US20020009878A1 - Method for manufacturing a multilayer interconnection structure - Google Patents
Method for manufacturing a multilayer interconnection structure Download PDFInfo
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- US20020009878A1 US20020009878A1 US09/901,682 US90168201A US2002009878A1 US 20020009878 A1 US20020009878 A1 US 20020009878A1 US 90168201 A US90168201 A US 90168201A US 2002009878 A1 US2002009878 A1 US 2002009878A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/528—Layout of the interconnection structure
- H01L23/5283—Cross-sectional geometry
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/528—Layout of the interconnection structure
- H01L23/5286—Arrangements of power or ground buses
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Definitions
- the present invention relates to a method for manufacturing a multilevel interconnection structure.
- the present invention relates to a method for forming a multilevel interconnection structure on a wafer which is capable of preventing peeling-off of the deposited films in the peripheral area and an intermediate area of the wafer during subsequent fabrication steps.
- the semiconductor devices include fine-patterned, multilevel interconnection structures in the semiconductor devices,
- an embedded multilevel interconnection structure has been frequently employed for interconnections of circuit elements in the semiconductor devices.
- Such embedded multilevel interconnection structures are formed by a damascene process using the technique of chemical mechanical polishing (CMP) method.
- CMP chemical mechanical polishing
- FIGS. 1A to 1 K show partial sectional views of a central area of a wafer, which is used for forming the product chips, during consecutive steps of fabrication process therefor.
- the film thickness, width and other dimensions or values are mere examples, and the present invention is not limited to those values in any sense.
- a first multilayer interlevel dielectric film 14 composed of a 4000- ⁇ -thick SiO 2 film(top layer)/a 500- ⁇ -thick SiON filmbottom layer) to be used for forming trenches therein is deposited on a wafer, or a substrate 12 .
- a photoresist film is formed on the dielectric film 14 by a coating process, followed by a photolithographic process to form an etching mask 16 having an interconnection trench pattern thereon, as shown in FIG. 1B.
- first interconnection trenches 18 are formed by etching the dielectric film 14 by the etching mask 16 .
- a barrier layer composed of a 200- ⁇ -thick TaN layer (bottom layer)/a 200- ⁇ -thick Ta layer (top layer) and a 1000- ⁇ -thick copper layer are formed in this order on the dielectric film 14 by using a barrier-seed sputtering method.
- a 6000- ⁇ -thick copper (Cu) layer is formed by Cu plating to fill the interconnection trenches 18 .
- FIG. 1D such a multilayer metallic film is denoted by numeral 20 , which is herein called a CaU layer 20 .
- the Cu layer 20 is polished by the CMP method to form first level interconnections 22 that are mostly made of Cu filling the interconnection trenches 18 formed in the dielectric film 14 .
- a first interlevel dielectric film 24 is formed that is composed of a 500- ⁇ -thick SiN film (bottom layer)/a 7000- ⁇ -thick SiO 2 film (top layer).
- an etching mask (not shown) is formed on the first interlevel dielectric film 24 .
- the interlevel dielectric film 24 underlying the etching mask is etched to form 0.2- ⁇ m-diameter via holes 26 which expose the first level interconnection 22 therethrough.
- tungsten (W) layer is deposited by CVD (Chemical Vapo Deposition) method on the first interlevel dielectric film 24 while filling the via holes 26 . Then, the tungsten layer formed on top of the first interlevel dielectric film 24 is removed by a CMP process to leave first tungsten plugs 28 that contact with the respective first level interconnections 22 , as shown in FIG. 1H.
- CVD Chemical Vapo Deposition
- a second multilayer dielectric film 30 to be used for forming trenches therein is deposited on the interlevel dielectric film 24 as well as the exposed first tungsten plugs 28 ; the dielectric film 30 is patterned to form interconnection trenches; a Cu layer is deposited; and as shown in FIG. 1I, second level interconnections 32 are formed by a CMP process.
- another interlevel dielectric film 34 having a structure similar to the structure of the interlevel dielectric film 24 is deposited on the second level interconnections 32 and the second dielectric film 30 ; via holes are formed by using the process similar to that used in forming the first tungsten plugs 28 ; and as shown in FIG. 1J, second tungsten plugs 36 are formed that connect to the second level interconnections 32 .
- the first level interconnections 22 and second level interconnections 32 which are called herein lower-level interconnections are fabricated.
- interconnection trenches are formed by patterning the dielectric film 38 , and a barrier layer composed of a 200- ⁇ -thick TaN layer (bottom layer)/a 200- ⁇ -thick Ta layer (top layer) and a 2000- ⁇ -thick Cu film are formed in this order. On those layers, a 30000- ⁇ -thick Cu plating layer is formed by a plating technique. Next, a third level interconnection 40 composed of multilayer metallic films is formed by CMP processing of the Cu plating layer, as shown in FIG. 1K.
- a multilayer interlevel dielectric film 42 composed of a 500- ⁇ -thick SiN film (bottom layer)/a 7000- ⁇ -thick SiO 2 film (top layer) is formed and then via holes of 0.56- ⁇ m-diameter are formed in the dielectric film 42 . Further, a 4000- ⁇ -thick tungsten film is deposited by CVD method and third tungsten plugs 44 are formed by CMP processing of the tungsten film as shown in FIG. 1L.
- a fourth interlevel dielectric film 46 to be used for forming trenches therein is deposited and patterned to form interconnection trenches.
- fourth level interconnections 48 connecting to the tungsten plugs 44 are formed in the steps similar to those used in forming the third level interconnections 40 , as shown in FIG. 1L.
- the third-level interconnections 40 and the fourth level interconnections 48 are formed and are referred to as upper level interconnections hereinafter.
