US20150311355A1 - Thermally-insulated micro-fabricated atomic clock structure and method of forming the atomic clock structure - Google Patents
Thermally-insulated micro-fabricated atomic clock structure and method of forming the atomic clock structure Download PDFInfo
- Publication number
- US20150311355A1 US20150311355A1 US14/703,364 US201514703364A US2015311355A1 US 20150311355 A1 US20150311355 A1 US 20150311355A1 US 201514703364 A US201514703364 A US 201514703364A US 2015311355 A1 US2015311355 A1 US 2015311355A1
- Authority
- US
- United States
- Prior art keywords
- metal
- wafer
- traces
- thermal
- trace
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/60—Arrangements for cooling, heating, ventilating or compensating for temperature fluctuations
-
- H01L31/024—
-
- G—PHYSICS
- G04—HOROLOGY
- G04F—TIME-INTERVAL MEASURING
- G04F5/00—Apparatus for producing preselected time intervals for use as timing standards
- G04F5/14—Apparatus for producing preselected time intervals for use as timing standards using atomic clocks
-
- H01L31/022408—
-
- H01L31/18—
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03L—AUTOMATIC CONTROL, STARTING, SYNCHRONISATION OR STABILISATION OF GENERATORS OF ELECTRONIC OSCILLATIONS OR PULSES
- H03L7/00—Automatic control of frequency or phase; Synchronisation
- H03L7/26—Automatic control of frequency or phase; Synchronisation using energy levels of molecules, atoms, or subatomic particles as a frequency reference
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F30/00—Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors
- H10F30/20—Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors
- H10F30/21—Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation
- H10F30/22—Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation the devices having only one potential barrier, e.g. photodiodes
- H10F30/221—Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation the devices having only one potential barrier, e.g. photodiodes the potential barrier being a PN homojunction
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
- H10F71/121—The active layers comprising only Group IV materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/20—Electrodes
- H10F77/206—Electrodes for devices having potential barriers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F99/00—Subject matter not provided for in other groups of this subclass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
- H01L2224/4809—Loop shape
- H01L2224/48091—Arched
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/49—Structure, shape, material or disposition of the wire connectors after the connecting process of a plurality of wire connectors
- H01L2224/491—Disposition
- H01L2224/49105—Connecting at different heights
- H01L2224/49107—Connecting at different heights on the semiconductor or solid-state body
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/161—Cap
- H01L2924/1615—Shape
- H01L2924/16195—Flat cap [not enclosing an internal cavity]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/547—Monocrystalline silicon PV cells
Definitions
- the present invention relates to atomic clocks and, more particularly, to a thermally-insulated micro-fabricated atomic clock structure and a method of forming the atomic clock structure.
- a planar coil is a coil where each loop of the coil lies within the same plane.
- a current flowing in a planar coil generates a magnetic field that is perpendicular to the plane.
- the magnetic field exerts a force on the magnetic moment that tries to align the magnetic moment with the direction of the magnetic field.
- Individual electrons also have an intrinsic angular momentum that is associated with the intrinsic magnetic moment.
- the interaction of the intrinsic angular momentum with the alignment force of the magnetic field causes the intrinsic magnetic moment of the electron to precess about the direction of the magnetic field. This precession is analogous to a spinning top as the top wobbles.
- the intrinsic magnetic moment of an electron precessing about the direction of an applied magnetic field is at an angular frequency known as the Larmor frequency.
- the Larmor frequency can be used as a standard to maintain the frequency of a clock.
- the clock which is commonly known as an atomic clock, oscillates at the Larmor frequency. I n addition, the clock periodically determines the Larmor frequency, and uses the determined Larmor frequency to correct any drift in the oscillation frequency of the clock.
- Atomic clocks which utilize the Larmor frequency as the frequency standard typically include a vapor cell, a vertical cavity surface emitting laser (VCSEL), and a photodiode.
- the vapor cell which lies in an externally generated magnetic field, contains a gas that includes alkali atoms and buffer atoms.
- Alkali atoms have a single electron in the outer s subshell of the atom.
- rubidium 87 has a single electron in the 5 s subshell of the fifth shell
- cesium has a single electron in the 6 s subshell.
- the s subshell has two energy levels known as hyperfine energy levels.
- the subshell has a number of energy levels known as Zeeman sublevels within the hyperfine energy levels.
- the alkali atoms within the gas are commonly implemented with, for example, 85 Rb atoms, 87 Rb atoms, K, or Cs atoms.
- the buffer atoms within the gas which are utilized to reduce collisions between the alkali atoms and the inner surface of the vapor cell, are commonly implemented with, for example, N 2 atoms.
- the light output by the VCSEL is tuned to a frequency which, when circularly polarized (and after having been linearly polarized by either a linear polarizing element or if the VCSEL is designed to produce linear polarized light), is absorbed by the single electrons in the outer shells of the alkali atoms in the gas.
- the VCSEL can be tuned to output light with a wavelength of 794.8 nm which, after being circularly polarized, is absorbed by the single electrons in the outer shells of the 87 Rb atoms.
- the VCSEL can alternately be turned to output light with a wavelength of 894.35 nm which, after being circularly polarized, is absorbed by the single electrons in the outer shells of the Cs atoms.
- the single electron in the outer shell of an alkali atom absorbs right-hand circularly polarized light, then the electron transitions from the s subshell to either the outer p subshell, while the projection number M of the electron is always raised by +1.
- the single electron emits a photon in a random direction, and falls back to one of the Zeeman sublevels within the hyperfine energy levels of the s subshell. The state the electron falls to is exactly defined by the quantum selection rules.
- the projection number M of the electron When the electron falls back, the projection number M of the electron also changes by ⁇ 1, 0, or +1 but in a random manner. Thus, when a number of such events occur to the same electron, each time the electron goes to a higher state, the projection number M of the electron is always raised by +1. However, as the electron falls down to the ground state, the projection number M of the electron on average does not change.
- both the ground state S 1/2 and the elevated state P 1/2 have the same number for M levels.
- the electron when the electron reaches the highest M level in the g round state, the electron cannot be pumped because there is not a higher M level in the excited state.
- the population in the ground state M levels has to be de-pumped. Additional energy (magnetic or optical) must be supplied to the electron at the Larmor frequency. The additional energy at the Larmor frequency causes the electron in the highest ground state M level to drop to a lower M level that is associated with the outer shell where the electron can again absorb light energy.
- the photons that pass out of the vapor cell include a non-absorption component, which represents the light output by the VCSEL that was not absorbed by the electrons in the outer shell of the gas within the vapor cell, and an emission component, which represents the photons that are randomly emitted by the falling electrons.
- the photodiode detects these photons, and generates an output signal that has both a non-absorption component and an emission component.
- BB Bell-Bloom
- the Larmor frequency can be determined by determining the modulated frequency that caused the intensity of the received light to dip.
- the detected Larmor frequency is then used to correct any drift in the frequency oscillation of the clock, thereby ensuring that the clock oscillates at the Larmor frequency.
- FIG. 1 is a block diagram illustrating an example of a thermally-insulated micro-fabricated atomic clock structure 100 in accordance with the present invention.
- FIGS. 2A-2C are a flow chart illustrating an example of a method 200 of forming a thermally-insulated micro-fabricated atomic clock structure in accordance with the present invention.
- FIGS. 3A-3G are a series of cross-sectional views illustrating an example of a method of forming a photodiode wafer in accordance with the present invention.
- FIGS. 4A-4C are a series of cross-sectional views illustrating an example of a method of forming a vapor cell wafer in accordance with the present invention.
- FIG. 5 is a plan view further illustrating vapor cell wafer 420 in accordance with the present invention.
- FIGS. 6A-6B are a series of cross-sectional views illustrating an example of a method of forming a lid wafer in accordance with the present invention.
- FIG. 7 is a cross-sectional view illustrating an example of a method of forming an intermediate wafer in accordance with the present invention.
- FIG. 8 is a cross-sectional view illustrating an example of a method of forming a photocell wafer in accordance with the present invention.
- FIGS. 9A-9H are a series of cross-sectional views illustrating an example of a method of forming a thermal photocell wafer in accordance with the present invention.
- FIG. 10 is a plan view further illustrating thermal photocell wafer 950 in accordance with the present invention.
- FIGS. 11A-11B are a series of cross-sectional views illustrating an example of a method of forming an optics structure in accordance with the present invention.
- FIG. 12 is a cross-sectional view illustrating an example of a method of forming an optical photocell wafer in accordance with the present invention.
- FIG. 13 is a cross-sectional view illustrating an example of a method of forming a spacer wafer in accordance with the present invention.
- FIG. 14 is a cross-sectional view illustrating an example of a method of forming a spaced photocell wafer in accordance with the present invention.
- FIGS. 15A-15C are a series of cross-sectional views illustrating an example of a method of forming a laser support wafer in accordance with the present invention.
- FIG. 16 is a top down view of FIG. 15C further illustrating laser support wafer 1550 in accordance with the present invention.
- FIG. 17 is a cross-sectional view illustrating an example of a method of forming a VCSEL wafer in accordance with the present invention.
- FIG. 18 is a cross-sectional view illustrating an example of a method of forming a thermal clock structure wafer in accordance with the present invention.
- FIG. 19 is a cross-sectional view illustrating an example of a method of forming a wired clock structure die in accordance with the present invention.
- FIG. 20 is a cross-sectional view illustrating an example of a method of forming a packaged clock structure chip in accordance with the present invention.
- FIG. 1 shows a block diagram that illustrates an example of a thermally-insulated micro-fabricated atomic clock structure 100 in accordance with the present invention.
- the present invention thermally insulates a micro-fabricated atomic clock structure so that the clock structure can operate with very little power in an environment where the external temperature can drop to ⁇ 40° C., while at the same time maintaining the temperature required for the proper operation of the VCSEL and the gas within the vapor cell.
- clock structure 100 includes a photodiode structure 110 that has a substrate 112 , a number of circuit elements 114 that lie within substrate 112 , and a metal interconnect structure 116 that touches substrate 112 .
- substrate 112 is implemented with p ⁇ single-crystal silicon that has a device surface and an opposing non-device surface.
- substrate 112 has a thermal barrier opening 112 T and a peripheral opening 112 P that each extends into substrate 112 from the non-device surface.
- thermal barrier opening 112 T and peripheral opening 112 P each extend completely through substrate 112 to expose metal interconnect structure 116 .
- thermal barrier opening 112 T laterally surrounds the number of circuit elements 114 .
- the number of circuit elements 114 include a photodiode 120 which has a p ⁇ well 120 P that is formed in substrate 112 , and an n-type region 120 N that is formed in substrate 112 to lie within p ⁇ well 120 P.
- photodiode 120 includes a p+ contact region 120 CP that is formed in substrate 112 to lie within p ⁇ well 120 P, and an n+ contact region 120 CN that is formed in substrate 112 to lie within n-type region 120 N.
- photodiode 120 also includes a p+layer 120 TP that is formed in substrate 112 to lie between n-type region 120 N and the device surface of substrate 112 .
- P+ layer 120 TP is utilized to reduce surface recombination.
- P ⁇ well 120 P has a dopant concentration that is greater than the dopant concentration of p ⁇ substrate 112
- p+ contact region 120 CP has a dopant concentration that is greater than the dopant concentration of p ⁇ well 120 P
- n+ contact region 1200 N has a dopant concentration that is greater than the dopant concentration of n-type region 120 N.
- the number of circuit elements 114 also includes transimpedance amplifier circuit elements 122 which, for purposes of simplicity, are represented as a pair of n+ regions 122 A and 122 B.
- the transimpedance amplifier circuit elements 122 are formed in a different substrate such that only photodiode 120 is formed in substrate 112 .
- Metal interconnect structure 116 includes a non-conductive layer 116 F that touches the device surface of substrate 112 , and a number of contacts 116 C that extend through non-conductive layer 116 F to make electrical connections to the number of circuit elements 114 .
- Metal interconnect structure 116 further includes a number of metal-1 traces 116 L that touch non-conductive layer 116 F.
- the metal-1 traces 116 L include a heater trace 116 H, a temperature sensor trace 116 X, a number of contact traces 116 Y that each touch a contact 116 C, and a number of thermal bridge traces 1168 . Only one thermal bridge trace 1168 is shown for simplicity. Further, non-conductive layer 116 F has bond pad openings 116 P that expose bond pad regions 116 R of heater trace 116 H, temperature sensor trace 116 X, and the thermal bridge traces 1168 . As a result, the bond pad regions 116 R of heater trace 116 H, temperature sensor trace 116 X, and the thermal bridge traces 1168 are exposed by peripheral opening 112 P.
- Metal interconnect structure 116 additionally includes a non-conductive layer 1165 that touches the non-conductive layer 116 F and the metal-1 traces 116 L, and a number of vias 116 V that extend through non-conductive layer 1165 to make electrical connections to the metal-1 traces 116 L.
- Metal interconnect structure 116 also includes a number of metal-2 traces 116 U that touch non-conductive layer 1165 and the vias 116 V, and a non-conductive layer 116 T that touches non-conductive layer 1165 and the metal-2 traces 116 U. (Metal interconnect structure 116 can alternately include additional layers of metal traces.)
- the metal-1 traces 116 L have a resistance that is greater than the resistance of the metal-2 traces 116 U (and any additional layers of metal traces), and a thermal conductivity that is less than the thermal conductivity of the metal-2 traces 116 U (and any additional layers of metal traces).
- photodiode structure 110 additionally includes a metal plate 124 that touches the non-device surface of substrate 112 , and a metal trace 126 that touches the non-device surface of substrate 112 .
- Metal trace 126 which is spaced apart from metal plate 124 , forms a coil that horizontally surrounds metal plate 124 .
- Photodiode structure 110 can also optionally include a metal side wall cover 128 that touches metal plate 124 and substrate 112 , and extends into thermal barrier opening 112 T. In the present example, metal side wall cover 128 is spaced apart from metal interconnect structure 116 .
- Metal plate 124 , metal trace 126 , and metal side wall cover 128 are implemented with a metal that is a poor thermal radiator.
- metal plate 124 , metal trace 126 , and metal side wall cover 128 can be implemented with a metal structure that includes copper, which is poor thermal radiator.
- photodiode 120 receives light energy, and generates a current with a magnitude that varies with the intensity of the light energy.
- a transimpedance amplifier which is formed from the transimpedance amplifier circuit elements 122 , receives the current and generates an amplified photodiode signal that is output by way of a thermal bridge trace 1168 and the bond pad regions 116 R of the thermal bridge trace 116 B. (The current from photodiode 120 is directly output to the bond pad regions 116 R when the transimpedance amplifier circuit elements 122 are optionally omitted.)
- a current is input to metal trace 126 to generate a magnetic field.
- a current is also input as needed to heater trace 116 H which, by the resistance of heater trace 116 H, generates heat.
- a current is input as needed to temperature sensor trace 116 X to measure the temperature adjacent to heater trace 116 H. The resistivity of temperature sensor trace 116 X varies in response to the temperature.
- thermal barrier opening 112 T, heater trace 116 H, temperature sensor trace 116 X, the thermal bridge traces 1168 , metal plate 124 , and metal side wall cover 128 provide thermal insulation that retains the heat generated by heater trace 116 H.
- the heat which would radiate out from the non-device surface of substrate 112 is substantially reduced by metal plate 124 because metal plate 124 includes a metal, such as copper, which is a poor radiator of heat.
- thermal barrier opening 112 T and metal side wall cover 128 the heat which would radiate out laterally from substrate 112 is substantially reduced by thermal barrier opening 112 T and metal side wall cover 128 .
- the air pressure within thermal barrier opening 112 T and peripheral opening 112 P is less than an outside atmospheric pressure. Less heat radiates out into thermal barrier opening 112 T as the air pressure is reduced.
- metal side wall cover 128 further reduces lateral heat loss from substrate 112 because metal side wall cover 128 includes a metal, such as copper, that is a poor radiator of heat.
