US1781902A - Manifolding - Google Patents
Manifolding Download PDFInfo
- Publication number
- US1781902A US1781902A US332697A US33269729A US1781902A US 1781902 A US1781902 A US 1781902A US 332697 A US332697 A US 332697A US 33269729 A US33269729 A US 33269729A US 1781902 A US1781902 A US 1781902A
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- US
- United States
- Prior art keywords
- sheet
- reagent
- sheets
- reagents
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000003153 chemical reaction reagent Substances 0.000 description 38
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 19
- 239000000976 ink Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 11
- 235000004515 gallic acid Nutrition 0.000 description 9
- 229940074391 gallic acid Drugs 0.000 description 9
- 150000002505 iron Chemical class 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/132—Chemical colour-forming components; Additives or binders therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S101/00—Printing
- Y10S101/29—Printing involving a color-forming phenomenon
Definitions
- My invention relates to manifolding and comprises a new method by whichtwo or more copies of a Writing may be made by a single impression.
- any reasonable number of duplicate copies may be produced at a single writing without the use of carbon or ink coated paper, or any sheet corresponding thereto.
- This result may be obtained in a number of ways, asby applying to the rear surfaceof the first sheet, that is, the sheet upon which typewriter ribbon or'the pencil or pen of the user, and upon the front surface of the second sheet, which in use underlies the first sheet, chemical reagents which when brought into intimate contact with each other, will react to form an ink.
- Each sheet is ordinarily made of paper and various reagents may be used, resulting in inks of difierent colors, durability, etc.
- the number of copies of the original writing can be increased as desired by treating the rear as well as the front surface of the second sheet, and placing it in contact with a third sheet to the front face of which a reagent has beenapplied which is capable of. reacting with that the written impression is to be made by the' on the rear face of the second sheet to form an ink.
- the reagent instead of being applied to the surface of the sheet may be incorporated in the sheet during its process of manufacture.
- Numerous other modifications may be made in the carrying out of the invention and I do notdesire to limit myself to any particular manner of using the invention, but to include all such methods and vmeans, as are defined by the accompanying second sheet suitably prepared for carrying out my invention.
- Fig. 2 is a similar view of a three sheet arrangement.
- Fig. 3 is a similar view of a modified three sheet arrangement
- Fig. 4 is a similar View of a two sheet modification.
- the rear surface of the first sheet 1 which may be ordinary typewriter paper or Writing paperpreferably not highly calendered, is provided with a reagent 2, and the front surface of the second sheetv 3, also of paper similar to that of sheet 1, is provided with a reagent 4 which when brought into intimate contact with reagent 2 will react therewith to form an ink.
- a reagent 2 which when brought into intimate contact with reagent 2 will react therewith to form an ink.
- reagents are capable of producing such a result and many different kinds of ink can be so produced, and the invention is not limited to any particular reagents or ink.
- gallic acid series for example, ordinary gallic acid.
- gallo-t'annic acid series for example, tannic acid will also give good results.
- Other reagents which may be used in place of gallic acid and which are equivalent thereto are salicylic acid, oxysalicyll ic acid, and oxymesitylenic acid and its sa s.
- gallic acid which is a light powder
- the material may beanu'bbed on to I the paper sheet by a felt covered roll. This causes it to be distributed over the surface and to be rubbed into the minute depressions, pores and cavities of its surface. The sheet should then be brushed, as by a revolving brush, to remove loose or surplus particles of the acid.
- the reagent 4 to be applied tothe front surface of sheet 3 will be such as to react with reagent 2 of sheet 1 and in case gallic acid is used as described may be a ferrlc or ferrous salt, for example, ferric sulphate or ferric chloride either alone or a mixture of both. In using these materials a water solution of the salt or salts is applied to the paper and allowed to dry. It is desirable that the reagent 4 should not be completely dry, and I prefer, therefore, to add to the solution a small percentage of glycerine or other nondrying substance, or a hygroscopic in-- gredient.
- the combination produced by the intimate contact of the reagents upon the two sheets may be colorless, but may be readily made visible by exposing same to steam or water spray or by breathing thereon.
- the use of such reagents is included within my invention.
- reagent 2 In case it is desired to make more than one duplicate of the writing upon the first sheet, I provide the rear surface of the second sheet 5 with reagent 2, its front surface being provided with reagent 4, the reagents 2 and 4 of Fig. 2 being the same as those of Fig. 1 and applied in the same way.
