US1856144A - Production of phosphoric acid - Google Patents
Production of phosphoric acid Download PDFInfo
- Publication number
- US1856144A US1856144A US529809A US52980931A US1856144A US 1856144 A US1856144 A US 1856144A US 529809 A US529809 A US 529809A US 52980931 A US52980931 A US 52980931A US 1856144 A US1856144 A US 1856144A
- Authority
- US
- United States
- Prior art keywords
- phosphoric acid
- acid
- production
- phosphorous
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title description 22
- 229910000147 aluminium phosphate Inorganic materials 0.000 title description 11
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 6
- 229910017604 nitric acid Inorganic materials 0.000 description 6
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 150000002927 oxygen compounds Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/237—Selective elimination of impurities
- C01B25/2372—Anionic impurities, e.g. silica or boron compounds
Definitions
- the present invention relates to the production of phosphoric acid from oxygen compounds of phosphorus which are still capable of being further oxidized. More particularly the present invention relates to the treatment of phosphoric acid containing phosphorous acid such as is obtained by the catalytic oxidation of phosphorus by means of water or steam; in such crude phosphoric acid the content in phosphorous acid is troublesome when the phosphoric acid is to be used for the production of fertilizers, so that it is es sential to oxidize the phosphorous acid contained therein before the acid can be made use of for the said purpose. Such oxidation cannot be effected by the usual oxidizing agents such as air or chlorine. The oxida tion can be carried through with the aid of nitric acid, but leads to success only when the nitric acid is used in excess and when the content of the solution in phosphoric acid and phosphorous acid is at least per cent.
- Example An aqueous solution of phosphoric acid having a specific gravity of 1.4 and containing L per cent of phosphorous acid (calculated with reference to the phosphoric acid present) is mixed with the amount of nitric acid theoretically necessary for the oxidation of the phosphorous acid.
- the mixture is heated in an autoclave to 120 C. whereby the pressure increases to 1.3 atmospheres.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Patented May 3, 1932 UNITED STATES PATENT OFFICE GUSTAV WIIETZEL, 0F MANNHEIM, AND FERDINAND HAUBACH, 0F LUDWIGSHAFEN-ON- THE-RHINE, GERMANY, ASSIGNORS TO I. G. FARIBENINDUSTRIE AK'IIENGESELL- SCHAFI, 01E FRANKFORT-ON-THE-MAIN, GERMANY IPLROIDUCTION OF PHOSPHORIC ACID No Drawing. Application filed April 13, 1931, Serial N0. 529,809, and in Germany April 25, 1980.
The present invention relates to the production of phosphoric acid from oxygen compounds of phosphorus which are still capable of being further oxidized. More particularly the present invention relates to the treatment of phosphoric acid containing phosphorous acid such as is obtained by the catalytic oxidation of phosphorus by means of water or steam; in such crude phosphoric acid the content in phosphorous acid is troublesome when the phosphoric acid is to be used for the production of fertilizers, so that it is es sential to oxidize the phosphorous acid contained therein before the acid can be made use of for the said purpose. Such oxidation cannot be effected by the usual oxidizing agents such as air or chlorine. The oxida tion can be carried through with the aid of nitric acid, but leads to success only when the nitric acid is used in excess and when the content of the solution in phosphoric acid and phosphorous acid is at least per cent.
We have now found that a practically complete oxidation of oxygen compounds of phosphorus, which are still capable of being further oxidized, can be carried through with the amount of nitric acid theoretically neces sary if the operation is carried out at temperatures above C. and in a confined re action space, that is in a closed vessel and accordingly under an elevated pressure. This manner of working may even successfully be applied to solutions of a lower concentration than 60 per cent, for example to solutions containing only 45 per cent of phosphoric and phosphorous acids. The oxides of nitrogen evolved during the reaction may separately be regenerated by means of air or oxygen, whereby they are converted into nitrogen dioxide and nitric acid and can then be used over again for the oxidation.
The following example will further illustrate the nature of this invention, but the invention is not limited to this example.
Example An aqueous solution of phosphoric acid having a specific gravity of 1.4 and containing L per cent of phosphorous acid (calculated with reference to the phosphoric acid present) is mixed with the amount of nitric acid theoretically necessary for the oxidation of the phosphorous acid. The mixture is heated in an autoclave to 120 C. whereby the pressure increases to 1.3 atmospheres. Atter the treatment the phosphoric acid contilllclls only about 0.05 per cent of phosphorous acl WVhat we claim is 1. In the production of phosphoric acid by oxidizing oxygen compounds of phosphorus still capable of being further oxidized by means of nitric acid, the step which comprises carrying out the oxidation with the
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1856144X | 1930-04-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1856144A true US1856144A (en) | 1932-05-03 |
Family
ID=7746220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US529809A Expired - Lifetime US1856144A (en) | 1930-04-25 | 1931-04-13 | Production of phosphoric acid |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1856144A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2968528A (en) * | 1957-07-01 | 1961-01-17 | Int Minerals & Chem Corp | Process for producing clarified phosphoric acid |
| US3361528A (en) * | 1964-09-08 | 1968-01-02 | Monsanto Co | Purification of orthophosphorous acid |
| US3436184A (en) * | 1964-08-25 | 1969-04-01 | Monsanto Co | Process for recovering phosphorus from sludge |
-
1931
- 1931-04-13 US US529809A patent/US1856144A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2968528A (en) * | 1957-07-01 | 1961-01-17 | Int Minerals & Chem Corp | Process for producing clarified phosphoric acid |
| US3436184A (en) * | 1964-08-25 | 1969-04-01 | Monsanto Co | Process for recovering phosphorus from sludge |
| US3361528A (en) * | 1964-09-08 | 1968-01-02 | Monsanto Co | Purification of orthophosphorous acid |
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