US1522813A - Alloy - Google Patents
Alloy Download PDFInfo
- Publication number
- US1522813A US1522813A US745229A US74522924A US1522813A US 1522813 A US1522813 A US 1522813A US 745229 A US745229 A US 745229A US 74522924 A US74522924 A US 74522924A US 1522813 A US1522813 A US 1522813A
- Authority
- US
- United States
- Prior art keywords
- alloy
- nickel
- carbon
- iron
- chromium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000956 alloy Substances 0.000 title description 21
- 229910045601 alloy Inorganic materials 0.000 title description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 13
- 229910052759 nickel Inorganic materials 0.000 description 13
- 229910052742 iron Inorganic materials 0.000 description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 9
- 229910052804 chromium Inorganic materials 0.000 description 9
- 239000011651 chromium Substances 0.000 description 9
- 239000000470 constituent Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000010941 cobalt Substances 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241001600451 Chromis Species 0.000 description 1
- 241001078909 Clematis hirsutissima Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- -1 a'nickel-likemetal Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 235000007983 food acid Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
Definitions
- the proportion of nickel has varied from 0.57 the chromium from 3% carbon from 0.2% to 1%,
- Such alloys are prepared by melting the constituents together, or
- My invention is a minimum' ossible in the stainas low as ductility an characterized in that I nickel content of 26%,
- the physical properties otthe alloy will be. somewhat modified by varying the proportions of the elements or constituents designated as impurities (hereinafter, for the sake of brevity, referred to in the appended. claiins,'as additions) whether the, same be added or whether they occur as impurities, in regard working; but'the alloys' resistance to corrosion will not be vitally impaired and it will still be capable oftaking a fine polish and resisting staining by the usual agents, such as vinegar and other food acids.
- impurities hereinafter, for the sake of brevity, referred to in the appended. claiins,'as additions
- an alloy containing substantially z-nickel, 30% chromium, 11% iron, 58%; carbon, 0.15%; manganese, 0.35%; silicon, 0.20%; sulphur," 0.02%; phosphorus, 0.02%; aluminium, trace would give the following tensile properties in its forged condition, on V diameter section: yield point, 25 tons per sguare inch; maximum stress, 42.5 tons per square inch; elongation, 38% on a 2" length; reduction of area", 54.8 Brinell hardness, 156.
- Such an alloy 0r any'other alloy made according to this invention, will be machinable and will roll in the hot or cold state. It will stamp satisfactorily by the usual methods of preparing such objects as spoons and forks, and may be drawn into wire by the usual processes. Further, it will have a leasing colour and a silvery lustre rendermg'it particularly suitable for table and decorative ware.
- Such an alloy will be ractieally non:cor-" rosive in 5% strength of iydrochloric acid or sulphuric acid or nitric acid with water.
- Such an alloy will show remarkable resistance to corrosion by sea water and atmospheric a ents generally, and by reason of its remarka le physical characteristics may be used for many engineering purposes.
- the cost of preparing these alloys is such as to-render them competitive with existing methods for the manufacture of cutlery and similar purposes, while the development of their properties without frequent and expensive heat treatment renders them economical in the processof manufacture.
- the alloy is produced by a method of reduction of the oxides of the principal metals, any one metal or proportion thereof may be used with the remainder as oxides, or any of the metals maybe used with the oxide of the remaining one, but where oxides are used any or all of the reducing agents, such as silicon, magnesium; and aluminium, must be used.
- ters Patent is 1.
- An alloy having as the principal constituent, a'nickel-likemetal, chromium, iron and carbon, the proportions of the nickellike metal being 30%; those of the chromi- -um-being 11%; those of the iron being 58% and those of the carbon being 0.15%; the balance being impurities.
- An alloy having, as the principal constituents, a nickel-like metal',”chromi um, iron and carbon, the proportions of the nickellike metal being 30 per cent, those of the chromium being 11 per cent, those of the iron being 58 per cent and those of the car'- bon being 0.15 percent, the balance being manganese, silicon, sulphur, phosphorus and aluminium.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Adornments (AREA)
Description
. an alloy,
1 employ Patented Jan. 13,
AIDWAY, NEAR SHEFFIELD, ENGLAND. v
HARRY No Drawing.
