US20010050020A1 - Jacketed frangible bullets - Google Patents
Jacketed frangible bullets Download PDFInfo
- Publication number
- US20010050020A1 US20010050020A1 US09/540,569 US54056900A US2001050020A1 US 20010050020 A1 US20010050020 A1 US 20010050020A1 US 54056900 A US54056900 A US 54056900A US 2001050020 A1 US2001050020 A1 US 2001050020A1
- Authority
- US
- United States
- Prior art keywords
- core member
- bullet
- frangible
- jacket
- frangible bullet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910052751 metal Inorganic materials 0.000 claims abstract description 41
- 239000002184 metal Substances 0.000 claims abstract description 41
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 18
- 229920001778 nylon Polymers 0.000 claims description 27
- 239000004677 Nylon Substances 0.000 claims description 22
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- 229910001385 heavy metal Inorganic materials 0.000 claims description 10
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- 230000005484 gravity Effects 0.000 claims description 6
- 239000000314 lubricant Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims 3
- 238000002788 crimping Methods 0.000 claims 1
- 238000012549 training Methods 0.000 abstract description 6
- 238000013467 fragmentation Methods 0.000 abstract description 4
- 238000006062 fragmentation reaction Methods 0.000 abstract description 4
- 239000011162 core material Substances 0.000 description 53
- 229920000642 polymer Polymers 0.000 description 23
- 239000000463 material Substances 0.000 description 19
- 239000007789 gas Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 239000000203 mixture Substances 0.000 description 11
- 238000013461 design Methods 0.000 description 10
- 150000002739 metals Chemical class 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 6
- 239000002861 polymer material Substances 0.000 description 5
- 230000035515 penetration Effects 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012486 side-by-side testing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/72—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material
- F42B12/74—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material of the core or solid body
- F42B12/745—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material of the core or solid body the core being made of plastics; Compounds or blends of plastics and other materials, e.g. fillers
Definitions
- the present invention relates to frangible ammunition or bullets for use in training ranges as an alternative to live ammunition. More specifically, the invention relates to frangible bullets having a heavy metal loaded polymer core which is partially jacketed in a high-density high-strength material, such as copper.
- Lead has been a preferred material mainly because of its high density, which is beneficial for range of firing and for weapon functioning. Furthermore, because of their high ductility, lead bullets may be easily manufactured in various shapes and sizes. While lead has many characteristics beneficial to bullet manufacture, it also has drawbacks. Lead is a toxic metal that presents a health risk to the shooter from lead fumes and dust, and endangers the environment through contamination of ground water supplies.
- lead rifle bullets present additional hazards to individuals engaged in weapons training and to the range infrastructure, such as over-penetration, ricochet and backsplatter.
- Lead rifle bullets particularly those used in the military, are designed to penetrate hard surfaces such as mild steel and concrete. While in a combat situation this penetration may be desirable, in training it causes costly damage to target systems and training structures.
- FIG. 1 shows a prior art unjacketed, one piece, polymer frangible bullet.
- the bullet has a cylindrical body formed with a tapered nose portion.
- Prior art bullets of this type are commonly manufactured by injection molding.
- a common composition of such prior art frangible bullets is a compounded mixture of type 11 nylon (known generally in the art as N11 nylon), copper powder and tungsten powder.
- a typical bullet manufactured of such a mixture in the shape depicted in FIG. 1 weighs 33 grains.
- One solution is to increase the ratio of metal powders to polymer until the desired bullet weight is obtained.
- the physical dimensional constraints of the bullet limit the overall bullet weight using existing metal powders and polymer materials.
- the physical dimensions of the rifle chamber fix the bullet's diameter and overall length. Therefore, all combinations of metal powders and polymer are constrained in overall volume by the requirement of dimensional compatibility with existing weaponry.
- polymer bullets In addition to high chamber pressures and supersonic velocities, polymer bullets must also endure high chamber and barrel temperatures that result from automatic fire. These temperatures may exceed the melting temperature of the polymer used in the bullet's compound. Thus, if the bullet remains in the chamber too long before exiting, the polymer may soften, again resulting in a catastrophic bullet failure. This is especially the case in prior art unjacketed frangible bullet designs, in which the bullet material is exposed directly to the combustion gases which propel the bullet through the barrel.
- a frangible bullet having a core member constructed of a mixture containing a thermoplastic polymer and a lead-free heavy metal, in combination with an outer jacket.
- the core member has a back end, an opposite tip end, and a central portion therebetween, defining a core length between the back end and the tip end.
- a core member having suitable strength and weight characteristics may be formed from a mixture of a type 6 nylon polymer, copper powder, and tungsten powder.
- the outer jacket which may be constructed of copper or other suitable high density, high strength metal, plastic or other polymer, has an enclosed first end and an opposite open second end defining a jacket length between its two ends.
- the outer jacket defines a jacket chamber for encapsulating the back end and a part of the central portion of the core member, thereby shielding the core member from the high chamber temperatures which have led to in-bore bullet failure in prior art frangible bullet embodiments.
- the outer jacket also forms the circumferential perimeter of the bullet of the present invention, enabling more precise control of bullet caliber than is possible in prior art designs.
- the outer jacket is configured such that the nose or tip of the frangible core member is exposed.
- the unjacketed tip end of the core member impacts the target first. Deceleration shock on impact causes disintegration of the bullet core member, and rearward radiation of that shock ensures fragmentation of the outer jacket.
- Addition of the outer jacket to the frangible core member increases the bullet's dynamic strength such that less costly, lower shear strength polymer materials may be utilized in manufacture of the core member.
- use of a lower shear strength polymer also ensures more complete disintegration of the core member upon bullet impact.
- Incorporation of the outer jacket into the bullet design also results in an increased bullet weight, which yields greater reliability and accuracy than may be obtained with prior art unjacketed frangible ammunition.
- FIG. 1 is a side elevational view of a prior art unjacketed frangible bullet.
- FIG. 2 is a perspective view of a frangible munitions cartridge according to the present invention.
- FIG. 3 is a side elevational view of an embodiment of the core member of the jacketed frangible bullet according to the present invention.
- FIG. 4 is a side elevational view of an embodiment of the jacketed frangible bullet according to the present invention.
- the invention is a jacketed frangible bullet 20 having two main components, an elongated frangible core member 30 and an outer jacket 40 .
