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US20050130851A1 - Nanostructured lubricating oil - Google Patents

Nanostructured lubricating oil Download PDF

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Publication number
US20050130851A1
US20050130851A1 US10/735,831 US73583103A US2005130851A1 US 20050130851 A1 US20050130851 A1 US 20050130851A1 US 73583103 A US73583103 A US 73583103A US 2005130851 A1 US2005130851 A1 US 2005130851A1
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US
United States
Prior art keywords
lubricating oil
oil
nanostructured
nanometered
graphite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/735,831
Inventor
Ming-Theng Wang
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Individual
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Individual
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Publication date
Application filed by Individual filed Critical Individual
Priority to US10/735,831 priority Critical patent/US20050130851A1/en
Publication of US20050130851A1 publication Critical patent/US20050130851A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/02Carbon; Graphite
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/105Silica
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/14Group 7
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/16Groups 8, 9, or 10
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/055Particles related characteristics
    • C10N2020/06Particles of special shape or size
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure

Definitions

  • the present invention relates to lubricating oils and, more particularly, to a nanostructured lubricating oil that forms a protective oil film on the surface of the mechanical parts when applied to the engine of a motor vehicle.
  • Engine oil is adapted to form a lubricating medium between parts inside the engine of a motor vehicle, reducing friction between the parts and simultaneously dissipating heat from the parts during operation of the engine.
  • Regular engine oil is formed by mixing an oil with additives.
  • additives may be used to improve the surface condition of the mechanical parts (for example, cleaning agent, heat dissipating agent, high pressure/wear protecting agent, corrosion protective agent, friction modifier, etc.), to improve oil grade (for example, viscosity improver, flow point improver, elasticity modifier, etc.), or to save oil consumption (for example, age resistor, metal deactivator, bubble eliminator).
  • additives are active and oil soluble, and can be mixed in a mineral-contained basal oil to improve the quality of the oil and/or to let the oil have special properties.
  • the type and amount of additives determine the performance of the lubricating oil.
  • Additives in an engine oil may improve the quality of the basal oil (VT reaction), or eliminate certain material properties (aging under a high temperature or oxide-contained environment.
  • an engine oil has the functions of lubricating and cleaning the mechanical parts of the engine, protecting the mechanical parts of the engine against corrosion, stabilizing the aging of the mechanical parts of the engine, and cooling down the temperature of the mechanical parts of the engine.
  • Conventional lubricating oils provide different features. However, it is still desirable to improve the performance of conventional lubricating oils on lubrication and heat dissipation.
  • the present invention has been accomplished under the circumstances in view. It is one object of the present invention to provide a nanostructured lubricating oil, which contains nanometered graphite that fills up the holes in the surface of the mechanical parts when the nanostructured lubricating oil is used to lubricate the engine of a motor vehicle. It is another object of the present invention to provide a nanostructure lubricating oil, which forms a three-layer oil film of ferric oxide-silicon-oxide-graphite when applied to the engine of a motor vehicle, improving heat dissipating, lubricating, and wear resisting performance.
  • the nanostructured lubricating oil is comprised of one part of nanometered graphite and four parts of a lubricating oil.
  • the nanostructured lubricating oil is comprised of one part of a first synthesized oil and nine parts of a second synthesized oil.
  • the first synthesized oil is comprised of a low viscosity lubricating oil and equal amount of nanometered silicon oxide and nanometered ferric oxide mixed in the low viscosity lubricating oil.
  • the second synthesized oil is comprised of one part of nanometered graphite and four parts of a standard viscosity lubricating oil.
  • FIG. 1 is a schematic drawing showing the formation of an oil film according to the present invention.
  • a nanostructured lubricating oil according to the first embodiment of the present invention is obtained by: grinding graphite into graphite powder of particle diameter within 100 ⁇ 200 nanometers, and then mixing 20 wt % of the graphite powder with 80 wt % of lubricating oil of standard viscosity. Because the nanostructured lubricating oil contains nanometered graphite molecules, nanometered graphite will fill up the holes in the surface of the mechanical parts when lubricating the engine with the nanostructured lubricating oil. Therefore, the nanostructured lubricating oil smoothes the surface of the mechanical parts, improving the wearing resistance power of the mechanical parts of the engine.
  • a nanostructured lubricating oil according to the second embodiment of the present invention is obtained by: grinding silicon oxide and ferric oxide into powder of particle diameter within about 20 nanometers, and then mixing 0.5 wt % of the nanometered silicon oxide with 0.5 wt % of the nanometered ferric oxide with 99 wt % low viscosity lubricating oil to form a first synthesized oil, and then mixing 20 wt % of the first synthesized oil with 80 wt % of the nanostructured lubricating oil thus obtained from the aforesaid first embodiment to form a second synthesized oil, and then mixing 10 wt % of the first synthesized oil with 90 wt % of the second synthesized oil to form the desired nanostructured lubricating oil.
  • the nanostructured lubricating oil forms an oil film on the surface of the mechanical parts when applied to lubricate the engine.
  • the oil film is a three-layer structure comprising a bottom ferric oxide layer 3 , a top graphite layer 1 , and an intermediate silicon oxide layer 2 .
  • the oil film fills up holes in the surface of the mechanical parts 4 , improving the wear resistance power as well as the heat absorbing and dissipating power of the mechanical parts 4 , and reducing the coefficient of expansion of the mechanical parts 4 .

