US1945A - Improvement in the process of manufacturing sulphate of alumina - Google Patents

Description

UNITED STATES PATENT OFFICE.

MAX J OSEPH FUNOKE, OF EIKELSKAMP, PRUSSIA, ASSIGNOR TO RUDOLPH BONINGER AND GUSTAVA BONINGER.

IMPROVl-IMENT IN THE PROCESS OF MANUFACTURING SULPHATE 0F ALUMINA.

Specification forming part of Letters Patent No. 1,945, dated January 93, 1841; antedated November To all whom it may concern:

Be itknown that I, MAX JOSEPH FUNOKE, a subject of the King of Prussia, residing at Eikelskamp, in the circuit of the government to Dusseldorf, in the said Kingdom, have invented an Improvement in the Manner or Process of Manufacturing Sulphate of Alumina, so as to produce the same free, or very nearly free, from iron and from alkali, whereby it is more perfectly adapted to he used as a mordant or for other purposes in the useful arts than the alum of commerce, or than the suiphate of alumina as ordinarily prepared; and I do hereby declare that the tollowingis a full and exact description thereof.

I take potteis clay, pipe-clay, or clay ofany other kind as free from iron as it can possibly be obtained, and this I dry at such degree of heat as is necessary to drive oft all its free moisture. The clay so calcined is next to be reduced to powder, and this powder I pntinto suitable leaden-vessels or vessels of other umterial not acted upon by sulphuric acid. To these vessels a moderate degree of heat. is to be applied by means of steam or otherwise. Sulphuric acid of 66 Baum is then to he added to the clay in such quantity as shall suffice to dissolve nearly the whole of the alumina contained in the clay which may be ascertained by a previous test on a small quantity. An excess of acid should not be used, as the whole ought to be pertectly neutralized by the alumina. After the addition of the acid the mass in the-pans is to be stirred until itis perfectly dry. Boiling water is then to be added in sufiicient quantity to dissolve the whole of the salt. The liquid thus obtained is to be placed in vats and to remain at rest until it becomes perfectly clear. It should then be tested by means oflime-water, to be certain that it does not contain any free acid, and should any be present lime-water is to be added until the whole excess of acid has combined with the lime and has been precipitated in the form of sulphate of lime. When perfectly clear the liquor is to be drawn off into other vats preparatory to the separating from it the iron, which will always be found combined with it in a greater or less quantity. A measured portion of this liquid-=say 0nepint--is then to be taken and the iron contained in it is to be precipitated by means of a solution of prussia-te of potash in such manner as to ascertain the exact quantity of said solution necesl sary to the precipitation of the contained iron The quantity of liquid contained in the vat being known, the portion of the solution of prussiate of potash necessary to the precipitation of the whole of the iron will consequently be known and this is to be added to it, the mixture stirred, and the prussiate of iron formed allowed to fall to the bottom. The liquid is then to be drawn of clear from the precipitate and a pure, or nearly pure, solution of sulphate of alumina will be thus obtained, and it may in this state be applied to various purposes in the arts.

It desired, the water may be quickly evaporated in leaden or other vess ls. until apellicle appears on its surface, when it may be putinto suitable forms and allowed to cool and crystallize or consolidate.

1 am aware that cltty has been heretofore treated with sulphuric acid to form a sulphate of alumina; and [am also aware that it is known to every chemist that iron may be precipitated from its solution in sulphuric or other acid by means of prnssiate of potash. I do not the efore make any c aim to the discovery of either of these processes when taken alone; but

I do claim- The combination of means herein pointed out tor the manutactnring of sulphate ofalumina, by which it is produced with greater facility, and in a state of greater purity than by any of the processes heretofore adopted in its manufacture-that is to say, I claim, in

combination, the preparing of the clay by des iccation, the combining thereof with sulphuric acid, and the subsequent solution and precipi tation ofthe iron, substantially in the manner and for the purpose herein fully made known. I will here ohservethat although I have pointed out a solution of the prussiate of potash as the article by which the iron is topre cipitate, I have done so-becauseI esteem this as the best mode of attaining the end desired; but I do notint'end hereby to limit or confine myself to the use of this salt, but to use any other of theknown reagents by which a similar result may be attained, and a sulphate of alumina free, or nearly free, from alkali and from iron be produced.

MAX JOSEPH FUNOKE.

Witnesses: i

M. E. MATTHES, FRIEDRICH GARTRIOH.