from about 560 nanometers to about 610 nanometers in water and/or methanol.
Although any suitable chromophore may be used, the dye chromophore is, in one aspect, selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone, anthraquinone, azo, oxazine, azine, xanthene, triphenodioxazine and phthalocyanine dye chromophores. Mono and di-azo dye chromophores are may be preferred.
The hueing dye may comprise a dye polymer comprising a chromophore covalently bound to one or more of at least three consecutive repeat units. It should be understood that the repeat units themselves do not need to comprise a chromophore. The dye polymer may comprise at least 5, or at least 10, or even at least 20 consecutive repeat units.
The repeat unit can be derived from an organic ester such as phenyl dicarboxylate in combination with an oxyalkyleneoxy and a polyoxyalkyleneoxy. Repeat units can be derived from alkenes, epoxides, aziridine, carbohydrate including the units that comprise modified celluloses such as hydroxyalkylcellulose; hydroxypropyl cellulose; hydroxypropyl methylcellulose; hydroxybutyl cellulose; and, hydroxybutyl methylcellulose or mixtures thereof. The repeat units may be derived from alkenes, or epoxides or mixtures thereof. The repeat units may be C₂-C₄alkyleneoxy groups, sometimes called alkoxy groups, in one aspect, derived from C₂-C₄alkylene oxide. The repeat units may be C₂-C₄alkoxy groups, in one aspect, ethoxy groups.
For the purposes of the present invention, the at least three consecutive repeat units form a polymeric constituent. The polymeric constituent may be covalently bound to the chromophore group, directly or indirectly via a linking group. Examples of suitable polymeric constituents include polyoxyalkylene chains having multiple repeating units. In one aspect, the polymeric constituents include polyoxyalkylene chains having from 2 to about 30 repeating units, from 2 to about 20 repeating units, from 2 to about 10 repeating units or even from about 3 or 4 to about 6 repeating units. Non-limiting examples of polyoxyalkylene chains include ethylene oxide, propylene oxide, glycidol oxide, butylene oxide and mixtures thereof.
Surfactants—The compositions according to the present invention may comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic surfactants, anionic surfactants, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semi-polar nonionic surfactants and mixtures thereof.
The surfactant is typically present at a level of from about 0.1% to about 60%, from about 1% to about 50% or even from about 5% to about 40% by weight of the subject composition.
Chelating Agents—The compositions herein may contain a chelating agent. Suitable chelating agents include copper, iron and/or manganese chelating agents and mixtures thereof. When a chelating agent is used, the composition may comprise from about 0.1% to about 15% or even from about 3.0% to about 10% chelating agent by weight of the subject composition.
Dye Transfer Inhibiting Agents—The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.
When present in a subject composition, the dye transfer inhibiting agents may be present at levels from about 0.0001% to about 10%, from about 0.01% to about 5% or even from about 0.1% to about 3% by weight of the composition.
Dispersants—The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials include the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms.
Perfumes—The dispersed phase may comprise a perfume that may include materials selected from the group consisting of perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, α-damascone, β-damascone, δ-damascone, β-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and β-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.
Perfume Delivery Technologies—The compositions of the present invention may comprise one or more perfume delivery technologies that stabilize and enhance the deposition and release of perfume ingredients from treated substrate. Such perfume delivery technologies can also be used to increase the longevity of perfume release from the treated substrate. Perfume delivery technologies, methods of making certain perfume delivery technologies and the uses of such perfume delivery technologies are disclosed in US 2007/0275866 A1.
In one aspect, the compositions of the present invention may comprise from about 0.001% to about 20%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or even from about 0.1% to about 0.5% by weight of the perfume delivery technology. In one aspect, said perfume delivery technologies may be selected from the group consisting of: perfume microcapsules, pro-perfumes, polymer particles, functionalized silicones, polymer assisted delivery, molecule assisted delivery, fiber assisted delivery, amine assisted delivery, cyclodextrins, starch encapsulated accord, zeolite and inorganic carrier, and mixtures thereof:
In one aspect, said perfume delivery technology may comprise microcapsules formed by at least partially surrounding a benefit agent with a wall material. Said benefit agent may include materials selected from the group consisting of perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, α-damascone, β-damascone, δ-damascone, β-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and β-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable perfume materials can be obtained from Givaudan Corp. of Mount Olive, N.J., USA, International Flavors & Fragrances Corp. of South Brunswick, N.J., USA, or Quest Corp. of Naarden, Netherlands. In one aspect, the microcapsule wall material may comprise: melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, gelatin, styrene malic anhydride, polyamides, and mixtures thereof. In one aspect, said melamine wall material may comprise melamine crosslinked with formaldehyde, melamine-dimethoxyethanol crosslinked with formaldehyde, and mixtures thereof. In one aspect, said polystyrene wall material may comprise polyestyrene cross-linked with divinylbenzene. In one aspect, said polyurea wall material may comprise urea crosslinked with formaldehyde, urea crosslinked with gluteraldehyde, and mixtures thereof. In one aspect, said polyacrylate based materials may comprise polyacrylate formed from methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formed from amine acrylate and/or methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and/or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and/or methacrylate monomer and a carboxylic acid acrylate and/or carboxylic acid methacrylate monomer, and mixtures thereof. In one aspect, the perfume microcapsule may be coated with a deposition aid, a cationic polymer, a non-ionic polymer, an anionic polymer, or mixtures thereof. Suitable polymers may be selected from the group consisting of: polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol, polyacrylates, and combinations thereof. In one aspect, the microcapsule may be a perfume microcapsule. In one aspect, one or more types of microcapsules, for example two microcapsules types having different benefit agents may be used.
In one aspect, said perfume delivery technology may comprise an amine reaction product (ARP) or a thio reaction product. One may also use “reactive” polymeric amines and or polymeric thiols in which the amine and/or thiol functionality is pre-reacted with one or more PRMs to form a reaction product. Typically the reactive amines are primary and/or secondary amines, and may be part of a polymer or a monomer (non-polymer). Such ARPs may also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine-assisted delivery. Nonlimiting examples of polymeric amines include polymers based on polyalkylimines, such as polyethyleneimine (PEI), or polyvinylamine (PVAm). Nonlimiting examples of monomeric (non-polymeric) amines include hydroxyl amines, such as 2-aminoethanol and its alkyl substituted derivatives, and aromatic amines such as anthranilates. The ARPs may be premixed with perfume or added separately in leave-on or rinse-off applications. In another aspect, a material that contains a heteroatom other than nitrogen and/or sulfur, for example oxygen, phosphorus or selenium, may be used as an alternative to amine compounds. In yet another aspect, the aforementioned alternative compounds can be used in combination with amine compounds. In yet another aspect, a single molecule may comprise an amine moiety and one or more of the alternative heteroatom moieties, for example, thiols, phosphines and selenols. The benefit may include improved delivery of perfume as well as controlled perfume release. Suitable ARPs as well as methods of making same can be found in USPA 2005/0003980 A1 and U.S. Pat. No. 6,413,920 B1.

Fabric Softening Actives

The compositions of the present invention may comprise a fabric softening active (“FSA”). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quaternary ammonium compounds (quat), amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty acids, softening oils, polymer latexes and mixtures thereof.
Non-limiting examples of water insoluble fabric care benefit agents include dispersible polyethylene and polymer latexes.
Quat—Suitable quats include but are not limited to, materials selected from the group consisting of ester quats, amide quats, imidazoline quats, alkyl quats, amdioester quats and mixtures thereof. Suitable ester quats include but are not limited to, materials selected from the group consisting of monoester quats, diester quats, triester quats and mixtures thereof. In one aspect, a suitable ester quat is bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.85 to 1.99, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of the fatty acid moieties, calculated for the free fatty acid, of from 0.5 to 60 or 15 to 50. In one aspect, the cis-trans-ratio of double bonds of unsaturated fatty acid moieties of the bis (2 hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is from 55:45 to 75:25, respectively. Suitable amide quats include but are not limited to, materials selected from the group consisting of monoamide quats, diamide quats and mixtures thereof. Suitable alkyl quats include but are not limited to, materials selected from the group consisting of mono alkyl quats, dialkyl quats quats, trialkyl quats, tetraalkyl quats and mixtures thereof.
In one embodiment, the fabric softening active is a quaternary ammonium compound suitable for softening fabric in a rinse step. In one embodiment, the fabric softening active is formed from a reaction product of a fatty acid and an aminoalcohol obtaining mixtures of mono-, di-, and, in one embodiment, tri-ester compounds. In another embodiment, the fabric softening active comprises one or more softener quaternary ammonium compounds such, but not limited to, as a monoalkyquaternary ammonium compound, dialkylquaternary ammonium compound, a diamido quaternary compound, a diester quaternary ammonium compound, or a combination thereof.
In one aspect, the fabric softening active comprises a diester quaternary ammonium or protonated diester ammonium (hereinafter “DQA”) compound composition. In certain embodiments of the present invention, the DQA compound compositions also encompass diamido fabric softening actives s and fabric softening actives with mixed amido and ester linkages as well as the aforementioned diester linkages, all herein referred to as DQA.
In one embodiment, the fabric softening agent is chosen from at least one of the following: ditallowoyloxyethyl dimethyl ammonium chloride, dihydrogenated-tallowoyloxyethyl dimethyl ammonium chloride, ditallow dimethyl ammonium chloride, dihydrogenatedtallow dimethyl ammonium chloride, ditallowoyloxyethyl methylhydroxyethylammonium methyl sulfate, dihydrogenated-tallowoyloxyethyl methyl hydroxyethylammonium chloride, or combinations thereof.
It will be understood that combinations of softener actives disclosed above are suitable for use in this invention.