- the embodiment pictured in FIGS. 2 and 4 represents a 5.56 mm jacketed frangible bullet 20 designed for rifle use, but it should be understood that the scope of this invention extends to all calibers of bullets for use in any pistol or manual, semi-automatic or fully-automatic rifle or machine gun, or any other weapon system in which use of a frangible bullet 20 is advantageous.
- the core member 30 has a back end 32 , an opposite tip end 34 and a central portion 36 therebetween.
- the length of the core member 30 is defined by the distance between the back end 32 and the tip end 34 .
- the core length L 1 is approximately 0.8 inch.
- the core member 30 is fabricated from materials including a thermoplastic polymer and at least one metal. Both type 11 and type 6 nylon materials (commonly known in the art as N11 and N6 nylons, respectively), have been successfully utilized in fabricating frangible munitions. It has been discovered that N6 nylon is preferable to N11 nylon because of its lower cost and higher specific gravity and because of its greater frangibility. N11 nylon, however, exhibits greater shear strength and bonding characteristics over N6 nylon, such that use of N11 nylon permits the use of an increased ratio of metal powder to thermoplastic polymer in the core member 30 composition.
- thermoplastic polymer materials in addition to those discussed above may also be utilized, including other polyamids (including other nylon formulations), polyesters and polyurethanes.
- the thermoplastic polymer component may be fabricated partially or exclusively of polyvinyl chloride, fluorocarbons, linear polyethylene, polyurethane prepolymer, polystyrene, polypropylene and cellulosic and acrylic resins. It is critical, however, that the selected thermoplastic polymer utilized to form the core member 30 be highly frangible in order not to increase the terminal penetration effects of the bullet 20 .
- a metal component is provided in combination with the above-described thermoplastic polymer to form the core member 30 .
- the metal component of the core member 30 includes at least one metal, and may include a combination of two or more metals as needed to achieve the desired bullet weight for the selected weapon system.
- Metal components are selected, in part, based upon their density and their suitability for combination with the selected thermoplastic polymer to form a completed core member 30 . Because of their relatively high specific gravity, heavy metal elements have been utilized to form the metal component of the core member 30 .
- the metal component is commonly utilized in powder form, because of the relative ease with which powdered metals may be mixed and combined with the thermoplastic polymer material. Alternatively, metals in particulate or other forms may be utilized if they are capable of combination with the thermoplastic polymer.
- copper powder and tungsten powder are have been utilized to form the metal component of the core member 30 .
- a core member 30 including N6 nylon, copper powder and tungsten powder is utilized, in relative concentrations that result in an overall core member 30 specific gravity of 6.0.
- This material is commercially available from Saracen Chemicals, Ltd., a United Kingdom company with offices at Vulcan House, Restmer Way, Ralphbridge, Surrey, SM6 7AH, England. This material has been found to exhibit superior frangibility over a similar material containing N11 nylon, copper powder and tungsten powder having a specific gravity of 5.4.
- the addition of the outer jacket 40 which significantly increases the structural and thermal durability of the bullet 20 , enables use of the N6 nylon core member 30 , resulting in reduced cost and superior performance over the prior art.
- Other metals may be utilized in the core member 30 without departing from the scope of the invention.
- Selected or combined heavy metals including transition metals, lanthanides and actinides provide suitable mass to the core member 30 to meet performance criteria of frangible ammunition. Because of price, availability and manufacturing concerns, four common metals have been primarily utilized in the art: zinc, tin, copper and tungsten. Any metal selected from this group may be utilized to produce frangible ammunition according to the invention.
- the core member 30 may be manufactured according to methods known in the art, including injection molding.
- FIG. 3 illustrates a reduced diameter, 30-grain frangible bullet core member 30 according to the present invention, compounded of a mixture of N6 nylon, copper powder and tungsten powder.
- the core diameter is reduced relative to unjacketed bullet core members to allow for application of the outer jacket 40 illustrated in FIGS. 2 and 4 and as described in detail below.
- FIGS. 2 and 4 illustrate the placement of the outer jacket 40 on the frangible core member 30 .
- Encapsulating the core member 30 in the outer jacket 40 isolates the core member 30 from direct contact with the heated chamber of the weapon, significantly reducing the potential for softening of the material and in-bore catastrophic failure of the bullet 20 .
- the outer jacket 40 has a closed first end 42 and an opposite opened second end 44 .
- the jacket length L 2 is the distance between the first end 42 and the second end 44 of the outer jacket 40 .
- the hollow interior of the outer jacket 40 is referred to herein as the jacket chamber.
- the outer jacket 40 encloses a portion of the frangible core member 30 , including the back end 32 and a portion of the central portion 36 of the core member 30 , leaving at least the tip end 34 fully exposed. Installation of the outer jacket 40 over the back end 32 of the core member 30 with the tip end 34 exposed ensures that the frangible material will impact the target first.
- the deceleration shock generated by impact radiates rearward, ensuring the effective disintegration of the entire core member 30 .
- Outer jackets 40 fabricated from copper have been utilized and found acceptable for use in the present invention because of the ductility, weight and deformability of copper.
- Other materials may be utilized to form the outer jacket 40 without departing from the scope of the invention.
- outer jackets 40 may be fabricated from other metals, including mild steel, guilding metal, guilding clad steel or coated tin.
- synthetic thermoplastic polymer materials may be utilized to form the outer jacket 40 , provided that the selected polymer exhibits sufficient rigidity under barrel operating temperatures, without departing from the invention.
- the back end 32 of the core member 30 When assembled, the back end 32 of the core member 30 is inserted into the jacket chamber until the back end 32 is seated adjacent the first end 42 of the outer jacket 40 .
- the second end 44 of the outer jacket 40 is crimped or necked-down to fixedly secure the core member 30 within the outer jacket 40 .
- Adding this outer jacket 40 to the 30-grain core member 30 produces an overall bullet weight of 45 grains. This jacketing procedure increases the 5.56 mm bullet weight by 36 percent.
- the dimensions of the core member 30 and the outer jacket 40 are controlled such that the core length L 1 is greater than the jacket length L 2 . Consequently, the tip end 34 , or ogive, of the core member 30 is unjacketed and exposed to impact with targets. As discussed above, this condition has been found to promote full frangibility without significantly compromising performance of the munitions. Conversely, testing conducted with fully copper-jacketed frangible bullets has resulted in over penetration and significantly limited disintegration of the bullet.
- a lubricant may be applied to the exterior surface of the outer jacket 40 to improve weapon performance.
- Suitable lubricants include coatings such as Teflon, a variety of oil-based lubricants such as Militec, and a variety of powder-based lubricants such as graphite, which are known generally in the art. It should be noted that the use of some lubricants such as Teflon is restricted by various legislation currently in place.