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A nanostructured lubricating oil formed by mixing 80 wt % of a standard viscosity lubricating oil with 20 wt % of nanometered graphite. Alternatively, nanometered silicon oxide and nanometered ferric oxide may be added to the graphite-contained nanostructured lubricating oil so as to form a three-layer structure of ferric oxide-silicon-oxide-graphite, improving heat dissipating, lubricating, and wear resisting performance.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to lubricating oils and, more particularly, to a nanostructured lubricating oil that forms a protective oil film on the surface of the mechanical parts when applied to the engine of a motor vehicle.
  • 2. Description of the Related Art
  • Engine oil (lubricating oil) is adapted to form a lubricating medium between parts inside the engine of a motor vehicle, reducing friction between the parts and simultaneously dissipating heat from the parts during operation of the engine. Regular engine oil is formed by mixing an oil with additives. Various additives may be used to improve the surface condition of the mechanical parts (for example, cleaning agent, heat dissipating agent, high pressure/wear protecting agent, corrosion protective agent, friction modifier, etc.), to improve oil grade (for example, viscosity improver, flow point improver, elasticity modifier, etc.), or to save oil consumption (for example, age resistor, metal deactivator, bubble eliminator). These additives are active and oil soluble, and can be mixed in a mineral-contained basal oil to improve the quality of the oil and/or to let the oil have special properties. The type and amount of additives determine the performance of the lubricating oil. Additives in an engine oil may improve the quality of the basal oil (VT reaction), or eliminate certain material properties (aging under a high temperature or oxide-contained environment. In general, an engine oil has the functions of lubricating and cleaning the mechanical parts of the engine, protecting the mechanical parts of the engine against corrosion, stabilizing the aging of the mechanical parts of the engine, and cooling down the temperature of the mechanical parts of the engine. Conventional lubricating oils provide different features. However, it is still desirable to improve the performance of conventional lubricating oils on lubrication and heat dissipation.
  • SUMMARY OF THE INVENTION
  • The present invention has been accomplished under the circumstances in view. It is one object of the present invention to provide a nanostructured lubricating oil, which contains nanometered graphite that fills up the holes in the surface of the mechanical parts when the nanostructured lubricating oil is used to lubricate the engine of a motor vehicle. It is another object of the present invention to provide a nanostructure lubricating oil, which forms a three-layer oil film of ferric oxide-silicon-oxide-graphite when applied to the engine of a motor vehicle, improving heat dissipating, lubricating, and wear resisting performance.
  • According to a first embodiment of the present invention, the nanostructured lubricating oil is comprised of one part of nanometered graphite and four parts of a lubricating oil. According to a second embodiment of the present invention, the nanostructured lubricating oil is comprised of one part of a first synthesized oil and nine parts of a second synthesized oil. The first synthesized oil is comprised of a low viscosity lubricating oil and equal amount of nanometered silicon oxide and nanometered ferric oxide mixed in the low viscosity lubricating oil. The second synthesized oil is comprised of one part of nanometered graphite and four parts of a standard viscosity lubricating oil.
  • BRIEF DESCRIPTION OF THE DRAWING
  • FIG. 1 is a schematic drawing showing the formation of an oil film according to the present invention.
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • A nanostructured lubricating oil according to the first embodiment of the present invention is obtained by: grinding graphite into graphite powder of particle diameter within 100˜200 nanometers, and then mixing 20 wt % of the graphite powder with 80 wt % of lubricating oil of standard viscosity. Because the nanostructured lubricating oil contains nanometered graphite molecules, nanometered graphite will fill up the holes in the surface of the mechanical parts when lubricating the engine with the nanostructured lubricating oil. Therefore, the nanostructured lubricating oil smoothes the surface of the mechanical parts, improving the wearing resistance power of the mechanical parts of the engine.
  • A nanostructured lubricating oil according to the second embodiment of the present invention is obtained by: grinding silicon oxide and ferric oxide into powder of particle diameter within about 20 nanometers, and then mixing 0.5 wt % of the nanometered silicon oxide with 0.5 wt % of the nanometered ferric oxide with 99 wt % low viscosity lubricating oil to form a first synthesized oil, and then mixing 20 wt % of the first synthesized oil with 80 wt % of the nanostructured lubricating oil thus obtained from the aforesaid first embodiment to form a second synthesized oil, and then mixing 10 wt % of the first synthesized oil with 90 wt % of the second synthesized oil to form the desired nanostructured lubricating oil.
  • Because the specific gravity of silicon oxide and ferric oxide are 2.3˜2.6 and 7.8 respectively, and the diameter of graphite molecule is greater than silicon oxide and ferric oxide, the nanostructured lubricating oil forms an oil film on the surface of the mechanical parts when applied to lubricate the engine. As illustrated in FIG. 1, the oil film is a three-layer structure comprising a bottom ferric oxide layer 3, a top graphite layer 1, and an intermediate silicon oxide layer 2. The oil film fills up holes in the surface of the mechanical parts 4, improving the wear resistance power as well as the heat absorbing and dissipating power of the mechanical parts 4, and reducing the coefficient of expansion of the mechanical parts 4.
  • Although particular embodiments of the invention have been described in detail for purposes of illustration, various modifications and enhancements may be made without departing from the spirit and scope of the invention. Accordingly, the invention is not to be limited except as by the appended claims.

