US1689426A - Differential colored fabric and method of making same - Google Patents
Differential colored fabric and method of making same Download PDFInfo
- Publication number
- US1689426A US1689426A US212832A US21283227A US1689426A US 1689426 A US1689426 A US 1689426A US 212832 A US212832 A US 212832A US 21283227 A US21283227 A US 21283227A US 1689426 A US1689426 A US 1689426A
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- US
- United States
- Prior art keywords
- cellulose
- fabric
- design
- color
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title description 70
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920002678 cellulose Polymers 0.000 description 97
- 239000001913 cellulose Substances 0.000 description 96
- 235000010980 cellulose Nutrition 0.000 description 96
- 239000000463 material Substances 0.000 description 68
- 239000000975 dye Substances 0.000 description 39
- 239000000243 solution Substances 0.000 description 27
- 229920002301 cellulose acetate Polymers 0.000 description 21
- 229920000742 Cotton Polymers 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 238000004043 dyeing Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- 239000003086 colorant Substances 0.000 description 6
- 210000002268 wool Anatomy 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 108010010803 Gelatin Proteins 0.000 description 4
- 239000005018 casein Substances 0.000 description 4
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 4
- 235000021240 caseins Nutrition 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 239000010446 mirabilite Substances 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 2
- 229920001727 cellulose butyrate Polymers 0.000 description 2
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 229920003087 methylethyl cellulose Polymers 0.000 description 2
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 2
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000139306 Platt Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000009699 differential effect Effects 0.000 description 1
- SUXCALIDMIIJCK-UHFFFAOYSA-L disodium;4-amino-3-[[4-[4-[(1-amino-4-sulfonatonaphthalen-2-yl)diazenyl]-3-methylphenyl]-2-methylphenyl]diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(N=NC3=CC=C(C=C3C)C=3C=C(C(=CC=3)N=NC=3C(=C4C=CC=CC4=C(C=3)S([O-])(=O)=O)N)C)=CC(S([O-])(=O)=O)=C21 SUXCALIDMIIJCK-UHFFFAOYSA-L 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002895 organic esters Chemical class 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- RTMDXOMALVABDU-UHFFFAOYSA-M sodium 4-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-1-olate Chemical compound [Na+].Oc1ccc(N=Nc2ccc(c3ccccc23)S([O-])(=O)=O)c2ccccc12 RTMDXOMALVABDU-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0096—Multicolour dyeing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/40—Cellulose acetate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/921—Cellulose ester or ether
Definitions
- Io mun This invention relates to fabric having a design thereon which design is due to the difference of the effects of dyes upon the material of which the fabric is com osed and the material with which the fabric is printed.
- An object of our invention is to provide a fabric having a design thereon, which deslgn is not made by the ordinary process of printing by means of dyes or other colors, but which is obtained by the differential dyeing of the fabric due to the printing or the application by other means of material upon such fabric, which material is affected by dyes in a manner different from the material of which the fabric is composed.
- Another object of our invention is to'providea fabric which is cross-dyed, wherein color effect or design produced is independent of the weave but which may be produced in any desired configuration.
- Another object of our invention is to roduce a design by cross-dyeing upon a fa ric composed at least in art of an orgamc derivative of cellulose aving a design of cellulose rinted thereon.
- cellulose whether natural cellulose such as cotton, or reconstituted cellulose such as is obtained from viscose, reacts in a different manner from cellulose acetate silk, natural silk or wool towards many dyes, or that differential effects may be obtained b dyeing a mixture of cellulose and these fibres in one bath containing a dye or mixture of dyes. This principle is used commonly in cross-dyeing.
- the fabric to be treated may be made entirely of an organic derivative of cellulose, such as organic esters of cellulose or organic ethers of cellulose. Examples of organic Application filed August 18, 1927- Serlal No. 212,882.
- esters of cellulose that may be used are cellulose formate, cellulose acetate, cellulose propionate and cellulose butyrate.
- examples of cellulose ethers that may be used are methyl cellulose and ethyl cellulose.
