US20130161091A1 - Bus Bar Electrical Feedthrough For Electrorefiner System - Google Patents
Bus Bar Electrical Feedthrough For Electrorefiner System Download PDFInfo
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- US20130161091A1 US20130161091A1 US13/335,139 US201113335139A US2013161091A1 US 20130161091 A1 US20130161091 A1 US 20130161091A1 US 201113335139 A US201113335139 A US 201113335139A US 2013161091 A1 US2013161091 A1 US 2013161091A1
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- Prior art keywords
- bus bar
- electrical feedthrough
- contact block
- electrical
- retaining plate
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
- C25C7/025—Electrodes; Connections thereof used in cells for the electrolysis of melts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/34—Electrolytic production, recovery or refining of metals by electrolysis of melts of metals not provided for in groups C25C3/02 - C25C3/32
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/005—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells for the electrolysis of melts
Definitions
- the present invention relates to an electrical feedthrough for an electrolytic system configured to recover a metal from an impure feed material.
- An electrochemical process may be used to recover metals from an impure feed and/or to extract metals from a metal-oxide.
- a conventional process typically involves dissolving a metal-oxide in an electrolyte followed by electrolytic decomposition or (for insoluble metal oxides) selective electrotransport to reduce the metal-oxide to its corresponding metal.
- Conventional electrochemical processes for reducing insoluble metal-oxides to their corresponding metallic state may employ a single step or multiple-step approach.
- a multiple-step approach may be a two-step process that utilizes two separate vessels.
- the extraction of uranium from the uranium oxide of spent nuclear fuels includes an initial step of reducing the uranium oxide with lithium dissolved in a molten LiCl electrolyte so as to produce uranium metal and Li 2 O in a first vessel, wherein the Li 2 O remains dissolved in the molten LiCl electrolyte.
- the process then involves a subsequent step of electrowinning in a second vessel, wherein the dissolved Li 2 O in the molten LiCl is electrolytically decomposed to form oxygen gas and regenerate lithium. Consequently, the resulting uranium metal may be extracted in an electrorefining process, while the molten LiCl with the regenerated lithium may be recycled for use in the reduction step of another batch.
- a multi-step approach involves a number of engineering complexities, such as issues pertaining to the transfer of molten salt and reductant at high temperatures from one vessel to another.
- the reduction of oxides in molten salts may be thermodynamically constrained depending on the electrolyte-reductant system.
- this thermodynamic constraint will limit the amount of oxides that can be reduced in a given batch. As a result, more frequent transfers of molten electrolyte and reductant will be needed to meet production requirements.
- a single-step approach generally involves immersing a metal oxide in a compatible molten electrolyte together with a cathode and anode.
- the metal oxide which is in electrical contact with the cathode
- the yield of the metallic product is relatively low.
- the metallic product still contains unwanted impurities.
- a bus bar electrical feedthrough for an electrorefiner system may include a retaining plate, an electrical isolator, and/or a contact block.
- the retaining plate may include a central opening.
- the electrical isolator may include a top portion, a base portion, and a slot extending through the top and base portions.
- the top portion of the electrical isolator may be configured to extend through the central opening of the retaining plate.
- the contact block may include an upper section, a lower section, and a ridge separating the upper and lower sections.
- the upper section of the contact block may be configured to extend through the slot of the electrical isolator and the central opening of the retaining plate.
- FIG. 1 is a perspective view of an electrorefiner system including an electrical feedthrough according to a non-limiting embodiment of the present invention.
- FIG. 2 is a cross-sectional side view of an electrorefiner system including an electrical feedthrough according to a non-limiting embodiment of the present invention.
- FIG. 3 is a perspective view of a plurality of cathode assemblies connected to a common bus bar and an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 4 is an exploded view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 5 is a partial top view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 6 is a partial side view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 7 is a partial bottom view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 8 is a cross-sectional end view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- first, second, third, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers, and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer, or section from another region, layer, or section. Thus, a first element, component, region, layer, or section discussed below could be termed a second element, component, region, layer, or section without departing from the teachings of example embodiments.
- spatially relative terms e.g., “beneath,” “below,” “lower,” “above,” “upper,” and the like
- the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below” or “beneath” other elements or features would then be oriented “above” the other elements or features. Thus, the term “below” may encompass both an orientation of above and below.
- the device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
- Example embodiments are described herein with reference to cross-sectional illustrations that are schematic illustrations of idealized embodiments (and intermediate structures) of example embodiments. As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, example embodiments should not be construed as limited to the shapes of regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. For example, an implanted region illustrated as a rectangle will, typically, have rounded or curved features and/or a gradient of implant concentration at its edges rather than a binary change from implanted to non-implanted region.
- a buried region formed by implantation may result in some implantation in the region between the buried region and the surface through which the implantation takes place.
- the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the actual shape of a region of a device and are not intended to limit the scope of example embodiments.
- An electrorefiner system may be used to recover a purified metal (e.g., uranium) from a relatively impure nuclear feed material (e.g., impure uranium feed material).
- the electrorefiner system may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000252/US, GE Ref. 24NS250931, filed on even date herewith, titled “ELECTROREFINER SYSTEM FOR RECOVERING PURIFIED METAL FROM IMPURE NUCLEAR FEED MATERIAL,” the entire contents of which are incorporated herein by reference.
- the impure nuclear feed material may be a metallic product of an electrolytic oxide reduction system.
- the electrolytic oxide reduction system may be configured to facilitate the reduction of an oxide to its metallic form so as to permit the subsequent recovery of the metal.
- the electrolytic oxide reduction system may be as described in U.S. application Ser. No. 12/978,027, filed Dec. 23, 2010, “ELECTROLYTIC OXIDE REDUCTION SYSTEM,” HDP Ref.: 8564-000228/US, GE Ref.: 24AR246140, the entire contents of which is incorporated herein by reference.
- the electrorefiner system may include a vessel, a plurality of cathode assemblies, a plurality of anode assemblies, a power system, a scraper, and/or a conveyor system.
- the power system may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000254/US, GE Ref. 24AR252783, filed on even date herewith, titled “CATHODE POWER DISTRIBUTION SYSTEM AND METHOD OF USING THE SAME FOR POWER DISTRIBUTION,” the entire contents of which are incorporated herein by reference.
- the scraper may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000255/US, GE Ref.
- the electrorefiner system and/or electrolytic oxide reduction system may be used to perform a method for corium and used nuclear fuel stabilization processing.
- the method may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000262/US, GE Ref. 24AR253193, filed on MM/DD/YYYY, titled “METHOD FOR CORIUM AND USED NUCLEAR FUEL STABILIZATION PROCESSING,” the entire contents of which are incorporated herein by reference.
- a table of the incorporated applications being filed on even date herewith is provided below.
- the impure nuclear feed material for the electrorefiner system may be a metallic product of an electrolytic oxide reduction system.
- a plurality of anode and cathode assemblies are immersed in a molten salt electrolyte.
