US20070044397A1

US20070044397A1 - Skid resistant surfaces

Info

Publication number: US20070044397A1
Application number: US11/199,943
Authority: US
Inventors: Robert Wiercinski; David Zalanowski; Paul Westgate; Felek Jachimowicz
Original assignee: WR Grace and Co Conn
Current assignee: WR Grace and Co Conn
Priority date: 2005-08-09
Filing date: 2005-08-09
Publication date: 2007-03-01
Also published as: CA2617825A1; CA2617825C; MX2008001453A; EP1934415A1; JP2009504948A; WO2007021653A1

Abstract

Skid-resistant surfaces as described having either a pressure-sensitive adhesive layer or a highly filled, textured binder to reduce skidding. The surfaces are applied to trafficable surfaces such as roof and floors. Products such as roof underlyments bearing the surfaces are described in particular.

Description

FIELD OF THE INVENTION

The present invention relates to skid-resistant surfaces especially when wet, and in particular to skid-resistant trafficable surfaces such as roofs and floors as well as skid resistant packaging for lumber and the like.

BACKGROUND OF THE INVENTION

Roofing underlayments are typically installed over the roof deck and under the primary roof covering or overlayment, which can be asphalt shingles, metal shingles, or metal roofing, tiles such as Spanish or slate tile, wood shakes, concrete, slate, etc. The underlayment provides a secondary moisture barrier to protect the roof deck and building interior from moisture that may penetrate through the primary roof covering. Commercially effective underlayments must maintain their strength and integrity even after exposure to the elements. Underlayments are used both in new construction and in re-roofing projects.
It is known in the waterproofing art to combine a pre-formed waterproofing membrane, such as a rubberized bitumen/oil layer, with a carrier support sheet or film, and to utilize this as an underlayment The carrier support film may comprise a variety of materials, such as rubber, plastic, and/or metal, or combinations of the same. The use of metals is desirable, for example, to improve dimensional stability of the support film, which is subjected to oil migration from the oil-plasticized bitumen layer. It has also been desirable to employ cross-laminated plastic films, such as high density polyethylene, for improved stability of the carrier support sheet.
Such pre-formed waterproofing membrane laminates are considered “sheet-like” because they are sufficiently flexible that they can be rolled up and transported after manufacture to the job site where they are unrolled and installed on the building surface. This kind of membrane laminate, useful as an underlayment on sloped roofs, is commercially available from Grace Construction Products (W.R. Grace & Co.-Conn) under the name “ICE & WATER SHIELD” (a registered trademark of W.R.Grace & Co.-Conn.) The underlayment is applied to the roof deck before installation of the overlayment. The function of the membrane underlayment is to seal around roofing fasteners and to protect against damage from ice dams and wind-driven rain.
Another commercially available example of an underlayment is “TRI-FLEX 30”, (a product also available from Grace Construction Products) which is spun-bonded polypropylene coated with a thin layer of U.V. stabilized polypropylene on both of its surfaces.
In addition to its water shedding capabilities, an important characteristic of a roofing underlayment is its skid or slip resistance. Since roofing applicators must walk on the underlayment during roofing installation, the exposed surface should have a sufficiently high coefficient of friction, even when wet, so as to minimize or prevent an applicator from slipping when walking or standing on the surface.
It is also desirable that the roofing underlayment be rollable for ease of transportation and handling, and be readily unrollable, ideally by a single person, for application. However, maintaining unrollability while providing sufficient skid resistance can be problematic, particularly where the skid resistance is due to the tackiness or stickiness of the walking surface. That is, the same tackiness that is advantageously used to provide skid resistance can make it difficult or impossible to unroll the underlayment, particularly if the unrolling is to be carried out by only one person.
It is also desirable that the underlayment be light in weight, i.e. low weight per unit area. Lightweight provides for easier transportation to the roofdeck and easier installation. There are fewer trips up a ladder to a roofdeck with a lightweight membrane as compared to a heavier membrane. Some underlayments comprise a heavy layer of a large particulate that provides for a heavyweight membrane.
It therefore would be desirable to provide a lightweight roofing underlayment having excellent skid resistance while maintaining unrollability.

SUMMARY OF THE INVENTION

One embodiment of the invention is the provision of a skid-resistant surface comprising a substrate coated with a skid resistant layer. The substrate is preferably a pedestrian trafficable surface such as a roofing or flooring surface. The skid or slip-resistant layer is preferably a pressure sensitive adhesive or a highly filled textured binder.
Another embodiment of the invention is a lightweight roofing underlayment having excellent skid or slip-resistance to foot traffic under dry, wet and/or dusty conditions on a sloped surface, and is both readily rollable and unrollable as a coherent unit. The present invention overcomes problems associated with the prior art. The underlayment is preferably a multi-layered sheet material that includes a support layer composed of a film or fabric or both, and a skid or slip resistant layer on one or both faces of the support layer. The skid or slip resistant layer is preferably a pressure sensitive adhesive or a highly filled textured binder. The resulting sheet-like underlayment is sufficiently flexible to allow it to be formed into rolls and readily installed by unrolling over a support structure such as a roof deck. It also provides a sloped walking surface having a high coefficient of friction and excellent skid resistance even when wet and/or dusty, and even at high roof pitches such as those between about 4:12 and 12:12.
In its method aspects, the present invention relates to a method of forming a skid-resistant surface useful for example as a roofing underlayment by coating a thin layer of a pressure sensitive adhesive or a filled textured binder to a support layer such as a film or fabric, and to a method of waterproofing a roof or floor by unrolling the underlayment and applying it to the roof or floor such as by mechanical fastening or with an adhesive.
Another embodiment of the invention is an organic or inorganic roofing felt coated with a pressure sensitive adhesive or a highly filled textured binder.
Another embodiment of the invention is an exposed roofing membrane coated with a pressure sensitive adhesive or a highly filled textured binder.
Another embodiment of the invention is a roof decking comprising plywood or other decking material such as oriented strand board coated with a pressure sensitive adhesive or a highly filled textured binder.
Another embodiment of the invention is non-skid flexible packaging comprising a support layer coated with a pressure sensitive adhesive or a highly filled textured binder.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic diagram of a roofing underlayment in accordance with one embodiment of the present invention;
FIG. 2 is a schematic diagram of a roofing underlayment in accordance with another embodiment of the present invention;
FIG. 3 is a schematic diagram of a roofing underlayment in accordance with yet another embodiment of the present invention;
FIG. 4 is a schematic diagram of a roofing underlayment in accordance with still another embodiment of the present invention;
FIG. 5 is a schematic diagram of a roofing underlayment in accordance with a still further embodiment of the present invention;
FIG. 6 is a schematic diagram of a roofing underlayment in accordance with yet another embodiment of the present invention;
FIGS. 7A-7C are photomicrographs of a non-skids surface of the invention comprising a filled textured binder, looking down from above at the surface;
FIG. 8 is a schematic of a Meyer rod coater;
FIG. 9 is a schematic of a modified Meyer rod coater;
FIG. 10 is a schematic of a gravure coater;
FIG. 11 is a plot of adhesion value, a measure of blocking, versus adhesive coating thickness for an SIS pressure sensitive adhesive on various membranes;
FIG. 12 is a plot of adhesion value, a measure of blocking, versus adhesive coating thickness for an acrylic pressure sensitive adhesive on various membranes;
FIG. 13 is a plot of adhesion value, a measure of blocking, versus adhesive coating thickness for an SEBS pressure sensitive adhesive on various membranes;
FIG. 14 is a plot of adhesion value, a measure of blocking, versus membrane type for a filled acrylic pressure sensitive adhesive;
FIG. 15 is a plot of adhesion value, a measure of blocking, versus coating volume for a filled SEBS pressure sensitive adhesive on various membranes; and
FIG. 16 is a plot of adhesion value, a measure of blocking, versus coating volume for a filled SEBS pressure sensitive adhesive at various loadings of filler by volume.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