- the only metal traces that extend out to the periphery to be electrically connected to a metal lead frame are heater trace 116 H, temperature sensor trace 116 X, and the thermal bridge traces 1168 .
- the heat which would conduct laterally outward from the aluminum traces 100 - 40000 (P 07832 ) conventionally used in a metal interconnect structure is substantially reduced by heater trace 116 H, temperature sensor trace 116 X, and the thermal bridge traces 116 B because heater trace 116 H, temperature sensor trace 116 X, and the thermal bridge traces 116 B are formed from a metal, such as a refractory metal, which is a poor conductor of heat.
- clock structure 100 includes a vapor cell structure 130 that touches metal interconnect structure 116 .
- Vapor cell structure 130 has a vapor cell opening 132 and a thermal barrier opening 134 . Both openings 132 and 134 extend completely through vapor cell structure 130 , while thermal barrier opening 134 horizontally surrounds vapor cell opening 132 .
- Metal interconnect structure 116 in turn, fully closes one end of vapor cell opening 132 and one end of thermal barrier opening 134 .
- Clock structure 100 further includes a lid structure 140 that touches vapor cell structure 130 to close and hermetically seal vapor cell opening 132 to form a vapor cell 142 .
- Vapor cell 142 has a gas region 142 G, a deposition region 142 D, and a channel region 142 C that links deposition region 142 D to gas region 142 G.
- Channel region 142 C is thin enough to prevent an aqueous solution from flowing from deposition region 142 D to gas region 142 G, but wide enough to allow a gas to flow from deposition region 142 D to gas region 142 G.
- lid structure 140 has an access opening 144 that extends completely through lid structure 140 to expose thermal barrier opening 134 .
- Clock structure 100 additionally includes a gas 146 that lies within vapor cell 142 .
- gas 146 includes alkali atoms and buffer atoms.
- the alkali atoms within gas 146 can be implemented with, for example, 85 Rb atoms, 87 Rb atoms, K, orCs atoms.
- the buffer atoms within gas 146 can be implemented with, for example, N2 atoms.
- gas 146 In operation, light from a light source is directed into vapor cell 142 where the light energy is absorbed by alkali atoms in gas 146 . Proper operation requires that gas 146 within vapor cell 142 be heated to lie within a temperature range. The heat required by gas 146 is provided by heater trace 116 H.
- thermal barrier opening 134 and access opening 144 provide thermal insulation that retains the heat generated by heater trace 116 H. The heat which would radiate out from vapor cell 142 is substantially reduced by thermal barrier opening 134 and access opening 144 . As further described below, the air pressure within thermal barrier opening 134 and access opening 144 is less than an outside atmospheric pressure. Less heat radiates out into thermal barrier opening 134 and access opening 144 as the air pressure is reduced.
- Clock structure 100 also includes an optics structure 150 that is attached to lid structure 140 with a conventional die attach material 151 .
- Optics structure 150 has an access opening 152 that extends completely through optics structure 150 to expose thermal barrier opening 134 and access opening 144 .
- Clock structure 100 further includes an optics package 154 that is attached to optics structure 150 with a conventional die attach material 156 .
- Optics package 154 includes an attenuator 154 A that reduces the intensity of the input light, a linear polarizer 154 L that linearly polarizes the light output from attenuator 154 A, and a quarter wave plate circular polarizer 154 C that circularly polarizes the light output from linear polarizer 154 L.
- Attenuator 154 A in turn, has an outer surface covered with a non-reflective coating 154 R.
- clock structure 100 includes a spacer structure 160 that is attached to optics structure 150 with blobs 161 of a conventional die attach material.
- Spacer structure 160 has an optical opening 162 and an access opening 164 that both extend completely through spacer structure 160 .
- Optics package 154 lies within optical opening 162 of spacer structure 160 , while access opening 164 exposes thermal barrier opening 134 and access opening 144 .
- clock structure 100 includes a vertical cavity surface emitting laser (VCSEL) support structure 170 that is attached to spacer structure 160 with blobs 171 of a conventional die attach material.
- VCSEL support structure 170 has a substrate 172 and a metal interconnect structure 174 that touches substrate 172 .
- substrate 172 is implemented with glass that has an interconnect surface and an opposing non-interconnect surface.
- Metal interconnect structure 174 includes a non-conductive layer 174 F that touches the interconnect surface of substrate 172 , and a number of metal-1 traces 174 L that touch non-conductive layer 174 F.
- Metal interconnect structure 174 also includes a non-conductive layer 1745 that touches non-conductive layer 174 F and the metal-1 traces 174 L, and a number of vias 174 V that extend through non-conductive layer 1745 to make electrical connections with the metal-1 traces 174 L.
- metal interconnect structure 174 includes a number of metal-2 traces 174 M that touch non-conductive layer 1745 .
- the metal-2 traces 174 M include a heater trace 174 H, a temperature sensor trace 174 X, a number of thermal bridge traces 174 B (only one is shown for simplicity), and a number of contact traces 174 C that each touch a via 174 V.
- Metal interconnect structure 174 also includes a non-conductive layer 174 T that touches non-conductive layer 174 T and the metal-2 traces 174 M.
- metal interconnect structure 174 includes a number of metal-3 traces 174 U that touch non-conductive layer 174 T.
- the metal-3 traces 174 U include a number of contact traces 174 G that have via sections that extend down through non-conductive layer 174 T to touch the ends of the metal-2 heater trace 174 H, the ends of the metal-2 temperature sensor trace 174 X, and an end of each thermal bridge traces 174 B.
- the metal-3 traces 174 include a coil trace 174 Ithat is laid out as a planar coil. (The planar coil is illustrated with a single loop for simplicity. Additional loops can alternately be used to increase the magnetic field.)
- the metal-1 traces 174 L and the metal-3 traces 174 U include metals which have a resistance that is lower than the resistance of the metal-2 traces 174 M.
- the metal-1 traces 174 L have a thermal conductivity that is greater than the thermal conductivity of the metal-2 traces 174 M.
- the metal-2 traces 174 M can be formed from a refractory metal, such as tungsten, titanium, cobalt, zirconium, or molybdenum, while the metal-1 traces 174 L can be formed from a metal such as aluminum and the metal-3 traces 174 U can include copper.
- VCSEL support structure 170 has a metal plate 176 that touches the non-interconnect surface of substrate 172 , a number of pillars 178 that touch metal plate 176 , and a lattice structure 180 that touches the pillars 178 .
- the pillars 178 are non-conductive and spaced apart from each other, while lattice structure 180 , which is non-conductive, has a number of openings that extend completely through lattice structure 180 .
- clock structure 100 has a VCSEL 182 that outputs a laser light beam B.
- VCSEL 182 is attached to non-conductive layer 174 T of metal interconnect structure 174 with a conventional die attach material 183 .
- Clock structure 100 also includes a number of bonding wires 184 that are attached to VCSEL 182 and a number of the contact traces 174 G that are associated with VCSEL 182 .
- a current is input to coil trace 174 Ito generate a magnetic field.
- a current is also input as needed to heater trace 174 H which, by the resistance of heater trace 174 H, generates heat.
- a current is input as needed to temperature sensor trace 174 X to measure the temperature adjacent to heater trace 174 H.
- the resistivity of temperature sensor trace 174 X varies in response to the temperature.
- the laser beam B output by VCSEL 182 is directed into vapor cell 142 where alkali atoms in vapor cell 142 absorb light energy from the laser beam B.
- the single electron in the outer shell transitions from the 1s subshell to either the 2 s or 2p subshell.
- the single electron emits a photon in a random direction, and falls back to one of the Zeeman sublevels within the hyperfine energy levels of the 1s subshell.
- VCSEL 182 Proper operation requires that VCSEL 182 be heated to lie within a temperature range.
- the heat required by VCSEL 182 is provided by heater trace 174 H.
- metal plate 176 , the pillars 178 , and lattice structure 180 provide thermal insulation that retains the heat generated by heater trace 174 H.
- the heat which would radiate out the non-interconnect surface of substrate 172 is substantially reduced by metal plate 176 because metal plate 176 includes a metal, such as copper, which is a poor radiator of heat.
- the air pressure between the pillars 178 is less than an outside atmospheric pressure. Less heat radiates out past lattice structure 180 as the air pressure is reduced.
- the only metal traces that extend out to the periphery to make electrical connections with the metal-3 contact traces 174 G are heater trace 174 H, temperature sensor trace 174 X, and the thermal bridge traces 174 B.
- heater trace 174 H the heat which would conduct laterally outward from the aluminum traces conventionally used in a metal interconnect structure is substantially reduced by heater trace 174 H, temperature sensor trace 174 X, and the thermal bridge traces 174 B because heater trace 174 H, temperature sensor trace 174 X, and the thermal bridge traces 1748 are formed from a metal, such as a refractory metal, which is a poor conductor of heat.
- clock structure 100 has a package structure 190 , a metal lead frame 192 that is connected to package structure 190 , and a die attach pad (DAP) 194 that is connected to metal lead frame 192 .
- Lattice structure 180 is attached to DAP 194 with a conventional die attach material 195 .
- Clock structure 100 also has a number of bonding wires 196 that are connected to metal lead frame 192 and metal trace 126 , the bond pad regions 116 R, and the contact traces 174 G.
- Clock structure 100 further has a metal lid 198 that is attached to package structure 190 to close and hermetically seal the inside of package structure 190 to have an internal air pressure that is substantially less than the air pressure outside of package structure 190 .
- clock structure 100 thermally insulates heater traces 116 H and 174 H, thereby substantially reducing the heat that is lost. As a result, clock structure 100 can operate with very little power in an environment where the external temperature can drop to ⁇ 40° C., while at the same time maintaining the temperature required for the proper operation of vapor cell 142 and VCSEL 182 .
- the metal interconnect structure which is electrically connected to the number of circuit elements, has a number of metal-1 traces and a number of metal-2 traces.
- the metal-2 traces have a thermal conductivity that is greater than the thermal conductivity of the metal-1 traces, and a resistance that is less than the resistance of the metal-1 traces.
- FIGS. 3A-3G show a series of cross-sectional views that illustrate an example of a method of forming a photodiode wafer in accordance with the present invention.
- the method utilizes a conventionally formed p ⁇ single-crystal silicon wafer 310 approximately 600 ⁇ m thick.
- Silicon wafer 310 has a device surface, an opposing non-device surface, and rows and columns of identical die regions. Only one die region is shown and discussed for simplicity.
- the method begins by forming a number of circuit elements 311 that lie within silicon wafer 310 in a conventional manner.
- the number of circuit elements 311 include a photodiode 312 which has a p ⁇ well 312 P that is formed in silicon wafer 310 , and ann-type region 312 N that is formed in silicon wafer 310 to lie within p ⁇ well 312 P.
- photodiode 312 includes a p+ contact region 312 CP that is formed in silicon wafer 310 to lie within p ⁇ well 312 P, and ann+ contact region 312 CN that is formed in silicon wafer 310 to lie within n-type region 312 N.
- photodiode 312 also includes a p+ layer 312 TP that is formed in silicon wafer 310 to lie between n-type region 312 N and the device surface of silicon wafer 310 .
- P+ layer 312 TP is utilized to reduce surface recombination.
- P ⁇ well 312 P has a dopant concentration that is greater than the dopant concentration of p ⁇ single-crystal silicon wafer 310
- p+ contact region 312 CP has a dopant concentration that is greater than the dopant concentration of p ⁇ well 312 P
- n+ contact region 312 CN has a dopant concentration that is greater than the dopant concentration of n-type region 312 N.
- the number of circuit elements 311 also includes transimpedance amplifier circuit elements 314 .
- the transimpedance amplifier circuit elements 314 are well known and represented as a pair of n+ regions 314 A and 314 B for simplicity. In an alternate embodiment, the transimpedance amplifier circuit elements 314 are formed in a different substrate such that only photodiode 312 is formed in silicon wafer 310 .
- a layer of oxide 316 is formed in a conventional manner on the device surface of silicon wafer 310 to lie over photodiode 312 and the transimpedance amplifier circuit elements 314 .
- a number of metal contacts 318 are formed in a conventional manner to extend through oxide layer 316 and make electrical connections with the number of circuit elements 311 .
- the contacts 318 make electrical connections top+ contact region 312 CP and n+ contact region 312 CN of photodiode 312 , and the n+ regions 314 A and 314 B of the circuit elements 314 .
- the to-be-contacted regions such as p+ contact region 312 CP and n+ contact region 312 CN of photodiode 312 , and then+ regions 314 A and 314 B of the circuit elements 314 , can optionally be silicided after oxide layer 316 has been formed and before the contacts 318 are formed.
- a layer of metal 320 is deposited to touch oxide layer 316 and the contacts 318 .
- a patterned photoresist layer 322 is formed on metal layer 320 in a conventional manner.
- the exposed regions of metal layer 320 are etched to form a number of metal-1 traces 324 .
- the metal-1 traces 324 which each lie in a plane P 1 , include a heater trace 324 H, a temperature sensor trace 324 S, a number of contact traces 324 C that each touch a contact 318 , and a number of thermal bridge traces 324 B. Only one thermal bridge trace 324 B is shown for simplicity.
- Heater trace 324 H has opposite ends that both lie in the periphery of the die region.
- temperature sensor trace 324 S also has opposite ends that both lie in the periphery of the die region.
- thermal bridge traces 324 B each have an end that lies in the periphery of the die region.
- Heater trace 324 H can be laid out to minimize the magnetic field that is generated by current flowing through heater trace 324 H.
- heater trace 324 H can be laid out with long parallel strips with alternate strip ends connected together to form a serpentine pattern.
- temperature sensor trace 324 S can be laid out to minimize the magnetic field that is generated by current flowing through temperature sensor trace 324 S.
- temperature sensor trace 324 S can be laid out in two long parallel strips with one pair of strip ends connected together to form a long U-shape pattern.
- patterned photoresist layer 322 is removed in a conventional manner.
- patterned photoresist layer 322 can be removed with acetone, followed by a cleaning, such as with a conventional Piranha etch, to remove organics.
- a layer of oxide 326 is next formed on oxide layer 316 and the metal-1 traces 324 .
- a number of openings 327 are then formed in oxide layer 326 using a patterned photoresist layer and an etch to expose selected regions of the thermal bridge traces 324 B and the contact traces 324 C.
- a metal layer is deposited, and then planarized to remove the metal layer from the outer surface of oxide layer 326 and form vias 328 in the openings 327 .
- the vias 328 touch the thermal bridge traces 324 B and the contact traces 324 C.
- a layer of metal 330 is deposited onto oxide layer 326 and the vias 328 .
- a patterned photoresist layer 332 is formed on metal layer 330 in a conventional manner.
- metal-2 traces 334 are connected to the vias 328 .
- metal layer 330 is formed from a metal which has a lower resistance and a higher thermal conductivity than the metal that is used to form metal layer 320 .
- metal layer 320 can be formed from a refractory metal, such as tungsten, titanium, cobalt, zirconium, or molybdenum (which remain stable at temperatures above 450° C., the melting point of aluminum), while metal layer 330 can be formed from a metal such as aluminum.
- a refractory metal such as tungsten, titanium, cobalt, zirconium, or molybdenum (which remain stable at temperatures above 450° C., the melting point of aluminum)
- metal layer 330 can be formed from a metal such as aluminum.
- the metal-1 traces 324 have a higher resistance and a lower thermal conductivity than the metal-2 traces 334 .
- a layer of oxide 336 is next formed on oxide layer 326 and the metal-2 traces 334 in a conventional manner.
- Oxide layer 336 is then planarized in a conventional manner, such as with chemical-mechanical polishing, until the top surface of oxide layer 336 is flat enough for wafer level fusion bonding. Completion of the planarization completes the formation of a photodiode wafer 340 . (Additional layers of metal traces that each has a lower resistance and a higher thermal conductivity than the metal-1 traces 324 can alternately be formed.)