- the molten salt electrolyte may be lithium chloride (LiCl).
- the molten salt electrolyte may be maintained at a temperature of about 650° C. (+50° C., ⁇ 30° C.).
- An electrochemical process is carried out such that a reducing potential is generated at the cathode assemblies, which contain the oxide feed material (e.g., metal oxide).
- the metal ion of the metal oxide is reduced to metal and the oxygen (O) from the metal oxide (MO) feed material dissolves into the molten salt electrolyte as an oxide ion, thereby leaving the metal (M) behind in the cathode assemblies.
- the cathode reaction may be as follows:
- the oxide ion is converted to oxygen gas.
- the anode shroud of each of the anode assemblies may be used to dilute, cool, and remove the oxygen gas from the electrolytic oxide reduction system during the process.
- the anode reaction may be as follows:
- the metal oxide may be uranium dioxide (UO 2 ), and the reduction product may be uranium metal.
- UO 2 uranium dioxide
- the reduction product may be uranium metal.
- other types of oxides may also be reduced to their corresponding metals with the electrolytic oxide reduction system.
- the molten salt electrolyte used in the electrolytic oxide reduction system is not particularly limited thereto and may vary depending of the oxide feed material to be reduced.
- the basket containing the metallic product in the electrolytic oxide reduction system is transferred to the electrorefiner system according to the present invention for further processing to obtain a purified metal from the metallic product.
- the metallic product from the electrolytic oxide reduction system will serve as the impure nuclear feed material for the electrorefiner system according to the present invention.
- the basket containing the metallic product is a cathode assembly in the electrolytic oxide reduction system
- the basket containing the metallic product is an anode assembly in the electrorefiner system.
- the electrorefiner system according to the present invention allows for a significantly greater yield of purified metal.
- FIG. 1 is a perspective view of an electrorefiner system including an electrical feedthrough according to a non-limiting embodiment of the present invention.
- FIG. 2 is a cross-sectional side view of an electrorefiner system including an electrical feedthrough according to a non-limiting embodiment of the present invention.
- the electrorefiner system 100 includes a vessel 102 , a plurality of cathode assemblies 104 , a plurality of anode assemblies 108 , a power system, a scraper 110 , and/or a conveyor system 112 .
- Each of the plurality of cathode assemblies 104 may include a plurality of cathode rods 106 .
- the power system may include an electrical feedthrough 132 that extends through the floor structure 134 .
- the floor structure 134 may be a glovebox floor in a glovebox. Alternatively, the floor structure 134 may be a support plate in a hot-cell facility.
- the conveyor system 112 may include an inlet pipe 113 , a trough 116 , a chain, a plurality of flights, an exit pipe 114 , and/or a discharge chute 128 .
- the vessel 102 is configured to maintain a molten salt electrolyte.
- the molten salt electrolyte may be LiCl, a LiCl-KCl eutectic, or another suitable medium.
- the vessel 102 may be situated such that a majority of the vessel 102 is below the floor structure 134 . For instance, an upper portion of the vessel 102 may extend above the floor structure 134 through an opening in the floor structure 134 . The opening in the floor structure 134 may correspond to the dimensions of the vessel 102 .
- the vessel 102 is configured to receive the plurality of cathode assemblies 104 and the plurality of anode assemblies 108 .
- the plurality of cathode assemblies 104 are configured to extend into the vessel 102 so as to at least be partially submerged in the molten salt electrolyte. For instance, the dimensions of the plurality of cathode assemblies 104 and/or the vessel 102 may be adjusted such that the majority of the length of the plurality of cathode assemblies 104 is submerged in the molten salt electrolyte in the vessel 102 .
- Each cathode assembly 104 may include a plurality of cathode rods 106 having the same orientation and arranged so as to be within the same plane.
- the plurality of anode assemblies 108 may be alternately arranged with the plurality of cathode assemblies 104 such that each anode. assembly 108 is flanked by two cathode assemblies 104 .
- the plurality of cathode assemblies 104 and anode assemblies 108 may be arranged in parallel.
- Each anode assembly 108 may be configured to hold and immerse an impure uranium feed material in the molten salt electrolyte maintained by the vessel 102 .
- the dimensions of the plurality of anode assemblies 108 and/or the vessel 102 may be adjusted such that the majority of the length of the plurality of anode assemblies 108 is submerged in the molten salt electrolyte in the vessel 102 .
- the electrorefiner system 100 is illustrated in FIGS. 1-2 as having eleven cathode assemblies 104 and ten anode assemblies 108 , it should be understood that the example embodiments herein are not limited thereto.
- a power system is connected to the plurality of cathode assemblies 104 and anode assemblies 108 .
- the power system may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000254/US, GE Ref. 24AR252783, filed on even date herewith, titled “CATHODE POWER DISTRIBUTION SYSTEM AND METHOD OF USING THE SAME FOR POWER DISTRIBUTION,” the entire contents of which are incorporated herein by reference.
- the plurality of cathode assemblies 104 may be connected to a common bus bar 118 , and the common bus bar 118 may be connected to an electrical feedthrough 132 that extends through the floor structure 134 .
- the electrical feedthrough 132 allows power to be supplied to the common bus bar 118 without loss of atmosphere containment of the hermetically sealed glovebox or hot-cell facility.
- the power system is configured to supply a voltage adequate to oxidize the impure uranium feed material in the plurality of anode assemblies 108 to form uranium ions that migrate through the molten salt electrolyte and deposit on the plurality of cathode rods 106 of the plurality of cathode assemblies 104 as purified uranium.
- the scraper 110 is configured to move up and down along the length of the plurality of cathode rods 106 to dislodge the purified uranium deposited on the plurality of cathode rods 106 of the plurality of cathode assemblies 104 .
- the dislodged purified uranium sinks through the molten salt electrolyte to the bottom of the vessel 102 .
- the conveyor system 112 is configured such that at least a portion of it is disposed at the bottom of the vessel 102 .
- the trough 116 of the conveyor system 112 may be disposed at the bottom of the vessel 102 such that the purified uranium dislodged from the plurality of cathode rods 106 accumulates in the trough 116 .
- the conveyor system 112 is configured to transport the purified uranium accumulated in the trough 116 through an exit pipe 114 to a discharge chute 128 so as to remove the purified uranium from the vessel 102 .
- FIG. 3 is a perspective view of a plurality of cathode assemblies connected to a common bus bar and an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- each of the plurality of cathode assemblies 104 includes a plurality of cathode rods 106 .
- the plurality of cathode assemblies 104 are shown as having seven cathode rods 106 each, it should be understood that the example embodiments are not limited thereto.
- each cathode assembly 104 may include less than seven cathode rods 106 or more than seven cathode rods 106 , provided that sufficient current is being provided to the electrorefiner system 100 .
- the plurality of cathode assemblies 104 are connected to a common bus bar 118 .
- the plurality of cathode assemblies 104 may be arranged parallel to each other and perpendicularly to the common bus bar 118 .