One embodiment of the invention is a skid-resistant surface comprising a substrate coated with a skid resistant layer that is skid resistant particularly when wet. The skid or slip resistant layer is preferably a pressure sensitive adhesive or a highly filled textured binder. The substrate may be a pedestrian trafficable surface such as roofing surfaces and flooring surfaces. Roofing surfaces include rollable roofing underlayments including synthetic polymeric mechanically attached underlayments, synthetic polymeric adhesively attached underlayments, organic and inorganic asphalt saturated roofing felts, liquid-applied roofing surfaces including urethanes, asphaltic-based materials, acrylics, and silicones, etc. Roofing surfaces further may be rollable exposed roofing membranes including rubber sheets, vinyl sheets, and TPO sheets. Flooring surfaces include wood-based materials, Portland cement-based materials, ceramic materials, naturally occurring stone materials, and synthetic polymeric materials as well as composite materials containing combinations of the foregoing.
Suitable pressure sensitive adhesive layers comprise rubbers such as those selected from the group consisting of SIS (styrene-isoprene-styrene block copolymers), SBS (styrene-butadiene-styrene block copolymers), SEBS (styrene-ethylene-butylene-styrene block copolymers), SBR, natural rubber, silicone rubber, butyl rubber, polyisoprene, polyisobutylene, chloroprene, ethylene-propylene rubber, ethylene alpha olefin, polybutadiene, nitrile rubbers, and acrylic rubber. A rubber modified bitumen pressure sensitive adhesive may also be used. All of the rubbers listed above, except silicone, may be blended with bitumen to produce a pressure sensitive adhesive. Preferably the pressure sensitive adhesive comprises a weatherable rubber such as those selected from the group consisting of SEBS, acrylic, silicone, and butyl. Preferably the pressure sensitive adhesive used is free of surfactant, since the presence of surfactant tends to reduce the skid resistance when the surface is wet.
The pressure sensitive adhesive generally comprises a rubber, a tackifier, and a plasticizer. The plasticizer and tackifier modify the properties of the rubber to make it pressure sensitive. A plasticizer is generally a low molecular weight ingredient that is compatible with the rubber. It lowers the plateau modulus of a mixture of rubber and plasticizer vs. the rubber alone. A tackifier is generally a low molecular weight ingredient that is compatible with the rubber and exhibits a high glass transition temperature vs. the rubber. It lowers the plateau modulus of a mixture of rubber and tackifier vs. the rubber alone, and the glass transition temperature of the blend of tackifier and rubber is higher than rubber alone. These features are known to those skilled in the art of pressure sensitive adhesive formulation.
The pressure sensitive adhesive may comprise rubber alone. Such is the case for some acrylic polymers such as butyl acrylate and ethyl-hexyl acrylate that are inherently pressure sensitive.
Preferably the pressure sensitive adhesive layer is used in a thickness of less than or equal to about 10 microns, more preferably less than or equal to about 5 microns. Use of such a thin pressure sensitive layer insures good skid-resistance, including wet skid-resistance, while insuring that a pedestrian does not become stuck to the surface while walking.
For embodiments where the skid-resistant layer is a pressure sensitive adhesive the pressure sensitive adhesive exhibits a minimum peel adhesion value of 1 pound per linear inch (pli) to the substrate. Adhesion is measured by applying a one inch wide tape comprising a 5 mil layer of the pressure sensitive adhesive laminated to the face of a 4 mil thick cross-laminated, high density polyethylene sheet such as “Valeron”, a commercial product of Valeron Strength Films, to the substrate. This “tape” may be prepared by coating the pressure sensitive adhesive from solution and drying, or coating the molten pressure sensitive adhesive at elevated temperature onto the 4 mil Valeton. The face of the pressure sensitive adhesive side of the one inch wide tape is applied to the substrate. The construction is rolled in four times in one second passes with a 30 pound roller. Adhesion is measured fifteen minutes later with a mechanical test device such as an Instron. The peel angle is 90 degrees. The cross-head speed is 2″/min.
In the embodiment where the skid-resistant layer is a filled textured binder the binder is a material that adheres to both the filler and the substrate, as described in a test below, and is organic solvent soluble. Preferred binders include: pressure sensitive adhesives as described above for a skid resistant layer comprising only a pressure sensitive adhesive, rubbers, and resins. Another preferred binder comprises an amorphous polyolefin such as that produced by Eastman Chemical under the trade name “Eastoflex”.
For binders that comprise a rubber the rubber is selected from the group consisting of SIS (styrene-isoprene-styrene block copolymers), SBS (styrene-butadiene-styrene block copolymers), SEBS (styrene-ethylene-butylene-styrene block copolymers), SBR, natural rubber, silicone rubber, butyl rubber, polyisoprene, polyisobutylene, chloroprene, ethylene-propylene rubber, ethylene alpha olefin, polybutadiene, nitrile rubbers, thermoplastic polyurethanes (TPUs), thermoplastic polyolefins (TPOs), and acrylic rubber. Preferably the rubber is weatherable such as those selected from the group consisting of SEBS, acrylic, silicone, and butyl. Preferably the rubber used is free of surfactant, since the presence of surfactant tends to reduce the skid-resistance when the surface is wet.
For binders that comprise a resin, the resin may be selected from a group of materials including hydrocarbon resins, C-5 hydrocarbon resins, C-9 hydrocarbon resins, (C-5)₂hydrocarbon resins, rosin acids, rosin esters, terpene resins, coumarone indene resins, phenol formaldehyde resins, urea formaldehyde resins, melamine resins, polyester resins, acrylic resins, alkyd resins, bitumen, aldehyde & ketone resins, amides & polyamides, amines & polyamines, maleic resins, melamine resins, oxazole resins, phenolic resins, phenoxy resins, phthalic anhydrides, styrene resins, urea resins, vinyl resins. Preferably, the resin has a Tg or ring and ball softening point that is greater than or exceeds 75F. More preferably the resin has a Tg or ring and ball softening point that is greater than or exceeds 140F.
Adhesion of the filled textured binder to the substrate is measured in a peel adhesion test using a pre-formed pressure sensitive tape. A 2″ wide preformed tape, (commercially available as “Preprufe”, a registered trademark of W.R. Grace & Co.-Conn.) is applied to the non-skid coated substrate. The sample is rolled 4 times, at 1 second per pass, with a 30 lb roller. Adhesion is measured in a T-peel adhesion test 15 min after rolling at a crosshead speed of 2″ per minute with an Instron mechanical tester. The peel adhesion value must be greater than 1 pound per linear inch (“pli”). Preferably, the adhesion value is greater than 2 pounds pli.
In the embodiment where the skid-resistant layer is a filled textured binder the filler particles, including those on the exterior surface of the coating, are preferably substantially coated with binder and the coating is textured. “Substantially” coated means that at least about 95 percent of the filler's surface is coated. By “textured” is meant that the filler particles protrude from the surface and thus the surface coating is uneven and not smooth or planar. Such a textured surface is shown in FIGS. 7A-7C where the individual particles of coated filler are visually detectable in an SEM photomicrograph. The filler particles must be substantially coated with binder as a result of the preferred manufacturing process. This preferred process involves producing a coating comprising the binder, the filler, and a solvent that dissolves the binder, applying the coating to a substrate, and removing the solvent by evaporation thereby depositing a layer of coating on the filler particles.
In the embodiment where the skid-resistant layer is a filled textured binder, the filler is inorganic or organic and is used in an amount of at least about 25 percent by volume of the filled textured binder. In a preferred embodiment the filler is inorganic or organic and is used in an amount of greater than or equal to about 45 percent by volume. Use of a high filler volume insures that the filled binder is textured. If the filler volume is too low the layer is relatively smooth. The filler has a maximum average particle size of less than about 100 microns. Preferably the filler has a maximum average particle size of up to about 50 microns. More preferably the filler has a maximum average particle size up to about 25 microns. The term “particles” as used herein is intended to encompass particles having regular (e.g., spherical) or irregular shapes, as well as shards. Suitable inorganic fillers include calcium carbonate, silica, clay, talc, vermiculite, mica, titanium dioxide, fly ash, alumina trihydrate, and slag The coating volume of the filled textured binder layer is less than 10 cc/ft2, more preferably less than about 5 cc/ft2, and most preferably less than about 2 cc/ft2.
Inorganic particulates that react with water may also be used. These include Portland cement calcium oxide, high-alumina cement, blast furnace slag, pozzolanas, and pozzolanic cement. These fillers may hydrate after the underlayment is installed on the roof deck. The net effect is an increase in the average size of the particulate after the membrane is installed.