- the present invention provides a method for manufacturing on a wafer a plurality of semiconductor chips each having a multilevel interconnection structure by using a damascene technique, the method comprising the steps of; separating the wafer into three areas including a peripheral area, an intermediate area and a central area, the central area including a plurality of product chips; forming a first dielectric film overlying the wafer, the first dielectric film having therein first trenches in the intermediate area and the central area; forming lower-level interconnections in the first trenches by using deposition and CMP processes; forming a second dielectric film overlying the first dielectric film and the lower-level interconnections, the second dielectric film having second trenches in the central area; forming upper-level interconnections in the second trenches by using deposition and CMP processes; and wet-etching remaining films in the peripheral area after the CMP process for the upper-level interconnections.
- the wet etching for the remaining films in the peripheral area does not affect the structure in the product chips formed in the central area of the wafer due to provision of the intermediate area.
- FIGS. 1 A-lL are sectional views of the periphery of the wafer, consecutively showing the process steps of forming multilevel interconnection structure in the central area of the wafer;
- FIG. 2 is a schematic perspective view illustrating the periphery of the wafer where a Cu layer is formed on the rear side beyond the periphery;
- FIGS. 3 A- 3 C are sectional views illustrating the defect generated in the conventional method for forming a multilevel interconnection structure
- FIG. 4 is a top plan view of a quarter of the wafer for showing the separated areas
- FIGS. 5 A- 5 R are sectional views of a semiconductor chip arranged in a peripheral area of the wafer, consecutively showing the process steps in a method according to a preferred embodiment of the present invention.
- FIGS. 6A and 6B are schematic sectional views, consecutively showing the process steps in a method according to another embodiment of the present invention.
- the multilevel interconnection structure fabricated by the conventional process, as shown in FIG. 1L, have the lower-level interconnections including the first-level interconnections 22 and the second-level interconnections 32 and the upper-level interconnections including the third-level interconnections 40 and the fourth-level interconnection 44 .
- the process steps described before are generally applicable to the chips of the wafer which are disposed in the central area of the wafer and to be used for forming product chips.
- the Cu layer formed by the above process extend beyond the periphery of the wafer toward the rear side of the wafer, as shown in FIG. 2.
- the Cu layer formed on the periphery of the wafer is more liable to be peeled-off from the wafer to form Cu particles that may pollute the product chips of the same wafer or other wafers.
- an additional step of wet etching is used for removing the Cu layer thus formed on the periphery of the wafer, thereby preventing the Cu layer from later peeling off from the wafer
- the wet etching generally uses a mixture of hydrofluoric acid, hydrogen peroxide and water as an etchant.
- FIG. 3A shows the situation wherein the Cu layer in the interconnection trenches 39 formed in the dielectric film 38 is removed by the wet etching. In this case, after deposition of the overlying interlevel dielectric film 42 , the interconnection trenches 39 are not sufficiently filled with the interlevel dielectric film 42 to leave concave portions, as shown in FIG. 3B.
- via holes are formed by patterning the dielectric film 42 ; the tungsten layer is deposited; and the third tungsten plug 44 is formed by the CMP process.
- tungsten particles generated by the CMP processing of the tungsten film fill the concave portion of the interconnection trenches 39 , as shown in FIG. 3C. Because such tungsten particles contain moisture which may emit gases, these particles cause a variety of problems, such as peeling-off of films in the subsequent process steps.
- the above problem becomes noticeable if the interconnection trenches receiving therein upper-level interconnections constitute a power source line or a ground line and have a larger width, as shown in FIG. 1L.
- the upper-level interconnection trenches are signal lines and have a lower width, substantially no problem arises in the subsequent process steps.
- the wafer surface on which a plurality of chips are to be formed is classified into three areas, as shown in FIG. 4.
- the three areas of the wafer 50 include a marginal area or peripheral area 52 which defines an annular shape having a width of 5 mm, for example, a central area 56 which is used for forming a plurality of product chips, and an intermediate area 54 disposed between the marginal area 52 and the central area 56 and not used for forming the product chips.
- the central area 56 is used for forming product chips each having a multilevel interconnection structure by using exposure and deposition techniques.
- the intermediate area 54 is not used for the product chips because the patterns formed in this area may have incorrect dimensions.
- the outer edge of the intermediate area 54 is formed as, a circle and the inner edge of the intermediate area 54 is stepwise.
- FIGS. 5A to 5 R there is shown a process according to an embodiment of the present invention.
- the first level interconnections 22 through the fourth level interconnections 48 are formed by the process steps similar to those used in the conventional method for forming the multilevel interconnection structure. Different process steps are applied to the peripheral area and the intermediate area of the wafer, as will be detailed below. It is to be noted that unless otherwise specified, the same process for the central area is also applied to the peripheral area and the intermediate area of the wafer.
- an etching mask 16 having a trench pattern is formed on the first dielectric film 14 by coating and photolithographic steps.
- the etching mask 16 exposes a portion of the first dielectric film 14 disposed on the peripheral area 17 of the wafer 12 together with the portions of the dielectric film 14 at which the trenches are to be formed, as shown in FIG. 5A.
- the peripheral area 17 of the wafer is an annular peripheral portion of the wafer having a width of 5 mm disposed between the periphery of the wafer and a circle 5 mm apart from the periphery of the wafer toward the center thereof.
- the dielectric film 14 is etched by using the etching mask 16 , and thereby first interconnection trenches 18 are formed, as shown in FIG. 5B.
- a Cu layer 20 is formed by deposition on the entire surface of the dielectric film 14 except for the most portion of the peripheral area 17 of the wafer. Subsequently, the Cu layer 20 is etched by a CMP process to form first level interconnections 22 , as shown in FIG. 5D.
- the Cu layer 20 left on the peripheral area 17 of the wafer during the CMP process is removed by wet etching.