- the common bus bar 118 is connected to an electrical feedthrough 132 . As a result, power may be supplied to the common bus bar 118 through the floor structure 134 via the electrical feedthrough 132 without compromising the quality of the atmosphere inside the glovebox or hot-cell facility.
- FIG. 4 is an exploded view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 5 is a partial top view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 6 is a partial side view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 7 is a partial bottom view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- FIG. 8 is a cross-sectional end view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.
- an electrical feedthrough 132 may include a retaining plate 200 , an electrical isolator 204 , and a contact block 212 .
- the retaining plate 200 , electrical isolator 204 , and contact block 212 are designed to be united to form a single structural unit that is clamped onto a floor structure 134 .
- the retaining plate 200 includes a central opening 202 .
- the electrical isolator 204 includes a top portion 206 , a base portion 208 , and a slot 210 extending through the top 206 and base portions 208 .
- the top portion 206 of the electrical isolator 204 is configured to extend through the central opening 202 of the retaining plate 200 .
- the contact block 212 includes an upper section 214 , a lower section 216 , and a ridge 218 separating the upper 214 and lower sections 216 .
- the upper section 214 of the contact block 212 is configured to extend through the slot 210 of the electrical isolator 204 and the central opening 202 of the retaining plate 200 .
- the upper section 214 of the contact block 212 is configured for connection with one or more bus bars.
- the upper section 214 of the contact block 212 may be connected to the common bus bar 118 .
- a plurality of connection holes are provided in the upper section 214 of the contact block 212 .
- the upper section 214 of the contact block 212 is shown as having three connection holes, it should be understood that the example embodiments are not limited thereto.
- the lower section 216 of the contact block 212 is configured for connection with one or more current supply cables.
- the lower section 216 of the contact block 212 may be connected to the current supply cables 220 .
- a plurality of connection holes are provided in the lower section 216 of the contact block 212 .
- the lower section 216 of the contact block 212 is shown as having three connection holes, it should be understood that the example embodiments are not limited thereto.
- the retaining plate 200 may have a plurality of threaded holes surrounding the central opening 202
- the electrical isolator 204 may have a plurality of blind threaded holes in the base portion 208 surrounding the top portion 206 .
- the plurality of threaded holes of the retaining plate 200 may be aligned with the plurality of blind threaded holes of the electrical isolator 204 .
- the contact block 212 also includes a plurality of threaded holes in the ridge 218 surrounding the upper section 214 . The plurality of threaded holes of the contact block 212 allows the contact block 212 to be secured to the electrical isolator 204 with a plurality of screws.
- the retaining plate 200 may be formed of a metal.
- the electrical isolator 204 may be formed of a plastic.
- the plastic may be polyetherketone.
- the contact block 212 may be formed of copper.
- the copper may be silver plated.
- the retaining plate 200 and the electrical isolator 204 are configured to clamp the floor structure 134 in between. Thus, when the electrical feedthrough 132 is properly installed, the retaining plate 200 will be on one surface of the floor structure 134 . Additionally, the base portion 208 of the electrical isolator 204 will be pressed against the opposing surface of the floor structure 134 , while the top portion 206 of the electrical isolator 204 extends through the floor structure 134 and the central opening 202 of the retaining plate 200 .
- the ridge 218 of the contact block 212 will be pressed against the underside of the base portion 208 of the electrical isolator 204 , while the upper section 214 of the contact block 212 extends through the electrical isolator 204 , the floor structure 134 , and the retaining plate 200 such that an exposed terminal portion of the upper section 214 of the contact block 212 protrudes from the slot 210 of the electrical isolator 204 .
- the electrical feedthrough 132 may further include at least one o-ring between the retaining plate 200 and the electrical isolator 204 .
- the electrical feedthrough 132 may also further include an o-ring between the electrical isolator 204 and the ridge 218 of the contact block 212 .
- the electrical feedthrough 132 is configured to allow the contact block 212 to be removed and replaced (e.g., because of damage) without compromising the quality of the atmosphere inside the glovebox or hot-cell facility.
- the electrical feedthrough 132 may further include a cap configured to attach to the top portion 206 of the electrical isolator 204 so as to allow a removal of the contact block 212 without compromising an atmosphere of a hermetically-sealed glovebox or hot-cell facility.
- a plurality of threaded holes may be provided in the upper face of the top portion 206 surrounding the slot 210 to allow the cap to be secured to the electrical isolator 204 .
- the contact block 212 may be removed and repaired (or replaced) without compromising the atmosphere of the hermatically-sealed glovebox or hot-cell facility.
- a method of electrorefining according to a non-limiting embodiment of the present invention may involve electrolytically processing a suitable feed material with the above-discussed electrorefiner system.
- the method may be used to recycle used nuclear fuel or recover a metal (e.g., uranium) from an off-specification metal oxide (e.g., uranium dioxide).
- a metal e.g., uranium
- an off-specification metal oxide e.g., uranium dioxide
- relatively high electrical currents may be transferred into a glovebox or hot-cell facility at a relatively low cost and higher amperage capacity without sacrificing atmosphere integrity.
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Abstract
Description
- The present invention was made with Government support under contract number DE-ACO2-06CH11357, which was awarded by the U.S. Department of Energy.
- 1. Field
- The present invention relates to an electrical feedthrough for an electrolytic system configured to recover a metal from an impure feed material.
- 2. Description of Related Art
- An electrochemical process may be used to recover metals from an impure feed and/or to extract metals from a metal-oxide. A conventional process (for soluble metal oxides) typically involves dissolving a metal-oxide in an electrolyte followed by electrolytic decomposition or (for insoluble metal oxides) selective electrotransport to reduce the metal-oxide to its corresponding metal. Conventional electrochemical processes for reducing insoluble metal-oxides to their corresponding metallic state may employ a single step or multiple-step approach.
- A multiple-step approach may be a two-step process that utilizes two separate vessels. For example, the extraction of uranium from the uranium oxide of spent nuclear fuels includes an initial step of reducing the uranium oxide with lithium dissolved in a molten LiCl electrolyte so as to produce uranium metal and Li2O in a first vessel, wherein the Li2O remains dissolved in the molten LiCl electrolyte. The process then involves a subsequent step of electrowinning in a second vessel, wherein the dissolved Li2O in the molten LiCl is electrolytically decomposed to form oxygen gas and regenerate lithium. Consequently, the resulting uranium metal may be extracted in an electrorefining process, while the molten LiCl with the regenerated lithium may be recycled for use in the reduction step of another batch.
- However, a multi-step approach involves a number of engineering complexities, such as issues pertaining to the transfer of molten salt and reductant at high temperatures from one vessel to another. Furthermore, the reduction of oxides in molten salts may be thermodynamically constrained depending on the electrolyte-reductant system. In particular, this thermodynamic constraint will limit the amount of oxides that can be reduced in a given batch. As a result, more frequent transfers of molten electrolyte and reductant will be needed to meet production requirements.
