US20080061359A1 - Dual charge storage node with undercut gate oxide for deep sub-micron memory cell - Google Patents
Dual charge storage node with undercut gate oxide for deep sub-micron memory cell Download PDFInfo
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/30—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
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- H—ELECTRICITY
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- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/30—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/68—Floating-gate IGFETs
- H10D30/681—Floating-gate IGFETs having only two programming levels
- H10D30/684—Floating-gate IGFETs having only two programming levels programmed by hot carrier injection
- H10D30/685—Floating-gate IGFETs having only two programming levels programmed by hot carrier injection from the channel
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/68—Floating-gate IGFETs
- H10D30/687—Floating-gate IGFETs having more than two programming levels
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/68—Floating-gate IGFETs
- H10D30/6891—Floating-gate IGFETs characterised by the shapes, relative sizes or dispositions of the floating gate electrode
- H10D30/6893—Floating-gate IGFETs characterised by the shapes, relative sizes or dispositions of the floating gate electrode wherein the floating gate has multiple non-connected parts, e.g. multi-particle floating gate
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- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/69—IGFETs having charge trapping gate insulators, e.g. MNOS transistors
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/69—IGFETs having charge trapping gate insulators, e.g. MNOS transistors
- H10D30/691—IGFETs having charge trapping gate insulators, e.g. MNOS transistors having more than two programming levels
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/69—IGFETs having charge trapping gate insulators, e.g. MNOS transistors
- H10D30/694—IGFETs having charge trapping gate insulators, e.g. MNOS transistors characterised by the shapes, relative sizes or dispositions of the gate electrodes
- H10D30/697—IGFETs having charge trapping gate insulators, e.g. MNOS transistors characterised by the shapes, relative sizes or dispositions of the gate electrodes having trapping at multiple separated sites, e.g. multi-particles trapping sites
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/031—Manufacture or treatment of data-storage electrodes
- H10D64/035—Manufacture or treatment of data-storage electrodes comprising conductor-insulator-conductor-insulator-semiconductor structures
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- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/031—Manufacture or treatment of data-storage electrodes
- H10D64/037—Manufacture or treatment of data-storage electrodes comprising charge-trapping insulators
Definitions
- Embodiments of the present invention generally relate to the field of semiconductor devices. More particularly, embodiments relate to memory storage cells.
- dual bit memory cells such as those employing MirrorBit® technology developed by Spansion, Inc.
- dual bit memory cells double the intrinsic density of a flash memory array by storing two physically distinct bits on opposite sides of a memory cell. Ideally, reading or programming one side of a memory cell occurs independently of whatever data is stored on the opposite side of the cell.
- FIG. 1A illustrates a conventional dual-bit memory cell 100 .
- Conventional dual bit memory cell 100 typically includes a substrate 110 with source/drain regions 120 implanted therein, a first oxide layer 130 above the substrate 110 , a continuous charge trapping layer 140 , a second oxide layer 150 , and a poly layer 160 .
- the bottom oxide layer 130 is also commonly referred to as a tunnel oxide layer.
- Hot electron injection involves applying appropriate voltage potentials to the gate, source, and drain of the cell 100 for a specified duration until the charge trapping layer 140 accumulates charge. While for simplicity, charge is typically thought of as being stored in a fixed location (i.e., the edges) of charge trapping layer 140 , in reality the location of the trapped charge for each node falls under a probability curve, such as curves 170 and 175 .
- the bit associated with curve 170 shall be referred to as the “normal bit” and the bit associated with curve 175 shall be referred to as the “complementary bit”. It should be appreciated from FIG. 1A that the memory cell 100 illustrated therein is reasonably large, such that the two sides can be fairly localized and well separated.
- FIG. 1B illustrates a conventional dual bit memory cell 105 having a smaller process geometry than the memory cell 100 of FIG. 1A .
- FIG. 1B illustrates that as the cell gets smaller, the distribution curves 170 and 175 stay the same, resulting in an overlap of the curves 170 and 175 . Such an overlap in these regions can result in the contamination of one bit by its neighboring bit. This is also known as complementary bit disturb.
- FIG. 2 graphically illustrates complementary bit disturb in a conventional memory cell having a continuous charge trapping layer.
- FIG. 2 illustrates the example of when the normal bit has been programmed, but the complement your bit has not. In such a case, the normal bit should read “0” and the complementary bit should read “1”. Whether or not a bit is programmed is reflected by a delta in the threshold voltage associated with that bit.
- programming of a normal bit also results in a shift of the V t of the complementary bit. For example, in a memory cell having a channel length L 1 , changing the V t of the normal bit by X results in a change of the V t of the complementary bit of Y.
- An embodiment of the present invention is directed to a memory cell.
- the memory cell includes a stack formed over a substrate.
- the stack includes a gate oxide layer and an overlying polycrystalline silicon layer.
- the stack further includes first and second undercut regions formed under the polycrystalline silicon layer and adjacent to the gate oxide layer.
- the memory cell further includes a first charge storage element formed in the first undercut region and a second charge storage element formed in the second undercut region.
- embodiments provide for dual storage node memory cells with physical separation of the storage nodes by an insulator. Such separation of the storage nodes greatly reduces program disturb between the two storage nodes, which is a critical issue as process geometries continue to decrease. As a result, embodiments are able to achieve geometries beyond 100 nm technology.