The skid-resistant surfaces are applied to a substrate as an organic solvent-based coating. For a pressure sensitive adhesive non-skid surface the coating comprises a pressure sensitive adhesive and an organic solvent. For a filled textured binder non-skid surface the coating comprises a binder, filler, and an organic solvent. The coatings may be applied to a substrate by brush, roller, or spray application. The solvent evaporates leaving the non-skid coating. Continuous processes for coating a substrate are also contemplated. These processes include spray, roll coating, gravure coating, and knife coating.
Another embodiment of the invention is a roofing underlayment comprising a woven fabric, a non-woven fabric, a film, or a combination of these and a skid-resistant layer comprising a pressure sensitive adhesive or a highly filled textured binder.
The preferred underlayments to which a skid resistance layer is added comprises a spun bonded polypropylene substrate, both sides of which have been extrusion coated with a polyolefin, and an underlayment comprising a woven fabric that is laminated to a polyolefin film.
Turning first to FIG. 1, there is shown one embodiment of the underlayment 10 of the present invention. The underlayment 10 has an uppermost layer 13 of the skid-resistant layer of the invention supported by a support layer which can be one or more layers of a film or fabric, or both. In the embodiment shown in FIG. 1, the support layer is comprised of a lowermost layer 11 of fabric and intermediate layer 12 of film. Suitable films 12 are those comprised of a synthetic organic polymer such as a polyolefin or a blend of polyolefins, and films mentioned as suitable for this layer hereinafter. The preferred film is polypropylene or polyethylene or films made from mixtures of such. The present invention also contemplates the use of more than one film layer, such as layers laminated and/or co-extruded or cross-laminated together. Those skilled in the art will appreciate that the underlayments can be produced by any method known in the art such as extrusion, lamination and calendaring. The film layer 12 has a thickness in the range from 0.5 mils to 10 mils. Preferably, the thickness is in the range from 1 mil to 3 mils.
Suitable fabrics for use in the support layer 11 include both natural and synthetic woven and non-woven fabrics, and preferably is synthetic such as a polyolefin, such as polypropylene or polyethylene, a polyester, etc., or glass. Preferably the woven fabric has less than or equal to 25 percent open space. Woven and non-woven fabrics exhibit a weight ranging from 0.5 oz/yd2 to 10 oz/yd2. Preferably, woven and non-woven fabrics exhibit a weight in the range from 1 oz/yd2 to 3 oz/yd2.
In the particular embodiment of FIG. 1, as mentioned the support layer is comprised of (i) a non-woven or woven fabric layer 11, and (ii) a synthetic organic polymer film 12 attached to one surface of the fabric 11. On the surface of the synthetic organic polymer film 12 is a skid-resistance layer 13, which is a pressure sensitive adhesive or a highly filled textured binder. It is this skid-resistance layer 13 that provides the walking surface for the roof applicator, and is ultimately covered by the primary roof covering or overlayment such as shingles or tiles.
In the case where fabric layer 11 is a non-woven fabric, it may be comprised of one or more synthetic organic polymers such as polyolefins, for example polypropylene or polyethylene, or may be comprised of polyester. Polypropylene is preferred. Where fabric layer 11 is a woven fabric, it may be comprised of one or more one or more synthetic polymers such as polyolefins, for example polypropylene, or polyethylene, or may be comprised of polyester. The fabric may also comprise a woven or non-woven glass fiber mat. Fabrics comprised of polypropylene are preferred for use in the embodiment shown in FIG. 1.
The synthetic polymer film 12 as aforementioned comprises one or more polymers such as polyolefins, for example polypropylene, polyethylene, a polymer comprising ethylene and propylene, a polymer comprising ethylene and methyl acrylate, a polymer comprising ethylene and ethyl acrylate, a polymer comprising ethylene and butyl acrylate, a polymer comprising ethylene and an alpha olefin, a polymer comprising ethylene and vinyl acetate or polyester, and includes mixtures of the foregoing. Polyethylene, polypropylene, and mixtures of the two are preferred. The synthetic polymer film 12 may also be a coextruded film layer (not shown as such in FIG. 1). Each layer may comprise one or more of the polymers listed above.
The laminate comprising the non-woven or woven fabric 11 attached to a synthetic organic polymer film 12 may be manufactured by extrusion coating the layer 12 as a polymer melt onto the fabric.
Suitable pressure sensitive adhesive layers 13 comprise rubbers such as those selected from the group consisting of SIS (styrene-isoprene-styrene block copolymers), SBS (styrene-butadiene-styrene block copolymers), SEBS (styrene-ethylene-butylene-styrene block copolymers), SBR, natural rubber, silicone rubber, butyl rubber, polyisoprene, polyisobutylene, chloroprene, ethylene-propylene rubber, ethylene alpha olefin, polybutadiene, nitrile rubbers, and acrylic rubber. A rubber modified bitumen pressure sensitive adhesive may also be used. All of the rubbers listed above, except silicone, may be blended with bitumen to produce a pressure sensitive adhesive. Preferably the pressure sensitive adhesive comprises a weatherable rubber such as those selected from the group consisting of SEBS, acrylic, silicone, and butyl. Preferably the pressure sensitive adhesive used is free of surfactant, since the presence of surfactant tends to reduce the skid resistance when the surface is wet.
A pressure sensitive adhesive generally comprises a rubber, a tackifier, and a plasticizer. The plasticizer and tackifier modify the properties of the rubber to make it pressure sensitive. A plasticizer is generally a low molecular weight ingredient that is compatible with the rubber. It lowers the plateau modulus of a mixture of rubber and plasticizer vs. the rubber alone. A tackifier is generally a low molecular weight ingredient that is compatible with the rubber and it exhibits a high glass transition temperature vs. the rubber. It lowers the plateau modulus of a mixture of rubber and tackifier vs. the rubber alone, and the glass transition temperature of the blend of tackifier and rubber is higher vs. rubber alone. These features are known to those skilled in the art of pressure sensitive adhesive formulation.
The pressure sensitive adhesive may comprise rubber alone. Such is the case for some acrylic polymers such as butyl acrylate and ethyl-hexyl acrylate that are inherently pressure sensitive.
Preferably the pressure sensitive adhesive layer 13 is used in a thickness of less than or equal to about 10 microns, more preferably less than or equal to about 5 microns. Use of such a thin pressure sensitive layer insures good skid resistance, including wet skid resistance, while maintaining the ability to unroll the membrane.
For embodiments where the non-skid layer 13 is a pressure sensitive adhesive, the pressure sensitive adhesive exhibits a minimum peel adhesion value of 1 pound per linear inch (pli) to the support sheet. Adhesion is measured by applying a tape comprising a 5 mil layer of the pressure sensitive adhesive to the face of the support sheet in contact with the non-skid layer. This “tape” may be prepared by coating the pressure sensitive adhesive from solution and drying or coating the molten pressure sensitive adhesive at elevated temperature on to the support sheet. The face of a 1″ wide tape comprising the pressure sensitive adhesive is applied to the face of another layer of support sheet. The “sandwich” is rolled in 4-1 sec. passes with a 30 pound roller. Adhesion is measured fifteen minutes later with a mechanical test device such as an Instron. The peel angle is 180 degrees. The cross-head speed is 2″/min.
In the embodiment where the skid resistant layer 13 is a filled textured binder the binder is a material that adheres to both the filler and the support sheet, as described in a test below, and is organic solvent soluble. Preferred binders include: pressure sensitive adhesives as described above for a skid resistant layer comprising only a pressure sensitive adhesive, rubbers, and resins. Another preferred binder comprises an amorphous polyolefin like those produced by Eastman Chemical under the trade name of Eastoflex.
For binders that comprise a rubber the rubber is selected from the group consisting of SIS (styrene-isoprene-styrene block copolymers), SBS (styrene-butadiene-styrene block copolymers), SEBS (styrene-ethylene-butylene-styrene block copolymers), SBR, natural rubber, silicone rubber, butyl rubber, polyisoprene, polyisobutylene, chloroprene, ethylene-propylene rubber, ethylene alpha olefin, polybutadiene, nitrite rubbers, thermoplastic polyurethanes (TPUs), thermoplastic polyolefins (TPOs), and acrylic rubber. Preferably the rubber is weatherable such as those selected from the group consisting of SEBS, acrylic, silicone, and butyl. Preferably the rubber used is free of surfactant, since the presence of surfactant tends to reduce the skid resistance when the surface is wet.
For binders that comprise a resin the resin may be selected from a group of materials including hydrocarbon resins, C-5 hydrocarbon resins, C-9 hydrocarbon resins, (C-5)₂hydrocarbon resins, rosin acids, rosin esters, terpene resins, coumarone indene resins, phenol formaldehyde resins, urea formaldehyde resins, melamine resins, polyester resins, acrylic resins, alkyd resins, bitumen, aldehyde & ketone resins, amides & polyamides, amines & polyamines, maleic resins, melamine resins, oxazole resins, phenolic resins, phenoxy resins, phthalic anhydrides, styrene resins, urea resins, vinyl resins. Preferably, the resin has a Tg or ring and ball softening point that is greater than or exceeds 75F. More preferably the resin has a Tg or ring and ball softening point that is greater than or exceeds 140F.