- On the other hand, a single-step approach generally involves immersing a metal oxide in a compatible molten electrolyte together with a cathode and anode. By charging the anode and cathode, the metal oxide (which is in electrical contact with the cathode) can be reduced to its corresponding metal through electrolytic conversion and ion exchange through the molten electrolyte. However, although a conventional single-step approach may be less complex than a multi-step approach, the yield of the metallic product is relatively low. Furthermore, the metallic product still contains unwanted impurities.
- A bus bar electrical feedthrough for an electrorefiner system may include a retaining plate, an electrical isolator, and/or a contact block. The retaining plate may include a central opening. The electrical isolator may include a top portion, a base portion, and a slot extending through the top and base portions. The top portion of the electrical isolator may be configured to extend through the central opening of the retaining plate. The contact block may include an upper section, a lower section, and a ridge separating the upper and lower sections. The upper section of the contact block may be configured to extend through the slot of the electrical isolator and the central opening of the retaining plate.
- The various features and advantages of the non-limiting embodiments herein may become more apparent upon review of the detailed description in conjunction with the accompanying drawings. The accompanying drawings are merely provided for illustrative purposes and should not be interpreted to limit the scope of the claims. The accompanying drawings are not to be considered as drawn to scale unless explicitly noted. For purposes of clarity, various dimensions of the drawings may have been exaggerated.
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FIG. 1 is a perspective view of an electrorefiner system including an electrical feedthrough according to a non-limiting embodiment of the present invention. -
FIG. 2 is a cross-sectional side view of an electrorefiner system including an electrical feedthrough according to a non-limiting embodiment of the present invention. -
FIG. 3 is a perspective view of a plurality of cathode assemblies connected to a common bus bar and an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention. -
FIG. 4 is an exploded view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention. -
FIG. 5 is a partial top view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention. -
FIG. 6 is a partial side view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention. -
FIG. 7 is a partial bottom view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention. -
FIG. 8 is a cross-sectional end view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention. - It should be understood that when an element or layer is referred to as being “on,” “connected to,” “coupled to,” or “covering” another element or layer, it may be directly on, connected to, coupled to, or covering the other element or layer or intervening elements or layers may be present. In contrast, when an element is referred to as being “directly on,” “directly connected to,” or “directly coupled to” another element or layer, there are no intervening elements or layers present. Like numbers refer to like elements throughout the specification. As used herein, the term in “and/or” includes any and all combinations of one or more of the associated listed items.
- It should be understood that, although the terms first, second, third, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers, and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer, or section from another region, layer, or section. Thus, a first element, component, region, layer, or section discussed below could be termed a second element, component, region, layer, or section without departing from the teachings of example embodiments.
- Spatially relative terms (e.g., “beneath,” “below,” “lower,” “above,” “upper,” and the like) may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. It should be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below” or “beneath” other elements or features would then be oriented “above” the other elements or features. Thus, the term “below” may encompass both an orientation of above and below. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
- The terminology used herein is for the purpose of describing various embodiments only and is not intended to be limiting of example embodiments. As used herein, the singular forms “a,” “an,” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “includes,” “including,” “comprises,” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
- Example embodiments are described herein with reference to cross-sectional illustrations that are schematic illustrations of idealized embodiments (and intermediate structures) of example embodiments. As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, example embodiments should not be construed as limited to the shapes of regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. For example, an implanted region illustrated as a rectangle will, typically, have rounded or curved features and/or a gradient of implant concentration at its edges rather than a binary change from implanted to non-implanted region. Likewise, a buried region formed by implantation may result in some implantation in the region between the buried region and the surface through which the implantation takes place. Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the actual shape of a region of a device and are not intended to limit the scope of example embodiments.
- Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which example embodiments belong. It will be further understood that terms, including those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
- An electrorefiner system according to a non-limiting embodiment of the present invention may be used to recover a purified metal (e.g., uranium) from a relatively impure nuclear feed material (e.g., impure uranium feed material). The electrorefiner system may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000252/US, GE Ref. 24NS250931, filed on even date herewith, titled “ELECTROREFINER SYSTEM FOR RECOVERING PURIFIED METAL FROM IMPURE NUCLEAR FEED MATERIAL,” the entire contents of which are incorporated herein by reference. The impure nuclear feed material may be a metallic product of an electrolytic oxide reduction system. The electrolytic oxide reduction system may be configured to facilitate the reduction of an oxide to its metallic form so as to permit the subsequent recovery of the metal. The electrolytic oxide reduction system may be as described in U.S. application Ser. No. 12/978,027, filed Dec. 23, 2010, “ELECTROLYTIC OXIDE REDUCTION SYSTEM,” HDP Ref.: 8564-000228/US, GE Ref.: 24AR246140, the entire contents of which is incorporated herein by reference.
- Generally, the electrorefiner system may include a vessel, a plurality of cathode assemblies, a plurality of anode assemblies, a power system, a scraper, and/or a conveyor system. The power system may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000254/US, GE Ref. 24AR252783, filed on even date herewith, titled “CATHODE POWER DISTRIBUTION SYSTEM AND METHOD OF USING THE SAME FOR POWER DISTRIBUTION,” the entire contents of which are incorporated herein by reference. The scraper may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000255/US, GE Ref. 24AR252787, filed on even date herewith, titled “CATHODE SCRAPER SYSTEM AND METHOD OF USING THE SAME FOR REMOVING URANIUM,” the entire contents of which are incorporated herein by reference. The conveyor system may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000260/US, GE Ref. 24AR256355, filed on even date herewith, titled “CONTINUOUS RECOVERY SYSTEM FOR ELECTROREFINER SYSTEM,” the entire contents of which are incorporated herein by reference. However, it should be understood that the electrorefiner system is not limited thereto and may include other components that may not have been specifically identified herein. Furthermore, the electrorefiner system and/or electrolytic oxide reduction system may be used to perform a method for corium and used nuclear fuel stabilization processing. The method may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000262/US, GE Ref. 24AR253193, filed on MM/DD/YYYY, titled “METHOD FOR CORIUM AND USED NUCLEAR FUEL STABILIZATION PROCESSING,” the entire contents of which are incorporated herein by reference. A table of the incorporated applications being filed on even date herewith is provided below.