- An operational frangible munitions cartridge 50 is produced by loading the frangible bullet 20 described above into a cartridge case 52 .
- the cartridge case 52 has a base end 54 and an opposite opened mouth end 56 .
- the cartridge case 52 is generally hollow, defining a chamber therein which is loaded with powder and air to provide a charge.
- the jacketed frangible bullet 20 is mounted within the opening defined by the mouth end 56 of the cartridge case 52 as is generally known in the art.
- the jacketed frangible bullet 20 protrudes from the mouth end 56 of the cartridge case 52 , such that the first end 42 and a portion of the outer jacket 40 are contained within the cartridge case 52 .
- the second end 44 of the outer jacket 40 and the remaining portion of the outer jacket 40 protrude from the mouth end 56 of the cartridge case 52 .
- a primer (not shown) is provided in the base end 54 of the cartridge case 52 that detonates the charge when the weapon is fired.
- the sudden and substantial pressure created by the combustion of the charge within the confined chamber within the cartridge case 52 impart the forces necessary to eject the frangible bullet 20 from the cartridge case 52 and accelerate the bullet 20 to its firing speed.
- the diameter of the bullet 20 illustrated in FIG. 4 is full caliber, meaning that the outside dimension of the bullet 20 conforms to the minimum and maximum outside dimensions established for this caliber bullet 20 by the Sporting Arms and Ammunition Manufacturers Institute (SAAMI) specification.
- SAAMI Sporting Arms and Ammunition Manufacturers Institute
- the overall length of the cartridge 50 , once loaded in the cartridge case 52 also falls within those standards.
- testing of the heavier, copper jacketed 45-grain 5.56 mm bullet according to one embodiment of the present invention demonstrated not only improvement, but pressures and accuracy equal to or surpassing that achieved by conventional military combat ball ammunition.
- the new 45-grain bullet produced chamber pressures and gas port pressures of 50,300 and 14,915 pounds per square inch respectively, while the military's issued ammunition provided pressures of 47,000 and 15,139 pounds per square inch.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A frangible bullet for use in training ranges as an alternative to live ammunition, which disintegrates upon impact with a target. The frangible bullet includes an elongated frangible core member fabricated from a thermoplastic polymer and at least one metal, the core member having a back end, an opposite tip end and a central portion therebetween, and having a core length between the back end and the tip end. The core member is jacketed in an outer jacket having a closed first end and an opposite opened second end, having a jacket length between the first end and second end, and defining a jacket chamber for complementarily receiving the core member therein. The core member fits inside the outer jacket such that the tip end of the frangible core member is exposed and impacts the target first, resulting in fragmentation of the core member and the outer jacket.
Description
- This application claims priority to U.S. provisional application Ser. No. 60/127,657 filed on Apr. 2, 1999. The No. 60/127,657 provisional patent application is herein incorporated by this reference in its entirety.
- 1. Field of the Invention
- The present invention relates to frangible ammunition or bullets for use in training ranges as an alternative to live ammunition. More specifically, the invention relates to frangible bullets having a heavy metal loaded polymer core which is partially jacketed in a high-density high-strength material, such as copper.
- 2. Background Art
- Traditionally, rifle bullets have been manufactured from lead. Lead has been a preferred material mainly because of its high density, which is beneficial for range of firing and for weapon functioning. Furthermore, because of their high ductility, lead bullets may be easily manufactured in various shapes and sizes. While lead has many characteristics beneficial to bullet manufacture, it also has drawbacks. Lead is a toxic metal that presents a health risk to the shooter from lead fumes and dust, and endangers the environment through contamination of ground water supplies.
- In addition to the health and environmental issues addressed above, lead rifle bullets present additional hazards to individuals engaged in weapons training and to the range infrastructure, such as over-penetration, ricochet and backsplatter. Lead rifle bullets, particularly those used in the military, are designed to penetrate hard surfaces such as mild steel and concrete. While in a combat situation this penetration may be desirable, in training it causes costly damage to target systems and training structures.
- These environmental, health, and bullet performance concerns have precipitated a number of bullet developments and innovations. New bullet designs have emerged which incorporate a variety of non-toxic material alternatives to the lead contained in standard ammunition. Included in this group are a number bullet designs utilizing heavy metal loaded polymers, generally classified as “frangible” ammunition.
- Frangible bullets, which typically contain no lead, were designed to address both the physical hazards and adverse performance characteristics of lead bullets. The heavy metal loaded polymer construction of these bullets was designed to ensure consistent breakup of the bullet on impact with solid materials such as steel. These early frangible rifle bullets demonstrated a significant reduction in ricochet with a total elimination of lead toxins.
- FIG. 1 shows a prior art unjacketed, one piece, polymer frangible bullet. The bullet has a cylindrical body formed with a tapered nose portion. Prior art bullets of this type are commonly manufactured by injection molding. A common composition of such prior art frangible bullets is a compounded mixture of type 11 nylon (known generally in the art as N11 nylon), copper powder and tungsten powder. A typical bullet manufactured of such a mixture in the shape depicted in FIG. 1 weighs 33 grains.
- There are a number of competing design considerations at work in the construction of a frangible bullet. A primary design focus for developers of this type of bullet has always been bullet weight. Prior art bullets have been molded from a compound comprising a metal powder or combination of metal powders combined with a nylon polymer. The metal powder mixture is incorporated with the nylon polymer to provide an increased bullet weight over bullet constructions containing only nylon polymer. Of course, an increased density or ratio of metal powder to nylon in the bullet composition produces a commensurate increase in bullet weight. Bullet weights that approximate the weight of standard lead-core bullets are most conducive to proper weapon functioning. Bullet weights that approach the weight of standard bullets also improve bullet down-range accuracy by sustaining higher bullet energy levels at greater distances.
- Reliable weapons functioning in most automatic and semiautomatic rifles is a result of adequate gas pressure, produced by the burning propellant in the cartridge, reaching the rifle's gas operating system. Higher gas pressure within the barrel frequently has a direct, positive effect on the reliability of weapon. Bullet weight is also relevant to reliability of weapons functioning. The cartridge, regardless of the bullet weight, produces approximately the same initial gas pressure within the barrel. The amount and type of powder utilized, not the bullet composition, dictates the initial pressure level. As the powder burns, pressure builds behind the bullet, causing the bullet to travel down the barrel of the weapon toward the gas port located near the muzzle. The pressure level rearward of the bullet as the bullet passes the gas port is critical to proper weapon functioning.