Anion A

In the cationic nitrogenous salts herein, the anion A⁻, which comprises any softener compatible anion, provides electrical neutrality. Most often, the anion used to provide electrical neutrality in these salts is from a strong acid, especially a halide, such as chloride, bromide, or iodide. However, other anions can be used, such as methylsulfate, ethylsulfate, acetate, formate, sulfate, carbonate, fatty acid anions and the like. In one aspect, the anion A may comprise chloride or methylsulfate. The anion, in some aspects, may carry a double charge. In this aspect, A⁻ represents half a group.
Silicone
In one embodiment, the compositions of the present invention may comprise a silicone. Suitable levels of silicone may comprise from about 0.1% to about 70%, alternatively from about 0.3% to about 40%, alternatively from about 0.5% to about 30%, alternatively from about 1% to about 20% by weight of the composition. Useful silicones can be any silicone comprising compound. In one embodiment, the silicone polymer is selected from the group consisting of cyclic silicones, polydimethylsiloxanes, aminosilicones, cationic silicones, silicone polyethers, silicone resins, silicone urethanes, and mixtures thereof. In one embodiment, the silicone is a polydialkylsilicone, alternatively a polydimethyl silicone (polydimethyl siloxane or “PDMS”), or a derivative thereof. In another embodiment, the silicone is chosen from an aminofunctional silicone, amino-polyether silicone, alkyloxylated silicone, cationic silicone, ethoxylated silicone, propoxylated silicone, ethoxylated/propoxylated silicone, quaternary silicone, or combinations thereof.
In another embodiment, the silicone may be chosen from a random or blocky organosilicone polymer having the following formula:
[R₁R₂R₃SiO_1/2]_(j+2)[(R₄Si(X—Z)O_2/2]_k[R₄R₄SiO_2/2]_m[R₄SiO_3/2]_j
wherein:

- j is an integer from 0 to about 98; in one aspect j is an integer from 0 to about 48; in one aspect, j is 0;
- k is an integer from 0 to about 200, in one aspect k is an integer from 0 to about 50; when k=0, at least one of R₁, R₂or R₃is —X—Z;
- m is an integer from 4 to about 5,000; in one aspect m is an integer from about 10 to about 4,000; in another aspect m is an integer from about 50 to about 2,000;
  - R₁, R₂and R₃are each independently selected from the group consisting of H, OH, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, C₆-C₃₂substituted alkylaryl, C₁-C₃₂alkoxy, C₁-C₃₂substituted alkoxy and X—Z;
  - each R₄is independently selected from the group consisting of H, OH, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, C₆-C₃₂substituted alkylaryl, C₁-C₃₂alkoxy and C₁-C₃₂substituted alkoxy;
  - each X in said alkyl siloxane polymer comprises a substituted or unsubstituted divalent alkylene radical comprising 2-12 carbon atoms, in one aspect each divalent alkylene radical is independently selected from the group consisting of —(CH₂)_s— wherein s is an integer from about 2 to about 8, from about 2 to about 4; in one aspect, each X in said alkyl siloxane polymer comprises a substituted divalent alkylene radical selected from the group consisting of: —CH₂—CH(OH)—CH₂—; —CH₂—CH₂—CH(OH)—; and

- - each Z is selected independently from the group consisting of

with the proviso that when Z is a quat, Q cannot be an amide, imine, or urea moiety and if Q is an amide, imine, or urea moiety, then any additional Q bonded to the same nitrogen as said amide, imine, or urea moiety must be H or a C₁-C₆alkyl, in one aspect, said additional Q is H; for Z Aⁿ⁻ is a suitable charge balancing anion. In one aspect Aⁿ⁻ is selected from the group consisting of Cl⁻, Br⁻, I⁻, methylsulfate, toluene sulfonate, carboxylate and phosphate; and at least one Q in said organosilicone is independently selected from —CH₂—CH(OH)—CH₂—R₅;

- - each additional Q in said organosilicone is independently selected from the group comprising of H, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, C₆-C₃₂substituted alkylaryl, —CH₂—CH(OH)—CH₂—R₅;

- - wherein each R₅is independently selected from the group consisting of H, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, C₆-C₃₂substituted alkylaryl, —(CHR₆—CHR₆—O—)_w-L and a siloxyl residue;
  - each R₆is independently selected from H, C₁-C₁₈alkyl
  - each L is independently selected from —C(O)—R₇or R₇;
  - w is an integer from 0 to about 500, in one aspect w is an integer from about 1 to about 200; in one aspect w is an integer from about 1 to about 50;
  - each R₇is selected independently from the group consisting of H; C₁-C₃₂alkyl; C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl; C₆-C₃₂substituted alkylaryl and a siloxyl residue;
  - each T is independently selected from H, and

and wherein each v in said organosilicone is an integer from 1 to about 10, in one aspect, v is an integer from 1 to about 5 and the sum of all v indices in each Q in the said organosilicone is an integer from 1 to about 30 or from 1 to about 20 or even from 1 to about 10.
In another embodiment, the silicone may be chosen from a random or blocky organosilicone polymer having the following formula:
[R₁R₂R₃SiO_1/2]_(j+2)[(R₄Si(X—Z)O_2/2]_k[R₄R₄SiO_2/2]_m[R₄SiO_3/2]_j
wherein

- j is an integer from 0 to about 98; in one aspect j is an integer from 0 to about 48; in one aspect, j is 0;
- k is an integer from 0 to about 200; when k=0, at least one of R₁, R₂or R₃═—X—Z, in one aspect, k is an integer from 0 to about 50
- m is an integer from 4 to about 5,000; in one aspect m is an integer from about 10 to about 4,000; in another aspect m is an integer from about 50 to about 2,000;
  - R₁, R₂and R₃are each independently selected from the group consisting of H, OH, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, C₆-C₃₂substituted alkylaryl, C₁-C₃₂alkoxy, C₁-C₃₂substituted alkoxy and X—Z;
  - each R₄is independently selected from the group consisting of H, OH, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, C₆-C₃₂substituted alkylaryl, C₁-C₃₂alkoxy and C₁-C₃₂substituted alkoxy;
  - each X comprises of a substituted or unsubstituted divalent alkylene radical comprising 2-12 carbon atoms; in one aspect each X is independently selected from the group consisting of —(CH₂)_s—O—; —CH₂—CH(OH)—CH₂—O—;

- - wherein each s independently is an integer from about 2 to about 8, in one aspect s is an integer from about 2 to about 4;
  - At least one Z in the said organosiloxane is selected from the group consisting of R₅;

provided that when X is
then Z═—OR₅or

- - wherein A⁻ is a suitable charge balancing anion. In one aspect A⁻ is selected from the group consisting of Cl⁻, Br⁻,
  - I⁻, methylsulfate, toluene sulfonate, carboxylate and phosphate and
  - each additional Z in said organosilicone is independently selected from the group comprising of H, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, C₆-C₃₂substituted alkylaryl, R₅,

provided that when X is
then Z═—OR₅or

- - each R₅is independently selected from the group consisting of H; C₁-C₃₂alkyl; C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl or C₆-C₃₂alkylaryl, or C₆-C₃₂substituted alkylaryl,
  - —(CHR₆—CHR₆—O—)_w—CHR₆—CHR₆-L and siloxyl residue wherein each L is independently selected from —O—C(O)—R₇or —O—R₇;

- - w is an integer from 0 to about 500, in one aspect w is an integer from 0 to about 200, one aspect w is an integer from 0 to about 50;
  - each R₆is independently selected from H or C₁-C₁₈alkyl;
  - each R₇is independently selected from the group consisting of H; C₁-C₃₂alkyl; C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, and C₆-C₃₂substituted aryl, and a siloxyl residue;
  - each T is independently selected from H;

- - wherein each v in said organosilicone is an integer from 1 to about 10, in one aspect, v is an integer from 1 to about 5 and the sum of all v indices in each Z in the said organosilicone is an integer from 1 to about 30 or from 1 to about 20 or even from 1 to about 10.

