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US20160297008A1 - One-piece component and method for its production - Google Patents

One-piece component and method for its production Download PDF

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Publication number
US20160297008A1
US20160297008A1 US15/189,713 US201615189713A US2016297008A1 US 20160297008 A1 US20160297008 A1 US 20160297008A1 US 201615189713 A US201615189713 A US 201615189713A US 2016297008 A1 US2016297008 A1 US 2016297008A1
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United States
Prior art keywords
subregion
piece component
base material
injection
present
Prior art date
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Abandoned
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US15/189,713
Inventor
Tilla Haubold
Matthias Schumacher
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Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
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Filing date
Publication date
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Priority to US15/189,713 priority Critical patent/US20160297008A1/en
Publication of US20160297008A1 publication Critical patent/US20160297008A1/en
Abandoned legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/22—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/22—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
    • B22F3/225—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip by injection molding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/02—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00—Metallic composition of the powder or its coating
    • B22F2301/35—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2302/00—Metal Compound, non-Metallic compound or non-metal composition of the powder or its coating
    • B22F2302/10—Carbide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2302/00—Metal Compound, non-Metallic compound or non-metal composition of the powder or its coating
    • B22F2302/20—Nitride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2302/00—Metal Compound, non-Metallic compound or non-metal composition of the powder or its coating
    • B22F2302/25—Oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2302/00—Metal Compound, non-Metallic compound or non-metal composition of the powder or its coating
    • B22F2302/25—Oxide
    • B22F2302/253—Aluminum oxide (Al2O3)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/005—Ferrite