- The heavier the bullet, the greater its inertia, and consequently the slower its initial velocity within the barrel. A heavier, slower moving bullet provides more time for the powder to burn, resulting in a higher pressure buildup within the barrel, and particularly at the gas port. Inversely, lighter bullets travel through the barrel at increased velocities, resulting in reduced pressure at the gas port.
- One solution is to increase the ratio of metal powders to polymer until the desired bullet weight is obtained. However, the physical dimensional constraints of the bullet limit the overall bullet weight using existing metal powders and polymer materials. The physical dimensions of the rifle chamber fix the bullet's diameter and overall length. Therefore, all combinations of metal powders and polymer are constrained in overall volume by the requirement of dimensional compatibility with existing weaponry.
- Other elements constraining the ratio of metal powders to polymer are the desired terminal characteristics of the bullet and the internal ballistic environment within the chamber of the weapon. The desired terminal effect of a frangible bullet is frangibility. It is desired that the bullet disintegrate as completely as possible upon impact with solid objects. Total disintegration to dust is the ultimate design objective. The degree of fragmentation is determined in part by bullet diameter and terminal velocity. Generally, the smaller the bullet diameter and higher the terminal velocity, the more complete the disintegration. In the case of heavy metal loaded polymer frangible bullets, the fragmentation or disintegration of the bullet on impact is also a function of the ratio of metals to polymer. The polymer dictates the strength of the bullet. Thus, a higher relative content of polymer produces a stronger bullet. While this consideration would appear to further support the use of higher ratios of metals in frangible bullet design, the ratio is constrained by the internal ballistic environment that the bullet must survive within the weapon.
- Internal chamber pressures of automatic and semiautomatic rifles are approximately 50,000 pounds per square inch, and bullet velocities exceed 3,000 feet per second. The material strength of polymer frangible bullets must be sufficient to withstand these extreme pressures and velocities. If the ratio of metal to polymer is too high, the bullet will suffer a catastrophic, in-bore failure, which may damage the weapon and present a physical hazard to people in the proximity of the weapon. Thus, to ensure sufficient bullet strength, a minimum polymer to metals ratio must be maintained in the compound.
- In addition to high chamber pressures and supersonic velocities, polymer bullets must also endure high chamber and barrel temperatures that result from automatic fire. These temperatures may exceed the melting temperature of the polymer used in the bullet's compound. Thus, if the bullet remains in the chamber too long before exiting, the polymer may soften, again resulting in a catastrophic bullet failure. This is especially the case in prior art unjacketed frangible bullet designs, in which the bullet material is exposed directly to the combustion gases which propel the bullet through the barrel.
- In 1997, the Light Weapons Division of the Armament and Ammunition Testing Directorate of the U.S. Army Aberdeen Test Center, Aberdeen Proving Grounds, Md., published a Report of a Technical Feasibility Test of then-existing 5.56 mm and 9 mm Frangible Training Ammunition. This early government testing of unjacketed polymer ammunition documented unacceptable operational reliability for frangible rifle caliber bullets as a direct result of low chamber/gas port pressures across the spectrum of material candidates. In addition, all candidate bullets tested performed poorly in accuracy testing at ranges exceeding 50 meters. Some candidate compounds also suffered catastrophic failure due to inadequate bullet strength.
- Thus, it is an object of the invention to provide a non-toxic frangible bullet which will provide the necessary bullet weight to function reliably in existing firearms. More specifically, significant demand exists for a such a frangible bullet for use in military automatic rifles and light machine guns.
- It is a further object of the invention to eliminate the potential of catastrophic bullet failure by ensuring material strength and core isolation from chamber heat.
- It is a further object of the invention to improve the accuracy and performance of polymer frangible bullets by increasing both bullet weight and bullet to barrel interface.
- It is a further object of the invention to accomplish the above-mentioned improvements without sacrificing the reduced over-penetration, ricochet and backsplatter hazard characteristics previously demonstrated by unjacketed polymer frangible bullets.
- The disadvantages of the prior art are overcome by the present invention which, in one aspect, is a frangible bullet having a core member constructed of a mixture containing a thermoplastic polymer and a lead-free heavy metal, in combination with an outer jacket. The core member has a back end, an opposite tip end, and a central portion therebetween, defining a core length between the back end and the tip end. In one embodiment, a core member having suitable strength and weight characteristics may be formed from a mixture of a type 6 nylon polymer, copper powder, and tungsten powder.
- The outer jacket, which may be constructed of copper or other suitable high density, high strength metal, plastic or other polymer, has an enclosed first end and an opposite open second end defining a jacket length between its two ends. The outer jacket defines a jacket chamber for encapsulating the back end and a part of the central portion of the core member, thereby shielding the core member from the high chamber temperatures which have led to in-bore bullet failure in prior art frangible bullet embodiments. The outer jacket also forms the circumferential perimeter of the bullet of the present invention, enabling more precise control of bullet caliber than is possible in prior art designs.
- The outer jacket is configured such that the nose or tip of the frangible core member is exposed. Thus, the unjacketed tip end of the core member impacts the target first. Deceleration shock on impact causes disintegration of the bullet core member, and rearward radiation of that shock ensures fragmentation of the outer jacket.
- Addition of the outer jacket to the frangible core member increases the bullet's dynamic strength such that less costly, lower shear strength polymer materials may be utilized in manufacture of the core member. In addition to an increased cost-effectiveness, use of a lower shear strength polymer also ensures more complete disintegration of the core member upon bullet impact. Incorporation of the outer jacket into the bullet design also results in an increased bullet weight, which yields greater reliability and accuracy than may be obtained with prior art unjacketed frangible ammunition.
- FIG. 1 is a side elevational view of a prior art unjacketed frangible bullet.
- FIG. 2 is a perspective view of a frangible munitions cartridge according to the present invention.
- FIG. 3 is a side elevational view of an embodiment of the core member of the jacketed frangible bullet according to the present invention.
- FIG. 4 is a side elevational view of an embodiment of the jacketed frangible bullet according to the present invention.
- The present invention is more particularly described in the following examples that are intended as illustrative only since numerous modifications and variations therein will be apparent to those skilled in the art. As used in the specification and in the claims, “a” can mean one or more, depending upon the context in which it is used. The preferred embodiment is now described with reference to the figures, in which like components indicate like parts throughout the figures.
