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US1883635A - Mercury boiler - Google Patents

Mercury boiler Download PDF

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Publication number
US1883635A
US1883635A US363872A US36387229A US1883635A US 1883635 A US1883635 A US 1883635A US 363872 A US363872 A US 363872A US 36387229 A US36387229 A US 36387229A US 1883635 A US1883635 A US 1883635A
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United States
Prior art keywords
mercury
gases
boiler
receptacle
outlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US363872A
Inventor
George D Ebbets
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Babcock and Wilcox Co
Original Assignee
Babcock and Wilcox Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Babcock and Wilcox Co filed Critical Babcock and Wilcox Co
Priority to US363872A priority Critical patent/US1883635A/en
Application granted granted Critical
Publication of US1883635A publication Critical patent/US1883635A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B3/00Other methods of steam generation; Steam boilers not provided for in other groups of this subclass
    • F22B3/02Other methods of steam generation; Steam boilers not provided for in other groups of this subclass involving the use of working media other than water

Definitions

  • This invention relates to a mercury boiler so arranged that the mercury vapors can be recovered in case of rupture of a mercury Vapor generating element.
  • Fig. 1 is a vertical section through anillustrative embodi- 'ment of the invention
  • Fig. 2 is a vertical section on an enlarged scale, showing some of the details
  • Fig. 3 is a side View of amodification of some of the parts
  • Fig. 4 is a section at right angles to Fig. 3.
  • reference character 1 inv dicates the walls of the furnace in the upper portion of which a mercury boiler is located having mercury vapor generating tubes 2 depending from headers 3 in the well known way.
  • Feed ipes 4 for mercury are provided leading to t e upper portions of the drums 3 and mercury vapor pipes 5 extend from the upper portions of the drums 3 to a header 6 from which tubes 7 lead to a header 8'that may be connected to the place where the mercury vapors are used.
  • An economizer 9 of a well known sort may be located in the flue 10 through which the waste gases from the furnace pass down wardly.
  • An air heater 11 is also located in the flue 10, preferably below the economizer 9.
  • a receptacle 13 through which the waste gases pass is provided below the air heater 11.
  • a series of perforated pipes 14 extend across the upper portion of the receptacle 13 for spraying water into the receptacle 13,
  • water outlet pipe 15 extends from a point along the sloping bottom of the receptacle some distance above its lowermost point.
  • sump 16 is provided at the lowest point of the sloping bottom of the receptacle 13 and a U-shaped outlet 17 leads from the sump 16 to a container 18 at the lower portion of which an outlet pipe 19 is provided.
  • the spray may be operated manually when a rupture occurs or it may be made to operate automatically when a changed condition occurs in the boiler due to rupture, such as a decrease in the pressure in the boiler or an increase in the temperature of the escaping furnace gases.
  • the mixture of water and mercury collects in the lower portion of the receptacle 13, the mercury gravitating to the bottom. lVhen the mercury accumulates sulficiently to fill the tube 17 with a slight excess, the excess mercury passes into the container 18 and out through the pipe 19'. The excess water escapes through the pipe 15 as soon as the water level reaches this point.
  • the mercury in the tube 17 prevents water from passingout through this tube.
  • the legs of the U-tube are sulficiently long to enable enough water to accumulate in the receptacle 13 to overflow through the pipe 15, without forcing the level of the mercury to the lower'end ofthe leg that is attached to the sump 16.
  • the economizer 9 may be used'for heating water that passes through it or it may be used for preheating the mercury before it is introduced into the drums 3 during the normal operation of the boiler.
  • the air heater 11 may heat combustion air for the boiler furnace.
  • a modification is shown in which the mercury and water are separated after the mercury has been condensed by the water spray, and the mercury is withdrawn automatically from the receptacle after a predetermined amount thereof has accumulated.
  • the bottom portion of the receptacle 13 is made separate from the remainder of the receptacle and is movable in a vertical direction.
  • a liquid seal 21 is provided between the upper edge 22 of the portion 20 and the lower edge 23 of the receptacle 13.
  • Supports 24 are provided near the lower portion of the receptacle 13 and supporting rods 25 for the lower portion 20 are supported upon springs 26 upon the supports 24.
  • the rods 25 are attached to brackets 27 upon the movable portion 20.
  • a valve seat 28 is provided in the lower end of the conical bottom of the portion 20 and a fixed valve 29 is provided for the valve seat 28.
  • the stem 30 of the valve 29 is screwed into a threaded lug in the fixed out- 1 let pipe 31-and an expansible tube connection 32 is provided between the valve seat 28 and the upper end of the pipe 31.
  • the pipe 31 may be supported in a fixed position by means of the support 33.
  • valve 29 is kept closed normally by the springs 26 holding the bottom 20 in its uppermost position with the seat 28 and valve 29 in contact.
  • the springs are so adjusted that the weight of a suflicient amount of water accumulated in the portion 20 to overflow through the outlet 15 will not compress the springs 26 sufficiently to move the portion 20 downwardly. If, however, a portion of the liquid in the bottom 20 filling the same to the overflow pipe 15 is mercury, the weight will be suflicient to open the valve 29 and permit the mercury to escape.
  • the springs 26 raise the bottom with its decreased weight of liquid sufficiently to close the valve 29 before the water begins to escape. The mercury and water are thereby automatically separated from each other. The mercury that would otherwise be wasted is recovered.
  • a soot blower 34 shown somewhat diagrammatically in Fig. 1 may be provided in the receptacle 13 to remove soot that may collect during the normal operation vof the boiler.
  • a mercury boiler a flue for spent gases leaving said boiler and means in said flue for recovering mercury from said gases that may escape from said boiler into said gases, said means comprising a cold water spray, and over-flow means actuated by a predetermined bulk of mercury within said recovering means.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Description