- method 200 moves to 212 to form a vapor cell wafer.
- the vapor cell wafer has a vapor cell opening and a thermal barrier opening that each extend completely through the vapor cell wafer.
- the thermal barrier opening which is spaced apart from the vapor cell opening, laterally surrounds the vapor cell opening.
- FIGS. 4A-4C show a series of cross-sectional views that illustrate an example of a method of forming a vapor cell wafer in accordance with the present invention.
- the method utilizes a conventionally formed p ⁇ single-crystal silicon wafer 410 approximately 1 mm thick. Silicon wafer 410 has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity.
- the method begins by forming a hard mask 412 on silicon wafer 410 in a conventional manner. After hard mask 412 has been formed, as shown in FIG. 4B , the exposed regions of silicon wafer 410 are etched to form a vapor cell opening 414 and a thermal barrier opening 416 that each extends completely through silicon wafer 410 .
- Vapor cell opening 414 has a gas region 414 G, a deposition region 414 D, and a channel region 414 C that links deposition region 414 D to gas region 414 G.
- hard mask 412 is removed in a conventional manner to complete the formation of a vapor cell wafer 420 .
- FIG. 5 shows a plan view that further illustrates vapor cell wafer 420 in accordance with the present invention.
- channel region 414 C is thin enough to prevent an aqueous solution from flowing from deposition region 414 D to gas region 414 G, but wide enough to allow a gas to flow from deposition region 414 D to gas region 414 G.
- Other opening shapes can alternately be used.
- method 200 moves to 214 to form a lid wafer.
- the lid wafer has an access opening that extends completely through the lid wafer, and an ionic barrier structure that provides a barrier to the diffusion of impurity ions.
- FIGS. 6A-6B show a series of cross-sectional views that illustrate an example of a method of forming a lid wafer in accordance with the present invention.
- the method utilizes a conventionally formed transparent wafer 610 approximately 500 ⁇ m thick that has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity.
- transparent wafer 610 is implemented with glass that has an ionic impurity, such as sodium ions, that makes the glass suitable for anodic bonding to single-crystal silicon.
- an ionic impurity such as sodium ions
- Pyrex® by Corning or Schott Borofloat 33® by Schott is a glass product which can be utilized.
- the method begins by forming an ionic barrier structure 612 on the surface of transparent wafer 610 .
- ionic barrier structure 612 is formed by depositing a layer of nitride, followed by the conventional formation of a patterned photoresist layer. After the patterned photoresist layer has been formed, the exposed regions of the nitride layer are etched away to leave ionic barrier structure 612 . Following this, the patterned photoresist layer is removed in a conventional manner.
- an access opening 614 that extends completely through transparent wafer 610 is formed in a conventional manner. Completion of the formation of access opening 614 completes the formation of a lid wafer 620 .
- method 200 moves to 216 to attach the vapor cell wafer to the photodiode wafer and form an intermediate wafer.
- the intermediate wafer has a vapor cell cavity and a thermal barrier cavity, which are formed by the photodiode wafer closing one side of the vapor cell opening and one side of the thermal barrier opening.
- the vapor cell cavity in turn, includes a gas region, a channel region, and a deposition region.
- FIG. 7 shows a cross-sectional view that illustrates an example of a method of forming an intermediate wafer in accordance with the present invention.
- the method fusion bonds vapor cell wafer 420 to photodiode wafer 340 in a conventional manner.
- Completion of the bonding of vapor cell wafer 420 to photodiode wafer 340 completes the formation of an intermediate wafer 710 that has a vapor cell cavity 712 and a thermal barrier cavity 714 .
- Vapor cell cavity 712 includes a gas region 712 G, a channel region 712 C, and a deposition region 712 D.
- method 200 moves to 218 to place a substance which can be decomposed by ultraviolet (UV) light into alkali and barrier atoms into the vapor cell cavity.
- the substance is placed into the vapor cell cavity by first dissolving cesium azide (CsN 3 ) into water to form an aqueous solution, and then placing a measured amount of the solution (e.g., 10 ⁇ L) into the deposition region at room temperature using, for example, micro-pipettes.
- CsN 3 cesium azide
- the channel region is thin enough to prevent the aqueous solution from flowing into the gas region.
- the intermediate wafer is heated to evaporate away the water and leave a cesium azide solid residue in the deposition region.
- method 200 moves to 220 to attach the lid wafer to the intermediate wafer and form a photocell wafer that has a hermetically sealed vapor cell and an exposed thermal barrier opening.
- FIG. 8 shows a cross-sectional view that illustrates an example of a method of forming a photocell wafer in accordance with the present invention.
- the method anodically bonds lid wafer 620 to vapor cell wafer 420 of intermediate wafer 710 in a conventional manner to form a photocell wafer 810 .
- Cesium azide is unstable at 400° C., and diffuses into glass at 350° C.
- the anodic bonding is performed in a conventional manner at a reduced temperature, such as 300° C., and in a noble gas environment, such as nitrogen gas, with increased bonding time.
- a reduced temperature requires a higher voltage.
- a thinner wafer requires a lower voltage.
- a standard voltage of 1000 V can be used.
- Vapor cell 810 includes a gas region 810 G, a channel region 810 CC, and a deposition region 810 D.
- the cesium azide powder is hermetically sealed only within deposition region 810 D.
- access opening 614 exposes thermal barrier opening 714 to form an exposed thermal barrier opening.
- ionic barrier structure 612 closes vapor cell 810 and prevents the sodium in lid wafer 620 from diffusing into vapor cell 810 .
- lid wafer 620 can be formed without ionic barrier structure 612 .
- lid wafer 620 is anodically bonded to vapor cell wafer 420 of intermediate wafer 710 in the same manner as above.
- lid wafer 620 can be formed without an ionic impurity, e.g., without sodium ions.
- lid wafer 620 is fusion bonded to vapor cell wafer 420 of intermediate wafer 710 in the same manner that vapor cell wafer 420 was fusion bonded to photodiode wafer 340 .
- vapor cell 810 is irradiated with UV light for approximately 10 or more hours at room temperature, which decomposes the cesium azide solid residue into a gas 812 that has cesium (alkali) and barrier atoms.
- Gas 812 can freely move from deposition region 810 D through channel region 810 C into gas region 810 G.
- Gas region 810 G should have approximately 10 12 -10 13 cesium atoms per cubic centimeter following the irradiation.
- nitrogen atoms are used as a buffer gas, insufficient nitrogen atoms are present, and the noble gas used during bonding is nitrogen, then the anodic bonding can take place under pressure to increase the number of nitrogen atoms.
- the maximum pressure is limited, however, as too many nitrogen atoms degrades the signal (widens the line width of the wavelength that represents the point of absorption by the outer electrons).
- method 200 moves to 224 to form a thermal photocell wafer.
- the thermal photocell wafer has a metal plate that is a poor thermal radiator and vertically aligned with the number of circuit elements, a metal trace that is a poor thermal radiator and formed as a coil around the periphery of the metal plate, and a number of thermal barrier openings.
- FIGS. 9A-9H show a series of cross-sectional views that illustrate an example of a method of forming a thermal photocell wafer in accordance with the present invention.
- the method forms the metal plate and the metal trace by first depositing a seed layer 910 on the non-device surface of silicon wafer 310 of photocell wafer 810 .
- Seed layer 910 can be implemented with, for example, 300A of titanium and 3000A of copper. (The titanium layer enhances the adhesion of the copper.)
- a mold 912 is formed on seed layer 910 . Mold 912 can be formed, for example, by depositing and patterning a photoresist layer, such as NR 2 by Futurrex (http://futurrex.com/en/), in a conventional manner.
- mold 912 As shown in FIG. 9B , following the formation of mold 912 , copper, which is a poor thermal radiator, is electroplated to form a plate 914 and a trace 916 .
- Plate 914 is vertically aligned with photodiode circuit 311 , while trace 916 is laid out as a planar coil around the periphery of plate 914 . (The planar coil is shown with a single loop for simplicity. Additional loops can alternately be used to increase the magnetic field.)
- mold 912 is removed in a conventional manner, followed by the conventional removal of the exposed regions of seed layer 910 .
- the exposed regions of silicon wafer 310 are etched using plate 914 and trace 916 as a hard mask to form a number of thermal barrier openings 920 (only one is shown for simplicity) and a peripheral opening 921 that expose oxide layer 316 .
- Silicon wafer 310 can be etched using, for example, KOH or TMAH, which produce side walls that are sloped at 54.7 degrees. Alternately, a conventional deep reactive ion etch (DRIE), such as a Bosch process, can be used to form the thermal barrier openings 920 and peripheral opening 921 .
- DRIE deep reactive ion etch
- a patterned photoresist layer 930 is formed on oxide layer 316 , plate 914 , and trace 916 in a conventional manner.
- FIG. 9E following the formation of patterned photoresist layer 930 , the exposed regions of oxide layer 316 are etched to expose a number of bond pad regions 932 .
- the bond pad regions 932 include a bond pad region 932 H at each end of heater trace 324 H, a bond pad region at each end of temperature sensor trace 3245 , and a bond pad region 932 B at the end of each thermal bridge trace 324 B. Once the bond pad regions 932 have been exposed, patterned photoresist layer 930 is removed in a conventional manner.
- seed layer 934 is deposited on silicon wafer 310 , oxide layer 316 , plate 914 , and trace 916 .
- Seed layer 934 can be implemented with, for example, 300A of titanium and 3000A of copper. (The titanium layer enhances the adhesion of the copper.)
- a conformal non-planarizing layer of photoresist is sprayed on seed layer 934 .
- a light is then projected through a patterned black/clear glass plate known as a mask to form a patterned image on the layer of photoresist that softens the photoresist regions exposed by the light.
- the depth of focus of the light is varied to expose the layer of photoresist at different depths. After this, the softened photoresist regions are developed and washed away to leave a patterned photoresist layer 936 .
- patterned photoresist layer 936 As shown in FIG. 9G , after patterned photoresist layer 936 has been formed, the exposed regions of seed layer 934 are etched to form a side wall cover 940 that touches silicon wafer 310 and plate 914 , and copper bond pads 942 that touch and lie over the bond pad regions 932 .
- patterned photoresist layer 924 is removed in a conventional manner. (Copper plugs can optionally be formed on the copper bond pads 942 by forming a mold and electroplating in a conventional manner.)
- FIG. 9H removal of patterned photoresist layer 936 completes the formation of a thermal photocell wafer 950 .
- FIG. 10 shows a plan view that further illustrates thermal photocell wafer 950 in accordance with the present invention.
- trace 916 is spaced apart from plate 914 , and laid out as a planar coil that laterally surrounds plate 914 .
- the planar coil is shown with a single loop for simplicity. Additional loops can alternately be used to increase the magnetic field.
- the bond pad regions 942 are formed around the periphery of the die region.
- method 200 moves to 226 to form an optical support wafer.
- the optical support wafer has an access opening that extends completely through the optical support wafer.
- the method moves to 228 to attach an optics package to the optical support wafer to form an optics structure.
- the optics package converts light from a laser light source to circularly polarized light.
- FIGS. 11A-11B show a series of cross-sectional views that illustrate an example of a method of forming an optics structure in accordance with the present invention.
- the method utilizes a conventionally formed transparent wafer 1110 approximately 500 ⁇ m thick that has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity.
- transparent wafer 1110 has an optics surface and an opposing non-optics surface. Further, transparent wafer 1110 is implemented with glass such as Pyrex® by Corning or Schott Borofloat 33® by Schott. As further shown in FIG. 11A , the method begins by forming an access opening 1112 that extends completely through transparent wafer 1110 in a conventional manner.
- an optics package 1114 is attached to the optics surface of transparent wafer 1110 .
- Optics package 1114 can be attached with an optical epoxy layer 1116 that leaves no gaps between optics package 1114 and the surface of transparent wafer 1110 to eliminate reflections.
- Optics package 1114 outputs circularly polarized light in response to light received from a light source, and can be implemented with any arrangement that outputs circularly polarized light.
- optics package 1114 includes an attenuator 1114 A that reduces the intensity of the input light, a linear polarizer 1114 L that linearly polarizes the light output from attenuator 1114 A, and a quarter wave plate circular polarizer 1114 C that circularly polarizes the light output from linear polarizer 1114 L.
- Attenuator 1114 A in turn, has an outer surface covered with a non-reflective coating 1114 R.
- Optics package 1114 is commercially available from a number of sources, such as JDS Uniphase (www.jdsu.com), Thorlabs (www.thorlabs.com) or CVI Melles Griot (www.cvimellesgriot), which provide optics packages to meet customer specified requirements for the layers and exterior dimensions.
- JDS Uniphase www.jdsu.com
- Thorlabs www.thorlabs.com
- CVI Melles Griot www.cvimellesgriot
- the attachment of optics package 1114 to transparent wafer 1110 completes the formation of an optics structure 1120 .
- method 200 moves to 230 to attach the optics structure to the thermal photocell wafer to form an optical photocell wafer.
- FIG. 12 shows a cross-sectional view that illustrates an example of a method of forming an optical photocell wafer in accordance with the present invention.
- the method adhesively attaches the non-optics surface of optics structure 1120 to lid wafer 620 of thermal photocell wafer 950 with an optical epoxy layer 1210 that leaves no gaps between a region of the surface of optics structure 1120 and a region of the surface of lid wafer 620 of thermal photocell wafer 950 to prevent reflections.
- access opening 1112 exposes thermal barrier opening 714 .
- the attachment of optics structure 1120 to thermal photocell wafer 950 completes the formation of an optical photocell wafer 1220 .
- method 200 moves to 232 to form a spacer wafer that has an optical opening and an access opening that each extends completely through the spacer wafer.
- FIG. 13 shows a cross-sectional view that illustrates an example of a method of forming a spacer wafer in accordance with the present invention.
- the method utilizes a conventionally formed transparent wafer 1310 approximately 500 ⁇ m thick that has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity.
- transparent wafer 1310 is implemented with glass such as Pyrex® by Corning or Schott Borofloat 33® by Schott.
- the method forms an optical opening 1312 and an access opening 1314 that each extends completely through transparent wafer 1310 in a conventional manner.
- the formation of optical opening 1312 and access opening 1314 completes the formation of a spacer wafer 1320 .
- method 200 moves to 234 to attach the spacer wafer to the optical photocell wafer to form a spaced photocell wafer.
- FIG. 14 shows a cross-sectional view that illustrates an example of a method of forming a spaced photocell wafer in accordance with the present invention.
- the method adhesively attaches a surface of spacer wafer 1320 to optics structure 1120 of optical photocell wafer 1220 with spaced-apart blobs 1410 (which leave an airway path) of a conventional die attach material that leaves gaps between the surface of spacer wafer 1320 and optics wafer 1120 of optical photocell wafer 1220 .
- access opening 1314 exposes thermal barrier opening 714 .
- the attachment of spacer wafer 1320 to optics structure 1120 of optical photocell wafer 1220 completes the formation of a spaced photocell wafer 1420 .
- method 200 moves to 236 to dice the spaced photocell wafer in a conventional manner and form a number of thermal photo-optical die. After this, method 200 moves to 238 to form a laser support wafer which has a substrate and a metal interconnect structure that touches the substrate.
- the metal interconnect structure has a number of metal-1 traces, a number of metal-2 traces, and a number of metal-3 traces.
- the metal-1 and metal-3 traces include metals which have a resistance that is lower than the resistance of the metal-2 traces.
- the metal-1 traces have a thermal conductivity that is greater than the thermal conductivity of the metal-2 traces.
- FIGS. 15A-15C show a series of cross-sectional views that illustrate an example of a method of forming a laser support wafer in accordance with the present invention.
- the method utilizes a conventionally formed transparent wafer 1510 approximately 500 ⁇ m thick that has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity.
- transparent wafer 1510 has an interconnect surface and an opposing non-interconnect surface.
- transparent wafer 1510 is implemented with glass such as Pyrex® by Corning or Schott Borofloat 33® by Schott.
