US1597840A - Paper pulp and paper - Google Patents
Paper pulp and paper Download PDFInfo
- Publication number
- US1597840A US1597840A US724972A US72497224A US1597840A US 1597840 A US1597840 A US 1597840A US 724972 A US724972 A US 724972A US 72497224 A US72497224 A US 72497224A US 1597840 A US1597840 A US 1597840A
- Authority
- US
- United States
- Prior art keywords
- paper
- phosphoric acid
- pulp
- hydration
- found
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001131 Pulp (paper) Polymers 0.000 title description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 38
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 19
- 239000000123 paper Substances 0.000 description 7
- 230000036571 hydration Effects 0.000 description 6
- 238000006703 hydration reaction Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000010009 beating Methods 0.000 description 4
- 239000002655 kraft paper Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241001446467 Mama Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000011084 greaseproof paper Substances 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 239000011088 parchment paper Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
- D21C9/004—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives inorganic compounds
Definitions
- PAPER PULP AND PAPER PAPER PULP AND PAPER.
- My invention has for its object the improvement of the quality of the pulp andpaper made thereof. It is based on the discovery which I have made that if the paper 5 making materials are treated with phosphoric acid or soluble salts thereof in the course of their preparation the phosphoric acid combines or is incorporated with the cellulose in such a way that even after bleaching the material will show a firm test for phosphoric acid. The presence of phosphoric acid in the pulp gives the paper formed therefrom a certain toughness and characteristic feel, aids its bleaching and facilitates the hydration of the pulp when treated in the beater.
- the combination may be brought about in several Ways and in its broader aspect the invention is independent of the particular manner by which this combination or assimilation of the phosphoric acid with the cellulose is effected.
- the phosphoric acid may be introduced into the digester with the material to be pulped. It may be 2 introduced into the beating engine with the pulp when the latter is being beaten. Or, the phosphoric acid may be used to dissolve material like casein, size, etc., and the resulting solution introduced into the beating engine or used to coat the paper.
- the invention is particularly applicable to pulps made from the kraft process wherein I the combination of the cellulose of the kraft pulp with the phosphoric acid also aids the bleaching to such an extent as to make it possible to produce a white pulp of high color and at the same time very soft and strong.
- the phosphoric acid addition is found to be of advantage in the digesting process whether graft liquor or the usual sulphite digesting liquor be employed.
- the addition of the phosphoric acid to kraft liquor has the unexpected and very desirable feature of preventing the very disagreeable odors characteristic of the kraft process.
- the action of hydration which is achieved or assisted by the use of phosphoric acid, may be carried to any desired extent. If a less degree of hydration is effected it will be found that 0 the resultant sheet will have a noticeable effect of sizing, and if the hydration is carried further the sizing effect is more pronounced.
- a more complete hydration gives the characteristics of imitation parchment and grease-proof papers, depending to some extent upon the nature of the stock treated. In any case, the paper pulp or sheet is found to contain an appreciable amount of phosphoric acid which is largely responsible for the characteristics described.
- the use of the phosphoric acid does not preclude the additions of such other materials as are commonly employed in the paper of the kind referred to, such as starch, casein, silicate of soda, etc.
- the eifect of the phosphoric acid is added to that of the additions referred to. I have found the addition of starch to be particularly desirable especially in case a fully grease-proof sheet is desired.
- the paper and paper lyzed cellulose fibre containing an appreci- 15 pulp produced by my process is or may be able amount of phosphoric acid compounds.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
Description
Patented Aug. 31, 1926.
UNHTE srras mama IBERTR-AND S. SUMMERS, OF PORT HURON, MICHIGAN."
PAPER PULP AND PAPER.
4N0 Drawing.
My invention has for its object the improvement of the quality of the pulp andpaper made thereof. It is based on the discovery which I have made that if the paper 5 making materials are treated with phosphoric acid or soluble salts thereof in the course of their preparation the phosphoric acid combines or is incorporated with the cellulose in such a way that even after bleaching the material will show a firm test for phosphoric acid. The presence of phosphoric acid in the pulp gives the paper formed therefrom a certain toughness and characteristic feel, aids its bleaching and facilitates the hydration of the pulp when treated in the beater.
