US20020074073A1 - Polyurethane coating process for carpet backing - Google Patents
Polyurethane coating process for carpet backing Download PDFInfo
- Publication number
- US20020074073A1 US20020074073A1 US09/993,864 US99386401A US2002074073A1 US 20020074073 A1 US20020074073 A1 US 20020074073A1 US 99386401 A US99386401 A US 99386401A US 2002074073 A1 US2002074073 A1 US 2002074073A1
- Authority
- US
- United States
- Prior art keywords
- polyurethane
- greige
- backing
- primary backing
- carpet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000576 coating method Methods 0.000 title claims description 6
- 239000011527 polyurethane coating Substances 0.000 title description 3
- 239000004814 polyurethane Substances 0.000 claims abstract description 109
- 229920002635 polyurethane Polymers 0.000 claims abstract description 109
- 238000000034 method Methods 0.000 claims abstract description 53
- 239000000835 fiber Substances 0.000 claims abstract description 20
- 230000008569 process Effects 0.000 claims description 40
- 238000000137 annealing Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 14
- 229920005862 polyol Polymers 0.000 claims description 13
- 150000003077 polyols Chemical class 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 239000012948 isocyanate Substances 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 10
- 150000002513 isocyanates Chemical class 0.000 claims description 10
- 239000007921 spray Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003063 flame retardant Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 12
- 239000000178 monomer Substances 0.000 abstract 1
- 239000004816 latex Substances 0.000 description 29
- 229920000126 latex Polymers 0.000 description 29
- 230000001070 adhesive effect Effects 0.000 description 14
- 238000001723 curing Methods 0.000 description 13
- 239000000853 adhesive Substances 0.000 description 12
- 230000007423 decrease Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000005056 polyisocyanate Substances 0.000 description 3
- 229920001228 polyisocyanate Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 150000002483 hydrogen compounds Chemical class 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- 229920001944 Plastisol Polymers 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- -1 aromatic isocyanates Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
- D06N3/009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin by spraying components on the web
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0063—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
- D06N7/0071—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing
- D06N7/0086—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing characterised by the cushion backing, e.g. foamed polyurethane
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/068—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
Definitions
- the present invention relates to improved methods for adhering secondary backing to tufted or woven carpeting employing polyurethane adhesive systems.
- the secondary backing In order to achieve suitable annealing strength, the secondary backing must be in direct contact with the greige, and a sufficient amount of adhesive must be interjacent the greige and the secondary backing to ensure complete wet out of the fibers.
- Another key property is, the fiber lock, which measures the force necessary to pull face fibers from the carpet.
- Latex is typically applied by methods involving roll over flatbed or roll over roll processes. Regardless, of the method used, the greige is coated with an adhesive precoat of latex, and the secondary backing, also coated with latex, is married to the greige and cured.
- latex is a popular adhesive
- carpet prepared from latex displays numerous shortcomings.
- the strength and hydrolytic stability of latex is less than desired, and latex is less durable over time than alternative polymer systems such as PVC plastisol or polyurethane.
- latex curing requires the evaporation of large amounts of water during cure, a process that is both expensive and energy intensive.
- the use of latex also hinders the effective recycling of manufacturing remnants and used carpet at the end of its life cycle.
- polyurethane adhesives are capable of forming carpet with superior annealing strength as well as other desirable physical properties.
- technical problems have kept it from widespread use in the industry.
- polyurethane application from bulk troughs is made very difficult due to premature polymerization in the delivery line.
- polyurethane is applied as “froth,” polymerized prior to application and sprayed onto the primary or secondary backing before the upstream edge of a doctor blade.
- the delivery line becomes clogged retarding the flow of polyurethane to the spray apparatus.
- polyurethane begins to lose its adhesiveness soon after polymerization begins unless the manufacturer controls the polymerization rate by using heat sensitive catalysts or other chemical agents designed to maintain the viscosity of the polyurethane.
- U.S. Pat. No. 6,264,775 offers the addition of various chemical thickening agents to the polyurethane to maintain viscosity and adhesiveness.
- Another process provides for the use of multiple applications of polyurethane to the primary backing prior to joining the secondary backing. See e.g., U.S. Pat. No. 6,299,715.
- Still another technique disclosed in U.S. Pat. No. 6,299,715, is the application of both polyurethane to the primary backing and another tacky composition to the secondary backing prior to joining the two backings. None of these techniques have been favored over standard latex based carpet laminates, primarily due to the increased cost and complexity associated with building and using separate manufacturing lines to implement the new technologies.