Definitions

  • the present invention relates to a one-piece component which has a first and a second subregion, and to a method for producing the one-piece component by means of a MIM (Metal Injection Molding) method.
  • MIM Metal Injection Molding
  • the one-piece component according to the present invention has the advantage that it may be produced in an especially simple as well as cost-effective manner within the shortest period of time.
  • this is achieved by producing the one-piece component with a first subregion made of a base material, and a second subregion made of the base material as binder, together with intercalated hard material particles, utilizing MIM technology.
  • the second subregion is injected onto the first subregion in order to produce an integral connection between the two subregions.
  • the first and second subregions are able to be produced by injection molding in an injection molding die.
  • the base material preferably is an austenitic or ferritic steel, especially steel including Fe and Cr.
  • the hard material particles preferably are oxides, especially Al 2 O 3 , ZrO 2 and/or Y 2 O 3 .
  • the hard material particles are carbides, in particular titanium carbide, wolfram carbide, niobium carbide or tantalum carbide.
  • the hard material particles are nitrides, especially titanium nitride. With regard to the mentioned hard material particles, it should be noted that they are able to be mixed exclusively with the base material so as to form the material for the second subregion, or they may be mixed in any desired combinations so as to form an injectable metal powder.
  • a volumetric component of the hard material particles in the material for the second subregion lies in a range of 5 vol. % to 20 vol. %, and especially preferably, amounts to 10 vol. %.
  • the one-piece component is a component of a motor vehicle, in particular, an internal combustion engine.
  • the one-piece component is a piston, a cylinder or a valve member, especially a valve seat, a valve stop or a needle stop.
  • the one-piece component is a part of gasoline injectors or fuel pumps.
  • the present invention relates to a method for producing a one-piece component by means of 2-component MIM technology.
  • the method according to the present invention includes the steps of injection-molding a first subregion of the one-piece component using a base material, and injection-molding a second subregion onto the first subregion, the base material being used as binder and including intercalated hard material particles as material for the second subregion.
  • the one-piece component according to the present invention preferably is used in applications in which the one-piece component is moving or used as a stop.
  • the use in piston pumps, splitter valves, injectors, and other mechanical valves may be possible.
  • Another preferred possibility is the use in fuel-carrying components, especially fuels having poor lubrication properties, e.g., components for gasoline engines.
  • the use as injection valve, metering valve, quantity-control valve or fuel pumps, in particular, is conceivable.
  • FIG. 1 a schematic sectional view of a one-piece component according to a first exemplary embodiment of the present invention.
  • FIG. 2 a schematic sectional view of a one-piece component according to a second exemplary embodiment of the present invention.
  • FIG. 3 a schematic sectional view of a one-piece component according to a third exemplary embodiment of the present invention.
  • FIG. 4 a schematic sectional view of a one-piece component according to a fourth exemplary embodiment of the present invention.
  • FIG. 5 a schematic sectional view of a one-piece component according to a fifth exemplary embodiment of the present invention.
  • FIG. 6 a schematic sectional view of a one-piece component according to a sixth exemplary embodiment of the present invention.
  • One-piece component 1 encompasses a first subregion 2 made of a base material, and a second subregion 3 made of a material that includes the base material as binder as well as intercalated hard material particles. An integral connection between first subregion 2 and second subregion 3 is formed in the process.
  • One-piece component 1 is produced by means of 2-component MIM injection-molding, in which first subregion 2 is produced first, in a first step, and second subregion 3 is injection-molded onto first subregion 2 in a second step.
  • MIM technology allows metal powders to be injection-molded, for which purpose an austenitic or ferritic steel is preferably used as base material, and for which the relatively cost-effective base material may be used as binder with additional intercalated hard material particles for the material of second subregion 3 .
  • the one-piece component shown in FIG. 1 is a piston for a piston machine and includes the wear-resistant layer on an outer surface of the piston. Since second subregion 3 forms the outer layer, high robustness with regard to frictional wear is obtained, and thus a long service life. In addition, reduced friction also leads to lower heat generation with its attendant advantages.
  • FIG. 2 shows a cylinder where second subregion 3 forms the bearing surface of the cylinder.
  • FIGS. 3 through 5 show alternative exemplary embodiments of the present invention, which may be used as injectors or switching valves.
  • Second subregion 3 forms a valve seat in each case: for a ball valve in FIG. 3 , for a cone valve in FIG. 4 , and for a flat-seat valve in FIG. 5 .
  • the valve seat implemented as one-piece component having first and second subregions 2 , 3 , but valve-closure member 6 as well, which has a first subregion 7 and a second subregion 8 as valve-closure surface.
  • the double arrows in FIGS. 3 through 5 indicate the movement direction of the valve members.
  • flat-seat valve as slide valve.
  • FIG. 6 shows a further exemplary embodiment of the present invention in a one-piece stop 10 , which features a first subregion 11 and a second, harder subregion 12 .
  • Stop 10 delimits a movement of valve member 13 in the direction of arrow A. Via second subregion 12 , stop 10 strikes a counter stop 14 , which likewise may possibly be made up of a first and second subregion according to the present invention.
  • the present invention makes it possible to provide a one-piece component, which is able to be produced in cost-effective manner using a 2-component MIM injection-molding method.
  • austenitic or ferritic steel based on iron and chromium with a weight proportion of 13% chromium is preferably used as base material for all exemplary embodiments described.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Powder Metallurgy (AREA)
  • Fuel-Injection Apparatus (AREA)

Abstract

A one-piece component includes a first subregion made of a base material, and a second subregion made of the base material as binder with intercalated hard material particles, the second subregion being injection-molded onto the first subregion by means of MIM injection molding, so that an integral connection is formed between the first subregion and the second subregion. Furthermore, a method for producing the one-piece component by means of MIM injection molding is described.