- FIG. 1A illustrates a conventional dual-bit memory cell.
- FIG. 1B illustrates a conventional dual bit memory cell having a smaller process geometry than the memory cell of FIG. 1A .
- FIG. 2 graphically illustrates complementary bit disturb in a conventional memory cell having a continuous charge trapping layer.
- FIG. 3 illustrates a cross-sectional view of an exemplary semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 4 illustrates selective etching of undercut regions in the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 5 illustrates formation of a tunnel oxide layer on the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 6 illustrates formation of a charge trapping layer on the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 7 illustrates removal of a portion of the charge trapping layer on the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 8 illustrates formation of sidewall spacers on the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 9 illustrates formation of bit lines in the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 10 illustrates oxide filling in the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 11 illustrates removal of hard masks and excess oxide from the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 12 illustrates formation of a polysilicon layer on the semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 13 illustrates a flowchart a process for fabricating a semiconductor memory cell having at least two charge storage elements, in accordance with various embodiments of the present invention.
- FIG. 14 illustrates a flowchart foreign method of forming a charge storage element in an undercut region, in accordance with various embodiments of the present invention.
- FIG. 15 shows a block diagram of a conventional portable telephone, upon which embodiments can be implemented.
- FIG. 16 illustrates advantages of a memory cell according to one embodiment over conventional memory cells designs, with respect to program disturb.
- embodiments reduce the likelihood of program disturb in a dual bit memory cell through physical separation of the charge storage nodes by forming a charge trapping regions in undercut regions of a gate oxide, thereby preventing charge contamination between the storage nodes. Because two separate charge storage regions are used, rather than one continuous charge storage layer, the separate charge storage nodes are insulated from each other.
- FIG. 3 illustrates a cross-sectional view of an exemplary semiconductor device, in accordance with various embodiments of the present invention.
- FIG. 3 shows a substrate 10 after etching an overlying gate oxide layer 12 , polysilicon layer 14 , and a hard mask 16 , to expose surface areas for the fabrication of bit lines.
- the hard mask 16 may be a number of materials, including silicon nitride and the like.
- the gate oxide 12 has a thickness on the order of 20-500 angstroms.
- the polysilicon layer 14 as a thickness on the order of 200-2000 angstroms.
- the gate oxide layer 12 is selectively etched to form first and second undercut regions on either side of the gate oxide layer 12 and under the polysilicon layer 14 .
- the widths of the first and second undercut regions are in the range of 50-500 angstroms.
- the selective etch is performed by a wet etch process.
- the wet edge may be a diluted HF etch, a chemical oxide removal (COR) etch, or the like.
- a tunnel oxide layer 18 is then formed over the substrate 10 and the exposed regions of the polysilicon layer 14 .
- the tunnel oxide layers 18 may be formed in a number of ways.
- the tunnel oxide layer 18 may be formed by growing, by plasma oxidation, by chemical vapor deposition, or the like.
- the tunnel oxide layer 18 is on the order of 10-100 angstroms thick. In other embodiments, other thickness may be used for the tunnel oxide layer 18 . It should be appreciated at this point that the first and second undercut regions now contain two oxide layers separated by empty space.
- a layer of charge trapping material 20 is formed over the tunnel oxide layer 18 .
- the layer of charge trapping material 20 is formed such that it fills the remainder of the first and second undercut regions.
- multiple cycles of partial deposition and partial etch may be performed.
- the charge trapping material 20 may be selected from a number of materials including, but not limited to, silicon nitride (SiN), silicon rich nitride (SiRN), polysilicon, high-K materials, and any combination thereof. It should be appreciated by one of skill in the art that although polysilicon and nitride materials may be used, the properties of the two materials are very different. For example, polysilicon is a conductor, which means that an electron may freely move throughout the material. By contrast, nitrides such as SiN and SiRN are insulators, wherein the location of a given electron stays relatively constant.
- the charge trapping material 20 is then removed, except for the portions in the first and second undercut regions. It should be appreciated that this may be achieved in a number of ways. For example, in one embodiment, the charge trapping material 20 is removed by a dry etch. The charge trapping material 20 may also be removed by a wet etch or any combination of wet and dry etch. In another embodiment, the charge trapping material 20 is carefully oxidized with a well-controlled process such that only the portions of the charge trapping material 20 in the first and second undercut regions remain. The oxidation may be thermal or plasma oxidation, for example. Regardless, the result is two physically isolated charge trapping regions 20 at each memory cell. In other words, the charge trapping regions 20 are insulated from each other by the oxide materials 12 , 18 , 22 .
- the oxide layer 22 is etched to form sidewall spacers 22 around the periphery of the polysilicon layer 14 .
- bit lines are formed in the substrate 10 by ion implantation using the sidewall spacers 22 as masks, as shown in FIG. 9 .
- the gaps above the bit lines 30 and between the sidewall spacers 22 are then filled with silicon oxide 26 , as shown in FIG. 10 .
- the hard masks 16 and any surplus oxide material 26 are removed. In one embodiment, this is achieved by a chemical mechanical processing (CMP) polish. Thereafter, a second polysilicon layer 28 is deposited over the structure, as shown in FIG. 12 .
- the polysilicon layer 28 is on the order of 200-2000 angstroms thick. In other embodiments, other thicknesses of the polysilicon layer 28 may be employed.