- the method begins by forming a copper-topped metal interconnect structure 1512 on the interconnect surface of transparent wafer 1510 in a conventional manner.
- Copper-topped metal interconnect structure 1512 includes an oxide layer 1514 that touches the interconnect surface of transparent wafer 1510 , and a number of metal-1 traces 1516 that touch oxide layer 1514 .
- Copper-topped metal interconnect structure 1512 also includes an oxide layer 1520 that touches oxide layer 1514 and the metal-1 traces 1516 , and a number of vias 1522 that extend through oxide layer 1520 to make electrical connections with the metal-1 traces 1516 .
- copper-topped metal interconnect structure 1512 includes a number of metal-2 traces 1524 that touch oxide layer 1520 .
- the metal-2 traces 1524 include a heater trace 1524 H, a temperature sensor trace 1524 S, a number of thermal bridge traces 15248 , and a number of contact traces 1524 C that each touch a via 1522 .
- Heater trace 1524 H has opposite ends that both lie in the periphery of the die region.
- temperature sensor trace 1524 S also has opposite ends that both lie in the periphery of the die region.
- an end of each thermal bridge trace 15248 lies in the periphery of the die region.
- Heater trace 1524 H can be laid out to minimize the magnetic field that is generated by current flowing through heater trace 1524 H.
- heater trace 1524 H can be laid out with long parallel strips with alternate strip ends connected together to form a serpentine pattern.
- temperature sensor trace 1524 S can be laid out to minimize the magnetic field that is generated by current flowing through temperature sensor trace 1524 S.
- temperature sensor trace 1524 S can be laid out in two long parallel strips with one pair of strip ends connected together to form a long U-shape pattern.
- copper-topped metal interconnect structure 1512 includes an oxide layer 1526 that touches oxide layer 1520 and the metal-2 traces 1524 .
- copper-topped metal interconnect structure 1512 includes a number of metal-3 traces 1530 that touch oxide layer 1526 .
- the metal-1 traces 1516 and the metal-3 traces 1530 include metals which have a resistance that is lower than the resistance of the metal-2 traces 1524 .
- the metal-1 traces 1516 have a thermal conductivity that is greater than the thermal conductivity of the metal-2 traces 1524 .
- the metal-2 traces 1524 can be formed from a refractory metal, such as tungsten, titanium, cobalt, zirconium, or molybdenum, while the metal-1 traces 1516 can be formed from a metal such as aluminum and the metal-3 traces 1530 can include copper.
- metal layer 1538 is deposited on the non-interconnect surface of transparent wafer 1510 .
- Metal layer 1538 is a poor thermal radiator.
- metal layer 1538 includes copper, and is conventionally formed, e.g., by depositing a seed layer and electroplating a copper layer onto the non-interconnect surface of transparent wafer 1510 .
- a layer of photoimageable epoxy or polymer 1540 such as SU-8, benzocyclobutene (BCB), or polybenzoxazole (PBO), which are substantially self planarizing, is deposited on metal layer 1538 .
- a light is projected through a mask to form a patterned image on layer 1540 that softens the regions of layer 1540 that are exposed by the light.
- a second layer of photoimageable epoxy or polymer 1542 is deposited on layer 1540 .
- a light is projected through a mask to form a patterned image on layer 1542 that softens the regions of layer 1542 that are exposed by the light.
- Pillared structure 1544 includes a number of spaced-apart vertical pillars 1546 (with nothing laterally between each adjacent pair of pillars 1546 ) and a horizontal beam 1548 that touches each of the vertical pillars 1546 .
- the formation of pillared structure 1544 completes the formation of a laser support wafer 1550 .
- FIG. 16 shows a top down view of FIG. 15C that further illustrates laser support wafer 1550 in accordance with the present invention.
- horizontal beam 1548 of pillared structure 1544 has a lattice structure that exposes metal layer 1538 .
- method 200 moves to 240 to physically and electrically attach a VCSEL to each die region of the laser support wafer to form a VCSEL wafer.
- FIG. 17 shows a cross-sectional view that illustrates an example of a method of forming a VCSEL wafer in accordance with the present invention. As shown in FIG. 17 , the method attaches a VCSEL 1710 to oxide layer 1526 in each die region of laser support wafer 1550 with a conventional die attach epoxy 1712 .
- VCSEL 1710 is commercially available from a number of sources, such as Princeton Optronics (www.princetonoptronics.com) or M-Com (www.m-com.com.tw/en), which provide VCSELs to meet customer specified requirements for light frequency, tuning range, power rating, and exterior dimensions.
- VCSEL 1710 is a laser light source that provides light with the longitudinal axis B. Once VCSEL 1710 has been attached, bonding wires 1714 are attached to VCSEL 1710 and a number of contact traces 1530 G that are associated with VCSEL 1710 to form a VCSEL wafer 1720 .
- method 200 moves to 242 to attach a thermal photo-optical die to each die region of the VCSEL wafer to form a thermal clock structure wafer.
- FIG. 18 shows a cross-sectional view that illustrates an example of a method of forming a thermal clock structure wafer in accordance with the present invention.
- the method adhesively attaches a thermal photo-optical die 1810 to each die region of VCSEL wafer 1710 with blobs 1812 of a conventional die attach material.
- the attachment of a thermal photo-optical die 1810 to each die region of VCSEL wafer 1720 completes the formation of a thermal clock structure wafer 1820 .
- method 200 moves to 244 to dice the thermal clock structure wafer in a conventional manner and form a number of thermal clock structure die. After this, method 200 moves to 246 to attach a thermal clock structure die to a die attach pad (DAP) of a metal lead frame of a package. Method 200 then moves to 248 to attach a number of bonding wires to the thermal clock structure die and the metal lead frame and form a wired clock structure die.
- DAP die attach pad
- FIG. 19 shows a cross-sectional view that illustrates an example of a method of forming a wired clock structure die in accordance with the present invention.
- the method adhesively attaches a thermal clock structure die 1910 to a DAP 1912 of a metal lead frame 1914 of a package 1916 with a layer 1920 of a conventional die attach material.
- a ceramic package is utilized.
- a number of bonding wires 1922 are attached to thermal clock structure die 1910 and metal lead frame 1914 of package 1916 in a conventional manner. The attachment of the bonding wires 1922 completes the formation of a wired clock structure die 1930 .
- method 200 moves to 250 to reduce the air pressure inside the package to substantially less than the atmospheric pressure.
- method 200 moves to 252 to attach a metal lid to the package and form a packaged clock structure chip that maintains the reduced air pressure inside the package.
- FIG. 20 shows a cross-sectional view that illustrates an example of a method of forming a packaged clock structure chip in accordance with the present invention.
- the method places wired clock structure die 1930 inside a pressure chamber and reduces the air pressure inside package 1916 to substantially less than the air pressure outside package 1916 .
- the air pressure is reduced to a near vacuum.
- a metal lid 2010 such as a mu metal lid, is attached to package 1916 in a conventional manner to hermetically seal package 1916 and form a packaged clock structure chip 2020 that maintains the reduced pressure inside package 1916 .
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Photometry And Measurement Of Optical Pulse Characteristics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Light Receiving Elements (AREA)
Abstract
Description
- 1. Field of the Invention.
- The present invention relates to atomic clocks and, more particularly, to a thermally-insulated micro-fabricated atomic clock structure and a method of forming the atomic clock structure.
- 2. Description of the Related Art.
- A planar coil is a coil where each loop of the coil lies within the same plane. A current flowing in a planar coil generates a magnetic field that is perpendicular to the plane. When an object with a magnetic moment is placed in a magnetic field, the magnetic field exerts a force on the magnetic moment that tries to align the magnetic moment with the direction of the magnetic field.
- Individual electrons have an intrinsic magnetic moment which can be thought of in the same manner as the magnetic moment that results from a current in a planar coil. As a result, when an electron is placed in a magnetic field, the magnetic field tries to align the intrinsic magnetic moment of the electron with the direction of the magnetic field.
- Individual electrons also have an intrinsic angular momentum that is associated with the intrinsic magnetic moment. The interaction of the intrinsic angular momentum with the alignment force of the magnetic field causes the intrinsic magnetic moment of the electron to precess about the direction of the magnetic field. This precession is analogous to a spinning top as the top wobbles. The intrinsic magnetic moment of an electron precessing about the direction of an applied magnetic field is at an angular frequency known as the Larmor frequency.
- The Larmor frequency can be used as a standard to maintain the frequency of a clock. The clock, which is commonly known as an atomic clock, oscillates at the Larmor frequency. I n addition, the clock periodically determines the Larmor frequency, and uses the determined Larmor frequency to correct any drift in the oscillation frequency of the clock.
- Atomic clocks which utilize the Larmor frequency as the frequency standard typically include a vapor cell, a vertical cavity surface emitting laser (VCSEL), and a photodiode. The vapor cell, which lies in an externally generated magnetic field, contains a gas that includes alkali atoms and buffer atoms.
- Alkali atoms have a single electron in the outer s subshell of the atom. For example, rubidium87 has a single electron in the 5 s subshell of the fifth shell, while cesium has a single electron in the 6 s subshell. In the absence of a magnetic field, the s subshell has two energy levels known as hyperfine energy levels. However, in the presence of a magnetic field, the subshell has a number of energy levels known as Zeeman sublevels within the hyperfine energy levels.
- The alkali atoms within the gas are commonly implemented with, for example, 85Rb atoms, 87Rb atoms, K, or Cs atoms. The buffer atoms within the gas, which are utilized to reduce collisions between the alkali atoms and the inner surface of the vapor cell, are commonly implemented with, for example, N2 atoms.
- The light output by the VCSEL is tuned to a frequency which, when circularly polarized (and after having been linearly polarized by either a linear polarizing element or if the VCSEL is designed to produce linear polarized light), is absorbed by the single electrons in the outer shells of the alkali atoms in the gas. For example, the VCSEL can be tuned to output light with a wavelength of 794.8 nm which, after being circularly polarized, is absorbed by the single electrons in the outer shells of the 87 Rb atoms. The VCSEL can alternately be turned to output light with a wavelength of 894.35 nm which, after being circularly polarized, is absorbed by the single electrons in the outer shells of the Cs atoms.
- If the single electron in the outer shell of an alkali atom absorbs right-hand circularly polarized light, then the electron transitions from the s subshell to either the outer p subshell, while the projection number M of the electron is always raised by +1. When the output light is removed, the single electron emits a photon in a random direction, and falls back to one of the Zeeman sublevels within the hyperfine energy levels of the s subshell. The state the electron falls to is exactly defined by the quantum selection rules.
- When the electron falls back, the projection number M of the electron also changes by −1, 0, or +1 but in a random manner. Thus, when a number of such events occur to the same electron, each time the electron goes to a higher state, the projection number M of the electron is always raised by +1. However, as the electron falls down to the ground state, the projection number M of the electron on average does not change.
- As a result, the electron will eventually land on the highest M level in the ground state. In the gasses under consideration, both the ground state S1/2 and the elevated state P1/2 (or P3/2) have the same number for M levels. Thus, when the electron reaches the highest M level in the g round state, the electron cannot be pumped because there is not a higher M level in the excited state.
- To again reabsorb light, the population in the ground state M levels has to be de-pumped. Additional energy (magnetic or optical) must be supplied to the electron at the Larmor frequency. The additional energy at the Larmor frequency causes the electron in the highest ground state M level to drop to a lower M level that is associated with the outer shell where the electron can again absorb light energy.
- The photons that pass out of the vapor cell include a non-absorption component, which represents the light output by the VCSEL that was not absorbed by the electrons in the outer shell of the gas within the vapor cell, and an emission component, which represents the photons that are randomly emitted by the falling electrons. The photodiode detects these photons, and generates an output signal that has both a non-absorption component and an emission component.
- One common approach to adding additional energy at the Larmor frequency is the Bell-Bloom (BB) technique. In the BB technique, the light output by the VCSEL is modulated by a frequency that is swept across a range of frequencies. When the light output by the VCSEL is frequency modulated at the Larmor frequency, the electrons drop to a lower energy level and begin reabsorbing light energy, which causes a noticeable dip in the intensity of light received by the photo detector.
- Thus, the Larmor frequency can be determined by determining the modulated frequency that caused the intensity of the received light to dip. The detected Larmor frequency is then used to correct any drift in the frequency oscillation of the clock, thereby ensuring that the clock oscillates at the Larmor frequency.
- Two of the drawbacks of conventional Larmor-based atomic clocks are size and cost, which then limit the types of applications where atomic clocks can be commercially utilized. In response to these drawbacks, micro-fabricated atomic clocks have been proposed which can be mass produced in conventional integrated circuit fabrication facilities.
- However, many of the applications for micro-fabricated atomic clocks require the clock to operate with very little power in an environment where the external temperature can range from, for example, −40° C. to +100° C. This is difficult to achieve because the VCSEL and the gas within the vapor cell must each be heated to operate within specific temperature ranges to ensure proper operation.
- Thus, there is a need for a micro-fabricated atomic clock which can operate with very little power in an environment where the external temperature can drop to −40° C., while at the same time maintaining the temperature required for the proper operation of the VCSEL and the gas within the vapor cell.
