US1852109A - Froth flotation - Google Patents
Froth flotation Download PDFInfo
- Publication number
- US1852109A US1852109A US423892A US42389230A US1852109A US 1852109 A US1852109 A US 1852109A US 423892 A US423892 A US 423892A US 42389230 A US42389230 A US 42389230A US 1852109 A US1852109 A US 1852109A
- Authority
- US
- United States
- Prior art keywords
- ores
- froth flotation
- ore
- promotor
- minerals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009291 froth flotation Methods 0.000 title description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 description 13
- 239000011707 mineral Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 10
- 238000005188 flotation Methods 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 159000000011 group IA salts Chemical class 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 238000005273 aeration Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- KJLLKLRVCJAFRY-UHFFFAOYSA-N mebutizide Chemical compound ClC1=C(S(N)(=O)=O)C=C2S(=O)(=O)NC(C(C)C(C)CC)NC2=C1 KJLLKLRVCJAFRY-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 239000006012 monoammonium phosphate Substances 0.000 description 1
- -1 naph'thyl Chemical group 0.000 description 1
- JOVOSQBPPZZESK-UHFFFAOYSA-N phenylhydrazine hydrochloride Chemical compound Cl.NNC1=CC=CC=C1 JOVOSQBPPZZESK-UHFFFAOYSA-N 0.000 description 1
- 229940038531 phenylhydrazine hydrochloride Drugs 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S209/00—Classifying, separating, and assorting solids
- Y10S209/901—Froth flotation; copper
Definitions
- This invention relates to the froth flotation of ores and more particularly to a process which involves the use of promotors of flotation which are novel and useful.
- oxidized minerals we include compounds of heavy metals, such as lead, zinc, copper, etc., in chemical combination with elements or groups of elements'other than sulphur, for instance, in theform of oxides, hydroxides, carbonates and the like.
- Our invention contemplates the use as a promotor in a froth flotation operation, of the reaction products of carbon bisulphide and a hydrazine.
- promotors may be successfully used in the flotation of sulfide ores, relatively few are efiective in the flotation of oxidized minerals.
- the abpve mentioned class of comuse salts thereof such salts being s pounds, and particularly the dithiocarbazides, are effective not only for sulfide flotation but also for oxide flotation.
- the free carbazide may be used, we prefer to generally of an alkaline nature. We may a 0 use such reagents in combination with other promotors and with frothers and conditioners.
- a sample was stage crushed to minus 20 mesh. A 1200 gram portion of this minus 20 mesh ore and 600 cc. of water with 4 lbs. of lime per ton were ground in a steel laboratory'rod mill for a 10 minute period. The above grind was transferred to a flotation machine of the sub-aeration type and diluted to 22% solids. Reagents were added to the machine as follows 0.05 lbs. of tphenyldithiocarbazide made up as sodium salt per on 0.03 lbs.
- R is the aryl or alkyl group, such as phenyl, tolyl, naph'thyl, methyl and the like, or hydrogen; and Me is an alkaline metal such as calcium, ammonium, sodium and the like, or hydrogen.
- a method of recovering minerals from ores which comprises subjecting an ore'to a froth flotation operation in the presence of a dithiocarbazide as a promotor.
- a method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the presence of a substituted dithiocarbazide as a promotor.
- a method of recovering minerals from ores which comprises subjectingan ore to a froth flotation operation in the presence of an aryl dithiocarbazide as a promotor.
- a method of recovering minerals from ores which comprises subjectingan ore to a froth flotation operation in the presence of a phenyl dithiocarbazide as a promotor.
- a method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the resence of an alkaline salt of a dithiocarbazi e as a promotor.
- a method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the resence of an alkaline salt of asubstitute dithiocarbazide as a promotor.
- a method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the presence of an alkaline salt of a phenyl dithlocarbazide as a promotor.
- a method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the presence of a promotor having the following structural,
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Description
atented Apr. 5, 1932 UNITED STATES L'UDWIG J'- CHRISTMAI TN, OF JERSEY CITY, AND STUART A. FALCONER, OF ELIZABETH, NEW JERSEY, ASSIGNORS 'IO AMERICAN CYANAMID COMPANY, OF NEW YORK, N. Y.,
A CORPORATION OF MAINE FROTH FLO'IATIOIF No Drawing.
This invention relates to the froth flotation of ores and more particularly to a process which involves the use of promotors of flotation which are novel and useful.
It is among the objects of this invention to provide a method for the separation of various minerals from ores containing the same.
More particularly it is amon the objects of this invention to recover sulfi e minerals and oxidized minerals even in very small amounts from ores. By oxidized minerals, we include compounds of heavy metals, such as lead, zinc, copper, etc., in chemical combination with elements or groups of elements'other than sulphur, for instance, in theform of oxides, hydroxides, carbonates and the like. Our invention contemplates the use as a promotor in a froth flotation operation, of the reaction products of carbon bisulphide and a hydrazine. We generally utilize a substituted hydrazine, either of the aryl or alkyl t pe.
