US1525502A - Method of treating metal articles - Google Patents
Method of treating metal articles Download PDFInfo
- Publication number
- US1525502A US1525502A US567432A US56743222A US1525502A US 1525502 A US1525502 A US 1525502A US 567432 A US567432 A US 567432A US 56743222 A US56743222 A US 56743222A US 1525502 A US1525502 A US 1525502A
- Authority
- US
- United States
- Prior art keywords
- gears
- article
- scale
- articles
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 12
- 239000002184 metal Substances 0.000 title description 10
- 239000002253 acid Substances 0.000 description 19
- 229910000760 Hardened steel Inorganic materials 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
- C25F1/02—Pickling; Descaling
- C25F1/04—Pickling; Descaling in solution
- C25F1/06—Iron or steel
Definitions
- This invention or discovery relates to the treatment of metal articles and it is particularly directed to the cleaning and removal of scale from hardened steel articles such as gears without injuring the articles or materially changing the physical properties thereof.
- the gears are, after being cut, hardened by heating to a temperature of around 1500 F. and then quenched in liquid such as oil.
- This operation produces a scale on the surface ofthe articles and they are unfit for use until such scale has been removed and the surface of the gear, particularly the teeth, is left clean.
- the scale is a hard abrasive substance which would soon wear bearing surfaces and would, therefore, quickly destroy the gears if they were used without having the scale removed from them.
- the present invention or discovery permits the use of an electrically operated acid bath in removing the scale from hardened gears without materially changing the physical properties of the metal.
- the present invention or discovery consists principally of somewhat drawing the temper from the hardened steel articl'esbefore subjecting them to the acid bath and thus the strains in the metal are removed before the acid is permitted to act upon the articles. More specifically, the invention or discovery may be described as follows: The metal artieleis heated to a suitable temperature above its critical point, say 1500 F., and quenched in oil, thus hardening it. Sometimes this hardening step is repeated by a second heating and quenching. This hardening operation leaves a scale on the gear or article and it is then heated again, preferably to a lesser degree than in the hardening operation, say 7009 F., so that a part of the temper is drawn from the gear. The gear is then cooled.
- This acid cleaning operation in full, preferably consists of, first, washing the gears in an alkaline solution to clean the oil from the surface, next, washing them in cool water to remove the solution and cool the gears so that they will not heat the next bath, next, subjecting the gears to an electrically operated acid bath, next, again washing the gears in cold water, and then washing the gearsin a solution of sal soda (about one ound of sal soda to-ten or fifteengallons of water) to remove the acid.
- the ears are sometimes brushed with a fibre brus .to remove the slight deposit that is sometimes present on the surface and which may interfere with inspecting the gears.
- the electrically operated acid bath above referred to is preferably a solution of approximately nine parts (by Volume) of water and one part of acid, the acid content consisting of two parts of commercial muriatic acid (specific gravity 1.15) and one part of commercial sulphuric acid (66 Baum).
- This acid bath should be kept cool in order to prevent pitting of the gears and its acid content may be varied somewhat to suit the particular case; Also; the length of time that the gears or other articles are subjected to this acid bath may be varied somewhat, the usual time-being from eight to twelve minutes.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- ing And Chemical Polishing (AREA)
Description
Patented Feb. 10, 1925. I
UNITED STATES PATENT OFFICE.
WILLIAM H. GRAVES, JR., OF DETR OIT, MICHIGAN, ASSIGNOR TO PACKARD MOTOR CAR COMPANY, 015 DETROIT, MICHIGAN, ACORPQRATION OF MICHIGAN.
METHOD OF TREATING METAL ARTICLES.
No Drawing.
To all whom it may. concern-.-
Be it known that I, WILLIAM H. GRAVES, J12, a citizen of the United States, and resident of Detroit, WVayne County, State of Michigan, have invented certain new and useful Improvements in Methods of Treating MetalvArticlcs, of which the following is a specification.
This invention or discovery relates to the treatment of metal articles and it is particularly directed to the cleaning and removal of scale from hardened steel articles such as gears without injuring the articles or materially changing the physical properties thereof.
The invention or discovery will be described in connection with the treatment of hardenedsteel gears such as are used in the transmission or gear box of an automobile, though it is, of course, applicable to other gears and to other metal articles.
In the manufacture of steel gears for such uses as suggested above, the gears are, after being cut, hardened by heating to a temperature of around 1500 F. and then quenched in liquid such as oil. This operation produces a scale on the surface ofthe articles and they are unfit for use until such scale has been removed and the surface of the gear, particularly the teeth, is left clean. The scale is a hard abrasive substance which would soon wear bearing surfaces and would, therefore, quickly destroy the gears if they were used without having the scale removed from them.
In usual practice the scale is removed by the use of rapidly Evolving wire brushes and in some cases by a file or' the scraping action of a hard instrument. This requires considerable time and the brushes wear rapidly so that this method is expensive. This is also a difficult method where the gear or article has small teeth or interstices or where teeth or key-ways are cut inside of the gear hub.
Attempts have been made to clean such gears or remove the scale therefrom by the use of an electricallv operated acid bath but it has been found that subjecting a hardened gear to such bath greatly changes the physical properties of the material as by reducing its strength or ductility and such cleaning operations have not, therefore, been found practicable where maximum strength of material is important.
Application filed June 10, 1922. semi No. 567,432.
from which the hardening strains have not been removed, it results in greatly reducing the strength of the hardened gear and while drawing the temper thereafter restores the strength somewhat yet the gear is still far from its original strength. The present invention or discovery permits the use of an electrically operated acid bath in removing the scale from hardened gears without materially changing the physical properties of the metal.
