US1404653A - Composition for railway signal torpedoes - Google Patents
Composition for railway signal torpedoes Download PDFInfo
- Publication number
- US1404653A US1404653A US415264A US41526420A US1404653A US 1404653 A US1404653 A US 1404653A US 415264 A US415264 A US 415264A US 41526420 A US41526420 A US 41526420A US 1404653 A US1404653 A US 1404653A
- Authority
- US
- United States
- Prior art keywords
- composition
- railway signal
- torpedoes
- detonation
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 23
- 241000251729 Elasmobranchii Species 0.000 title description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 238000005474 detonation Methods 0.000 description 10
- 229910052749 magnesium Inorganic materials 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 5
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 5
- 239000002360 explosive Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000002269 spontaneous effect Effects 0.000 description 3
- 229920001353 Dextrin Polymers 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000003137 locomotive effect Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003826 tablet Substances 0.000 description 2
- 239000003832 thermite Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000002991 molded plastic Substances 0.000 description 1
- 239000007932 molded tablet Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B29/00—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
- C06B29/02—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
- C06B29/12—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal with carbon or sulfur
Definitions
- This invention relates to improvements in compositions for railway signal torpedoes, and is for use in torpedoes that are suitably attached to the head of a railroad rail to be exploded by the wheel of the locomotive for giving a signalto the engineer, as is well understood'by those skilled in this art.
- the primary objects of my improved composition for railway signal torpedoes are- 1. To produce a louder detonation for a given quantity. of composition, whereby the amount of composition used may be reduced,
- composition which involves all the foregoing objects is composed of perchlorate, aluminum, sulphur, barium nitrate,
- composition is to be used in powder form dextrine is omitted, and in either form of the composition'the sand or flint may be omitted if desired.
- composition can'be made to give a more brilliant flash, but at somewhat more expense, by the addition of magnesium, and also magnesium can be substituted entirely for the aluminum.
- composition may be manufactured as a moulded plastic without the aluminum or magnesium, or both, and then the desired amount of either aluminum or magnesium,
- barium nitrate may be omitted, but I find that better results are obtained by its use than without it.
- the perchlorate adds to .the safety of the manufacture of the torpedo and safety in the storage of the torpedoes and at the same time adds to the sharpness of its detonation.
- the aluminum or magnesium, or both rapidly extracts the oxygen from the other chemicals of the compound so that the violence of their action adds to the sharpness and loudness of the detonation.
- the perchlorate in this composition increases the thermite effect, and thereby adds also to the sharpness and violence of the detonation.
- the barium in this composition not only imparts insensitiveness, but also furnishes additional oxygen to be extracted by the aluminum or magnesium, or both. It' allows the last-mentioned chemicals to do more Work by rapid extraction of the oxygen, and this adds to the flash as well as the detonation.
- Aluminum I find, is a better extractor of oxygen than magnesium, and it is also cheaper and, therefore, under ordinary conditions, preferable to the use of magnesium.
- the aluminum, or magnesium, or both may be omitted from the composition, and in this event, the remaining ingredients produce a composition having the advantages of louder detonation and combined in substantially the proportions specified for producing a torpedo with inducing a sharp flash detonation, and a composition which is not subject to spontaneous ignition.
- An improved explosive composition for railway signal torpedoes comprising sulphur one part,- aluminum one and threefourths parts, barium nitrate one part and perchlorate two parts, combined in substantially the proportions specified, producing a composition with a sharp flash detonation and which is not subject to spontaneous ignition.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
Description
UNITED STATES arent ossica.
LOUIS ROSS, NEWTON'VILLE, MASSACHUSETTS, ASSIGNOR TO CENTRAL RAILWAY SIGNAL COMPANY, OF PITTSBURGH, PENNSYLVANIA, A. CORPORATION OF NEW 1 No Drawing.
JERSEY.
' COMPOSITION FOR RAILWAY SIGNAL TORIPEDO ES.
To all whom it may concern: V Be it known that I, LOUIS S. Ross, a citizen of the United States residing at Newtonville, in the county of" Middlesex and State of Massachusetts, have invented certain new and useful Improvements in Compositions for Railway following is a specification. v
This invention relates to improvements in compositions for railway signal torpedoes, and is for use in torpedoes that are suitably attached to the head of a railroad rail to be exploded by the wheel of the locomotive for giving a signalto the engineer, as is well understood'by those skilled in this art.
It is well-known to those skilled inthis art that the explosive for railway signal torpedoes is made either in the form of a loose powder or a molded tablet, and my improved composition is adapted to be used in either of the above' forms, or partly tablet and partly'loose powder, as will be pointed out hereinafter.