-
Related Applications Incorporated by Reference U.S. Appl. No. HDP/GE Ref. Filing Date Title XX/XXX,XXX 8564-000252/US Filed on even ELECTROREFINER 24NS250931 date SYSTEM FOR herewith RECOVERING PURIFIED METAL FROM IMPURE NUCLEAR FEED MATERIAL XX/XXX,XXX 8564-000254/US Filed on even CATHODE POWER 24AR252783 date DISTRIBUTION SYSTEM herewith AND METHOD OF USING THE SAME FOR POWER DISTRIBUTION XX/XXX,XXX 8564-000255/US Filed on even CATHODE SCRAPER 24AR252787 date SYSTEM AND METHOD herewith OF USING THE SAME FOR REMOVING URANIUM XX/XXX,XXX 8564-000260/US Filed on even CONTINUOUS 24AR256355 date RECOVERY SYSTEM herewith FOR ELECTROREFINER SYSTEM XX/XXX,XXX 8564-000262/US Filed on METHOD FOR CORIUM 24AR253193 MM/DD/YY AND USED NUCLEAR FUEL STABILIZATION PROCESSING - As noted above, the impure nuclear feed material for the electrorefiner system may be a metallic product of an electrolytic oxide reduction system. During the operation of an electrolytic oxide reduction system, a plurality of anode and cathode assemblies are immersed in a molten salt electrolyte. In a non-limiting embodiment of the electrolytic oxide reduction system, the molten salt electrolyte may be lithium chloride (LiCl). The molten salt electrolyte may be maintained at a temperature of about 650° C. (+50° C., −30° C.). An electrochemical process is carried out such that a reducing potential is generated at the cathode assemblies, which contain the oxide feed material (e.g., metal oxide). Under the influence of the reducing potential, the metal ion of the metal oxide is reduced to metal and the oxygen (O) from the metal oxide (MO) feed material dissolves into the molten salt electrolyte as an oxide ion, thereby leaving the metal (M) behind in the cathode assemblies. The cathode reaction may be as follows:
-
MO+2e−→M+O2− - At the anode assemblies, the oxide ion is converted to oxygen gas. The anode shroud of each of the anode assemblies may be used to dilute, cool, and remove the oxygen gas from the electrolytic oxide reduction system during the process. The anode reaction may be as follows:
-
O2−→ 1/20O2+2e− - The metal oxide may be uranium dioxide (UO2), and the reduction product may be uranium metal. However, it should be understood that other types of oxides may also be reduced to their corresponding metals with the electrolytic oxide reduction system. Similarly, the molten salt electrolyte used in the electrolytic oxide reduction system is not particularly limited thereto and may vary depending of the oxide feed material to be reduced.
- After the electrolytic oxide reduction, the basket containing the metallic product in the electrolytic oxide reduction system is transferred to the electrorefiner system according to the present invention for further processing to obtain a purified metal from the metallic product. Stated more clearly, the metallic product from the electrolytic oxide reduction system will serve as the impure nuclear feed material for the electrorefiner system according to the present invention. Notably, while the basket containing the metallic product is a cathode assembly in the electrolytic oxide reduction system, the basket containing the metallic product is an anode assembly in the electrorefiner system. Compared to prior art apparatuses, the electrorefiner system according to the present invention allows for a significantly greater yield of purified metal.
-
FIG. 1 is a perspective view of an electrorefiner system including an electrical feedthrough according to a non-limiting embodiment of the present invention.FIG. 2 is a cross-sectional side view of an electrorefiner system including an electrical feedthrough according to a non-limiting embodiment of the present invention. - Referring to
FIGS. 1-2 , theelectrorefiner system 100 includes avessel 102, a plurality ofcathode assemblies 104, a plurality ofanode assemblies 108, a power system, ascraper 110, and/or aconveyor system 112. Each of the plurality ofcathode assemblies 104 may include a plurality ofcathode rods 106. The power system may include anelectrical feedthrough 132 that extends through thefloor structure 134. Thefloor structure 134 may be a glovebox floor in a glovebox. Alternatively, thefloor structure 134 may be a support plate in a hot-cell facility. Theconveyor system 112 may include aninlet pipe 113, atrough 116, a chain, a plurality of flights, anexit pipe 114, and/or adischarge chute 128. - The
vessel 102 is configured to maintain a molten salt electrolyte. In a non-limiting embodiment, the molten salt electrolyte may be LiCl, a LiCl-KCl eutectic, or another suitable medium. Thevessel 102 may be situated such that a majority of thevessel 102 is below thefloor structure 134. For instance, an upper portion of thevessel 102 may extend above thefloor structure 134 through an opening in thefloor structure 134. The opening in thefloor structure 134 may correspond to the dimensions of thevessel 102. Thevessel 102 is configured to receive the plurality ofcathode assemblies 104 and the plurality ofanode assemblies 108. - The plurality of
cathode assemblies 104 are configured to extend into thevessel 102 so as to at least be partially submerged in the molten salt electrolyte. For instance, the dimensions of the plurality ofcathode assemblies 104 and/or thevessel 102 may be adjusted such that the majority of the length of the plurality ofcathode assemblies 104 is submerged in the molten salt electrolyte in thevessel 102. Eachcathode assembly 104 may include a plurality ofcathode rods 106 having the same orientation and arranged so as to be within the same plane. - The plurality of
anode assemblies 108 may be alternately arranged with the plurality ofcathode assemblies 104 such that each anode.assembly 108 is flanked by twocathode assemblies 104. The plurality ofcathode assemblies 104 andanode assemblies 108 may be arranged in parallel. Eachanode assembly 108 may be configured to hold and immerse an impure uranium feed material in the molten salt electrolyte maintained by thevessel 102. The dimensions of the plurality ofanode assemblies 108 and/or thevessel 102 may be adjusted such that the majority of the length of the plurality ofanode assemblies 108 is submerged in the molten salt electrolyte in thevessel 102. Although theelectrorefiner system 100 is illustrated inFIGS. 1-2 as having elevencathode assemblies 104 and tenanode assemblies 108, it should be understood that the example embodiments herein are not limited thereto. - In the
electrorefiner system 100, a power system is connected to the plurality ofcathode assemblies 104 andanode assemblies 108. As previously noted above, in addition to the disclosure herein, the power system may be as described in U.S. application Ser. No. ______, HDP Ref. 8564-000254/US, GE Ref. 24AR252783, filed on even date herewith, titled “CATHODE POWER DISTRIBUTION SYSTEM AND METHOD OF USING THE SAME FOR POWER DISTRIBUTION,” the entire contents of which are incorporated herein by reference. - For instance, the plurality of
cathode assemblies 104 may be connected to acommon bus bar 118, and thecommon bus bar 118 may be connected to anelectrical feedthrough 132 that extends through thefloor structure 134. Theelectrical feedthrough 132 allows power to be supplied to thecommon bus bar 118 without loss of atmosphere containment of the hermetically sealed glovebox or hot-cell facility. During operation of theelectrorefiner system 100, the power system is configured to supply a voltage adequate to oxidize the impure uranium feed material in the plurality ofanode assemblies 108 to form uranium ions that migrate through the molten salt electrolyte and deposit on the plurality ofcathode rods 106 of the plurality ofcathode assemblies 104 as purified uranium. - To initiate the removal of the purified uranium, the
scraper 110 is configured to move up and down along the length of the plurality ofcathode rods 106 to dislodge the purified uranium deposited on the plurality ofcathode rods 106 of the plurality ofcathode assemblies 104. As a result of the scraping, the dislodged purified uranium sinks through the molten salt electrolyte to the bottom of thevessel 102. - The