- the fabrlc may be composed of a mixture of any of the above organic derivatives of cellulose with one or more other fibres such as natural silk, wool, cotton or reconstituted cellulose.
- the fabric to be treated may be com osed wholly of silk or wool or a mixture 0 these animal fibres.
- the fabric constituted as above set forth, is printed with a material whose behavior toward dyestuffs is different from that of organic derivative of cellulose, natural silk or wool.
- a material whose behavior toward dyestuffs is different from that of organic derivative of cellulose, natural silk or wool.
- materials used for thispurpose may be mentioned cellulose, gelatin or casein.
- the so printed fabric is then dyed in a differential dye bath.
- One mode of carrying out our invention is to print the fabric, constituted as above set forth, with one of the common solutions of cellulose used in making reconstituted cellulose artificual silk, such as a solution of cellulose xanthate (viscose) or a cuprammonium solution of cellulose.
- a solution of cellulose xanthate (viscose) or a cuprammonium solution of cellulose such as a solution of cellulose xanthate (viscose) or a cuprammonium solution of cellulose.
- the thickness or concentration of the cellulose solution to be used for printing may be varied in accordance with the type of fabric to be treated or the nature of the design desired.
- After the fabric has been printed with the cellulose solution it is permitted to dry if desired.
- the fabric is then treated to reconvert the cellulose compound of the print back to cellulose.
- the cellulose is reconstituted by immersing the fabric in a dilute aqueous solution of sulphuric acid.
- a solution of sodium acid sulfate, ora solution of sodium acid sulfate and sodium sulfate as the precipitating bath.
- the fabric now has a design of cellulose imprinted or impressed upon it.
- the fabric may now be washed and/or dried if desired. It is now ready for the dyeing treatment.
- the fabric which contains at least some fibres or yarns of one or more of the following substances, viz, organic derivative of cellulose, silk, wool, or some other fibre other than cellulose, and which has a design of cellulose imprinted thereon, is now placed in a dye bath which contains one or more" dyes which act differently towards the cellulose and the other material of which at least some of the fibres are composed.
- the dye may color cellulose and not color the other material, or it may color the cellulose more deeply than the other material. ()n the other hand the dye may color the other material and not color the cellulose or else color the other material more deeply than the cellulose.
- the dye bath may contain two or more dyes, one of which colors the other material and not the cellulose, while the other of which colors the cellulose but not the other material.
- the dye bath may contain two or more dyes, one of which colors the other material and not the cellulose, while the other of which colors the cellulose but not the other material.
- the cotton yarn will be dyed or remain undyed in the same manner as the cellulose of the print. This will give the double effect of ordinary cross-dyeing of mixed fabrics together with the effect of the cross-dyeing of the printed cellulose design.
- the fabric constituted as above set forth is printed with a solution of gelatin or a solution of casein, and then dyed.
- the parts of the fabric printed by the gelatin or casein are not affected by the dyes and thus differential color effects are obtained.
- the gelatin or casein is then washed off by appropriate treatment and the fabric is then finished in any appropriate manner.
- Glaubers salt (sodium sulfate) 30 The percentages given are based on the weight of the fabric treated.
- the background of the fabric is colored blue, while the design is of a greenish color due to the combined effects of the yellow color of the cellulose print and the blue of the cellulose fabric under the print.
- Example I I SRA blue IV CR cotton fast scarlet 4 BS (color index #327 Schultz-Julius #279) 0.5 Glaubers salt 30 The percentages given are based on the weight of the fabric treated.
- the background of the fabric is co ored blue While the design is of a greyish-purple due to the combination of the red color of the cellulose acetate print and the blue color of the cellulose acetate fabric under the print.
- a cellulose acetate satin is printed with cellulose in the maner set forth in Example I. Itis then immersed in a dye bath containing a dye which dyes cellulose brown but which does not affect the cellulose acetate. This dye bath is made up as follows:
- the background of the fabric is of the original natural color of the cellulose acetate silk (white) while the design is brown.