-
FIG. 1 is a block diagram illustrating an example of a thermally-insulated micro-fabricatedatomic clock structure 100 in accordance with the present invention. -
FIGS. 2A-2C are a flow chart illustrating an example of a method 200 of forming a thermally-insulated micro-fabricated atomic clock structure in accordance with the present invention. -
FIGS. 3A-3G are a series of cross-sectional views illustrating an example of a method of forming a photodiode wafer in accordance with the present invention. -
FIGS. 4A-4C are a series of cross-sectional views illustrating an example of a method of forming a vapor cell wafer in accordance with the present invention. -
FIG. 5 is a plan view further illustratingvapor cell wafer 420 in accordance with the present invention. -
FIGS. 6A-6B are a series of cross-sectional views illustrating an example of a method of forming a lid wafer in accordance with the present invention. -
FIG. 7 is a cross-sectional view illustrating an example of a method of forming an intermediate wafer in accordance with the present invention. -
FIG. 8 is a cross-sectional view illustrating an example of a method of forming a photocell wafer in accordance with the present invention. -
FIGS. 9A-9H are a series of cross-sectional views illustrating an example of a method of forming a thermal photocell wafer in accordance with the present invention. -
FIG. 10 is a plan view further illustratingthermal photocell wafer 950 in accordance with the present invention. -
FIGS. 11A-11B are a series of cross-sectional views illustrating an example of a method of forming an optics structure in accordance with the present invention. -
FIG. 12 is a cross-sectional view illustrating an example of a method of forming an optical photocell wafer in accordance with the present invention. -
FIG. 13 is a cross-sectional view illustrating an example of a method of forming a spacer wafer in accordance with the present invention. -
FIG. 14 is a cross-sectional view illustrating an example of a method of forming a spaced photocell wafer in accordance with the present invention. -
FIGS. 15A-15C are a series of cross-sectional views illustrating an example of a method of forming a laser support wafer in accordance with the present invention. -
FIG. 16 is a top down view ofFIG. 15C further illustratinglaser support wafer 1550 in accordance with the present invention. -
FIG. 17 is a cross-sectional view illustrating an example of a method of forming a VCSEL wafer in accordance with the present invention. -
FIG. 18 is a cross-sectional view illustrating an example of a method of forming a thermal clock structure wafer in accordance with the present invention. -
FIG. 19 is a cross-sectional view illustrating an example of a method of forming a wired clock structure die in accordance with the present invention. -
FIG. 20 is a cross-sectional view illustrating an example of a method of forming a packaged clock structure chip in accordance with the present invention. -
FIG. 1 shows a block diagram that illustrates an example of a thermally-insulated micro-fabricatedatomic clock structure 100 in accordance with the present invention. As described in greater detail below, the present invention thermally insulates a micro-fabricated atomic clock structure so that the clock structure can operate with very little power in an environment where the external temperature can drop to −40° C., while at the same time maintaining the temperature required for the proper operation of the VCSEL and the gas within the vapor cell. - As shown in
FIG. 1 ,clock structure 100 includes aphotodiode structure 110 that has asubstrate 112, a number ofcircuit elements 114 that lie withinsubstrate 112, and ametal interconnect structure 116 that touchessubstrate 112. In the present example,substrate 112 is implemented with p− single-crystal silicon that has a device surface and an opposing non-device surface. - In addition,
substrate 112 has athermal barrier opening 112T and aperipheral opening 112P that each extends intosubstrate 112 from the non-device surface. In the present example,thermal barrier opening 112T andperipheral opening 112P each extend completely throughsubstrate 112 to exposemetal interconnect structure 116. Thus, in the present example, thermal barrier opening 112T laterally surrounds the number ofcircuit elements 114. - The number of
circuit elements 114 include aphotodiode 120 which has a p− well 120P that is formed insubstrate 112, and an n-type region 120N that is formed insubstrate 112 to lie within p− well 120P. In addition,photodiode 120 includes a p+ contact region 120CP that is formed insubstrate 112 to lie within p− well 120P, and an n+ contact region 120CN that is formed insubstrate 112 to lie within n-type region 120N. - Further, in the present example,
photodiode 120 also includes a p+layer 120TP that is formed insubstrate 112 to lie between n-type region 120N and the device surface ofsubstrate 112. P+ layer 120TP is utilized to reduce surface recombination. P− well 120P has a dopant concentration that is greater than the dopant concentration of p−substrate 112, while p+ contact region 120CP has a dopant concentration that is greater than the dopant concentration of p− well 120P, and n+ contact region 1200N has a dopant concentration that is greater than the dopant concentration of n-type region 120N. - In the present example, the number of
circuit elements 114 also includes transimpedanceamplifier circuit elements 122 which, for purposes of simplicity, are represented as a pair of 122A and 122B. In an alternate embodiment, the transimpedancen+ regions amplifier circuit elements 122 are formed in a different substrate such thatonly photodiode 120 is formed insubstrate 112. -
Metal interconnect structure 116, in turn, includes anon-conductive layer 116F that touches the device surface ofsubstrate 112, and a number ofcontacts 116C that extend throughnon-conductive layer 116F to make electrical connections to the number ofcircuit elements 114.Metal interconnect structure 116 further includes a number of metal-1traces 116L that touchnon-conductive layer 116F. - The metal-1
traces 116L include aheater trace 116H, atemperature sensor trace 116X, a number of contact traces 116Y that each touch acontact 116C, and a number of thermal bridge traces 1168. Only one thermal bridge trace 1168 is shown for simplicity. Further,non-conductive layer 116F hasbond pad openings 116P that exposebond pad regions 116R ofheater trace 116H,temperature sensor trace 116X, and the thermal bridge traces 1168. As a result, thebond pad regions 116R ofheater trace 116H,temperature sensor trace 116X, and the thermal bridge traces 1168 are exposed byperipheral opening 112P. -
Metal interconnect structure 116 additionally includes a non-conductive layer 1165 that touches thenon-conductive layer 116F and the metal-1traces 116L, and a number ofvias 116V that extend through non-conductive layer 1165 to make electrical connections to the metal-1traces 116L.Metal interconnect structure 116 also includes a number of metal-2traces 116U that touch non-conductive layer 1165 and thevias 116V, and anon-conductive layer 116T that touches non-conductive layer 1165 and the metal-2traces 116U. (Metal interconnect structure 116 can alternately include additional layers of metal traces.) - In the present example, the metal-1
traces 116L have a resistance that is greater than the resistance of the metal-2traces 116U (and any additional layers of metal traces), and a thermal conductivity that is less than the thermal conductivity of the metal-2traces 116U (and any additional layers of metal traces). - As further shown in
FIG. 1 ,photodiode structure 110 additionally includes ametal plate 124 that touches the non-device surface ofsubstrate 112, and ametal trace 126 that touches the non-device surface ofsubstrate 112.Metal trace 126, which is spaced apart frommetal plate 124, forms a coil that horizontally surroundsmetal plate 124. (Metal trace 126 is illustrated with a single loop for simplicity. Additional loops can alternately be utilized.)Photodiode structure 110 can also optionally include a metalside wall cover 128 that touchesmetal plate 124 andsubstrate 112, and extends intothermal barrier opening 112T. In the present example, metalside wall cover 128 is spaced apart frommetal interconnect structure 116. -
Metal plate 124,metal trace 126, and metalside wall cover 128 are implemented with a metal that is a poor thermal radiator. For example,metal plate 124,metal trace 126, and metalside wall cover 128 can be implemented with a metal structure that includes copper, which is poor thermal radiator. - In operation,
photodiode 120 receives light energy, and generates a current with a magnitude that varies with the intensity of the light energy. In the present example, a transimpedance amplifier, which is formed from the transimpedanceamplifier circuit elements 122, receives the current and generates an amplified photodiode signal that is output by way of a thermal bridge trace 1168 and thebond pad regions 116R of thethermal bridge trace 116B. (The current fromphotodiode 120 is directly output to thebond pad regions 116R when the transimpedanceamplifier circuit elements 122 are optionally omitted.) - In addition, a current is input to
metal trace 126 to generate a magnetic field. A current is also input as needed toheater trace 116H which, by the resistance ofheater trace 116H, generates heat. Further, a current is input as needed totemperature sensor trace 116X to measure the temperature adjacent toheater trace 116H. The resistivity oftemperature sensor trace 116X varies in response to the temperature. - In the present example,
thermal barrier opening 112T,heater trace 116H,temperature sensor trace 116X, the thermal bridge traces 1168,metal plate 124, and metalside wall cover 128 provide thermal insulation that retains the heat generated byheater trace 116H. The heat which would radiate out from the non-device surface ofsubstrate 112 is substantially reduced bymetal plate 124 becausemetal plate 124 includes a metal, such as copper, which is a poor radiator of heat. - Further, the heat which would radiate out laterally from
substrate 112 is substantially reduced bythermal barrier opening 112T and metalside wall cover 128. As further described below, the air pressure withinthermal barrier opening 112T andperipheral opening 112P is less than an outside atmospheric pressure. Less heat radiates out intothermal barrier opening 112T as the air pressure is reduced. In addition, metalside wall cover 128 further reduces lateral heat loss fromsubstrate 112 because metalside wall cover 128 includes a metal, such as copper, that is a poor radiator of heat. - Further, the only metal traces that extend out to the periphery to be electrically connected to a metal lead frame are
heater trace 116H,temperature sensor trace 116X, and the thermal bridge traces 1168. Thus, the heat which would conduct laterally outward from the aluminum traces 100-40000 (P07832) conventionally used in a metal interconnect structure is substantially reduced byheater trace 116H,temperature sensor trace 116X, and the thermal bridge traces 116B becauseheater trace 116H,temperature sensor trace 116X, and the thermal bridge traces 116B are formed from a metal, such as a refractory metal, which is a poor conductor of heat. - As additionally shown in
FIG. 1 ,clock structure 100 includes avapor cell structure 130 that touchesmetal interconnect structure 116.Vapor cell structure 130 has avapor cell opening 132 and athermal barrier opening 134. Both 132 and 134 extend completely throughopenings vapor cell structure 130, while thermal barrier opening 134 horizontally surroundsvapor cell opening 132.Metal interconnect structure 116, in turn, fully closes one end ofvapor cell opening 132 and one end ofthermal barrier opening 134. -
Clock structure 100 further includes alid structure 140 that touchesvapor cell structure 130 to close and hermetically sealvapor cell opening 132 to form avapor cell 142.Vapor cell 142, in turn, has agas region 142G, adeposition region 142D, and achannel region 142C that linksdeposition region 142D togas region 142G.Channel region 142C is thin enough to prevent an aqueous solution from flowing fromdeposition region 142D togas region 142G, but wide enough to allow a gas to flow fromdeposition region 142D togas region 142G. In addition,lid structure 140 has an access opening 144 that extends completely throughlid structure 140 to exposethermal barrier opening 134. -
Clock structure 100 additionally includes agas 146 that lies withinvapor cell 142. In the present example,gas 146 includes alkali atoms and buffer atoms. The alkali atoms withingas 146 can be implemented with, for example, 85Rb atoms, 87Rb atoms, K, orCs atoms. The buffer atoms withingas 146 can be implemented with, for example, N2 atoms. - In operation, light from a light source is directed into
vapor cell 142 where the light energy is absorbed by alkali atoms ingas 146. Proper operation requires thatgas 146 withinvapor cell 142 be heated to lie within a temperature range. The heat required bygas 146 is provided byheater trace 116H. - In addition, thermal barrier opening 134 and access opening 144 provide thermal insulation that retains the heat generated by
heater trace 116H. The heat which would radiate out fromvapor cell 142 is substantially reduced by thermal barrier opening 134 andaccess opening 144. As further described below, the air pressure within thermal barrier opening 134 and access opening 144 is less than an outside atmospheric pressure. Less heat radiates out into thermal barrier opening 134 and access opening 144 as the air pressure is reduced. -
Clock structure 100 also includes anoptics structure 150 that is attached tolid structure 140 with a conventional die attachmaterial 151.Optics structure 150 has an access opening 152 that extends completely throughoptics structure 150 to expose thermal barrier opening 134 andaccess opening 144.Clock structure 100 further includes anoptics package 154 that is attached tooptics structure 150 with a conventional die attachmaterial 156. -
Optics package 154, in turn, includes anattenuator 154A that reduces the intensity of the input light, alinear polarizer 154L that linearly polarizes the light output fromattenuator 154A, and a quarter wave platecircular polarizer 154C that circularly polarizes the light output fromlinear polarizer 154L.Attenuator 154A, in turn, has an outer surface covered with anon-reflective coating 154R. - In addition,
clock structure 100 includes aspacer structure 160 that is attached tooptics structure 150 withblobs 161 of a conventional die attach material.Spacer structure 160 has anoptical opening 162 and an access opening 164 that both extend completely throughspacer structure 160.Optics package 154 lies withinoptical opening 162 ofspacer structure 160, while access opening 164 exposes thermal barrier opening 134 andaccess opening 144. - As also shown in
FIG. 1 ,clock structure 100 includes a vertical cavity surface emitting laser (VCSEL)support structure 170 that is attached tospacer structure 160 withblobs 171 of a conventional die attach material.VCSEL support structure 170 has asubstrate 172 and ametal interconnect structure 174 that touchessubstrate 172. I n the present example,substrate 172 is implemented with glass that has an interconnect surface and an opposing non-interconnect surface. -
Metal interconnect structure 174, in turn, includes anon-conductive layer 174F that touches the interconnect surface ofsubstrate 172, and a number of metal-1traces 174L that touchnon-conductive layer 174F.Metal interconnect structure 174 also includes a non-conductive layer 1745 that touchesnon-conductive layer 174F and the metal-1traces 174L, and a number ofvias 174V that extend through non-conductive layer 1745 to make electrical connections with the metal-1traces 174L. - In addition,
metal interconnect structure 174 includes a number of metal-2traces 174M that touch non-conductive layer 1745. The metal-2traces 174M include aheater trace 174H, atemperature sensor trace 174X, a number of thermal bridge traces 174B (only one is shown for simplicity), and a number of contact traces 174C that each touch a via 174V.Metal interconnect structure 174 also includes anon-conductive layer 174T that touchesnon-conductive layer 174T and the metal-2traces 174M. - In addition,
metal interconnect structure 174 includes a number of metal-3traces 174U thattouch non-conductive layer 174T. The metal-3traces 174U include a number of contact traces 174G that have via sections that extend down throughnon-conductive layer 174T to touch the ends of the metal-2heater trace 174H, the ends of the metal-2temperature sensor trace 174X, and an end of each thermal bridge traces 174B. In addition, the metal-3traces 174 include a coil trace 174Ithat is laid out as a planar coil. (The planar coil is illustrated with a single loop for simplicity. Additional loops can alternately be used to increase the magnetic field.) - In the present example, the metal-1
traces 174L and the metal-3traces 174U include metals which have a resistance that is lower than the resistance of the metal-2traces 174M. In addition, the metal-1traces 174L have a thermal conductivity that is greater than the thermal conductivity of the metal-2traces 174M. For example, the metal-2traces 174M can be formed from a refractory metal, such as tungsten, titanium, cobalt, zirconium, or molybdenum, while the metal-1traces 174L can be formed from a metal such as aluminum and the metal-3traces 174U can include copper. - In addition,
VCSEL support structure 170 has ametal plate 176 that touches the non-interconnect surface ofsubstrate 172, a number ofpillars 178 that touchmetal plate 176, and alattice structure 180 that touches thepillars 178. Thepillars 178 are non-conductive and spaced apart from each other, whilelattice structure 180, which is non-conductive, has a number of openings that extend completely throughlattice structure 180. - As further shown in
FIG. 1 ,clock structure 100 has aVCSEL 182 that outputs a laser lightbeam B. VCSEL 182 is attached tonon-conductive layer 174T ofmetal interconnect structure 174 with a conventional die attachmaterial 183.Clock structure 100 also includes a number of bonding wires 184 that are attached to VCSEL 182 and a number of the contact traces 174G that are associated withVCSEL 182. - In operation, a current is input to coil trace 174Ito generate a magnetic field. A current is also input as needed to
heater trace 174H which, by the resistance ofheater trace 174H, generates heat. Further, a current is input as needed totemperature sensor trace 174X to measure the temperature adjacent toheater trace 174H. The resistivity oftemperature sensor trace 174X varies in response to the temperature. - In addition, the laser beam B output by
VCSEL 182 is directed intovapor cell 142 where alkali atoms invapor cell 142 absorb light energy from the laser beam B. In the alkali atoms that absorb light energy, the single electron in the outer shell transitions from the 1s subshell to either the 2 s or 2p subshell. When the light energy is removed, the single electron emits a photon in a random direction, and falls back to one of the Zeeman sublevels within the hyperfine energy levels of the 1s subshell. - When alkali atoms are no longer capable of transitioning from the 1s subshell to either the 2s or 2p subshell, additional optical energy is supplied to the electrons at the Larmor frequency by sweeping a modulated frequency across a range of frequencies. When the light output by
VCSEL 182 is frequency modulated at the Larmor frequency, the electrons drop to a lower energy level and begin reabsorbing light energy, which causes a noticeable dip in the intensity of light received byphotodiode 120. - Proper operation requires that
VCSEL 182 be heated to lie within a temperature range. The heat required byVCSEL 182 is provided byheater trace 174H. I n addition,metal plate 176, thepillars 178, andlattice structure 180 provide thermal insulation that retains the heat generated byheater trace 174H. The heat which would radiate out the non-interconnect surface ofsubstrate 172 is substantially reduced bymetal plate 176 becausemetal plate 176 includes a metal, such as copper, which is a poor radiator of heat. - In addition, as further described below, the air pressure between the
pillars 178 is less than an outside atmospheric pressure. Less heat radiates outpast lattice structure 180 as the air pressure is reduced. I n addition, the only metal traces that extend out to the periphery to make electrical connections with the metal-3 contact traces 174G areheater trace 174H,temperature sensor trace 174X, and the thermal bridge traces 174B. - Thus, the heat which would conduct laterally outward from the aluminum traces conventionally used in a metal interconnect structure is substantially reduced by
heater trace 174H,temperature sensor trace 174X, and the thermal bridge traces 174B becauseheater trace 174H,temperature sensor trace 174X, and the thermal bridge traces 1748 are formed from a metal, such as a refractory metal, which is a poor conductor of heat. - As further shown in
FIG. 1 ,clock structure 100 has apackage structure 190, ametal lead frame 192 that is connected to packagestructure 190, and a die attach pad (DAP) 194 that is connected tometal lead frame 192.Lattice structure 180, in turn, is attached toDAP 194 with a conventional die attachmaterial 195. -
Clock structure 100 also has a number ofbonding wires 196 that are connected tometal lead frame 192 andmetal trace 126, thebond pad regions 116R, and the contact traces 174G.Clock structure 100 further has ametal lid 198 that is attached to packagestructure 190 to close and hermetically seal the inside ofpackage structure 190 to have an internal air pressure that is substantially less than the air pressure outside ofpackage structure 190. - One of the advantages of
clock structure 100 is thatclock structure 100 thermally insulates heater traces 116H and 174H, thereby substantially reducing the heat that is lost. As a result,clock structure 100 can operate with very little power in an environment where the external temperature can drop to −40° C., while at the same time maintaining the temperature required for the proper operation ofvapor cell 142 andVCSEL 182. -
FIGS. 2A-2C show a flow chart that illustrates an example of a method 200 of forming a thermally-insulated micro-fabricated atomic clock structure in accordance with the present invention. As shown inFIGS. 2A-2C , method 200 begins at 210 by forming a photodiode wafer that has a substrate, a number of circuit elements that lie within the substrate, and a metal interconnect structure that touches the substrate. - The metal interconnect structure, which is electrically connected to the number of circuit elements, has a number of metal-1 traces and a number of metal-2 traces. The metal-2 traces have a thermal conductivity that is greater than the thermal conductivity of the metal-1 traces, and a resistance that is less than the resistance of the metal-1 traces.