- the second polysilicon layer 28 is then selectively masked and etched to form the word lines of the memory array.
- flowcharts 1300 and 1400 each illustrate example fabrication steps used and various embodiments. Although specific steps are disclosed in flowcharts 1300 and 1400 , such steps are examples. That is, embodiments are well suited to using various other steps or variations of the steps recited in flowcharts 1300 and 1400 . It is appreciated that the steps in flowcharts 1300 and 1400 may be performed in an order different than presented, and that not all of the steps in flowcharts 1300 and 1400 may be performed.
- FIG. 13 illustrates a flowchart 1300 a process for fabricating a semiconductor memory cell having at least two charge storage elements, in accordance with various embodiments of the present invention.
- spaced stacks of gate silicon oxide 12 and overlying polycrystalline silicon 14 are formed on the surface of a semiconductor substrate 10 . In one embodiment, this is achieved by forming a layer of gate silicon oxide 12 on the substrate, forming a layer of polycrystalline silicon 14 over the gate silicon oxide 12 , forming masks 16 over portions of the polycrystalline silicon 14 , and etching to expose portions of the substrate 10 .
- undercut regions are formed in the gate silicon oxide 12 . This may be achieved, for example, by a diluted HF etch, a chemical oxide removal (COR), or the like.
- charge storage elements are formed in the undercut regions. It should be appreciated that this may be achieved in a number of ways.
- FIG. 14 illustrates a flowchart 1400 foreign method of forming a charge storage element in an undercut region, in accordance with various embodiments of the present invention.
- a tunnel oxide layer 18 is formed on the substrate 10 on the exposed gate polycrystalline silicon 14 .
- Block 1420 then involves forming a layer of charge trapping material 20 over the tunnel oxide layer 18 sufficient to fill the remainder of the undercut region.
- the charge trapping material 20 may be selected from a number of materials including, but not limited to, silicon nitride (SiN), silicon rich nitride (SiRN), polysilicon, high-K materials, and any combination thereof. In one embodiment, in order to avoid any seam void during the undercut filling, multiple cycles of partial deposition and partial etch may be performed. The charge trapping material 20 is then removed except for portions in the undercut region (block 1430 ). At block 1440 , silicon oxide sidewall spacers 22 are formed on the stacks sufficient to cover any remaining exposed portions of the charge trapping material 20 . This may be achieved, for example, by forming a silicon oxide layer and etching to form the sidewall spacers 22 around the periphery of the polysilicon layer 14 . Thus, using this technology, physically separate and isolated charge storage elements may be created.
- block 1340 involves forming bit lines 30 in the semiconductor substrate 10 .
- this is accomplished by implanting the bit lines 30 while using the sidewall spacers 22 as masks.
- the remaining space between the stacks is then filled with silicon oxide filler 26 (block 1350 ).
- word lines are formed over the silicon oxide filler 26 and the stacks (block 1360 ). This may involve, for example, polishing down the hard masks 16 and portions of the silicon oxide sidewall spacers 22 and the silicon oxide filler 26 , depositing a polysilicon layer 28 , and etching the polysilicon layer 28 to form the word lines.
- Embodiments generally relate to semiconductor devices. More particularly, embodiments provide for a nonvolatile storage device having a dual bit memory cell with physically separated storage nodes. In one implementation, the various embodiments are applicable to flash memory and devices that utilize flash memory.
- Flash memory is a form of non-volatile memory that can be electrically erased and reprogrammed.
- flash memory in general, is a type of electrically erasable programmable read only memory (EEPROM).
- EEPROM electrically erasable programmable read only memory
- flash memory is nonvolatile and thus can maintain its contents even without power.
- flash memory is not standard EEPROM.
- Standard EEPROMs are differentiated from flash memory because they can be erased and reprogrammed on an individual byte or word basis while flash memory can be programmed on a byte or word basis, but is generally erased on a block basis.
- standard EEPROMs may appear to be more versatile, their functionality requires two transistors to hold one bit of data.
- flash memory requires only one transistor to hold one bit of data, which results in a lower cost per bit. As flash memory costs far less than EEPROM, it has become the dominant technology wherever a significant amount of non-volatile, solid-state storage is needed.
- flash memory Exemplary applications include digital audio players, digital cameras, digital video recorders, and mobile phones. Flash memory is also used in USB flash drives, which are used for general storage and transfer of data between computers. Also, flash memory is gaining popularity in the gaming market, where low-cost fast-loading memory in the order of a few hundred megabytes is required, such as in game cartridges. Additionally, flash memory is applicable to cellular handsets, smartphones, personal digital assistants, set-top boxes, digital video recorders, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, portable multimedia devices, and gaming systems.
- flash memory is a type of non-volatile memory, it does not need power to maintain the information stored in the chip.
- flash memory offers fast read access times and better shock resistance than traditional hard disks. These characteristics explain the popularity of flash memory for applications such as storage on battery-powered devices (e.g., cellular phones, mobile phones, IP phones, wireless phones, etc.). Since flash memory is widely used in such devices, and users would desire the devices to have as large a storage capacity as possible, an increase in memory density would be advantageous. Users would also benefit from reduced memory read time and reduced cost.
- FIG. 9 shows an exemplary system 3100 in accordance with an embodiment of the invention.
