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US1857163A - Method of treating fabrics and product thereof - Google Patents

Method of treating fabrics and product thereof Download PDF

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Publication number
US1857163A
US1857163A US36310929A US1857163A US 1857163 A US1857163 A US 1857163A US 36310929 A US36310929 A US 36310929A US 1857163 A US1857163 A US 1857163A
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US
United States
Prior art keywords
fabric
cellulose
scroop
treating
improving
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Inventor
Platt Herbert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Priority to US36310929 priority Critical patent/US1857163A/en
Priority to GB1357130A priority patent/GB354200A/en
Application granted granted Critical
Publication of US1857163A publication Critical patent/US1857163A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
    • Y10T442/277—Coated or impregnated cellulosic fiber fabric

Definitions

  • This invention relates to the method of treating fabric and relates more particularly to the treatment of fabrics containing organic derivative of cellulose yarn to increase the scroop thereof.
  • An object of my invention is to increase the scroop of fabrics containing organic derivatives of cellulose by subjecting them to the action of suitable reagents.
  • I improve the scroop of fabric containing yarns of organic derivatives of cellulose by treating the same with polybasic acid compounds, such as I the acids themselves or their salts, and preferably, though not necessarily, in the presence of an emulsion of oily bodies.
  • a fabric of any construction may be treated in accordance with my invention.
  • the fabric may be either a woven, knitted or netted fabric, but the greatest advantages of my invention accrue when it is applied to fabric, such as taffeta, where high scroop is desired.
  • the fabric may contain yarns of any suitable organic derivatives of cellulose such as orangic esters or cellulose ethers. Examples of organic esters of cellulose are cellulose acetate, cellulose formate, cellulose propionate and cellulose butyrate while examples of cellulose ethers are ethyl cellulose, methyl cellulose and benzyl cellulose.
  • the fabric may consist wholly of such yarns of organic derivatives of cellulose, or it may be a mixed fabric containing such yarns and yarns of other fibres, such as cotton, reconstituted cellulose, natural silk, wool, etc.
  • the fabric may be treated with a liquid containing in solution or in suspension salts of polybasic aliphatic acids or the acids themselves.
  • a liquid containing in solution or in suspension salts of polybasic aliphatic acids or the acids themselves are the tar- Application filed Kay 14, 1929. Serial No. 363,109.
  • the fabric is dried, without prior washing, in a stretched condition on a frame or tenter.
  • the scroop of the fabric is found to be materially increased.
  • the time of treatment of the fabric in the bath is 15 minutes and the temperature of the bath 45 C.
  • the goods are then removed from the bath, and the excess liquid removed by wringing or centrifugal, extraction, and then, without washing or otherwise removing the liquid still remaining in the fabric, the fabric is dried while stretched on a tenter or frame.
  • the scroop of the fabric is greatly improved, the degree of improvement of scroop being in the order given in the above list of reagents; that is, the fabric treated with sodium tartrate and olive oil emulsion has the highest scroop, while the fabric treated with sodium oxalate alone has the least amount of increase of scroop imparted thereto.
  • Method of improving the scroop of a fabric containing yarns of organic derivatives of cellulose comprising treating the fabric with a polybasic aliphatic acid compound.
  • Method of improving the scroop of a fabric containing yarns of cellulose acetate comprising treating the fabric with a poly lulose comprisingtreating the same with a liquid containing asalt of oxalic acid.
  • Method of improving the scroop of a fabric containing cellulose acetate comprising treating the s'ametvith a liquid containing a salt of oxalic acid.
  • Method of improving the scroop of a fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of oxalic acid and in the presence of an olive oil emulsion.
  • Method of improving the scroop of a fabric containing cellulose acetate comprising treating the same with a liquid containing a salt of oxalic acid and in the presence of an olive oil emulsion.
  • Method of improving the scroop of a fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of oxalic acid and in the presence .of an olive oil emulsion, andthen, without prior washing, drying the fabric.
  • Method of improving the scroop of a fabric containing cellulose acetate comprisin g treating the same with a'liquid containing a salt of oxalic acid and in the presence of an fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of tartaric acid.
  • Method of improving the scroop of a fabric containing cellulose acetate comprising treating the same with a liquid containing a salt of tartaric acid.
  • Method of improving the scroop of a fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of tartaric acid and in the presence of an olive oil emulsion.
  • Method of improving the scroop of a fabric containing cellulose acetate comprising treating the same with a liquid containing a salt of tartaric acid and in the presence of an olive oil emulsion.
  • Method of improving the scroop of a .fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of tartaric acid and in the persence of an olive oil emulsion, and then,
  • Method of improving the scroop of a fabric containing cellulose acetate comprising treating the same with a liquid containing a salt of tartaric acid and in the presence of an olive oil emulsion, and then, without prior washing, drying the fabric.
  • a fabric containing organic derivatives of cellulose yarn having an improved scroop and containing a tartrate is provided.
  • a fabric containing cellulose acetate yarn having an improved scroop and containing a tartrate is provided.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)