In one embodiment, the silicone is one comprising a relatively high molecular weight. A suitable way to describe the molecular weight of a silicone includes describing its viscosity. A high molecular weight silicone is one having a viscosity of from about 10 cSt to about 3,000,000 cSt, or from about 100 cSt to about 1,000,000 cSt, or from about 1,000 cSt to about 600,000 cSt, or even from about 6,000 cSt to about 300,000 cSt,

In one embodiment, the silicone comprises a blocky cationic organopolysiloxane having the formula:

M_wD_xT_yQ_z

wherein:
M=[SiR₁R₂R₃O_1/2], [SiR₁R₂G₁O_1/2], [SiR₁G₁G₂O_1/2], [SiG₁G₂G₃O_1/2], or combinations thereof;
D=[SiR₁R₂O_2/2], [SiR₁G₁O_2/2], [SiG₁G₂O_2/2] or combinations thereof;
T=[SiR₁O_3/2], [SiG₁O_3/2] or combinations thereof;
Q=[SiO_4/2];
w=is an integer from 1 to (2+y+2z);
x=is an integer from 5 to 15,000;
y=is an integer from 0 to 98;
z=is an integer from 0 to 98;
R₁, R₂and R₃are each independently selected from the group consisting of H, OH, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, C₆-C₃₂substituted alkylaryl, C₁-C₃₂alkoxy, C₁-C₃₂substituted alkoxy, C₁-C₃₂alkylamino, and C₁-C₃₂substituted alkylamino;
at least one of M, D, or T incorporates at least one moiety G₁, G₂or G_3;and G₁, G₂, and G₃are each independently selected from the formula:

wherein:
X comprises a divalent radical selected from the group consisting of C₁-C₃₂alkylene, C₁-C₃₂substituted alkylene, C₅-C₃₂or C₆-C₃₂arylene, C₅-C₃₂or C₆-C₃₂substituted arylene, C₆-C₃₂arylalkylene, C₆-C₃₂substituted arylalkylene, C₁-C₃₂alkoxy, C₁-C₃₂substituted alkoxy, C₁-C₃₂alkyleneamino, C₁-C₃₂substituted alkyleneamino, ring-opened epoxide, and ring-opened glycidyl, with the proviso that if X does not comprise a repeating alkylene oxide moiety then X can further comprise a heteroatom selected from the group consisting of P, N and O;
each R₄comprises identical or different monovalent radicals selected from the group consisting of H, C₁-C₃₂alkyl, C₁-C₃₂substituted alkyl, C₅-C₃₂or C₆-C₃₂aryl, C₅-C₃₂or C₆-C₃₂substituted aryl, C₆-C₃₂alkylaryl, and C₆-C₃₂substituted alkylaryl;
E comprises a divalent radical selected from the group consisting of C₁-C₃₂alkylene, C₁-C₃₂substituted alkylene, C₅-C₃₂or C₆-C₃₂arylene, C₅-C₃₂or C₆-C₃₂substituted arylene, C₆-C₃₂arylalkylene, C₆-C₃₂substituted arylalkylene, C₁-C₃₂alkoxy, C₁-C₃₂substituted alkoxy, C₁-C₃₂alkyleneamino, C₁-C₃₂substituted alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with the proviso that if E does not comprise a repeating alkylene oxide moiety then E can further comprise a heteroatom selected from the group consisting of P, N, and O;
E′ comprises a divalent radical selected from the group consisting of C₁-C₃₂alkylene, C₁-C₃₂substituted alkylene, C₅-C₃₂or C₆-C₃₂arylene, C₅-C₃₂or C₆-C₃₂substituted arylene, C₆-C₃₂arylalkylene, C₆-C₃₂substituted arylalkylene, C₁-C₃₂alkoxy, C₁-C₃₂substituted alkoxy, C₁-C₃₂alkyleneamino, C₁-C₃₂substituted alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with the proviso that if E′ does not comprise a repeating alkylene oxide moiety then E′ can further comprise a heteroatom selected from the group consisting of P, N, and O;
p is an integer independently selected from 1 to 50;
n is an integer independently selected from 1 or 2;
when at least one of G₁, G₂, or G₃is positively charged, A^−tis a suitable charge balancing anion or anions such that the total charge, k, of the charge-balancing anion or anions is equal to and opposite from the net charge on the moiety G₁, G₂or G_3;wherein t is an integer independently selected from 1, 2, or 3; and k≦(p*2/t)+1; such that the total number of cationic charges balances the total number of anionic charges in the organopolysiloxane molecule; and wherein at least one E does not comprise an ethylene moiety.

Test Methods

Malodor reduction materials may be separated from mixtures, including but not limited to finished products such as consumer products and indentified, by analytical methods that include GC-MS and/or NMR.

MORV and Universal MORV Calculation

1.) Search Chemical Abstracts using the name and/or the CAS Registry number for the material of interest and use the structure provided. If there are multiple isomers for a given material, use the structure provided by Chemical Abstracts or use the isomer that is most prevalent in the material. Input structure of material into winMolconn (Hall Associates, version 1.1.2.1).
2.) Input values from 1.) above into the following four equations:

a) MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22)
b) MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2O2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar)
c) MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403×(idc)−0.23286×(nd2).
d) MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C3O2)−0.45767×(c1C2C3)+0.7684×(CKetone)

Equation a) is for the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors)
Equation b) is for the malodor trimethylamine (amine based malodors)
Equation c) is for the malodor 3-mercapto-3-methylhexan-1-ol (thiol based malodors)
Equation d) is for the malodor skatole (indole based malodors)
3.) For purpose of the present application, a material's MORV is the highest MORV value from equations 2.)a) through 2.)d).
4.) If all MORV values from equations 2.)a) through 2.)d) above are greater than 0.5, the subject material has a Universal MORV.

EXAMPLE 1

Malodor Reduction Composition


		MRC A	MRC B	MRC C
Ingredient	CAS #	Percent	Percent	Percent

5-Cyclohexadecen-1-One	37609-25-9	15.0	2.00	2.00
decahydro-2,2,7,7,8,9,9-	476332-65-7	0.005	0.01	0.01
heptamethylindeno(4,3a-b)furan
2,3-Dihydro-5,6-dimethoxy-2-(4-	33704-61-9	0.3	0.5	0.5
piperidinylmethylene)-1H-inden-1-one
Cedryl Methyl Ether	19870-74-7	6.0	10.0	4.0
Trans-4-Decenal	65405-70-1	0.005	0.002	0.002
Decyl Aldehyde	112-31-2	3.74	2.0	2.0
3-methyl cyclopentadecenone	63314-79-4	0.4	1.0	1.0
Diphenyl Oxide	101-84-8	0.5	1.0	1.0
3a,4,5,6,7,7a-hexahydro-4,7-methano-	54830-99-8	5.0	8.0	8.0
1H-indenyl acetate
3a,4,5,6,7,7a-hexahydro-1H-4,7-	68912-13-0	6.0	8.0	8.0
methanoinden-1-yl propanoate
2-(5-methyl-2-propan-2-yl-8-	68901-32-6	10.0	15.0	15.0
bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane
(E)-3,7-dimethyl-2,6-	3681-73-0	10.0	10.0	16.0
octadienylhexadecanoate
Iso Nonyl Acetate	58430-94-7	6.65	8.0	3.0
2,2,7,7-	23787-90-8	10.0	8.0	8.0
tetramethyltricyclo[6.2.1.01,6]undecan-
5-one
(1-Methyl-2-(1,2,2-	198404-98-7	0.1	0.3	0.3
trimethylbicyclo[3.1.0]-hex-3-
ylmethyl)cyclopropyl)methanol
Lauric Aldehyde	112-54-9	0.625	1.0	0.7
Methyl Iso Eugenol	93-16-3	18.000	10.0	13.0
Methyl hexadecanoate	112-39-0	3.000	10.0	12.0
2,3-dihydro-1,1-1H-dimethyl-indene-	300371-33-9	0.400	0.0	0.3
ar-propanal
4-tert-butylcyclohexanol	98-52-2	0.400	0.1	0.1
2-isobutyl-4-hydroxy-4-	63500-71-0	1.600	2.0	2.0
methyltetrahydropyran
Undecyl Aldehyde	112-44-7	1.725	2.888	1.888
Undecylenic Aldehyde	112-45-8	0.550	0.2	1.2
Total		100	100.0	100.0

The term “air refresher” or “air freshener”, as used herein, refer to any suitable composition that reduces odors in air, and/or reduces the impression of odors in the air by masking, layering or including malodor counteractant perfume raw materials into the composition.