- System 3100 is well-suited for a number of applications, including digital audio players, digital cameras, digital video recorders, mobile phones, game cartridges, smartphones, personal digital assistants, set-top boxes, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, portable multimedia devices, gaming systems, and the like.
- the system 3100 includes a processor 3102 that pertains to a microprocessor or controller for controlling the overall operation of the system 3100 .
- the system 3100 also includes flash memory 3130 .
- the flash memory 3130 may include: a stack formed over a substrate, the stack having a gate oxide layer and an overlying polycrystalline silicon layer, the stack having first and second undercut regions formed under the polycrystalline silicon layer and adjacent to the gate oxide layer; a first charge storage element formed in the first undercut region; and a second charge storage element formed in the second undercut region.
- the flash memory 3130 may also include other features of a memory cell as described above. According to various embodiments, it is possible to provide a semiconductor device, such as flash memory, such that the memory cells therein each have two physically separated charge storage nodes. As a result, the flash memory 3130 can be manufactured in much smaller packages and much smaller geometries.
- This decreased size for the flash memory translates into decreased size for various devices, such as personal digital assistants, set-top boxes, digital video recorders, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, gaming systems, mobile phones, cellular phones, internet protocol phones, and/or wireless phones.
- devices such as personal digital assistants, set-top boxes, digital video recorders, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, gaming systems, mobile phones, cellular phones, internet protocol phones, and/or wireless phones.
- the system 3100 stores media data pertaining to media assets in a file system 3104 and a cache 3106 .
- the file system 3104 is, typically, a storage medium or a plurality of storage media, such as disks, memory cells, and the like.
- the file system 3104 typically provides high capacity storage capability for the system 3100 .
- the system 3100 may also include a cache 3106 .
- the cache 3106 is, for example, Random-Access Memory (RAM) provided by semiconductor memory.
- RAM Random-Access Memory
- the relative access time to the cache 3106 is substantially shorter than for the file system 3104 .
- the cache 3106 does not have the large storage capacity of the file system 3104 .
- the file system 3104 when active, consumes more power than does the cache 3106 .
- the power consumption is particularly important when the system 3100 is a portable media player that is powered by a battery (not shown).
- the system 3100 also includes a RAM 3122 and a Read-Only Memory (ROM) 3120 .
- the ROM 3120 can store programs, utilities or processes to be executed in a non-volatile manner.
- the RAM 3122 provides volatile data storage, such as for the cache 3106 .
- the system 3100 also includes a user input device 3108 that allows a user of the system 3100 to interact with the system 3100 .
- the user input device 3108 can take a variety of forms, such as a button, keypad, dial, etc.
- the system 3100 includes a display 3110 (screen display) that can be controlled by the processor 3102 to display information to the user.
- a data bus 3124 can facilitate data transfer between at least the file system 3104 , the cache 3106 , the processor 3102 , and the CODEC 3112 .
- the system 3100 also includes a bus interface 3116 that couples to a data link 3118 .
- the data link 3118 allows the system 3100 to couple to a host computer.
- the system 3100 serves to store a plurality of media assets (e.g., songs, photos, video, etc.) in the file system 3104 .
- a user desires to have the media player play/display a particular media item, a list of available media assets is displayed on the display 3110 .
- a user can select one of the available media assets.
- the processor 3102 upon receiving a selection of a particular media item, supplies the media data (e.g., audio file, graphic file, video file, etc.) for the particular media item to a coder/decoder (CODEC) 3110 .
- CDEC coder/decoder
- the CODEC 3110 then produces analog output signals for a speaker 3114 or a display 3110 .
- the speaker 3114 can be a speaker internal to the system 3100 or external to the system 3100 .
- headphones or earphones that connect to the system 3100 would be considered an external speaker.
- the available media assets are arranged in a hierarchical manner based upon a selected number and type of groupings appropriate to the available media assets.
- the available media assets take the form of MP3 files (each of which corresponds to a digitally encoded song or other audio rendition) stored at least in part in the file system 3104 .
- the available media assets (or in this case, songs) can be grouped in any manner deemed appropriate.
- the songs can be arranged hierarchically as a list of music genres at a first level, a list of artists associated with each genre at a second level, a list of albums for each artist listed in the second level at a third level, while at a fourth level a list of songs for each album listed in the third level, and so on.
- flash memory is applicable to a variety of devices other than portable media devices.
- flash memory can be utilized in personal digital assistants, set-top boxes, digital video recorders, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, and gaming systems.
- FIG. 14 illustrates advantages of memory cells according to one embodiment (solid line) over conventional memory cell designs (dashed line).
- the effect of program disturb in embodiments is much less than in conventional designs.
- the effect of decreasing channel length e.g., L 2 vs. L 1
- embodiments provide for dual storage node memory cells with physical separation of the storage nodes by an insulator. Such separation of the storage nodes greatly reduces program disturb between the two storage nodes, which is a critical issue as process geometries continue to decrease.
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Abstract
Description
- This application claims priority to U.S. Provisional Patent Application No. 60/765,351 entitled “PROCESS FOR FABRICATING DUAL CHARGE STORAGE NODE WITH UNDERCUT GATE OXIDE FOR DEEP SUB-MICRON MEMORY CELL AND RESULTING STRUCTURE” filed Feb. 4, 2006, and assigned to the assignee hereof and hereby expressly incorporated by reference herein.
