US1777858A - Laundering method - Google Patents
Laundering method Download PDFInfo
- Publication number
- US1777858A US1777858A US742268A US74226824A US1777858A US 1777858 A US1777858 A US 1777858A US 742268 A US742268 A US 742268A US 74226824 A US74226824 A US 74226824A US 1777858 A US1777858 A US 1777858A
- Authority
- US
- United States
- Prior art keywords
- goods
- ammonium
- alkali
- soap
- bleach
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 9
- 238000004900 laundering Methods 0.000 title description 7
- 239000003513 alkali Substances 0.000 description 11
- 150000003863 ammonium salts Chemical class 0.000 description 11
- 239000000344 soap Substances 0.000 description 10
- 239000007844 bleaching agent Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
Definitions
- ammonium sulfite or ammonium thiosulfate will serve not only as an antichlor but also as a modifying agent for the sodium carbonate or other alkali.
- the present application is based specifically on the'use of such a single agent.
- the goods are subjected to the usual baths among which is a bath containing a bleach and an alkali. Thereafter the goods are subjected to a bath containing an ammonium salt such as the sulfite or thiosulfate, or equivalent agent, which serves both to reduce the bleach and tomodify the alkali to a less alkaline product.
- an equivalent agent I mean an ammonium salt in which the ammonium group is combined with a reducing sulphur acid to form -a salt which will reduce chlorine and hypochlorites and not decompose soap.
- the amount of the ammonium salts necessary to give the best results depends, of course, on the previous treatment of the goods, the amount of alkalinity, the amount of bleach and the amount of rinsing. Sulficient ammonium salt should be added to the water to neutralize the oxidizing power of the bleach and turn the stronger alkalies over to the harmless ammonia. An excess of the 2. 60 gallons warm water, suflicient" Application filed October 7, 1924. Serial No. 742,268.
- ammonium salt will do no harm.
- a typical washing formula would be as follows:
- What I claim is 1.
- the method which includes subjecting the goods'to a bath con taining the usual soap and bleach and an alkali and thereafter, before the soap has been washed out, subjecting the goods to an ammonium salt in which the ammonium group is combined with a reducing'acid and which will function as an antichlor for the chlorine and hypochlorites and not decompose soap and which will modify the alkali to a less alkaline product.
- the method which includes subjecting t e goods to an ammonium sulfite.
- the method which includessubjecting the goods to a bath containing soap, hypochlorite liquor and sodium bicarbonate and thereafter, before the soap has been rinsed out, subjecting the goods to an ammonium salt in which the ammonium group is combined with a reducing acid and which will function as an antichlor for the chlorine and hypochlorites and will not decompose soap and which will modify the alkali to a less alkaline product.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Patented Oct. 1930 UNITED- STATES PATENT OFFICE ROBERT A. PHAIR, OF ALLENDALE, NEW JERSEY, ASSIGNOR TO H. KOHNS'IAMM'. & (10., INC., 01 NEW YORK, N. Y., A CORPORATION OF NEW YORK LAUNDERING METHOD R Drawing.
In my application N 0. 644,818, filed June 11, 1923, I have described a laundering method in which the goods are subjected to a bath containing a bleach such as hypo- 5 chlorite liquor and an alkali such as sodium bicarbonate, and are subjected to a chlorine reducing agent or antichlor such as sodium sulfite and to an alkali-modifying salt such as ammonium sulfate which converts the alkali into a harmless and easily removable substance. These two agents, the antichlor and the alkali-modifier, may be separate substances added to the same water with or without preliminary mixing.
In order to secure the two efiects referred to, I may use a single agent which combines them. For example ammonium sulfite or ammonium thiosulfate will serve not only as an antichlor but also as a modifying agent for the sodium carbonate or other alkali.
The present application is based specifically on the'use of such a single agent. In this method, the goods are subjected to the usual baths among which is a bath containing a bleach and an alkali. Thereafter the goods are subjected to a bath containing an ammonium salt such as the sulfite or thiosulfate, or equivalent agent, which serves both to reduce the bleach and tomodify the alkali to a less alkaline product.
By an equivalent agent I mean an ammonium salt in which the ammonium group is combined with a reducing sulphur acid to form -a salt which will reduce chlorine and hypochlorites and not decompose soap.
