US1965340A - Apparatus for handling molten - Google Patents
Apparatus for handling molten Download PDFInfo
- Publication number
- US1965340A US1965340A US1965340DA US1965340A US 1965340 A US1965340 A US 1965340A US 1965340D A US1965340D A US 1965340DA US 1965340 A US1965340 A US 1965340A
- Authority
- US
- United States
- Prior art keywords
- parts
- molten metal
- molten
- coating
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 description 34
- 239000002184 metal Substances 0.000 description 34
- 239000011248 coating agent Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 14
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000011109 contamination Methods 0.000 description 5
- 238000004512 die casting Methods 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 244000261422 Lysimachia clethroides Species 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 238000005246 galvanizing Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005058 metal casting Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/011—Layered products comprising a layer of metal all layers being exclusively metallic all layers being formed of iron alloys or steels
Definitions
- the primary object of this invention is to prowherein a durable and emcient coating is provided to protect the parts against the action of molten metals which may come in contact therewith.
- the invention 25 contemplates the provision of an apparatus wherein those parts which are subject to attack by the corrosive molten metals are provided with a protective coating consisting preferably of black iron oxide.
- any suitable known actuating mechanism for swinging the gooseneck down into the melting pot to receive a charge of molten metal, and then up into engagement with a stationary die plate 9 of the apparatus when the dies are to be charged.
- a stationary die 10 secured to the stationary plate 9 is engaged by a movable die 11' which. is mounted on a reciproeating plate 12 actuatedby suitable control apfor drogen liberated from 5 which is also usually constructed of cast iron or other ferrous metal.
- the invention contemplates the coating of these ferrous metal parts oxide of iron, preferably formed bythe process set forth in Patent 1,690,378 issued November 6,
- the parts to be coated are placed in an air-tight oven or muffle, brought to a temperature of approximately 1400" F., and subjected to the action of superheated steam which is gradually introduced into the furnace, a small quantity of hydrocarbon oil being placed in a container in the muumble with the iron parts to 0 absorb the excess oxygen which may later be present.
- the amount of steam admitted is gradually increased, and the oxygen thereof combines chemically with the ferrous metal parts to form a black oxide 5 coating over all of their exposed surfaces.
- the hythe steam is driven out of the furnace by opening the door burn.
- An additional'quantity of hydrocarbon oil is then placed in the mufile of the furnace and the door immediately closed.
- the temperature is then raised to about 1420 F., the normal op-.-
- the parts will-have an adherent coating of the black oxide produced on all their surfaces both exterior and interior, as designated by the numerals 15, 16 and 1'7, referring to the melting pot, the gooseneck and the nozzle, respectively. If a smooth protective oxide coating is desired on the parts, they are heated for.
- the inven tion may also be applied to other apparatus for handling molten'metal, wherever it is desired to protect a ferrous metal element from attack by molten metals or alloys.
- a particularly useful application of the method may be made in connection with the galvanizing of sheet metal.
- the ferrous metal container of the molten galvanizing material is also subject to corrosion the same as the die casting apparatus above described, and an oxide coating provided on the container in accordance with this invention prevents undesirable contamination of the molten galvanizing material. with corroded portions of the container.
- this oxide coating may be provided on a great variety of ferrous containers or members used for handling various moltenmetals because it remains inert for temperatures below 1700 F. and does not become wetted by the molten metal.
- a ferrous metal member having a surface designed to contact with molten metal, said surface being provided with a protective crystalline coating of black iron oxide to prevent contamination of the molten metal with the ferrous metal.
- a ferrous metal member having a surface designed to contact with molten metal, said surface being provided with a coating of black iron oxide.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
Description
July'3, 1934. l H. M. HEINICKEI 1,965,340
' APPARATUS. FOR HANDLING MOLTEN METAL Filed Dec. 19, 1930 Patented July 3, 1934 9 UNlTED STATES PATENT OFF-ice 1,965,340 APPARATUS FOR HANDLING MOLTEN METAL Herbert E. Heinicke, Elgin, 111., assignor to Western Electric Company,
Incorporated, New
York, N. 71., a corporation of New York 10 molten metal used in die casting, which may Application December 19, 1930, Serial No. 503,373
3 Claims. (Cl. 2269) paratus (not shown). A nozzle 13 is secured to the discharging end of the gooseneck for conveying the molten metal therefrom through a water cooled bushing 14 and into the dies 10 and l1. During the charging operation, the lower part 8 60 of the goos'eneck and the nozzle 13 are, of course, brought into contact with the molten metal, and as these parts are usually constructed of cast iron, the molten casting alloy attacks them and dissolves or corrodes their exposed surfaces, as 5 well as dissolving or corroding the melting pot This invention relates to apparatus for'handling molten metal, and more particularly to apparatus wherein certain parts are provided with a coating to protect them fromthe action of the 5 molten metal. I
In the casting of metals, it is desirable to provide means whereby the casting apparatus may be protected against the erosive attack of the molten metal which is to be cast. The
be an alloy composed essentially of aluminum or ls problem exists in the vide an improved apparatus theblack oxide coating is zinc, attacks and dissolves the iron of the molding equipment and produces an undesirable contamination of the molded articles. A similar case of other apparatus handling molten metal wherein ferrous metal parts are brought-into contactwith molten metal which tends to dissolve or corrode the parts.