The primary objects of my improved composition for railway signal torpedoes are- 1. To produce a louder detonation for a given quantity. of composition, whereby the amount of composition used may be reduced,
thus effecting economy in the manufacture,
torpedo, and; would be of value to the train tions now in use.
and at the same time to enable a smaller torpedo to be used, which among other advantages, is less liable to be pushed from the track, by the locomotive wheel than a larger men because of the reduced size, enabling a greater number to be carried in a given space. 2. Toaadd to the saftey in the manufacture sensitiveness ofv previous torpedo compositions to friction and spontaneous ignition, which are present in the torpedo composi- 3. To produce a railway signal torpedo composition, which adds a signal flash to the signal detonation, whereby the engineer may see as well as hear the explosion of the torpedo which takes place the'instant it is struck by the en ine. y
y improved composition which involves all the foregoing objects is composed of perchlorate, aluminum, sulphur, barium nitrate,
sand or sharp flint; and when made in tablet form dextrine is added as a binder. If, .how-
Signal Torpedoes, of which the pilot wheels at the front end of the Specification of Letterslatent. Patnted an. 24, 1922. Application filed October 7, 1920. Serial No. 415,264.
"ever, the composition is to be used in powder form dextrine is omitted, and in either form of the composition'the sand or flint may be omitted if desired.
" In practice, I haveused the foregoing ingredients in substantially the following proportions:
The foregoing proportions of the several parts may be widely varied either way without departing fromthe spirit and scope of my present invention.
The foregoing composition can'be made to give a more brilliant flash, but at somewhat more expense, by the addition of magnesium, and also magnesium can be substituted entirely for the aluminum.
This composition may be manufactured as a moulded plastic without the aluminum or magnesium, or both, and then the desired amount of either aluminum or magnesium,
or both, added as a loose binder in the case or envelope containing the explosive composition.
Furthermore, barium nitrate may be omitted, but I find that better results are obtained by its use than without it.
The perchlorate adds to .the safety of the manufacture of the torpedo and safety in the storage of the torpedoes and at the same time adds to the sharpness of its detonation.
The function of the aluminum or magnesium, or both, is primarily twofold. One
to furnish a flash and the other to cause a thermite reaction, causing a violent combining with the oxygen of the composition, thus adding to the violence of the detonation. The aluminum or magnesium, or both, rapidly extracts the oxygen from the other chemicals of the compound so that the violence of their action adds to the sharpness and loudness of the detonation.
It may be added here that the perchlorate in this compositionincreases the thermite effect, and thereby adds also to the sharpness and violence of the detonation.
The barium in this composition not only imparts insensitiveness, but also furnishes additional oxygen to be extracted by the aluminum or magnesium, or both. It' allows the last-mentioned chemicals to do more Work by rapid extraction of the oxygen, and this adds to the flash as well as the detonation.
Aluminum, I find, is a better extractor of oxygen than magnesium, and it is also cheaper and, therefore, under ordinary conditions, preferable to the use of magnesium.
I desire it to be understood that where a flash is notdesired the aluminum, or magnesium, or both, may be omitted from the composition, and in this event, the remaining ingredients produce a composition having the advantages of louder detonation and combined in substantially the proportions specified for producing a torpedo with inducing a sharp flash detonation, and a composition which is not subject to spontaneous ignition.
3. An improved explosive composition for railway signal torpedoes, comprising sulphur one part,- aluminum one and threefourths parts, barium nitrate one part and perchlorate two parts, combined in substantially the proportions specified, producing a composition with a sharp flash detonation and which is not subject to spontaneous ignition.
r 4. An improved composition for railway signal torpedoes, comprising a perchlorate and barium nitrate combined for the purpose described.
In testimony whereofI hereunto aflix my signature.
LOUIS S. ROSS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US415264A US1404653A (en) | 1920-10-07 | 1920-10-07 | Composition for railway signal torpedoes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US415264A US1404653A (en) | 1920-10-07 | 1920-10-07 | Composition for railway signal torpedoes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1404653A true US1404653A (en) | 1922-01-24 |
Family
ID=23645000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US415264A Expired - Lifetime US1404653A (en) | 1920-10-07 | 1920-10-07 | Composition for railway signal torpedoes |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1404653A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2451864A (en) * | 1945-05-15 | 1948-10-19 | Daniel P O'brien | Explosives |
| US3508518A (en) * | 1968-05-27 | 1970-04-28 | Dow Chemical Co | Combination night-day signaling device |
| US4307665A (en) * | 1965-12-21 | 1981-12-29 | General Dynamics Corporation | Decoy rounds |
| US4355577A (en) * | 1979-08-24 | 1982-10-26 | Ady Michael S | Model rocket propulsion system |
-
1920
- 1920-10-07 US US415264A patent/US1404653A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2451864A (en) * | 1945-05-15 | 1948-10-19 | Daniel P O'brien | Explosives |
| US4307665A (en) * | 1965-12-21 | 1981-12-29 | General Dynamics Corporation | Decoy rounds |
| US3508518A (en) * | 1968-05-27 | 1970-04-28 | Dow Chemical Co | Combination night-day signaling device |
| US4355577A (en) * | 1979-08-24 | 1982-10-26 | Ady Michael S | Model rocket propulsion system |
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