The present invention or discovery consists principally of somewhat drawing the temper from the hardened steel articl'esbefore subjecting them to the acid bath and thus the strains in the metal are removed before the acid is permitted to act upon the articles. More specifically, the invention or discovery may be described as follows: The metal artieleis heated to a suitable temperature above its critical point, say 1500 F., and quenched in oil, thus hardening it. Sometimes this hardening step is repeated by a second heating and quenching. This hardening operation leaves a scale on the gear or article and it is then heated again, preferably to a lesser degree than in the hardening operation, say 7009 F., so that a part of the temper is drawn from the gear. The gear is then cooled. Some of the scale still remains on the gear and it is then subjected to an acid cleaning operation. This acid cleaning operation, in full, preferably consists of, first, washing the gears in an alkaline solution to clean the oil from the surface, next, washing them in cool water to remove the solution and cool the gears so that they will not heat the next bath, next, subjecting the gears to an electrically operated acid bath, next, again washing the gears in cold water, and then washing the gearsin a solution of sal soda (about one ound of sal soda to-ten or fifteengallons of water) to remove the acid. After drying, the ears are sometimes brushed with a fibre brus .to remove the slight deposit that is sometimes present on the surface and which may interfere with inspecting the gears.
The electrically operated acid bath above referred to is preferably a solution of approximately nine parts (by Volume) of water and one part of acid, the acid content consisting of two parts of commercial muriatic acid (specific gravity 1.15) and one part of commercial sulphuric acid (66 Baum). This acid bath should be kept cool in order to prevent pitting of the gears and its acid content may be varied somewhat to suit the particular case; Also; the length of time that the gears or other articles are subjected to this acid bath may be varied somewhat, the usual time-being from eight to twelve minutes. In a two hundred gallon lead lined tank ten carbon plates 10 "x 5"x 1% may be used and the electrical connections are so made that these plates will operate as the anode and the work (that is the metal articles) as the cathode. This tank when loaded may be run with say five volts to produce good results, and the amperage varies with the amount of work in the tank. Although the invention or discovery has been described rather specifically as to particular methods or processes that have been practiced under it, it will be understood that it is not thus limited in its application.
Having thus described the invention or discovery, what is claimed as new and desired to be secured by Letters Patent is:
1. The process of treating hardened steel articles consisting in partly drawing the temper from the article and then subjecting the article to an electrically operated acid bath to remove the scale.
2. The process of treating hardened steel articles consisting in partly drawing the temper from the article, then cleaning the oil from the article, and then subjecting the article to an electrically operated acid bath to remove the scale.
3. The process of treating hardened-steel articles consisting in partly drawing the temper from the article, then subjecting the article to an alkaline solution to clean the oil from the surface, and then subjecting the article to an electrically operated acid bath to remove the scale.
4. The process of treating metal articles such as gears consisting in hardening the article as by heating and quenching, then heating the article to a lesser degree than when hardening to thus partly draw the temper, and then subjecting the article to an electrically operated acid bath to remove the scale.
5. The process of treating metal articles consisting in heating the article and quenching in oil to harden it, then heating the article to partly draw the temper and cooling it, then subjecting the article to an oil cleaning bath, and then to an electrically operated acid bath to remove the scale.
In testimony whereof I aifix my signature.
WILLIAM H. GRAVES, JR.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US567432A US1525502A (en) | 1922-06-10 | 1922-06-10 | Method of treating metal articles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US567432A US1525502A (en) | 1922-06-10 | 1922-06-10 | Method of treating metal articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1525502A true US1525502A (en) | 1925-02-10 |
Family
ID=24267123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US567432A Expired - Lifetime US1525502A (en) | 1922-06-10 | 1922-06-10 | Method of treating metal articles |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1525502A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002006566A1 (en) * | 2000-07-19 | 2002-01-24 | Dr.-Ing. Max Schlötter Gmbh & Co. Kg | Method for coating components consisting of hardened steel or cast iron with a zinc-nickel alloy |
-
1922
- 1922-06-10 US US567432A patent/US1525502A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002006566A1 (en) * | 2000-07-19 | 2002-01-24 | Dr.-Ing. Max Schlötter Gmbh & Co. Kg | Method for coating components consisting of hardened steel or cast iron with a zinc-nickel alloy |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| USRE22887E (en) | Process for removing oxide from | |
| US2468006A (en) | Electrolytic cleaning of metal | |
| US2880855A (en) | Method of processing steel | |
| US1525502A (en) | Method of treating metal articles | |
| US2538702A (en) | Metal surface cleaning | |
| US2437474A (en) | Method of anodic cleaning | |
| DE1817581A1 (en) | Method and device for the treatment of fiber material | |
| US3489625A (en) | Process for metal surface conditioning | |
| US1678359A (en) | Method of treating metal articles | |
| US1977448A (en) | Process of making automobile bumpers and the like | |
| US1399044A (en) | Heat treatment of metals | |
| US1952417A (en) | Process for cleaning metal molds used for the vulcanization of rubber articles | |
| US2383434A (en) | Oxidation removing process | |
| US2418955A (en) | Process of removing foreign matter from magnesium surfaces | |
| US2317205A (en) | Method of working metals | |
| US2173218A (en) | Method for whetting files, rasps, and the like | |
| US1878096A (en) | Treatment of metal articles | |
| US1373573A (en) | Method of treating steel and iron parts | |
| US2410322A (en) | Treatment of manganese steel | |
| US1279101A (en) | Method of preparing pickled iron and steel for painting. | |
| US2738293A (en) | Salt bath system and method for treating metals | |
| US1371445A (en) | Lead-coating process | |
| US2405101A (en) | Method of reconditioning files | |
| US1978151A (en) | Method of pickling metal | |
| US1314450A (en) | Process of resharpening files. |