- a third sheet 3 is provided which is identical with the second sheet 3 of Fig. 1 and has the same kind of reagent coating 4.
- Fig. 3 shows the application of the invention to a three sheet combination in which 6 is an ordinary-sheet of paper without any ink forming reagent, 7 is a sheet of transparent paper provided with the reagent 4 as previously described upon its rear surface, and 8 is a third sheet of paper having upon its front surface the reagent 2, applied as hereinbefore described.
- the first sheet 1 with reagent 2 is the same as in Figs. 1 and 2
- the second sheet 9 is a sheet of paper within which a ferric or ferrous salt is incorporated during its manufacture in suflicient quantity to produce the desired result.
- sheets which are all alike, for example the sheet 50f Fig. 2 having reagent 4 on its front surface and reagent 2 on its rear surface. Such sheets may be superposed upon each other to produce the desired number of copies.
- ink in the claims is intended to include not only technical inks obtained by a combination of iron compound with a member of the tannic acid series, but also all colored compounds derived from the union of equivalent chemicals in the manner herein set forth.
- the method of manifolding which consists in respectively providing the surfaces of two sheet members with chemical reagents which are capable of reacting with each other to form an ink, superposing said sheets with the reagent surfaces in contact and impressing written matter upon the outer surface of one of said sheets with pressure suflicient to bring said reagents into intimate contact with each other.
- the contacting surfaces be ing provided respectively with gallic acid and an iron salt with a. hygroscopic substance.
- the method of printing which consists in respectively providing the surfaces of two sheet members with chemical reagents which are capable of reacting. with each other to form an ink, superposing said sheets with the treatedsurfaces in contact and apply ing to one of said sheets concentrated pressure along a line or lines of the shape of a legible character to bring the reagent materials which are subjected to such pressure into sufliciently intimate contact to cause them to react.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Color Printing (AREA)
Description
Nov. 18, 1930. E. R. GILL, JR
MANIFQLDING Filed Jan. 15. 1929 INVENTOR. EDWIN G/L L. .BY
A TTORNEYS.
' v Patented Nov. 18, 1930 UNITED STATES -EDITIN' R. GILL, JR.-, OF YONKERS, NEW YORK v MANIFOLDING Applicatiom filed January 15, 1929. Serial No. 332,697.
My invention relates to manifolding and comprises a new method by whichtwo or more copies of a Writing may be made by a single impression.
5 Heretofore the usual method of securing a plurality of copies at a single writing has been to provide a sheet of socalled carbon paper which has one or both of its surfaces coated with an ink which is capable of being transferred by contact pressure to the surface of a blank sheet of paper to produce a duplicate of the original writing. Such method is universally used in connection with typewriting machines and is also very extensively used in connection with hand written documents of various kinds, for example, orders for goods, sales slips, shipping recei ts, etc.
uch method produces satisfactory copies or duplicates, but is open to the objection that carbon paper is expensive and its handling in order to place or arrange it in proper relation to the various sheets upon which copies are to be produced requires considerable time and soils the fingers.
In accordance with my invention any reasonable number of duplicate copiesmay be produced at a single writing without the use of carbon or ink coated paper, or any sheet corresponding thereto.
This result may be obtained in a number of ways, asby applying to the rear surfaceof the first sheet, that is, the sheet upon which typewriter ribbon or'the pencil or pen of the user, and upon the front surface of the second sheet, which in use underlies the first sheet, chemical reagents which when brought into intimate contact with each other, will react to form an ink. Each sheet is ordinarily made of paper and various reagents may be used, resulting in inks of difierent colors, durability, etc. The number of copies of the original writing can be increased as desired by treating the rear as well as the front surface of the second sheet, and placing it in contact with a third sheet to the front face of which a reagent has beenapplied which is capable of. reacting with that the written impression is to be made by the' on the rear face of the second sheet to form an ink.
In some cases the reagent instead of being applied to the surface of the sheet may be incorporated in the sheet during its process of manufacture. Numerous other modifications may be made in the carrying out of the invention and I do notdesire to limit myself to any particular manner of using the invention, but to include all such methods and vmeans, as are defined by the accompanying second sheet suitably prepared for carrying out my invention.
Fig. 2 is a similar view of a three sheet arrangement.
Fig. 3 is a similar view of a modified three sheet arrangement, and
Fig. 4 is a similar View of a two sheet modification.