-
FIGS. 3A-3G show a series of cross-sectional views that illustrate an example of a method of forming a photodiode wafer in accordance with the present invention. As shown inFIG. 3A , the method utilizes a conventionally formed p− single-crystal silicon wafer 310 approximately 600 μm thick.Silicon wafer 310 has a device surface, an opposing non-device surface, and rows and columns of identical die regions. Only one die region is shown and discussed for simplicity. - As further shown in
FIG. 3A , the method begins by forming a number of circuit elements 311 that lie withinsilicon wafer 310 in a conventional manner. The number of circuit elements 311 include aphotodiode 312 which has a p− well 312P that is formed insilicon wafer 310, and ann-type region 312N that is formed insilicon wafer 310 to lie within p− well 312P. In addition,photodiode 312 includes a p+ contact region 312CP that is formed insilicon wafer 310 to lie within p− well 312P, and ann+ contact region 312CN that is formed insilicon wafer 310 to lie within n-type region 312N. - Further, in the present example,
photodiode 312 also includes a p+ layer 312TP that is formed insilicon wafer 310 to lie between n-type region 312N and the device surface ofsilicon wafer 310. P+ layer 312TP is utilized to reduce surface recombination. P− well 312P has a dopant concentration that is greater than the dopant concentration of p− single-crystal silicon wafer 310, while p+ contact region 312CP has a dopant concentration that is greater than the dopant concentration of p− well 312P, and n+ contact region 312CN has a dopant concentration that is greater than the dopant concentration of n-type region 312N. - In the present example, the number of circuit elements 311 also includes transimpedance
amplifier circuit elements 314. The transimpedanceamplifier circuit elements 314 are well known and represented as a pair of 314A and 314B for simplicity. In an alternate embodiment, the transimpedancen+ regions amplifier circuit elements 314 are formed in a different substrate such thatonly photodiode 312 is formed insilicon wafer 310. - Following the conventional formation of
photodiode 312 and the transimpedanceamplifier circuit elements 314, a layer ofoxide 316 is formed in a conventional manner on the device surface ofsilicon wafer 310 to lie overphotodiode 312 and the transimpedanceamplifier circuit elements 314. - After this, a number of
metal contacts 318 are formed in a conventional manner to extend throughoxide layer 316 and make electrical connections with the number of circuit elements 311. In the present example, thecontacts 318 make electrical connections top+ contact region 312CP and n+ contact region 312CN ofphotodiode 312, and the 314A and 314B of then+ regions circuit elements 314. The to-be-contacted regions, such as p+ contact region 312CP and n+ contact region 312CN ofphotodiode 312, and 314A and 314B of thethen+ regions circuit elements 314, can optionally be silicided afteroxide layer 316 has been formed and before thecontacts 318 are formed. - As shown in
FIG. 3B , following the conventional formation of thecontacts 318, a layer ofmetal 320 is deposited to touchoxide layer 316 and thecontacts 318. Oncemetal layer 320 has been deposited, a patternedphotoresist layer 322 is formed onmetal layer 320 in a conventional manner. - As shown in
FIG. 3C , after patternedphotoresist layer 322 has been formed, the exposed regions ofmetal layer 320 are etched to form a number of metal-1 traces 324. The metal-1traces 324, which each lie in a plane P1, include aheater trace 324H, atemperature sensor trace 324S, a number of contact traces 324C that each touch acontact 318, and a number of thermal bridge traces 324B. Only onethermal bridge trace 324B is shown for simplicity. -
Heater trace 324H has opposite ends that both lie in the periphery of the die region. Similarly,temperature sensor trace 324S also has opposite ends that both lie in the periphery of the die region. In addition, the thermal bridge traces 324B each have an end that lies in the periphery of the die region. -
Heater trace 324H can be laid out to minimize the magnetic field that is generated by current flowing throughheater trace 324H. For example,heater trace 324H can be laid out with long parallel strips with alternate strip ends connected together to form a serpentine pattern. Similarly,temperature sensor trace 324S can be laid out to minimize the magnetic field that is generated by current flowing throughtemperature sensor trace 324S. - For example,
temperature sensor trace 324S can be laid out in two long parallel strips with one pair of strip ends connected together to form a long U-shape pattern. Once the metal-1traces 324 have been formed, patternedphotoresist layer 322 is removed in a conventional manner. For example, patternedphotoresist layer 322 can be removed with acetone, followed by a cleaning, such as with a conventional Piranha etch, to remove organics. - As shown in
FIG. 3D , a layer ofoxide 326 is next formed onoxide layer 316 and the metal-1 traces 324. A number ofopenings 327 are then formed inoxide layer 326 using a patterned photoresist layer and an etch to expose selected regions of the thermal bridge traces 324B and the contact traces 324C. - Following this, as shown in
FIG. 3E , a metal layer is deposited, and then planarized to remove the metal layer from the outer surface ofoxide layer 326 and form vias 328 in theopenings 327. Thevias 328 touch the thermal bridge traces 324B and the contact traces 324C. Once thevias 328 have been formed, a layer ofmetal 330 is deposited ontooxide layer 326 and thevias 328. Next, a patternedphotoresist layer 332 is formed onmetal layer 330 in a conventional manner. - As shown in
FIG. 3F , after patternedphotoresist layer 332 has been formed, the exposed regions ofmetal layer 330 are etched to form a number of metal-2 traces 334. The metal-2traces 334, which each lie in a plane P2 that lies over and substantially parallel to plane P1, are connected to thevias 328. In the present example,metal layer 330 is formed from a metal which has a lower resistance and a higher thermal conductivity than the metal that is used to formmetal layer 320. - For example,
metal layer 320 can be formed from a refractory metal, such as tungsten, titanium, cobalt, zirconium, or molybdenum (which remain stable at temperatures above 450° C., the melting point of aluminum), whilemetal layer 330 can be formed from a metal such as aluminum. As a result, the metal-1traces 324 have a higher resistance and a lower thermal conductivity than the metal-2 traces 334. Once the metal-2traces 334 have been formed, patternedphotoresist layer 332 is removed in a conventional manner. - As shown in
FIG. 3G , a layer ofoxide 336 is next formed onoxide layer 326 and the metal-2traces 334 in a conventional manner.Oxide layer 336 is then planarized in a conventional manner, such as with chemical-mechanical polishing, until the top surface ofoxide layer 336 is flat enough for wafer level fusion bonding. Completion of the planarization completes the formation of aphotodiode wafer 340. (Additional layers of metal traces that each has a lower resistance and a higher thermal conductivity than the metal-1traces 324 can alternately be formed.) - Referring again to
FIGS. 2A-2C , after the photodiode wafer has been formed, method 200 moves to 212 to form a vapor cell wafer. The vapor cell wafer has a vapor cell opening and a thermal barrier opening that each extend completely through the vapor cell wafer. The thermal barrier opening, which is spaced apart from the vapor cell opening, laterally surrounds the vapor cell opening. -
FIGS. 4A-4C show a series of cross-sectional views that illustrate an example of a method of forming a vapor cell wafer in accordance with the present invention. As shown inFIG. 4A , the method utilizes a conventionally formed p− single-crystal silicon wafer 410 approximately 1 mm thick.Silicon wafer 410 has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity. - As shown in
FIG. 4A , the method begins by forming ahard mask 412 onsilicon wafer 410 in a conventional manner. Afterhard mask 412 has been formed, as shown inFIG. 4B , the exposed regions ofsilicon wafer 410 are etched to form avapor cell opening 414 and a thermal barrier opening 416 that each extends completely throughsilicon wafer 410. -
Vapor cell opening 414, in turn, has agas region 414G, adeposition region 414D, and achannel region 414C that linksdeposition region 414D togas region 414G. Following this, as shown inFIG. 4C ,hard mask 412 is removed in a conventional manner to complete the formation of avapor cell wafer 420. -
FIG. 5 shows a plan view that further illustratesvapor cell wafer 420 in accordance with the present invention. As shown inFIG. 5 ,channel region 414C is thin enough to prevent an aqueous solution from flowing fromdeposition region 414D togas region 414G, but wide enough to allow a gas to flow fromdeposition region 414D togas region 414G. Other opening shapes can alternately be used. - Referring again to
FIGS. 2A-2C , after the vapor cell wafer has been formed, method 200 moves to 214 to form a lid wafer. The lid wafer has an access opening that extends completely through the lid wafer, and an ionic barrier structure that provides a barrier to the diffusion of impurity ions. -
FIGS. 6A-6B show a series of cross-sectional views that illustrate an example of a method of forming a lid wafer in accordance with the present invention. As shown inFIG. 6A , the method utilizes a conventionally formedtransparent wafer 610 approximately 500 μm thick that has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity. - In the present example,
transparent wafer 610 is implemented with glass that has an ionic impurity, such as sodium ions, that makes the glass suitable for anodic bonding to single-crystal silicon. For example, Pyrex® by Corning or Schott Borofloat 33® by Schott is a glass product which can be utilized. - As further shown in
FIG. 6A , the method begins by forming anionic barrier structure 612 on the surface oftransparent wafer 610. In the present example,ionic barrier structure 612 is formed by depositing a layer of nitride, followed by the conventional formation of a patterned photoresist layer. After the patterned photoresist layer has been formed, the exposed regions of the nitride layer are etched away to leaveionic barrier structure 612. Following this, the patterned photoresist layer is removed in a conventional manner. - As shown in
FIG. 6B , onceionic barrier structure 612 has been formed, an access opening 614 that extends completely throughtransparent wafer 610 is formed in a conventional manner. Completion of the formation of access opening 614 completes the formation of alid wafer 620. - Referring again to
FIGS. 2A-2C , after the lid wafer has been formed, method 200 moves to 216 to attach the vapor cell wafer to the photodiode wafer and form an intermediate wafer. The intermediate wafer has a vapor cell cavity and a thermal barrier cavity, which are formed by the photodiode wafer closing one side of the vapor cell opening and one side of the thermal barrier opening. The vapor cell cavity, in turn, includes a gas region, a channel region, and a deposition region. -
FIG. 7 shows a cross-sectional view that illustrates an example of a method of forming an intermediate wafer in accordance with the present invention. As shown inFIG. 7 , the method fusion bondsvapor cell wafer 420 tophotodiode wafer 340 in a conventional manner. Completion of the bonding ofvapor cell wafer 420 tophotodiode wafer 340 completes the formation of anintermediate wafer 710 that has avapor cell cavity 712 and athermal barrier cavity 714.Vapor cell cavity 712, in turn, includes agas region 712G, a channel region 712C, and a deposition region 712D. - Referring back to
FIGS. 2A-2C , after the intermediate wafer has been formed, method 200 moves to 218 to place a substance which can be decomposed by ultraviolet (UV) light into alkali and barrier atoms into the vapor cell cavity. In the present example, the substance is placed into the vapor cell cavity by first dissolving cesium azide (CsN3) into water to form an aqueous solution, and then placing a measured amount of the solution (e.g., 10 μL) into the deposition region at room temperature using, for example, micro-pipettes. - The channel region, in turn, is thin enough to prevent the aqueous solution from flowing into the gas region. After the aqueous solution has been placed into the deposition region, the intermediate wafer is heated to evaporate away the water and leave a cesium azide solid residue in the deposition region.
- After the substance has been placed into the vapor cell cavity, method 200 moves to 220 to attach the lid wafer to the intermediate wafer and form a photocell wafer that has a hermetically sealed vapor cell and an exposed thermal barrier opening.
-
FIG. 8 shows a cross-sectional view that illustrates an example of a method of forming a photocell wafer in accordance with the present invention. As shown inFIG. 8 , the method anodically bondslid wafer 620 tovapor cell wafer 420 ofintermediate wafer 710 in a conventional manner to form aphotocell wafer 810. - Cesium azide is unstable at 400° C., and diffuses into glass at 350° C. As a result, the anodic bonding is performed in a conventional manner at a reduced temperature, such as 300° C., and in a noble gas environment, such as nitrogen gas, with increased bonding time. A reduced temperature requires a higher voltage. However, a thinner wafer requires a lower voltage. Asa result, a standard voltage of 1000V can be used.
- The anodic bonding process closes the top of
vapor cell cavity 712 to form a hermetically sealedvapor cell 810.Vapor cell 810, in turn, includes agas region 810G, a channel region 810CC, and adeposition region 810D. In the present example, the cesium azide powder is hermetically sealed only withindeposition region 810D. Further, after the wafers have been bonded together, access opening 614 exposes thermal barrier opening 714 to form an exposed thermal barrier opening. In addition,ionic barrier structure 612 closesvapor cell 810 and prevents the sodium inlid wafer 620 from diffusing intovapor cell 810. - In an alternate embodiment,
lid wafer 620 can be formed withoutionic barrier structure 612. In this embodiment,lid wafer 620 is anodically bonded tovapor cell wafer 420 ofintermediate wafer 710 in the same manner as above. In another alternate embodiment,lid wafer 620 can be formed without an ionic impurity, e.g., without sodium ions. In this embodiment,lid wafer 620 is fusion bonded tovapor cell wafer 420 ofintermediate wafer 710 in the same manner thatvapor cell wafer 420 was fusion bonded tophotodiode wafer 340. - Referring back to
FIGS. 2A-2C , after the photocell wafer has been formed, the method moves to 222 to form a gas in the vapor cell. In the present example, as shown inFIG. 8 ,vapor cell 810 is irradiated with UV light for approximately 10 or more hours at room temperature, which decomposes the cesium azide solid residue into agas 812 that has cesium (alkali) and barrier atoms.Gas 812, in turn, can freely move fromdeposition region 810D throughchannel region 810C intogas region 810G.Gas region 810G should have approximately 1012-1013 cesium atoms per cubic centimeter following the irradiation. - If nitrogen atoms are used as a buffer gas, insufficient nitrogen atoms are present, and the noble gas used during bonding is nitrogen, then the anodic bonding can take place under pressure to increase the number of nitrogen atoms. The maximum pressure is limited, however, as too many nitrogen atoms degrades the signal (widens the line width of the wavelength that represents the point of absorption by the outer electrons).