- the first level interconnections 22 formed in the first interconnection trenches 18 disposed in the vicinity of the peripheral area 17 of the wafer is also etched to expose the corresponding interconnection trenches 18 .
- an interlevel dielectric film 24 is deposited on the first level interconnections 22 and the dielectric film 14 .
- an etching mask is formed on the interlevel dielectric film 24 .
- via holes 26 are formed by etching the interlevel dielectric film 24 , as shown in FIG. 5G, a portion of the interlevel dielectric film 24 disposed on another annular peripheral area having a width of 2 m and residing between the periphery of the wafer 12 and the circle 2 mm apart from the periphery of the wafer 12 is also removed at the same time to expose the dielectric film 14 .
- No via holes are formed in another portion of the dielectric film 14 disposed on the intermediate area having a specific width and residing between the annular peripheral area and a circle apart from the inner edge of the annular peripheral area by a specific distance or the outer edge of the central area which is to be used for product chips.
- a tungsten layer is formed on the interlevel dielectric film 24 by sputtering, followed by polishing thereof to form first tungsten plugs 28 by using a CMP process.
- a second interlevel dielectric film 30 is formed thereon and, as shown in FIG. 5H, an etching mask 29 having an interconnect pattern is formed on the second dielectric film 30 by coating and photolithographic steps.
- the etching mask 29 exposes an annular peripheral area of the dielectric film 30 residing between the outer periphery of the wafer and a circle 5 mm apart from the outer periphery.
- the dielectric film 30 underlying the etching mask 29 is etched to form second interconnection trenches.
- a Ca layer 31 is deposited on the second dielectric film to fill the interconnection trenches.
- the outer edge of the Cu layer 31 resides within the 5-mm-wide annular peripheral area.
- second level interconnections 32 are formed by a CMP process to polish the Cu layer 31 , as shown in FIG. 5J.
- the Cu layer left on the outer periphery of the wafer is removed.
- the Cu layer formed in some of the second interconnection trenches disposed in the intermediate area which is an effective exposed area in the vicinity of the outer periphery of the wafer, is also removed to expose the walls and bottoms of the second interconnection trenches 33 .
- an interlevel dielectric film 34 is deposited over the entire surface of the wafer as shown in FIG. 5L.
- an etching mask is formed on the interlevel dielectric film 34 .
- via holes 35 are formed by etching the interlevel dielectric film 34 , as shown in FIG. 5M, a portion of the interlevel dielectric film 34 disposed on the 2-mm-wide annular are of the wafer is also removed in the step of forming the via holes.
- via holes are not formed in the specified annular area of the wafer disposed between the outer periphery of the wafer and the circle apart from the outer periphery by specified distance, as illustrated in FIG. 5M.
- the specified annular area includes the peripheral area and the intermediate area, which resides between the peripheral area and the central area and is not used for forming the product chips.
- a third interlevel dielectric film 38 for forming therein interconnection trenches is deposited on the interlevel dielectric film 34 . Further, as shown in FIG. 5N, an etching mask 39 for patterning the third interconnection trench is formed on the dielectric film 38 . In this stage, the photoresist film on the 5-mm-wide peripheral area 52 is exposed to light, developed and then removed, to expose the dielectric film 38 Interconnection trenches are not formed in the intermediate area 54 , because it is covered with the etching mask 39 .
- the third interconnection trench is formed by etching the dielectric film 38 by using the etching mask 39 , and the Cu layer is filled in the third interconnection trench on the dielectric film 38 in the central area 56 .
- a third level interconnections 40 are formed by CMP processing, as shown in FIG. 5O.
- the Cu layer on the peripheral area 52 of the wafer is removed by wet etching.
- any via hole is not formed, and the etching mask 43 is formed so that the interlevel dielectric film 42 is left as it is.
- a third tungsten plug 44 penetrating through the interlevel dielectric film 42 are formed by filling the via holes with tungsten. Then, a fourth dielectric film 46 for forming trenches is deposited on the interlevel dielectric film 42 .
- an etching mask 47 for forming therein fourth interconnection trenches is formed.
- the photoresist film on the 5-mm-wide annular area of the wafer 12 is exposed to light, developed and then removed to expose the dielectric film 46 .
- the dielectric film 46 is etched using the etching mask 47 to form fourth level interconnections; the Cu layer is deposited; and fourth level interconnections 48 are formed by CMP processing, as shown in FIG. 5R. Subsequently. the Cu layer on the peripheral area 52 of the wafer is removed by wet etching.
- the intermediate area 54 of the water resides between the central area 56 and the peripheral area 52 of the wafer in this embodiment, the area from which the Cu layer should be removed is precisely limited to the peripheral area 52 of the wafer when the Cu layer on the peripheral area of the wafer is removed by wet etching. Therefore, the problem involved in the conventional method does not occur
- interconnection trenches are not formed and the dielectric films for forming interconnection trenches are left as they are in the intermediate area 54 of the wafer during forming the upper-level interconnections.
- upper-level interconnection trenches may be formed which have the same or a similar dimensions as those of the lower-level interconnection trenches.
- interconnection trenches for upper-level interconnections are not formed in the intermediate area and the peripheral area of the wafer, and formed in the central area of the wafer, with the dielectric film for forming interconnection trenches being left in the periphery of the wafer.
- the intermediate area the wafer residing between the central area of the wafer and the peripheral area of the wafer limits the wet etching of the Cu layer only to the peripheral area.
- the upper-level interconnections may be formed in the intermediate area substantially without causing any trouble so long as the upper-level interconnections have a smaller width or comparable width to the width of the lower-level interconnections, as detailed below.
- dielectric film 62 has interconnection trenches 64 having a maximum width W 1 and a depth of d 1 , within which an interconnection 66 is to be formed.
- An overlying dielectric film 68 overlying the dielectric film 62 has a thickness t 1 and receives a tungsten plug 70 having a diameter of r 1 .
