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US1666523A - House electbic - Google Patents

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US1666523A
US1666523A US1666523DA US1666523A US 1666523 A US1666523 A US 1666523A US 1666523D A US1666523D A US 1666523DA US 1666523 A US1666523 A US 1666523A
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steam
turbine
corrosion
superheated
house
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00General layout or general methods of operation of complete plants
    • F01K13/02Controlling, e.g. stopping or starting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00General layout or general methods of operation of complete plants
    • F01K13/02Controlling, e.g. stopping or starting
    • F01K13/025Cooling the interior by injection during idling or stand-by

Definitions

  • This invention relates to means for reducing or preventing corrosion of turbine blad ing. It has been observed that the corrosion of the blading of steam turbines appears to be most severe in the region where mois ture is first formed and where the moisture content or wetness of the steam is comparatively low. The moisture content of the steam increases as it passes through the turbine towards the condenser and this is accompanied by a diminution of corrosion until in the last stages of expansion of the.
  • liquid in the form of a fine spray or atomized condition is injected into the steam which operates the turbine.
  • the liquid employed may either be Water. or an alkali which will dilute or neutralize the action of corrosive constituents, such as free oxygen or both water and a neutralizing solution may be separately injected in the steam path.
  • the steam gradually loses its superheat and becomes wet steam, the zone in which the change from superheated to wet steam takes place being indicated by b, while the zones of superheated and of wet steam are indicated by a and respectively.
  • I provide suitable nozzles 14, which are arranged to be supplied with a suitable inert liquid diluent from the manifold 16.
  • nozzles 14 which are arranged to be supplied with a suitable inert liquid diluent from the manifold 16.
  • I have shown a plurality of nozzles, it will be understood that only one may be used, and also that the nozzles need not be all disposed to discharge into the same stage as shown.
  • the nozzles are arranged to discharge into a stage of the turbine on the high pressure side of the zone of change 1) as shown.
  • the injection may take place either at that part of the steam path where moisture is first formed or a little earlier in the super-' heated region. From thermodynamic considerations the temperature of the' water should be equal or as nearly equal as pos sible to the saturation temperature corresponding to the temperature of the steam at the point of injection and the rate of injection should be proportionate to the flow of steam to, in effect, give a degree of dilution which prevents or adequately reduces corroslon.
  • an alkali is employed, this is injection at a stage of the turbine in which the steam is still superheate'd,the object'being to provide alkali or other nuclei around which moisture can form and thereby the active corrosive substances may be diluted to such an extent that corrosion is reduced due to the dissolution of the corrosive substances by the water particles.
  • a solution is used whose boiling point is higher than that of water under the same condition of pressure and consequently the liquid can exist as such at the point of injection and be available for performing the function above mentioned.
  • An aqueous solution of caustic soda is a suitable'medium to employ when blades of ferrous material are used in the turbine, but the invention is not limited to the use of this substance as the most suitable substance would be determined by a consideration of the corrosive constituents of the steam having regard to the material of the blades and the action on other parts of the plant, the condenser tubes, for example. Other solu-.
  • tions suitable to employ are solutions of the carbonates and hydroxides of sodium and potassium, also any other soluble hydroxides.
  • nozzles may obviously be injected on either side of a suitable nozzle or nozzles to which the liquid is supplied at a suitable pressure, said nozzles being adapted to atomize the liquid into the form of a fine spray.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Description