Adhesion of the filled textured binder to the support sheet is measured in a peel adhesion test using a pre-formed pressure sensitive tape. A 2″ wide preformed tape. Preprufe® Tape, is applied to the non-skid coated face of the underlayment. The sample is rolled 4 times, at 1 second per pass, with a 30 lb roller. Adhesion is measured in a T-peel adhesion test 15 min after rolling at a cross head speed of 2″ per minute with an Instron mechanical tester. The peel adhesion value must be greater than 1 pound per linear inch (pli). Preferably, the adhesion value is greater than 2 pounds per linear inch.
As mentioned previously, in the embodiment where the skid resistant layer 13 is a filled textured binder the filler particles, including those on the exterior surface of the coating, are preferably substantially coated with binder and the coating is textured. This texturing is clearly visible. See FIGS. 7A to 7C for an illustration. The ability to visually detect particles in an SEM photomicrograph is one test for an embodiment of the invention comprising a filled textured binder. The filler particles must be coated with binder as a result of the preferred manufacturing process. This involves producing a coating comprising the binder, the filler, and a solvent that dissolves the binder, applying the coating to a substrate, and removing the solvent by evaporation thereby depositing a layer of coating on the filler particles.
As mentioned, in the embodiment where the skid resistant layer 13 is a filled textured binder, the filler is inorganic or organic and is used in an amount of at least about 25 percent by volume of the filled textured binder. In a preferred embodiment the filler is inorganic or organic and is used in an amount of at least about 45 percent by volume. Use of a high filler volume insures that the filled binder is textured. If the filler volume is too low the layer is relatively smooth. The filler has a maximum average particle size of up to about 100 microns. Preferably the filler has a maximum average particle size of less than about 50 microns. More preferably the filler has a maximum average particle size of up to about 25 microns. Larger particle sizes hinder the coating application process, and add excessive weight to the underlayment. The term “particles” as used herein is intended to encompass particles having regular (e.g., spherical) or irregular shapes, as well as shards. Suitable inorganic fillers include calcium carbonate, silica, clay, talc, vermiculite, mica, titanium dioxide, fly ash, alumina trihydrate, and slag. The coating volume of the filled textured binder layer is up to about 10 cubic centimeters per square foot, more preferably less than about 5 cc/ft2, and most preferably less than about 2 cc/ft2.
Inorganic particulates that react with water may also be used. These include Portland cement, calcium oxide, high-alumina cement, blast furnace slag, pozzolanas, and pozzolanic cement. These fillers may hydrate after the underlayment is installed on the roof deck. The net effect is an increase in the average size of the particulate after the membrane is installed.
Some underlayments of the present invention are textured at 2 levels. These include embodiments where the support sheet comprises a woven or a non-woven fabric in direct contact with non-skid layer 13 or separated from non-skid layer 13 by a thin polymer film 12. One level of texturing is provided by the filler. Another level of texturing is provided by the fabric. While not being bound by theory, it is believed that both levels of texturing contribute to the performance of the underlayments. The dual texturing enhances resistance to “blocking” (the tendency of the front face of the underlayment to stick to its rear face when unrolled) by minimizing contact between opposite faces of the underlayment within a roll of underlayment. The dual texturing also enhances skid resistance by enhancing mechanical interlock between the surface of the underlayment and the sole of a shoe in contact with the surface of the underlayment. The dual texturing also enhances skid resistance by providing channels for lubricant migration when a shoe sole comes into contact with an underlayment that is coated with lubricant(s). Lubricants include water and dirt. To avoid skidding the lubricant must be channeled away from the contact area between a shoe sole and the surface of the underlayment.
The pressure sensitive adhesive layer and the filled textured binder layer are preferably coated as a solution in an organic solvent. The organic solvent-based solution of a pressure sensitive adhesive or filled binder is coated onto a web comprising the support layer, and the solvent is removed by evaporation. The resulting web can then be wound into a roll. Suitable organic solvents include those that will completely dissolve the pressure sensitive adhesive or the binder and also exhibit a high vapor pressure so that evaporation can be affected quickly in the coating process.
Other methods may be utilized to coat a filled textured binder on to a support sheet. One option is to coat a solution of the binder on to the support sheet, apply the filler to the solution coated web, and remove the solvent by evaporation. Yet another option is to coat the binder as a molten layer on the support sheet, apply the filler while the binder is still molten, and cool to solidify the binder. The manufacturing method where a mixture of an organic solvent, binder, and filler is coated onto a web comprising the support layer, and the solvent is removed by evaporation, is preferred because the filler is well bonded to the support sheet in comparison to other manufacturing methods by virtue of being substantially coated with binder.
FIG. 2 illustrates a second embodiment of the present invention. The underlayment 21 comprises a non-woven or woven fabric layer 11, a synthetic organic polymer film layer 12 adhered to both faces of the fabric 11, and a pressure sensitive adhesive layer or filled textured binder layer 13 on the surface of the polymer film 12. The polymer film 12 may be a coextruded layer (not shown) polymer film.
Yet another embodiment is shown in FIG. 3, where the underlayment 22 comprises a non-woven or woven fabric 11, a synthetic organic polymer film 12 adhered to both faces of the fabric 11, a pressure sensitive adhesive layer or filled textured binder layer 13 on the surface of one of the polymer film layers 12, and a further non-skid layer 14 on the surface of the other polymer film layer 12. The non-skid layer 14 can minimize or prevent relative movement between the underlayment and the roofing deck during and after installation. Suitable non-skid layers 14 include one or more polyolefins such as polyethylene, polypropylene, a polymer comprising ethylene and propylene, a polymer comprising ethylene and methyl acrylate, a polymer comprising ethylene and ethyl acrylate, a polymer comprising ethylene and butyl acrylate, a polymer comprising ethylene and vinyl acetate, a polymer comprising ethylene and an alpha olefin, and a polymer comprising ethylene and octene. The non-skid layer 14 preferably has a thickness of less than about 1 mil, and exhibits a Shore D hardness, ASTM D2240, of less than about 45.
The multi-layer synthetic organic polymer film 12 and 14 in FIG. 3 may be co-extrusion coated onto the fabric 11 to produce a structure comprising layers 11, 12 and 14 of underlayment 22. Synthetic polymer layer 12 is extrusion coated to the other face of fabric 11. This may also be a coextruded layer (not shown) The non-skid layer 13 then may be applied to such structures to produce the underlayment of FIG. 3 by coating, as a mixture with an organic solvent that dissolves the organic portion of the coating, onto a web comprising a support in a continuous web coating operation. The solvent is removed by evaporation and the resulting underlayment is wound into rolls. Various types of coaters may be used to apply the organic solvent based coating, including wire wound rod (also called Meyer rod), roll coater, gravure coater, air knife, and a knife over roll coater.
FIG. 8 is a schematic of “Meyer” rod coating using a wire wound rod, the preferred coating method used herein. In Meyer rod coating, a coating roll 31 is situated in a bath 30 filled with coating. A layer of coating is deposited on the coating roll 31 as the roll is rotated. Coating from the roll is transferred to the web 34 comprising the support sheet. The wire-wound metering rod 32 sometimes known as a “Meyer Bar”, allows the desired quantity of the coating to remain on the substrate 34. The excess coating is deposited back into the pan 30. The quantity metered on to the substrate is determined by the diameter of the wire used on the rod. For coatings comprising a highly filled textured binder the machine design may be modified to accommodate potential problems with filler settling during the coating process. Filler may tend to settle in the bath 30 of FIG. 8. This is particularly important when a low viscosity coating is applied. One option is to recirculate the coating in the pan. This may be facilitated with a tapered pan 25 design and recirclation system 36 and 37 as shown in FIG. 9.
FIG. 10 shows a schematic of gravure coating. The gravure coater depends on an engraved roller 38 running in a coating bath that fills the imprinted dots or lines of the roller with the coating material. The excess coating on the roller is removed by the doctor blade and the coating is then deposited onto the substrate as it passes through the engraved roller and a pressure roller. As immediately applied to the web, the coating is textured. If the coating viscosity is low and or solvent evaporation is slow, the textured pattern levels to produce a smooth coating except for filler particles that are thicker than the binder layer. If the coating viscosity is high and or solvent evaporation is fast, then a textured pattern results after solvent evaporation. This may be affected for a non-skid layer comprising a pressure sensitive adhesive (no filler) or a filled textured binder. For a non-skid layer comprising a filled textured binder the net effect is to have 2 levels of texturing. The smaller-scale texturing is contributed by the filler particles. The larger-scale texturing is related to the gravure roll pattern.