- the thickness of the tungsten film 72 after deposition, as shown in FIG. 6B is set at half the diameter r 1 of the tungsten plug 70 .
- the volume V 2 of the sum of the overlying dielectric film 68 and the tungsten film 72 filling the interconnection trench 64 is obtained by the following equation:
- the interconnection trenches 64 in the intermediate area which do not receive therein the interconnection 66 after the etching of the Cu layer at the peripheral area of the wafer can be entirely filled with the overlying dielectric film 68 and the tungsten film 72 after the deposition thereof. This case does not involve that the tungsten particles later fill the interconnection trenches 64 , and can be employed safely without causing any problem.
- the lower-level interconnection has a smaller sectional area and thus a smaller width due to a smaller current flowing therethrough, whereas the upper-level interconnection has a larger sectional area and thus a larger sectional area due to a larger current flowing therethrough.
- the effective total area of the interconnections in a single CMP process should be sufficiently large.
- the lower-level interconnections are preferably formed in the intermediate area, which is not used for product chips, to enlarge the CMP area.
- the upper-level interconnections need not be formed in the intermediate area because a sufficient CMP area can be obtained by the interconnections only in the central area due to the larger width of the upper-level interconnections.
- the interconnection formed in the trench may be made of any material, and is preferably made of a metal or alloy including Cu as a main component thereof.
- the interconnection may be a multilayer conductive film such as including a TaN/Ta barrier layer and a Cu layer formed thereon.
- the type or composition of the etchant or the etching conditions for the wet etching may be selected from those used in the conventional technique.
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Abstract
Description
- 1. Field of the Invention
- The present invention relates to a method for manufacturing a multilevel interconnection structure. In particular, the present invention relates to a method for forming a multilevel interconnection structure on a wafer which is capable of preventing peeling-off of the deposited films in the peripheral area and an intermediate area of the wafer during subsequent fabrication steps.
- 2. Description of the Prior Art
- Because of the demand for finer patterned, higher density semiconductor devices, the semiconductor devices include fine-patterned, multilevel interconnection structures in the semiconductor devices,
- In order to form fine-patterned, multilayer interconnections an embedded multilevel interconnection structure has been frequently employed for interconnections of circuit elements in the semiconductor devices. Such embedded multilevel interconnection structures are formed by a damascene process using the technique of chemical mechanical polishing (CMP) method.
- Referring now to FIGS. 1A to 1K, a conventional method of forming the embedded multilevel interconnection structure using the damascene process will be described. These figures show partial sectional views of a central area of a wafer, which is used for forming the product chips, during consecutive steps of fabrication process therefor. In the descriptions to follow, the film thickness, width and other dimensions or values are mere examples, and the present invention is not limited to those values in any sense.
- First, as shown in FIG. 1A, a first multilayer interlevel
dielectric film 14 composed of a 4000-Å-thick SiO2 film(top layer)/a 500-Å-thick SiON filmbottom layer) to be used for forming trenches therein is deposited on a wafer, or asubstrate 12. - Then, a photoresist film is formed on the
dielectric film 14 by a coating process, followed by a photolithographic process to form anetching mask 16 having an interconnection trench pattern thereon, as shown in FIG. 1B. - Next, as shown in FIG. 1C,
first interconnection trenches 18 are formed by etching thedielectric film 14 by theetching mask 16. - After removing the
etching mask 16, a barrier layer composed of a 200-Å-thick TaN layer (bottom layer)/a 200-Å-thick Ta layer (top layer) and a 1000-Å-thick copper layer are formed in this order on thedielectric film 14 by using a barrier-seed sputtering method. On top of those films, a 6000-Å-thick copper (Cu) layer is formed by Cu plating to fill theinterconnection trenches 18. In FIG. 1D such a multilayer metallic film is denoted bynumeral 20, which is herein called aCaU layer 20. - Next, the
Cu layer 20 is polished by the CMP method to formfirst level interconnections 22 that are mostly made of Cu filling theinterconnection trenches 18 formed in thedielectric film 14. - In the next step, as shown in FIG. 1F, on the
dielectric film 14 havingtrenches 18 receiving therein the exposedfirst level interconnections 22, a first interleveldielectric film 24 is formed that is composed of a 500-Å-thick SiN film (bottom layer)/a 7000-Å-thick SiO2 film (top layer). - Subsequently, as shown in FIG. 1G, an etching mask (not shown) is formed on the first interlevel
dielectric film 24. Then, the interleveldielectric film 24 underlying the etching mask is etched to form 0.2-μm-diameter viaholes 26 which expose thefirst level interconnection 22 therethrough. - Next, a 4000-Å-thick tungsten (W) layer is deposited by CVD (Chemical Vapo Deposition) method on the first interlevel
dielectric film 24 while filling thevia holes 26. Then, the tungsten layer formed on top of the first interleveldielectric film 24 is removed by a CMP process to leavefirst tungsten plugs 28 that contact with the respectivefirst level interconnections 22, as shown in FIG. 1H. - In the next step, by the process steps similar to those employed in forming the
first level interconnections 22, a second multilayerdielectric film 30 to be used for forming trenches therein is deposited on the interleveldielectric film 24 as well as the exposedfirst tungsten plugs 28; thedielectric film 30 is patterned to form interconnection trenches; a Cu layer is deposited; and as shown in FIG. 1I,second level interconnections 32 are formed by a CMP process. - In the following steps, another interlevel
dielectric film 34 having a structure similar to the structure of the interleveldielectric film 24 is deposited on thesecond level interconnections 32 and the seconddielectric film 30; via holes are formed by using the process similar to that used in forming thefirst tungsten plugs 28; and as shown in FIG. 1J,second tungsten plugs 36 are formed that connect to thesecond level interconnections 32. - By using the above process steps, the
first level interconnections 22 andsecond level interconnections 32 which are called herein lower-level interconnections are fabricated. - Next, as shown in FIG. 1K, a third interlevel
dielectric film 38 to be used for forming trenches and composed of a 1000-Å-thick SiON film (bottom layer)/a 19000-Å-thick SiO2 film (top layer) is formed on the interleveldielectric film 34 as well as the exposedsecond tungsten plugs 36. - Subsequently, interconnection trenches are formed by patterning the
