US20020088169A1 - Method of storing solar energy - Google Patents
Method of storing solar energy Download PDFInfo
- Publication number
- US20020088169A1 US20020088169A1 US10/091,066 US9106602A US2002088169A1 US 20020088169 A1 US20020088169 A1 US 20020088169A1 US 9106602 A US9106602 A US 9106602A US 2002088169 A1 US2002088169 A1 US 2002088169A1
- Authority
- US
- United States
- Prior art keywords
- charcoal
- energy
- wood
- amount
- mio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims description 14
- 239000003610 charcoal Substances 0.000 claims abstract description 39
- 239000002028 Biomass Substances 0.000 claims abstract description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 11
- 239000001257 hydrogen Substances 0.000 claims abstract description 11
- 230000029553 photosynthesis Effects 0.000 claims description 3
- 238000010672 photosynthesis Methods 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims 2
- 239000002023 wood Substances 0.000 abstract description 23
- 238000002485 combustion reaction Methods 0.000 abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000003245 coal Substances 0.000 description 7
- 239000000446 fuel Substances 0.000 description 7
- 241000273930 Brevoortia tyrannus Species 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 230000000243 photosynthetic effect Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000002309 gasification Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 229940090441 infed Drugs 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1693—Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
Definitions
- the invention relates to a method of storing solar energy in conjunction with reducing the CO 2 content of air.
- the invention is based on the object of providing a method of producing and storing energy from solar energy while simultaneously effecting a reduction in the CO 2 content of the air.
- the method according to the invention comprises the following method steps:
- the remaining fraction may be converted in known manner into energy or an energy source like heat, electricity or hydrogen.
- the land, on which the plant biomass had been generated prior to the conversion into charcoal may be replanted in suitable manner and thus be used again for producing photosynthetic biomass and charcoal therefrom.
- Charcoal which has been produced from photosynthetic biomass in known manner, is stored in a bunker plant.
- the charcoal is infed into the bunker plant and outfed therefrom upon request by using technically conventional conveying means.
- subterraneous cavities such as present in a coal, ore or salt mine or the like as well as known above-ground constructions are considered for such bunker plants.
- the charcoal storage is intended for time periods of up to 20 years or more.
- the charcoal is stored under non-ignitable protective gas having a density greater than air such as CO 2 or, if desired, a rare gas.
- Each bunker plant is equipped with known means in a manner such that the stored charcoal is protected from water ingress and/or excess temperatures.
- a number of mutually separate charcoal reservoirs may be provided in a given bunker plant.
- the CO 2 content of the air can be reduced if either (a) wood production is increased whereby more CO 2 is removed, and/or (b) production of CO 2 by wood combustion is reduced, whereby the additionally produced wood and/or the non-burned wood is converted into charcoal and stored in accordance with Example 1.
- the conversion into charcoal has the added advantage that during this process valuable side products such as acetic acid and homologues thereof, methanol and acetone are produced and thus are obtained in desired manner from renewable resources and not from fossile sources.
- a typical Texaco plant for coal gasification (Kirk-Othmer, ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY 3rd Ed. Vol. 12, Wiley, New York, pp. 959/960) having a capacity of 2.83 ⁇ 10 6 m 3 /d of raw hydrogenis charged with 1,852 t/d of finely divided charcoal (of which 83.4% are process charcoal).
- charcoal has the advantage of being free of any sulfur and heavy metal catalyst poisons whereby the useful life of the catalysts is prolonged and their efficiency is improved while special gas purification operations become superfluous.
- a typical Texaco plant processing 1,852 t/d or 0.676 mio t p.a. of charcoal is confronted with 25% or 6.1 mio t p.a. of charcoal originating from storage in 2005 whereby 9 such plants can be operated.
- Sizable storage of the charcoal thus may be the foundation of the reliability of the logistics for the solar hydrogen economy.
- the stored charcoal can be accessed for hydrogen production at any desired time because the main amount thereof must remain stored for sustained energy provision by reversing combustion.
- the thus generated amount of CO 2 corresponds to the amount which has been removed from the atmosphere before and which has been bound in the photosynthetic biomass of wood.
- the thus generated amount of CO 2 is thus balanced by the corresponding amount of photosynthetic biomass which has been formed.
- the thus produced hydrogen substitutes other fuels, particularly fuels originating from fossile sources, which form CO 2 on combustion, and preferably serves for generating energy by means of fuel cells.
- reaction (1) may also be conducted such that the synthesis gas, which is obtained by reaction (1), is reacted by known, particularly catalytic processes to form industrial products for use in many technical fields.