Description

    CROSS-REFERENCE TO RELATED APPLICATION
  • The present application is a divisional application of U.S. patent application Ser. No. 13/760,181, filed on Feb. 6, 2013, which claims priority to and the benefit of German Patent Application No. 10 2012 201 880.8, filed on Feb. 9, 2012, the disclosures of which are incorporated herein by reference.
    • FIELD OF INVENTION
  • The present invention relates to a one-piece component which has a first and a second subregion, and to a method for producing the one-piece component by means of a MIM (Metal Injection Molding) method.
    • BACKGROUND INFORMATION
  • Many components which are moving or which serve as stops are subjected to wear. Therefore there is a need to provide components that have the most advantageous wear characteristics possible. In addition, greater wear occurs if sufficient lubrication in the case of moved components, or sufficient damping in the case of stops is impossible. One pertinent example are devices for injecting fuel, in particular gasoline, since gasoline exhibits very poor lubricating properties. To provide the highest possible service life for gasoline injectors, for example, highly wear-resistant materials are used as a rule, which have the particular disadvantage of being very costly. As an alternative, it is also possible to use supplementary components, such as wear-resistant bushings or the like; however, this increases the number of parts as well as the production and installation costs. In this regard, cost-effective alternatives would thus be desirable, which could solve the wear problems without additional individual components and/or additional working steps.
    • SUMMARY
  • By contrast, the one-piece component according to the present invention has the advantage that it may be produced in an especially simple as well as cost-effective manner within the shortest period of time. According to the present invention, this is achieved by producing the one-piece component with a first subregion made of a base material, and a second subregion made of the base material as binder, together with intercalated hard material particles, utilizing MIM technology. In the process, the second subregion is injected onto the first subregion in order to produce an integral connection between the two subregions. As a result, the first and second subregions are able to be produced by injection molding in an injection molding die.
  • The base material preferably is an austenitic or ferritic steel, especially steel including Fe and Cr. The hard material particles preferably are oxides, especially Al2O3, ZrO2 and/or Y2O3. As an alternative, the hard material particles are carbides, in particular titanium carbide, wolfram carbide, niobium carbide or tantalum carbide. As a further alternative, the hard material particles are nitrides, especially titanium nitride. With regard to the mentioned hard material particles, it should be noted that they are able to be mixed exclusively with the base material so as to form the material for the second subregion, or they may be mixed in any desired combinations so as to form an injectable metal powder.
  • Preferably, a volumetric component of the hard material particles in the material for the second subregion lies in a range of 5 vol. % to 20 vol. %, and especially preferably, amounts to 10 vol. %.
  • Preferably, the one-piece component is a component of a motor vehicle, in particular, an internal combustion engine. Especially preferably, the one-piece component is a piston, a cylinder or a valve member, especially a valve seat, a valve stop or a needle stop. Preferably, the one-piece component is a part of gasoline injectors or fuel pumps.
  • In addition, the present invention relates to a method for producing a one-piece component by means of 2-component MIM technology. The method according to the present invention includes the steps of injection-molding a first subregion of the one-piece component using a base material, and injection-molding a second subregion onto the first subregion, the base material being used as binder and including intercalated hard material particles as material for the second subregion. This makes it possible for the MIM injection-molding technology to produce a one-piece component featuring an integral connection between the first and second subregions of the component.
  • The one-piece component according to the present invention preferably is used in applications in which the one-piece component is moving or used as a stop. For example, the use in piston pumps, splitter valves, injectors, and other mechanical valves may be possible. Another preferred possibility is the use in fuel-carrying components, especially fuels having poor lubrication properties, e.g., components for gasoline engines. In this case the use as injection valve, metering valve, quantity-control valve or fuel pumps, in particular, is conceivable.
  • Exemplary embodiments of the present invention are described in detail below, with reference to the accompanying drawings.
    • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 a schematic sectional view of a one-piece component according to a first exemplary embodiment of the present invention.
  • FIG. 2 a schematic sectional view of a one-piece component according to a second exemplary embodiment of the present invention.
  • FIG. 3 a schematic sectional view of a one-piece component according to a third exemplary embodiment of the present invention.
  • FIG. 4 a schematic sectional view of a one-piece component according to a fourth exemplary embodiment of the present invention.
  • FIG. 5 a schematic sectional view of a one-piece component according to a fifth exemplary embodiment of the present invention.
  • FIG. 6 a schematic sectional view of a one-piece component according to a sixth exemplary embodiment of the present invention.
    •  DETAILED DESCRIPTION
  • In the following text, a one-piece component 1 according to a first exemplary embodiment of the present invention is described in detail with reference to FIG. 1.
  • One-piece component 1 encompasses a first subregion 2 made of a base material, and a second subregion 3 made of a material that includes the base material as binder as well as intercalated hard material particles. An integral connection between first subregion 2 and second subregion 3 is formed in the process. One-piece component 1 is produced by means of 2-component MIM injection-molding, in which first subregion 2 is produced first, in a first step, and second subregion 3 is injection-molded onto first subregion 2 in a second step.
  • The use of MIM technology allows metal powders to be injection-molded, for which purpose an austenitic or ferritic steel is preferably used as base material, and for which the relatively cost-effective base material may be used as binder with additional intercalated hard material particles for the material of second subregion 3. This makes it possible to use a cost-effective binder for the hard material particles, which, for instance, are suitable oxides, carbides or nitrides.
  • The one-piece component shown in FIG. 1 is a piston for a piston machine and includes the wear-resistant layer on an outer surface of the piston. Since second subregion 3 forms the outer layer, high robustness with regard to frictional wear is obtained, and thus a long service life. In addition, reduced friction also leads to lower heat generation with its attendant advantages.
  • As an alternative, exemplary one-piece component of the present invention, FIG. 2 shows a cylinder where second subregion 3 forms the bearing surface of the cylinder.
  • FIGS. 3 through 5 show alternative exemplary embodiments of the present invention, which may be used as injectors or switching valves. Second subregion 3 forms a valve seat in each case: for a ball valve in FIG. 3, for a cone valve in FIG. 4, and for a flat-seat valve in FIG. 5. In the exemplary embodiment shown in FIG. 5, not only is the valve seat implemented as one-piece component having first and second subregions 2, 3, but valve-closure member 6 as well, which has a first subregion 7 and a second subregion 8 as valve-closure surface. The double arrows in FIGS. 3 through 5 indicate the movement direction of the valve members. However, it would also be conceivable, for example, to implement flat-seat valve as slide valve.
  • FIG. 6 shows a further exemplary embodiment of the present invention in a one-piece stop 10, which features a first subregion 11 and a second, harder subregion 12. Stop 10 delimits a movement of valve member 13 in the direction of arrow A. Via second subregion 12, stop 10 strikes a counter stop 14, which likewise may possibly be made up of a first and second subregion according to the present invention.
  • As a result, the present invention makes it possible to provide a one-piece component, which is able to be produced in cost-effective manner using a 2-component MIM injection-molding method. For gasoline applications, austenitic or ferritic steel based on iron and chromium with a weight proportion of 13% chromium is preferably used as base material for all exemplary embodiments described.