The amount of the ammonium salts necessary to give the best results depends, of course, on the previous treatment of the goods, the amount of alkalinity, the amount of bleach and the amount of rinsing. Sulficient ammonium salt should be added to the water to neutralize the oxidizing power of the bleach and turn the stronger alkalies over to the harmless ammonia. An excess of the 2. 60 gallons warm water, suflicient" Application filed October 7, 1924. Serial No. 742,268.
ammonium salt will do no harm. A typical washing formula would be as follows:
soap for'suds 10 3. gallons hot water 36 oz. 12%
available chlorine bleach 20 4. 120 gallons hot water oz. ammonium sulfite dry 5 5. 120 gallons hot water rinse 5 6. 120 gallons warm water rinse 5 7. 120 gallons cold water rinse 5 take care of the'alkali a sample of the bath may be taken and boiled until no more ammonia distills off; if the sample still reacts red with phenolphthalein, more of the ammonium salt should be added.
What I claim is 1. In laundering, the method'which includes subjecting the goods'to a bath con taining the usual soap and bleach and an alkali and thereafter, before the soap has been washed out, subjecting the goods to an ammonium salt in which the ammonium group is combined with a reducing'acid and which will function as an antichlor for the chlorine and hypochlorites and not decompose soap and which will modify the alkali to a less alkaline product. v
2. In laundering, themethod which includes subjecting the goods toa bath containing a bleach and an alkali and thereafter subjecting the goods to an ammonium salt in which the ammonium group is combined 4. In launderin bicarbonate and thereafter,
' with a reducing acid containing sulfur and oxygen.
3. In launderin the method which includes subjecting t e goods to an ammonium salt selected from the group consistinguof ammonium sulfite and ammonium t 'osulfate. 4
the method which includes subjecting t e goods to an ammonium sulfite.
5. In laundering, the method which includessubjecting the goods to a bath containing soap, hypochlorite liquor and sodium bicarbonate and thereafter, before the soap has been rinsed out, subjecting the goods to an ammonium salt in which the ammonium group is combined with a reducing acid and which will function as an antichlor for the chlorine and hypochlorites and will not decompose soap and which will modify the alkali to a less alkaline product.
6. In laundering the method which includes subjecting the goods to a bath containing soap, hypochlorite lirgleor and sodium fore the soap has been rinsed out subjecting the goods to an ammonium salt in which the ammonium group is combined with a reducing acid containing sulfur and oxygen.
In witness whereof, I have hereunto signed my name.
- ROBERT A. PHAIR.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US742268A US1777858A (en) | 1924-10-07 | 1924-10-07 | Laundering method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US742268A US1777858A (en) | 1924-10-07 | 1924-10-07 | Laundering method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1777858A true US1777858A (en) | 1930-10-07 |
Family
ID=24984149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US742268A Expired - Lifetime US1777858A (en) | 1924-10-07 | 1924-10-07 | Laundering method |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1777858A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2733120A (en) * | 1953-10-12 | 1956-01-31 | Ouakum kuuivi | |
| US2753241A (en) * | 1953-12-23 | 1956-07-03 | Olin Mathieson | Process of laundering using hth and composition therefor |
| US3900284A (en) * | 1973-06-21 | 1975-08-19 | Basf Wyandotte Corp | Process for the removal of silver nitrate stains |
| US20110107527A1 (en) * | 2009-11-11 | 2011-05-12 | De Buzzaccarini Francesco | Cleaning method |
| US20120048307A1 (en) * | 2010-08-25 | 2012-03-01 | Ecolab Usa Inc. | Method and system for dispensing incompatible products |
-
1924
- 1924-10-07 US US742268A patent/US1777858A/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2733120A (en) * | 1953-10-12 | 1956-01-31 | Ouakum kuuivi | |
| US2753241A (en) * | 1953-12-23 | 1956-07-03 | Olin Mathieson | Process of laundering using hth and composition therefor |
| US3900284A (en) * | 1973-06-21 | 1975-08-19 | Basf Wyandotte Corp | Process for the removal of silver nitrate stains |
| US20110107527A1 (en) * | 2009-11-11 | 2011-05-12 | De Buzzaccarini Francesco | Cleaning method |
| US8449626B2 (en) * | 2009-11-11 | 2013-05-28 | The Procter & Gamble Company | Cleaning method |
| US20120048307A1 (en) * | 2010-08-25 | 2012-03-01 | Ecolab Usa Inc. | Method and system for dispensing incompatible products |
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