Description

Patented May 10, 1932 UNITED. STATES PATENT OFFICE HERBERT PLATT, CUMBERLAND, MARYLAND, ASSIGNQR TO CELANESE CORPORA- TIONOF AMERICA, A CORPORATION OF DELAWARE METHOD OF TREATING FABRICS AND PRODUCT THEREOF No Drawing.
This invention relates to the method of treating fabric and relates more particularly to the treatment of fabrics containing organic derivative of cellulose yarn to increase the scroop thereof.
An object of my invention is to increase the scroop of fabrics containing organic derivatives of cellulose by subjecting them to the action of suitable reagents. Other objects of my invention will appear from the following detailed description.
Often it is desirable to increase the scroop of fabrics containing organic derivative of cellulose yarn, and this is particularly true in case of fabrics such as taffeta. I have found that if such fabric is treated with polybasic aliphatic acids and particularly the salts thereof, and part of such acids or salts is permitted to remain in the fabric, an appreciable increase in scroop results.
In accordance with my invention, I improve the scroop of fabric containing yarns of organic derivatives of cellulose by treating the same with polybasic acid compounds, such as I the acids themselves or their salts, and preferably, though not necessarily, in the presence of an emulsion of oily bodies.
A fabric of any construction may be treated in accordance with my invention. Thus the fabric may be either a woven, knitted or netted fabric, but the greatest advantages of my invention accrue when it is applied to fabric, such as taffeta, where high scroop is desired. The fabric may contain yarns of any suitable organic derivatives of cellulose such as orangic esters or cellulose ethers. Examples of organic esters of cellulose are cellulose acetate, cellulose formate, cellulose propionate and cellulose butyrate while examples of cellulose ethers are ethyl cellulose, methyl cellulose and benzyl cellulose. The fabric may consist wholly of such yarns of organic derivatives of cellulose, or it may be a mixed fabric containing such yarns and yarns of other fibres, such as cotton, reconstituted cellulose, natural silk, wool, etc.
The fabric may be treated with a liquid containing in solution or in suspension salts of polybasic aliphatic acids or the acids themselves. Examples of such salts are the tar- Application filed Kay 14, 1929. Serial No. 363,109.
ing and scouring, and after the removal of the excess reagent by wringing or centrifuging, the fabric is dried, without prior washing, in a stretched condition on a frame or tenter. The scroop of the fabric is found to be materially increased.
In order further to illustrate my invention but without being limited thereto, the following specific example is given.
E wample A woven fabric of tafieta construction and consisting wholly of cellulose acetate yarns,
'after'having been scoured, but not calendered, is subjected to any one of the aqueous baths containing the following reagents:
(1) 4 grams sodium tartrate per litre and 6 cc. oliveoil emulsion per litre.
(2) 4 grams calcium oxalate or potassium oxalate per litre and 6 cc. olive oil emulsion per litre.
I (3) 4 grams sodium oxalate per litre and 6 cc. olive oil emulsion per litre.
(4) 4 grams tartaric acid per litre and 6 cc. olive oil emulsion per litre.
(5) 4 grams barium oxalate per litre.
(6) 4 grams sodium tartrate per litre.
(7-) 4 grams sodium oxalate per litre.
' The time of treatment of the fabric in the bath is 15 minutes and the temperature of the bath 45 C. The goods are then removed from the bath, and the excess liquid removed by wringing or centrifugal, extraction, and then, without washing or otherwise removing the liquid still remaining in the fabric, the fabric is dried while stretched on a tenter or frame. The scroop of the fabric is greatly improved, the degree of improvement of scroop being in the order given in the above list of reagents; that is, the fabric treated with sodium tartrate and olive oil emulsion has the highest scroop, while the fabric treated with sodium oxalate alone has the least amount of increase of scroop imparted thereto. I
It is to be understood that the foregoing detailed description is given merely by way of illustration, and that many variations may be made therein Without departing from the spirit of my invention.