To all whom. it may .130. it known that Limbcrlost, near Shetlield, in the land. a subject of the King of and Ireland, have invented certain new anc usei'nl Improvements 111 or Alloys, of which the tion.
Alloys comprising ments or constituents,
heretofore been proposed,
and carbon have concern l, 'I'lARRY Twentywoll Lane,
n'rcnELLs, or an s PATENT. OFFICE.
v ALLOY.
Application filed October 22, 1924. Serial No. 745,229.
ErorrELLs, of Bradway, county of Derby, Eng- Great-Britain Relating to followm IS a s )ecificaas the principal elenickel, chromium, iron the respective proportions varying within wide limits.
iron constituting For instance, the proportion of nickel has varied from 0.57 the chromium from 3% carbon from 0.2% to 1%,
the balance.
to 80%, that of to 4.0%, that of the and that of the loys embodying nickel and carbon contents have had 0.30%
of carbon with the nickel content of 25% upwardsfwh-ile in alloys containing a nic content of 20% to 25 to have a carbon 0.20% to 0.50%.
as the minimum proportion and kel it has been proposed content varyingfrom Such alloys are prepared by melting the constituents together, or
by reducing e oxides of the constituent metals by suitable agents.
The object of this including elements or tional properties in and corrosive action of the acids,
constituents,
invention is to provide the aforesaid principal possessing excep resisting the stainin alkalies an salts usually encountered in the preparation of food,in the machinery of general sanitation, and in many industrial processes, in
which connection it is essential that the carkept the bon content be order to increase lessness.
My invention is a minimum' ossible in the stainas low as ductility an characterized in that I nickel content of 26%,
with a maximum carbon content of 0.25% for that proportion and over it, together with the chromium and iron in various proportions.
The particular proportions of the principal elements or constituents invention vary bodying my limits depending 7 upon the service of the articles made from it, such limits being as follows: nickel, 26% to 30%; iron, 25% t ceeding 0.25%.
to 50%; chromium, 5% o 69%; carbon, not ex- All suchal-- tov tensile strength,
will not stain or combination with, the nickel, so long as the cobalt alone, or the cobalt and'nickel in combination, are used in the proportion of 26% Cobalt has ahnost thesame prop erties as nickel, theonly objection being that it makes the alloy more expensive. Hence I denominate cobalt or'a mixture of cobalt and nickel or nickel, a nickel-like metal.
It will be appreciated that the physical properties otthe alloy will be. somewhat modified by varying the proportions of the elements or constituents designated as impurities (hereinafter, for the sake of brevity, referred to in the appended. claiins,'as additions) whether the, same be added or whether they occur as impurities, in regard working; but'the alloys' resistance to corrosion will not be vitally impaired and it will still be capable oftaking a fine polish and resisting staining by the usual agents, such as vinegar and other food acids.
In order to more particularly describe the characteristics and properties referred to, it may be mentioned that an alloy containing substantially z-nickel, 30% chromium, 11% iron, 58%; carbon, 0.15%; manganese, 0.35%; silicon, 0.20%; sulphur," 0.02%; phosphorus, 0.02%; aluminium, tracewould give the following tensile properties in its forged condition, on V diameter section: yield point, 25 tons per sguare inch; maximum stress, 42.5 tons per square inch; elongation, 38% on a 2" length; reduction of area", 54.8 Brinell hardness, 156.
Such an alloy, 0r any'other alloy made according to this invention, will be machinable and will roll in the hot or cold state. It will stamp satisfactorily by the usual methods of preparing such objects as spoons and forks, and may be drawn into wire by the usual processes. Further, it will have a leasing colour and a silvery lustre rendermg'it particularly suitable for table and decorative ware.
ductility andease of Such an alloy will be ractieally non:cor-" rosive in 5% strength of iydrochloric acid or sulphuric acid or nitric acid with water.
tarnish when immersed in vinegar, or the water in which green too vegetables have been boiled, and is thus en -l-- I inently'suitable for the manufacture of cooking utensils and'food-pr'eserving utensils.
Such an alloy will show remarkable resistance to corrosion by sea water and atmospheric a ents generally, and by reason of its remarka le physical characteristics may be used for many engineering purposes.