- a tricot knit cellulose acetate fabric is printed with cellulose in the manner set forth in Example I. It is now immersed in a dye bath containing a dye which colors cellulose red but which does not affect the cellulose acetate silk. This dye bath is made up as follows:
- ganic derivatives of cellulose may be used such as cellulose esters, e. g. cellulose formate, cellulose pro ionate or cellulose butyrate, or cellulose et ers e. g. methyl cellulose or ethyl cellulose.
- a fabric comprising yarn of a material other than cellulose having a design of cellulose material imprinted thereon.
- a fabric comprising yarn of an orgamc derivative of cellulose material having a design of cellulose material imprinted thereon.
- a fabric comprising yarn of cellulose acetate material having a design of cellulose material imprinted thereon.
- a fabric comprising yarn of a material other than cellulose having a design of cellulose material im rinted thereon said yarn having a color difi rent from said design of cellulose.
- a fabric comprising yarn of an organic derivative of cellulose material having a design imprinted thereon said yarn having a color different from said design of cellulose.
- a fabric comprising yarn of cellulose acetate material having a design of cellulose material imprinted thereon said yarn having a color different from said design of cellulose.
- a fabric comprising yarn of a material other than cellulose having a design of cellulose material imprinted thereon at least one of said materials being dyed b a dye that does not impart color to the ot er material.
- a fabric comprising yarn of cellulose acetate material having a design of cellulose material imprinted thereon at least one of said materials being dyed by a dye that does not impart color to the other material.
- a fabric comprising yarn of an organic derivative of cellulose material having a design of cellulose material imprinted thereon said organic derivative of cellulose material being dyed by a dye which does 'not substantially color. the cellulose and said cellulose being dyed by a dye which does not substantially color said organic derivative of cellu-' lose.
- a fabric comprising yarn of cellulose acetate material having a design of cellulose material imprinted thereon said cellulose acetate material being dyed 'bya dye which does not substantiall co or the cellulose and said cellulosebeing dg'ed b a d e which does not ap reciably color sai cel ulose acetate.
- process which comprises imprinting a design ofa solution of cel ulose material on a fabric comprisin yarn of a material other than cellulose an treating the so printed fabric with a solution adapted to reconstitute thecellulose material of the print.
- a process which comprises imprint' a desi of a solution of cellulose mater ifi on a abric com rising yarn of an organic derivative of celliilose material and treatin the so printed fabric with a solution ada ted to reconstitute the cellulose material oI the print.
- a process which comprises 1mprmtm a desi of a solution of cellulose materi on a abric comprising yarn of an organic derivative of cellulose material, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print and dyeing with a dye that does not dye said cellulose and said organic derivative of cellulose the same shade.
- a process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarn of cellulose acetate, treating the so printed fabric with a solution'adapted to reconstitute the cellulose material of the that does not dye said cellulose and said cellulose acetate the same shade.
- a process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarn of an organic derivative of cellulose, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print, and treating the fabric with a dye which colors one of the said materials but does not appreciably color the other material.
- a process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarnof cellulose acetate, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print and treating the fabric with a dye which colors one of the said materials but does not appreciably colorthe other material.
- a process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarn of an organic derivative of cellulose material, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print and treating in a bath containing a dye print and dyeing with a dye which dyes said organic derivative of cellulose but does not appreciably color said organic derivative of cellulose.
- a process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarn of cellulose acetate material, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print and treating in a bath containing a dye which dyes said 10 In testimony whereof,' they have hereunto 15 subscribed their names.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Coloring (AREA)
Description
Patented Oct. 30, 1928.
UNITED STATES PATENT OFFICE.-
OAMII|LE DBEYFUS, 01' NEW YORK, N. Y., AIhTD HERBERT PLATT, OI OUKBEBLAND,
HABYLAND, ASSIGNOBS TO CELANESE CORPORATION 01 AMERICA, A CORPORA- TION OF DELAWARE.
DII'i'EBENTIAL COLORED FABRIC AND METHOD OF MAKING- SAME.