Claims (5)

1. A nanostructured lubricating oil comprising one part of nanometered graphite and four parts of a lubricating oil.
2. The nanostructured lubricating oil as claimed in claim 1, wherein said nanometered graphite has a molecule diameter within about 100˜200 nanometers.
3. A nanostructured lubricating oil comprising one part of a first synthesized oil and nine parts of a second synthesized oil, said first synthesized oil comprising a low viscosity lubricating oil and equal amount of nanometered silicon oxide and nanometered ferric oxide mixed in said low viscosity lubricating oil, said second synthesized oil comprising one part of nanometered graphite and four parts of a standard viscosity lubricating oil.
4. The nanostructured lubricating oil as claimed in claim 3, wherein said nanometered graphite has a molecule diameter within about 100˜200 nanometers.
5. The nanostructured lubricating oil as claimed in claim 3, wherein said nanometered silicon oxide and said nanometered ferrite oxide have a molecule diameter within about 20 nanometers.
US10/735,831 2003-12-16 2003-12-16 Nanostructured lubricating oil Abandoned US20050130851A1 (en)

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Application Number Priority Date Filing Date Title
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090042751A1 (en) * 2007-08-11 2009-02-12 Jagdish Narayan Lubricant having nanoparticles and microparticles to enhance fuel efficiency, and a laser synthesis method to create dispersed nanoparticles
EP2105490A1 (en) 2008-03-29 2009-09-30 Stefan Graichen High temperature lubricant, in particular casting lubricant containing at least one oxidation catalyst
CN106590812A (en) * 2016-11-17 2017-04-26 江苏大学 Friction-reducing and wear-resistant composite material for titanium alloy and preparation method thereof
CZ307068B6 (en) * 2016-06-23 2017-12-27 Technická univerzita v Liberci A method of evaluation of modification of oils used in transmission systems or oils for machining of metallic materials
CN110860859A (en) * 2019-11-29 2020-03-06 华中科技大学 A processing method for inhibiting the wear of diamond tools when cutting silicon materials
CN113383059A (en) * 2018-11-20 2021-09-10 李泓雨 Lubricating oil containing spherical graphite nanoparticles
CN114085695A (en) * 2021-09-26 2022-02-25 希玛石油制品(镇江)有限公司 Special oil for rust prevention and lubrication of high-speed moving assembly and preparation process thereof
PL441075A1 (en) * 2022-04-30 2023-11-06 Uniwersytet Warszawski Magnetorheological fluid based on metal oxides and method of its preparation

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5782954A (en) * 1995-06-07 1998-07-21 Hoeganaes Corporation Iron-based metallurgical compositions containing flow agents and methods for using same
