US1858631A - Process for producing alpha coating of chromium on objects of iron and steel or aluminum and particularly on knives, forks, and spoons - Google Patents
Process for producing alpha coating of chromium on objects of iron and steel or aluminum and particularly on knives, forks, and spoons Download PDFInfo
- Publication number
- US1858631A US1858631A US293314A US29331428A US1858631A US 1858631 A US1858631 A US 1858631A US 293314 A US293314 A US 293314A US 29331428 A US29331428 A US 29331428A US 1858631 A US1858631 A US 1858631A
- Authority
- US
- United States
- Prior art keywords
- chromium
- objects
- coating
- iron
- spoons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title description 18
- 238000000576 coating method Methods 0.000 title description 18
- 239000011248 coating agent Substances 0.000 title description 17
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title description 13
- 229910052804 chromium Inorganic materials 0.000 title description 13
- 239000011651 chromium Substances 0.000 title description 13
- 229910052742 iron Inorganic materials 0.000 title description 9
- 238000000034 method Methods 0.000 title description 9
- 229910000831 Steel Inorganic materials 0.000 title description 4
- 239000010959 steel Substances 0.000 title description 4
- 229910052782 aluminium Inorganic materials 0.000 title description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title description 3
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 239000010410 layer Substances 0.000 description 6
- 229910001369 Brass Inorganic materials 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000010951 brass Substances 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000003825 pressing Methods 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 2
- 239000010956 nickel silver Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000009996 mechanical pre-treatment Methods 0.000 description 1
- 239000005300 metallic glass Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
Definitions
- Such a pretreatment is commerciall possible for high grade metals, which are ree of pores and are smooth like brass, German silver and the like.
- this pretreatment is so diflicult' and expensive that the costs are prohibitive, so that it is preferable to use instead of iron more expenlsiilie metals like brass, German silver and the Further it must be considered that the iron during the mechanical treatment is subject, to fine pores or surface cracks which must be removed with a corres onding considerable Waste of material, grin ing means and work.
- the objects after the operations of forming or before one of the last operations of forming in a manner known per se are coated with one or more intermediate layers of other metals before depositing the coating of chromium.
- the invention in first line is distinguished by the feature that the inner coating layer for the objects,-which need not be polishedbefore, is applied in molten state, whereupon after applying the further intermediate metal layer the objects if desired without any further polishing step are provided With the chromium deposit galvanically, which deposit shows at once a shiny surface.
- the coating applied by melting in distinction from a galvanic coating fills out all.
- the surface is improved and if necessary or desirable a further improvement can be obtained by treating the objects in a rotating drum by the sheradizing process.
- the relatively thick and tenacious coating of tin applied by melting is particularly well adapted for being smoothed by pressing.
- the coatingv of brass can be applied galvanically.
- this sec- 0nd intermediate layer is heated at or after applying it.
- This second layer may be applied for example by spraying with the spraying gun or by, melting or by applying fine amorphous metal powders, which if necessary or desired can be alloyed byheating in a reducing atmosphere and are protected against oxidation in accordance with the nature of the metal.
- the chromium coating is deposited galvanically and has im mediately Claims a shiny surface.
- a method for covering with chromium forks and spoons or the like formed from iron comprising the steps of melting on the objects a coating of tin, arranging a coating of'brass thereon, and chromium-plating the articles so formed.
- a method for chromium-plating objects made from coarse-grain metals withthe use of a plurality of intermediate metal' layers between the chromium and the base, comprlsing the steps of covering the objects with a coating of melted tin, arranging a second coating of an electro-positive metal thereon, and thereafter applying a coating of chromium thereon.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Coating By Spraying Or Casting (AREA)
Description
Patented May 17, 1932 UNITED STATES PA TEN-T Torrlee HEINIBJCH LEISER, or BERLIN-ERIEDENAI'I, GERMANY PROCESS FOR PRODUCING A COATING 0F CHROMIIIM ON OBJECTS OF IRON AND STEEL I OR ALUMINUM AND PARTICULARLY 0N KNIVES, FORKS, AND SPOONS v No Drawing. Application filed July 16, 1928, Serial No. 293,314, and in Germany July 21, 1 927.