EXAMPLE 2.1-2.3

Energized Air Refresher

An energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.


Example	Example	Example
2.1	2.2	2.3

Perfume composition	40-60	50-60	30-50
Malodor reducing composition	10-20	15-30	10-25
Functional Perfume Component	30-50	10-30	25-60

Use of Functional Perfume Components at the recited levels may help modulate the evaporation profile of an entire perfume composition to provide perfume character consistency over the intended usage period.

Suitable FPCs may be highly volatile, low boiling, perfume ingredients. Non-limiting, suitable FPCs include iso-nonyl acetate, dihydro myrcenol (3-methylene-7-methyloctan-7-ol), linalool (3-hydroxy-3,7-dimethyl-1,6 octadiene), geraniol (3,7 dimethyl-2,6-octadien-1-ol), d-limonene, 1-methyl-4-isopropenyl-1-cyclohexene, benzyl acetate, isopropyl mystristate, and combinations thereof.

Functional Perfume Component Examples 2.1-2.3


Example A1	Example A2	Example A3

Benzyl alcohol	10-50	0-50	0-20
Iso nonyl acetate	1-20	1-10	1-10
Dipropylene glycol methyl	40-70	5-65	2-50
ether

An energized air freshening device is filled with the composition above. The resulting air freshener is effective at reducing malodor.

EXAMPLES 3.1-3.3

Non-Energized Air Freshener

A non-energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.


	Example	Example	Example
	3.1	3.2	3.3

Perfume composition	20-30	20-50	10-30
Malodor reducing composition	10-20	10-20	20-50
Functional Perfume components	0-70	40-70	20-70

	Example	Example	Example
Functional Perfume components	1	2	3

3a,4,5,6,7,7a-hexahydro-1H-4,7-	15-25	20-25	0-20
methanoinden-1-yl propanoate
Iso nonyl acetate	30-75	15-75	1-10
2-isobutyl-4-hydroxy-4-	20-30	5-65	2-50
methyltetrahydropyran

A non-energized air freshener is filled with the example composition above. The resulting air freshener is effective at reducing malodor.

EXAMPLES 4.1-4.2

Fabric and Air Refresher Composition

A fabric refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.


			Example
	Example	Example	4.3
Ingredient	4.1	4.2	(ranges)

Deionized Water	Balance	Balance	Balance
Ethanol	3.0	3.0	1-5.0%
Lupasol HF+	0.0650	0.0650	0-0.1%
Diethylene Glycol	0.175	0.175	0-0.2%
Silwet L-7600	0.1	0.100	0-0.2
Maleic Acid and/or Citric	0.05	0.05	0-0.2
Acid
Koralone B-119	0.015	0.015	0-0.1
Hydroxypropyl β-cyclodextrin	0.630	0.630	0-2.0%
Sodium Hydroxide	0.003	0.003	0.001-0.01
Fragrance	0	0.4%	0-1.0%
Malodor Reduction Composi-	0.03%	0.04%	0-0.1%
tion (MRC A, B, or C)
Total	100.000	100.000	100.000

Lupasol HF Polyethyleneimine (available from BASF)
Silwet L-7600 Organosilicone (available from BASF)
Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical)

The resulting Fabric fresher composition is effective at reducing or preventing malodor when sprayed on fabrics, such as articles of clothing or upholstery.

EXAMPLE 5.1-5.2

Aerosol Air Freshener Composition

An aerosol air freshener composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.


Ingredient	Example 5.1	Example 5.2

Water Purified USP	Balance	92.370
Ethyl Alcohol	5.000	5.000
Acid Polyacrylic	0.185	—
Sodium Citrate, Dihydrate	—	0.100
Acid Citric Solution 50%	—	0.100
Sodium Dicoctyl	0-0.200	—
Sulfosuccinate
Silwet L-7600	0-0.2	0.200
Hydrogenated Castor Oil	1.400	1.400
PEG 60
Fragrance	0-1.5%	0-1.5%
Malodor Reduction	1.0	0-1.50%
Composition (MRC A, B, or
C)
Hydroxypropyl	0.380	0.380
BetaCyclodextrine
Koralone B-119	0.050	0.050
Sodium Hydroxide 20%	0-0.3	—
Total	100	100

Silwet L-7600 Organosilicone (available from BASF)
Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical)

A resulting aerosol air freshener is effective at reducing malodor in the air when sprayed. In addition the aerosol can be sprayed on fabrics to reduce or prevent malodor.

EXAMPLES 6.1-6.4

Heavy Duty Liquid Composition

A HDL-Heavy Duty Liquid composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.


	Example	Example	Example	Example
	6.1	6.2	6.3	6.4
	WT %	WT %	WT %	WT %
Ingredient	Active	Active	Active	Active

AE_1.8S	16.3	16.3	12	8
C_11.8linear alkyl benzene	2.8	2.8	8	—
sulfonic acid
HSAS	13.6	13.6	0	22
C24 alcohol, EO9	2.2	2.2	1	1.8
Citric Acid	0.9	0.9	2	1.7
Lactic Acid	—	5.8	—	—
C₁₂-C₁₈Fatty Acid	2.3	1.3	0.8	3.0
Protease (55.3 mg/g)	1.7	1.7	1.7	1.7
Amylase (25.4 mg/g)	0.7	0.7	0.7	0.7
Borax	3.6	3.6	3.6	3.6
Calcium Formate	0.2	0.2	0.2	0.2
Polyethyleneimine 600,	1.6	1.6	—	1.6
EO20
Polyethyleneimine 600,	1.6	—	2.0	1.6
EO24, PO16
DTPA	0.3	0.3	0.3	0.3
Tiron ®	0.8	0.8	0.8	0.8
Optical Brightener [7]	0.3	0.3	0.3	0.3
NaOH	4.0	9.3	4.0	9.3
Na Cumene Sulfonate	1.1	1.1	1.1	1.1
Na Formate	0.2	0.2	0.2	0.2
Aesthetics Dye	0.03-1.0	0.03-1.0	0.03-1.0	0.03-1.0
Perfume	0.5-3.0	0.5-3.0	0.5-3.0	0.5-3.0
Malodor Reducing	0.15-1.0	0.15-1.0	0.15-1.0	0.15-1.0
Composition
Water and Solvent	Balance	Balance	Balance	Balance
pH	5.0	8.0	5.0	8.0

HSAS secondary alkyl sulfate, acid form
DTPA diethylene triamine pentaacetic acid (DTPA)
Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate

The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.

EXAMPLES 7.1-7.3

Heavy Duty Liquid Composition

Other examples of HDL—Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.


	Example	Example	Example
	7.1	7.2	7.33
	WT %	WT %	WT %
Ingredient	Active	Active	Active

AE_1.8S	14%	8%	11%
Amine Oxide	2%	—	—
C_11.8linear alkyl benzene sulfonic	10%	—	—
acid
HSAS	—	20%	15
HF LAS	—	—	—
C24 alcohol, EO9	1%	2%	1.2%
Citric Acid	3%	1.5%	0.9%
C₁₂-C₁₈Fatty Acid	2%	1%	1.5%
Protease (55.3 mg/g)	0.013	0.8	0.013
Amylase (25.4 mg/g)	0.02	0.7	0.02
Borax	2-8.0	2-8.0	2-8.0
Calcium Formate	0.2	0.2	0.2
Carezyme 5.0L	0.01-0.5	—	0.01-0.5
Polyethyleneimine 600, EO20	0.5-3.0	0.5-3.0	0.5-3.0
Polyethyleneimine 600, EO24,	0.5-3.0	—	0.5-3.0
PO16
DTPA	0.1-1.0	0.1-1.0	0.1-1.0
Tiron ®	0.1-1.5	0.1-1.5	0.1-1.5
Optical Brightener	0.1-1.0	0.1-1.0	0.1-1.0
MEA- Hydrogenated Castor Oil	0.5-3.0	—
NaOH	0.1-1.0	0.1-1.0
Na Cumene Sulfonate	1.1	—
Na Formate	0.2	0.2
Dye	0.1	0.1
Malodor Reducing Composition	0.15-1.0	0.15-1.0	0.15-1.0
Perfume	0.9	0.5-3
Water and Solvent	Balance	Balance	Balance

HSAS secondary alkyl sulfate, acid form
DTPA diethylene triamine pentaacetic acid (DTPA)
Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate

EXAMPLES 8.1-8.6

Soluble Uni-Dose Heavy Duty Liquid Composition

An example for a Soluble Uni-dose heavy duty liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.