The primary object of this invention is to prowherein a durable and emcient coating is provided to protect the parts against the action of molten metals which may come in contact therewith.
In accordance with this object, the invention 25 contemplates the provision of an apparatus wherein those parts which are subject to attack by the corrosive molten metals are provided with a protective coating consisting preferably of black iron oxide.
A clearer understanding of the invention will be had from the following description, taken in connection with the accompanying drawing, wherein the'single figure illustrates the invention as applied to the molten metal contacting parts 35 of die casting apparatus.
Referring now to the-drawing wherein reference numerals are used to designate the various parts, there is disclosed the charging end of a die casting apparatus in connection with which to be used. The reference numeral 5 designates the pot in which the casting alloy is melted for supplying the apparatus. A charging gun or gooseneck designated generally by the numeral 6 and comprising a. cover '7 which is clamped onto a lower molten metal containing portion 8, is pivotally:
supported by any suitable known actuating mechanism (not shown) for swinging the gooseneck down into the melting pot to receive a charge of molten metal, and then up into engagement with a stationary die plate 9 of the apparatus when the dies are to be charged. A stationary die 10 secured to the stationary plate 9 is engaged by a movable die 11' which. is mounted on a reciproeating plate 12 actuatedby suitable control apfor drogen liberated from 5 which is also usually constructed of cast iron or other ferrous metal.
The invention contemplates the coating of these ferrous metal parts oxide of iron, preferably formed bythe process set forth in Patent 1,690,378 issued November 6,
1928 to Franklin B. Rinck. As disclosed in the Rinck patent, the parts to be coated are placed in an air-tight oven or muffle, brought to a temperature of approximately 1400" F., and subjected to the action of superheated steam which is gradually introduced into the furnace, a small quantity of hydrocarbon oil being placed in a container in the muiile with the iron parts to 0 absorb the excess oxygen which may later be present. As the treating process progresses, the amount of steam admitted is gradually increased, and the oxygen thereof combines chemically with the ferrous metal parts to form a black oxide 5 coating over all of their exposed surfaces.
After the superheated steam is admitted for twenty minutes at maximum pressure, the hythe steam is driven out of the furnace by opening the door burn. An additional'quantity of hydrocarbon oil is then placed in the mufile of the furnace and the door immediately closed. The temperature is then raised to about 1420 F., the normal op-.-
'erating temperature of the furnace, and the superheated steam continues to oxidize the parts, until finally after an exposure of forty minutes at this temperature the parts will-have an adherent coating of the black oxide produced on all their surfaces both exterior and interior, as designated by the numerals 15, 16 and 1'7, referring to the melting pot, the gooseneck and the nozzle, respectively. If a smooth protective oxide coating is desired on the parts, they are heated for.
a. considerable time at the higher temperature mentioned, whereas if a more crystalline coating is to be produced, a temperature of about -1400 F. is maintained for the greater length of the process. In either case,
5, 8, and 13, with black 7o to permit it to 90 the treatment produces an adherent coating which protects the parts against the solvent and corrosive effect of p the molten metals which come in contact therewith, thereby preventing the undesirable contamination of the molten metals and the parts die-cast therefrom with the dissolved iron.
Although the invention has been specifically disclosed in connection with the provision of a protective coating on the parts of a die casting apparatus, it will be understood that the inven tion may also be applied to other apparatus for handling molten'metal, wherever it is desired to protect a ferrous metal element from attack by molten metals or alloys. A particularly useful application of the method may be made in connection with the galvanizing of sheet metal. There the ferrous metal container of the molten galvanizing material is also subject to corrosion the same as the die casting apparatus above described, and an oxide coating provided on the container in accordance with this invention prevents undesirable contamination of the molten galvanizing material. with corroded portions of the container. In fact, this oxide coating may be provided on a great variety of ferrous containers or members used for handling various moltenmetals because it remains inert for temperatures below 1700 F. and does not become wetted by the molten metal.
It will be understood that the invention may be applied not only to the specific apparatus here disclosed, but is limited only by the scope of the appended claims.
What is claimed is:
1. A ferrous metal member having a surface designed to contact with molten metal, said surface being provided with a protective crystalline coating of black iron oxide to prevent contamination of the molten metal with the ferrous metal.
2. A ferrous metal member having a surface designed to contact with molten metal, said surface being provided with a coating of black iron oxide.
