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US1565409A - Oil-gas apparatus - Google Patents

Oil-gas apparatus Download PDF

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Publication number
US1565409A
US1565409A US489010A US48901021A US1565409A US 1565409 A US1565409 A US 1565409A US 489010 A US489010 A US 489010A US 48901021 A US48901021 A US 48901021A US 1565409 A US1565409 A US 1565409A
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US
United States
Prior art keywords
compartment
gas
oil
catalyzing
gas apparatus
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Expired - Lifetime
Application number
US489010A
Inventor
Blanchet Leonce
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LA CHIMIE ET A CATALYSE INDUSTRIELLE SIEGE SOCIAL Ste
SOC D CHIMIE ET A CATALYSE IND
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SOC D CHIMIE ET A CATALYSE IND
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by SOC D CHIMIE ET A CATALYSE IND filed Critical SOC D CHIMIE ET A CATALYSE IND
Priority to US489010A priority Critical patent/US1565409A/en
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Publication of US1565409A publication Critical patent/US1565409A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/26Fuel gas

Definitions

  • the present invention relates .to the production of rich gases and liquid fuel by means of petroleum residues and other hydrocarbon products of low thermal value.
  • the ob]ect of the present invention is'to increase the calorific and lighting value of .blue water gas or other gas of low thermal value; and according to the invention, the
  • vapors of petroleum residues are passed through retorts containing catalyzers heated -tobetween 500 and 600 0.
  • the heavy hydrocarbons split up into vapors and gases consisting of non-condensible 'olefines and hgdro'carbons which distil-- paraffius, light over up to"150 bons.
  • the gases thus formed are andheavier hydrocarmixed with the blue water gas or'the like, whereas the liquid hydrocarbons which distil up to 150? C. may be used as fuel for explosion motors, Finally, a very small amount of carbon is deposited on the catalyzers.
  • the catalyzers used may be metals such "as, copper or iron, in the form offilings or' "powder, which are formed into briquettes by means of a binder (gum, glue, starch, and. .rthe like),
  • Figure 1 represents a diagrammatic vertical sectional BLANCHET, a
  • FIG. 2 is a fragmented horizontal section taken through the catalyzing compartment of the retort.
  • the retort of the present invention comprises a lower catalyzing portion or compartment A, in the mtoncn BLANCHET, or PARIS, FRANCE, nssxcnonmo LA soom'rn ms cumin ETA form 'of a pa'rallelepiped,'-and an upper vaporizing portion or compartment B; the two. portions A and B being'made of a single iron casting which is heated by a furnace or other means (not shown).
  • channel-iron supports C carrying rows of briquettes D prepared as described abovep- These briquettesare placed side by side and fill the entire length of the channel-iron supports and the available height of the compartment A.
  • the vaporizer B communis cates by means of a pipe connection E with a tank F containing the petroleum residues to be catalyzed, said pipe opening at its inlet end through the bottom wall of tank F and at its outlet end through one of the side walls of the vaporizer at H.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)