Io mun This invention relates to fabric having a design thereon which design is due to the difference of the effects of dyes upon the material of which the fabric is com osed and the material with which the fabric is printed.
An object of our invention is to provide a fabric having a design thereon, which deslgn is not made by the ordinary process of printing by means of dyes or other colors, but which is obtained by the differential dyeing of the fabric due to the printing or the application by other means of material upon such fabric, which material is affected by dyes in a manner different from the material of which the fabric is composed.
Another object of our invention is to'providea fabric which is cross-dyed, wherein color effect or design produced is independent of the weave but which may be produced in any desired configuration.
Another object of our invention is to roduce a design by cross-dyeing upon a fa ric composed at least in art of an orgamc derivative of cellulose aving a design of cellulose rinted thereon.
Other 0 jects of our invention will appear from the following detailed description.
It is 'well known that cellulose, whether natural cellulose such as cotton, or reconstituted cellulose such as is obtained from viscose, reacts in a different manner from cellulose acetate silk, natural silk or wool towards many dyes, or that differential effects may be obtained b dyeing a mixture of cellulose and these fibres in one bath containing a dye or mixture of dyes. This principle is used commonly in cross-dyeing.
mixed fabrics made by weaving yarns of cotton and one of the above mentioned materials. Obviousl in this method, the differential color efihct depends entirely upon the nature of the weave. In accordance with our invention, cross-dyeing effects are obtained by making a deslgn of cellulose, irrespective of weaving, on a fabric which contains at least some yarn of a material other than cellulose, and then immersing the fabric in a bath containing one or more dyes having different coloring effects upon the cotton and the other material.
The fabric to be treated may be made entirely of an organic derivative of cellulose, such as organic esters of cellulose or organic ethers of cellulose. Examples of organic Application filed August 18, 1927- Serlal No. 212,882.
esters of cellulose that may be used are cellulose formate, cellulose acetate, cellulose propionate and cellulose butyrate. Examples of cellulose ethers that may be used are methyl cellulose and ethyl cellulose. Or the fabrlc may be composed of a mixture of any of the above organic derivatives of cellulose with one or more other fibres such as natural silk, wool, cotton or reconstituted cellulose. Furthermore the fabric to be treated may be com osed wholly of silk or wool or a mixture 0 these animal fibres.
The fabric, constituted as above set forth, is printed with a material whose behavior toward dyestuffs is different from that of organic derivative of cellulose, natural silk or wool. Among the materials used for thispurpose may be mentioned cellulose, gelatin or casein. The so printed fabric is then dyed in a differential dye bath.
' One mode of carrying out our invention is to print the fabric, constituted as above set forth, with one of the common solutions of cellulose used in making reconstituted cellulose artificual silk, such as a solution of cellulose xanthate (viscose) or a cuprammonium solution of cellulose. The thickness or concentration of the cellulose solution to be used for printing may be varied in accordance with the type of fabric to be treated or the nature of the design desired. After the fabric has been printed with the cellulose solution, it is permitted to dry if desired. The fabric is then treated to reconvert the cellulose compound of the print back to cellulose. For instance, if viscose has been used for printing, the cellulose is reconstituted by immersing the fabric in a dilute aqueous solution of sulphuric acid. Better results may be obtained by using a solution of sodium acid sulfate, ora solution of sodium acid sulfate and sodium sulfate as the precipitating bath. The fabric now has a design of cellulose imprinted or impressed upon it. The fabric may now be washed and/or dried if desired. It is now ready for the dyeing treatment.
The fabric, which contains at least some fibres or yarns of one or more of the following substances, viz, organic derivative of cellulose, silk, wool, or some other fibre other than cellulose, and which has a design of cellulose imprinted thereon, is now placed in a dye bath which contains one or more" dyes which act differently towards the cellulose and the other material of which at least some of the fibres are composed. Thus the dye may color cellulose and not color the other material, or it may color the cellulose more deeply than the other material. ()n the other hand the dye may color the other material and not color the cellulose or else color the other material more deeply than the cellulose. Again, the dye bath may contain two or more dyes, one of which colors the other material and not the cellulose, while the other of which colors the cellulose but not the other material. When using such mixtures of dyes, it will be seen that by immersion of the fabric so printed with cellulose in a single dye bath, a two-colored design may be produced. The fabric is then given the ordinary finishing treatment.
