US1748949A - Transparent sheet - Google Patents
Transparent sheet Download PDFInfo
- Publication number
- US1748949A US1748949A US253794A US25379428A US1748949A US 1748949 A US1748949 A US 1748949A US 253794 A US253794 A US 253794A US 25379428 A US25379428 A US 25379428A US 1748949 A US1748949 A US 1748949A
- Authority
- US
- United States
- Prior art keywords
- cellulose nitrate
- coating
- transparent sheet
- film
- transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000020 Nitrocellulose Substances 0.000 description 11
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 11
- 229920001220 nitrocellulos Polymers 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000004359 castor oil Substances 0.000 description 6
- 235000019438 castor oil Nutrition 0.000 description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 6
- 235000018102 proteins Nutrition 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 102000004169 proteins and genes Human genes 0.000 description 5
- 108010010803 Gelatin Proteins 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000009975 flexible effect Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- KOWWOODYPWDWOJ-LVBPXUMQSA-N elatine Chemical compound C([C@]12CN(C3[C@@]45OCO[C@]44[C@H]6[C@@H](OC)[C@@H]([C@H](C4)OC)C[C@H]6[C@@]3([C@@H]1[C@@H]5OC)[C@@H](OC)CC2)CC)OC(=O)C1=CC=CC=C1N1C(=O)CC(C)C1=O KOWWOODYPWDWOJ-LVBPXUMQSA-N 0.000 description 1
- 108010025899 gelatin film Proteins 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2389/00—Characterised by the use of proteins; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31768—Natural source-type polyamide [e.g., casein, gelatin, etc.]
- Y10T428/31772—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31844—Of natural gum, rosin, natural oil or lac
Definitions
- the object of my present invention is to provide 'a' thin, fle xible, and durable tissue which shall be non-porous and impervious .to dust and moisture, of low combustibility, highly transparent, cheap to manufacture,
- a solution containing cellulose nitrate as its chief ingredientf -This coating solution? may be prepared by 'first' dissolving .the cellulose nitrate in a suitable solvent such as ethyl acetate, amyl acetate, ether, etc.,
- the coating solution can be applied to the base film or sheet in any suitable way, as by di ping the base sheet in, or drawing it th ough, a body of the coating solution, or by flowing the latter over, or brushing it on, the base sheet.
- the resultant product is a tough flexible, transparent sheet of greater strength" for the same thickness than either gelatin or gun cotton alone, less combustible than ordinary paper, non-porousand impervious to dust, grease and moisture and thus excellently adapted to serve the purpose of a sanitary wrapper "or container, especially for food products, medicines, and the like, and low in ,cost of materials and manufacture. And while I have found that the materials-best adapted to.
- I'claim- I 1 An integral transparent'wrapping sheet of the character described consisting of a thin filmof gelatin as a base, a'coating of cellulose nitrate having castor oil incorporated therein applied to each faceof said gelatin film, the castor oil functioning as anon-hygroscopic bonding agent and causing the cellulose nitrate coatin to become integrally united with the gelatin m on each" side thereof, said re sultant wrapping sheet being tough, pliable transparent, moisture, grease and water proof and being adapted to readilyconform to the "shape of packages and the like without cracking or separating.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Wrappers (AREA)
- Laminated Bodies (AREA)
Description
handle.
Patented Mar. 4, 1930 UN 'r-EDsTATEs PATENT OFFICE.
mime GEN'rILE, or cnrcaeo, rumors, ASSIGNOR or ONE-HALF 'ro SAMU L w. wars, A m onn roun'rn' 'IQ eaoaea PICK, BOTH or cnrcaeo, ILLINOIS mnsraann'r seam Ho Drawing. I
this material such' filmsbreak or tear easily and soon soften and disintegrate, especially m in damp climates; Films made of cellulose nitrate, or gun cotton, have also been known, but owing tothe high combustibility ofthis material, it is more The object of my present invention is to provide 'a' thin, fle xible, and durable tissue which shall be non-porous and impervious .to dust and moisture, of low combustibility, highly transparent, cheap to manufacture,
- and amply strong to serve the purpose of a.