Description

Patented Dec. 15, 1925'.
, UNITED STATES CATALYSE INDUSTBIELLE SIEGE SOCIAL, @E-QIABIS,
err-ens arrmarusf Application filed August 1, 1921. Serial 110.1,010.
(GRANTED UHDEB. THE PROVISIONS 01? THE ACT OF IABGH 3, 1921, 41 STAT. 1., 1315.)
To all whom it may concern:
Be it known that I, Liionon citizen of the Republicof France, and a resident of Paris, France, have invented certain new and useful Improvements in Oil-Gas Apparatus (for which I have filed applications in France on February 20, 1918, Patent No. 496,539, granted on August 6, 1919, and in England on October 15, 1918, Patent No. 140,128, dated March 25,
1920), of which the following is a speci-.
fication. 1
The present invention relates .to the production of rich gases and liquid fuel by means of petroleum residues and other hydrocarbon products of low thermal value.
It is known that the use of blue water gas or other gas of low thermal and lighting value is becoming more and more general for heating or lightinga its heatin and lighting pro erties becoming increase I by carbureting t e gas with hydrocarbon products of low value, such as by-products of petroleum, which are vaporized, in such 1 a manner that their almost complete, de-
com osition is effected and their transformation into hydro en and carbon. This method, however, oes not obtain the desired pur ose. I
a The ob]ect of the present invention is'to increase the calorific and lighting value of .blue water gas or other gas of low thermal value; and according to the invention, the
vapors of petroleum residues are passed through retorts containing catalyzers heated -tobetween 500 and 600 0. The heavy hydrocarbons split up into vapors and gases consisting of non-condensible 'olefines and hgdro'carbons which distil-- paraffius, light over up to"150 bons. The gases thus formed are andheavier hydrocarmixed with the blue water gas or'the like, whereas the liquid hydrocarbons which distil up to 150? C. may be used as fuel for explosion motors, Finally, a very small amount of carbon is deposited on the catalyzers.
.The catalyzers used may be metals such "as, copper or iron, in the form offilings or' "powder, which are formed into briquettes by means of a binder (gum, glue, starch, and. .rthe like),
1 r In the accompanying drawing, Figure 1 -represents a diagrammatic vertical sectional BLANCHET, a
' catal view of a unitary retort embodying the invention, andFig. 2 is a fragmented horizontal section taken through the catalyzing compartment of the retort.
As shown in said drawing, the retort of the present invention comprises a lower catalyzing portion or compartment A, in the mtoncn BLANCHET, or PARIS, FRANCE, nssxcnonmo LA soom'rn ms cumin ETA form 'of a pa'rallelepiped,'-and an upper vaporizing portion or compartment B; the two. portions A and B being'made of a single iron casting which is heated by a furnace or other means (not shown). In the interior of the compartment A are arranged channel-iron supports C carrying rows of briquettes D prepared as described abovep- These briquettesare placed side by side and fill the entire length of the channel-iron supports and the available height of the compartment A. The vaporizer B communis cates by means of a pipe connection E with a tank F containing the petroleum residues to be catalyzed, said pipe opening at its inlet end through the bottom wall of tank F and at its outlet end through one of the side walls of the vaporizer at H.
The petroleum residues contained in tank F and fed through ipe E are va orized in the vaporizer B, wgnch is heated y reason of its direct connection to the catalyzing compartment A whereon it is mounted, both compartments fol-min parts of the retort, as already stated. he vapors enter the zin compartment A through an opening an flow. through the catalytic mass formed by the briquettes ,D, contact with which decomposes them into amixture of light hydrocarbon vapors and gas. This mixture is discharged from the catalyzing.
compartment A through a pipe G which opens into a suitable condensing coil J, the
latter discharging, inturn, into a tank K;. .The liquid condensates discharged from coil J collect in tank K and the gas, which i also passes from said coil into the tank,
escapes therefrom through the outlet pipe L, whence it is sent into gas generators in order to be mixed-with blue' water gas or other gas of low thermal value. The light,
hydrocarbons obtained" by this process as previouslydescribed are likewise recovered.---
The arrangement described above has the advantage of enabl' the catalytic mass to be easily introduce 'into and withdrawn fi orn. the catalyzing chamber or compartqf merit A for removing the deposited carbonl. p
For this purpose it is sufficient to open the outerdoor A of said compartment and to withdraw in' succession the several channeliron" supports C with all the briquettes I thereom. The catalytic masscan then Joev easily regenerated. I claim as my inventior p z, I -1.;A unitary oil; gas" retort embodyirigfi'a' l w c ly c p mentw sepag 1; I rate upper vaporizing compartment mount .Qed. directly u 'onand directly; communh eating withtt e-"catalyzir'lg compartmenmf means for supplying liquid hydrocarbon to i the vaporizing compartment; and catalyz-r ers disposed; in a plurality of removable rows' upon th e floor of the catalyzing compartment and over which theyaporsjrom a catalyzing "compartment; 9.- separate vaporizing compartment located upon and {top of thecatalyzing compartment and (11- rectly communicating with the same;v a.
plurality. of channel-iron supports disposed within the catalyzing compartment in close {parallel relation. to' or'ie another; and a'row offcatalyzers arranged in each of said supports, and over which the 'vapors from Naporizing compartments are caused; to pass, said supports' being'removable bodily rein the catalyzing compartment "with the catalyzers in place therein.-
In testimony whereof I havefsigried this specification; l
the "'vaporiaihg compartment are I caused to 21 y Y unitary oil retort comprising
US489010A 1921-08-01 1921-08-01 Oil-gas apparatus Expired - Lifetime US1565409A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2643943A (en) * 1949-06-14 1953-06-30 So Hugo De Andrade Gas generator for stoves and the like

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2643943A (en) * 1949-06-14 1953-06-30 So Hugo De Andrade Gas generator for stoves and the like

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