- 1. Field
- Embodiments of the present invention generally relate to the field of semiconductor devices. More particularly, embodiments relate to memory storage cells.
- 2. Background
- In recent years, dual bit memory cells, such as those employing MirrorBit® technology developed by Spansion, Inc., have been developed. As the name suggests, dual bit memory cells double the intrinsic density of a flash memory array by storing two physically distinct bits on opposite sides of a memory cell. Ideally, reading or programming one side of a memory cell occurs independently of whatever data is stored on the opposite side of the cell.
-
FIG. 1A illustrates a conventional dual-bit memory cell 100. Conventional dualbit memory cell 100 typically includes asubstrate 110 with source/drain regions 120 implanted therein, afirst oxide layer 130 above thesubstrate 110, a continuouscharge trapping layer 140, asecond oxide layer 150, and apoly layer 160. Thebottom oxide layer 130 is also commonly referred to as a tunnel oxide layer. - Programming of a dual
bit memory cell 100 can be accomplished, for example, by hot electron injection. Hot electron injection involves applying appropriate voltage potentials to the gate, source, and drain of thecell 100 for a specified duration until thecharge trapping layer 140 accumulates charge. While for simplicity, charge is typically thought of as being stored in a fixed location (i.e., the edges) ofcharge trapping layer 140, in reality the location of the trapped charge for each node falls under a probability curve, such as 170 and 175. For the purposes of this discussion the bit associated withcurves curve 170 shall be referred to as the “normal bit” and the bit associated withcurve 175 shall be referred to as the “complementary bit”. It should be appreciated fromFIG. 1A that thememory cell 100 illustrated therein is reasonably large, such that the two sides can be fairly localized and well separated. -
FIG. 1B illustrates a conventional dualbit memory cell 105 having a smaller process geometry than thememory cell 100 ofFIG. 1A .FIG. 1B illustrates that as the cell gets smaller, the 170 and 175 stay the same, resulting in an overlap of thedistribution curves 170 and 175. Such an overlap in these regions can result in the contamination of one bit by its neighboring bit. This is also known as complementary bit disturb.curves -
FIG. 2 graphically illustrates complementary bit disturb in a conventional memory cell having a continuous charge trapping layer.FIG. 2 illustrates the example of when the normal bit has been programmed, but the complement your bit has not. In such a case, the normal bit should read “0” and the complementary bit should read “1”. Whether or not a bit is programmed is reflected by a delta in the threshold voltage associated with that bit. In conventional dual bit memory cells, programming of a normal bit also results in a shift of the Vt of the complementary bit. For example, in a memory cell having a channel length L1, changing the Vt of the normal bit by X results in a change of the Vt of the complementary bit of Y. As the cell size gets smaller, resulting in a shorter channel length (e.g., L2), the disturbance increases, even before the bits physically touch each other. Thus, conventional dual bit memory cells do not have adequate protection against physical contamination of one bit by its neighboring bit, as well as program disturb in general. - An embodiment of the present invention is directed to a memory cell. The memory cell includes a stack formed over a substrate. The stack includes a gate oxide layer and an overlying polycrystalline silicon layer. The stack further includes first and second undercut regions formed under the polycrystalline silicon layer and adjacent to the gate oxide layer. The memory cell further includes a first charge storage element formed in the first undercut region and a second charge storage element formed in the second undercut region.
- Thus, embodiments provide for dual storage node memory cells with physical separation of the storage nodes by an insulator. Such separation of the storage nodes greatly reduces program disturb between the two storage nodes, which is a critical issue as process geometries continue to decrease. As a result, embodiments are able to achieve geometries beyond 100 nm technology.
-
FIG. 1A illustrates a conventional dual-bit memory cell. -
FIG. 1B illustrates a conventional dual bit memory cell having a smaller process geometry than the memory cell ofFIG. 1A . -
FIG. 2 graphically illustrates complementary bit disturb in a conventional memory cell having a continuous charge trapping layer. -
FIG. 3 illustrates a cross-sectional view of an exemplary semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 4 illustrates selective etching of undercut regions in the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 5 illustrates formation of a tunnel oxide layer on the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 6 illustrates formation of a charge trapping layer on the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 7 illustrates removal of a portion of the charge trapping layer on the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 8 illustrates formation of sidewall spacers on the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 9 illustrates formation of bit lines in the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 10 illustrates oxide filling in the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 11 illustrates removal of hard masks and excess oxide from the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 12 illustrates formation of a polysilicon layer on the semiconductor device, in accordance with various embodiments of the present invention. -
FIG. 13 illustrates a flowchart a process for fabricating a semiconductor memory cell having at least two charge storage elements, in accordance with various embodiments of the present invention. -
FIG. 14 illustrates a flowchart foreign method of forming a charge storage element in an undercut region, in accordance with various embodiments of the present invention. -
FIG. 15 shows a block diagram of a conventional portable telephone, upon which embodiments can be implemented. -
FIG. 16 illustrates advantages of a memory cell according to one embodiment over conventional memory cells designs, with respect to program disturb. - The present invention will now be described in detail with reference to a various embodiments thereof as illustrated in the accompanying drawings. In the following description, specific details are set forth in order to provide a thorough understanding of the present invention. It will be apparent, however, to one skilled in the art, that the present invention may be practiced without using some of the implementation details set forth herein. It should also be understood that well known operations have not been described in detail in order to not unnecessarily obscure the present invention.