A process for producing a coating of chromium on objects of iron and steel or aluminum and particularly on knives, forks and spoons.
For obtaining a shiny coating of chromium it was necessary until now to subject the ob jects in question to be coated electrically namely galvanically with chromium to an expensive mechanical pretreatment by grinding and polishing.
Such a pretreatment is commerciall possible for high grade metals, which are ree of pores and are smooth like brass, German silver and the like. However in the case of iron this pretreatment is so diflicult' and expensive that the costs are prohibitive, so that it is preferable to use instead of iron more expenlsiilie metals like brass, German silver and the Further it must be considered that the iron during the mechanical treatment is subject, to fine pores or surface cracks which must be removed with a corres onding considerable Waste of material, grin ing means and work.
I For instance in manufacturing spoons even if a ground and polished slieet'metal has been used the spoons after the rolling and press ing, etc., show pores and cracks or fissures so that it is necessary to again grind and polish which operation is very expensive;
. However just from such pores, cracks and fissures corrosion starts.
It is the purpose of the present invention to propose a method for obtaining shiny chromium coatings of a highly polished appearance on iron and steel in a cheap and reliable manner.
Corresponding to this method the objects after the operations of forming or before one of the last operations of forming in a manner known per se are coated with one or more intermediate layers of other metals before depositing the coating of chromium.
The invention in first line is distinguished by the feature that the inner coating layer for the objects,-which need not be polishedbefore, is applied in molten state, whereupon after applying the further intermediate metal layer the objects if desired without any further polishing step are provided With the chromium deposit galvanically, which deposit shows at once a shiny surface. The coating applied by melting in distinction from a galvanic coating fills out all.
pores and fissures, has a uite better adhesion or adherence and is thic er.
With particular'advantage tin is used for the innermost coating layer upon the iron.
By a last pressing or other smoothing operation before or after applying the second 6 intermediate layer consisting of brass the surface is improved and if necessary or desirable a further improvement can be obtained by treating the objects in a rotating drum by the sheradizing process. The relatively thick and tenacious coating of tin applied by melting is particularly well adapted for being smoothed by pressing.
The coatingv of brass can be applied galvanically. Preferably however also this sec- 0nd intermediate layer is heated at or after applying it. This second layer may be applied for example by spraying with the spraying gun or by, melting or by applying fine amorphous metal powders, which if necessary or desired can be alloyed byheating in a reducing atmosphere and are protected against oxidation in accordance with the nature of the metal.
After such treatment the chromium coating is deposited galvanically and has im mediately Claims a shiny surface.
1. A method for. covering with chromium objects formed from coarse-grained metals, as
comprising the steps of covering the objects with a coating of melted tin, arranging a second coating of an electro-positive metal thereon, and thereafter applying a coating of chromium thereon.
2. A method for covering with chromium forks and spoons or the like formed from iron, comprising the steps of melting on the objects a coating of tin, arranging a coating of'brass thereon, and chromium-plating the articles so formed.
3. A method for chromium-plating objects made from coarse-grain metals, withthe use of a plurality of intermediate metal' layers between the chromium and the base, comprlsing the steps of covering the objects with a coating of melted tin, arranging a second coating of an electro-positive metal thereon, and thereafter applying a coating of chromium thereon.
In testimony whereof I afiix m signature.
DR. HEINRICH EISER.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1858631X | 1927-07-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1858631A true US1858631A (en) | 1932-05-17 |
Family
ID=7746362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US293314A Expired - Lifetime US1858631A (en) | 1927-07-21 | 1928-07-16 | Process for producing alpha coating of chromium on objects of iron and steel or aluminum and particularly on knives, forks, and spoons |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1858631A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3070279A (en) * | 1959-04-21 | 1962-12-25 | Wilton J Lutwack | Portfolio made of paper |
-
1928
- 1928-07-16 US US293314A patent/US1858631A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3070279A (en) * | 1959-04-21 | 1962-12-25 | Wilton J Lutwack | Portfolio made of paper |
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