Referring to Fig. 1, the rear surface of the first sheet 1, which may be ordinary typewriter paper or Writing paperpreferably not highly calendered, is provided with a reagent 2, and the front surface of the second sheetv 3, also of paper similar to that of sheet 1, is provided with a reagent 4 which when brought into intimate contact with reagent 2 will react therewith to form an ink.
Many reagents are capable of producing such a result and many different kinds of ink can be so produced, and the invention is not limited to any particular reagents or ink.
I have obtained desirable results by applying to the rear surface of sheet 1 one of the gallic acid series, for example, ordinary gallic acid. Members of the gallo-t'annic acid series, for example, tannic acid will also give good results. Other reagents which may be used in place of gallic acid and which are equivalent thereto are salicylic acid, oxysalicyll ic acid, and oxymesitylenic acid and its sa s.
In applying gallic acid, which is a light powder, the material may beanu'bbed on to I the paper sheet by a felt covered roll. This causes it to be distributed over the surface and to be rubbed into the minute depressions, pores and cavities of its surface. The sheet should then be brushed, as by a revolving brush, to remove loose or surplus particles of the acid.
The reagent 4 to be applied tothe front surface of sheet 3 will be such as to react with reagent 2 of sheet 1 and in case gallic acid is used as described may be a ferrlc or ferrous salt, for example, ferric sulphate or ferric chloride either alone or a mixture of both. In using these materials a water solution of the salt or salts is applied to the paper and allowed to dry. It is desirable that the reagent 4 should not be completely dry, and I prefer, therefore, to add to the solution a small percentage of glycerine or other nondrying substance, or a hygroscopic in-- gredient.
In using certain reagents, where non-drying or hygroscopic ingredients are not present, the combination produced by the intimate contact of the reagents upon the two sheets ma be colorless, but may be readily made visible by exposing same to steam or water spray or by breathing thereon. The use of such reagents is included within my invention.
In case it is desired to make more than one duplicate of the writing upon the first sheet, I provide the rear surface of the second sheet 5 with reagent 2, its front surface being provided with reagent 4, the reagents 2 and 4 of Fig. 2 being the same as those of Fig. 1 and applied in the same way. In addition a third sheet 3 is provided which is identical with the second sheet 3 of Fig. 1 and has the same kind of reagent coating 4.
Fig. 3 shows the application of the invention to a three sheet combination in which 6 is an ordinary-sheet of paper without any ink forming reagent, 7 is a sheet of transparent paper provided with the reagent 4 as previously described upon its rear surface, and 8 is a third sheet of paper having upon its front surface the reagent 2, applied as hereinbefore described.
In Fig. 4, the first sheet 1 with reagent 2 is the same as in Figs. 1 and 2, and the second sheet 9 is a sheet of paper within which a ferric or ferrous salt is incorporated during its manufacture in suflicient quantity to produce the desired result.
In practice, in order to avoid the use of sheets of different character necessitating the work of keeping them in separate containers or drawers and putting them together as used, I may use sheets which are all alike, for example the sheet 50f Fig. 2 having reagent 4 on its front surface and reagent 2 on its rear surface. Such sheets may be superposed upon each other to produce the desired number of copies.
The word ink in the claims is intended to include not only technical inks obtained by a combination of iron compound with a member of the tannic acid series, but also all colored compounds derived from the union of equivalent chemicals in the manner herein set forth.
Having described my invention, what I claim is:
1. The method of manifolding which consists in respectively providing the surfaces of two sheet members with chemical reagents which are capable of reacting with each other to form an ink, superposing said sheets with the reagent surfaces in contact and impressing written matter upon the outer surface of one of said sheets with pressure suflicient to bring said reagents into intimate contact with each other.
2. The method of manifoldin by applying to the rear surface of ,a first sheet a chemical reagent and to the front surface of a rear sheet a chemical reagent which is capable of reacting with the first reagent to form an ink, superposing said sheets, and lmpressing Written matter upon the front surface of the first sheet with pressure sufficient to bring said reagents into intimate contact with each other.
3. The method of manifolding which consists in applying gallic acid to the surface of a sheet, applying an iron salt and a hygroscopic substance to another sheet, superposlng said sheets with the reagent surfaces in contact, and impressing written matter upon the outer surface of one of said sheets with pressure suflicient to bring said reagents into intimate contact with each other.