- Briefly stated, embodiments reduce the likelihood of program disturb in a dual bit memory cell through physical separation of the charge storage nodes by forming a charge trapping regions in undercut regions of a gate oxide, thereby preventing charge contamination between the storage nodes. Because two separate charge storage regions are used, rather than one continuous charge storage layer, the separate charge storage nodes are insulated from each other.
-
FIG. 3 illustrates a cross-sectional view of an exemplary semiconductor device, in accordance with various embodiments of the present invention.FIG. 3 shows asubstrate 10 after etching an overlyinggate oxide layer 12,polysilicon layer 14, and ahard mask 16, to expose surface areas for the fabrication of bit lines. It should be appreciated that thehard mask 16 may be a number of materials, including silicon nitride and the like. In one embodiment, thegate oxide 12 has a thickness on the order of 20-500 angstroms. Likewise, in one embodiment, thepolysilicon layer 14 as a thickness on the order of 200-2000 angstroms. - As shown in
FIG. 4 , thegate oxide layer 12 is selectively etched to form first and second undercut regions on either side of thegate oxide layer 12 and under thepolysilicon layer 14. In one embodiment, the widths of the first and second undercut regions are in the range of 50-500 angstroms. In one embodiment, the selective etch is performed by a wet etch process. For example, the wet edge may be a diluted HF etch, a chemical oxide removal (COR) etch, or the like. - As shown in
FIG. 5 , atunnel oxide layer 18 is then formed over thesubstrate 10 and the exposed regions of thepolysilicon layer 14. It should be appreciated that the tunnel oxide layers 18 may be formed in a number of ways. For example, thetunnel oxide layer 18 may be formed by growing, by plasma oxidation, by chemical vapor deposition, or the like. In one embodiment, thetunnel oxide layer 18 is on the order of 10-100 angstroms thick. In other embodiments, other thickness may be used for thetunnel oxide layer 18. It should be appreciated at this point that the first and second undercut regions now contain two oxide layers separated by empty space. - As shown in
FIG. 6 , a layer ofcharge trapping material 20 is formed over thetunnel oxide layer 18. The layer ofcharge trapping material 20 is formed such that it fills the remainder of the first and second undercut regions. In one embodiment, in order to avoid any seam void during the undercut filling, multiple cycles of partial deposition and partial etch may be performed. - The
charge trapping material 20 may be selected from a number of materials including, but not limited to, silicon nitride (SiN), silicon rich nitride (SiRN), polysilicon, high-K materials, and any combination thereof. It should be appreciated by one of skill in the art that although polysilicon and nitride materials may be used, the properties of the two materials are very different. For example, polysilicon is a conductor, which means that an electron may freely move throughout the material. By contrast, nitrides such as SiN and SiRN are insulators, wherein the location of a given electron stays relatively constant. - As shown in
FIG. 7 , thecharge trapping material 20 is then removed, except for the portions in the first and second undercut regions. It should be appreciated that this may be achieved in a number of ways. For example, in one embodiment, thecharge trapping material 20 is removed by a dry etch. Thecharge trapping material 20 may also be removed by a wet etch or any combination of wet and dry etch. In another embodiment, thecharge trapping material 20 is carefully oxidized with a well-controlled process such that only the portions of thecharge trapping material 20 in the first and second undercut regions remain. The oxidation may be thermal or plasma oxidation, for example. Regardless, the result is two physically isolatedcharge trapping regions 20 at each memory cell. In other words, thecharge trapping regions 20 are insulated from each other by the 12, 18, 22.oxide materials - As shown in
FIG. 8 , theoxide layer 22 is etched to formsidewall spacers 22 around the periphery of thepolysilicon layer 14. Thereafter, bit lines are formed in thesubstrate 10 by ion implantation using thesidewall spacers 22 as masks, as shown inFIG. 9 . The gaps above the bit lines 30 and between thesidewall spacers 22 are then filled withsilicon oxide 26, as shown inFIG. 10 . - As shown in
FIG. 11 , thehard masks 16 and anysurplus oxide material 26 are removed. In one embodiment, this is achieved by a chemical mechanical processing (CMP) polish. Thereafter, asecond polysilicon layer 28 is deposited over the structure, as shown inFIG. 12 . In one embodiment, thepolysilicon layer 28 is on the order of 200-2000 angstroms thick. In other embodiments, other thicknesses of thepolysilicon layer 28 may be employed. Thesecond polysilicon layer 28 is then selectively masked and etched to form the word lines of the memory array. - The following discussion sets forth in detail processes of fabrication according to various embodiments. With reference to
FIGS. 13-14 , 1300 and 1400 each illustrate example fabrication steps used and various embodiments. Although specific steps are disclosed inflowcharts 1300 and 1400, such steps are examples. That is, embodiments are well suited to using various other steps or variations of the steps recited inflowcharts 1300 and 1400. It is appreciated that the steps inflowcharts 1300 and 1400 may be performed in an order different than presented, and that not all of the steps inflowcharts 1300 and 1400 may be performed.flowcharts -