dielectric film 38, and a barrier layer composed of a 200-Å-thick TaN layer (bottom layer)/a 200-Å-thick Ta layer (top layer) and a 2000-Å-thick Cu film are formed in this order. On those layers, a 30000-Å-thick Cu plating layer is formed by a plating technique. Next, athird level interconnection 40 composed of multilayer metallic films is formed by CMP processing of the Cu plating layer, as shown in FIG. 1K. - In the following step, on the
interconnection 40, a multilayer interleveldielectric film 42 composed of a 500-Å-thick SiN film (bottom layer)/a 7000-Å-thick SiO2 film (top layer) is formed and then via holes of 0.56-μm-diameter are formed in thedielectric film 42. Further, a 4000-Å-thick tungsten film is deposited by CVD method andthird tungsten plugs 44 are formed by CMP processing of the tungsten film as shown in FIG. 1L. - Next, a fourth interlevel
dielectric film 46 to be used for forming trenches therein is deposited and patterned to form interconnection trenches Thenfourth level interconnections 48 connecting to thetungsten plugs 44 are formed in the steps similar to those used in forming thethird level interconnections 40, as shown in FIG. 1L. - By the above process steps, the third-
level interconnections 40 and thefourth level interconnections 48 are formed and are referred to as upper level interconnections hereinafter. - In the conventional damascene process, there are some drawbacks wherein the tungsten particles generated by the CMP process cause some problems such as peeling-off of the deposited films in the subsequent steps.
- It is therefore an object of the present invention to provide a method for forming a multilevel interconnection structure in a semiconductor device by using a damascene process wherein peeling-off of the films is suppressed,
- The present invention provides a method for manufacturing on a wafer a plurality of semiconductor chips each having a multilevel interconnection structure by using a damascene technique, the method comprising the steps of; separating the wafer into three areas including a peripheral area, an intermediate area and a central area, the central area including a plurality of product chips; forming a first dielectric film overlying the wafer, the first dielectric film having therein first trenches in the intermediate area and the central area; forming lower-level interconnections in the first trenches by using deposition and CMP processes; forming a second dielectric film overlying the first dielectric film and the lower-level interconnections, the second dielectric film having second trenches in the central area; forming upper-level interconnections in the second trenches by using deposition and CMP processes; and wet-etching remaining films in the peripheral area after the CMP process for the upper-level interconnections.
- In accordance with the method of the present invention, the wet etching for the remaining films in the peripheral area does not affect the structure in the product chips formed in the central area of the wafer due to provision of the intermediate area.
- The above and other objects, features and advantages of the present invention will be more apparent from the following description, referring to the accompanying drawings.
- FIGS. 1A-lL are sectional views of the periphery of the wafer, consecutively showing the process steps of forming multilevel interconnection structure in the central area of the wafer;
- FIG. 2 is a schematic perspective view illustrating the periphery of the wafer where a Cu layer is formed on the rear side beyond the periphery;
- FIGS. 3A-3C are sectional views illustrating the defect generated in the conventional method for forming a multilevel interconnection structure;
- FIG. 4 is a top plan view of a quarter of the wafer for showing the separated areas;
- FIGS. 5A-5R are sectional views of a semiconductor chip arranged in a peripheral area of the wafer, consecutively showing the process steps in a method according to a preferred embodiment of the present invention; and
- FIGS. 6A and 6B are schematic sectional views, consecutively showing the process steps in a method according to another embodiment of the present invention.
- Before describing preferred embodiments of the present invention, the problems found by the inventors in the conventional process will be described for a better understanding of the present invention.
- The multilevel interconnection structure fabricated by the conventional process, as shown in FIG. 1L, have the lower-level interconnections including the first-
level interconnections 22 and the second-level interconnections 32 and the upper-level interconnections including the third-level interconnections 40 and the fourth-level interconnection 44. - The process steps described before are generally applicable to the chips of the wafer which are disposed in the central area of the wafer and to be used for forming product chips. On the other hand, in the periphery of the wafer, the Cu layer formed by the above process extend beyond the periphery of the wafer toward the rear side of the wafer, as shown in FIG. 2. The Cu layer formed on the periphery of the wafer is more liable to be peeled-off from the wafer to form Cu particles that may pollute the product chips of the same wafer or other wafers. Thus, an additional step of wet etching is used for removing the Cu layer thus formed on the periphery of the wafer, thereby preventing the Cu layer from later peeling off from the wafer The wet etching generally uses a mixture of hydrofluoric acid, hydrogen peroxide and water as an etchant.
- However, in the process of forming the above
third level interconnections 40, for example, there are some problems when removing the Cu layer on the periphery of the wafer. Specifically, when removing the Cu layer on the periphery of the wafer by the wet etching, it is difficult to precisely limit the area for the Cu etching to only the periphery of the wafer. Thus, the Cu layer formed in the interconnection trenches is also removed from the central area of the wafer which is to be used for forming the product chips FIG. 3A shows the situation wherein the Cu layer in theinterconnection trenches 39 formed in thedielectric film 38 is removed by the wet etching. In this case, after deposition of the overlying interleveldielectric film 42, theinterconnection trenches 39 are not sufficiently filled with the interleveldielectric film 42 to leave concave portions, as shown in FIG. 3B. - In the subsequent process steps: via holes are formed by patterning the
dielectric film 42; the tungsten layer is deposited; and thethird tungsten plug 44 is formed by the CMP process. Thus, tungsten particles generated by the CMP processing of the tungsten film fill the concave portion of theinterconnection trenches 39, as shown in FIG. 3C. Because such tungsten particles contain moisture which may emit gases, these particles cause a variety of problems, such as peeling-off of films in the subsequent process steps. - It is noted that the above problem becomes noticeable if the interconnection trenches receiving therein upper-level interconnections constitute a power source line or a ground line and have a larger width, as shown in FIG. 1L. On the other hand, if the upper-level interconnection trenches are signal lines and have a lower width, substantially no problem arises in the subsequent process steps.