conveyor system 112 is configured such that at least a portion of it is disposed at the bottom of thevessel 102. For example, thetrough 116 of theconveyor system 112 may be disposed at the bottom of thevessel 102 such that the purified uranium dislodged from the plurality ofcathode rods 106 accumulates in thetrough 116. Theconveyor system 112 is configured to transport the purified uranium accumulated in thetrough 116 through anexit pipe 114 to adischarge chute 128 so as to remove the purified uranium from thevessel 102. -
FIG. 3 is a perspective view of a plurality of cathode assemblies connected to a common bus bar and an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention. Referring toFIG. 3 , each of the plurality ofcathode assemblies 104 includes a plurality ofcathode rods 106. Although the plurality ofcathode assemblies 104 are shown as having sevencathode rods 106 each, it should be understood that the example embodiments are not limited thereto. Thus, eachcathode assembly 104 may include less than sevencathode rods 106 or more than sevencathode rods 106, provided that sufficient current is being provided to theelectrorefiner system 100. The plurality ofcathode assemblies 104 are connected to acommon bus bar 118. When positioned within thevessel 102 of theelectrorefiner system 100, the plurality ofcathode assemblies 104 may be arranged parallel to each other and perpendicularly to thecommon bus bar 118. Thecommon bus bar 118 is connected to anelectrical feedthrough 132. As a result, power may be supplied to thecommon bus bar 118 through thefloor structure 134 via theelectrical feedthrough 132 without compromising the quality of the atmosphere inside the glovebox or hot-cell facility. -
FIG. 4 is an exploded view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.FIG. 5 is a partial top view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.FIG. 6 is a partial side view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.FIG. 7 is a partial bottom view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention.FIG. 8 is a cross-sectional end view of an electrical feedthrough of an electrorefiner system according to a non-limiting embodiment of the present invention. - Referring to
FIGS. 4-8 , an electrical feedthrough 132 (also referred to as a bus bar electrical feedthrough) may include a retainingplate 200, anelectrical isolator 204, and acontact block 212. The retainingplate 200,electrical isolator 204, and contact block 212 are designed to be united to form a single structural unit that is clamped onto afloor structure 134. - The retaining
plate 200 includes acentral opening 202. Theelectrical isolator 204 includes atop portion 206, abase portion 208, and aslot 210 extending through the top 206 andbase portions 208. Thetop portion 206 of theelectrical isolator 204 is configured to extend through thecentral opening 202 of the retainingplate 200. Thecontact block 212 includes anupper section 214, alower section 216, and aridge 218 separating the upper 214 andlower sections 216. Theupper section 214 of thecontact block 212 is configured to extend through theslot 210 of theelectrical isolator 204 and thecentral opening 202 of the retainingplate 200. - The
upper section 214 of thecontact block 212 is configured for connection with one or more bus bars. For example, theupper section 214 of thecontact block 212 may be connected to thecommon bus bar 118. To facilitate the connection, a plurality of connection holes are provided in theupper section 214 of thecontact block 212. Although theupper section 214 of thecontact block 212 is shown as having three connection holes, it should be understood that the example embodiments are not limited thereto. - The
lower section 216 of thecontact block 212 is configured for connection with one or more current supply cables. For example, thelower section 216 of thecontact block 212 may be connected to thecurrent supply cables 220. To facilitate the connection, a plurality of connection holes are provided in thelower section 216 of thecontact block 212. Although thelower section 216 of thecontact block 212 is shown as having three connection holes, it should be understood that the example embodiments are not limited thereto. - The retaining
plate 200 may have a plurality of threaded holes surrounding thecentral opening 202, and theelectrical isolator 204 may have a plurality of blind threaded holes in thebase portion 208 surrounding thetop portion 206. The plurality of threaded holes of the retainingplate 200 may be aligned with the plurality of blind threaded holes of theelectrical isolator 204. As a result, when mounted so as to sandwich thefloor structure 134, the retainingplate 200 may be secured to the electrical isolator 204 (with thefloor structure 134 in between) with a plurality of screws. Thecontact block 212 also includes a plurality of threaded holes in theridge 218 surrounding theupper section 214. The plurality of threaded holes of thecontact block 212 allows thecontact block 212 to be secured to theelectrical isolator 204 with a plurality of screws. - The retaining
plate 200 may be formed of a metal. Theelectrical isolator 204 may be formed of a plastic. For example, the plastic may be polyetherketone. Thecontact block 212 may be formed of copper. In a non-limiting embodiment, the copper may be silver plated. - The retaining
plate 200 and theelectrical isolator 204 are configured to clamp thefloor structure 134 in between. Thus, when theelectrical feedthrough 132 is properly installed, the retainingplate 200 will be on one surface of thefloor structure 134. Additionally, thebase portion 208 of theelectrical isolator 204 will be pressed against the opposing surface of thefloor structure 134, while thetop portion 206 of theelectrical isolator 204 extends through thefloor structure 134 and thecentral opening 202 of the retainingplate 200. Furthermore, theridge 218 of thecontact block 212 will be pressed against the underside of thebase portion 208 of theelectrical isolator 204, while theupper section 214 of thecontact block 212 extends through theelectrical isolator 204, thefloor structure 134, and the retainingplate 200 such that an exposed terminal portion of theupper section 214 of thecontact block 212 protrudes from theslot 210 of theelectrical isolator 204. - The
electrical feedthrough 132 may further include at least one o-ring between the retainingplate 200 and theelectrical isolator 204. Theelectrical feedthrough 132 may also further include an o-ring between theelectrical isolator 204 and theridge 218 of thecontact block 212. - The
electrical feedthrough 132 is configured to allow thecontact block 212 to be removed and replaced (e.g., because of damage) without compromising the quality of the atmosphere inside the glovebox or hot-cell facility. For instance, theelectrical feedthrough 132 may further include a cap configured to attach to thetop portion 206 of theelectrical isolator 204 so as to allow a removal of thecontact block 212 without compromising an atmosphere of a hermetically-sealed glovebox or hot-cell facility. A plurality of threaded holes (FIG. 4 ) may be provided in the upper face of thetop portion 206 surrounding theslot 210 to allow the cap to be secured to theelectrical isolator 204. Thus, when the cap is secured to the upper face of thetop portion 206 of the electrical isolator, thecontact block 212 may be removed and repaired (or replaced) without compromising the atmosphere of the hermatically-sealed glovebox or hot-cell facility. - A method of electrorefining according to a non-limiting embodiment of the present invention may involve electrolytically processing a suitable feed material with the above-discussed electrorefiner system. As a result, the method may be used to recycle used nuclear fuel or recover a metal (e.g., uranium) from an off-specification metal oxide (e.g., uranium dioxide). Furthermore, as a result of the bus bar electrical feedthrough, relatively high electrical currents may be transferred into a glovebox or hot-cell facility at a relatively low cost and higher amperage capacity without sacrificing atmosphere integrity.