Oct. 18, 1932. 3, 55551-5 1,883,635
MERCURY BOILER Filed May 17, 1929 2 Sheets-Sheet 1 Fig! INVENTOR 6 M w fflbRNEg' G. D. EBBETS MERCURY BOILER Oct. 18, 1932.
2 Sheets-Sheet 2 Filed May 17. 1929 w wk m hm Patented a. 18, 1932 UNITED STATES,
PATENT OFFICE GEORGE D. EBIBETS, OF KENILWOBTH, NEWJERSEY, ASSIGNOR TO THE BABCO GK & WILCOX COMPANY, OF BAYONNE, NEW JERSEY, A CORPORATION OF NEW JERSEY IERC RY BOILER Application filed Kay 17, 1929. Serial No. 863,872.
This invention relates to a mercury boiler so arranged that the mercury vapors can be recovered in case of rupture of a mercury Vapor generating element.
The invention will be understood from the description in connection with the accompanying drawings in which Fig. 1 is a vertical section through anillustrative embodi- 'ment of the invention; Fig. 2 is a vertical section on an enlarged scale, showing some of the details; Fig. 3 is a side View of amodification of some of the parts; and Fig. 4 is a section at right angles to Fig. 3.
In the drawings reference character 1 inv dicates the walls of the furnace in the upper portion of which a mercury boiler is located having mercury vapor generating tubes 2 depending from headers 3 in the well known way. Feed ipes 4 for mercury are provided leading to t e upper portions of the drums 3 and mercury vapor pipes 5 extend from the upper portions of the drums 3 to a header 6 from which tubes 7 lead to a header 8'that may be connected to the place where the mercury vapors are used.
An economizer 9 of a well known sort may be located in the flue 10 through which the waste gases from the furnace pass down wardly. An air heater 11 is also located in the flue 10, preferably below the economizer 9. A receptacle 13 through which the waste gases pass is provided below the air heater 11. A series of perforated pipes 14 extend across the upper portion of the receptacle 13 for spraying water into the receptacle 13,
which is provided with a sloping. bottom. A
water outlet pipe 15 extends from a point along the sloping bottom of the receptacle some distance above its lowermost point. A
sump 16 is provided at the lowest point of the sloping bottom of the receptacle 13 and a U-shaped outlet 17 leads from the sump 16 to a container 18 at the lower portion of which an outlet pipe 19 is provided. The
' outlet end of the U-shaped pipe 17 extends upwardly into the container 18 to a level approximately the same as the bottom of. the sump 16. The pipe 17 serves as a trap for mercury.
Heretofore when mercury boilers have become ruptured the mercury vapors became out through the stack and lost. By the present invention the mercury, which would otherwise be lost in this way, is recovered. The hot gases carrying the mercury vapors, which accidentally escape. into these gases, are cooled by passing across the tubes of the economizer 9 and are further cooled by passmg through the air heater 11. l/Vhen a rup ture occurs to cause mercury vapors to'es cape into 'the hot gases, the pipe leading to the perforated pipes 14 is opened to cause sprays to be projected downwardly into the gases passing through the receptacle 13, thus further cooling the gases and condensing the mercury vapors and removing the mercury from the gases. The spray may be operated manually when a rupture occurs or it may be made to operate automatically when a changed condition occurs in the boiler due to rupture, such as a decrease in the pressure in the boiler or an increase in the temperature of the escaping furnace gases. The mixture of water and mercury collects in the lower portion of the receptacle 13, the mercury gravitating to the bottom. lVhen the mercury accumulates sulficiently to fill the tube 17 with a slight excess, the excess mercury passes into the container 18 and out through the pipe 19'. The excess water escapes through the pipe 15 as soon as the water level reaches this point. The mercury in the tube 17 prevents water from passingout through this tube. The legs of the U-tube are sulficiently long to enable enough water to accumulate in the receptacle 13 to overflow through the pipe 15, without forcing the level of the mercury to the lower'end ofthe leg that is attached to the sump 16.
The economizer 9 may be used'for heating water that passes through it or it may be used for preheating the mercury before it is introduced into the drums 3 during the normal operation of the boiler. The air heater 11 may heat combustion air for the boiler furnace.