- Now, the present invention will be described in more detail with reference to the preferred embodiments thereof.
- In this text, the wafer surface on which a plurality of chips are to be formed is classified into three areas, as shown in FIG. 4. The three areas of the
wafer 50 include a marginal area orperipheral area 52 which defines an annular shape having a width of 5 mm, for example, acentral area 56 which is used for forming a plurality of product chips, and anintermediate area 54 disposed between themarginal area 52 and thecentral area 56 and not used for forming the product chips. Thecentral area 56 is used for forming product chips each having a multilevel interconnection structure by using exposure and deposition techniques. Theintermediate area 54 is not used for the product chips because the patterns formed in this area may have incorrect dimensions. The outer edge of theintermediate area 54 is formed as, a circle and the inner edge of theintermediate area 54 is stepwise. - Referring to FIGS. 5A to 5R, there is shown a process according to an embodiment of the present invention.
- In the manufacture of the multilevel interconnection structure by using the method according to the present embodiment, in the central area of the wafer, the
first level interconnections 22 through thefourth level interconnections 48 are formed by the process steps similar to those used in the conventional method for forming the multilevel interconnection structure. Different process steps are applied to the peripheral area and the intermediate area of the wafer, as will be detailed below. It is to be noted that unless otherwise specified, the same process for the central area is also applied to the peripheral area and the intermediate area of the wafer. - First, an
etching mask 16 having a trench pattern is formed on thefirst dielectric film 14 by coating and photolithographic steps. Theetching mask 16 exposes a portion of thefirst dielectric film 14 disposed on theperipheral area 17 of thewafer 12 together with the portions of thedielectric film 14 at which the trenches are to be formed, as shown in FIG. 5A. In this embodiment, theperipheral area 17 of the wafer is an annular peripheral portion of the wafer having a width of 5 mm disposed between the periphery of the wafer and a circle 5 mm apart from the periphery of the wafer toward the center thereof. - Next, the
dielectric film 14 is etched by using theetching mask 16, and therebyfirst interconnection trenches 18 are formed, as shown in FIG. 5B. - Then, as shown in FIG. 5C, a
Cu layer 20 is formed by deposition on the entire surface of thedielectric film 14 except for the most portion of theperipheral area 17 of the wafer. Subsequently, theCu layer 20 is etched by a CMP process to formfirst level interconnections 22, as shown in FIG. 5D. - Then, the
Cu layer 20 left on theperipheral area 17 of the wafer during the CMP process is removed by wet etching. At this stage, as shown in FIG. 5E, thefirst level interconnections 22 formed in thefirst interconnection trenches 18 disposed in the vicinity of theperipheral area 17 of the wafer is also etched to expose thecorresponding interconnection trenches 18. - Next, as shown in FIG. 5F, an interlevel
dielectric film 24 is deposited on thefirst level interconnections 22 and thedielectric film 14. - Then, an etching mask is formed on the interlevel
dielectric film 24. When via holes 26 are formed by etching the interleveldielectric film 24, as shown in FIG. 5G, a portion of the interleveldielectric film 24 disposed on another annular peripheral area having a width of 2 m and residing between the periphery of thewafer 12 and thecircle 2 mm apart from the periphery of thewafer 12 is also removed at the same time to expose thedielectric film 14. No via holes are formed in another portion of thedielectric film 14 disposed on the intermediate area having a specific width and residing between the annular peripheral area and a circle apart from the inner edge of the annular peripheral area by a specific distance or the outer edge of the central area which is to be used for product chips. - Subsequently, a tungsten layer is formed on the interlevel
dielectric film 24 by sputtering, followed by polishing thereof to form first tungsten plugs 28 by using a CMP process. Further, a secondinterlevel dielectric film 30 is formed thereon and, as shown in FIG. 5H, anetching mask 29 having an interconnect pattern is formed on thesecond dielectric film 30 by coating and photolithographic steps. Theetching mask 29 exposes an annular peripheral area of thedielectric film 30 residing between the outer periphery of the wafer and a circle 5 mm apart from the outer periphery. - Next, the
dielectric film 30 underlying theetching mask 29 is etched to form second interconnection trenches. After removing theetching mask 29, as shown in FIG. 51, aCa layer 31 is deposited on the second dielectric film to fill the interconnection trenches. In this step, the outer edge of theCu layer 31 resides within the 5-mm-wide annular peripheral area. - In the next step,
second level interconnections 32 are formed by a CMP process to polish theCu layer 31, as shown in FIG. 5J. - Subsequently, the Cu layer left on the outer periphery of the wafer is removed. In this step, as shown in FIG. 5K, the Cu layer formed in some of the second interconnection trenches disposed in the intermediate area, which is an effective exposed area in the vicinity of the outer periphery of the wafer, is also removed to expose the walls and bottoms of the
second interconnection trenches 33. - Then, an interlevel
dielectric film 34 is deposited over the entire surface of the wafer as shown in FIG. 5L. - Subsequently, an etching mask is formed on the interlevel
dielectric film 34. When via holes 35 are formed by etching the interleveldielectric film 34, as shown in FIG. 5M, a portion of the interleveldielectric film 34 disposed on the 2-mm-wide annular are of the wafer is also removed in the step of forming the via holes. In this step, via holes are not formed in the specified annular area of the wafer disposed between the outer periphery of the wafer and the circle apart from the outer periphery by specified distance, as illustrated in FIG. 5M. The specified annular area includes the peripheral area and the intermediate area, which resides between the peripheral area and the central area and is not used for forming the product chips. - Subsequently, the process proceeds to the step of forming upper-level interconnections.