					3 compartments
					pouched product
8.1	8.2	8.3	8.4	8.5	8.6

Form	liquid	liquid	liquid	liquid	gel	liq	liq	liq
Compartment #	1	1	1	1	1	1	2	3
Dosage (g)	36.0	38.0	32.0	36.0	40.0	34.0	25	35
Alkylbenzene	14.5	13.8	16.0	14.5	13.5	14.5	20.0
sulfonic acid
C_12-14alkyl	8.5	16.4	10.0	8.5	15.0	8.5
ethoxy 3 sulfate
C_12-13alkyl 3-				13.0
ethoxylate
C_12-14alkyl 7-	12.5	9.0	14.0		4.0	12.5	17.0
ethoxylate
C12-18 Fatty	14.5	8.5	16.0	15.0	7.2	14.5	13.0
acid
Citric acid				2.0	4.1
Enzymes	0-3	0-3	0-3		0-3	0-3	0-3
PAP granule¹								50.0
Ethoxysulfated		3.0					2.2
Hexamethylene
Diamine
Dimethyl Quat
Ethoxylated	4.0	1.0		4.0	3.0	2.0
Polyethylenimine
Hydroxyethane	1.0	1.0			1.6	0.6	0.6
diphosphonic
acid
Ethylene				1.0
diamine
tetra(methylene
phosphonic)
acid
Brightener	0.2	0.2	0.3	0.3	0.2	0.2	0.2
Polydimethyl			3.0
Siloxane
Hueing dye²							0.05
Perfume	1.5-2.0	1.5-2.0	1.5-2.0	1.5-2.0	1.5-2.0	1.5-2.0
Malodor	0.3-0.7	0.3-0.7	0.3-0.7	0.3-0.7	0.3-0.7	0.3-0.7
reducing
composition

Water and	To 100%
minors
Buffers (sodium	To pH 8.0
carbonate,
monoethanolamine)
Solvents (1,2	To 100%
propanediol,
ethanol), Sulfate

¹PAP granule
²Hueing dye

The resulting Unidose pouch product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.

EXAMPLES 9.1-9.5

Fabric Enhancer Solid Particle or Bead Composition

An example of a Fabric Enhancer bead composition prepared with malodor reduction composition, according to the compositions shown in Example 1.


	Example	Example	Example	Example	Example
	9.1	9.2	9.3	9.4	9.5
	Active	Active	Active	Active	Active
Ingredients	Wt %	Wt %	Wt %	Wt %	Wt %

PEG 8000	86.21	83.255	83.255	86.21	82.49
Free (Neat)	4.41	5.88	4.41	4.25	5.88
Perfume
Malodor	0.75-1.5	0.75-1.5	0.75-1.5	0.75-1.5	0.75-1.5
reducing
composition
Perfume	5.88	8.22	8.88	5.88	8.70
Micro Cap-
sule (PMC)
Encapsulated	1.88	1.88	1.88	1.88	1.88
Perfume
Malodor	1.47	—	1.47	1.63	—
Reducing
Composition
Encapsulated	—	0.75	0.75	—	0.9
Malodor
Reducing
Composition
Aesthetics	0.015	0.015	0.015	0.015	0.015
Dye

1. PMC is a friable PMC with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.
2. Encapsulated perfume (within PMC) assumes about 32% active

The resulting Fabric enhancing bead product when added to an automatic washing machine is effective at reducing malodor on the clothing.

EXAMPLES 10.1-10.4

Dryer Added Fabric Softener Sheet Composition

An example of a dryer added fabric softener sheet composition prepared with malodor reduction composition, according to the compositions shown in Example 1.


	Example	Example	Example	Example
	10.1	10.2	10.3	10.4
	Wt %	Wt %	Wt %	Wt %
Ingredient	Active	Active	Active	Active

DEQA¹	—	50	—	—
DEQA²	30	—	—	30
DTDMAMS³	—	—	50	—
7018FA⁴	—	—	50	—
TS-20⁵	15	—	—	15
SMS⁶	15	—	—	15
SDASA⁷	19	25	—	19
TPED⁸	—	3	—	—
Complex⁹	16.5	16.5	—	8.0
Clay¹⁰	3	4	—	3
Free (Neat) Perfume	1.5	1.5	—	1.5
Free (Neat) malodor	0.5	0.5	0.5	—
reducing compostion
Encapsulated Perfume/	—	—	—	1.56
malodor reducing
composition ¹¹
Encapsulated Perfume¹²	—	0.4	—	—
Encap malodor reducing	—	—	—	0.5
composition
Active Weight (g/sheet)	2.4	2.4	1.9	2.4

¹DEQA¹: Di(soft tallowoyloxyethyl)dimethylammonium methyl sulfate with 25%> 7018 FA, as described below, as solvent
²DEQA²: Di(soft tallowoyloxyethyl)hydroxyethylmethylammoniun methyl sulfate with 18% partially hydrogenated tallow fatty acid solvent
³DTDMAMS: Di(hydrogenated tallowalkyl)dimethylammonium methyl sulfate
⁴7018FA: 70:30 Stearic Acid:Palmitic Acid (IV = 0) Industrene 7018 sold by Witco
⁵TS-20: Polyoxyethylene-20 Sorbitan Tristearate (Glycosperse TS-20, sold by Lonza
⁶SMS: Sorbitan Mono Stearate
⁷SDASA: 1:2 ratio of stearyl dimethyl amine:triple pressed stearic acid
⁸TPED: N,N,N′,N′-Tetrakis(2-hydroxypropyl)ethylenediamine (Quadrol, sold by BASF)
⁹Complex: Beta-Cyclodextrin/Perfume Complex
¹⁰Clay: Calcium Bentonite Clay (Bentonite L sold by Southern Clay Products Free (Neat) Perfume
¹¹PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/or blocker) is assumed.
¹²Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active

The compositions of Example 10 are mixed homogeneously and impregnated onto a non-woven polyester sheet having dimensions of about 6% in×12″ (about 17.1 cm×30.5 cm) and weighing about 1 gram.
The resulting dryer added fabric softener sheet product when added to an automatic dryer is effective at reducing malodor on the clothing.

EXAMPLES 11.1-11.4

Liquid Fabric Enhancer Composition

An example of a Liquid Fabric Enhancer composition prepared with malodor reduction composition, according to the compositions shown in Example 1.


	Example	Example	Example	Example
	11.1	11.2	11.3	11.4
	Wt %	Wt %	Wt %	Wt %
Ingredient	Active	Active	Active	Active

FSA¹	12	21	18	14
Low MW alcohol	1.95	3.0	3.0	2.28
Structurant^2,3	1.25^e	—	0.2^f	—
Free (Neat) Perfume	1.50	1.8	2.0	1.50
Free (Neat) malodor	0.3	0.7	—	—
reducing composition
Encapsulated Perfume⁴	—	0.6	—	0.6
Encap malodor reducing	—	—	0.6	0.6
composition⁴
Perfume/malodor	—	1.85	1.85	3.7
reducing composition
encapsulated⁵
Calcium Chloride	0.10	0.12	0.1	0.45
DTPA⁶	0.005	0.005	0.005	0.005
Preservative (ppm)⁷	5	5	5	5
Antifoam⁸	0.015	0.15	0.11	0.011
Polyethylene imines⁹	0.15	0.05	—	0.1
Delivery enhancing	0.1	0.1	0.2	0.05
PDMS emulsion¹⁰	—	0.5	1	2.0
Dispersant¹¹	—	—	0.5	0.2
Organosiloxane	5	—	—	—
Front-end Stability	0.06¹¹	0.63¹²	0.36¹¹	0.14¹²
Aid^12,13
Dye (parts per million	40	11	30	40
ppm)
Ammonium Chloride				0.10
Hydrochloric Acid	0.010	0.01	0.10	0.010
Deionized Water	Balance	Balance	Balance	Balance