Claims (4)

What is claimed is:
1. A method for producing a one-piece component by means of MIM injection molding, comprising:
injection-molding a first subregion made of a base material, and
injection-molding a second subregion made of the base material as binder and including intercalated hard material particles, onto the first subregion, such that an integral connection is formed between the first and second subregions.
2. The method according to claim 2, wherein the base material is an austenitic or ferritic steel, which includes iron and chromium.
3. The method according to claim 2, wherein the hard material particles are oxides, including Al2O3, ZrO2 or Y2O3.
4. The method according to claim 2, wherein the hard material particles are one of a) carbides, including titanium carbide, wolfram carbide, niobium carbide or tantalum carbide, or b) nitrides, including titanium nitride.
US15/189,713 2012-02-09 2016-06-22 One-piece component and method for its production Abandoned US20160297008A1 (en)

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DE102012201880A DE102012201880A1 (en) 2012-02-09 2012-02-09 One-piece component and method for its production
US13/760,181 US9409234B2 (en) 2012-02-09 2013-02-06 One-piece component and method for its production
US15/189,713 US20160297008A1 (en) 2012-02-09 2016-06-22 One-piece component and method for its production

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CN106015727A (en) * 2016-07-07 2016-10-12 无锡戴尔普机电设备有限公司 Novel air volume adjustment valve end plate material
US9966425B1 (en) 2017-02-28 2018-05-08 United Microelectronics Corp. Method for fabricating a MIM capacitor

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US20130209815A1 (en) 2013-08-15
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US9409234B2 (en) 2016-08-09
DE102012201880A1 (en) 2013-08-14
EP2626157A3 (en) 2017-09-06

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