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US1748949A - Transparent sheet - Google Patents

Transparent sheet Download PDF

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Publication number
US1748949A
US1748949A US253794A US25379428A US1748949A US 1748949 A US1748949 A US 1748949A US 253794 A US253794 A US 253794A US 25379428 A US25379428 A US 25379428A US 1748949 A US1748949 A US 1748949A
Authority
US
United States
Prior art keywords
cellulose nitrate
coating
transparent sheet
film
transparent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US253794A
Inventor
Gentile Marino
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEORGE PICK
SAMUEL W WEIS
Original Assignee
GEORGE PICK
SAMUEL W WEIS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GEORGE PICK, SAMUEL W WEIS filed Critical GEORGE PICK
Priority to US253794A priority Critical patent/US1748949A/en
Application granted granted Critical
Publication of US1748949A publication Critical patent/US1748949A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2389/00Characterised by the use of proteins; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2401/00Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31725Of polyamide
    • Y10T428/31768Natural source-type polyamide [e.g., casein, gelatin, etc.]
    • Y10T428/31772Next to cellulosic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31844Of natural gum, rosin, natural oil or lac

Definitions

  • the object of my present invention is to provide 'a' thin, fle xible, and durable tissue which shall be non-porous and impervious .to dust and moisture, of low combustibility, highly transparent, cheap to manufacture,
  • a solution containing cellulose nitrate as its chief ingredientf -This coating solution? may be prepared by 'first' dissolving .the cellulose nitrate in a suitable solvent such as ethyl acetate, amyl acetate, ether, etc.,
  • the coating solution can be applied to the base film or sheet in any suitable way, as by di ping the base sheet in, or drawing it th ough, a body of the coating solution, or by flowing the latter over, or brushing it on, the base sheet.
  • the resultant product is a tough flexible, transparent sheet of greater strength" for the same thickness than either gelatin or gun cotton alone, less combustible than ordinary paper, non-porousand impervious to dust, grease and moisture and thus excellently adapted to serve the purpose of a sanitary wrapper "or container, especially for food products, medicines, and the like, and low in ,cost of materials and manufacture. And while I have found that the materials-best adapted to.
  • I'claim- I 1 An integral transparent'wrapping sheet of the character described consisting of a thin filmof gelatin as a base, a'coating of cellulose nitrate having castor oil incorporated therein applied to each faceof said gelatin film, the castor oil functioning as anon-hygroscopic bonding agent and causing the cellulose nitrate coatin to become integrally united with the gelatin m on each" side thereof, said re sultant wrapping sheet being tough, pliable transparent, moisture, grease and water proof and being adapted to readilyconform to the "shape of packages and the like without cracking or separating.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Wrappers (AREA)
  • Laminated Bodies (AREA)

Description

handle.
Patented Mar. 4, 1930 UN 'r-EDsTATEs PATENT OFFICE.
mime GEN'rILE, or cnrcaeo, rumors, ASSIGNOR or ONE-HALF 'ro SAMU L w. wars, A m onn roun'rn' 'IQ eaoaea PICK, BOTH or cnrcaeo, ILLINOIS mnsraann'r seam Ho Drawing. I
this material such' filmsbreak or tear easily and soon soften and disintegrate, especially m in damp climates; Films made of cellulose nitrate, or gun cotton, have also been known, but owing tothe high combustibility ofthis material, it is more The object of my present invention is to provide 'a' thin, fle xible, and durable tissue which shall be non-porous and impervious .to dust and moisture, of low combustibility, highly transparent, cheap to manufacture,
- and amply strong to serve the purpose of a.
v wrapper, seal, or container for food and other products under all climatic and atmospheric conditions. I
In carrying out my invention, I start with a thin filmor sheetof a protein substance such as elatin, casein or albumen, all 0 which su%stances are capable of being prepared in the form of a thin transparent film,
and I then coat this film, preferably on both sides, with a solution containing cellulose nitrate as its chief ingredientf -This coating solution? may be prepared by 'first' dissolving .the cellulose nitrate in a suitable solvent such as ethyl acetate, amyl acetate, ether, etc.,
which yields a thick or viscous product, and
then- .thinning-the tter to .a freely flowing state by the additio of a suitable-amount of alcohol. To this cellulose nitrate solution is then added a non-hygroscopic material which 40 renders the same soft and pliable, vwhen dry,
- andalso causes it to adhere evenly and uniforml to the gelatin or other protein film; the 'su stance whichI have found best adapted to this purpose beingcastor oil. For practical purposes proportions of 40% to 60% of -ping films or sheets ofgelatin have heretofore or less dangerous to limit the invention, in its broadest aspect, to
Application flled February 11, 1928. Serial masawaz.
castor oil, by wei ht, of the dried coating of a cellulose nitrate lxas proven to be satisfactory. n
The coating solution can be applied to the base film or sheet in any suitable way, as by di ping the base sheet in, or drawing it th ough, a body of the coating solution, or by flowing the latter over, or brushing it on, the base sheet. When the coating or covering has dried, the resultant product is a tough flexible, transparent sheet of greater strength" for the same thickness than either gelatin or gun cotton alone, less combustible than ordinary paper, non-porousand impervious to dust, grease and moisture and thus excellently adapted to serve the purpose of a sanitary wrapper "or container, especially for food products, medicines, and the like, and low in ,cost of materials and manufacture. And while I have found that the materials-best adapted to. serve all the purposes and characteristics of the invention are gelatinfor the base film, and cellulose nitrate admixed with castor oil for the coating or covering, I do not 0 all of these substances, but may employ such equivalents as are adapted to yield a product having the qualities'and characteristics hereinabove. described. I
I'claim- I 1. An integral transparent'wrapping sheet of the character described consisting of a thin filmof gelatin as a base, a'coating of cellulose nitrate having castor oil incorporated therein applied to each faceof said gelatin film, the castor oil functioning as anon-hygroscopic bonding agent and causing the cellulose nitrate coatin to become integrally united with the gelatin m on each" side thereof, said re sultant wrapping sheet being tough, pliable transparent, moisture, grease and water proof and being adapted to readilyconform to the "shape of packages and the like without cracking or separating.
of the character described consisting of a thin protein film as a base, a coating of cellulose nitrate having castor oil incorporated therein applied to each face of said protein film,'the castor oil functioning as a non-hygroscopic bonding agent and causing the cel- .lulose nitrate coating to become integrally united with the protein film on each side thereof, said resultant wrapping sheet being tough pliable, transparent, m0isture, grease and Water proof and being adapted to readil conform to the shape of packages and the lie Without cracking or separating.
' MARINO GENTILE.
US253794A 1928-02-11 1928-02-11 Transparent sheet Expired - Lifetime US1748949A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US253794A US1748949A (en) 1928-02-11 1928-02-11 Transparent sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US253794A US1748949A (en) 1928-02-11 1928-02-11 Transparent sheet

Publications (1)

Publication Number Publication Date
US1748949A true US1748949A (en) 1930-03-04

Family

ID=22961728

Family Applications (1)

Application Number Title Priority Date Filing Date
US253794A Expired - Lifetime US1748949A (en) 1928-02-11 1928-02-11 Transparent sheet

Country Status (1)

Country Link
US (1) US1748949A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2430885A (en) * 1944-05-12 1947-11-18 Chemprotin Products Gliadin suspensions and films

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2430885A (en) * 1944-05-12 1947-11-18 Chemprotin Products Gliadin suspensions and films

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