4. The method of manifolding which consists in applying gallic acid to the surface of a sheet, applying an iron salt and glycerbeing respectively provided with reagents capable of reacting when in intimate contact to form an ink.
6. In a manifolding system, superposed contacting sheets, the contacting surfaces being provided respectively with gallic acid and an iron salt.
7. In a manifolding system,superposed contacting sheets, the contacting surfaces being provided respectively with gallic acid and an iron salt and glycerin.
8. In a manifolding system, superposed contacting sheets, the contacting surfaces be ing provided respectively with gallic acid and an iron salt with a. hygroscopic substance.
9. The method of printing which consists in respectively providing the surfaces of two sheet members with chemical reagents which are capable of reacting. with each other to form an ink, superposing said sheets with the treatedsurfaces in contact and apply ing to one of said sheets concentrated pressure along a line or lines of the shape of a legible character to bring the reagent materials which are subjected to such pressure into sufliciently intimate contact to cause them to react.
In testimony whereof, I have signed my name hereto.
EDWIN R. GILL, JR.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US332697A US1781902A (en) | 1929-01-15 | 1929-01-15 | Manifolding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US332697A US1781902A (en) | 1929-01-15 | 1929-01-15 | Manifolding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1781902A true US1781902A (en) | 1930-11-18 |
Family
ID=23299448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US332697A Expired - Lifetime US1781902A (en) | 1929-01-15 | 1929-01-15 | Manifolding |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1781902A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2548364A (en) * | 1948-07-13 | 1951-04-10 | Ncr Co | Pressure sensitive record materials |
| US2588572A (en) * | 1947-09-23 | 1952-03-11 | Potteiger Roy Victor | Method of making mechanical negatives for photocopies |
| US2663653A (en) * | 1948-03-17 | 1953-12-22 | Standard Register Co | Manifold sheet and process of making same |
| US2663579A (en) * | 1948-03-17 | 1953-12-22 | Standard Register Co | Manifolding transfer and method of making |
| US2870040A (en) * | 1957-08-06 | 1959-01-20 | Jr Edwin R Gill | Coated manifolding sheets and method of making them |
| US2939009A (en) * | 1956-02-01 | 1960-05-31 | Jack M Tien | Thermotransfer duplicating process |
| US3000298A (en) * | 1956-01-03 | 1961-09-19 | Sherman | Printing by diazotization |
| US3637414A (en) * | 1967-12-20 | 1972-01-25 | Columbia Ribbon & Carbon | Thermographic transfer sheet |
| US3870435A (en) * | 1969-07-09 | 1975-03-11 | Pilot Pen Co Ltd | Visual recording method and means |
| US4062567A (en) * | 1974-05-03 | 1977-12-13 | Moore Business Forms, Inc. | Dual system carbonless paper |
-
1929
- 1929-01-15 US US332697A patent/US1781902A/en not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2588572A (en) * | 1947-09-23 | 1952-03-11 | Potteiger Roy Victor | Method of making mechanical negatives for photocopies |
| US2663653A (en) * | 1948-03-17 | 1953-12-22 | Standard Register Co | Manifold sheet and process of making same |
| US2663579A (en) * | 1948-03-17 | 1953-12-22 | Standard Register Co | Manifolding transfer and method of making |
| US2548364A (en) * | 1948-07-13 | 1951-04-10 | Ncr Co | Pressure sensitive record materials |
| US2548366A (en) * | 1948-07-13 | 1951-04-10 | Ncr Co | Manifold record material and process for making it |
| US2548365A (en) * | 1948-07-13 | 1951-04-10 | Ncr Co | Process for making pressure sensitive record materials |
| US3000298A (en) * | 1956-01-03 | 1961-09-19 | Sherman | Printing by diazotization |
| US2939009A (en) * | 1956-02-01 | 1960-05-31 | Jack M Tien | Thermotransfer duplicating process |
| US2870040A (en) * | 1957-08-06 | 1959-01-20 | Jr Edwin R Gill | Coated manifolding sheets and method of making them |
| US3637414A (en) * | 1967-12-20 | 1972-01-25 | Columbia Ribbon & Carbon | Thermographic transfer sheet |
| US3870435A (en) * | 1969-07-09 | 1975-03-11 | Pilot Pen Co Ltd | Visual recording method and means |
| US4062567A (en) * | 1974-05-03 | 1977-12-13 | Moore Business Forms, Inc. | Dual system carbonless paper |
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