FIG. 13 illustrates a flowchart 1300 a process for fabricating a semiconductor memory cell having at least two charge storage elements, in accordance with various embodiments of the present invention. Atblock 1310, spaced stacks ofgate silicon oxide 12 and overlyingpolycrystalline silicon 14 are formed on the surface of asemiconductor substrate 10. In one embodiment, this is achieved by forming a layer ofgate silicon oxide 12 on the substrate, forming a layer ofpolycrystalline silicon 14 over thegate silicon oxide 12, formingmasks 16 over portions of thepolycrystalline silicon 14, and etching to expose portions of thesubstrate 10. - At
block 1320, undercut regions are formed in thegate silicon oxide 12. This may be achieved, for example, by a diluted HF etch, a chemical oxide removal (COR), or the like. Atblock 1330, charge storage elements are formed in the undercut regions. It should be appreciated that this may be achieved in a number of ways. For example,FIG. 14 illustrates aflowchart 1400 foreign method of forming a charge storage element in an undercut region, in accordance with various embodiments of the present invention. At block 1410, atunnel oxide layer 18 is formed on thesubstrate 10 on the exposedgate polycrystalline silicon 14.Block 1420 then involves forming a layer ofcharge trapping material 20 over thetunnel oxide layer 18 sufficient to fill the remainder of the undercut region. Thecharge trapping material 20 may be selected from a number of materials including, but not limited to, silicon nitride (SiN), silicon rich nitride (SiRN), polysilicon, high-K materials, and any combination thereof. In one embodiment, in order to avoid any seam void during the undercut filling, multiple cycles of partial deposition and partial etch may be performed. Thecharge trapping material 20 is then removed except for portions in the undercut region (block 1430). Atblock 1440, siliconoxide sidewall spacers 22 are formed on the stacks sufficient to cover any remaining exposed portions of thecharge trapping material 20. This may be achieved, for example, by forming a silicon oxide layer and etching to form thesidewall spacers 22 around the periphery of thepolysilicon layer 14. Thus, using this technology, physically separate and isolated charge storage elements may be created. - With reference again to
FIG. 13 ,block 1340 involves formingbit lines 30 in thesemiconductor substrate 10. In one embodiment, this is accomplished by implanting the bit lines 30 while using thesidewall spacers 22 as masks. The remaining space between the stacks is then filled with silicon oxide filler 26 (block 1350). Subsequently, word lines are formed over thesilicon oxide filler 26 and the stacks (block 1360). This may involve, for example, polishing down thehard masks 16 and portions of the siliconoxide sidewall spacers 22 and thesilicon oxide filler 26, depositing apolysilicon layer 28, and etching thepolysilicon layer 28 to form the word lines. - Embodiments generally relate to semiconductor devices. More particularly, embodiments provide for a nonvolatile storage device having a dual bit memory cell with physically separated storage nodes. In one implementation, the various embodiments are applicable to flash memory and devices that utilize flash memory.
- Flash memory is a form of non-volatile memory that can be electrically erased and reprogrammed. As such, flash memory, in general, is a type of electrically erasable programmable read only memory (EEPROM).
- Like Electrically Erasable Programmable Read Only Memory (EEPROM), flash memory is nonvolatile and thus can maintain its contents even without power.
- However, flash memory is not standard EEPROM. Standard EEPROMs are differentiated from flash memory because they can be erased and reprogrammed on an individual byte or word basis while flash memory can be programmed on a byte or word basis, but is generally erased on a block basis. Although standard EEPROMs may appear to be more versatile, their functionality requires two transistors to hold one bit of data. In contrast, flash memory requires only one transistor to hold one bit of data, which results in a lower cost per bit. As flash memory costs far less than EEPROM, it has become the dominant technology wherever a significant amount of non-volatile, solid-state storage is needed.
- Exemplary applications of flash memory include digital audio players, digital cameras, digital video recorders, and mobile phones. Flash memory is also used in USB flash drives, which are used for general storage and transfer of data between computers. Also, flash memory is gaining popularity in the gaming market, where low-cost fast-loading memory in the order of a few hundred megabytes is required, such as in game cartridges. Additionally, flash memory is applicable to cellular handsets, smartphones, personal digital assistants, set-top boxes, digital video recorders, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, portable multimedia devices, and gaming systems.
- As flash memory is a type of non-volatile memory, it does not need power to maintain the information stored in the chip. In addition, flash memory offers fast read access times and better shock resistance than traditional hard disks. These characteristics explain the popularity of flash memory for applications such as storage on battery-powered devices (e.g., cellular phones, mobile phones, IP phones, wireless phones, etc.). Since flash memory is widely used in such devices, and users would desire the devices to have as large a storage capacity as possible, an increase in memory density would be advantageous. Users would also benefit from reduced memory read time and reduced cost.
