US1681499A - Etching solution - Google Patents
Etching solution Download PDFInfo
- Publication number
- US1681499A US1681499A US187412A US18741227A US1681499A US 1681499 A US1681499 A US 1681499A US 187412 A US187412 A US 187412A US 18741227 A US18741227 A US 18741227A US 1681499 A US1681499 A US 1681499A
- Authority
- US
- United States
- Prior art keywords
- solution
- etching solution
- ounce
- sulphate
- copper sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005530 etching Methods 0.000 title description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 235000002639 sodium chloride Nutrition 0.000 description 8
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 7
- 235000003891 ferrous sulphate Nutrition 0.000 description 6
- 239000011790 ferrous sulphate Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910001369 Brass Inorganic materials 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 239000010951 brass Substances 0.000 description 5
- 235000011167 hydrochloric acid Nutrition 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- 238000005034 decoration Methods 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241001275902 Parabramis pekinensis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/52—Treatment of copper or alloys based thereon
Definitions
- the invention is adapted for use in decorating various articles, particularly those which are cast or otherwise formed and produced of brass which, while due to the different compositions of various brasses, results in a decoration in which'the portions thereof differ both as to shade and outline.
- One formula whereby a solution capable of resulting in an action and formations such as those hereinbefore referred to includes copper sulphate, nitric acid, muriatic acid,
- ingredients when added to one gallon of water in the following proportions and left for substantially one-half day prior to use will, upon subjecting the article to the solution for about one-half hour, accomplish the above result: water, one gallon; copper sulphate, 2 ounces; nitric acid, one-fourth ounce; muriatic acid, one-fourth ounce; ferrous sulphate, one-fourth ounce; salt, onehalf pound.
- the copper sulphate, ferrous sulphate and the salt are employed to produce the different shades and tinge or color to the various decorative portions, for instance, the copper sulphate produces a blue tinge, the ferrous sulphate a green tinge, and the salt a lighter tinge. Therefore, it is obvious that these above ingredients may be varied or added to, to reduce or increase the number of colors which may result depending upon desire or necessity.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- ing And Chemical Polishing (AREA)
Description
Patented Aug. 21 1928 .PATEN T OFFICE.
JOHN W. SAUER, OF CHICAGO, ILLINOIS.
ETCHING SOLUTION.
No Drawing.
allof which will be more thoroughly understood from the following description, it being obvious that changes and modifications of the ingredients of the formula may be varied without departing from the scope of the appended claims forming a part hereof.
The invention is adapted for use in decorating various articles, particularly those which are cast or otherwise formed and produced of brass which, while due to the different compositions of various brasses, results in a decoration in which'the portions thereof differ both as to shade and outline.
hen brass of one character is subjected to the action of the solution for a certain period oftime, the decorations produced upon; the surface of the article resemble flat facets, which vary in shade, color and also shape and size, giving the article a mottled appearance, the facets being defined by straight lines, whereas when brass having different characteristics than that above referred to is subjected to the action of the solution, the outline of the decorative portions may be of a rounded character, which differ in shade relatively to each other and also, due to the difference in color of the brass, will present a different general appearance compared to that previously referred to. 3
One formula whereby a solution capable of resulting in an action and formations such as those hereinbefore referred to includes copper sulphate, nitric acid, muriatic acid,
' ferrous sulphate, and sodium chloride or salt in water, makinga bath in which the article to be decorated is immersed for a suitable period.
'Application filed April 28,
1927. Serial No. 187,412.
The ingredients when added to one gallon of water in the following proportions and left for substantially one-half day prior to use will, upon subjecting the article to the solution for about one-half hour, accomplish the above result: water, one gallon; copper sulphate, 2 ounces; nitric acid, one-fourth ounce; muriatic acid, one-fourth ounce; ferrous sulphate, one-fourth ounce; salt, onehalf pound.
' The copper sulphate, ferrous sulphate and the salt are employed to produce the different shades and tinge or color to the various decorative portions, for instance, the copper sulphate produces a blue tinge, the ferrous sulphate a green tinge, and the salt a lighter tinge. Therefore, it is obvious that these above ingredients may be varied or added to, to reduce or increase the number of colors which may result depending upon desire or necessity.
It is manifest that the action of the solution will vary, depending upon the particular consistency oricomposition of the brass, and will thus produce a variation of outline to the etched portions which will result in the production of different efiects.
Having thus described the invention, what I claim and desire to cover by Letters Patent 1. A solution of the character described acid, muriatic acid, ferrous sulphate, and sodium chloride.
2. A solution of the character described containing water, nitric acid, muriatic acid and ferrous sulphatein equal portions, copper sulphate, and sodium chloride.
3. A solution of the character described containing water, copper sulphate two ounces, nitric acid one-fourth ounce, muriatic acid one-fourth ounce, ferrous sulphate onefourth ounce, and sodium chloride one-half pound.
In witness whereof, I hereunto subscribe my name this 12th day of March A. D., 1927.
JOHN w. SAUER.
composed of water, copper sulphate. nitric
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US187412A US1681499A (en) | 1927-04-28 | 1927-04-28 | Etching solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US187412A US1681499A (en) | 1927-04-28 | 1927-04-28 | Etching solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1681499A true US1681499A (en) | 1928-08-21 |
Family
ID=22688868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US187412A Expired - Lifetime US1681499A (en) | 1927-04-28 | 1927-04-28 | Etching solution |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1681499A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2796335A (en) * | 1955-04-13 | 1957-06-18 | Aluminum Co Of America | Aluminum etching |
| US2796334A (en) * | 1955-02-23 | 1957-06-18 | Aluminum Co Of America | Etching aluminum |
-
1927
- 1927-04-28 US US187412A patent/US1681499A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2796334A (en) * | 1955-02-23 | 1957-06-18 | Aluminum Co Of America | Etching aluminum |
| US2796335A (en) * | 1955-04-13 | 1957-06-18 | Aluminum Co Of America | Aluminum etching |
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