- Referring back to
FIGS. 2A-2C , after a gas has been formed, method 200 moves to 224 to form a thermal photocell wafer. The thermal photocell wafer has a metal plate that is a poor thermal radiator and vertically aligned with the number of circuit elements, a metal trace that is a poor thermal radiator and formed as a coil around the periphery of the metal plate, and a number of thermal barrier openings. -
FIGS. 9A-9H show a series of cross-sectional views that illustrate an example of a method of forming a thermal photocell wafer in accordance with the present invention. As shown inFIG. 9A , the method forms the metal plate and the metal trace by first depositing aseed layer 910 on the non-device surface ofsilicon wafer 310 ofphotocell wafer 810.Seed layer 910 can be implemented with, for example, 300A of titanium and 3000A of copper. (The titanium layer enhances the adhesion of the copper.) Afterseed layer 910 has been formed, amold 912 is formed onseed layer 910.Mold 912 can be formed, for example, by depositing and patterning a photoresist layer, such as NR2 by Futurrex (http://futurrex.com/en/), in a conventional manner. - As shown in
FIG. 9B , following the formation ofmold 912, copper, which is a poor thermal radiator, is electroplated to form aplate 914 and atrace 916.Plate 914 is vertically aligned with photodiode circuit 311, whiletrace 916 is laid out as a planar coil around the periphery ofplate 914. (The planar coil is shown with a single loop for simplicity. Additional loops can alternately be used to increase the magnetic field.) After this,mold 912 is removed in a conventional manner, followed by the conventional removal of the exposed regions ofseed layer 910. - As shown in
FIG. 9C , after the exposed regions ofseed layer 910 have been removed, the exposed regions ofsilicon wafer 310 are etched usingplate 914 and trace 916 as a hard mask to form a number of thermal barrier openings 920 (only one is shown for simplicity) and aperipheral opening 921 that exposeoxide layer 316.Silicon wafer 310 can be etched using, for example, KOH or TMAH, which produce side walls that are sloped at 54.7 degrees. Alternately, a conventional deep reactive ion etch (DRIE), such as a Bosch process, can be used to form thethermal barrier openings 920 andperipheral opening 921. - As shown in
FIG. 9D , onceoxide layer 316 has been exposed, a patternedphotoresist layer 930 is formed onoxide layer 316,plate 914, and trace 916 in a conventional manner. As shown inFIG. 9E , following the formation of patternedphotoresist layer 930, the exposed regions ofoxide layer 316 are etched to expose a number of bond pad regions 932. - The bond pad regions 932 include a
bond pad region 932H at each end ofheater trace 324H, a bond pad region at each end of temperature sensor trace 3245, and abond pad region 932B at the end of eachthermal bridge trace 324B. Once the bond pad regions 932 have been exposed, patternedphotoresist layer 930 is removed in a conventional manner. - As shown in
FIG. 9F , after patternedphotoresist layer 930 has been removed, aseed layer 934 is deposited onsilicon wafer 310,oxide layer 316,plate 914, andtrace 916.Seed layer 934 can be implemented with, for example, 300A of titanium and 3000A of copper. (The titanium layer enhances the adhesion of the copper.) - After
seed layer 934 has been formed, a conformal non-planarizing layer of photoresist is sprayed onseed layer 934. A light is then projected through a patterned black/clear glass plate known as a mask to form a patterned image on the layer of photoresist that softens the photoresist regions exposed by the light. The depth of focus of the light is varied to expose the layer of photoresist at different depths. After this, the softened photoresist regions are developed and washed away to leave a patternedphotoresist layer 936. - As shown in
FIG. 9G , after patternedphotoresist layer 936 has been formed, the exposed regions ofseed layer 934 are etched to form aside wall cover 940 that touchessilicon wafer 310 andplate 914, andcopper bond pads 942 that touch and lie over the bond pad regions 932. Onceside wall cover 940 and thecopper bond pads 942 has been formed, patterned photoresist layer 924 is removed in a conventional manner. (Copper plugs can optionally be formed on thecopper bond pads 942 by forming a mold and electroplating in a conventional manner.) As shown inFIG. 9H , removal of patternedphotoresist layer 936 completes the formation of athermal photocell wafer 950. -
FIG. 10 shows a plan view that further illustratesthermal photocell wafer 950 in accordance with the present invention. As shown inFIG. 10 ,trace 916 is spaced apart fromplate 914, and laid out as a planar coil that laterally surroundsplate 914. (The planar coil is shown with a single loop for simplicity. Additional loops can alternately be used to increase the magnetic field.) In addition, thebond pad regions 942 are formed around the periphery of the die region. - Referring back to
FIGS. 2A-2C , after the thermal photocell wafer has been formed, method 200 moves to 226 to form an optical support wafer. The optical support wafer has an access opening that extends completely through the optical support wafer. Once the optical support wafer has been formed, the method moves to 228 to attach an optics package to the optical support wafer to form an optics structure. The optics package converts light from a laser light source to circularly polarized light. -
FIGS. 11A-11B show a series of cross-sectional views that illustrate an example of a method of forming an optics structure in accordance with the present invention. As shown inFIG. 11A , the method utilizes a conventionally formedtransparent wafer 1110 approximately 500 μm thick that has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity. - In the present example,
transparent wafer 1110 has an optics surface and an opposing non-optics surface. Further,transparent wafer 1110 is implemented with glass such as Pyrex® by Corning or Schott Borofloat 33® by Schott. As further shown inFIG. 11A , the method begins by forming anaccess opening 1112 that extends completely throughtransparent wafer 1110 in a conventional manner. - As shown in
FIG. 11B , afteraccess opening 1112 has been formed, anoptics package 1114 is attached to the optics surface oftransparent wafer 1110.Optics package 1114 can be attached with anoptical epoxy layer 1116 that leaves no gaps betweenoptics package 1114 and the surface oftransparent wafer 1110 to eliminate reflections.Optics package 1114 outputs circularly polarized light in response to light received from a light source, and can be implemented with any arrangement that outputs circularly polarized light. - In the present example,
optics package 1114 includes anattenuator 1114A that reduces the intensity of the input light, alinear polarizer 1114L that linearly polarizes the light output fromattenuator 1114A, and a quarter wave platecircular polarizer 1114C that circularly polarizes the light output fromlinear polarizer 1114L.Attenuator 1114A, in turn, has an outer surface covered with anon-reflective coating 1114R. -
Optics package 1114 is commercially available from a number of sources, such as JDS Uniphase (www.jdsu.com), Thorlabs (www.thorlabs.com) or CVI Melles Griot (www.cvimellesgriot), which provide optics packages to meet customer specified requirements for the layers and exterior dimensions. (Thorlabs NE220B is an attenuator, Thorlabs LPVIS100 is a linear polarizer, and CVIMelles Griot QWP0-895-15-4 is a circular polarizer.) The attachment ofoptics package 1114 totransparent wafer 1110 completes the formation of anoptics structure 1120. - Referring back to
FIGS. 2A-2C , after the optics structure has been formed, method 200 moves to 230 to attach the optics structure to the thermal photocell wafer to form an optical photocell wafer. -
FIG. 12 shows a cross-sectional view that illustrates an example of a method of forming an optical photocell wafer in accordance with the present invention. As shown inFIG. 12 , the method adhesively attaches the non-optics surface ofoptics structure 1120 tolid wafer 620 ofthermal photocell wafer 950 with anoptical epoxy layer 1210 that leaves no gaps between a region of the surface ofoptics structure 1120 and a region of the surface oflid wafer 620 ofthermal photocell wafer 950 to prevent reflections. Further, after the wafers have been attached together, access opening 1112 exposesthermal barrier opening 714. The attachment ofoptics structure 1120 tothermal photocell wafer 950 completes the formation of anoptical photocell wafer 1220. - Referring back to
FIGS. 2A-2C , after the optical photocell wafer has been formed, method 200 moves to 232 to form a spacer wafer that has an optical opening and an access opening that each extends completely through the spacer wafer. -
FIG. 13 shows a cross-sectional view that illustrates an example of a method of forming a spacer wafer in accordance with the present invention. As shown inFIG. 13 , the method utilizes a conventionally formedtransparent wafer 1310 approximately 500 μm thick that has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity. In addition,transparent wafer 1310 is implemented with glass such as Pyrex® by Corning or Schott Borofloat 33® by Schott. - As further shown in
FIG. 13 , the method forms anoptical opening 1312 and anaccess opening 1314 that each extends completely throughtransparent wafer 1310 in a conventional manner. The formation ofoptical opening 1312 andaccess opening 1314 completes the formation of aspacer wafer 1320. - Referring back to
FIGS. 2A-2C , after the spacer wafer has been formed, method 200 moves to 234 to attach the spacer wafer to the optical photocell wafer to form a spaced photocell wafer. -
FIG. 14 shows a cross-sectional view that illustrates an example of a method of forming a spaced photocell wafer in accordance with the present invention. As shown inFIG. 14 , the method adhesively attaches a surface ofspacer wafer 1320 tooptics structure 1120 ofoptical photocell wafer 1220 with spaced-apart blobs 1410 (which leave an airway path) of a conventional die attach material that leaves gaps between the surface ofspacer wafer 1320 andoptics wafer 1120 ofoptical photocell wafer 1220. Further, after the wafers have been attached together, access opening 1314 exposesthermal barrier opening 714. The attachment ofspacer wafer 1320 tooptics structure 1120 ofoptical photocell wafer 1220 completes the formation of a spacedphotocell wafer 1420. - Referring back to
FIGS. 2A-2C , after the spaced photocell wafer has been formed, method 200 moves to 236 to dice the spaced photocell wafer in a conventional manner and form a number of thermal photo-optical die. After this, method 200 moves to 238 to form a laser support wafer which has a substrate and a metal interconnect structure that touches the substrate. - The metal interconnect structure has a number of metal-1 traces, a number of metal-2 traces, and a number of metal-3 traces. The metal-1 and metal-3 traces include metals which have a resistance that is lower than the resistance of the metal-2 traces. In addition, the metal-1 traces have a thermal conductivity that is greater than the thermal conductivity of the metal-2 traces.
-
FIGS. 15A-15C show a series of cross-sectional views that illustrate an example of a method of forming a laser support wafer in accordance with the present invention. As shown inFIG. 15A , the method utilizes a conventionally formedtransparent wafer 1510 approximately 500 μm thick that has rows and columns of identical die regions. Only one die region is shown and discussed for simplicity. In the present example,transparent wafer 1510 has an interconnect surface and an opposing non-interconnect surface. Further,transparent wafer 1510 is implemented with glass such as Pyrex® by Corning or Schott Borofloat 33® by Schott. - As further shown in
FIG. 15A , the method begins by forming a copper-toppedmetal interconnect structure 1512 on the interconnect surface oftransparent wafer 1510 in a conventional manner. Copper-toppedmetal interconnect structure 1512 includes anoxide layer 1514 that touches the interconnect surface oftransparent wafer 1510, and a number of metal-1traces 1516 thattouch oxide layer 1514. - Copper-topped
metal interconnect structure 1512 also includes anoxide layer 1520 that touchesoxide layer 1514 and the metal-1traces 1516, and a number ofvias 1522 that extend throughoxide layer 1520 to make electrical connections with the metal-1 traces 1516. In addition, copper-toppedmetal interconnect structure 1512 includes a number of metal-2traces 1524 thattouch oxide layer 1520. - The metal-2
traces 1524 include aheater trace 1524H, atemperature sensor trace 1524S, a number of thermal bridge traces 15248, and a number of contact traces 1524C that each touch a via 1522.Heater trace 1524H has opposite ends that both lie in the periphery of the die region. Similarly,temperature sensor trace 1524S also has opposite ends that both lie in the periphery of the die region. In addition, an end of each thermal bridge trace 15248 lies in the periphery of the die region. -
Heater trace 1524H can be laid out to minimize the magnetic field that is generated by current flowing throughheater trace 1524H. For example,heater trace 1524H can be laid out with long parallel strips with alternate strip ends connected together to form a serpentine pattern. Similarly,temperature sensor trace 1524S can be laid out to minimize the magnetic field that is generated by current flowing throughtemperature sensor trace 1524S. For example,temperature sensor trace 1524S can be laid out in two long parallel strips with one pair of strip ends connected together to form a long U-shape pattern. - As further shown in
FIG. 15A , copper-toppedmetal interconnect structure 1512 includes anoxide layer 1526 that touchesoxide layer 1520 and the metal-2 traces 1524. In addition, copper-toppedmetal interconnect structure 1512 includes a number of metal-3traces 1530 thattouch oxide layer 1526. - The metal-3
traces 1530 include a number of contact traces 1530G that have via sections that extend down throughoxide layer 1526 to touch the ends of the metal-2heater trace 1524H, the ends of the metal-2 temperature sensor trace 15245, and an end of each thermal bridge trace 15248. In addition, the metal-3traces 1530 include acoil trace 1530T that is laid out as a planar coil. (The planar coil is illustrated with a single loop for simplicity. Additional loops can alternately be used to increase the magnetic field.) - In the present example, the metal-1
traces 1516 and the metal-3traces 1530 include metals which have a resistance that is lower than the resistance of the metal-2 traces 1524. In addition, the metal-1traces 1516 have a thermal conductivity that is greater than the thermal conductivity of the metal-2 traces 1524. For example, the metal-2traces 1524 can be formed from a refractory metal, such as tungsten, titanium, cobalt, zirconium, or molybdenum, while the metal-1traces 1516 can be formed from a metal such as aluminum and the metal-3traces 1530 can include copper. - As shown in
FIG. 15B , after copper-toppedmetal interconnect structure 1512 has been formed,wafer 1510 is flipped over and ametal layer 1538 is deposited on the non-interconnect surface oftransparent wafer 1510.Metal layer 1538, in turn, is a poor thermal radiator. In the present example,metal layer 1538 includes copper, and is conventionally formed, e.g., by depositing a seed layer and electroplating a copper layer onto the non-interconnect surface oftransparent wafer 1510. - Following this, a layer of photoimageable epoxy or
polymer 1540, such as SU-8, benzocyclobutene (BCB), or polybenzoxazole (PBO), which are substantially self planarizing, is deposited onmetal layer 1538. Once the photoimageable epoxy orpolymer 1540 has been deposited, a light is projected through a mask to form a patterned image onlayer 1540 that softens the regions oflayer 1540 that are exposed by the light. - Following this, a second layer of photoimageable epoxy or
polymer 1542 is deposited onlayer 1540. Once the photoimageable epoxy orpolymer 1542 has been deposited, a light is projected through a mask to form a patterned image onlayer 1542 that softens the regions oflayer 1542 that are exposed by the light. - As shown in
FIG. 15C , after photoimageable epoxy orpolymer 1542 has been exposed, photoimageable epoxy orpolymer 1540 and photoimageable epoxy orpolymer 1542 are developed and then rinsed to form apillared structure 1544.Pillared structure 1544 includes a number of spaced-apart vertical pillars 1546 (with nothing laterally between each adjacent pair of pillars 1546) and ahorizontal beam 1548 that touches each of thevertical pillars 1546. The formation ofpillared structure 1544 completes the formation of alaser support wafer 1550. -
FIG. 16 shows a top down view ofFIG. 15C that further illustrateslaser support wafer 1550 in accordance with the present invention. As shown inFIG. 16 ,horizontal beam 1548 ofpillared structure 1544 has a lattice structure that exposesmetal layer 1538. - Referring again to