- the present invention pertains to a polyurethane carpet annealing system which discloses two unique advantages over the prior art. First it requires only a single application of polyurethane. The lower amount of polyurethane employed in a single application significantly decreases the weight of the carpet and decreases raw material costs. Second, the polyurethane is cured at ambient temperature. The absence of an oven-curing step markedly decreases the time from application of the polyurethane to product roll-up. The carpet produced by the process exhibits acceptable fiber lock and initial secondary backing adhesion without the use of large quantities of polyurethane and without the expensive heat curing step common in other annealing systems. In combination, the two advantages significantly increase the commercial utility of the product.
- FIG. 1 illustrates a typical prior art latex-based carpet annealing process.
- FIG. 2 illustrates a prior art single application polyurethane-based carpet annealing process.
- FIG. 3 illustrates a prior art dual application polyurethane-based carpet annealing process.
- FIG. 4 illustrates a prior art polyurethane-based process that coats primary backing with polyurethane and the secondary backing with a skip-coat adhesive.
- FIG. 5 illustrates one embodiment of the present invention.
- FIG. 1 illustrates a typical prior art commercial latex-based carpet annealing process.
- the greige 5 with top carpet face 10 and bottom primary backing side 15 to which fiber lock adhesive is applied, is directed by rollers 20 to place the primary backing side 15 of the greige under trough 25 , which is supplied with latex through line 30 .
- the downstream edge of trough 25 serves as a doctor blade 35 , in conjunction with plate 40 .
- Adjusting the amount of latex applied also serves to force the latex through the primary backing 15 into the fibers. Further penetration is provided by pressure roller 45 .
- Secondary backing 55 is supplied from roll 60 and directed by rollers 65 across wheel roll 70 , which rotates in trough 75 filled with additional latex which coats the secondary backing 55 .
- the coated secondary backing 77 is pressed onto the latex-coated greige 80 by their travel through ligation rolls 85 .
- the carpet then passes through oven 90 where water is removed from the latex, and the latex cures, adhering fibers and secondary backing to form a lamellar carpet.
- FIG. 2 illustrates a single application polyurethane-based carpet annealing process.
- the greige 5 with carpet face 10 downward is fed onto a metering plate 95 .
- polyurethane “froth” 100 is placed on the backing side 15 using a mixing head 105 .
- a secondary backing 55 is then applied to the surface of the uncured polyurethane 100 using a ligation roller 85 .
- the coated and backed greige 78 is then passed through oven 90 to cure the polyurethane layer 100 .
- the carpet may then be advanced through a trimmer 115 and finally to an accumulator 120 or roll-up area.
- FIG. 3 illustrates a dual application polyurethane-based carpet annealing process.
- polyurethane 100 is applied from first line 30 .
- Doctor blade 35 in cooperation with plate 40 , limits the applied weight of polyurethane 100 and forces it into the greige 5 .
- second line 32 which supplies additional frothed polyurethane 100 .
- Doctor blade 36 in conjunction with plate 41 , adjusts the thickness of the deposited polyurethane 100 .
- the second doctor blade 36 is spaced a distance away to allow enough polyurethane 100 to be deposited to temporarily bind the secondary backing 55 before curing.
- the secondary backing 55 supplied from roll 60 , contacts the coated greige 80 below ligation roller 85 .
- press rollers 125 Prior to entry into the oven 90 for curing, press rollers 125 assist in maintaining stable contact between the secondary backing 55 and the greige 5 .
- FIG. 4 illustrates a polyurethane-based process that coats the primary backing with polyurethane and the secondary backing with a polyurethane adhesive.
- the carpet is contacted with a wheel-coated secondary backing 55 .
- the secondary backing 55 supplied from roll 60 , has been directed by rollers 65 past wheel roll 130 which rotates in trough 135 filled with wheel coating agent. Rotation of wheel roll 130 in the trough 135 coats the roll with wheel coating agent which is then transferred to the secondary backing 55 to form a wheel-coated secondary backing 140 .
- Wheel roll 130 supplies a tacky polyurethane based coating agent which is not “self-curing” and therefore does not substantially increase in viscosity over the life of the composition in the trough 135 .
- Wheel-coated secondary backing 140 mates with the polyurethane adhesive coated greige below roller 85 , which may be supplemented with a roller directly below, or a plate, to form a pair of ligation rollers or equivalent devices. The carpet then passes between press rollers 125 into oven 90 for curing.
- FIG. 5 illustrates the carpet manufacturing process according to the present invention.
- the greige 5 with carpet face 10 downward is fed onto a tenter roll 12 that directs the greige 5 to metering plate 95 , the carpet face 10 is advanced over the metering plate 95 using pulling rollers 21 .