- While a number of example embodiments have been disclosed herein, it should be understood that other variations may be possible. Such variations are not to be regarded as a departure from the spirit and scope of the present disclosure, and all such modifications as would be obvious to one skilled in the art are intended to be included within the scope of the following claims.
Claims (12)
Priority Applications (5)
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|---|---|---|---|
| US13/335,139 US8598473B2 (en) | 2011-12-22 | 2011-12-22 | Bus bar electrical feedthrough for electrorefiner system |
| KR1020147016809A KR101925048B1 (en) | 2011-12-22 | 2012-10-04 | Bus bar electrical feedthrough for electrorefiner system |
| JP2014549038A JP6043364B2 (en) | 2011-12-22 | 2012-10-04 | Bus bar electric feedthrough for electric refining system |
| EP12844661.4A EP2794959B1 (en) | 2011-12-22 | 2012-10-04 | Bus bar electrical feedthrough for electrorefiner system |
| PCT/US2012/058663 WO2013112210A2 (en) | 2011-12-22 | 2012-10-04 | Bus bar electrical feedthrough for electrorefiner system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/335,139 US8598473B2 (en) | 2011-12-22 | 2011-12-22 | Bus bar electrical feedthrough for electrorefiner system |
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| US20130161091A1 true US20130161091A1 (en) | 2013-06-27 |
| US8598473B2 US8598473B2 (en) | 2013-12-03 |
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| US (1) | US8598473B2 (en) |
| EP (1) | EP2794959B1 (en) |
| JP (1) | JP6043364B2 (en) |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103334123A (en) * | 2013-07-24 | 2013-10-02 | 阳谷祥光铜业有限公司 | Copper electrolysis system and running method |
| CN108505072A (en) * | 2018-04-03 | 2018-09-07 | 金川集团股份有限公司 | A kind of annular totally-enclosed button Winning cell |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8945354B2 (en) | 2011-12-22 | 2015-02-03 | Ge-Hitachi Nuclear Energy Americas Llc | Cathode scraper system and method of using the same for removing uranium |
| CN110528030B (en) * | 2019-09-17 | 2020-12-08 | 益阳鸿源稀土有限责任公司 | A rare earth electrolysis device |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7449635B2 (en) * | 2006-03-06 | 2008-11-11 | Siemens Energy & Automation, Inc. | Bus joint assembly |
| US7563982B2 (en) * | 2006-11-30 | 2009-07-21 | Continental Automotive Systems Us, Inc. | Bus bar assembly |
Family Cites Families (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US422139A (en) | 1890-02-25 | Daniel m | ||
| GB284678A (en) | 1927-02-03 | 1928-11-29 | Paul Leon Hulin | |
| US2089738A (en) | 1935-08-10 | 1937-08-10 | Redler Conveyor Co | Conveyer |
| US2194444A (en) | 1937-07-06 | 1940-03-19 | Du Pont | Fused salt electrolysis cell |
| GB506590A (en) | 1937-11-29 | 1939-05-30 | George William Johnson | Improvements in the electrolytic manufacture and production of zinc dust |
| US2800219A (en) | 1954-09-30 | 1957-07-23 | Ance E Carroll | Conveyor for handling pulverized uranium |
| US3562131A (en) | 1968-03-21 | 1971-02-09 | Bunker Hill Co | Cathode handling equipment |
| US3697404A (en) | 1971-01-29 | 1972-10-10 | Peter M Paige | Apparatus to support the electrodes and bus bars in an electrolytic cell |
| CA1034533A (en) * | 1974-11-28 | 1978-07-11 | Ronald N. Honey | Contact bar for electrolytic cells |
| GB1476055A (en) | 1975-03-05 | 1977-06-10 | Imp Metal Ind Kynoch Ltd | Eletro-winning metals |
| DE2600344A1 (en) | 1976-01-07 | 1977-07-14 | H T Hydrotechnik Gmbh | Water electrolyser cell stack - using thin walled channel frame with web strips supporting channel flanges |
| US4013329A (en) | 1976-02-23 | 1977-03-22 | Multilam Corporation | Multiple plate assembly for forming electrical connector or switch |
| US4073703A (en) | 1976-12-14 | 1978-02-14 | Aluminum Company Of America | Electrolytic production of magnesium |
| DE2728634C2 (en) | 1977-06-24 | 1979-03-08 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Ultrasonic solder bath with a sonotrode arranged with a solder bath container |
| CA1142123A (en) | 1980-01-31 | 1983-03-01 | Hugh D. Kelley | Conveyor for handling free-flowing material |
| US4492621A (en) | 1982-09-29 | 1985-01-08 | Stubb Paul R | Method and apparatus for electrodeposition of materials |
| US4668353A (en) | 1984-10-10 | 1987-05-26 | Desom Engineered Systems Limited | Method and apparatus for acid mist reduction |
| EP0286092B1 (en) | 1987-04-10 | 1993-01-07 | Mitsubishi Materials Corporation | Apparatus for hanging and handling plate members |
| US4880506A (en) | 1987-11-05 | 1989-11-14 | The United States Of America As Represented By The Department Of Energy | Electrorefining process and apparatus for recovery of uranium and a mixture of uranium and plutonium from spent fuels |
| US4863580A (en) | 1988-08-10 | 1989-09-05 | Epner R L | Waste metal extraction apparatus |
| US5279715A (en) | 1991-09-17 | 1994-01-18 | Aluminum Company Of America | Process and apparatus for low temperature electrolysis of oxides |
| JP3074919B2 (en) | 1992-03-31 | 2000-08-07 | 三菱マテリアル株式会社 | Cathode scraper driving device in electrolytic cell |
| US5454914A (en) | 1993-12-23 | 1995-10-03 | The United States Of America As Represented By The United States Department Of Energy | Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing |
| JPH07316894A (en) * | 1994-05-20 | 1995-12-05 | Toyo Tanso Kk | Connecting appliance of electrode for electrolysis |
| US5531868A (en) | 1994-07-06 | 1996-07-02 | The United States Of America As Represented By The United States Department Of Energy | Advanced electrorefiner design |
| DE29505938U1 (en) | 1995-04-06 | 1996-08-08 | Stocko Metallwarenfab Henkels | Electrical contact element and plastic housing for receiving the contact element |
| AU703999B2 (en) | 1995-04-21 | 1999-04-01 | Alcan International Limited | Multi-polar cell for the recovery of a metal by electrolysis of a molten electrolyte |
| US5582706A (en) | 1995-06-02 | 1996-12-10 | Rockwell International Corporation | Electroseparation of actinide and rare earth metals |