FIG. 4 illustrates a further embodiment 23 that comprises a woven fabric layer 15 with less than or equal to 25 percent open space, a pressure sensitive adhesive layer or filled textured binder layer 13, a lamination layer 20, a polymer film 16 and a second non-skid layer 14. Layer 15 comprises a material selected from a list including polyethylene, polypropylene, polyester, or glass. The weight of layer 15 is 0.5 oz/yd2 to 10 oz/yd2. Preferably, the weight of layer 15 is 1 oz/yd2 to 3 oz/yd2. Options for materials for layer 14 are described above. Layer 16 is a polymer film comprising one or more materials selected from a list including polypropylene, polyethylene, a polyolefin, or polyester. The thickness of layer 16 is 0.5 mils to 10 mils. Preferably the thickness of layer 16 is 1 to 3 mils. Polypropylene is preferred. Layer 20 adheres layer 15 to layer 16. Layer 20 may comprise the same materials as previously described above for layer 12. The film layer 20 has a thickness in the range from 0.5 mils to 10 mils. Preferably, the thickness of layer 20 is in the range from 1 mil to 3 mils.
Layer 20 may also comprise a pressure sensitive adhesive as described above for layer 13. Layer 20 may also comprise bitumen. Layer 20 may also comprise rubber and bitumen. For the case where layer 20 comprises a pressure sensitive adhesive, bitumen, or bitumen and rubber, the thickness is in the range from 1 mil to 50 mils. For the case where layer 20 comprises a pressure sensitive adhesive, bitumen, or bitumen and rubber the underlayment 23 exhibits nail sealing characteristics, i.e. the material of layer 20 tends to seal around nails that are made to penetrate the underlayment 23.
The underlayment 23 of FIG. 4 may be made in several ways. A preferred process is described as follows. A coextruded film comprising layers 14 and 16 is made in a coextrusion process. Next the coextruded film 14/16 is laminated to woven fabric 15 via extrusion lamination with lamination layer 20. A solution comprising a pressure sensitive adhesive or filled textured binder is coated on to the other face of woven fabric 15, and the solvent is removed via evaporation leaving layer 13.
The embodiment 24 of FIG. 5 shows a polyethylene or polypropylene film 17, and a layer of pressure sensitive adhesive 13 on one face thereof. Cross-laminated films are preferred, such as cross-laminated films commercially available from Van Leer under the trademark VALERON. Other suitable cross-laminated films are those manufactured by Interplas/Formosa.
Another embodiment of the invention (not shown) is an organic or inorganic roofing felt coated with a pressure sensitive adhesive or a filled textured binder. An organic roofing felt comprises paper saturated with asphalt. An inorganic roofing felt comprises a non-woven glass fabric saturated with asphalt.
FIG. 6 illustrates an embodiment 25 of a self-adhering underlayment comprising a support layer 19, a pressure sensitive adhesive layer or filled textured binder layer 13 on one major surface thereof, and a second pressure sensitive adhesive 18 on the opposite major surface thereof. The pressure sensitive layer 18 may include rubber modified bitumen, and non-bituminous adhesives comprising rubbers such as SIS, SBS, SEBS, SBR, natural rubber, silicone, butyl rubber, isoprene, butadiene and acrylic rubber. Preferably the layer 18 is used in a thickness of greater than or equal to 5 mils, more preferably greater than or equal to 20 mils.
The support layer 19 comprises a film, a woven fabric, a non-woven fabric, or a combination of these. Preferrably, the films comprise a polyolefin, polyethylene, polypropylene, a polyester, or a combination of these materials.
The non-skid underlayments of the present invention exhibit a unique combination of valuable features in comparison to other underlayments including: excellent skid resistance, yet are still trafficable (the shoe soles of a pedestrian walking on the surface of an underlayment of the present invention do not become stuck to the underlayment), particularly when wet, lightweight, rollable, and unrollable. For embodiments comprising a filled textured binder, where the binder is a pressure sensitive adhesive or a rubber, a unique combination of mechanisms act to impart a high coefficient of friction, particularly when wet. Furthermore, for embodiments comprising a filled textured binder the filler is better adhered to the support sheet in comparison to the case for other underlayments where the surface comprises a filler or aggregate.
Skid resistance is demonstrated in example 2 below. Underlayments of the present invention are lightweight in comparison to other underlayments (and other roofing products) comprising filler or aggregate on the surface because a low level of filler is used and the particle size of the filler is small. It was surprising to find that good skid resistance can be achieved using a low level of small particle filler.
It was also surprising that a surface could be rendered skid resistant with a pressure sensitive adhesive without compromising the ability to unroll the membrane or walk on the membrane without becoming stuck. For embodiments where the skid resistant layer comprises only a pressure sensitive adhesive this is achieved by use of a very thin layer of pressure sensitive adhesive. If a thick layer of pressure sensitive adhesive were used as the non-skid layer the underlayment would be impossible or difficult to unroll. For example, for a 30″ wide membrane the minimum force required to unroll the membrane comprising more than about 5 mils of pressure sensitive adhesive or binder would be equal to or greater than 30 lbs. For embodiments comprising a filled textured binder, where the binder is a pressure sensitive adhesive or rubber, (rubbers are slightly tacky) excellent skid resistance, particularly when wet, is achieved by the use of a thin non-skid layer that is textured with a small particle size filler.
While not being bound by any specific theory, it is believed that a single mechanism contributes to provide skid resistance for embodiments comprising a pressure sensitive adhesive while two possible mechanisms contribute to provide skid resistance for embodiments comprising a filled textured binder where the binder is a pressure sensitive adhesive or a rubber. For embodiments comprising a pressure sensitive, adhesion of the non-skid coated underlayment to the shoe sole of the walker provides for non skid properties. For embodiments comprising a filled textured binder, where the binder is a pressure sensitive adhesive or a rubber, adhesion of the non-skid coated underlayment to the shoe sole of the walker and mechanical interlock of the non-skid coated underlayment to the shoe sole of the walker provide for non-skid properties. For embodiments of the invention where the binder is a resin it is believed that mechanical interlock substantially provides for skid resistance. For resins, adhesion likely contributes little to non-skid properties as resins are hard, low tack materials by comparison with pressure sensitive adhesives and rubbers. Embodiments of the invention comprising a filled textured binder are textured as aforementioned as a result of the high filler level and the filler is substantially coated with binder. This is evident from the SEM photomicrographs of the top surfaces of an underlayments coated with a filled textured binder in FIGS. 7A-7C.
The manufacturing method where a mixture of an organic solvent, binder, and filler is coated onto a web comprising the support layer, and the solvent is removed by evaporation, is preferred because the filler is well bonded to the support sheet in comparison to other manufacturing methods by virtue of being substantially coated with binder. Other methods may be utilized to coat a filled textured binder on to a support sheet. One option is to coat a solution of the binder on to the support sheet, apply the filler to the solution coated web, and remove the solvent by evaporation. Yet another option is to coat the binder as a molten layer on the support sheet, apply the filler while the binder is still molten, and cool to solidify the binder. For these other methods filler that is not well bonded to the support sheet acts as a lubricant to enhance skidding instead of preventing skidding. Other underlayments and other roofing products comprising an aggregate or filler coated surface are made by the method involving application of filler or aggregate to a molten surface. The molten surface is most often asphalt.
There is another known technology for imparting skid resistance to a trafficable surface. It involves coating with a soft polymeric material, like that described above for layer 14. These materials impart skid resistance by virtue of their softness. Embodiments of the current invention are differentiated from such materials compositionally and by the mechanism by which skid resistance is imparted.
Other applications for the non-skid coating are contemplated. The non-skid layers of the present invention may be applied to plywood and oriented strand board. Use of these coated decking materials enhances skid resistance particularly when these materials are used on a sloped roof deck.
Another application is non-skid flexible packaging materials. For example, plastic sacks may be coated with the non-skid layers of the present invention to prevent sliding of stacked arrays of products.