Having described my invention, what I claim and desire to secure by Letters Patent is:
1. Method of improving the scroop of a fabric containing yarns of organic derivatives of cellulose comprising treating the fabric with a polybasic aliphatic acid compound.
2. Method of improving the scroop of a fabric containing yarns of cellulose acetate comprising treating the fabric with a poly lulose comprisingtreating the same with a liquid containing asalt of oxalic acid.
6. Method of improving the scroop of a fabric containing cellulose acetate comprising treating the s'ametvith a liquid containing a salt of oxalic acid.
7. Method of improving the scroop of a fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of oxalic acid and in the presence of an olive oil emulsion.
8. Method of improving the scroop of a fabric containing cellulose acetate comprising treating the same with a liquid containing a salt of oxalic acid and in the presence of an olive oil emulsion.
9. Method of improving the scroop of a fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of oxalic acid and in the presence .of an olive oil emulsion, andthen, without prior washing, drying the fabric.
10. Method of improving the scroop of a fabric containing cellulose acetate comprisin g treating the same with a'liquid containing a salt of oxalic acid and in the presence of an fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of tartaric acid.
16. Method of improving the scroop of a fabric containing cellulose acetate comprising treating the same with a liquid containing a salt of tartaric acid.
17. Method of improving the scroop of a fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of tartaric acid and in the presence of an olive oil emulsion.
18. Method of improving the scroop of a fabric containing cellulose acetate comprising treating the same with a liquid containing a salt of tartaric acid and in the presence of an olive oil emulsion.
19. Method of improving the scroop of a .fabric containing organic derivatives of cellulose comprising treating the same with a liquid containing a salt of tartaric acid and in the persence of an olive oil emulsion, and then,
without prior washing, drying the fabric.
20. Method of improving the scroop of a fabric containing cellulose acetate comprising treating the same with a liquid containing a salt of tartaric acid and in the presence of an olive oil emulsion, and then, without prior washing, drying the fabric.
21. A fabric containing organic derivatives of cellulose yarn having an improved scroop and containing a tartrate.
22. A fabric containing cellulose acetate yarn having an improved scroop and containing a tartrate.
In testimony whereof, I have hereunto subscribed my name.
ER ERT PLATT. 4
US36310929 1929-05-14 1929-05-14 Method of treating fabrics and product thereof Expired - Lifetime US1857163A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US36310929 US1857163A (en) 1929-05-14 1929-05-14 Method of treating fabrics and product thereof
GB1357130A GB354200A (en) 1929-05-14 1930-05-02 Improvements in or relating to the treatment of materials containing organic derivatives of cellulose

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US36310929 US1857163A (en) 1929-05-14 1929-05-14 Method of treating fabrics and product thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2784116A (en) * 1954-03-31 1957-03-05 Kalle & Co Ag Coating process for regenerated cellulose foils
US2821489A (en) * 1955-03-28 1958-01-28 American Viscose Corp Discoloration-resistant regenerated cellulose articles
US2922728A (en) * 1956-11-05 1960-01-26 American Enka Corp Prevention of yellowing in freshly spun viscose rayon with tartaric, citric or gluconic acid

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2784116A (en) * 1954-03-31 1957-03-05 Kalle & Co Ag Coating process for regenerated cellulose foils
US2821489A (en) * 1955-03-28 1958-01-28 American Viscose Corp Discoloration-resistant regenerated cellulose articles
US2922728A (en) * 1956-11-05 1960-01-26 American Enka Corp Prevention of yellowing in freshly spun viscose rayon with tartaric, citric or gluconic acid

Also Published As

Publication number Publication date
GB354200A (en) 1931-08-04

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