- these products are also obtained from renewable resources without requiring recourse to fossile raw materials like crude oil, natural gas or coal.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Carbon And Carbon Compounds (AREA)
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
- Charge And Discharge Circuits For Batteries Or The Like (AREA)
- Treating Waste Gases (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/766,262 US7458999B2 (en) | 1999-09-06 | 2004-01-27 | Method of storing solar energy |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19942398.9 | 1999-09-06 | ||
| DE19942398A DE19942398A1 (de) | 1999-09-06 | 1999-09-06 | Verfahren zur Speicherung von Solarenergie |
| PCT/EP2000/008649 WO2001018151A1 (fr) | 1999-09-06 | 2000-09-05 | Procede d'accumulation d'energie solaire |
Related Parent Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2000/008649 Continuation WO2001018151A1 (fr) | 1999-09-06 | 2000-09-05 | Procede d'accumulation d'energie solaire |
| US10/055,105 Continuation US6592598B2 (en) | 1996-08-30 | 2002-01-23 | Method, instruments, and kit for autologous transplantation |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/090,922 Continuation US6592599B2 (en) | 1996-08-30 | 2002-03-05 | Method, instruments, and kit for autologous transplantation |
| US10/766,262 Continuation-In-Part US7458999B2 (en) | 1999-09-06 | 2004-01-27 | Method of storing solar energy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20020088169A1 true US20020088169A1 (en) | 2002-07-11 |
Family
ID=7920918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/091,066 Abandoned US20020088169A1 (en) | 1999-09-06 | 2002-03-05 | Method of storing solar energy |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20020088169A1 (fr) |
| EP (1) | EP1222238B1 (fr) |
| AT (1) | ATE359344T1 (fr) |
| AU (1) | AU7417000A (fr) |
| CA (1) | CA2383151A1 (fr) |
| DE (2) | DE19942398A1 (fr) |
| WO (1) | WO2001018151A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090155875A1 (en) * | 2005-02-16 | 2009-06-18 | Massachusetts Institute Of Technology | Methods to Enhance Carbon Monoxide Dehydrogenase Activity and Uses Thereof |
| US20100178231A1 (en) * | 2006-12-22 | 2010-07-15 | Turney Christian Stewart Macgregor | Method of Sequestering Carbon Dioxide |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10162071A1 (de) * | 2001-08-16 | 2003-02-27 | Hans-Joachim Boltersdorf | Verfahren zum Abreichern von Kohlendioxid, Verfahren zur Energiegewinnung, Energie bzw. Strom, COdukt, Verfahren zum Handeln von Kohlenstoff, von Kohlenstoffäquivalenten und COdukten |
| DE102007018875A1 (de) | 2007-04-19 | 2008-10-23 | COLLISI, Jörg | Vorrichtung zur Verringerung des CO2-Gehalts in der Luft |
| DE102009057109A1 (de) * | 2009-12-04 | 2011-06-09 | Tetzlaff, Karl-Heinz, Dipl.-Ing. | Simultane Herstellung von teerfreiem Synthesegas und Kohlenstoff aus Biomasse |
| US20120021123A1 (en) * | 2010-01-19 | 2012-01-26 | Leveson Philip D | process to sequester carbon, mercury, and other chemicals |
| DE202012012676U1 (de) * | 2012-04-26 | 2014-01-29 | Monika Holthausen | Holzkohleerzeuger für Kaminöfen |
| DE202020101310U1 (de) | 2020-03-10 | 2021-06-11 | Jörg Mayer | Pyrolyse-Vorrichtung |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3942956A (en) * | 1974-07-12 | 1976-03-09 | Mifuji Iron Works, Ltd. | Process for eliminating nitrogenous ingredients from solid fuel |
| US4272322A (en) * | 1978-04-03 | 1981-06-09 | Masahiro Kobayashi | Method for manufacturing charcoals from paper sludge |
| US5436516A (en) * | 1991-03-01 | 1995-07-25 | Semiconductor Energy Laboratory Co., Ltd. | Inertial device for energy storage |
| US5707762A (en) * | 1993-08-24 | 1998-01-13 | Hannelore Binsmaier Nee Gallin-Ast | Modular power plant for the generation of electrical energy from solar energy |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19618213A1 (de) * | 1996-05-07 | 1997-11-13 | Petersen Hugo Verfahrenstech | Verfahren zur Erzeugung von Brenngas und Anlage zur Durchführung des Verfahrens |
| NL1009745C2 (nl) * | 1998-07-27 | 2000-01-28 | Stichting Energie | Werkwijze en inrichting voor het vormen van synthesegas uit biomassa en reststoffen. |
-
1999
- 1999-09-06 DE DE19942398A patent/DE19942398A1/de not_active Ceased
-
2000
- 2000-09-05 AU AU74170/00A patent/AU7417000A/en not_active Abandoned
- 2000-09-05 AT AT00962441T patent/ATE359344T1/de not_active IP Right Cessation
- 2000-09-05 DE DE50014245T patent/DE50014245D1/de not_active Expired - Lifetime
- 2000-09-05 EP EP00962441A patent/EP1222238B1/fr not_active Expired - Lifetime
- 2000-09-05 WO PCT/EP2000/008649 patent/WO2001018151A1/fr not_active Ceased
- 2000-09-05 CA CA002383151A patent/CA2383151A1/fr not_active Abandoned
-
2002
- 2002-03-05 US US10/091,066 patent/US20020088169A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3942956A (en) * | 1974-07-12 | 1976-03-09 | Mifuji Iron Works, Ltd. | Process for eliminating nitrogenous ingredients from solid fuel |
| US4272322A (en) * | 1978-04-03 | 1981-06-09 | Masahiro Kobayashi | Method for manufacturing charcoals from paper sludge |
| US5436516A (en) * | 1991-03-01 | 1995-07-25 | Semiconductor Energy Laboratory Co., Ltd. | Inertial device for energy storage |
| US5707762A (en) * | 1993-08-24 | 1998-01-13 | Hannelore Binsmaier Nee Gallin-Ast | Modular power plant for the generation of electrical energy from solar energy |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090155875A1 (en) * | 2005-02-16 | 2009-06-18 | Massachusetts Institute Of Technology | Methods to Enhance Carbon Monoxide Dehydrogenase Activity and Uses Thereof |
| US20100178231A1 (en) * | 2006-12-22 | 2010-07-15 | Turney Christian Stewart Macgregor | Method of Sequestering Carbon Dioxide |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE359344T1 (de) | 2007-05-15 |
| EP1222238B1 (fr) | 2007-04-11 |
| CA2383151A1 (fr) | 2001-03-15 |
| WO2001018151A1 (fr) | 2001-03-15 |
| DE19942398A1 (de) | 2001-03-15 |
| EP1222238A1 (fr) | 2002-07-17 |
| DE50014245D1 (de) | 2007-05-24 |
| AU7417000A (en) | 2001-04-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |