[go: up one dir, main page]

US1965340A - Apparatus for handling molten - Google Patents

Apparatus for handling molten Download PDF

Info

Publication number
US1965340A
US1965340A US1965340DA US1965340A US 1965340 A US1965340 A US 1965340A US 1965340D A US1965340D A US 1965340DA US 1965340 A US1965340 A US 1965340A
Authority
US
United States
Prior art keywords
parts
molten metal
molten
coating
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Publication date
Application granted granted Critical
Publication of US1965340A publication Critical patent/US1965340A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08Orthophosphates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/011Layered products comprising a layer of metal all layers being exclusively metallic all layers being formed of iron alloys or steels

Definitions

  • the primary object of this invention is to prowherein a durable and emcient coating is provided to protect the parts against the action of molten metals which may come in contact therewith.
  • the invention 25 contemplates the provision of an apparatus wherein those parts which are subject to attack by the corrosive molten metals are provided with a protective coating consisting preferably of black iron oxide.
  • any suitable known actuating mechanism for swinging the gooseneck down into the melting pot to receive a charge of molten metal, and then up into engagement with a stationary die plate 9 of the apparatus when the dies are to be charged.
  • a stationary die 10 secured to the stationary plate 9 is engaged by a movable die 11' which. is mounted on a reciproeating plate 12 actuatedby suitable control apfor drogen liberated from 5 which is also usually constructed of cast iron or other ferrous metal.
  • the invention contemplates the coating of these ferrous metal parts oxide of iron, preferably formed bythe process set forth in Patent 1,690,378 issued November 6,
  • the parts to be coated are placed in an air-tight oven or muffle, brought to a temperature of approximately 1400" F., and subjected to the action of superheated steam which is gradually introduced into the furnace, a small quantity of hydrocarbon oil being placed in a container in the muumble with the iron parts to 0 absorb the excess oxygen which may later be present.
  • the amount of steam admitted is gradually increased, and the oxygen thereof combines chemically with the ferrous metal parts to form a black oxide 5 coating over all of their exposed surfaces.
  • the hythe steam is driven out of the furnace by opening the door burn.
  • An additional'quantity of hydrocarbon oil is then placed in the mufile of the furnace and the door immediately closed.
  • the temperature is then raised to about 1420 F., the normal op-.-
  • the parts will-have an adherent coating of the black oxide produced on all their surfaces both exterior and interior, as designated by the numerals 15, 16 and 1'7, referring to the melting pot, the gooseneck and the nozzle, respectively. If a smooth protective oxide coating is desired on the parts, they are heated for.
  • the inven tion may also be applied to other apparatus for handling molten'metal, wherever it is desired to protect a ferrous metal element from attack by molten metals or alloys.
  • a particularly useful application of the method may be made in connection with the galvanizing of sheet metal.
  • the ferrous metal container of the molten galvanizing material is also subject to corrosion the same as the die casting apparatus above described, and an oxide coating provided on the container in accordance with this invention prevents undesirable contamination of the molten galvanizing material. with corroded portions of the container.
  • this oxide coating may be provided on a great variety of ferrous containers or members used for handling various moltenmetals because it remains inert for temperatures below 1700 F. and does not become wetted by the molten metal.
  • a ferrous metal member having a surface designed to contact with molten metal, said surface being provided with a protective crystalline coating of black iron oxide to prevent contamination of the molten metal with the ferrous metal.
  • a ferrous metal member having a surface designed to contact with molten metal, said surface being provided with a coating of black iron oxide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Description