3. Die casting equipment having ferrous metal parts which contact the molten metal, said parts being provided with a black iron oxide coating to prevent contamination of the molten metal with the ferrous metal. i
HERBERT M. E. HEINICKE.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1965340A true US1965340A (en) | 1934-07-03 |
Family
ID=3426408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US1965340D Expired - Lifetime US1965340A (en) | Apparatus for handling molten |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1965340A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2592337A (en) * | 1949-07-23 | 1952-04-08 | Non Ferrous Die Casting Compan | Method of chill casting brass and other copper alloys containing zinc |
| US2724159A (en) * | 1951-04-06 | 1955-11-22 | Louis H Morin | Gooseneck construction of die casting machine |
| US2977649A (en) * | 1959-03-16 | 1961-04-04 | Glen R Morton | Molten metal feeding tube for metal casting machines |
| US3078528A (en) * | 1959-07-20 | 1963-02-26 | Perfect Equip Corp | Die casting machine |
| US3085035A (en) * | 1960-06-20 | 1963-04-09 | Gen Motors Corp | Composition and method for cleaning and blackening metal dies |
| US3193888A (en) * | 1961-08-29 | 1965-07-13 | Aluminium Lab Ltd | Continuous casting apparatus including endless steel belt with red iron oxide coating |
| US3421307A (en) * | 1964-12-24 | 1969-01-14 | Dana Corp | Bearing member having a composite coating |
| DE102024121344A1 (en) * | 2024-05-29 | 2025-12-04 | GM Global Technology Operations LLC | SPREADER FOR DIE CASTING AND METHOD FOR THEIR MANUFACTURE |
-
0
- US US1965340D patent/US1965340A/en not_active Expired - Lifetime
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2592337A (en) * | 1949-07-23 | 1952-04-08 | Non Ferrous Die Casting Compan | Method of chill casting brass and other copper alloys containing zinc |
| US2724159A (en) * | 1951-04-06 | 1955-11-22 | Louis H Morin | Gooseneck construction of die casting machine |
| US2977649A (en) * | 1959-03-16 | 1961-04-04 | Glen R Morton | Molten metal feeding tube for metal casting machines |
| US3078528A (en) * | 1959-07-20 | 1963-02-26 | Perfect Equip Corp | Die casting machine |
| US3085035A (en) * | 1960-06-20 | 1963-04-09 | Gen Motors Corp | Composition and method for cleaning and blackening metal dies |
| US3193888A (en) * | 1961-08-29 | 1965-07-13 | Aluminium Lab Ltd | Continuous casting apparatus including endless steel belt with red iron oxide coating |
| US3421307A (en) * | 1964-12-24 | 1969-01-14 | Dana Corp | Bearing member having a composite coating |
| DE102024121344A1 (en) * | 2024-05-29 | 2025-12-04 | GM Global Technology Operations LLC | SPREADER FOR DIE CASTING AND METHOD FOR THEIR MANUFACTURE |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US1965340A (en) | Apparatus for handling molten | |
| CN104275230B (en) | A kind of resistance to abrading-ball of high hardness spray coating | |
| US4140821A (en) | Process for preheating and preparing ferrous metal for galvanizing | |
| US3085028A (en) | Method and means for depositing silicon | |
| CN103266291B (en) | A kind of hot dip aluminum plating Mn series alloy layer method | |
| US1995349A (en) | Apparatus provided with a protective coating for handling molten metal | |
| US928385A (en) | Apparatus for coating metals. | |
| CA1158866A (en) | Separation of aluminum from articles composed of aluminum bonded to ferrous metal | |
| US1080059A (en) | Process for producing clean or deoxidized metal surfaces. | |
| KR101748975B1 (en) | Thermal treatment process of a steel sheet and device for its implementation | |
| US1476192A (en) | Method of casting light metal alloys | |
| US943161A (en) | Method of protecting molten metals. | |
| KR20040042830A (en) | Method and apparatus for change-over of the molten metal coating composition in a steel strip coating line | |
| CN114525468A (en) | Surface treatment process of carbon steel crucible | |
| US1501887A (en) | Protected metal and process of making it | |
| US943639A (en) | Method of protecting molten metals. | |
| US2159261A (en) | Method of removing a phosphate coating from a surface | |
| KR102885792B1 (en) | The alloy hot dip galvanizing method of steel structures with excellent surface quality and corrosion resistance | |
| US1951945A (en) | Method of treating metal parts to prevent adhesion of molten metal and composition of matter employed therein | |
| US1591983A (en) | Process of coating iron or steel articles | |
| US3018190A (en) | Method and apparatus for treating metallic strands in hot dip coating | |
| US1740639A (en) | Coating and heat treating | |
| US2847321A (en) | Metal surface treatment | |
| US2452996A (en) | Process for refining copper and its alloys | |
| GB1246498A (en) | Heat treatment of alloy coated articles |