EXAMPLE 1

A blocking test was conducted, which is a severe test designed to develop an understanding of blocking on a relative basis. A control membrane, a polyolefin (PO) coated non-woven is easily unrolled. The polyolefin coated control membrane comprises a 2 oz/yd non-woven polypropylene fabric coated on each side with 1.25 mils coex layer. On the side in contact with the skid-resistant layer the coex layer comprise 1.0 mil layer PP/LDPE blend and a 0.25 mils layer comprising a copolymer of ethylene and methyl acrylate. The thin layer faces outward. The coex layer on the other side of the non-woven comprises a 1 mil layer of a PP/LDPE blend and a 0.25 mil layer comprising an ethylene/propylene copolymer. The thin layer faces outward. If an experimental membrane exhibits an ability to unroll as easily or more easily versus the control in the accelerated test, than it is assumed that the experimental membrane will unroll easier than the control under normal circumstances.
The accelerated tests involve the application of high pressure and high temperature. Two sheets of membrane are positioned on top of the other with the surfaces to be tested in contact with one another. The sheets are sandwiched between 2 steel plates. The assembly is loaded in a heated press to 250 psi at 75° C. for 16 hrs. The force required to peel the sheets apart is then measured with a mechanical test device such as an Instron. The peel rate is 2″/min. A T-Peel test geometry is used. Results are shown in the five Tables below. In the Tables, “SIS” is a styrene/butadiene/styrene block copolymer, “PO” is polyolefin, “PP” is polypropylene, “HDPE” is high density polyethylene, “SEBS” is styrene/ethylene/butylenes/styrene block copolymer, and “PSA” indicates a pressure sensitive adhesive.
In FIGS. 11-13, peel force, a measure of blocking, is plotted versus the pressure sensitive adhesive coating thickness. An SIS, acrylic, and an SEBS pressure sensitive adhesive were evaluated by coating on different membranes including a polyolefin coated non-woven (described above), a membrane that comprises a 2 oz/yd polypropylene woven fabric laminated to a 1 mil polypropylene/ethylene vinyl acetate wherein the ethylene vinyl acetate layer faces outward coextruded film with 1 mil of a polypropylene/polyethylene mixture, and an HDPE film which is 3 mil Valeron.
With the exception of the acrylic coated HDPE film, all pressure sensitive adhesive coated webs exhibited a lower resistance to blocking versus the control (FIGS. 11 to 13).
Blocking was also evaluated for membranes coated with a filled textured acrylic pressure sensitive adhesive and the results are shown in FIG. 14. The filled coating comprises 75 percent, by weight, of a 325 mesh calcium carbonate. The volume of the coating on each membrane was ˜0.93 cc/ft2 (weight=16 g/yd2). All membranes coated with the filled pressure sensitive adhesive exhibit lower resistance to blocking versus the control.
Blocking was also evaluated for membranes coated with a filled textured SEBS pressure sensitive. The filler is 325 mesh calcium carbonate. The effects of coating volume and membrane type were evaluated. Coating volume was varied between about 1 cc/ft2 to 15 cc/ft2. Two membranes were evaluated. One comprises the polyolefin coated non-woven as described above. The other comprises the polypropylene woven as described above. The results are given in FIG. 15. Note that the level of blocking is proportional to the coating volume. The peel force is less than 0.5 pli for coating volumes less than about 10 cc/ft2.
Blocking was also evaluated for membranes coated with a filled textured SEBS pressure sensitive adhesive and the results are shown in FIG. 16. The effects of filler volume percent and the effects of coating volume on blocking were evaluated. The filler was a 325 mesh calcium carbonate. Blocking is lowest for underlayments comprising a low coating volume and a high percent by volume of filler. For the underlayment comprising a coating with 27 percent filler by volume and 10.3 cc/ft2 of coating blocking is severe.