- First, in the process of fabricating the upper-level interconnections, a third interlevel
dielectric film 38 for forming therein interconnection trenches is deposited on the interleveldielectric film 34. Further, as shown in FIG. 5N, anetching mask 39 for patterning the third interconnection trench is formed on thedielectric film 38. In this stage, the photoresist film on the 5-mm-wideperipheral area 52 is exposed to light, developed and then removed, to expose thedielectric film 38 Interconnection trenches are not formed in theintermediate area 54, because it is covered with theetching mask 39. - Next, the third interconnection trench is formed by etching the
dielectric film 38 by using theetching mask 39, and the Cu layer is filled in the third interconnection trench on thedielectric film 38 in thecentral area 56. Thus, athird level interconnections 40 are formed by CMP processing, as shown in FIG. 5O. - Next, the Cu layer on the
peripheral area 52 of the wafer is removed by wet etching. - In the next-step,-an-
interlevel dielectric film 42 is formed on thethird level interconnections 40. Then, as shown in FIG. 5P, anetching mask 43 is formed on the interleveldielectric film 42. When via holes are formed by etching the interleveldielectric film 42, the interleveldielectric film 42 on the 2-mm-wide annular area of thewafer 12 is also removed. - At the same time, in the
intermediate area 54, any via hole is not formed, and theetching mask 43 is formed so that the interleveldielectric film 42 is left as it is. - Next, a
third tungsten plug 44 penetrating through the interleveldielectric film 42 are formed by filling the via holes with tungsten. Then, afourth dielectric film 46 for forming trenches is deposited on the interleveldielectric film 42. - Subsequently, as shown in FIG. 5Q, an
etching mask 47 for forming therein fourth interconnection trenches is formed. Then, as shown in FIG. 5Q, the photoresist film on the 5-mm-wide annular area of thewafer 12 is exposed to light, developed and then removed to expose thedielectric film 46. - Subsequently, the
dielectric film 46 is etched using theetching mask 47 to form fourth level interconnections; the Cu layer is deposited; andfourth level interconnections 48 are formed by CMP processing, as shown in FIG. 5R. Subsequently. the Cu layer on theperipheral area 52 of the wafer is removed by wet etching. - Since the
intermediate area 54 of the water resides between thecentral area 56 and theperipheral area 52 of the wafer in this embodiment, the area from which the Cu layer should be removed is precisely limited to theperipheral area 52 of the wafer when the Cu layer on the peripheral area of the wafer is removed by wet etching. Therefore, the problem involved in the conventional method does not occur - In the above embodiment, interconnection trenches are not formed and the dielectric films for forming interconnection trenches are left as they are in the
intermediate area 54 of the wafer during forming the upper-level interconnections. However, upper-level interconnection trenches may be formed which have the same or a similar dimensions as those of the lower-level interconnection trenches. - In the embodiment according to the present invention, interconnection trenches for upper-level interconnections are not formed in the intermediate area and the peripheral area of the wafer, and formed in the central area of the wafer, with the dielectric film for forming interconnection trenches being left in the periphery of the wafer. By this configuration, the intermediate area the wafer residing between the central area of the wafer and the peripheral area of the wafer limits the wet etching of the Cu layer only to the peripheral area.
- The upper-level interconnections may be formed in the intermediate area substantially without causing any trouble so long as the upper-level interconnections have a smaller width or comparable width to the width of the lower-level interconnections, as detailed below.
- Referring to FIG. 6A and 6B, there are shown the dimensional relationship between the upper-level interconnection trenches and the thickness of the interlevel dielectric film. In FIG. 6A,
dielectric film 62 hasinterconnection trenches 64 having a maximum width W1 and a depth of d1, within which aninterconnection 66 is to be formed. Anoverlying dielectric film 68 overlying thedielectric film 62 has a thickness t1 and receives atungsten plug 70 having a diameter of r1. The thickness of thetungsten film 72 after deposition, as shown in FIG. 6B is set at half the diameter r1 of thetungsten plug 70. - From the above assumption: the volume S 1 per unit length of the
trench 64 is obtained by S1=d1−W1, whereas the volume V2 of the sum of theoverlying dielectric film 68 and thetungsten film 72 filling theinterconnection trench 64 is obtained by the following equation: - S2=(r1/2+t)·(w1−
r 1− 2·t1+2−d1) - If S 1<S2, then the
interconnection trenches 64 in the intermediate area which do not receive therein theinterconnection 66 after the etching of the Cu layer at the peripheral area of the wafer can be entirely filled with the overlyingdielectric film 68 and thetungsten film 72 after the deposition thereof. This case does not involve that the tungsten particles later fill theinterconnection trenches 64, and can be employed safely without causing any problem. - On the other hand, if S 1≧S2, then the
interconnection trenches 64 in the intermediate area which do not receive therein theinterconnections 66 cannot be entirely filled by the overlyingdielectric film 68 and thetungsten film 72. This case involves that the tungsten particles fill theinterconnection trenches 64 after CMP processing thereof, and causes the problem encountered in the conventional problem. - Based on this comparison of dimensions, it is determined whether or not the upper-level interconnection trench is to be formed in the intermediate area.