Although many of the promotors may be successfully used in the flotation of sulfide ores, relatively few are efiective in the flotation of oxidized minerals. We have discovered that the abpve mentioned class of comuse salts thereof, such salts being s pounds, and particularly the dithiocarbazides, are effective not only for sulfide flotation but also for oxide flotation. Although the free carbazide may be used, we prefer to generally of an alkaline nature. We may a 0 use such reagents in combination with other promotors and with frothers and conditioners.
In order to prepare the compounds constituting the subject matter of this invention, we may provide a mixture of 55 parts by weight of phenyl hydrazine hydrochloride with parts by weight of carbon disulfide and parts of water. This mixture is cooled in an ice bath and a solution of 33 parts of potassium hydroxide in 50 parts of water is slowly added with stirring.
After all the potassium hydroxide has been added the mixture is filtered and washed. The filtrate is acidified in an ice bathwith hydrochloric acid producing a white precipitate which is filtered and washed. The residue from the reaction mixture is dissolved Iron l 12.9
Application filed January 27, 1930. Serial No. 423,892.
Per cent Copper 5.10
Insoluble; 62.1
A sample was stage crushed to minus 20 mesh. A 1200 gram portion of this minus 20 mesh ore and 600 cc. of water with 4 lbs. of lime per ton were ground in a steel laboratory'rod mill for a 10 minute period. The above grind was transferred to a flotation machine of the sub-aeration type and diluted to 22% solids. Reagents were added to the machine as follows 0.05 lbs. of tphenyldithiocarbazide made up as sodium salt per on 0.03 lbs. of gns #5 "steam distilled pine oil per ton A concentrate Was removed for 3 minutes In the flotation of oxide ores these reagents are very effective and the following example illustrates our invention in connec tion with oxidized lead ore. y
1200 g. of minus ten mesh ore, 1200 g. of water 5.0 lbs. of crude mono ammonium phosphate per ton of ore were ground in a steel mesh of the feed was 60% minus 200 mesh The rod mill charge was transferred to a sub-aeration machine and diluted to 22% solids. The reagents are added to the ma chine and a mineralized froth collected for 20 minutes.
Reagents in lbs. per ton of ore Ammonium dibut '1 d1thlophospl1ate..-: 1. 25 1. 25 Phenyl dithiocar nzlde 4. 0 Crude mono-ammonium phosphate- 5. 0 5. 0 Percent lead in heads 26. 6 27. 2 Percent lead in concentrntes 38. 2 47. Percent lead in tails 19. 59 4. 88 Percent lead in recovery 54. 5 91. 4
The class of compounds used by us may be denoted by the following structural formula: i a
s n-nn-nu-d s-me in which R is the aryl or alkyl group, such as phenyl, tolyl, naph'thyl, methyl and the like, or hydrogen; and Me is an alkaline metal such as calcium, ammonium, sodium and the like, or hydrogen.
Although we have described our invention setting forth a few specific examples of the promotors which we have found effective and of ores with which we have worked, our invention is broader than the specific disclosure, in that a large number of compounds may be used in accordance withour invention and a largevariety of ores maybe successfully floated therewith.
Our invention is, therefore, to be construed broadl except as limited by the claims appende hereto. Y
What we claim is: 1. A method of recovering minerals from ores which comprises subjecting an ore'to a froth flotation operation in the presence of a dithiocarbazide as a promotor. 1
' 2. A method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the presence of a substituted dithiocarbazide as a promotor.
3. A method of recovering minerals from ores which comprises subjectingan ore to a froth flotation operation in the presence of an aryl dithiocarbazide as a promotor.
4. A method of recovering minerals from ores which comprises subjectingan ore to a froth flotation operation in the presence of a phenyl dithiocarbazide as a promotor.
5. A method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the resence of an alkaline salt of a dithiocarbazi e as a promotor. 1
6. A method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the resence of an alkaline salt of asubstitute dithiocarbazide as a promotor.
froth flotation operation'in the presence of an alkaline salt of an aryl dithiocarbazide as a promotor.
8. A method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the presence of an alkaline salt of a phenyl dithlocarbazide as a promotor.
9. A method of recovering minerals from ores which comprises subjecting an ore to a froth flotation operation in the presence of a promotor having the following structural,
formula n-mn-mn--s-m where R is aryl or alkyl or hydrogen and Me is alkaline radical or hydrogen;
In testimony whereof, we have hereunto subscribed-our names this 21st day of J anuary, 1930.
' LUDWIG J. CHRISTMANN.
STUART A. FALCONER. Y i
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US423892A US1852109A (en) | 1930-01-27 | 1930-01-27 | Froth flotation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US423892A US1852109A (en) | 1930-01-27 | 1930-01-27 | Froth flotation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1852109A true US1852109A (en) | 1932-04-05 |
Family
ID=23680593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US423892A Expired - Lifetime US1852109A (en) | 1930-01-27 | 1930-01-27 | Froth flotation |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1852109A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951786A (en) * | 1974-04-30 | 1976-04-20 | Vojislav Petrovich | Oxidizing method in froth flotation of minerals |
-
1930
- 1930-01-27 US US423892A patent/US1852109A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951786A (en) * | 1974-04-30 | 1976-04-20 | Vojislav Petrovich | Oxidizing method in froth flotation of minerals |
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