- a layer 100 of polyurethane polymer is deposited onto the primary backing side 15 as it passes over metering plate 95 using a mixing head 105 .
- the polyurethane is applied to the primary backing 15 at an area concentration of about 1.0 g/m 2 to about 30 g/m 2 or in a more preferred concentration of about 5.0 g/m 2 to about 12 g/m 2 .
- the polyol and isocyanate pre-polymer components are mechanically blown through a mixing head 105 to form the polyurethane layer 100 . This prevents the pre-polymers from contact until just prior to application to the primary backing 15 .
- the polymerization process does not begin to occur until just prior to the exit of the polyurethane components from the mixing head 105 .
- This process allows the relatively low viscosity polyurethane to deeply penetrate the fibers in the primary backing, resulting in excellent fiber lock characteristics.
- a preferred method of blowing the polyurethane layer is by feeding separate lines of polyol and isocyanate components and a stream of air into a Gusmer Corporation spray attachment (model GX7-400). If the need arises a third line is available for the introduction of catalyst.
- the spray attachment combined with the air stream provides sufficient turbulence to provide a homogenous solution of the urethane-forming components.
- polymerization accelerates and foaming begins.
- the thickness of the polyurethane foam may be adjusted by various means known in the art such as a doctor blade 35 or air knife.
- the polyurethane coated greige 79 is then optionally passed across a steam box 150 .
- Steam box 150 adds water to the reaction, to aid in accelerating the polymerization rate.
- the steam serves to enhance blooming of the yarns passing through the primary backing for deeper penetration and assures a more level coverage of polyurethane.
- a Fume hood 155 is placed above the steam box 150 to capture escaping volatiles released with the steam. Conspicuously absent at this stage of the process is an oven curing step.
- temperatures are generally maintained within 30° F. of ambient temperature or in a more preferred embodiment within 15° F. of ambient temperature during the carpet manufacturing process.
- prior art polyurethane curing processes are required to utilize heat sensitive catalysts and other chemical additives to maintain sufficient viscosities to apply the polyurethane, from various holding lines and troughs, to the backing surface. These additives necessitate a heat curing stage.
- the coated greige 79 is rapidly pulled to merge roll 160 where the secondary backing 55 , supplied from roll 60 , contacts the coated greige 79 downstream from roller 87 . Due to the short time that elapses between the initial application of polyurethane and the merger of the secondary backing 55 with the coated greige 79 , the polyurethane possesses sufficient tackiness to anneal the secondary backing in place. The annealed carpet can then be cooled briefly 190 and rolled for storage and transport.
- Polyurethane prepolymers useful in the practice of the present invention are prepared by the reaction of active hydrogen compounds with any amount of isocyanate in a stoichiometric excess relative to active hydrogen material.
- the prepolymer formulations of the present invention include a polyol component.
- Active hydrogen containing compounds most commonly used in polyurethane production are those compounds having at least two hydroxyl groups or amine groups. However, any active hydrogen containing compound can be used with the present invention.
- At least 50 weight percent of the active hydrogen compounds used to prepare the polyurethane is a polyol having molecular weight of from about 100-400.
- the polyisocyanate component of the formulations of the present invention can be prepared using any organic polyisocyanates, modified polyisocyanates, isocyanate based prepolymers and mixtures thereof. These can include aliphatic or aromatic isocyanates.
- the isocyanate used to prepare the prepolymer formulation of the present invention is methyl diisocyanates such as Bayer's 142L or Dow p901 or blends of equal type.
- Catalysts suitable for use in preparing the polyurethanes of the present invention include tertiary amines, and organometallic compounds and mixtures thereof.
- suitable catalysts include stannous octoate, triethylenediamine, N-methyl morpholine, like compounds and mixtures thereof.
- the catalysts do not necessarily need elevated activation temperatures or other promoters to initiate polymerization.
- Surfactants can be useful for preparing a stable dispersion or froth of the present invention.
- Surfactants useful for preparing a stable dispersion can be cationic, anionic, or non-ionic surfactants.
- the surfactants used to prepare the prepolymer formulation of the present invention are silicone surfactants such as Dow Corning DC-194 or Union Carbide's L-540.
- a surfactant can be included in a formulation of the present invention in an amount ranging from about 0.01 to about 7 parts per 100 parts by weight of polyurethane component.
- a compound of the present invention optionally includes a filler material.
- the filler material can include conventional fillers such as milled glass, calcium carbonate, aluminum trihydrate, barium sulfate, fly ash, dyes and pigments or fire retardants (aluminum trihydrate and Tris polyolefin glycol).
- the filler can be present in an amount ranging from 0 to 300 parts per 100 parts of the polyurethane component.