¹N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.
²Cationic high amylose maize starch-available from National Starch under the trade name HYLON VII ®.
³Cationic polymer available from BASF ® under the name Rheovis ® CDE.
⁴Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active
⁵PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/or malodor reducing composition) is assumed.
⁶Diethylene triamine pentaacetic acid
⁷19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water available from Dow Chemical under the trade name Koralone B-119
⁸Silicone antifoam agent available from Dow Corning ® under the trade name DC2310.
⁹Polyethylene imines available from BASF under the trade name Lupasol ®.
¹⁰Polydimethylsiloxane emulsion from Dow Corning ® under the trade name DC346.
¹¹Non-ionic such as TWEEN 20 ™ or cationic surfactant as Berol 648 and Ethoquad ® C 25 from Akzo Nobel.
¹²Organosiloxane polymer condensate made by reacting hexamethylenediisocyanate (HDI), and a, w silicone diol and 1,3-propanediamine, N′-(3-(dimethylamino)propyl)-N,N-dimethyl- Jeffcat Z130) or N-(3-dimethylaminopropyl)-N,Ndiisopropanolamine (Jeffcat
ZR50) commercially available from Wacker Silicones, Munich, Germany.
¹³Fineoxocol ® 180 from Nissan Chemical Co.
¹⁴Isofol ® 16 from Sasol.
**For example PGE

Examples 11.1 to 11.4 are made by combining the molten fabric softener active with the front-end stability agent to form a first mixture. This first mixture is combined with water and hydrochloric acid using a high shear mixing device to form a second mixture. The adjunct ingredients are combined with the second mixture using low shear mixing to form the fabric enhancing formula.
Examples 11.1 through 11.4 are used by dosing 10 to 60 g of the formula into the rinse liquor for example via dispensing into a clothes washing machine. Clothes are dried on a line or in an automated clothes dryer. The fabrics treated with these formulas have improved feel and scent and are effective at reducing malodor on the clothing.

EXAMPLE 12.1-12.2

Spray-Dried Laundry Detergent Powder Composition and Process of Making It

An example of a Spray-Dried Laundry Detergent Powder composition prepared with malodor reduction composition, according to the compositions shown in Example 1.


		Dried		Dried
	Slurry	Powder	Slurry	Powder
	12.1	12.1	12.2	12.2
Compositions	w/w %	w/w %	w/w %	w/w %

Linear alkyl benzene sulfonate	10.6	15.8	21.3	35.7
Acrylate/maleate copolymer	4.6	6.8	9.4	14.2
Ethylenediame disuccinic acid	1.4	2.1	1.7	2.9
and/or Hydroxyethane dimethylene
phosphonic acid
Sodium carbonate	19.4	26.5	18.8	29.9
Sodium sulfate	28.6	42.4	—	—
Carboxy methyl cellulose polymer	—	—	4.3	7.1
Miscellaneous, such as magnesium	1.4	2.2	2.5	4.2
sulfate, brightener and one or more
stabilizers
Free (Neat) Perfume (spray-on)	—	1.7	—	2.4
Free (Neat) malodor reduction	—	0.5	—	0.6
composition (spray-on)
Water	34.0	2.0	42.0	3.0

Preparation of Spray-Dried Laundry Detergent Powders.

Aqueous slurry 12.1 having the composition as described above is prepared having a moisture content of 34.0%. Any ingredient added above in liquid form is heated to 70° C., such that the aqueous slurry is never at a temperature below 70° C. At the end of preparation, the aqueous slurry is heated to 80° C. and pumped under pressure (5×10⁶Nm⁻²), into a counter current spray-drying tower with an air inlet temperature of from 290° C. The aqueous slurry is atomized and the atomized slurry is dried to produce a solid mixture, which is then cooled and sieved to remove oversize material (>1.8 mm) to form a spray-dried powder, which is free-flowing. Fine material (<0.15 mm) is elutriated with the exhaust the exhaust air in the spray-drying tower and collected in a post tower containment system. The spray-dried powder 12.1 has a moisture content of 2.0 wt %, a bulk density of 310 g/l and a particle size distribution such that greater than 90 wt % of the spray-dried powder has a particle size of from 150 to 710 micrometers. The composition of the spray-dried powder 12.1 is listed in the table above. Perfume and malodor reduction composition are sprayed onto the composition following the spray dry procedure.
Aqueous slurry 12.2 having the composition as described above is prepared having a moisture content of 42.0%. Any ingredient added above in liquid form is heated to 70° C., such that the aqueous slurry is never at a temperature below 70° C. At the end of preparation, the aqueous slurry is heated to 85° C. and pumped under pressure (from 6.5×10⁶Nm⁻²), into a counter current spray-drying tower with an air inlet temperature of from 275° C. The aqueous slurry is atomized and the atomized slurry is dried to produce a solid mixture, which is then cooled and sieved to remove oversize material (>1.8 mm) to form a spray-dried powder 12.2, which is free-flowing. Fine material (<0.15 mm) is elutriated with the exhaust the exhaust air in the spray-drying tower and collected in a post tower containment system. The spray-dried powder has a moisture content of 3.0 wt %, a bulk density of 250 g/l and a particle size distribution such that greater than 90 wt % of the spray-dried powder has a particle size of from 150 to 710 micrometers. The composition of the spray-dried powder is given in the table above. Perfume and malodor reduction composition are sprayed onto the composition after the spray dry process.

EXAMPLE 13

Plastic Film Example with Malodor Reducing Composition

A plastic film is treated with an Malodor Reduction Composition disclosed in the present specification. Said treatment is accomplished by spraying said Malodor Reduction Composition on the film. Said Malodor Reduction Composition is applied to at a level of 0.1% to 5% based on weight of the film. The Malodor Reduction Composition is found on the surface and may also be absorbed into the plastic film.

EXAMPLE 14

Diaper Example with Malodor Reducing Composition

A diaper article, is treated with a Malodor Reduction Composition disclosed in the present specification. The Malodor Reduction Composition is disposed on one or more areas such as:
- the garment-facing side;
- the body-facing side of the topsheet;
- the absorbent core;
- the body-facing side of the backsheet.
The Malodor Reduction Composition may also be disposed on the garment-facing side of the absorbent core and/or on other components such as the garment facing side of a nonwoven dusting layer or body-facing side of a secondary topsheet or acquisition layer. In some embodiments, a topsheet or an acquisition layer may comprise a tissue layer and/or a nonwoven layer, and the malodor reduction composition may be disposed on either the tissue layer or the nonwoven layer. As discussed below, the Malodor Reduction Composition may be in the absorbent article via incorporation into an adhesive. In some embodiments, the Malodor Reduction Composition may be incorporated into the absorbent article via a lotion that is applied to a substrate component of the article. In some embodiments, the malodor reduction composition may be incorporated into the absorbent article via an elastomeric film. In some embodiments, the malodor reduction composition may be in an article by having been incorporated into the making of an article component, including, but not limited to, a film, a nonwoven, AGM, elastics, and/or ink.

EXAMPLE 16.1-16.5

Deodorant Example with Malodor Reducing Composition

An example of Deodorant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.


Ingredient	16.1	16.2	16.3	16.4	16.5

Product Form	Solid	Solid	Solid	Solid	Aerosol
	Deodor-	Deodor-	Deodor-	Deodor-	Deodor-
	ant	ant	ant	ant	ant or
	Control				Body
					Spray
dipropylene glycol	48	48	20	30	20
propylene glycol	19.3	19.3	22	—	—
tripopylene glycol	—	—	25	—	—
Glycerine	—	—	—	10	—
PEG -8	—	—	—	20	—
Propylene Glycol 3	1.4	1.4	—	—	—
Myristyl Ether
ethanol	—	—	—	—	QS
Water	QS	QS	QS	QS	—
sodium stearate	5.4	5.4	5.5	5.5	—
tetra sodium EDTA	0.5	0.5	0.05	0.05	—
sodium hydroxide	—	—	0.04	0.04	—
triclosan	—	—	0.3	0.3	—
Neat Perfume	2.8	2.8	2	1.5	1.5
Malodor reducing	—	0.7	1.0	0.5	0.35
composition
Blue 1	0.0009	0.0009	—	—	—
Propellant (1,1	—	—	—	—	40
difluoroethane)

QS - Indicates that this material is used to bring the total to 100%.

EXAMPLES 17.1-17.3

Body Wash with Malodor Reducing Composition

An example of Body Wash compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.


17.1 Body	17.2Body	17.3Body
Wash	Wash	Wash

Sodium Laureth-3 Sulfate (as 28%	27.85%	27.85%	27.85%
active)
Water	Q.S.	Q.S.	Q.S.
Sodium Lauryl Sulfate (as 29%	10.34	10.34	10.34
active)
Cocamidopropyl Betaine B (30%	4.01	4.01	4.01
active)
Citric Acid	0.18	0.18	0.18
Sodium Benzoate	0.3	0.3	0.3
Disodium EDTA	0.12	0.12	0.12
Methylchloroisothiazolinone/	0.04	0.04	0.04
Methylisothiazolinone
Sodium Chloride	2.35	1.7	1.6
Neat Perfume	1.25	1	2
Malodor reducing composition	0.25	0.175	0.25

QS - indicates that this material is used to bring the total to 100%.

EXAMPLES 18.1-18.6

Antiperspirant Examples with Malodor Reducing Composition

An example of Antiperspirant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.


18.1	18.2	18.3	18.4	18.5	18.6
Invisible	Invisible	Invisible	Soft	Soft	Soft
Solid	Solid	Solid	Solid	Solid	Solid

Aluminum	24	24	24	26.5	26.5	26.5
Zirconium
Trichlorohydrex
Glycine Powder
Cyclopentasiloxane	Q.S	Q.S.	Q.S.	Q.S.	Q.S.	Q.S.
Dimethicone	—	—	—	5	5	5
CO-1897 Stearyl	14	14	14	—	—	—
Alcohol NF
Hydrogenated	3.85	3.85	3.85	—	—	—
Castor Oil MP80
Deodorized
Behenyl Alcohol	0.2	0.2	0.2	—	—	—
Tribehenin	—	—	—	4.5	4.5	4.5
C 18-36 acid	—	—	—	1.125	1.125	1.125
triglyceride
C12-15 Alkyl	9.5	9.5	5	—	—	—
Benzoate
PPG-14 Butyl	6.5	6.5	—	0.5	0.5	0.5
Ether
Phenyl	3	—	3	—	—	—
Trimethicone
White Petrolatum	3	—	—	3	3	3
Mineral Oil	1.0	1.0	1.0	—	—	—
Free (Neat)	1.0	0.75	2.0	0.75	1.0	1.25
Perfume
Malodor reducing	0.25	—	0.35	0.175	0.25	0.1
composition
Beta-Cyclodextrin	—	3.0	—	—	—	3.0
complexed with
Malodor reducing
composition
Talc Imperial 250	3.0	3.0	3.0	—	—	—
USP
Polyacrylate	—	—	1.9	—	—	—
Microcapsule
loaded with
Malodor reducing
composition

QS - indicates that this material is used to bring the total to 100%.

EXAMPLE 19.1-19.4

Dish Cleansing Composition Examples with Malodor Reducing Composition

An example of Dish cleaning compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.


19.1	19.2	19.3	19.4

Alkyl C_10-14Ethoxy	26.9	—	—	25.7
Sulphate (AE0.6S)
Alkyl C_10-14Ethoxy	—	18.7	26.9	—
Sulphate (AE2S)
Sodium alkyl benzene	—	8.0	—	—
sulfonate
C12-14 dimethyl amine	6.1	—	—	4.1
oxide
Cocamido propyl betaine	—	4.5	6.8	3.2
Branched Nonionic:	1.0	0.8	—	—
3-propyl heptanol EO8
PEI600-EO10-PO7	—	—	0.8	—
block polymer
Perfume	0.15-0.3	0.15-0.3	0.15-0.3	0.15-0.3
Malodor Reducing	0.06-0.15	0.06-0.15	0.06-0.15	0.06-0.15
Composition
Ethanol	4.0	5.0	3.0	3.0
Polypropylene glycol	1.1	0.8	1.1	1.1
MW2000
Sodium Chloride	1.3	0.8	1.3	0.5

Minors* and water	to balance up to 100%

EXAMPLES 20.1-20.4

Heavy Duty Liquid Composition


	Example	Example	Example	Example
	20.1	20.2	20.3	20.4
	WT %	WT %	WT %	WT %
Ingredient	Active	Active	Active	Active

AE_1.8S	16	16	12	8
C_11.8linear alkyl benzene	3	3	8	—
sulfonic acid
HSAS¹	14	14	0	22
C24 alcohol, EO9	2	2	1	2
Citric Acid	1	1	2	2
Lactic Acid	—	6	—	—
C₁₂-C₁₈Fatty Acid	2	1	1	3
Protease (55.3 mg/g)	2	2	2	2
Amylase (25.4 mg/g)	0.7	0.7	0.7	0.7
Borax	3.6	3.6	3.6	3.6
Calcium Formate	0.2	0.2	0.2	0.2
Polyethyleneimine 600,	1.6	1.6	—	1.6
EO20
Polyethyleneimine 600,	1.6	—	2.0	1.6
EO24, PO16
DTPA²	0.3	0.3	0.3	0.3
Tiron ®³	0.8	0.8	0.8	0.8
Optical Brightener	0.3	0.3	0.3	0.3
NaOH	4	9	4	9
Na Cumene Sulfonate	1	1	1	1
Na Formate	0.2	0.2	0.2	0.2
Aesthetics Dye	0.03-1	0.03-1	0.03-1	0.03-1
Perfume	0.5-3	0.5-3	0.5-3	0.5-3
Malodor Reducing	0.1-1	0.1-1	0.1-1	0.1-1
Composition
Water and Solvent	Balance	Balance	Balance	Balance
pH	5	8	5	8

EXAMPLES 21.1-21.3

Heavy Duty Liquid Composition

Other examples of HDL-Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.


	Example	Example	Example
	21.1	21.2	21.3
	WT %	WT %	WT %
Ingredient	Active	Active	Active

AE_1.8S	14	8	11
Amine Oxide	2	—	—
C_11.8linear alkyl benzene sulfonic	10%	—	—
acid
HSAS¹	—	20	15
C24 alcohol, EO9	1-2	1-2	1-2
Citric Acid	0.5-3	0.5-3	0.5-3
C₁₂-C₁₈Fatty Acid	1-2	1-2	1-2
Protease (55.3 mg/g)	0.013-0.8	0.013-0.8	0.013-0.8
Amylase (25.4 mg/g)	0.02-0.7	0.02-0.7	0.02-0.7
Borax	2-8	2-8	2-8
Calcium Formate	0.2	0.2	0.2
Carezyme 5.0L	0.01-0.5	—	0.01-0.5
Polyethyleneimine 600, EO20	0.5-3	0.5-3	0.5-3
Polyethyleneimine 600, EO24,	0.5-3	—	0.5-3
PO16
DTPA²	0.1-1	0.1-1	0.1-1
Tiron ® ³	0.1-2	0.1-2	0.1-2
Optical Brightener	0.1-1	0.1-1	0.1-1
MEA - Hydrogenated Castor Oil		0.5-3	0.5-3
NaOH	0.1-1	0.1-1	0.1-1
Na Cumene Sulfonate	1.1	—	—
Na Formate	0.2	0.2	0.2
Dye	0.1	0.1	0.1
Malodor Reducing Composition	0.15-1.0	—	0.15-1.0
Encapsulated Malodor Reducing⁴	—	0.3-3	—
Perfume	0.5-2	0.5-2	—
Encapsulated Perfume⁴	—	—	1.5-3
Water and Solvent	Balance	Balance	Balance

¹HSAS is secondary alkyl sulfate, acid form
²DTPA is diethylene triamine pentaacetic acid (DTPA)
³Tiron is 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate
⁴Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.

EXAMPLES 22.1-22.3

Fabric Enhancer Solid Particle or Bead Composition


	Example	Example	Example
	22.1	22.2	22.3
	Active	Active	Active
Ingredients	Wt %	Wt %	Wt %

PEG 8000	80-90	80-90	80-90
Free (Neat) Perfume	3.5-6	4-6	3-5
Malodor reducing composition	0.5-2	0.5-2	0.5-2
Encapsulated Perfume ¹	0-2	0-2	2-3
Encapsulated Malodor Reducing	—	0.5-2	—
Composition ¹
Dipropylene Glycol	0-6	0-5	0-4.5
Aesthetics Dye	0.015	0.015	0.015

- 3. Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.
The resulting Fabric enhancing bead product when added to an automatic washing machine is effective at reducing malodor on the clothing.

EXAMPLE: 23.1-23.6

Malodor Reduction Composition

The following malodor reduction malodor reduction compositions are made by combining the listed ingredients. All ingredients are in weight percent of the total malodor reduction composition.