July'3, 1934. l H. M. HEINICKEI 1,965,340
' APPARATUS. FOR HANDLING MOLTEN METAL Filed Dec. 19, 1930 Patented July 3, 1934 9 UNlTED STATES PATENT OFF-ice 1,965,340 APPARATUS FOR HANDLING MOLTEN METAL Herbert E. Heinicke, Elgin, 111., assignor to Western Electric Company,
Incorporated, New
York, N. 71., a corporation of New York 10 molten metal used in die casting, which may Application December 19, 1930, Serial No. 503,373
3 Claims. (Cl. 2269) paratus (not shown). A nozzle 13 is secured to the discharging end of the gooseneck for conveying the molten metal therefrom through a water cooled bushing 14 and into the dies 10 and l1. During the charging operation, the lower part 8 60 of the goos'eneck and the nozzle 13 are, of course, brought into contact with the molten metal, and as these parts are usually constructed of cast iron, the molten casting alloy attacks them and dissolves or corrodes their exposed surfaces, as 5 well as dissolving or corroding the melting pot This invention relates to apparatus for'handling molten metal, and more particularly to apparatus wherein certain parts are provided with a coating to protect them fromthe action of the 5 molten metal. I
In the casting of metals, it is desirable to provide means whereby the casting apparatus may be protected against the erosive attack of the molten metal which is to be cast. The
be an alloy composed essentially of aluminum or ls problem exists in the vide an improved apparatus theblack oxide coating is zinc, attacks and dissolves the iron of the molding equipment and produces an undesirable contamination of the molded articles. A similar case of other apparatus handling molten metal wherein ferrous metal parts are brought-into contactwith molten metal which tends to dissolve or corrode the parts.
The primary object of this invention is to prowherein a durable and emcient coating is provided to protect the parts against the action of molten metals which may come in contact therewith.
In accordance with this object, the invention 25 contemplates the provision of an apparatus wherein those parts which are subject to attack by the corrosive molten metals are provided with a protective coating consisting preferably of black iron oxide.
A clearer understanding of the invention will be had from the following description, taken in connection with the accompanying drawing, wherein the'single figure illustrates the invention as applied to the molten metal contacting parts 35 of die casting apparatus.
Referring now to the-drawing wherein reference numerals are used to designate the various parts, there is disclosed the charging end of a die casting apparatus in connection with which to be used. The reference numeral 5 designates the pot in which the casting alloy is melted for supplying the apparatus. A charging gun or gooseneck designated generally by the numeral 6 and comprising a. cover '7 which is clamped onto a lower molten metal containing portion 8, is pivotally:
supported by any suitable known actuating mechanism (not shown) for swinging the gooseneck down into the melting pot to receive a charge of molten metal, and then up into engagement with a stationary die plate 9 of the apparatus when the dies are to be charged. A stationary die 10 secured to the stationary plate 9 is engaged by a movable die 11' which. is mounted on a reciproeating plate 12 actuatedby suitable control apfor drogen liberated from 5 which is also usually constructed of cast iron or other ferrous metal.
The invention contemplates the coating of these ferrous metal parts oxide of iron, preferably formed bythe process set forth in Patent 1,690,378 issued November 6,
1928 to Franklin B. Rinck. As disclosed in the Rinck patent, the parts to be coated are placed in an air-tight oven or muffle, brought to a temperature of approximately 1400" F., and subjected to the action of superheated steam which is gradually introduced into the furnace, a small quantity of hydrocarbon oil being placed in a container in the muiile with the iron parts to 0 absorb the excess oxygen which may later be present. As the treating process progresses, the amount of steam admitted is gradually increased, and the oxygen thereof combines chemically with the ferrous metal parts to form a black oxide 5 coating over all of their exposed surfaces.
After the superheated steam is admitted for twenty minutes at maximum pressure, the hythe steam is driven out of the furnace by opening the door burn. An additional'quantity of hydrocarbon oil is then placed in the mufile of the furnace and the door immediately closed. The temperature is then raised to about 1420 F., the normal op-.-
'erating temperature of the furnace, and the superheated steam continues to oxidize the parts, until finally after an exposure of forty minutes at this temperature the parts will-have an adherent coating of the black oxide produced on all their surfaces both exterior and interior, as designated by the numerals 15, 16 and 1'7, referring to the melting pot, the gooseneck and the nozzle, respectively. If a smooth protective oxide coating is desired on the parts, they are heated for.
a. considerable time at the higher temperature mentioned, whereas if a more crystalline coating is to be produced, a temperature of about -1400 F. is maintained for the greater length of the process. In either case,
5, 8, and 13, with black 7o to permit it to 90 the treatment produces an adherent coating which protects the parts against the solvent and corrosive effect of p the molten metals which come in contact therewith, thereby preventing the undesirable contamination of the molten metals and the parts die-cast therefrom with the dissolved iron.
Although the invention has been specifically disclosed in connection with the provision of a protective coating on the parts of a die casting apparatus, it will be understood that the inven tion may also be applied to other apparatus for handling molten'metal, wherever it is desired to protect a ferrous metal element from attack by molten metals or alloys. A particularly useful application of the method may be made in connection with the galvanizing of sheet metal. There the ferrous metal container of the molten galvanizing material is also subject to corrosion the same as the die casting apparatus above described, and an oxide coating provided on the container in accordance with this invention prevents undesirable contamination of the molten galvanizing material. with corroded portions of the container. In fact, this oxide coating may be provided on a great variety of ferrous containers or members used for handling various moltenmetals because it remains inert for temperatures below 1700 F. and does not become wetted by the molten metal.
It will be understood that the invention may be applied not only to the specific apparatus here disclosed, but is limited only by the scope of the appended claims.
What is claimed is:
1. A ferrous metal member having a surface designed to contact with molten metal, said surface being provided with a protective crystalline coating of black iron oxide to prevent contamination of the molten metal with the ferrous metal.
2. A ferrous metal member having a surface designed to contact with molten metal, said surface being provided with a coating of black iron oxide.
3. Die casting equipment having ferrous metal parts which contact the molten metal, said parts being provided with a black iron oxide coating to prevent contamination of the molten metal with the ferrous metal. i
HERBERT M. E. HEINICKE.
US1965340D Apparatus for handling molten Expired - Lifetime US1965340A (en)

