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US1681499A - Etching solution - Google Patents

Etching solution Download PDF

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Publication number
US1681499A
US1681499A US187412A US18741227A US1681499A US 1681499 A US1681499 A US 1681499A US 187412 A US187412 A US 187412A US 18741227 A US18741227 A US 18741227A US 1681499 A US1681499 A US 1681499A
Authority
US
United States
Prior art keywords
solution
etching solution
ounce
sulphate
copper sulphate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US187412A
Inventor
John W Sauer
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Individual
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Individual
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Publication date
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Priority to US187412A priority Critical patent/US1681499A/en
Application granted granted Critical
Publication of US1681499A publication Critical patent/US1681499A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/52Treatment of copper or alloys based thereon

Definitions

  • the invention is adapted for use in decorating various articles, particularly those which are cast or otherwise formed and produced of brass which, while due to the different compositions of various brasses, results in a decoration in which'the portions thereof differ both as to shade and outline.
  • One formula whereby a solution capable of resulting in an action and formations such as those hereinbefore referred to includes copper sulphate, nitric acid, muriatic acid,
  • ingredients when added to one gallon of water in the following proportions and left for substantially one-half day prior to use will, upon subjecting the article to the solution for about one-half hour, accomplish the above result: water, one gallon; copper sulphate, 2 ounces; nitric acid, one-fourth ounce; muriatic acid, one-fourth ounce; ferrous sulphate, one-fourth ounce; salt, onehalf pound.
  • the copper sulphate, ferrous sulphate and the salt are employed to produce the different shades and tinge or color to the various decorative portions, for instance, the copper sulphate produces a blue tinge, the ferrous sulphate a green tinge, and the salt a lighter tinge. Therefore, it is obvious that these above ingredients may be varied or added to, to reduce or increase the number of colors which may result depending upon desire or necessity.

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • ing And Chemical Polishing (AREA)

Description

Patented Aug. 21 1928 .PATEN T OFFICE.
JOHN W. SAUER, OF CHICAGO, ILLINOIS.
ETCHING SOLUTION.
No Drawing.
allof which will be more thoroughly understood from the following description, it being obvious that changes and modifications of the ingredients of the formula may be varied without departing from the scope of the appended claims forming a part hereof.
The invention is adapted for use in decorating various articles, particularly those which are cast or otherwise formed and produced of brass which, while due to the different compositions of various brasses, results in a decoration in which'the portions thereof differ both as to shade and outline.
hen brass of one character is subjected to the action of the solution for a certain period oftime, the decorations produced upon; the surface of the article resemble flat facets, which vary in shade, color and also shape and size, giving the article a mottled appearance, the facets being defined by straight lines, whereas when brass having different characteristics than that above referred to is subjected to the action of the solution, the outline of the decorative portions may be of a rounded character, which differ in shade relatively to each other and also, due to the difference in color of the brass, will present a different general appearance compared to that previously referred to. 3
One formula whereby a solution capable of resulting in an action and formations such as those hereinbefore referred to includes copper sulphate, nitric acid, muriatic acid,
' ferrous sulphate, and sodium chloride or salt in water, makinga bath in which the article to be decorated is immersed for a suitable period.
'Application filed April 28,
1927. Serial No. 187,412.
The ingredients when added to one gallon of water in the following proportions and left for substantially one-half day prior to use will, upon subjecting the article to the solution for about one-half hour, accomplish the above result: water, one gallon; copper sulphate, 2 ounces; nitric acid, one-fourth ounce; muriatic acid, one-fourth ounce; ferrous sulphate, one-fourth ounce; salt, onehalf pound.
' The copper sulphate, ferrous sulphate and the salt are employed to produce the different shades and tinge or color to the various decorative portions, for instance, the copper sulphate produces a blue tinge, the ferrous sulphate a green tinge, and the salt a lighter tinge. Therefore, it is obvious that these above ingredients may be varied or added to, to reduce or increase the number of colors which may result depending upon desire or necessity.
It is manifest that the action of the solution will vary, depending upon the particular consistency oricomposition of the brass, and will thus produce a variation of outline to the etched portions which will result in the production of different efiects.
Having thus described the invention, what I claim and desire to cover by Letters Patent 1. A solution of the character described acid, muriatic acid, ferrous sulphate, and sodium chloride.
2. A solution of the character described containing water, nitric acid, muriatic acid and ferrous sulphatein equal portions, copper sulphate, and sodium chloride.
3. A solution of the character described containing water, copper sulphate two ounces, nitric acid one-fourth ounce, muriatic acid one-fourth ounce, ferrous sulphate onefourth ounce, and sodium chloride one-half pound.
In witness whereof, I hereunto subscribe my name this 12th day of March A. D., 1927.
JOHN w. SAUER.
composed of water, copper sulphate. nitric
US187412A 1927-04-28 1927-04-28 Etching solution Expired - Lifetime US1681499A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US187412A US1681499A (en) 1927-04-28 1927-04-28 Etching solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US187412A US1681499A (en) 1927-04-28 1927-04-28 Etching solution

Publications (1)

Publication Number Publication Date
US1681499A true US1681499A (en) 1928-08-21

Family

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Family Applications (1)

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US187412A Expired - Lifetime US1681499A (en) 1927-04-28 1927-04-28 Etching solution

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2796335A (en) * 1955-04-13 1957-06-18 Aluminum Co Of America Aluminum etching
US2796334A (en) * 1955-02-23 1957-06-18 Aluminum Co Of America Etching aluminum

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2796334A (en) * 1955-02-23 1957-06-18 Aluminum Co Of America Etching aluminum
US2796335A (en) * 1955-04-13 1957-06-18 Aluminum Co Of America Aluminum etching

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