Apart from the cost of the constituent materials, the cost of preparing these alloys is such as to-render them competitive with existing methods for the manufacture of cutlery and similar purposes, while the development of their properties without frequent and expensive heat treatment renders them economical in the processof manufacture.
\Vhere the alloy is produced by a method of reduction of the oxides of the principal metals, any one metal or proportion thereof may be used with the remainder as oxides, or any of the metals maybe used with the oxide of the remaining one, but where oxides are used any or all of the reducing agents, such as silicon, magnesium; and aluminium, must be used.
Among the uses be put are v (1) Manufacture of decorative articles in ships and railway coaches, for lamp reflecto which the alloy may ors, mountings onstove grates, and bright etal decorations generally, which are re- 1 uired to maintain their lust-re.
(12 Manufacture of tableware, such .as for spoons, waiters, sugar-bowls, bowls, vases, ash-trays, etc.
(3 Manufacture of cooking utensils, milk cans and food transporting and preserving containers generally.
( 1) Manufacture of valves and various mechanical parts exposed to sea water, di-
. ters Patent is 1. An alloy having as the principal constituent, a'nickel-likemetal, chromium, iron and carbon, the proportions of the nickellike metal being 30%; those of the chromi- -um-being 11%; those of the iron being 58% and those of the carbon being 0.15%; the balance being impurities.
2. An alloy having, as the principal constituents, a nickel-like metal',"chromi um, iron and carbon, the proportions of the nickellike metal being 30 per cent, those of the chromium being 11 per cent, those of the iron being 58 per cent and those of the car'- bon being 0.15 percent, the balance being manganese, silicon, sulphur, phosphorus and aluminium.
3. -An alloy having, as the principal con- I stituents, nickel, chromium, iron and carbon, the proportions of the" nickel being 30 per cent, those of the chromium being 11 per cent, those of the iron being 58 per cent, and those of the carbon being 0.15 per cent, the balance being manganese, silicon, sulphur, phosphorus and aluminium.
In testimony whereof,I afiix my signature.
' HARRY ETCHELLS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US745229A US1522813A (en) | 1924-10-22 | 1924-10-22 | Alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US745229A US1522813A (en) | 1924-10-22 | 1924-10-22 | Alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1522813A true US1522813A (en) | 1925-01-13 |
Family
ID=24995794
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US745229A Expired - Lifetime US1522813A (en) | 1924-10-22 | 1924-10-22 | Alloy |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1522813A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2496246A (en) * | 1948-05-05 | 1950-01-31 | Armco Steel Corp | High-temperature article |
| US2642357A (en) * | 1950-05-23 | 1953-06-16 | Crowley Republic Steel Corp | Low-temperature reduction of cobalt chloride |
| US2770870A (en) * | 1952-05-31 | 1956-11-20 | Wilson H A Co | Thermosensitive laminated metals |
| US3366471A (en) * | 1963-11-12 | 1968-01-30 | Republic Steel Corp | High strength alloy steel compositions and process of producing high strength steel including hot-cold working |
| USRE28523E (en) * | 1963-11-12 | 1975-08-19 | High strength alloy steel compositions and process of producing high strength steel including hot-cold working | |
| US4957550A (en) * | 1987-05-06 | 1990-09-18 | Manufacturers Hanover Trust Co. | Ultrasonic machining tool for machining orthodontic brackets |
-
1924
- 1924-10-22 US US745229A patent/US1522813A/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2496246A (en) * | 1948-05-05 | 1950-01-31 | Armco Steel Corp | High-temperature article |
| US2642357A (en) * | 1950-05-23 | 1953-06-16 | Crowley Republic Steel Corp | Low-temperature reduction of cobalt chloride |
| US2770870A (en) * | 1952-05-31 | 1956-11-20 | Wilson H A Co | Thermosensitive laminated metals |
| US3366471A (en) * | 1963-11-12 | 1968-01-30 | Republic Steel Corp | High strength alloy steel compositions and process of producing high strength steel including hot-cold working |
| USRE28523E (en) * | 1963-11-12 | 1975-08-19 | High strength alloy steel compositions and process of producing high strength steel including hot-cold working | |
| US4957550A (en) * | 1987-05-06 | 1990-09-18 | Manufacturers Hanover Trust Co. | Ultrasonic machining tool for machining orthodontic brackets |
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