- As shown in FIGS. 2 and 4, in one embodiment, the invention is a jacketed
frangible bullet 20 having two main components, an elongatedfrangible core member 30 and anouter jacket 40. The embodiment pictured in FIGS. 2 and 4 represents a 5.56 mm jacketedfrangible bullet 20 designed for rifle use, but it should be understood that the scope of this invention extends to all calibers of bullets for use in any pistol or manual, semi-automatic or fully-automatic rifle or machine gun, or any other weapon system in which use of afrangible bullet 20 is advantageous. - Referring to FIG. 3, the
core member 30 has aback end 32, anopposite tip end 34 and acentral portion 36 therebetween. The length of thecore member 30, or the core length L1, is defined by the distance between theback end 32 and thetip end 34. In the embodiment illustrated in FIGS. 3 and 4, corresponding to a 5.56 mm rifle bullet, the core length L1 is approximately 0.8 inch. - The
core member 30 is fabricated from materials including a thermoplastic polymer and at least one metal. Both type 11 and type 6 nylon materials (commonly known in the art as N11 and N6 nylons, respectively), have been successfully utilized in fabricating frangible munitions. It has been discovered that N6 nylon is preferable to N11 nylon because of its lower cost and higher specific gravity and because of its greater frangibility. N11 nylon, however, exhibits greater shear strength and bonding characteristics over N6 nylon, such that use of N11 nylon permits the use of an increased ratio of metal powder to thermoplastic polymer in thecore member 30 composition. - In prior art unjacketed frangible bullet designs for 5.56 mm weapons, as shown in FIG. 1, bullet performance criteria have not been met by bullets utilizing the less expensive N6 nylon material. Thus, prior art 5.56 mm unjacketed frangible bullets have been manufactured using N11 nylon materials. As discussed in detail below, however, by the addition of an
outer jacket 40 to thefrangible bullet 20, dynamic strength characteristics of thebullet 20 are significantly improved, permitting the use of the less costly and lower shear strength N6 nylon material as the bonding agent for the compound. Use of the N6 nylon results in a core material more frangible than compound made with the N11 nylon. - According to the invention, other thermoplastic polymer materials in addition to those discussed above may also be utilized, including other polyamids (including other nylon formulations), polyesters and polyurethanes. Additionally, the thermoplastic polymer component may be fabricated partially or exclusively of polyvinyl chloride, fluorocarbons, linear polyethylene, polyurethane prepolymer, polystyrene, polypropylene and cellulosic and acrylic resins. It is critical, however, that the selected thermoplastic polymer utilized to form the
core member 30 be highly frangible in order not to increase the terminal penetration effects of thebullet 20. - A metal component is provided in combination with the above-described thermoplastic polymer to form the
core member 30. The metal component of thecore member 30 includes at least one metal, and may include a combination of two or more metals as needed to achieve the desired bullet weight for the selected weapon system. Metal components are selected, in part, based upon their density and their suitability for combination with the selected thermoplastic polymer to form a completedcore member 30. Because of their relatively high specific gravity, heavy metal elements have been utilized to form the metal component of thecore member 30. - The metal component is commonly utilized in powder form, because of the relative ease with which powdered metals may be mixed and combined with the thermoplastic polymer material. Alternatively, metals in particulate or other forms may be utilized if they are capable of combination with the thermoplastic polymer.
- In one embodiment, copper powder and tungsten powder are have been utilized to form the metal component of the
core member 30. In a currently preferred embodiment, acore member 30 including N6 nylon, copper powder and tungsten powder is utilized, in relative concentrations that result in anoverall core member 30 specific gravity of 6.0. This material is commercially available from Saracen Chemicals, Ltd., a United Kingdom company with offices at Vulcan House, Restmer Way, Hackbridge, Surrey, SM6 7AH, England. This material has been found to exhibit superior frangibility over a similar material containing N11 nylon, copper powder and tungsten powder having a specific gravity of 5.4. The addition of theouter jacket 40, which significantly increases the structural and thermal durability of thebullet 20, enables use of the N6nylon core member 30, resulting in reduced cost and superior performance over the prior art. - Other metals may be utilized in the
core member 30 without departing from the scope of the invention. Selected or combined heavy metals including transition metals, lanthanides and actinides provide suitable mass to thecore member 30 to meet performance criteria of frangible ammunition. Because of price, availability and manufacturing concerns, four common metals have been primarily utilized in the art: zinc, tin, copper and tungsten. Any metal selected from this group may be utilized to produce frangible ammunition according to the invention. - Once the constituent materials are selected, the
core member 30 may be manufactured according to methods known in the art, including injection molding. - FIG. 3 illustrates a reduced diameter, 30-grain frangible
bullet core member 30 according to the present invention, compounded of a mixture of N6 nylon, copper powder and tungsten powder. The core diameter is reduced relative to unjacketed bullet core members to allow for application of theouter jacket 40 illustrated in FIGS. 2 and 4 and as described in detail below. - FIGS. 2 and 4 illustrate the placement of the
outer jacket 40 on thefrangible core member 30. Encapsulating thecore member 30 in theouter jacket 40 isolates thecore member 30 from direct contact with the heated chamber of the weapon, significantly reducing the potential for softening of the material and in-bore catastrophic failure of thebullet 20. - The
outer jacket 40 has a closedfirst end 42 and an opposite openedsecond end 44. The jacket length L2 is the distance between thefirst end 42 and thesecond end 44 of theouter jacket 40. The hollow interior of theouter jacket 40 is referred to herein as the jacket chamber. Theouter jacket 40 encloses a portion of thefrangible core member 30, including theback end 32 and a portion of thecentral portion 36 of thecore member 30, leaving at least thetip end 34 fully exposed. Installation of theouter jacket 40 over theback end 32 of thecore member 30 with thetip end 34 exposed ensures that the frangible material will impact the target first. The deceleration shock generated by impact radiates rearward, ensuring the effective disintegration of theentire core member 30. -
Outer jackets 40 fabricated from copper have been utilized and found acceptable for use in the present invention because of the ductility, weight and deformability of copper. Other materials may be utilized to form theouter jacket 40 without departing from the scope of the invention. For example,outer jackets 40 may be fabricated from other metals, including mild steel, guilding metal, guilding clad steel or coated tin. Alternatively, synthetic thermoplastic polymer materials may be utilized to form theouter jacket 40, provided that the selected polymer exhibits sufficient rigidity under barrel operating temperatures, without departing from the invention. - When assembled, the