Ingredient	CAS#	23.1	23.2	23.3	23.4	23.5	23.6

(3aR,5aS,9aS,9bR)-	6790-58-5	0.1	0.5	0	0	0.5	0.2
3a,6,6,9a-tetramethyl-
2,4,5,5a,7,8,9,9b-
octahydro-1H-
benzo[e][1]benzofuran
7-(3-methylbutyl)-1,5-	362467-67-2	1	0.5	0.07	0.6	0.01	0
benzodioxepin-3-one
triethyl 2-	77-93-0	0.05	0.2	1	0.5	0.09	0.03
hydroxypropane-1,2,3-
tricarboxylate
1,1,2,3,3-pentamethyl-	33704-61-9	1	1	0.5	0.5	0.2	0.2
2,5,6,7-tetrahydroinden-4-
one
(3R,3aS,6S,7R,8aS)-	19870-74-7	2	1	0	2	1	3
octahydro-6-methoxy-
3,6,8,8-tetramethyl-1H-
3a,7-methanoazulene
(5E)-3-	63314-79-4	0.3	0.2	0.43	0	0.15	0.17
methylcyclopentadec-5-
en-1-one
4-(octahydro-4,7-	30168-23-1	0.5	1	0.7	1	0.2	0.4
methano-5H-inden-5-
ylidene)butanal
3a,4,5,6,7,7a-hexahydro-	5413-60-5	3	1	0.5	0.5	1	0.8
4,7-methanoinden-6-yl
acetate
3a,4,5,6,7,7a-hexahydro-	68912-13-0	4	0.8	2	2	0.5	1
1H-4,7-methanoinden-1-yl
propanoate
5-(diethoxymethyl)-1,3-	40527-42-2	0.7	0.5	0	0	1	0
benzodioxole
1,3,4,6,7,8-hexahydro-	1222-05-5	5	8	3	8	10	5
4,6,6,7,8,8-
hexamethylcyclopenta(g)-
2-benzopyran
1-(2,3,8,8-tetramethyl-	54464-57-2	18	25	54	28	20	50
1,3,4,5,6,7-
hexahydronaphthalen-2-
yl)ethanone
2,2,7,7-	23787-90-8	0.6	0.5	0.5	3	1	0
tetramethyltricyclo[6.2.1.0
1,6]undecan-5-one
[(1R,2S)-1-methyl-2-	198404-98-7	0.05	0.5	0	0.18	0.05	0.1
[[(1R,3S,5S)-1,2,2-
trimethyl-3-
bicyclo[3.1.0]hexanyl]methyl]cyclopropyl]methanol
2,4-dimethyl-4,4a,5,9b-	27606-09-3	40	38	26	26	20	10
tetrahydroindeno[1,2-
d][1,3]dioxine
methyl 3-oxo-2-	24851-98-7	15	7	5	15	22	22
pentylcyclopentaneacetate
2-[2-(4-methyl-1-	95962-14-4	5	7	5	10	16	5
cyclohex-3-
enyl)propyl]cyclopentan-
1-one
2,2-	101-48-4	0.4	1	0.5	1	1	0
dimethoxyethylbenzene
(E)-3,3-dimethyl-5-(2,2,3-	107898-54-4	0.2	1	0	0.7	0.2	1
trimethyl-3-cyclopenten-
1-yl)-4-penten-2-ol
octahydro-5-methoxy-4,7-	86803-90-9	0.1	0.3	0.3	0.02	0.1	0.1
methano-1H-indene-2-
carboxaldehyde
1-oxacycloheptadecan-2-	109-29-5 &	3	5	0.5	1	5	1
one &	502-72-7
cyclopentadecanone
TOTAL		100	100	100	100	100	100

Each of the malodor reduction compositions of Examples 23.1 through 23.6 is used in a consumer product by combining the malodor reduction composition at a level of about 0.05% to about 0.35%, based on total consumer product weight, with the consumer product. Then the consumer product is applied to a site on the human body that is in need of malodor reduction. In one aspect, the consumer product is selected from a shampoo, body wash, conditioner and an antiperspirant/deodorant.

EXAMPLES 24.1-24.6

Malodor Reduction Composition


Ingredient	CAS #	24.1	24.2	24.3	24.4	24.5	24.6

(E)-1-(2,6,6-trimethyl-1-	127-42-4	4	8	2	8	3	2
cyclohex-2-enyl)pent-1-
en-3-one
ethyl dodecanoate	106-	0	1	0	3	0	0
	33-2
3a,4,5,6,7,7a-hexahydro-	68912-	8	30	1	4	1	3.5
1H-4,7-methanoinden-1-	13-0
yl propanoate
[1R-	1139-	0	0.3	2	.5	0	0.5
(1R,4R,6R,10S)]-	30-6
4,12,12-trimethyl-9-
methylene-5-
oxatricyclo[8.2.0.04,6]dodecane
(8E)-cyclohexadec-8-en-	3100-	0	5	0	7	0	0
1-one	36-5
3,5,5-trimethylhexyl	58430-	25	15	50	35	60	56
acetate	94-7
ethyl (2,3,6-	93981-	0	1	0	5	0	0
trimethylcyclohexyl)	50-1
carbonate
2,4-dimethyl-4,4a,5,9b-	27606-	25	10	15	15	16	15
tetrahydroindeno[1,2-	09-3
d][1,3]dioxine
2,2,7,7-	23787-	8	9	5	7	5	5
tetramethyltricyclo[6.2.1.01,	90-8
6]undecan-5-one
(3,5-dimethylcyclohex-3-	67634-	0	0.7	0	.5	0	0
en-1-yl)methanol	16-6
3-(7,7-dimethyl-4-	33885-	30	20	25	15	15	18
bicyclo[3.1.1]hept-3-	52-8
enyl)-2,2-
dimethylpropanal
Total		100	100	100	100	100	100

Each of the malodor reduction compositions of Examples 24.1 through 24.6 is used as a perfume component in an air care device at a level of form about 5% to about 100% or in other consumer products by combining the malodor reduction composition at a level of about 0.0003% to about 5% based on total consumer product weight, with the consumer product. Then the consumer product is applied to a site on the human body that is in need of malodor reduction, used in an air care device and/or as a treatment composition to treat a fabric and/or hard surface. In one aspect, the consumer product is selected from a shampoo, body wash, conditioner, an antiperspirant/deodorant and/or a fabric or hard surface cleaner or treatment composition such as a detergent or fabric enhancer.

The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims

What is claimed:

1. A malodor reduction composition comprising, based on total malodor reduction composition weight:

a) from about 2% to about 8% (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1-en-3-one;

b) from about 0% to about 3% ethyl dodecanoate;

c) from about 1% to about 30% 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-1-yl propanoate;

d) from about 0% to about 2% [1R-(1R*,4R*,6R*,10S*)]-4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.04,6]dodecane;

e) from about 0% to about 7% (8E)-cyclohexadec-8-en-1-one;

f) from about 15% to about 60% 3,5,5-trimethylhexyl acetate;

g) from about 0% to about 5% ethyl (2,3,6-trimethylcyclohexyl) carbonate;

h) from about 10% to about 25% 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine;

i) from about 5% to about 9% 2,2,7,7-tetramethyltricyclo[6.2.1.01,6]undecan-5-one;

j) from about 0% to about 0.7% (3,5-dimethylcyclohex-3-en-1-yl)methanol; and

k) from about 15% to about 30% 3-(7,7-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)-2,2-dimethylpropanal

with the proviso that the sum of the elements a) through k) does not exceed 100%.

2. A malodor reduction composition according to claim 1 comprising from about 0.3% to about 2% [1R-(1R*,4R*,6R*,10S*)]-4,12,12-trimethyl-9-methylene-5 oxatricyclo[8.2.0.04,6]dodecane.

3. A malodor reduction composition comprising, based on total composition weight, from 0.0001% to 100% of a malodor reduction composition according to claim 1 and an adjunct material, said composition being a consumer product.

4. A malodor reduction composition according to claim 3 wherein said adjunct material is selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments, fabric softener actives and mixtures thereof.

5. A malodor reduction composition comprising, based on total composition weight, from 0.0001% to 100% of a malodor reduction composition according to claim 2 and an adjunct material, said composition being a consumer product.

6. A malodor reduction composition according to claim 5 wherein said adjunct material is selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments, fabric softener actives and mixtures thereof.

7. A plastic film said plastic film comprising linear low-density polyethylene, low-density polyethylene, high-density polyethylene, and/or compostable film and a malodor reduction composition according to claim 1.

8. A plastic film said plastic film comprising linear low-density polyethylene, low-density polyethylene, high-density polyethylene, and/or compostable film and a malodor reduction composition according to claim 2.

9. A method of controlling malodors comprising contacting a material comprising a malodor with a malodor reduction composition according to claim 1.

10. A method of controlling malodors comprising contacting a material comprising a malodor with a malodor reduction composition according to claim 2.

11. A method of determining the material's ability to decrease or even eliminate the perception of one or more malodors comprising determining the MORV and/or Universal MORV of said material.