-
FIG. 9 shows anexemplary system 3100 in accordance with an embodiment of the invention.System 3100 is well-suited for a number of applications, including digital audio players, digital cameras, digital video recorders, mobile phones, game cartridges, smartphones, personal digital assistants, set-top boxes, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, portable multimedia devices, gaming systems, and the like. Thesystem 3100 includes aprocessor 3102 that pertains to a microprocessor or controller for controlling the overall operation of thesystem 3100. Thesystem 3100 also includesflash memory 3130. In the present embodiment, theflash memory 3130 may include: a stack formed over a substrate, the stack having a gate oxide layer and an overlying polycrystalline silicon layer, the stack having first and second undercut regions formed under the polycrystalline silicon layer and adjacent to the gate oxide layer; a first charge storage element formed in the first undercut region; and a second charge storage element formed in the second undercut region. Theflash memory 3130 may also include other features of a memory cell as described above. According to various embodiments, it is possible to provide a semiconductor device, such as flash memory, such that the memory cells therein each have two physically separated charge storage nodes. As a result, theflash memory 3130 can be manufactured in much smaller packages and much smaller geometries. This decreased size for the flash memory translates into decreased size for various devices, such as personal digital assistants, set-top boxes, digital video recorders, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, gaming systems, mobile phones, cellular phones, internet protocol phones, and/or wireless phones. - In the case where the
system 3100 is a portable media player. Thesystem 3100 stores media data pertaining to media assets in afile system 3104 and acache 3106. Thefile system 3104 is, typically, a storage medium or a plurality of storage media, such as disks, memory cells, and the like. Thefile system 3104 typically provides high capacity storage capability for thesystem 3100. - The
system 3100 may also include acache 3106. Thecache 3106 is, for example, Random-Access Memory (RAM) provided by semiconductor memory. The relative access time to thecache 3106 is substantially shorter than for thefile system 3104. However, thecache 3106 does not have the large storage capacity of thefile system 3104. Further, thefile system 3104, when active, consumes more power than does thecache 3106. The power consumption is particularly important when thesystem 3100 is a portable media player that is powered by a battery (not shown). Thesystem 3100 also includes aRAM 3122 and a Read-Only Memory (ROM) 3120. TheROM 3120 can store programs, utilities or processes to be executed in a non-volatile manner. TheRAM 3122 provides volatile data storage, such as for thecache 3106. - The
system 3100 also includes auser input device 3108 that allows a user of thesystem 3100 to interact with thesystem 3100. For example, theuser input device 3108 can take a variety of forms, such as a button, keypad, dial, etc. Still further, thesystem 3100 includes a display 3110 (screen display) that can be controlled by theprocessor 3102 to display information to the user. Adata bus 3124 can facilitate data transfer between at least thefile system 3104, thecache 3106, theprocessor 3102, and theCODEC 3112. Thesystem 3100 also includes a bus interface 3116 that couples to adata link 3118. Thedata link 3118 allows thesystem 3100 to couple to a host computer. - In one embodiment, the
system 3100 serves to store a plurality of media assets (e.g., songs, photos, video, etc.) in thefile system 3104. When a user desires to have the media player play/display a particular media item, a list of available media assets is displayed on thedisplay 3110. Then, using theuser input device 3108, a user can select one of the available media assets. Theprocessor 3102, upon receiving a selection of a particular media item, supplies the media data (e.g., audio file, graphic file, video file, etc.) for the particular media item to a coder/decoder (CODEC) 3110. - The
CODEC 3110 then produces analog output signals for a speaker 3114 or adisplay 3110. The speaker 3114 can be a speaker internal to thesystem 3100 or external to thesystem 3100. For example, headphones or earphones that connect to thesystem 3100 would be considered an external speaker. - In a particular embodiment, the available media assets are arranged in a hierarchical manner based upon a selected number and type of groupings appropriate to the available media assets. For example, in the case where the
system 3100 is an MP3-type media player, the available media assets take the form of MP3 files (each of which corresponds to a digitally encoded song or other audio rendition) stored at least in part in thefile system 3104. The available media assets (or in this case, songs) can be grouped in any manner deemed appropriate. In one arrangement, the songs can be arranged hierarchically as a list of music genres at a first level, a list of artists associated with each genre at a second level, a list of albums for each artist listed in the second level at a third level, while at a fourth level a list of songs for each album listed in the third level, and so on. It is to be understood that the present invention is not limited in its application to the above-described embodiments. Needless to say, various modifications and variations of the present invention may be made without departing from the spirit and scope of the present invention. - Also, as mentioned above, flash memory is applicable to a variety of devices other than portable media devices. For instance, flash memory can be utilized in personal digital assistants, set-top boxes, digital video recorders, networking and telecommunication equipments, printers, computer peripherals, automotive navigation devices, and gaming systems.
-
FIG. 14 illustrates advantages of memory cells according to one embodiment (solid line) over conventional memory cell designs (dashed line). As shown inFIG. 14 , for a given channel length (e.g., L1), the effect of program disturb in embodiments is much less than in conventional designs. Moreover, the effect of decreasing channel length (e.g., L2 vs. L1) is less significant with respect to the embodiment depicted as compared to conventional designs. Thus, embodiments provide for dual storage node memory cells with physical separation of the storage nodes by an insulator. Such separation of the storage nodes greatly reduces program disturb between the two storage nodes, which is a critical issue as process geometries continue to decrease. - The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (20)
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| US11/702,847 US20080061359A1 (en) | 2006-02-04 | 2007-02-05 | Dual charge storage node with undercut gate oxide for deep sub-micron memory cell |
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| US76535106P | 2006-02-04 | 2006-02-04 | |
| US11/702,847 US20080061359A1 (en) | 2006-02-04 | 2007-02-05 | Dual charge storage node with undercut gate oxide for deep sub-micron memory cell |
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| US20170018649A1 (en) * | 2014-08-13 | 2017-01-19 | United Microelectronics Corp. | Method for fabricating a flash memory |
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| CN107644874A (en) * | 2016-07-21 | 2018-01-30 | 联华电子股份有限公司 | Non-volatile memory structure and manufacturing method thereof |
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