back end 32 of thecore member 30 is inserted into the jacket chamber until theback end 32 is seated adjacent thefirst end 42 of theouter jacket 40. Using a dial press, a hand press or other methods known in the art, thesecond end 44 of theouter jacket 40 is crimped or necked-down to fixedly secure thecore member 30 within theouter jacket 40. Adding thisouter jacket 40 to the 30-grain core member 30 produces an overall bullet weight of 45 grains. This jacketing procedure increases the 5.56 mm bullet weight by 36 percent. - In the illustrated embodiment, the dimensions of the
core member 30 and theouter jacket 40 are controlled such that the core length L1 is greater than the jacket length L2. Consequently, thetip end 34, or ogive, of thecore member 30 is unjacketed and exposed to impact with targets. As discussed above, this condition has been found to promote full frangibility without significantly compromising performance of the munitions. Conversely, testing conducted with fully copper-jacketed frangible bullets has resulted in over penetration and significantly limited disintegration of the bullet. - Additionally, a lubricant may be applied to the exterior surface of the
outer jacket 40 to improve weapon performance. Suitable lubricants include coatings such as Teflon, a variety of oil-based lubricants such as Militec, and a variety of powder-based lubricants such as graphite, which are known generally in the art. It should be noted that the use of some lubricants such as Teflon is restricted by various legislation currently in place. - An operational frangible munitions cartridge 50 is produced by loading the
frangible bullet 20 described above into acartridge case 52. Referring now to FIG. 2, thecartridge case 52 has abase end 54 and an opposite openedmouth end 56. Thecartridge case 52 is generally hollow, defining a chamber therein which is loaded with powder and air to provide a charge. - The jacketed
frangible bullet 20 is mounted within the opening defined by the mouth end 56 of thecartridge case 52 as is generally known in the art. The jacketedfrangible bullet 20 protrudes from the mouth end 56 of thecartridge case 52, such that thefirst end 42 and a portion of theouter jacket 40 are contained within thecartridge case 52. Thesecond end 44 of theouter jacket 40 and the remaining portion of theouter jacket 40, including the crimped or necked-down portion of theouter jacket 40 and thetip end 34 of thecore member 30, protrude from the mouth end 56 of thecartridge case 52. - A primer (not shown) is provided in the
base end 54 of thecartridge case 52 that detonates the charge when the weapon is fired. The sudden and substantial pressure created by the combustion of the charge within the confined chamber within thecartridge case 52 impart the forces necessary to eject thefrangible bullet 20 from thecartridge case 52 and accelerate thebullet 20 to its firing speed. - The diameter of the
bullet 20 illustrated in FIG. 4 is full caliber, meaning that the outside dimension of thebullet 20 conforms to the minimum and maximum outside dimensions established for thiscaliber bullet 20 by the Sporting Arms and Ammunition Manufacturers Institute (SAAMI) specification. The overall length of the cartridge 50, once loaded in thecartridge case 52, also falls within those standards. - Testing Results
- Testing of an unjacketed 33-grain 5.56 mm frangible cartridge described above in the discussion of the prior art provided pressure results at the chamber of 124,136 pounds per square inch and 9,695 pounds per square inch at the gas port. These results indicate that the unjacketed 33-grain bullet of the prior art was producing case pressures 8,000 to 10,000 pounds per square inch less than currently used, non-frangible military ball ammunition. More importantly, the gas port pressures for the prior art style frangible bullet were 3,000 pounds per square inch lower than the minimal acceptable value for ball ammunition. The government's Report of its Technical Feasibility Test concluded that “[t]he ramification of these differences is that weapon function may be degraded across the temperature profile since all 5.56 mm weapon systems are gas operated.”
- In contrast to test results from prior art unjacketed 33-grain bullet test results, testing of the heavier, copper jacketed 45-grain 5.56 mm bullet according to one embodiment of the present invention demonstrated not only improvement, but pressures and accuracy equal to or surpassing that achieved by conventional military combat ball ammunition. In side-by-side testing, the new 45-grain bullet produced chamber pressures and gas port pressures of 50,300 and 14,915 pounds per square inch respectively, while the military's issued ammunition provided pressures of 47,000 and 15,139 pounds per square inch. These improved pressures result in enhanced reliability and performance of the frangible cartridge to levels that satisfy the military's requirement.
- In addition, accuracy improvements surpassed the performance of military ball ammunition at 100 meters and matched military ball's performance at 200 meters. Equally important, side-by-side comparative testing of the 33-grain unjacketed bullet and the 45-grain jacketed bullet demonstrated no measurable penetration or frangibility difference between the two cartridges.
- During all testing by both the inventors and by the government, no instance of catastrophic failure of the jacketed 45-grain bullet was experienced at operating temperatures that ranged from 60 to −29 degrees C.
- Although the present invention has been described with reference to specific details of certain embodiments thereof, it is not intended that such details should be regarded as limitations upon the scope of the invention except as and to the extent that they are included in the accompanying claims.
Claims (22)
1. A frangible bullet, comprising:
a. an elongated frangible core member comprising a thermoplastic polymer and at least one metal, having a back end, an opposite tip end and a central portion therebetween, and having a core length between the back end and the tip end; and
b. an outer jacket having a closed first end and an opposite opened second end, having a jacket length between the first end and second end, and defining a jacket chamber for complementarily receiving the core member therein,
wherein the back end of the core member is contained within the outer jacket adjacent the first end thereof, and wherein the core length is greater than the jacket length.
2. The frangible bullet of , wherein the metal of the core member is in powder form.
claim 1
3. The frangible bullet of , wherein the metal of the core member is in particulate form.
claim 1
4. The frangible bullet of , wherein the metal of the core member comprises a heavy metal.
claim 1
5. The frangible bullet of , wherein the core member comprises two different heavy metals.
claim 4
6. The frangible bullet of , wherein the heavy metals are copper and tungsten.
claim 5
7. The frangible bullet of , wherein the metal of the core member comprises zinc.
claim 4
8. The frangible bullet of , wherein the metal of the core member comprises copper.
claim 4
9. The frangible bullet of , wherein the metal of the core member comprises tungsten.
claim 4
10. The frangible bullet of , wherein the metal of the core member comprises tin.
claim 4
11. The frangible bullet of , wherein the outer jacket is constructed of copper.
claim 1
12. The frangible bullet of , wherein the outer jacket further comprises a jacket exterior surface extending between the first end and the second end, the exterior surface being coated with a lubricant.