April 17, 1928. 1,666,523
R. W. BAILEY TREATMENT OF STEAM I'd REDUCE 0R PREVENT CORROSION Filed Dec. 17, 1921 WITNESSES: INVENTOR ATTORNEY Patented Apr. 17, 1928.
UNITED STATES PATENT OFFICE.
RICHARD WILLIAM BAILEY, OF ALTRINCHAM, ENGLAND, ASSIGNOR TO WESTING- HOUSE ELECTRIC.& MANUFACTURING COMPANY, A. CORPORATION OF PENNSYL- VANIA.
TREATMENT OF STEAM TO REDUCE OR PREVENT CORROSION. I
Application filed December 17, 1921, Serial No. 523,054, and in Great Britain December 20, 1820.
This invention relates to means for reducing or preventing corrosion of turbine blad ing. It has been observed that the corrosion of the blading of steam turbines appears to be most severe in the region where mois ture is first formed and where the moisture content or wetness of the steam is comparatively low. The moisture content of the steam increases as it passes through the turbine towards the condenser and this is accompanied by a diminution of corrosion until in the last stages of expansion of the.
steam it is often negligible. The comparatively high rate of corrosion where moisture is first formed and where the'moisture content is low is thought to be due to the fact that the water particles dissolve the active gases in the steam thereby rendering them corrosive and carry them at an appreciable degree of concentration to the blade su1-- faces. At a later stage in the expansion of the steam the increasing'quantity of water present together with the partial exhaustion or neutralization of the corrosive elements which has taken place and the reductionin temperature results in diminishing the corrosion to an amount which is not serious.
In the accompanying drawing, I show a schematic representation of a turbine embodying my device.
According to the present invention, in order to reduce or prevent corrosion of turbine blading, liquid in the form of a fine spray or atomized condition is injected into the steam which operates the turbine. The liquid employed may either be Water. or an alkali which will dilute or neutralize the action of corrosive constituents, such as free oxygen or both water and a neutralizing solution may be separately injected in the steam path.
In the accompanying drawing, I show a. somewhat diagrammatic "elevation of a steam power installation, comprising a water tube boiler 10,- which is provided with a superheater 11, from which steam is supplied through the throttle valve I2,'to an elastic fluid turbine 13, in a manner well understood in the art. I
In expanding through the turbine, the steam gradually loses its superheat and becomes wet steam, the zone in which the change from superheated to wet steam takes place being indicated by b, while the zones of superheated and of wet steam are indicated by a and respectively.
In order to reduce the corrosive action of the steam in this zone of change, I provide suitable nozzles 14, which are arranged to be supplied with a suitable inert liquid diluent from the manifold 16. hile I have shown a plurality of nozzles, it will be understood that only one may be used, and also that the nozzles need not be all disposed to discharge into the same stage as shown. Preferably, the nozzles are arranged to discharge into a stage of the turbine on the high pressure side of the zone of change 1) as shown.
In the case where water only is employed, the injection may take place either at that part of the steam path where moisture is first formed or a little earlier in the super-' heated region. From thermodynamic considerations the temperature of the' water should be equal or as nearly equal as pos sible to the saturation temperature corresponding to the temperature of the steam at the point of injection and the rate of injection should be proportionate to the flow of steam to, in effect, give a degree of dilution which prevents or adequately reduces corroslon.
Where an alkali is employed, this isinjected at a stage of the turbine in which the steam is still superheate'd,the object'being to provide alkali or other nuclei around which moisture can form and thereby the active corrosive substances may be diluted to such an extent that corrosion is reduced due to the dissolution of the corrosive substances by the water particles. Preferably a solution is used whose boiling point is higher than that of water under the same condition of pressure and consequently the liquid can exist as such at the point of injection and be available for performing the function above mentioned.
An aqueous solution of caustic soda. is a suitable'medium to employ when blades of ferrous material are used in the turbine, but the invention is not limited to the use of this substance as the most suitable substance would be determined by a consideration of the corrosive constituents of the steam having regard to the material of the blades and the action on other parts of the plant, the condenser tubes, for example. Other solu-.