| US5770034A (en) | 1995-07-15 | 1998-06-23 | Agfa-Gevaert N.V. | Process and apparatus for desilvering a silver-containing solution |
| JPH0972991A (en) | 1995-09-05 | 1997-03-18 | Ishikawajima Harima Heavy Ind Co Ltd | Electrolytic separation device and electrolytic separation method for actinide element and lanthanoid element |
| FR2738661B1 (en) | 1995-09-11 | 1997-11-28 | Framatome Sa | DEVICE AND METHOD FOR RECOVERING AND COOLING THE FUSED HEART OF A NUCLEAR REACTOR |
| DE19845258C1 (en) | 1998-10-01 | 2000-03-16 | Hamburger Aluminium Werk Gmbh | Installation for sucking away waste gases and using their heat for aluminum multi cell electrolysis plant comprises waste gas collector hoods and suction ducts for each electrolysis cell of the plant |
| FI107941B (en) | 1999-06-10 | 2001-10-31 | Outokumpu Oy | Apparatus for transferring electrodes in electrolytic refining of metals |
| NO20010927D0 (en) | 2001-02-23 | 2001-02-23 | Norsk Hydro As | Method and apparatus for making metal |
| US6827828B2 (en) | 2001-03-29 | 2004-12-07 | Honeywell International Inc. | Mixed metal materials |
| US6689260B1 (en) | 2001-08-29 | 2004-02-10 | The United States Of America As Represented By The United States Department Of Energy | Nuclear fuel electrorefiner |
| US6540902B1 (en) | 2001-09-05 | 2003-04-01 | The United States Of America As Represented By The United States Department Of Energy | Direct electrochemical reduction of metal-oxides |
| US6866768B2 (en) | 2002-07-16 | 2005-03-15 | Donald R Bradford | Electrolytic cell for production of aluminum from alumina |
| NO318164B1 (en) | 2002-08-23 | 2005-02-07 | Norsk Hydro As | Method for electrolytic production of aluminum metal from an electrolyte and use of the same. |
| US6911134B2 (en) | 2002-09-06 | 2005-06-28 | The University Of Chicago | Three-electrode metal oxide reduction cell |
| AU2003275505A1 (en) | 2002-10-04 | 2004-04-23 | Michael John Sole | Electowinning of metals |
| US20040134785A1 (en) | 2003-01-09 | 2004-07-15 | The University Of Chicago | Advanced high-throughput electrorefiner design |
| TWI322198B (en) | 2003-01-22 | 2010-03-21 | Toyo Tanso Co | Electrolytic apparatus for molten salt |
| KR100593790B1 (en) | 2003-03-28 | 2006-07-03 | 한국원자력연구소 | A method for producing a nuclear fuel metal from an oxide fuel using a LiC-20-Ly₂O molten salt system, a reduction electrode for implementing the method, and a reduction apparatus including the reduction electrode |
| JP3913725B2 (en) | 2003-09-30 | 2007-05-09 | 日鉱金属株式会社 | High purity electrolytic copper and manufacturing method thereof |
| WO2005035404A1 (en) | 2003-10-14 | 2005-04-21 | Raijmakers Leon Fatima Peter H | Scraper conveyor |
| US7267754B1 (en) | 2004-01-21 | 2007-09-11 | U.S. Department Of Energy | Porous membrane electrochemical cell for uranium and transuranic recovery from molten salt electrolyte |
| DE102004018554B4 (en) | 2004-04-14 | 2018-09-27 | Wago Verwaltungsgesellschaft Mbh | Jumper for electrical terminals |
| WO2006007863A1 (en) | 2004-07-16 | 2006-01-26 | Cathingots Limited | Electrolysis apparatus with solid electrolyte electrodes |
| DE202004018757U1 (en) | 2004-12-04 | 2006-04-13 | Weidmüller Interface GmbH & Co. KG | Device for the electrical bridging of two busbars |
| JP2008533309A (en) | 2005-03-24 | 2008-08-21 | ビーエイチピー ビリトン イノベーション ピーティーワイ エルティーディー | Anode support device |
| JP4504247B2 (en) | 2005-04-28 | 2010-07-14 | 株式会社東芝 | Minor actinide recycling method |
| US7638026B1 (en) | 2005-08-24 | 2009-12-29 | The United States Of America As Represented By The United States Department Of Energy | Uranium dioxide electrolysis |
| DE102006062206B4 (en) | 2006-12-22 | 2011-06-16 | Minebea Co., Ltd. | Fluid dynamic bearing with axial preload |
| US7744734B2 (en) | 2007-08-24 | 2010-06-29 | Battelle Energy Alliance, Llc | High current density cathode for electrorefining in molten electrolyte |
| US7993501B2 (en) | 2007-11-07 | 2011-08-09 | Freeport-Mcmoran Corporation | Double contact bar insulator assembly for electrowinning of a metal and methods of use thereof |
| CN101453071B (en) | 2007-11-28 | 2013-05-08 | 李世煌 | Conductive body for electric power plug, socket and socket connector with conductive material improved |
| US8097142B2 (en) | 2008-02-29 | 2012-01-17 | Uchicago Argonne, Llc. | High-throughput electrorefiner for recovery of U and U/TRU product from spent fuel |
| WO2010080761A1 (en) | 2009-01-06 | 2010-07-15 | Epner R L | System for electrolytic recovery of metals with improved connection interface |
| US7980384B2 (en) | 2009-04-30 | 2011-07-19 | Hapman, Inc. | Tensioning device for drag conveyor |
| KR100958725B1 (en) | 2009-08-21 | 2010-05-18 | (주)동신이에이 | Bus bar connecting clamp for distribution board |
-
2011
- 2011-12-22 US US13/335,139 patent/US8598473B2/en active Active - Reinstated
-
2012
- 2012-10-04 JP JP2014549038A patent/JP6043364B2/en active Active
- 2012-10-04 EP EP12844661.4A patent/EP2794959B1/en active Active
- 2012-10-04 WO PCT/US2012/058663 patent/WO2013112210A2/en not_active Ceased
- 2012-10-04 KR KR1020147016809A patent/KR101925048B1/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7449635B2 (en) * | 2006-03-06 | 2008-11-11 | Siemens Energy & Automation, Inc. | Bus joint assembly |
| US7563982B2 (en) * | 2006-11-30 | 2009-07-21 | Continental Automotive Systems Us, Inc. | Bus bar assembly |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103334123A (en) * | 2013-07-24 | 2013-10-02 | 阳谷祥光铜业有限公司 | Copper electrolysis system and running method |
| CN108505072A (en) * | 2018-04-03 | 2018-09-07 | 金川集团股份有限公司 | A kind of annular totally-enclosed button Winning cell |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2794959B1 (en) | 2019-06-12 |
| JP2015503036A (en) | 2015-01-29 |
| WO2013112210A3 (en) | 2013-10-17 |
| KR20140108232A (en) | 2014-09-05 |
| EP2794959A2 (en) | 2014-10-29 |
| WO2013112210A2 (en) | 2013-08-01 |
| JP6043364B2 (en) | 2016-12-14 |
| US8598473B2 (en) | 2013-12-03 |
| KR101925048B1 (en) | 2018-12-04 |
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