claim 1
13. The frangible bullet of , wherein the thermoplastic polymer comprises a polyamid.
claim 1
14. The frangible bullet of , wherein the thermoplastic polymer comprises a polyurethane.
claim 1
15. The frangible bullet of , wherein the thermoplastic polymer comprises a polyester.
claim 1
16. The frangible bullet of , wherein the polyamid comprises Type 6 Nylon.
claim 13
17. The frangible bullet of , wherein the polyamid comprises Type 11 Nylon.
claim 13
18. The frangible bullet of , wherein the core member comprises Type 6 Nylon, copper powder and tungsten powder.
claim 1
19. The frangible bullet of , wherein the core member has a specific gravity greater than 5.4.
claim 18
20. The frangible bullet of , wherein the core member has a specific gravity substantially equal to 6.0.
claim 18
21. A frangible munitions cartridge, comprising:
a. a cartridge case having a base end with a primer disposed therein and an opposite opened mouth end, the cartridge case defining a chamber between the two ends and containing a charge therein;
b. a frangible bullet mounted within the opening defined by the mouth end of the cartridge case, the frangible bullet comprising: an elongated frangible core member comprising a thermoplastic polymer and at least one metal, having a back end, an opposite tip end and a central portion therebetween, and having a core length between the back end and the tip end; and an outer jacket having a closed first end and an opposite opened second end, having a jacket length between the first end and second end, and defining a jacket chamber for complementarily receiving the core member therein, wherein the back end of the core member is contained within the outer jacket adjacent the first end thereof, and wherein the core length is greater than the jacket length.
22. A method of forming a frangible bullet, comprising:
a. providing an elongated frangible core member comprising a thermoplastic polymer and at least one metal, having a back end, an opposite tip end and a central portion therebetween, and having a core length between the back end and the tip end;
b. providing an outer jacket having a closed first end and an opposite opened second end, having a jacket length between the first end and second end, and defining a jacket chamber for complementarily receiving the core member therein;
c. inserting the core member into the jacket chamber so that the back end of the core member is adjacent the first end of the outer jacket; and
d. crimping the outer jacket adjacent the second end to fixedly secure the core member within the outer jacket.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/540,569 US20010050020A1 (en) | 1999-04-02 | 2000-03-31 | Jacketed frangible bullets |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12765799P | 1999-04-02 | 1999-04-02 | |
| US09/540,569 US20010050020A1 (en) | 1999-04-02 | 2000-03-31 | Jacketed frangible bullets |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20010050020A1 true US20010050020A1 (en) | 2001-12-13 |
Family
ID=26825847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/540,569 Abandoned US20010050020A1 (en) | 1999-04-02 | 2000-03-31 | Jacketed frangible bullets |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US20010050020A1 (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030027005A1 (en) * | 2001-04-26 | 2003-02-06 | Elliott Kenneth H. | Composite material containing tungsten, tin and organic additive |
| US20030161751A1 (en) * | 2001-10-16 | 2003-08-28 | Elliott Kenneth H. | Composite material containing tungsten and bronze |
| US20030164063A1 (en) * | 2001-10-16 | 2003-09-04 | Elliott Kenneth H. | Tungsten/powdered metal/polymer high density non-toxic composites |
| US20040129165A1 (en) * | 2001-04-24 | 2004-07-08 | Cesaroni Anthony Joseph | Lead-free projectiles |
| US20050188890A1 (en) * | 2004-02-26 | 2005-09-01 | Alltrista Zinc Products, L.P. | Composition and method for making frangible bullet |
| US20050223882A1 (en) * | 2004-02-10 | 2005-10-13 | Yaich Daniel S | Cannelured frangible cartridge and method of canneluring a frangible projectible |
| US20090254171A1 (en) * | 2003-11-14 | 2009-10-08 | Tundra Compsites Llc | Enhanced property metal polymer composite |
| US8393273B2 (en) | 2009-01-14 | 2013-03-12 | Nosler, Inc. | Bullets, including lead-free bullets, and associated methods |
| US9052174B2 (en) | 2007-08-31 | 2015-06-09 | Ra Brands, L.L.C. | Tipped projectiles |
| US9105382B2 (en) | 2003-11-14 | 2015-08-11 | Tundra Composites, LLC | Magnetic composite |
| US9153377B2 (en) | 2008-01-18 | 2015-10-06 | Tundra Composites, LLC | Magnetic polymer composite |
| US9249283B2 (en) | 2009-04-29 | 2016-02-02 | Tundra Composites, LLC | Reduced density glass bubble polymer composite |
| US20160131463A1 (en) * | 2012-06-06 | 2016-05-12 | Saltech Ag | Training Projectile and Training Cartridge |
| US20190186880A1 (en) * | 2016-12-07 | 2019-06-20 | Russell LeBlanc | Frangible Projectile and Method of Manufacture |
| US10537429B2 (en) | 2012-10-31 | 2020-01-21 | Medtronic Vascular Galway | Prosthetic mitral valve and delivery method |
| US10760885B2 (en) | 2017-10-17 | 2020-09-01 | Smart Nanos, Llc. | Multifunctional composite projectiles and methods of manufacturing the same |
| US11821714B2 (en) | 2017-10-17 | 2023-11-21 | Smart Nanos, Llc | Multifunctional composite projectiles and methods of manufacturing the same |
| US20250277654A1 (en) * | 2024-02-29 | 2025-09-04 | The United States Of America, As Represented By The Secretary Of The Navy | Polymer jacked solid core projectile |
| US12442628B2 (en) | 2017-10-17 | 2025-10-14 | Smart Nanos, Llc | Multifunctional composite projectiles and methods of manufacturing the same |
-
2000
- 2000-03-31 US US09/540,569 patent/US20010050020A1/en not_active Abandoned
Cited By (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7607394B2 (en) * | 2001-04-24 | 2009-10-27 | Anthony Joseph Cesaroni | Lead-free projectiles |
| US20040129165A1 (en) * | 2001-04-24 | 2004-07-08 | Cesaroni Anthony Joseph | Lead-free projectiles |