tions suitable to employ are solutions of the carbonates and hydroxides of sodium and potassium, also any other soluble hydroxides.
Where the liquid is to be injected into the steam path where the steam is superheated,
y it may obviously be injected on either side of a suitable nozzle or nozzles to which the liquid is supplied at a suitable pressure, said nozzles being adapted to atomize the liquid into the form of a fine spray. In some cases it may be desirable to provide a number of such nozzles so that the injection liquid may be distributed throughout the body of the steam passing throughthe turbine at the stage or stages where the injection takes place. 7
While I have disclosed a plurality of ways in which my invention may be practiced, it will be obvious to those skilled in the art that it is not so limited, but is susceptible of being used or applied in various other ways without departing from the spirit thereof, and-I desire, therefore, that only such limitations shall be placed thereupon as are imposed by the prlor-art or as are specifically set forth in the appended claims. What I claim is Q 1. The process of minimizing corrosion in machines for abstractin the available energy of steam in the production of mechanical power, and in which steam changes from a superheated to a saturated condition, which consists in injecting an inert liquid diluent into the steam on the high pressure do of the zone of change from superheated to saturated conditions.
2. The process of reducing corrosion machines for abstracting the available energy of steam in the production of mechanical power, and in whlch steam changes from a superheated 'to a saturated condition, which consists in injecting an inert liquid diluent, at a temperature substantially corresponding to the saturation temperature of the steam in the zone of change from superheated to saturated conditions, into the steam entering the zone of change.
3. The process of reducing corrosion in machines for abstracting the available energy of steam in the roduction of mechanical power, and in which steam changes from superheated to wet steam, which consists in in ecting an inert liquid diluent, at a rate proportionate to the flow of steam, into the steam on the high pressure side of the zone of change from su erheated to wet steam.
In testimony w ereof, I have hereunto subscribed my name this 24th day of November, 1921.
' RICHARD WILLIAM BAILEY.
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2595490A (en) * 1945-01-04 1952-05-06 Wyandotte Chemicals Corp Prevention of siliceous deposition from steam
US2781005A (en) * 1950-06-28 1957-02-12 Power Jets Res & Dev Ltd Method of reducing vanadium corrosion in gas turbines
US2799353A (en) * 1941-12-29 1957-07-16 Edward F Andrews Jet driven helicopter rotor system
US2972861A (en) * 1953-03-11 1961-02-28 Midland Tar Distillers Ltd Method of reducing the corrosive attack of combustion gases on metal
US3081241A (en) * 1959-12-24 1963-03-12 Gen Electric Method and apparatus for introducing hydrogen into a steam atmosphere
US3171789A (en) * 1960-12-09 1965-03-02 Atomic Energy Authority Uk Inhibition of the corrosion of metals by steam at high temperatures
US3905197A (en) * 1974-04-29 1975-09-16 Carrier Corp Power expander centrifuge
US4282715A (en) * 1977-11-11 1981-08-11 Bengt Edwall Method and apparatus for preventing corrosion in a steam power plant
US5231832A (en) * 1992-07-15 1993-08-03 Institute Of Gas Technology High efficiency expansion turbines

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2799353A (en) * 1941-12-29 1957-07-16 Edward F Andrews Jet driven helicopter rotor system
US2595490A (en) * 1945-01-04 1952-05-06 Wyandotte Chemicals Corp Prevention of siliceous deposition from steam
US2781005A (en) * 1950-06-28 1957-02-12 Power Jets Res & Dev Ltd Method of reducing vanadium corrosion in gas turbines
US2972861A (en) * 1953-03-11 1961-02-28 Midland Tar Distillers Ltd Method of reducing the corrosive attack of combustion gases on metal
US3081241A (en) * 1959-12-24 1963-03-12 Gen Electric Method and apparatus for introducing hydrogen into a steam atmosphere
US3171789A (en) * 1960-12-09 1965-03-02 Atomic Energy Authority Uk Inhibition of the corrosion of metals by steam at high temperatures
US3905197A (en) * 1974-04-29 1975-09-16 Carrier Corp Power expander centrifuge
US4282715A (en) * 1977-11-11 1981-08-11 Bengt Edwall Method and apparatus for preventing corrosion in a steam power plant
US5231832A (en) * 1992-07-15 1993-08-03 Institute Of Gas Technology High efficiency expansion turbines

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