FIGS. 2A-2C , after the VCSEL wafer has been formed, method 200 moves to 240 to physically and electrically attach a VCSEL to each die region of the laser support wafer to form a VCSEL wafer. -
FIG. 17 shows a cross-sectional view that illustrates an example of a method of forming a VCSEL wafer in accordance with the present invention. As shown inFIG. 17 , the method attaches aVCSEL 1710 tooxide layer 1526 in each die region oflaser support wafer 1550 with a conventional die attach epoxy 1712. -
VCSEL 1710 is commercially available from a number of sources, such as Princeton Optronics (www.princetonoptronics.com) or M-Com (www.m-com.com.tw/en), which provide VCSELs to meet customer specified requirements for light frequency, tuning range, power rating, and exterior dimensions.VCSEL 1710 is a laser light source that provides light with the longitudinal axis B. OnceVCSEL 1710 has been attached,bonding wires 1714 are attached toVCSEL 1710 and a number of contact traces 1530G that are associated withVCSEL 1710 to form aVCSEL wafer 1720. - Referring again to
FIGS. 2A-2C , afterVCSEL wafer 1720 has been formed, method 200 moves to 242 to attach a thermal photo-optical die to each die region of the VCSEL wafer to form a thermal clock structure wafer. -
FIG. 18 shows a cross-sectional view that illustrates an example of a method of forming a thermal clock structure wafer in accordance with the present invention. As shown inFIG. 18 , the method adhesively attaches a thermal photo-optical die 1810 to each die region ofVCSEL wafer 1710 withblobs 1812 of a conventional die attach material. The attachment of a thermal photo-optical die 1810 to each die region ofVCSEL wafer 1720 completes the formation of a thermalclock structure wafer 1820. - Referring back to
FIGS. 2A-2C , after the thermal clock structure wafer has been formed, method 200 moves to 244 to dice the thermal clock structure wafer in a conventional manner and form a number of thermal clock structure die. After this, method 200 moves to 246 to attach a thermal clock structure die to a die attach pad (DAP) of a metal lead frame of a package. Method 200 then moves to 248 to attach a number of bonding wires to the thermal clock structure die and the metal lead frame and form a wired clock structure die. -
FIG. 19 shows a cross-sectional view that illustrates an example of a method of forming a wired clock structure die in accordance with the present invention. As shown inFIG. 19 , the method adhesively attaches a thermal clock structure die 1910 to aDAP 1912 of ametal lead frame 1914 of apackage 1916 with alayer 1920 of a conventional die attach material. In the present example, a ceramic package is utilized. Following this, a number ofbonding wires 1922 are attached to thermal clock structure die 1910 andmetal lead frame 1914 ofpackage 1916 in a conventional manner. The attachment of thebonding wires 1922 completes the formation of a wired clock structure die 1930. - Referring back to
FIGS. 2A-2C , after the wired clock structure die has been formed, method 200 moves to 250 to reduce the air pressure inside the package to substantially less than the atmospheric pressure. Following this, method 200 moves to 252 to attach a metal lid to the package and form a packaged clock structure chip that maintains the reduced air pressure inside the package. -
FIG. 20 shows a cross-sectional view that illustrates an example of a method of forming a packaged clock structure chip in accordance with the present invention. As shown inFIG. 20 , the method places wired clock structure die 1930 inside a pressure chamber and reduces the air pressure insidepackage 1916 to substantially less than the air pressure outsidepackage 1916. In the present example, the air pressure is reduced to a near vacuum. Following this, ametal lid 2010, such as a mu metal lid, is attached to package 1916 in a conventional manner to hermeticallyseal package 1916 and form a packagedclock structure chip 2020 that maintains the reduced pressure insidepackage 1916. - It should be understood that the above descriptions are examples of the present invention, and that various alternatives of the invention described herein may be employed in practicing the invention. Thus, it is intended that the following claims define the scope of the invention and that structures and methods within the scope of these claims and their equivalents be covered thereby.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/703,364 US10665735B2 (en) | 2012-01-07 | 2015-05-04 | Micro-fabricated atomic clock structure and method of forming the atomic clock structure |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/345,688 US9024397B2 (en) | 2012-01-07 | 2012-01-07 | Thermally-insulated micro-fabricated atomic clock structure and method of forming the atomic clock structure |
| US14/703,364 US10665735B2 (en) | 2012-01-07 | 2015-05-04 | Micro-fabricated atomic clock structure and method of forming the atomic clock structure |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/345,688 Division US9024397B2 (en) | 2012-01-07 | 2012-01-07 | Thermally-insulated micro-fabricated atomic clock structure and method of forming the atomic clock structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20150311355A1 true US20150311355A1 (en) | 2015-10-29 |
| US10665735B2 US10665735B2 (en) | 2020-05-26 |
Family
ID=48743786
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/345,688 Active 2033-06-21 US9024397B2 (en) | 2012-01-07 | 2012-01-07 | Thermally-insulated micro-fabricated atomic clock structure and method of forming the atomic clock structure |
| US14/703,364 Active US10665735B2 (en) | 2012-01-07 | 2015-05-04 | Micro-fabricated atomic clock structure and method of forming the atomic clock structure |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/345,688 Active 2033-06-21 US9024397B2 (en) | 2012-01-07 | 2012-01-07 | Thermally-insulated micro-fabricated atomic clock structure and method of forming the atomic clock structure |
Country Status (1)
| Country | Link |
|---|---|
| US (2) | US9024397B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9893119B2 (en) | 2016-03-15 | 2018-02-13 | Texas Instruments Incorporated | Integrated circuit with hall effect and anisotropic magnetoresistive (AMR) sensors |
| CN109461728A (en) * | 2017-09-06 | 2019-03-12 | 德州仪器公司 | Seal chamber in encapsulating electronic device |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9425125B2 (en) * | 2014-02-20 | 2016-08-23 | Altera Corporation | Silicon-glass hybrid interposer circuitry |
| US9343447B2 (en) * | 2014-09-26 | 2016-05-17 | Texas Instruments Incorporated | Optically pumped sensors or references with die-to-package cavities |
| US9639062B2 (en) | 2015-03-30 | 2017-05-02 | Texas Instruments Incorporated | Vapor cell and method for making same |
| US9529334B2 (en) | 2015-03-31 | 2016-12-27 | Texas Instruments Incorporated | Rotational transition based clock, rotational spectroscopy cell, and method of making same |
| US10374621B2 (en) * | 2016-12-01 | 2019-08-06 | Texas Instruments Incorporated | Method and apparatus to reduce the leakage rate of a hermetic cavity |
| US10498001B2 (en) | 2017-08-21 | 2019-12-03 | Texas Instruments Incorporated | Launch structures for a hermetically sealed cavity |
| US10775422B2 (en) | 2017-09-05 | 2020-09-15 | Texas Instruments Incorporated | Molecular spectroscopy cell with resonant cavity |
| US10131115B1 (en) | 2017-09-07 | 2018-11-20 | Texas Instruments Incorporated | Hermetically sealed molecular spectroscopy cell with dual wafer bonding |
| US10549986B2 (en) | 2017-09-07 | 2020-02-04 | Texas Instruments Incorporated | Hermetically sealed molecular spectroscopy cell |
| US10424523B2 (en) | 2017-09-07 | 2019-09-24 | Texas Instruments Incorporated | Hermetically sealed molecular spectroscopy cell with buried ground plane |
| US10551265B2 (en) | 2017-09-07 | 2020-02-04 | Texas Instruments Incorporated | Pressure sensing using quantum molecular rotational state transitions |
| US10444102B2 (en) | 2017-09-07 | 2019-10-15 | Texas Instruments Incorporated | Pressure measurement based on electromagnetic signal output of a cavity |
| US10544039B2 (en) | 2017-09-08 | 2020-01-28 | Texas Instruments Incorporated | Methods for depositing a measured amount of a species in a sealed cavity |
| US10364144B2 (en) | 2017-11-17 | 2019-07-30 | Texas Instruments Incorporated | Hermetically sealed package for mm-wave molecular spectroscopy cell |
| US10370760B2 (en) | 2017-12-15 | 2019-08-06 | Texas Instruments Incorporated | Methods for gas generation in a sealed gas cell cavity |
| US10509369B1 (en) * | 2018-04-05 | 2019-12-17 | The Government Of The United States Of America As Represented By The Secretary Of The Air Force | Method of manufacturing a vapor cell for alkaline-earth-like atoms inside an ultrahigh vacuum chamber |
| US11180844B2 (en) * | 2018-07-02 | 2021-11-23 | Government Of The United States Of America, As Represented By The Secretary Of Commerce | Process for making alkali metal vapor cells |
| US11899406B2 (en) | 2020-01-07 | 2024-02-13 | The Regents Of The University Of Colorado, A Body Corporate | Devices, systems, and methods for fabricating alkali vapor cells |
| US11600581B2 (en) | 2021-04-15 | 2023-03-07 | Texas Instruments Incorporated | Packaged electronic device and multilevel lead frame coupler |
| US20220415742A1 (en) * | 2021-06-23 | 2022-12-29 | Intel Corporation | Microelectronic assemblies having dies with backside back-end-of-line heater traces |
| US12444702B2 (en) | 2021-08-02 | 2025-10-14 | Texas Instruments Incorporated | Flip-chip enhanced quad flat no-lead electronic device with conductor backed coplanar waveguide transmission line feed in multilevel package substrate |
| US12489211B2 (en) | 2023-03-15 | 2025-12-02 | Texas Instruments Incorporated | Electronic device with patch antenna in packaging substrate |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020157247A1 (en) * | 1997-02-25 | 2002-10-31 | Li Chou H. | Heat-resistant electronic systems and circuit boards |
| US20070266784A1 (en) * | 2006-05-18 | 2007-11-22 | Honeywell International Inc. | Chip scale atomic gyroscope |
| US20080014667A1 (en) * | 2006-07-13 | 2008-01-17 | Hooper Stewart E | Modifying the optical properties of a nitride optoelectronic device |
| US20110187465A1 (en) * | 2010-02-04 | 2011-08-04 | Honeywell International Inc. | Design and processes for stabilizing a vcsel in a chip-scale atomic clock |
| US20130015850A1 (en) * | 2011-07-14 | 2013-01-17 | Philipp Lindorfer | Die-Sized Atomic Magnetometer and Method of Forming the Magnetometer |
| US20130147472A1 (en) * | 2011-12-07 | 2013-06-13 | William French | Micro-Fabricated Atomic Magnetometer and Method of Forming the Magnetometer |
| US8629524B2 (en) * | 2012-04-27 | 2014-01-14 | Taiwan Semiconductor Manufacturing Company, Ltd. | Apparatus for vertically integrated backside illuminated image sensors |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6963530B1 (en) * | 2000-02-01 | 2005-11-08 | Research Investment Network, Inc. | Near-field optical head system with integrated slider and laser |
| WO2002061858A2 (en) * | 2000-11-17 | 2002-08-08 | Thermogenic Imaging, Inc. | Apparatus and methods for infrared calorimetric measurements |
| US7612321B2 (en) * | 2004-10-12 | 2009-11-03 | Dcg Systems, Inc. | Optical coupling apparatus for a dual column charged particle beam tool for imaging and forming silicide in a localized manner |
| US9541398B2 (en) * | 2013-04-10 | 2017-01-10 | Microsemi Corporation | Chip-scale atomic gyroscope |
| US9343447B2 (en) * | 2014-09-26 | 2016-05-17 | Texas Instruments Incorporated | Optically pumped sensors or references with die-to-package cavities |
-
2012
- 2012-01-07 US US13/345,688 patent/US9024397B2/en active Active
-
2015
- 2015-05-04 US US14/703,364 patent/US10665735B2/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020157247A1 (en) * | 1997-02-25 | 2002-10-31 | Li Chou H. | Heat-resistant electronic systems and circuit boards |
| US20070266784A1 (en) * | 2006-05-18 | 2007-11-22 | Honeywell International Inc. | Chip scale atomic gyroscope |
| US20080014667A1 (en) * | 2006-07-13 | 2008-01-17 | Hooper Stewart E | Modifying the optical properties of a nitride optoelectronic device |
| US20110187465A1 (en) * | 2010-02-04 | 2011-08-04 | Honeywell International Inc. | Design and processes for stabilizing a vcsel in a chip-scale atomic clock |
| US20130015850A1 (en) * | 2011-07-14 | 2013-01-17 | Philipp Lindorfer | Die-Sized Atomic Magnetometer and Method of Forming the Magnetometer |
| US20130147472A1 (en) * | 2011-12-07 | 2013-06-13 | William French | Micro-Fabricated Atomic Magnetometer and Method of Forming the Magnetometer |
| US8629524B2 (en) * | 2012-04-27 | 2014-01-14 | Taiwan Semiconductor Manufacturing Company, Ltd. | Apparatus for vertically integrated backside illuminated image sensors |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9893119B2 (en) | 2016-03-15 | 2018-02-13 | Texas Instruments Incorporated | Integrated circuit with hall effect and anisotropic magnetoresistive (AMR) sensors |
| US10211255B2 (en) | 2016-03-15 | 2019-02-19 | Texas Instruments Incorporated | Integrated circuit with hall effect and anisotropic magnetoresistive (AMR) sensors |
| US10374004B2 (en) | 2016-03-15 | 2019-08-06 | Texas Instruments Incorporated | Integrated circuit with hall effect and anisotropic magnetoresistive (AMR) sensors |
| CN109461728A (en) * | 2017-09-06 | 2019-03-12 | 德州仪器公司 | Seal chamber in encapsulating electronic device |
Also Published As
| Publication number | Publication date |
|---|---|
| US9024397B2 (en) | 2015-05-05 |
| US20130176703A1 (en) | 2013-07-11 |
| US10665735B2 (en) | 2020-05-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10665735B2 (en) | Micro-fabricated atomic clock structure and method of forming the atomic clock structure | |
| US8836327B2 (en) | Micro-fabricated atomic magnetometer and method of forming the magnetometer | |
| US10042009B2 (en) | Die-sized atomic magnetometer and method of forming the magnetometer | |
| US9112518B2 (en) | Heater substrate, alkali metal cell unit and atomic oscillator | |
| CN103557855B (en) | A kind of colour center diamond gyro | |
| CN104734708B (en) | Quantum interference device, atomic oscillator, electronic equipment and moving body | |
| US20150244382A1 (en) | Atomic cell, manufacturing method for atomic cell, quantum interference device, atomic oscillator, electronic apparatus, and moving object | |
| JP6476751B2 (en) | Atomic cell manufacturing method, atomic cell, quantum interference device, atomic oscillator, and electronic device | |
| CN105577187A (en) | Quantum interference devices, atomic oscillators, electronic devices, and moving bodies | |
| JP2015231053A (en) | Atomic cell, quantum interference device, atomic oscillator, electronic device, and moving object | |
| JP2015118962A (en) | Quantum interference devices, atomic oscillators, electronic equipment, and moving objects | |
| KR101867054B1 (en) | chip-scale atomic clock | |
| JP2015185911A (en) | Atomic cell, quantum interference device, atomic oscillator, electronic device, and moving object | |
| US20130052405A1 (en) | Fabrication techniques to enhance pressure uniformity in anodically bonded vapor cells | |
| JPWO2018096730A1 (en) | Atomic oscillator and electronic equipment | |
| JP2015228461A (en) | Atomic resonance transition device, atomic oscillator, electronic apparatus, and movable body | |
| KR102244798B1 (en) | chip-scale atomic clock | |
| JP2016012855A (en) | Alkali metal cell and atomic oscillator | |
| JP2016021455A (en) | Alkali metal cell and atomic oscillator | |
| JP2007086038A (en) | Optical gas sensor | |
| JP7319623B2 (en) | quantum optics | |
| JP6264876B2 (en) | Quantum interference devices, atomic oscillators, and electronic equipment | |
| US9454135B2 (en) | Manufactureable long cell with enhanced sensitivity and good mechanical strength | |
| JP2016015363A (en) | Quantum interference device and atomic oscillator | |
| JP6447678B2 (en) | Atomic cell manufacturing method, atomic cell, quantum interference device, atomic oscillator, and electronic device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
| STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
| STPP | Information on status: patent application and granting procedure in general |
Free format text: EX PARTE QUAYLE ACTION MAILED |
|
| STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO EX PARTE QUAYLE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
| STPP | Information on status: patent application and granting procedure in general |
Free format text: NOTICE OF ALLOWANCE MAILED -- APPLICATION RECEIVED IN OFFICE OF PUBLICATIONS |
|
| STPP | Information on status: patent application and granting procedure in general |
Free format text: PUBLICATIONS -- ISSUE FEE PAYMENT VERIFIED |
|
| STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
| MAFP | Maintenance fee payment |
Free format text: PAYMENT OF MAINTENANCE FEE, 4TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1551); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY Year of fee payment: 4 |