| US6815066B2 (en) | 2001-04-26 | 2004-11-09 | Elliott Kenneth H | Composite material containing tungsten, tin and organic additive |
| US20030027005A1 (en) * | 2001-04-26 | 2003-02-06 | Elliott Kenneth H. | Composite material containing tungsten, tin and organic additive |
| US20060118211A1 (en) * | 2001-10-16 | 2006-06-08 | International Non-Toxic Composites | Composite material containing tungsten and bronze |
| US6916354B2 (en) | 2001-10-16 | 2005-07-12 | International Non-Toxic Composites Corp. | Tungsten/powdered metal/polymer high density non-toxic composites |
| US7232473B2 (en) | 2001-10-16 | 2007-06-19 | International Non-Toxic Composite | Composite material containing tungsten and bronze |
| US20030164063A1 (en) * | 2001-10-16 | 2003-09-04 | Elliott Kenneth H. | Tungsten/powdered metal/polymer high density non-toxic composites |
| US20030161751A1 (en) * | 2001-10-16 | 2003-08-28 | Elliott Kenneth H. | Composite material containing tungsten and bronze |
| US9105382B2 (en) | 2003-11-14 | 2015-08-11 | Tundra Composites, LLC | Magnetic composite |
| US20090254171A1 (en) * | 2003-11-14 | 2009-10-08 | Tundra Compsites Llc | Enhanced property metal polymer composite |
| US20050223882A1 (en) * | 2004-02-10 | 2005-10-13 | Yaich Daniel S | Cannelured frangible cartridge and method of canneluring a frangible projectible |
| US7143679B2 (en) | 2004-02-10 | 2006-12-05 | International Cartridge Corporation | Cannelured frangible cartridge and method of canneluring a frangible projectible |
| US20070144395A1 (en) * | 2004-02-10 | 2007-06-28 | International Cartridge Corporation | Cannelured frangible projectile and method of canneluring a frangible projectile |
| US7322297B2 (en) | 2004-02-10 | 2008-01-29 | International Cartridge Corporation | Cannelured frangible projectile and method of canneluring a frangible projectile |
| US20050188890A1 (en) * | 2004-02-26 | 2005-09-01 | Alltrista Zinc Products, L.P. | Composition and method for making frangible bullet |
| US9052174B2 (en) | 2007-08-31 | 2015-06-09 | Ra Brands, L.L.C. | Tipped projectiles |
| US9153377B2 (en) | 2008-01-18 | 2015-10-06 | Tundra Composites, LLC | Magnetic polymer composite |
| US8393273B2 (en) | 2009-01-14 | 2013-03-12 | Nosler, Inc. | Bullets, including lead-free bullets, and associated methods |
| US11767409B2 (en) | 2009-04-29 | 2023-09-26 | Tundra Composites, LLC | Reduced density hollow glass microsphere polymer composite |
| US11041060B2 (en) | 2009-04-29 | 2021-06-22 | Tundra Composites, LLC | Inorganic material composite |
| US9376552B2 (en) | 2009-04-29 | 2016-06-28 | Tundra Composites, LLC | Ceramic composite |
| US9771463B2 (en) | 2009-04-29 | 2017-09-26 | Tundra Composites, LLC | Reduced density hollow glass microsphere polymer composite |
| US9249283B2 (en) | 2009-04-29 | 2016-02-02 | Tundra Composites, LLC | Reduced density glass bubble polymer composite |
| US10508187B2 (en) | 2009-04-29 | 2019-12-17 | Tundra Composites, LLC | Inorganic material composite |
| US20160131463A1 (en) * | 2012-06-06 | 2016-05-12 | Saltech Ag | Training Projectile and Training Cartridge |
| US10537429B2 (en) | 2012-10-31 | 2020-01-21 | Medtronic Vascular Galway | Prosthetic mitral valve and delivery method |
| US11622855B2 (en) | 2012-10-31 | 2023-04-11 | Medtronic Vascular Galway | Prosthetic mitral valve and delivery method |
| US12232959B2 (en) | 2012-10-31 | 2025-02-25 | Medtronic Vascular Galway | Prosthetic mitral valve and delivery method |
| US10598472B2 (en) * | 2016-12-07 | 2020-03-24 | Russell LeBlanc | Frangible projectile and method of manufacture |
| US20190186880A1 (en) * | 2016-12-07 | 2019-06-20 | Russell LeBlanc | Frangible Projectile and Method of Manufacture |
| US10760885B2 (en) | 2017-10-17 | 2020-09-01 | Smart Nanos, Llc. | Multifunctional composite projectiles and methods of manufacturing the same |
| US11821714B2 (en) | 2017-10-17 | 2023-11-21 | Smart Nanos, Llc | Multifunctional composite projectiles and methods of manufacturing the same |
| US12442628B2 (en) | 2017-10-17 | 2025-10-14 | Smart Nanos, Llc | Multifunctional composite projectiles and methods of manufacturing the same |
| US20250277654A1 (en) * | 2024-02-29 | 2025-09-04 | The United States Of America, As Represented By The Secretary Of The Navy | Polymer jacked solid core projectile |
| US12460909B2 (en) * | 2024-02-29 | 2025-11-04 | The United States Of America, As Represented By The Secretary Of The Navy | Polymer jacked solid core projectile |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20010050020A1 (en) | Jacketed frangible bullets | |
| US6439124B1 (en) | Lead-free tin projectile | |
| US5665808A (en) | Low toxicity composite bullet and material therefor | |
| EP0890076B1 (en) | Lead-free bullet | |
| CA2301805C (en) | Jacketed projectile with a hard core | |
| US9212878B2 (en) | Composite projectile and cartridge with composite projectile | |
| CA1278952C (en) | Ammunition round | |
| US9134102B2 (en) | Light weight projectiles | |
| CA2124420A1 (en) | Projectiles | |
| CA2448968A1 (en) | Dual core ammunition | |
| EP0616684A1 (en) | Training projectile | |
| WO2000062009A1 (en) | Jacketed frangible bullets | |
| US20200141706A1 (en) | Small-arms ammunition with non-brass casing and non-lead projectile | |
| US20110167700A1 (en) | Light activated cartridge and gun for firing same | |
| JPH0445757B2 (en) | ||
| US20190033046A1 (en) | Small-arms ammunition with non-brass casing and non-lead projectile | |
| RU2851118C1 (en) | Shotgun shot cartridge | |
| WO2025122190A2 (en) | Ammunition round with frangible projectile | |
| CA2516893A1 (en) | Non-toxic jacketed ammunition | |
| MXPA00001994A (en) | Jacketed projectile with a hard core |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: DELTA FRANGIBLE AMMUNITION, LLC, VIRGINIA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BAINER, JOHN R.;DAVIS, GEORGE;REEL/FRAME:011256/0798 Effective date: 19990609 |
|
| STCB | Information on status: application discontinuation |
Free format text: EXPRESSLY ABANDONED -- DURING EXAMINATION |