When the fabric treated according to the above process is made of mixed yarns containing cotton, such as mixed cellulose acetate and cotton, mixed natural silk and cotton, or mixed wool and cotton, the cotton yarn will be dyed or remain undyed in the same manner as the cellulose of the print. This will give the double effect of ordinary cross-dyeing of mixed fabrics together with the effect of the cross-dyeing of the printed cellulose design.
In another application of our invention, the fabric constituted as above set forth, is printed with a solution of gelatin or a solution of casein, and then dyed. The parts of the fabric printed by the gelatin or casein are not affected by the dyes and thus differential color effects are obtained. The gelatin or casein is then washed off by appropriate treatment and the fabric is then finished in any appropriate manner.
To further elucidate the mode of carrying out our invention, the following specific examples are given by way of illustration only:
Example I Per cent.
SRA blue IV 0.5 GB cotton fast yellow B (color index #842 Schultz-Julius #617) 1.0
Glaubers salt (sodium sulfate) 30 The percentages given are based on the weight of the fabric treated.
After finishing in the ordinary manner the background of the fabric is colored blue, while the design is of a greenish color due to the combined effects of the yellow color of the cellulose print and the blue of the cellulose fabric under the print.
Example I I SRA blue IV CR cotton fast scarlet 4 BS (color index #327 Schultz-Julius #279) 0.5 Glaubers salt 30 The percentages given are based on the weight of the fabric treated.
After finishing in the ordinar manner the background of the fabric is co ored blue While the design is of a greyish-purple due to the combination of the red color of the cellulose acetate print and the blue color of the cellulose acetate fabric under the print.
Example [11.
A cellulose acetate satin is printed with cellulose in the maner set forth in Example I. Itis then immersed in a dye bath containing a dye which dyes cellulose brown but which does not affect the cellulose acetate. This dye bath is made up as follows:
Per cent. CR cotton fast brown R (color index #597) Glaubers salt 30 The percentages given are based on the weight of'the fabric treated.
After finishing in the ordinary manner the background of the fabric is of the original natural color of the cellulose acetate silk (white) while the design is brown.
Ewample IV.
A tricot knit cellulose acetate fabric is printed with cellulose in the manner set forth in Example I. It is now immersed in a dye bath containing a dye which colors cellulose red but which does not affect the cellulose acetate silk. This dye bath is made up as follows:
Per cent.
Per cent OR cotton scarlet 4 BS 0.5 Glaubers salt 30 The percentages given are based on the weight of the fabric treated.
fill
invention. Instead of cellulose acetate, or-
ganic derivatives of cellulose may be used such as cellulose esters, e. g. cellulose formate, cellulose pro ionate or cellulose butyrate, or cellulose et ers e. g. methyl cellulose or ethyl cellulose.
Having described our invention what we claim and desire to secure by Letters Patent 1s 1. A fabric comprising yarn of a material other than cellulose having a design of cellulose material imprinted thereon.
2. A fabric comprising yarn of an orgamc derivative of cellulose material having a design of cellulose material imprinted thereon.
3. A fabric comprising yarn of cellulose acetate material having a design of cellulose material imprinted thereon.
4. A fabric comprising yarn of a material other than cellulose having a design of cellulose material im rinted thereon said yarn having a color difi rent from said design of cellulose.
5. A fabric comprising yarn of an organic derivative of cellulose material having a design imprinted thereon said yarn having a color different from said design of cellulose.
6. A fabric comprising yarn of cellulose acetate material having a design of cellulose material imprinted thereon said yarn having a color different from said design of cellulose.
7. A fabric comprising yarn of a material other than cellulose having a design of cellulose material imprinted thereon at least one of said materials being dyed b a dye that does not impart color to the ot er material.
