US1622576A - Alloy - Google Patents
Alloy Download PDFInfo
- Publication number
- US1622576A US1622576A US124105A US12410526A US1622576A US 1622576 A US1622576 A US 1622576A US 124105 A US124105 A US 124105A US 12410526 A US12410526 A US 12410526A US 1622576 A US1622576 A US 1622576A
- Authority
- US
- United States
- Prior art keywords
- alloy
- chill
- depth
- mix
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title description 16
- 239000000956 alloy Substances 0.000 title description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 229910052717 sulfur Inorganic materials 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- 238000005266 casting Methods 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 239000011733 molybdenum Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- 241000282887 Suidae Species 0.000 description 2
- -1 hosphorus Chemical compound 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZTPQLYJGPLYBPS-UHFFFAOYSA-N phosphanylidynechromium Chemical compound [Cr]#P ZTPQLYJGPLYBPS-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000013641 positive control Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
Definitions
- This invention relates to an alloy of iron, ordinarily used for this purpose several the main constituents of which are iron, times. silicon, sulfur, hosphorus, manganese, car-
- the depth of the chill on castings formed 1 bon, and molybdbnum, with or without small from this alloy is readily controlled by varyquantities of either nickel or chromium or ing the sulfur content and by varying the both. heat'at which the metal is poured.
- the molybdenum may be added to the great strength and a very hard chill surface, mix as molybdenum scrap, as ferro-molyb also that the chill depth may be readily condenum, or as calcium molybdate, and is 10 trolled b the operator, either in a sand or preferably added after the other metals of I chill mo (1. the mix have .melted and just long enough
- This alloy may be used for making all before tapping the heat to permit of it becommercial castings requiring hardness and coming thoroughly diffused throughout the tensile strength, such as rolling mill guides, bath.
- the nickel and chromium serve to increase Heretofore, in casting iron alloys the chill the tensile I strength and toughness of the depth has been uncontrollable, except by the alloy and may be omitted for some purposes, use of chill pieces or chill molds, and even however, when makin rolling mill rolls then has been more or less of an uncertain chromium will prefera ly be used and in 20 matter, while the present alloy permits of some cases nickel will also be used although positive control of the chill depth at all the nickel is not essential. times.
- the invention consists in an ing method is carried out i alloy containing the elements and the per A cupola or other smelting furnace is first 25 centages thereof, follow1ngcharged with suitable scrap, pigs, or ores, of so Per cent. the proper analysis to produce the proper Silicon .75to1.50 proportion of silicon, sulfur, hosphorus, Sulfur ,05 to .35 manganese, and carbon, and if chromium Phosphorus .25 to .7 5 or nickel are to be included in the alloy, suit- Manganese .20to .70 able pigs or scrap containing these ingre- Carbon 2.00to3.75 batters are also added.
- the mix is Nickel .05 to .25 made up it is heated to from 2500 to 2700 Chromium .15 to .25 degrees Fahrenheit to melt the metals. That Molybdenum .10 to .30 is, the mix is raised to a heat materially 35 Iron sufiicient to make 100%. above the melting temperature in order to obtain a good pouring temperature.
- Mol bdenum also raises After the mix is melted it is tapped and 0 the ratio of the elastic, imit to the ultimate then poured into the molds at a temperature strength of the metal'and benefits the dueof from 2300. degrees to 2500 degrees Fahtility. renheit.
- the sulfur content is known and when it is slightly higher or lower than necessary to produce the correct depth of chill, the pouring temperature may be increased or lowered accordingly to give the correct depth of chill.
- I claim- A ferrous metal alloy'primarily suited for the making of castings having a hard chilled surface such as rolling mill rolls, and capable of forming a controllable chill in a sand mold without the use of chills, said alloy containing the following elements in substantially the following proportions- Per cent. Silicon 75 to 1. 50 Sulfur 05 to .35 Phosphorus 25 t 7 Manganese to 7 0 Carbon 2. 00 to 3.75 Nickel ..05 to .25 Chromium 15 to Molybdenum 10 to Iron approximately suflicient to complete In testimony whereof, I have hereunto signed my name.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Continuous Casting (AREA)
Description
5o alloy aside from its great strength, is its is controlled primaril by the pouring tem- 1 was a... 29,1921. 1,622,576
UNITED. sra'res PATENT OFFICE.
JOHN 1v. EARLY, or PITTSBURGH, PENNSYLVANIA.
ALLOY.
Ho Drawing. Application filed July 21, 1926. Serial No. 124,105.
This invention relates to an alloy of iron, ordinarily used for this purpose several the main constituents of which are iron, times. silicon, sulfur, hosphorus, manganese, car- The depth of the chill on castings formed 1 bon, and molybdbnum, with or without small from this alloy is readily controlled by varyquantities of either nickel or chromium or ing the sulfur content and by varying the both. heat'at which the metal is poured.