Publications (1)

Publication Number Publication Date
US1965340A true US1965340A (en) 1934-07-03

Family

ID=3426408

Family Applications (1)

Application Number Title Priority Date Filing Date
US1965340D Expired - Lifetime US1965340A (en) Apparatus for handling molten

Country Status (1)

Country Link
US (1) US1965340A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2592337A (en) * 1949-07-23 1952-04-08 Non Ferrous Die Casting Compan Method of chill casting brass and other copper alloys containing zinc
US2724159A (en) * 1951-04-06 1955-11-22 Louis H Morin Gooseneck construction of die casting machine
US2977649A (en) * 1959-03-16 1961-04-04 Glen R Morton Molten metal feeding tube for metal casting machines
US3078528A (en) * 1959-07-20 1963-02-26 Perfect Equip Corp Die casting machine
US3085035A (en) * 1960-06-20 1963-04-09 Gen Motors Corp Composition and method for cleaning and blackening metal dies
US3193888A (en) * 1961-08-29 1965-07-13 Aluminium Lab Ltd Continuous casting apparatus including endless steel belt with red iron oxide coating
US3421307A (en) * 1964-12-24 1969-01-14 Dana Corp Bearing member having a composite coating
DE102024121344A1 (en) * 2024-05-29 2025-12-04 GM Global Technology Operations LLC SPREADER FOR DIE CASTING AND METHOD FOR THEIR MANUFACTURE

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2592337A (en) * 1949-07-23 1952-04-08 Non Ferrous Die Casting Compan Method of chill casting brass and other copper alloys containing zinc
US2724159A (en) * 1951-04-06 1955-11-22 Louis H Morin Gooseneck construction of die casting machine
US2977649A (en) * 1959-03-16 1961-04-04 Glen R Morton Molten metal feeding tube for metal casting machines
US3078528A (en) * 1959-07-20 1963-02-26 Perfect Equip Corp Die casting machine
US3085035A (en) * 1960-06-20 1963-04-09 Gen Motors Corp Composition and method for cleaning and blackening metal dies
US3193888A (en) * 1961-08-29 1965-07-13 Aluminium Lab Ltd Continuous casting apparatus including endless steel belt with red iron oxide coating
US3421307A (en) * 1964-12-24 1969-01-14 Dana Corp Bearing member having a composite coating
DE102024121344A1 (en) * 2024-05-29 2025-12-04 GM Global Technology Operations LLC SPREADER FOR DIE CASTING AND METHOD FOR THEIR MANUFACTURE

Similar Documents

Publication Publication Date Title
US1965340A (en) Apparatus for handling molten
CN104275230B (en) A kind of resistance to abrading-ball of high hardness spray coating
US4140821A (en) Process for preheating and preparing ferrous metal for galvanizing
US3085028A (en) Method and means for depositing silicon
CN103266291B (en) A kind of hot dip aluminum plating Mn series alloy layer method
US1995349A (en) Apparatus provided with a protective coating for handling molten metal
US928385A (en) Apparatus for coating metals.
CA1158866A (en) Separation of aluminum from articles composed of aluminum bonded to ferrous metal
US1080059A (en) Process for producing clean or deoxidized metal surfaces.
KR101748975B1 (en) Thermal treatment process of a steel sheet and device for its implementation
US1476192A (en) Method of casting light metal alloys
US943161A (en) Method of protecting molten metals.
KR20040042830A (en) Method and apparatus for change-over of the molten metal coating composition in a steel strip coating line
CN114525468A (en) Surface treatment process of carbon steel crucible
US1501887A (en) Protected metal and process of making it
US943639A (en) Method of protecting molten metals.
US2159261A (en) Method of removing a phosphate coating from a surface
KR102885792B1 (en) The alloy hot dip galvanizing method of steel structures with excellent surface quality and corrosion resistance
US1951945A (en) Method of treating metal parts to prevent adhesion of molten metal and composition of matter employed therein
US1591983A (en) Process of coating iron or steel articles
US3018190A (en) Method and apparatus for treating metallic strands in hot dip coating
US1740639A (en) Coating and heat treating
US2847321A (en) Metal surface treatment
US2452996A (en) Process for refining copper and its alloys
GB1246498A (en) Heat treatment of alloy coated articles