In Figs. 3 and 4 a modification is shown in which the mercury and water are separated after the mercury has been condensed by the water spray, and the mercury is withdrawn automatically from the receptacle after a predetermined amount thereof has accumulated. In this modification the bottom portion of the receptacle 13 is made separate from the remainder of the receptacle and is movable in a vertical direction. A liquid seal 21 is provided between the upper edge 22 of the portion 20 and the lower edge 23 of the receptacle 13. Supports 24 are provided near the lower portion of the receptacle 13 and supporting rods 25 for the lower portion 20 are supported upon springs 26 upon the supports 24. The rods 25 are attached to brackets 27 upon the movable portion 20.
A valve seat 28 is provided in the lower end of the conical bottom of the portion 20 and a fixed valve 29 is provided for the valve seat 28. The stem 30 of the valve 29 is screwed into a threaded lug in the fixed out- 1 let pipe 31-and an expansible tube connection 32 is provided between the valve seat 28 and the upper end of the pipe 31. The pipe 31 may be supported in a fixed position by means of the support 33.
In the modification shown in Figs. 3 and 4 the valve 29 is kept closed normally by the springs 26 holding the bottom 20 in its uppermost position with the seat 28 and valve 29 in contact. The springs are so adjusted that the weight of a suflicient amount of water accumulated in the portion 20 to overflow through the outlet 15 will not compress the springs 26 sufficiently to move the portion 20 downwardly. If, however, a portion of the liquid in the bottom 20 filling the same to the overflow pipe 15 is mercury, the weight will be suflicient to open the valve 29 and permit the mercury to escape. As soon as the mercury escapes the springs 26 raise the bottom with its decreased weight of liquid sufficiently to close the valve 29 before the water begins to escape. The mercury and water are thereby automatically separated from each other. The mercury that would otherwise be wasted is recovered.
A soot blower 34 shown somewhat diagrammatically in Fig. 1 may be provided in the receptacle 13 to remove soot that may collect during the normal operation vof the boiler.
I claim:
1. lln a mercury boiler, a flue for spent gases leaving said boiler and means in said flue for recovering mercury from said gases that may escape from said boiler into said gases, said means comprising a cold water spray, and over-flow means actuated by a predetermined bulk of mercury within said recovering means.
2. The combination in a mercury boiler of an outlet for the heating gases, a mercury condensing chamber associated with said outlet and through which said gases pass, means for cooling said gases in said chamber to condense mercury vapor mixed with said gases and to deposit liquid mercury in the bottom thereof, an outlet in the bottom of said chamber and means operated by the accumulation of mercury for delivering mercury only through said outlet.
3. The combination in a mercury boiler of an outlet for the heating gases, a mercury condensing chamber associated with said outlet and through which said gases pass, means for cooling said gases in said chamber to condense mercury vapor mixed with said gases and to deposit liquid mercury in the bottom thereof, an outlet in the bottom of said chamber and valve means operated by the accumulation of mercury for delivering mercury only through said outlet.
GEORGE D. EBBETS.
US363872A 1929-05-17 1929-05-17 Mercury boiler Expired - Lifetime US1883635A (en)

Priority Applications (1)

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US363872A US1883635A (en) 1929-05-17 1929-05-17 Mercury boiler

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4059438A (en) * 1973-12-13 1977-11-22 Hoechst Aktiengesellschaft Process for the work-up of a contaminated inactive mercury(II)chloride/active carbon-catalyst

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4059438A (en) * 1973-12-13 1977-11-22 Hoechst Aktiengesellschaft Process for the work-up of a contaminated inactive mercury(II)chloride/active carbon-catalyst

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