- In general, the lower-level interconnection has a smaller sectional area and thus a smaller width due to a smaller current flowing therethrough, whereas the upper-level interconnection has a larger sectional area and thus a larger sectional area due to a larger current flowing therethrough. In order to obtain a uniform resistance in the interconnections by using a CMP process, the effective total area of the interconnections in a single CMP process should be sufficiently large. In this respect, the lower-level interconnections are preferably formed in the intermediate area, which is not used for product chips, to enlarge the CMP area. On the other hand, the upper-level interconnections need not be formed in the intermediate area because a sufficient CMP area can be obtained by the interconnections only in the central area due to the larger width of the upper-level interconnections.
- The interconnection formed in the trench may be made of any material, and is preferably made of a metal or alloy including Cu as a main component thereof. The interconnection may be a multilayer conductive film such as including a TaN/Ta barrier layer and a Cu layer formed thereon. The type or composition of the etchant or the etching conditions for the wet etching may be selected from those used in the conventional technique.
- Since the above embodiments are described only for examples, the present invention is not limited to the above embodiments and various modifications or alterations can be easily made therefrom by those skilled in the art without departing from the scope of the present invention.
Claims (7)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000209342A JP2002026008A (en) | 2000-07-11 | 2000-07-11 | Method for forming multilayer wiring structure and wafer on which multilayer wiring structure is formed |
| JP2000-209342 | 2000-07-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20020009878A1 true US20020009878A1 (en) | 2002-01-24 |
| US6458690B2 US6458690B2 (en) | 2002-10-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/901,682 Expired - Fee Related US6458690B2 (en) | 2000-07-11 | 2001-07-11 | Method for manufacturing a multilayer interconnection structure |
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|---|---|
| US (1) | US6458690B2 (en) |
| JP (1) | JP2002026008A (en) |
| TW (1) | TW505996B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2843651A1 (en) * | 2002-06-18 | 2004-02-20 | Nec Electronics Corp | INDUCTION COIL FOR INTEGRATED SEMICONDUCTOR CIRCUIT AND MANUFACTURING METHOD THEREOF |
| US20070290279A1 (en) * | 2006-05-23 | 2007-12-20 | Kentaro Imamizu | Semiconductor device including groove pattern around effective chip and method for fabricating the same |
| CN102117766A (en) * | 2009-12-30 | 2011-07-06 | 海力士半导体有限公司 | Method for fabricating semiconductor device |
| US20140264368A1 (en) * | 2013-03-15 | 2014-09-18 | Semiconductor Components Industries, Llc | Semiconductor Wafer and a Process of Forming the Same |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6696746B1 (en) * | 1998-04-29 | 2004-02-24 | Micron Technology, Inc. | Buried conductors |
| US6706622B1 (en) * | 2001-09-07 | 2004-03-16 | Lsi Logic Corporation | Bonding pad interface |
| US6624515B1 (en) * | 2002-03-11 | 2003-09-23 | Micron Technology, Inc. | Microelectronic die including low RC under-layer interconnects |
| JP4303547B2 (en) | 2003-01-30 | 2009-07-29 | Necエレクトロニクス株式会社 | Semiconductor device |
| JP2005217320A (en) * | 2004-01-30 | 2005-08-11 | Renesas Technology Corp | Method for forming wiring, fabrication process of semiconductor device and process for manufacturing semiconductor packaging equipment |
| JP4801333B2 (en) * | 2004-07-23 | 2011-10-26 | パナソニック株式会社 | Power supply wiring structure and semiconductor integrated circuit having the power supply wiring structure |
| KR100617066B1 (en) | 2005-06-02 | 2006-08-30 | 동부일렉트로닉스 주식회사 | Manufacturing method of semiconductor device |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6124198A (en) * | 1998-04-22 | 2000-09-26 | Cvc, Inc. | Ultra high-speed chip interconnect using free-space dielectrics |
| JP3660821B2 (en) * | 1999-01-19 | 2005-06-15 | 株式会社日立製作所 | Semiconductor device and manufacturing method thereof |
| US6204165B1 (en) * | 1999-06-24 | 2001-03-20 | International Business Machines Corporation | Practical air dielectric interconnections by post-processing standard CMOS wafers |
| US6214719B1 (en) * | 1999-09-30 | 2001-04-10 | Novellus Systems, Inc. | Method of implementing air-gap technology for low capacitance ILD in the damascene scheme |
-
2000
- 2000-07-11 JP JP2000209342A patent/JP2002026008A/en active Pending
-
2001
- 2001-07-11 TW TW090117034A patent/TW505996B/en not_active IP Right Cessation
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2843651A1 (en) * | 2002-06-18 | 2004-02-20 | Nec Electronics Corp | INDUCTION COIL FOR INTEGRATED SEMICONDUCTOR CIRCUIT AND MANUFACTURING METHOD THEREOF |
| US20070290279A1 (en) * | 2006-05-23 | 2007-12-20 | Kentaro Imamizu | Semiconductor device including groove pattern around effective chip and method for fabricating the same |
| CN102117766A (en) * | 2009-12-30 | 2011-07-06 | 海力士半导体有限公司 | Method for fabricating semiconductor device |
| US20140264368A1 (en) * | 2013-03-15 | 2014-09-18 | Semiconductor Components Industries, Llc | Semiconductor Wafer and a Process of Forming the Same |
| US9245736B2 (en) * | 2013-03-15 | 2016-01-26 | Semiconductor Components Industries, Llc | Process of forming a semiconductor wafer |
| US9842899B2 (en) | 2013-03-15 | 2017-12-12 | Semiconductor Components Industries, Llc | Semiconductor wafer including a monocrystalline semiconductor layer spaced apart from a poly template layer |
Also Published As
| Publication number | Publication date |
|---|---|
| TW505996B (en) | 2002-10-11 |
| US6458690B2 (en) | 2002-10-01 |
| JP2002026008A (en) | 2002-01-25 |
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