EXAMPLE 2

Skid resistance was measured in a “walk on” test as follows. Underlayment specimens to be tested were mechanically attached to a sheet of plywood and positioned at a test angle of 40°. The samples were sprayed with water prior to testing. A tester (“walker”) walks over the sample and compares the wet skid resistance of the sample to a “control”, which was a membrane comprising a 2 side polyolefin-coated polypropylene non-woven described above. The “walker” judges the sample membrane to exhibit better, similar or worse skid resistance versus the control membrane. The results for various underlayments tested are shown in Table 1. Samples 1-13 are embodiments of the present invention and all exhibit superior wet skid resistance in comparison to the control membrane. It's also important to note that water-based binders comprising a surfactant impart poor wet skid resistance. See test results for specimens 25 to 27 in Table 1 where all of the non-skid layers are acrylic emulsions commercially available from Rohm and Haas company. In the “walk on” test, these binders have poor wet adhesion to the support sheet which contributes to poor wet skid resistance. It is believed that the surfactant also lowers the surface tension of water on the wet surface which contributes to poor wet skid resistance.

TABLE 1


			Wet Skid
No.	Support Layer	Non-Skid Layer	Resistance

1	2 side polyolefin coated non-woven polypropylene¹	5 u SIS PSA	Better
2	2 side polyolefin coated non-woven polypropylene¹	5 u SEBS PSA	Better
3	2 side polyolefin coated non-woven polypropylene¹	5 u Acrylic PSA	Better
4	Woven polypropylene-polypropylene film laminate²	5 u SIS PSA	Better
5	Woven polypropylene-polypropylene film laminate²	5 u SEBS PSA	Better
6	Woven polypropylene-polypropylene film laminate²	5 u Acrylic PSA	Better
7	2 side polyolefin coated non-woven polypropylene¹	1 cc/ft2 - 325 mesh CaCO3/SIS PSA (53% by	Better
		volume CaCO3)
8	2 side polyolefin coated non-woven polypropylene¹	1 cc/ft2 - 325 mesh CaCO3/SEBS PSA (53% by	Better
		volume CaCO3)
9	2 side polyolefin coated non-woven polypropylene¹	1 cc/ft2 - 325 mesh CaCO3/acrylic PSA (53% by	Better
		volume CaCO3)
10	Woven polypropylene-polypropylene film laminate²	1 cc/ft2 - 325 mesh CaCO3/SIS PSA (53% by	Better
		volume CaCO3)
11	Woven polypropylene-polypropylene film laminate²	1 cc/ft2 - 325 mesh CaCO3/SEBS PSA (53% by	Better
		volume CaCO3)
12	Woven polypropylene-polypropylene film laminate²	1 cc/ft2 - 325 mesh CaCO3/acrylic PSA (53% by	Better
		volume CaCO3)
13	2 side polyolefin coated non-woven polypropylene¹	2 cc/ft2 - Portland Cement/amorphous polyolefin	Better
		(Eastoflex P1010-Eastman) (53% by volume
		Portland Cement)
14	Woven polypropylene-polypropylene film laminate²	1 cc/ft2 - 325 mesh CaCO3/butyl rubber (53% by	Better
		volume CaCO3)
15	Woven polypropylene-polypropylene film laminate²	1 cc/ft2 - 325 mesh CaCO3/chloroprene rubber	Better
		(53% by volume CaCO3)
16	2 side polyolefin coated non-woven polypropylene¹	none	NA (control)
17	Woven polypropylene-polypropylene film laminate	none	Same
18	2 side polyolefin coated non-woven polypropylene¹	1 oz/yd2 hot melt spray applied amorphous	Same
		polyolefin (Eastoflex P1010-Eastman)
19	Woven polypropylene-polypropylene film laminate²	1 oz/yd2 hot melt spray applied amorphous	Same
		polyolefin (Eastoflex P1010-Eastman)
20	EPDM Rubber Sheet	none	Same
21	2 side polyolefin coated non-woven polypropylene¹	2 to 3 oz/yd2 embossed low molecular weight	Same
		polyethylene/tackifier blend (70/30 by weight)
22	Woven polypropylene-polypropylene film laminate²	2 to 3 oz/yd2 embossed low molecular weight	Same
		polyethylene/tackifier blend (70/30 by weight)
23	Web comprising HPDE woven fabric and polyolefin grid	polyolefin coated polyolefin grid with nodes	Same
	with nodes³
24	Web comprising spunbonded/thermobonded	spunbonded/thermobonded polypropylene non-	Worse
	polypropylene non-woven fabric surface⁴	woven fabric surface
25	Woven polypropylene-polypropylene film laminate²	4 cc/ft2 - CaCO3/dry Acronal S400 (53% by	Worse
		volume CaCO3)
26	Woven polypropylene-polypropylene film laminate²	2.8 cc/ft2 - CaCO3/dry Acronal A3234 (53% by	Worse
		volume CaCO3)
27	Woven polypropylene-polypropylene film laminate²	4.1 cc/ft2 - CaCO3/dry Acronal V275 (53% by	Worse
		volume CaCO3)
	Acronal S400	acrylic emulsion	2.3
	Acronal A3234	acrylic emulsion	1.2
	Acronal V275	acrylic emulsion	1.9

^1-2oz/yd non-woven polypropylene fabric coated on each side with 1.25 mils coex layer. On the side in contact with the skid-resistant layer the coex layer comprise 1.0 mil layer PP/LDPE blend and a 0.25 mils
# layer comprising a copolymer of ethylene and methyl acrylate. The coex layer on the other side of the non-woven comprises a 1 mil layer of a PP/LDPE blend and a .25 mil mayer comprising an ethylene/propylene copolymer

EXAMPLE 3

Adhesion of the non-skid coating to the support sheet is measured in a peel adhesion test using a pre-formed pressure sensitive tape. A 2″ wide preformed tape, “Preprufe® Tape”, is applied to the non-skid coated face of the underlayment. The sample is rolled 4 times, at 1 second per pass, with a 30 lb roller. Adhesion is measured in a T-peel adhesion test 15 min after rolling at a cross head speed of 2″ per minute with an Instron mechanical tester. Results for various underlayments comprising a woven polypropylene mesh coated with a filled textured binder are shown in Table 2. Note that all underlayments, except for that comprising gilsonite, passes the minimum adhesion requirement for an underlayment comprising a filled textured binder. Also note that the 3 underlayments comprising the acrylic emulsion binders in the non-skid layer also pass the minimum adhesion requirement. However, these underlayments exhibit poor wet skid resistance as noted in example 2 because these binders are water-based and comprise a surfactant. These binders have poor wet adhesion to the support sheet. It is believed that the surfactant also lowers the surface tension of water on the wet surface which contributes to poor wet skid resistance.

TABLE 2


		Avg.	Coating
		Load	Volume
Binder Trade Name	Binder Type*	(pli)	(cc/ft2)

Elastotac H130	hydrocarbon resin	1.9	2.0
Gilsonite		0.1	3.3
Neoprene	Chloroprene rubber	1.9	1.0
	Butyl rubber	3.4	0.9
Acronal S400	acrylic emulsion	2.3	4.0
Acronal A3234	acrylic emulsion	1.2	2.8
Acronal V275	acrylic emulsion	1.9	4.1
	SEBS PSA	3.3	1.6

*53 percent filler, CaCO3, by volume for all formulations

EXAMPLE 4

For embodiments comprising a filled textured binder texturing may be observed via scanning electron microscopy SEM. SEM photomicrographs were recorded for a membranes comprising a woven polypropylene support sheet coated with binders comprising an SEBS adhesive filled with CaCO3. The volume fraction of filler was varied between 53 percent and 27 percent by volume. See FIGS. 7A, 7B, and & 7C for non-skid coatings comprising 53 percent, 38 percent, and 27 percent, respectively. Note that texturing may be observed even down to 27 percent by volume of filler.