8. A fabric comprising yarn of cellulose acetate material having a design of cellulose material imprinted thereon at least one of said materials being dyed by a dye that does not impart color to the other material.
9. A fabric comprising yarn of an organic derivative of cellulose material having a design of cellulose material imprinted thereon said organic derivative of cellulose material being dyed by a dye which does 'not substantially color. the cellulose and said cellulose being dyed by a dye which does not substantially color said organic derivative of cellu-' lose.
10. A fabric comprising yarn of cellulose acetate material having a design of cellulose material imprinted thereon said cellulose acetate material being dyed 'bya dye which does not substantiall co or the cellulose and said cellulosebeing dg'ed b a d e which does not ap reciably color sai cel ulose acetate. 1. process which comprises imprinting a design ofa solution of cel ulose material on a fabric comprisin yarn of a material other than cellulose an treating the so printed fabric with a solution adapted to reconstitute thecellulose material of the print.
12. A process which comprises imprint' a desi of a solution of cellulose mater ifi on a abric com rising yarn of an organic derivative of celliilose material and treatin the so printed fabric with a solution ada ted to reconstitute the cellulose material oI the print.
13. A process which com rises imprinting a design of a solution of celiillose material on a fabric comprising yarn of cellulose acetate material and treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print.
14. A process which comprises 1mprmtm a desi of a solution of cellulose materi on a abric comprising yarn of an organic derivative of cellulose material, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print and dyeing with a dye that does not dye said cellulose and said organic derivative of cellulose the same shade.
15. A process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarn of cellulose acetate, treating the so printed fabric with a solution'adapted to reconstitute the cellulose material of the that does not dye said cellulose and said cellulose acetate the same shade.
16. A process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarn of an organic derivative of cellulose, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print, and treating the fabric with a dye which colors one of the said materials but does not appreciably color the other material.
17. A process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarnof cellulose acetate, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print and treating the fabric with a dye which colors one of the said materials but does not appreciably colorthe other material.
18. A process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarn of an organic derivative of cellulose material, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print and treating in a bath containing a dye print and dyeing with a dye which dyes said organic derivative of cellulose but does not appreciably color said organic derivative of cellulose.
19. A process which comprises imprinting a design of a solution of cellulose material on a fabric comprising yarn of cellulose acetate material, treating the so printed fabric with a solution adapted to reconstitute the cellulose material of the print and treating in a bath containing a dye which dyes said 10 In testimony whereof,' they have hereunto 15 subscribed their names.
CAMILLE DREYFUS.
HERBERT PLATT.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US212832A US1689426A (en) | 1927-08-13 | 1927-08-13 | Differential colored fabric and method of making same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US212832A US1689426A (en) | 1927-08-13 | 1927-08-13 | Differential colored fabric and method of making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1689426A true US1689426A (en) | 1928-10-30 |
Family
ID=22792595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US212832A Expired - Lifetime US1689426A (en) | 1927-08-13 | 1927-08-13 | Differential colored fabric and method of making same |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1689426A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2526301A (en) * | 1949-02-11 | 1950-10-17 | United Merchants & Mfg | Composition and method for treating textile products |
| US8966832B1 (en) | 2014-04-11 | 2015-03-03 | Oscar T. Scott, IV | Mobile aboveground shelter with protected anchoring |
| US9982447B2 (en) | 2015-04-09 | 2018-05-29 | Red Dog Mobile Shelters, Llc | Mobile safety platform with integral transport |
-
1927
- 1927-08-13 US US212832A patent/US1689426A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2526301A (en) * | 1949-02-11 | 1950-10-17 | United Merchants & Mfg | Composition and method for treating textile products |
| US8966832B1 (en) | 2014-04-11 | 2015-03-03 | Oscar T. Scott, IV | Mobile aboveground shelter with protected anchoring |
| US9982447B2 (en) | 2015-04-09 | 2018-05-29 | Red Dog Mobile Shelters, Llc | Mobile safety platform with integral transport |
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