-This alloy is characterized by having The molybdenum may be added to the great strength and a very hard chill surface, mix as molybdenum scrap, as ferro-molyb also that the chill depth may be readily condenum, or as calcium molybdate, and is 10 trolled b the operator, either in a sand or preferably added after the other metals of I chill mo (1. the mix have .melted and just long enough This alloy may be used for making all before tapping the heat to permit of it becommercial castings requiring hardness and coming thoroughly diffused throughout the tensile strength, such as rolling mill guides, bath.
15 rolling mill rolls, crusher rolls, and the like. The nickel and chromium serve to increase Heretofore, in casting iron alloys the chill the tensile I strength and toughness of the depth has been uncontrollable, except by the alloy and may be omitted for some purposes, use of chill pieces or chill molds, and even however, when makin rolling mill rolls then has been more or less of an uncertain chromium will prefera ly be used and in 20 matter, while the present alloy permits of some cases nickel will also be used although positive control of the chill depth at all the nickel is not essential. times. In producingthis novel alloy, the follow- Generically, the invention consists in an ing method is carried out i alloy containing the elements and the per A cupola or other smelting furnace is first 25 centages thereof, follow1ngcharged with suitable scrap, pigs, or ores, of so Per cent. the proper analysis to produce the proper Silicon .75to1.50 proportion of silicon, sulfur, hosphorus, Sulfur ,05 to .35 manganese, and carbon, and if chromium Phosphorus .25 to .7 5 or nickel are to be included in the alloy, suit- Manganese .20to .70 able pigs or scrap containing these ingre- Carbon 2.00to3.75 dients are also added. After the mix is Nickel .05 to .25 made up it is heated to from 2500 to 2700 Chromium .15 to .25 degrees Fahrenheit to melt the metals. That Molybdenum .10 to .30 is, the mix is raised to a heat materially 35 Iron sufiicient to make 100%. above the melting temperature in order to obtain a good pouring temperature. The
Castings made from this alloy show remolybdenum is preferably added after the =markable results in tensile-strength and in mix is melted down and just long enough wearing quality, and in v the resistance to before tapping the heat to permit it to be- 40 the action of heat. come thoroughly diffused throughout the The molybdenum increases the tensile bath, although the molybdenum may be strength of the alloy 1 and the high sulfur added at any time during the melting operacontent causes a greater amount of the cartion or as scrap when making up the mix if bon to become combined than would otherdesired. a 45 wise be the case. Mol bdenum also raises After the mix is melted it is tapped and 0 the ratio of the elastic, imit to the ultimate then poured into the molds at a temperature strength of the metal'and benefits the dueof from 2300. degrees to 2500 degrees Fahtility. renheit.
The most notable characteristic of this The depth of chill on the finished casting abihty to chill in either a sand or chill mold, perature. That is, t e holler the pouring and the ease with which the operator can temperature the deeperwill be the chill; also I control the depth of chill. the depth of chill can be controlled some- When rolls are formed from this alloy they what by the sulfur content of the mix, that 66 will outwear ordinary rolls made from alloys is, the greater the sulfur content the greater ranges, 10
I the chill. However, the sulfur content is known and when it is slightly higher or lower than necessary to produce the correct depth of chill, the pouring temperature may be increased or lowered accordingly to give the correct depth of chill.
While I have described certain specific combinations of elements within certain it will be understood that I do not wish to be limited thereto beyond the express limits of the appended claim which is meant to cover various modifications and equivalents as may be readily practiced by those skilled in the art to which this inveni tion belongs, i
I claim- A ferrous metal alloy'primarily suited for the making of castings having a hard chilled surface such as rolling mill rolls, and capable of forming a controllable chill in a sand mold without the use of chills, said alloy containing the following elements in substantially the following proportions- Per cent. Silicon 75 to 1. 50 Sulfur 05 to .35 Phosphorus 25 t 7 Manganese to 7 0 Carbon 2. 00 to 3.75 Nickel ..05 to .25 Chromium 15 to Molybdenum 10 to Iron approximately suflicient to complete In testimony whereof, I have hereunto signed my name.
JOHN N. EARLY.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US124105A US1622576A (en) | 1926-07-21 | 1926-07-21 | Alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US124105A US1622576A (en) | 1926-07-21 | 1926-07-21 | Alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1622576A true US1622576A (en) | 1927-03-29 |
Family
ID=22412806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US124105A Expired - Lifetime US1622576A (en) | 1926-07-21 | 1926-07-21 | Alloy |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1622576A (en) |
-
1926
- 1926-07-21 US US124105A patent/US1622576A/en not_active Expired - Lifetime
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