The combination may be brought about in several Ways and in its broader aspect the invention is independent of the particular manner by which this combination or assimilation of the phosphoric acid with the cellulose is effected. Thus the phosphoric acid may be introduced into the digester with the material to be pulped. It may be 2 introduced into the beating engine with the pulp when the latter is being beaten. Or, the phosphoric acid may be used to dissolve material like casein, size, etc., and the resulting solution introduced into the beating engine or used to coat the paper.
The invention is particularly applicable to pulps made from the kraft process wherein I the combination of the cellulose of the kraft pulp with the phosphoric acid also aids the bleaching to such an extent as to make it possible to produce a white pulp of high color and at the same time very soft and strong.
I prefer to use the phosphoric acid in the form of one of its soluble salts, and trisodium-phosphat-e has been found to be satisfactory for the purpose.
The phosphoric acid addition is found to be of advantage in the digesting process whether graft liquor or the usual sulphite digesting liquor be employed. The addition of the phosphoric acid to kraft liquor has the unexpected and very desirable feature of preventing the very disagreeable odors characteristic of the kraft process. The
Application filed. July 9,
1924. Serial No. 724,972.
paper and paper pulp resulting from the process where phosphoric acid is added, whatever the nature of the digesting liquor employed, evidences the presence of phosphoric acid as above stated.
In the beating operation the action of hydration, which is achieved or assisted by the use of phosphoric acid, may be carried to any desired extent. If a less degree of hydration is effected it will be found that 0 the resultant sheet will have a noticeable effect of sizing, and if the hydration is carried further the sizing effect is more pronounced. A more complete hydration gives the characteristics of imitation parchment and grease-proof papers, depending to some extent upon the nature of the stock treated. In any case, the paper pulp or sheet is found to contain an appreciable amount of phosphoric acid which is largely responsible for the characteristics described. The use of the phosphoric acid does not preclude the additions of such other materials as are commonly employed in the paper of the kind referred to, such as starch, casein, silicate of soda, etc. The eifect of the phosphoric acid is added to that of the additions referred to. I have found the addition of starch to be particularly desirable especially in case a fully grease-proof sheet is desired.
I wlll now describe a typical example of the use of my proved process in which the phosphoric acid is added in the beater: To a body of 1600 pounds of air dried stock contained in a heater, 150 to 300 pounds of phosphate, preferably in the form of tri sodium-phosphate, is added. To the mixture I may add about 150 pounds of starch which has been previously jellified by hot water and to the whole add the usual quantity of water. The roll of the beating engine is then preferably set down hard and the stock beaten until a sample thereof shows the desired degree of hydration. The beater is then dropped and run over the machine in the usual manner. By reason of the hydrating effect of the phosphates if the stock is sufficiently beaten, the resultant sheet will be found to have the effect of having a heavy coat of size. A much smaller amount of phosphate, for example 50 pounds, will give I claim: 10
a noticeable size effect to the finished sheet. 1. As an article of manufacture, hydro Even in acid solution the hydrolizing effect lyzed paper pulp containing an appreciable is evident, but as above stated I prefer to use amount of phosphoric acid compounds.
a decidedly alkaline solution. 2. As an article of manufacture,v hydro- As heretofore stated, the paper and paper lyzed cellulose fibre containing an appreci- 15 pulp produced by my process is or may be able amount of phosphoric acid compounds.
more or less hydrolized and contains an appreciable content of phosphoric acid. BERTRAND S. SUMMERS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US724972A US1597840A (en) | 1924-07-09 | 1924-07-09 | Paper pulp and paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US724972A US1597840A (en) | 1924-07-09 | 1924-07-09 | Paper pulp and paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1597840A true US1597840A (en) | 1926-08-31 |
Family
ID=24912614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US724972A Expired - Lifetime US1597840A (en) | 1924-07-09 | 1924-07-09 | Paper pulp and paper |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1597840A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2575727A (en) * | 1947-11-12 | 1951-11-20 | Rhinelander Paper Company | Method of coating glassine |
-
1924
- 1924-07-09 US US724972A patent/US1597840A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2575727A (en) * | 1947-11-12 | 1951-11-20 | Rhinelander Paper Company | Method of coating glassine |
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