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US1669151A - Art of refining oil - Google Patents

Art of refining oil Download PDF

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Publication number
US1669151A
US1669151A US575610A US57561022A US1669151A US 1669151 A US1669151 A US 1669151A US 575610 A US575610 A US 575610A US 57561022 A US57561022 A US 57561022A US 1669151 A US1669151 A US 1669151A
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United States
Prior art keywords
petrolatum
steam
art
oil
refining oil
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Expired - Lifetime
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US575610A
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Cary R Wagner
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Priority to US575610A priority Critical patent/US1669151A/en
Priority to US717091A priority patent/US1669180A/en
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Publication of US1669151A publication Critical patent/US1669151A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/02Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils
    • C10G73/06Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils with the use of solvents

Definitions

  • This invention relates to the separation of petrolatum or so-called amorphous wax from steam-reduced crude oils, cylinder stocks or similar vehicles containing petrolatum.
  • Such steam-refined crude oils or cylinder stocks are prepared by the fire and steam distillation of crude oils, for example, to a 15 to 25% bottom and, when prepared from mid-continent crude, ordinarily have a gravity of about to 22 Baum and a flash point of about 515 to 530 F. It will be readily apparent that the specific gravity and flash points of the stocks are not material to the practice of the resent invention.
  • an e ective separation of the petrolatum from such stocks may be efl'eoted by diluting the stock with a suitable proportion of an oil solvent in which petrolatum is materially less soluble than in naphtha, chilling the mixture to a suitable temperature and separating the wax by settling or by difi'erence in specific gravity.
  • I may admix with a suitable steam-refined oil or cylinder stock from 25 to 75% of methylethylketone butanone) and chill the resulting mixture y suitable refrigerating means to a temperature suitable for the production of an oil havin the cold test desired for the end product 0 the process.
  • the petrolatum present separates out and may be readily re- Application filed July 17,
  • I claim: 1. The method of se are-ting petrolatum from steam-refined stoc s which comprises diluting the stock with methylethylketone, chilling the diluted stock, and separating the petrolatum by difference of specific gravity.
  • the method of separating petrolatum from steam refined stocks which comprises diluting the stock with methylethylketone containing water not exceeding about 3%, chilling the diluted stock and permitting the petrolatum to settle out by difierence of specific gravity.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

Patented May 8, 1928.
PATENT OFFICE.
CART 3. WAGNER, OF WOODBIVEB, ILLINOIS.
ART OiE' REFINING OIL.
Io Drawing.
This invention relates to the separation of petrolatum or so-called amorphous wax from steam-reduced crude oils, cylinder stocks or similar vehicles containing petrolatum. Such steam-refined crude oils or cylinder stocks are prepared by the fire and steam distillation of crude oils, for example, to a 15 to 25% bottom and, when prepared from mid-continent crude, ordinarily have a gravity of about to 22 Baum and a flash point of about 515 to 530 F. It will be readily apparent that the specific gravity and flash points of the stocks are not material to the practice of the resent invention.
I have found that an e ective separation of the petrolatum from such stocks may be efl'eoted by diluting the stock with a suitable proportion of an oil solvent in which petrolatum is materially less soluble than in naphtha, chilling the mixture to a suitable temperature and separating the wax by settling or by difi'erence in specific gravity. For example, I may admix with a suitable steam-refined oil or cylinder stock from 25 to 75% of methylethylketone butanone) and chill the resulting mixture y suitable refrigerating means to a temperature suitable for the production of an oil havin the cold test desired for the end product 0 the process. Upon standing, the petrolatum present separates out and may be readily re- Application filed July 17,
1922. Serial I0. 575,810.
moved. The diluted oil ma then be subected to distillation, prefer-a 1y with steam, for removal of the methylethylketone resent, which may be recovered and reused I have found that when butanone or methylethylketone is employed as a diluent in the manner described for removing wax from steam-refined oils, at a given chilling temperature, a better se aration of wax an a lower cold test, pet-r0 atum-free oil is obtained than when naphtha is employed. I prefer to use methylethylketone WhlCh has not been perfectly dehydrated, as the presence of small amounts of water, say up to 3%, further decreases the solubility of the petrolatum therein.
I claim: 1. The method of se are-ting petrolatum from steam-refined stoc s which comprises diluting the stock with methylethylketone, chilling the diluted stock, and separating the petrolatum by difference of specific gravity.
-2. The method of separating petrolatum from steam refined stocks which comprises diluting the stock with methylethylketone containing water not exceeding about 3%, chilling the diluted stock and permitting the petrolatum to settle out by difierence of specific gravity.
our R. WAGNER.
US575610A 1922-07-17 1922-07-17 Art of refining oil Expired - Lifetime US1669151A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US575610A US1669151A (en) 1922-07-17 1922-07-17 Art of refining oil
US717091A US1669180A (en) 1922-07-17 1924-05-31 Art of refining oils

Applications Claiming Priority (1)

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US575610A US1669151A (en) 1922-07-17 1922-07-17 Art of refining oil

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US1669151A true US1669151A (en) 1928-05-08

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446514A (en) * 1944-09-16 1948-08-03 Shell Dev Separation of hydrocarbon mixtures
US2726988A (en) * 1952-09-08 1955-12-13 Exxon Research Engineering Co Solvent dewaxing process
US2742400A (en) * 1952-10-06 1956-04-17 Texaco Development Corp Method of refining oil with a selective solvent
US2743213A (en) * 1952-09-27 1956-04-24 Union Oil Co Wax deoiling process
US3239446A (en) * 1961-09-08 1966-03-08 British Petroleum Co Dewaxing of lubricating oils

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446514A (en) * 1944-09-16 1948-08-03 Shell Dev Separation of hydrocarbon mixtures
US2726988A (en) * 1952-09-08 1955-12-13 Exxon Research Engineering Co Solvent dewaxing process
US2743213A (en) * 1952-09-27 1956-04-24 Union Oil Co Wax deoiling process
US2742400A (en) * 1952-10-06 1956-04-17 Texaco Development Corp Method of refining oil with a selective solvent
US3239446A (en) * 1961-09-08 1966-03-08 British Petroleum Co Dewaxing of lubricating oils

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