v wrapper, seal, or container for food and other products under all climatic and atmospheric conditions. I
In carrying out my invention, I start with a thin filmor sheetof a protein substance such as elatin, casein or albumen, all 0 which su%stances are capable of being prepared in the form of a thin transparent film,
and I then coat this film, preferably on both sides, with a solution containing cellulose nitrate as its chief ingredientf -This coating solution? may be prepared by 'first' dissolving .the cellulose nitrate in a suitable solvent such as ethyl acetate, amyl acetate, ether, etc.,
which yields a thick or viscous product, and
then- .thinning-the tter to .a freely flowing state by the additio of a suitable-amount of alcohol. To this cellulose nitrate solution is then added a non-hygroscopic material which 40 renders the same soft and pliable, vwhen dry,
- andalso causes it to adhere evenly and uniforml to the gelatin or other protein film; the 'su stance whichI have found best adapted to this purpose beingcastor oil. For practical purposes proportions of 40% to 60% of -ping films or sheets ofgelatin have heretofore or less dangerous to limit the invention, in its broadest aspect, to
Application flled February 11, 1928. Serial masawaz.
castor oil, by wei ht, of the dried coating of a cellulose nitrate lxas proven to be satisfactory. n
The coating solution can be applied to the base film or sheet in any suitable way, as by di ping the base sheet in, or drawing it th ough, a body of the coating solution, or by flowing the latter over, or brushing it on, the base sheet. When the coating or covering has dried, the resultant product is a tough flexible, transparent sheet of greater strength" for the same thickness than either gelatin or gun cotton alone, less combustible than ordinary paper, non-porousand impervious to dust, grease and moisture and thus excellently adapted to serve the purpose of a sanitary wrapper "or container, especially for food products, medicines, and the like, and low in ,cost of materials and manufacture. And while I have found that the materials-best adapted to. serve all the purposes and characteristics of the invention are gelatinfor the base film, and cellulose nitrate admixed with castor oil for the coating or covering, I do not 0 all of these substances, but may employ such equivalents as are adapted to yield a product having the qualities'and characteristics hereinabove. described. I
I'claim- I 1. An integral transparent'wrapping sheet of the character described consisting of a thin filmof gelatin as a base, a'coating of cellulose nitrate having castor oil incorporated therein applied to each faceof said gelatin film, the castor oil functioning as anon-hygroscopic bonding agent and causing the cellulose nitrate coatin to become integrally united with the gelatin m on each" side thereof, said re sultant wrapping sheet being tough, pliable transparent, moisture, grease and water proof and being adapted to readilyconform to the "shape of packages and the like without cracking or separating.
of the character described consisting of a thin protein film as a base, a coating of cellulose nitrate having castor oil incorporated therein applied to each face of said protein film,'the castor oil functioning as a non-hygroscopic bonding agent and causing the cel- .lulose nitrate coating to become integrally united with the protein film on each side thereof, said resultant wrapping sheet being tough pliable, transparent, m0isture, grease and Water proof and being adapted to readil conform to the shape of packages and the lie Without cracking or separating.
' MARINO GENTILE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US253794A US1748949A (en) | 1928-02-11 | 1928-02-11 | Transparent sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US253794A US1748949A (en) | 1928-02-11 | 1928-02-11 | Transparent sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1748949A true US1748949A (en) | 1930-03-04 |
Family
ID=22961728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US253794A Expired - Lifetime US1748949A (en) | 1928-02-11 | 1928-02-11 | Transparent sheet |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1748949A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2430885A (en) * | 1944-05-12 | 1947-11-18 | Chemprotin Products | Gliadin suspensions and films |
-
1928
- 1928-02-11 US US253794A patent/US1748949A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2430885A (en) * | 1944-05-12 | 1947-11-18 | Chemprotin Products | Gliadin suspensions and films |
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