US20040209782A1 (en) * 2002-05-30 2004-10-21 Ashland Inc. Enhancing thermal conductivity of fluids with graphite nanoparticles and carbon nanotube
US6944930B2 (en) * 2000-02-24 2005-09-20 Mitsubishi Materials Corporation Method for manufacturing low-oxygen copper

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5782954A (en) * 1995-06-07 1998-07-21 Hoeganaes Corporation Iron-based metallurgical compositions containing flow agents and methods for using same
US6944930B2 (en) * 2000-02-24 2005-09-20 Mitsubishi Materials Corporation Method for manufacturing low-oxygen copper
US20040209782A1 (en) * 2002-05-30 2004-10-21 Ashland Inc. Enhancing thermal conductivity of fluids with graphite nanoparticles and carbon nanotube

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090042751A1 (en) * 2007-08-11 2009-02-12 Jagdish Narayan Lubricant having nanoparticles and microparticles to enhance fuel efficiency, and a laser synthesis method to create dispersed nanoparticles
US7994105B2 (en) * 2007-08-11 2011-08-09 Jagdish Narayan Lubricant having nanoparticles and microparticles to enhance fuel efficiency, and a laser synthesis method to create dispersed nanoparticles
EP2105490A1 (en) 2008-03-29 2009-09-30 Stefan Graichen High temperature lubricant, in particular casting lubricant containing at least one oxidation catalyst
DE102008016348A1 (en) 2008-03-29 2009-10-15 Stefan Graichen High-temperature lubricant, in particular die lubricant, containing at least one oxidation catalyst
CZ307068B6 (en) * 2016-06-23 2017-12-27 Technická univerzita v Liberci A method of evaluation of modification of oils used in transmission systems or oils for machining of metallic materials
CN106590812A (en) * 2016-11-17 2017-04-26 江苏大学 Friction-reducing and wear-resistant composite material for titanium alloy and preparation method thereof
CN113383059A (en) * 2018-11-20 2021-09-10 李泓雨 Lubricating oil containing spherical graphite nanoparticles
CN110860859A (en) * 2019-11-29 2020-03-06 华中科技大学 A processing method for inhibiting the wear of diamond tools when cutting silicon materials
CN114085695A (en) * 2021-09-26 2022-02-25 希玛石油制品(镇江)有限公司 Special oil for rust prevention and lubrication of high-speed moving assembly and preparation process thereof
PL441075A1 (en) * 2022-04-30 2023-11-06 Uniwersytet Warszawski Magnetorheological fluid based on metal oxides and method of its preparation
PL246587B1 (en) * 2022-04-30 2025-02-17 Inst Chemii Fizycznej Polskiej Akademii Nauk Ferromagnetic additive to magnetorheological fluid, method of obtaining it, magnetorheological fluid containing it and method of obtaining it

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