Claims

1. A pedestrian trafficable surface that is skid-resistant when wet and which comprises a roofing substrate or a flooring substrate having a non-skid coating comprising a pressure sensitive adhesive or a filled textured binder.

2. The surface of claim 1 wherein the filler in said binder is substantially coated with binder.

3. The surface of claim 1 wherein filled binder protrudes from the surface.

4. A roofing underlayment comprising at least one support layer having first and second opposite major surfaces, and a pressure sensitive layer attached to said first major surface of said at least one support layer, such that upon application of said underlayment to a roof, said pressure sensitive layer provides a skid resistant surface for foot traffic thereon.

5. The roofing underlayment of claim 4, wherein said at least one support layer is a woven or non-woven fabric.

6. The roofing underlayment of claim 4, wherein said at least one support layer is a polyolefin film.

7. The roofing underlayment of claim 4, wherein said at least one support layer comprises spun bonded polypropylene or woven polypropylene.

8. The roofing underlayment of claim 4, wherein said pressure sensitive layer comprises a rubber selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-butadiene-styrene block copolymers, styrene-ethylene-butylene-styrene block copolymers strene/butadiene rubber, natural rubber, silicone rubber, butyl rubber, polyisoprene, polyisobutylene, chloroprene, ethylene-propylene rubber, ethylene alpha olefin, polybutadiene, nitrile rubbers, and acrylic rubber.

9. The roofing underlayment of claim 4 wherein the pressure sensitive adhesive layer is less than about 10 microns thick.

10. The roofing underlayment of claim 4 wherein the pressure sensitive adhesive layer is preferably less than about 5 microns thick.

11. The roofing underlayment of claim 4 wherein the underlayment width is less than about 30 inches.

12. A roofing underlayment comprising at least one support layer having first and second opposite major surfaces, and a filled textured binder layer attached to said first major surface of said at least one support layer, such that upon application of said underlayment to a roof, said filled textured binder layer provides a skid resistant surface for foot traffic thereon.

13. The underlayment of claim 12 wherein the filler is substantially coated with the binder

14. The roofing underlayment of claim 12, wherein said at least one support layer is a woven or non-woven fabric.

15. The roofing underlayment of claim 12, wherein said at least one support layer is a polyolefin film.

16. The roofing underlayment of claim 12, wherein said at least one support layer comprises spun bonded polypropylene or woven polpropylene.

17. The roofing underlayment of claim 12, wherein said binder is a pressure sensitive adhesive comprising a rubber selected from the group consisting of styrene/isoprene/styrene block copolymers, styrene-butadiene-styrene block copolymers, styrene-ethylene-butylene-styrene block copolymers, styrene/butadiene rubber, natural rubber, silicone rubber, butyl rubber, polyisoprene, polyisobutylene, chloroprene, ethylene-propylene rubber, ethylene alpha olefin, polybutadiene, nitrile rubbers, and acrylic rubber.

18. The roofing underlayment of claim 12, wherein said binder is a non-pressure sensitive rubber selected from the group consisting of styrene/isoprene/styrene block copolymers, styrene/butadiene/styrene block copolymers, styrene/ethylene/butylene/styrene block copolymers, styrene/butadiene rubber, natural rubber, silicone rubber, butyl rubber, polyisoprene, polyisobutylene, chloroprene, ethylene-propylene rubber, ethylene alpha olefin, polybutadiene, nitrile rubbers, thermoplastic polyurethanes (TPUs), thermoplastic polyolefins (TPOs), and acrylic rubber.

19. The roofing underlayment of claim 12, wherein said binder is a resin selected from the group including hydrocarbon resins, C-5 hydrocarbon resins, C-9 hydrocarbon resins, (C-5)₂hydrocarbon resins, rosin acids, rosin esters, terpene resins, coumarone indene resins, phenol formaldehyde resins, urea formaldehyde resins, melamine resins, polyester resins, acrylic resins, alkyd resins, and bitumen.

20. The roofing underlayment of claim 12 wherein the filled textured binder layer comprises a filler and the volume percent of filler is more than about 25 percent.

21. The roofing underlayment of claim 12 wherein the filled textured binder adhesive layer comprises a filler and the volume percent of filler is preferably more than about 45 percent.

22. The roofing underlayment of claim 12 wherein the average filler particle size is less than about 100 microns

23. The roofing underlayment of claim 12 wherein the average particle size is less than about 50 microns.

24. The roofing underlayment of claim 12 wherein the average filler particle size is less than about 25 microns.

25. The roofing underlayment of claim 12 wherein the volume of coating is less than about 10 cc/ft2.

26. The roofing underlayment of claim 12 wherein the volume of coating is less than about 5 cc/ft2.

27. The roofing underlayment of claim 12 wherein the volume of coating is less than about 2 cc/ft2.

28. The roofing underlayment of claim 12 wherein the filler is inorganic or organic,

29. The roofing underlayment of claim 12 wherein the filler is hydratable.

30. The roofing underlayment of claim 12 wherein the width of the underlayment is less than about 30 inches.

31. A flexible, rollable roofing underlayment comprising at least one support layer having first and second opposite major surfaces, and a pressure sensitive adhesive layer or a filled textured binder layer attached to said first major surface of said at least one support layer, such that upon application of said underlayment to a roof by unrolling, said filled textured binder layer provides a skid resistant surface for foot traffic thereon, and a pressure sensitive adhesive attached to said second major surface of said at least one support layer such that upon application of said underlayment to a roof the membrane is adhered to said roof.

32. The underlayment of claim 31 wherein said support layer is a cross-laminated high density polyethylene film

33. The underlayment of claim 31 wherein the pressure sensitive adhesive attached to said second major face of said at least one support layer comprises rubber and bitumen.

34. A rigid product comprising a rigid substrate selected from plywood or oriented strand board having the non-skid surface of claim 1.

35. A roofing underlayment positioned between a roof support structure and an overlayment, comprising at least one support layer having first and second opposite major surfaces, said first major surface abutting said roof support structure, and a pressure sensitive layer or a filled textured binder layer attached to said second major surface of said at least one support layer, such that upon application of said overlayment to said roof and over said underlayment, said pressure sensitive layer provides a skid resistant surface for foot traffic thereon.

36. The roofing underlayment of claim 35, wherein said at least one support layer is a woven or non-woven fabric.

37. The roofing underlayment of claim 35 wherein said at least one support layer is a polyolefin film.

38. The roofing underlayment of claim 35 wherein said at least one support layer comprises spun bonded polypropylene.

39. The roofing underlayment of claim 35 wherein said pressure sensitive layer comprises a rubber selected from the group consisting of styrene/isoprene/styrene copolymer, ethylene/butylene/styrene block copolymer, styrene butadiene rubber, natural rubber, silicone, butyl rubber, isoprene, butadiene and acrylic rubber.

40. The roofing underlayment of claims 35 wherein the support layer in said underlayment comprises one or more layers of polymer and one or more layers of fabric.

41. A method of waterproofing a roof, comprising the steps of:

1) providing a roof deck;

2) providing a roll of roof underlayment comprising at least one support layer having a skid-resistant coating therein comprising a layer of pressure sensitive adhesive or filled textured binder; and

3) unrolling said underlayment and applying it to said roof deck.

42. The method of claim 41, wherein said underlayment is applied to said roof deck by mechanical fastening.

43. The method of claim 41, wherein said underlayment is applied to said roof deck by adhesively adhering said underlayment to said deck.

44. An article comprising a product packaged within a flexible packaging, said packaging having the non-skid surface of claim 1 coated on its exterior.

45. An organic or inorganic roofing felt coated having as its exterior surface, the non-skid surface of claim 1.