- any method known to one skilled in the art of preparing polyurethane froths can be used in the practice of the present invention to prepare a polyurethane froth suitable for preparing, for example, a carpet of the present invention.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/993,864 US20020074073A1 (en) | 2000-11-03 | 2001-11-05 | Polyurethane coating process for carpet backing |
| PCT/US2002/035391 WO2003039869A1 (fr) | 2001-11-05 | 2002-11-05 | Processus d'enrobage de polyurethanne ameliore pour sous-couche de tapis |
| US10/625,212 US20040123934A1 (en) | 2000-11-03 | 2003-07-23 | Polyurethane coating process for carpet backing |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24596600P | 2000-11-03 | 2000-11-03 | |
| US09/993,864 US20020074073A1 (en) | 2000-11-03 | 2001-11-05 | Polyurethane coating process for carpet backing |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2002/035391 Continuation-In-Part WO2003039869A1 (fr) | 2000-11-03 | 2002-11-05 | Processus d'enrobage de polyurethanne ameliore pour sous-couche de tapis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20020074073A1 true US20020074073A1 (en) | 2002-06-20 |
Family
ID=25540014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/993,864 Abandoned US20020074073A1 (en) | 2000-11-03 | 2001-11-05 | Polyurethane coating process for carpet backing |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US20020074073A1 (fr) |
| WO (1) | WO2003039869A1 (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050053760A1 (en) * | 2003-09-04 | 2005-03-10 | Shaw Industries Group, Inc. | Reinforced secondary backing fabric and method of using the same |
| US20050266205A1 (en) * | 2004-05-25 | 2005-12-01 | New Spirit Backing, Llc | Polyurethane roller coating process for carpet backing |
| WO2009056284A1 (fr) * | 2007-10-30 | 2009-05-07 | Mapei S.P.A. | Procédé pour la fabrication de tapis d'herbe artificielle |
| US8910588B2 (en) | 2004-05-25 | 2014-12-16 | Kusters Zima Corporation | Polyurethane roller coating device for carpet backing |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1597515A1 (de) * | 1967-10-28 | 1970-06-11 | Basf Ag | Verfahren zum Aufbringen lichtempfindlicher Platten,Filme oder Folien auf metallischen Unterlagen |
| US3821056A (en) * | 1972-04-07 | 1974-06-28 | Du Pont | Method of bonding hydroxyl containing substrates |
| US4156041A (en) * | 1975-11-27 | 1979-05-22 | Imperial Chemical Industries Limited | Deposition of polyurethane foam-forming liquid reaction mixture |
| US4512831A (en) * | 1979-01-02 | 1985-04-23 | Tillotson John G | Method for forming a layer of blown cellular urethane on a carpet backing |
| US4515646A (en) * | 1983-11-22 | 1985-05-07 | Paul Walker | Method for applying polyurethane backing |
| US6962636B2 (en) * | 1998-09-17 | 2005-11-08 | Urethane Soy Systems Company, Inc. | Method of producing a bio-based carpet material |
-
2001
- 2001-11-05 US US09/993,864 patent/US20020074073A1/en not_active Abandoned
-
2002
- 2002-11-05 WO PCT/US2002/035391 patent/WO2003039869A1/fr not_active Ceased
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050053760A1 (en) * | 2003-09-04 | 2005-03-10 | Shaw Industries Group, Inc. | Reinforced secondary backing fabric and method of using the same |
| US7115315B2 (en) | 2003-09-04 | 2006-10-03 | Shaw Industries Group, Inc. | Reinforced secondary backing fabric and method of using the same |
| US20060270295A1 (en) * | 2003-09-04 | 2006-11-30 | Shaw Industries Group, Inc. | Reinforced secondary backing fabric and method of using the same |
| US20050266205A1 (en) * | 2004-05-25 | 2005-12-01 | New Spirit Backing, Llc | Polyurethane roller coating process for carpet backing |
| US7638008B2 (en) * | 2004-05-25 | 2009-12-29 | New Spirit Backing Llc | Polyurethane roller coating process for carpet backing |
| US8910588B2 (en) | 2004-05-25 | 2014-12-16 | Kusters Zima Corporation | Polyurethane roller coating device for carpet backing |
| WO2009056284A1 (fr) * | 2007-10-30 | 2009-05-07 | Mapei S.P.A. | Procédé pour la fabrication de tapis d'herbe artificielle |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2003039869A1 (fr) | 2003-05-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: SIMPLICITY COATING, LLC, GEORGIA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WALKER, PAUL;HAMRICK, GLEN;REEL/FRAME:012334/0330 Effective date: 20011031 |
|
| STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |